KR101819467B1 - Piezoelectric cosmetic composition - Google Patents

Piezoelectric cosmetic composition Download PDF

Info

Publication number
KR101819467B1
KR101819467B1 KR1020160109329A KR20160109329A KR101819467B1 KR 101819467 B1 KR101819467 B1 KR 101819467B1 KR 1020160109329 A KR1020160109329 A KR 1020160109329A KR 20160109329 A KR20160109329 A KR 20160109329A KR 101819467 B1 KR101819467 B1 KR 101819467B1
Authority
KR
South Korea
Prior art keywords
piezoelectric
skin
cosmetic composition
present
liquid crystal
Prior art date
Application number
KR1020160109329A
Other languages
Korean (ko)
Inventor
홍성윤
장지희
김수지
이준배
김연준
유권종
황희윤
안준혁
황상균
Original Assignee
코스맥스 주식회사
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 코스맥스 주식회사 filed Critical 코스맥스 주식회사
Priority to KR1020160109329A priority Critical patent/KR101819467B1/en
Priority to PCT/KR2017/000770 priority patent/WO2018038333A1/en
Priority to US16/082,421 priority patent/US20190083368A1/en
Priority to CN201780047568.0A priority patent/CN109562028B/en
Application granted granted Critical
Publication of KR101819467B1 publication Critical patent/KR101819467B1/en

Links

Images

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0295—Liquid crystals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216—Solid or semisolid forms
    • A61K8/022—Powders; Compacted Powders
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/27—Zinc; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A61K8/553—Phospholipids, e.g. lecithin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/63—Steroids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/68—Sphingolipids, e.g. ceramides, cerebrosides, gangliosides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/805—Corresponding aspects not provided for by any of codes A61K2800/81 - A61K2800/95

Abstract

The present invention relates to a cosmetic composition having piezoelectric properties and, more specifically, to a piezoelectric cosmetic composition comprising a piezoelectric material generating micro current when pressure is applied as an active ingredient. According to the present invention, a piezoelectric cosmetic composition is applied to the skin and micro current is generated when a user gets a massage so skin care effects such as a skin elasticity improvement effect can be maximized.

Description

압전 화장료 조성물{Piezoelectric cosmetic composition} [0001] Piezoelectric cosmetic composition [0002]

본 발명은 압전성을 가지는 화장료 조성물에 관한 것으로서, 더욱 상세하게는 압력을 가하였을 때 미세전류를 발생하여 피부 탄력을 증진시키는 압전 화장료 조성물 개발에 관한 것이다. The present invention relates to a cosmetic composition having piezoelectricity, and more particularly, to the development of a piezoelectric cosmetic composition for improving skin elasticity by generating a microcurrent when a pressure is applied.

인체 내에는 각 기관 사이의 신호 전달을 위하여 미세전류가 흐르고 있다. 일반적으로 건강이 악화되거나 신체 상태가 불안정해지면 인체 내에 흐르는 미세전류가 약해진다. 이를 보완하기 위하여 미세전류를 발생시키는 기기를 사용하여 인체에 흘려주어 활성을 증대시켜준다. 문헌 Military Medical Research, 2014, 1:24에 의하면 미세전류는 상처 난 피부 세포에 자극을 주어 치유에 도움을 주며, Journal of Physical Therapy Science, 2011, 23, 515-518에 의하면 혈류속도를 증가시켜 혈액순환에 도움을 주는 것으로 알려져 있다. 특히, Homeopathy, 2012, 101, 147-153에 의하면 피부에 미세전류 도입시 콜라겐 섬유가 두꺼워지며, 피부 조밀도가 상승하여 피부 탄력 증진에 효과를 주는 것으로 알려져 있다. Clin Orthop, 1982, 171, 264-272에 의하면 미세전류 도입시 아미노산의 흡수를 증진시키는 것으로 나타났다. In the human body, micro current flows for signal transmission between the organs. In general, when the health deteriorates or the body condition becomes unstable, the microcurrent flowing through the body weakens. In order to compensate for this, the micro-current generating device is used to increase the activity by flowing into the human body. According to Military Medical Research, 2014, 1:24, microcurrent stimulates wounded skin cells to help heal, and according to the Journal of Physical Therapy Science, 2011, 23, 515-518, It is known to help with circulation. In particular, according to Homeopathy, 2012, 101, 147-153, collagen fibers are thickened when microcurrent is introduced into skin, and it is known that skin denseness increases, thereby improving skin elasticity. According to Clin Orthop, 1982, 171, 264-272, it was shown that the microcurrent induces the absorption of amino acids.

최근에는 이러한 결과를 바탕으로 미세전류 발생 미용기기를 출시하고 있으며, 그 예로서 등록특허 제10-1050069호(이온도입기능을 갖는 휴대용 맛사지기), 제10-0614799호(휴대용 피부 미용기), 제10-1209102호(전기자극 기능을 가지는 미세전류 기기) 등이 있다. 또한, 피부 전문가의 도움으로 진피까지 도달이 어려운 효능 성분 물질을 주사로 투입하는 등의 방법으로 피부를 관리하는 경우도 많다. 그러나, 미용기기 이용시에 발생하는 충전 또는 배터리 장착, 고장 발생, 휴대의 어려움, 경제성 문제, 피부과 방문, 주사에 의한 자극 등의 번거로움이 발생하는 문제가 있다. In recent years, micro-current generating beauty devices have been introduced based on these results. Examples of such beauty devices include a portable massage machine having an ion introducing function, Patent No. 10-1050069, a portable massage machine having an ion introducing function, -1209102 (micro-current device having electric stimulation function). In addition, there are many cases where the skin is managed by injecting an effective ingredient substance hard to reach the dermis with the help of a skin specialist. However, there arises a problem that troubles such as charging or battery mounting occurring at the time of using a beauty device, occurrence of trouble, difficulty of carrying, economic problem, dermatological visit, irritation by injection occur.

이에, 본 발명자들은 상기 미용기기 또는 피부 전문가 도움 등에 의해 발생하는 한계점들을 극복하기 위해 별도의 미용기기 없이 쉽게 미세전류를 발생시킬 수 있는 방법을 연구하던 중, 화장료 조성물 내에 압력을 가하였을 때 미세전류를 발생시킬 수 있는 압전물질(piezoelectric material)을 포함시킨 경우 화장료를 피부에 적용하여 누르거나 문지를 때 자연스럽게 미세전류를 발생시켜 피부미용에 도움을 줄 수 있음을 발견하고, 본 발명을 완성하게 되었다.Accordingly, the inventors of the present invention have been studying a method capable of easily generating microcurrent without additional beauty equipment in order to overcome the limitations caused by the help of the beauty device or the skin specialist. When the microcurrent is generated in the cosmetic composition, The present invention has been accomplished on the basis of finding that a cosmetic material can be applied to the skin to naturally generate micro currents when pressed or rubbed to help skin beauty.

KRKR 10-105006910-1050069 BB KRKR 10-061479910-0614799 BB KRKR 10-120910210-1209102 BB

본 발명의 주요 목적은 상기 문제점을 개선하기 위한 것으로서, 미세전류 발생 미용기기 사용시에 발생하는 불편함을 없애고자 화장료 조성물 내에 압전물질을 내포하여 피부에 도포시 미세전류를 유도함으로써 피부 마사지 효과 및 피부 관리 효과를 극대화할 수 있는 압전 화장료 조성물을 제공하는 것에 있다.The main object of the present invention is to solve the above problem, and it is an object of the present invention to provide a skin care cosmetic composition containing a piezoelectric substance in a cosmetic composition in order to eliminate the inconvenience caused when using a micro- And to provide a piezoelectric cosmetic composition capable of maximizing the management effect.

상기 목적을 달성하기 위하여, 본 발명은 피부에 적용하는 화장료 조성물에 있어서, 압력을 가하였을 때 미세전류를 발생할 수 있는 압전물질(piezoelectric material)을 유효성분으로 포함하는 것을 특징으로 하는 압전 화장료 조성물을 제공한다.In order to achieve the above object, the present invention provides a cosmetic composition for skin, which comprises, as an active ingredient, a piezoelectric material capable of generating a microcurrent upon application of pressure, to provide.

압전 현상은 재료에 압력이 가해졌을 때 변형에 의해(기계에너지) 내부 분극이 변화하여 전하가 발생하는 것(전기에너지)으로 1880년 Jacques와 Pierre Curie에 의해 석영에서 최초로 관찰되었다. 대표적인 압전성 물질로는 Brium titanate(BaTiO3), Lead zirconate titanate(Pb(Zr,Ti)O3, PZT) 등 무기 압전 소자가 있다. 최근에는 압전성 고분자 물질로 PVDF가 관심을 끌고 있으며, 그밖에도 금속산화물 등의 고체 재료를 사용한다. 산업적으로는 이들 재료를 센서, 필터, 공진기, 액추에이터, 스피커, 에너지 하베스팅 등에 응용하여 다양한 분야에서 사용하고 있으나, 아직까지 화장료 조성물 분야에 사용된 적은 없다.Piezoelectric phenomena were first observed in quartz by Jacques and Pierre Curie in 1880 (electric energy), in which internal polarization changes due to deformation (mechanical energy) when material is pressurized and electrical charge is generated. Typical piezoelectric materials include inorganic piezoelectric elements such as barium titanate (BaTiO 3 ) and lead zirconate titanate (Pb (Zr, Ti) O 3 , PZT). In recent years, PVDF has attracted attention as a piezoelectric polymer material. In addition, solid materials such as metal oxides are used. Industrially, these materials are used in various fields by applying them to sensors, filters, resonators, actuators, speakers, energy harvesting, etc. However, they have not been used in the field of cosmetic compositions.

본 발명에 있어서, 상기 압전 물질은 압력을 가하였을 때 미세전류를 발생시킬 수 있기 때문에 이를 포함하는 화장료를 피부에 적용하여 누르거나 문지를 때 자연스럽게 미세전류를 발생시켜 피부미용에 도움을 줄 수 있다. 본 발명에 있어서, 바람직하게는 상기 압전물질은 액상 압전 물성 측정 장치로 측정하였을 때 1 내지 20 pC/N의 압전상수를 나타내는 것을 특징으로 한다. 본 발명자들은 액상 재료의 압전 물성을 측정할 수 있는 장치를 고안한 후 (한국특허출원 제10-2016-0095633호 참조). 여러 가지 압전물질을 포함하는 화장료 조성물의 압전물성을 측정한 결과, 상기 수치범위내의 압전상수를 나타냄을 확인하였다.In the present invention, since the piezoelectric material can generate a microcurrent when pressure is applied thereto, the cosmetic material containing the same can be applied to the skin to naturally generate minute currents when pressed or rubbed, thereby helping skin. In the present invention, preferably, the piezoelectric material exhibits a piezoelectric constant of 1 to 20 pC / N as measured by a liquid phase piezoelectric property measuring device. The present inventors have devised a device capable of measuring the piezoelectric properties of a liquid material (see Korean Patent Application No. 10-2016-0095633). As a result of measuring the piezoelectric properties of the cosmetic composition containing various piezoelectric materials, it was confirmed that the piezoelectric constant was within the above-mentioned range.

본 발명에 있어서, 상기 압전물질은 압력을 가하였을 때 미세전류를 발생시킬 수 있는 종래 알려진 어떤 압전성 물질도 포함하나, 바람직하게는 액정에멀젼 자체, 무기안료 분체, 압전소자 또는 압전폴리머인 것을 특징으로 하는 압전 화장료 조성물을 제공한다.In the present invention, the piezoelectric material includes any known piezoelectric material capable of generating a microcurrent when pressure is applied, but is preferably a liquid crystal emulsion itself, an inorganic pigment powder, a piezoelectric element, or a piezoelectric polymer The present invention provides a piezoelectric cosmetic composition comprising

본 발명자들은 이종산업인 액정 디스플레이 산업에서 사용되는 액정상의 압전성을 갖는 특징(Liquid Crystals, 2010, 37, 825-837 참조)에서 아이디어를 얻어, 종래 화장료로 사용되는 액정 에멀젼도 압전성을 가질 수 있음에 착안하여 액정 에멀젼과 일반 에멀젼을 제조하여 압전 물성을 측정한 결과 액정 에멀젼이 일반 에멀젼과 달리 압전 물성을 나타내며 그로인해 피부 탄력도가 증진된다는 사실을 확인하였다.The inventors of the present invention have obtained the idea of piezoelectricity characteristics (Liquid Crystals, 2010, 37, 825-837) used in the liquid crystal display industry, which is a heterogeneous industry, and liquid crystal emulsions conventionally used as cosmetics can have piezoelectricity As a result of measuring the piezoelectric properties of liquid crystal emulsion and general emulsion, it was confirmed that liquid crystal emulsion exhibits piezoelectric property unlike general emulsion, thereby improving skin elasticity.

본 발명에 있어서, 압전물질로 사용되는 액정 에멀젼은 종래 화장료분야에서 알려진 액정 유화 기술로 제조되는 어떤 액정 에멀젼도 사용될 수 있으며, 예컨대, 온도에 따라 변화되는 써모트로픽 액정(Thermotropic Liquid Crystal) 또는 조성의 변화에 따라 변화되는 라이오트로픽 액정(Lyotropic Liquid Crystal)도 될 수 있으며, 이중에서 라이오트로픽 액정은 예컨대, 세틸알코올, 스테아릴알코올 등과 같은 지방알코올을 사용하는 방법, 콜레스테롤, 콜레스테릴미리스테이트나 세라마이드를 이용하는 방법, 또는 레시틴과 같은 인지질을 이용하는 방법이 사용될 수 있다.In the present invention, a liquid crystal emulsion to be used as a piezoelectric substance may be any liquid crystal emulsion produced by a liquid crystal emulsification technique known in the cosmetics field. For example, a thermotropic liquid crystal or a composition of a composition The lyotropic liquid crystal may be a method of using fatty alcohols such as cetyl alcohol and stearyl alcohol, a method of using cholesterol, cholesteryl myristate or ceramide , Or a method using a phospholipid such as lecithin can be used.

본 발명에 있어서, 압전물질로 사용되는 무기안료 분체는 종래 화장료분야에서 사용되던 어떤 무기안료 분체도 사용될 수 있으며, 예컨대, 티타늄디옥사이드(TiO2), 징크옥사이드(ZnO)과 같은 백색안료 뿐만 아니라, 실리카(SiO2), 마이카와 같은 체질안료도 포함될 수 있다. 본 발명자들은 액정 에멀젼이 일반 에멀젼에 여러 가지 무기 안료 분체를 포함시켜 압전 물성을 측정한 결과 이를 포함하지 않는 일반 에멀젼과 달리 압전 물성을 나타내며, 무기 안료 분체의 양을 증가시킴에 따라 압전 물성도 커지는 것을 확인하였다.The inorganic pigment powder used as the piezoelectric material in the present invention may be any inorganic pigment powder conventionally used in the field of cosmetics. Examples of the inorganic pigment powder include white pigments such as titanium dioxide (TiO 2 ) and zinc oxide (ZnO) And extender pigments such as silica (SiO 2 ), mica, and the like. The inventors of the present invention have found that liquid crystal emulsions contain various inorganic pigment powders in a general emulsion to measure their piezoelectric properties and, as a result, they exhibit piezoelectric properties unlike ordinary emulsions which do not contain such inorganic emulsions. As the amount of inorganic pigment powders increases, Respectively.

본 발명에 있어서, 압전물질로 사용되는 압전소자는 종래 압전소자로 널리 알려진 수정, 티탄산바륨, 티탄산지르콘산납, 또는 이들을 소결한 압전 세라믹 등의 압전소자가 포함될 수 있으며, 압전물질로 사용되는 압전폴리머는 종래 압전성이 알려진 polyvinylidene fluoride (PVDF), polyamides, ParyleneC 등의 폴리머가 포함될 수 있다.In the present invention, the piezoelectric element used as the piezoelectric material may include piezoelectric elements such as quartz, titanium barium titanate, lead zirconate titanate, sintered piezoelectric ceramics, and the like widely known as conventional piezoelectric elements. May include polymers such as polyvinylidene fluoride (PVDF), polyamides, and ParyleneC, which are known for their piezoelectric properties.

본 발명에 있어서, 상기 압전물질은 액정에멀젼 자체인 경우에는 화장료 조성물의 일부 또는 전체 제형이 될 수 있으며, 그 외 무기 안료 분체 등의 경우에는 화장료 조성물의 총중량 대비 1 내지 10 중량% 함유되어 있는 것을 특징으로 하는 압전 화장료 조성물을 제공한다.In the present invention, the piezoelectric substance may be a part or whole formulation of the cosmetic composition in the case of the liquid crystal emulsion itself, or in the case of the inorganic pigment powder in an amount of 1 to 10% by weight based on the total weight of the cosmetic composition Which is characterized by providing a piezoelectric cosmetic composition.

본 발명에 있어서, 상기 압전물질에 의해 발생된 미세전류는 화장료의 피부침투를 도와줄 뿐만 아니라 피부자극을 통해 피부탄력을 개선하는 것을 특징으로 하는 압전 화장료 조성물을 제공한다. 본 발명자들은 상기 압전물질을 포함한 화장료 조성물이 이를 포함하지 않는 화장료조성물보다 피부탄력을 증가시켜 피부활성에 도움을 준다는 것을 확인하였다.In the present invention, the microcurrent generated by the piezoelectric material not only helps penetrate the skin of the cosmetic, but also improves skin elasticity through skin irritation. The present inventors have confirmed that the cosmetic composition containing the piezoelectric material is more effective for skin activation than the cosmetic composition not containing the same by increasing skin elasticity.

본 발명에 있어서, 상기 압전 화장료 조성물은 압전물질을 유효성분으로 포함하는 것을 제외하고는 일반적인 화장료 조성물의 성분을 포함할 수 있으며, 예컨대, 물, 오일, 폴리올, 계면활성제, 및 보습제로 구성된 군에서 선택된 어느 하나 이상의 화장료를 더 포함하는 것을 특징으로 하는 압전 화장료 조성물을 제공한다.In the present invention, the piezoelectric cosmetic composition may comprise components of a common cosmetic composition except that it contains a piezoelectric material as an active ingredient, and may be a cosmetic composition such as water, an oil, a polyol, a surfactant, And further comprising at least one selected cosmetic material selected from the group consisting of cosmetics and cosmetics.

본 발명에 있어서, 상기 화장료 조성물은 화장수, 스킨, 로션, 크림 또는 에센스의 제형을 갖는 것을 특징으로 하는 압전 화장료 조성물을 제공한다.In the present invention, the cosmetic composition is provided with a formulation of lotion, skin, lotion, cream or essence.

본 발명에 따르면, 미세전류를 발생시킬 수 있는 압전물질을 화장료 조성물에 포함시킴으로써 피부에 도포하고 마사지시에 미세전류를 발생하여 피부 탄력 개선 효과 등 피부관리 효과를 극대화 시킬 수 있다. According to the present invention, it is possible to maximize the skin care effect such as skin elasticity improving effect by applying a piezoelectric material capable of generating a microcurrent to the skin by applying the piezoelectric substance to the skin and generating minute current during massage.

도 1은 화장료의 압전 물성을 측정하기 위한 장치의 개략도이다. 밀폐된 용기내에 액체 시료(speciment)를 넣고 수직 하중(vertical load)을 인가하면서 시료 양측에 위치한 전극(electrodes)사이의 전하량을 측정한다.
도 2는 비교예 1 ~ 2 및 실시예 1 ~ 3의 화장료 조성물의 압전 물성을 비교한 그래프이다.BRIEF DESCRIPTION OF DRAWINGS FIG. 1 is a schematic view of an apparatus for measuring piezoelectric properties of a cosmetic. Put a liquid specimen in a closed container and measure the amount of charge between the electrodes located on both sides of the sample while applying a vertical load.
2 is a graph comparing the piezoelectric properties of the cosmetic compositions of Comparative Examples 1 to 2 and Examples 1 to 3.

이하 실시예를 통하여 본 발명을 더욱 구체적으로 설명하기로 한다. 이들 실시예는 단지 본 발명을 설명하기 위한 것이므로, 본 발명의 범위가 이들 실시예에 국한되지 않는다는 것은 당업자에게 있어서 자명하다.Hereinafter, the present invention will be described in more detail with reference to examples. It is apparent to those skilled in the art that these embodiments are merely illustrative of the present invention, and thus the scope of the present invention is not limited to these embodiments.

[시험예 1]: 비교예 및 실시예 제조[Test Example 1]: Preparation of Comparative Examples and Examples

본 발명에서 사용되는 일반 에멀젼과 액정 에멀젼을 제조하기 위해 다음의 표 1과 같은 조성으로 에멀젼을 제조하였다.In order to prepare the general emulsion and the liquid crystal emulsion to be used in the present invention, an emulsion was prepared with the composition shown in Table 1 below.

성분ingredient 비교예 1Comparative Example 1 비교예 2Comparative Example 2 실시예 1Example 1 실시예2Example 2 실시예3Example 3 1. polydecene1. polydecene 0.0090.009 -- -- -- -- 2. Squalane2. Squalane 0.00050.0005 -- -- -- -- 3. Cetearyl alcohol3. Cetearyl alcohol -- -- 44 -- -- 4. C14-22 alcohol4. C14-22 alcohol -- -- 1.61.6 -- -- 5. Vitamin E acetate5. Vitamin E acetate -- 0.20.2 -- 0.20.2 0.20.2 6. Glyceryl stearate SE6. Glyceryl stearate SE -- -- 0.50.5 -- -- 7. Caprylic/capric triglyceride7. Caprylic / capric triglyceride -- 33 1010 33 33 8. PEG/PPG-19/19 dimethicone8. PEG / PPG-19/19 dimethicone -- 1.51.5 0.10.1 1.51.5 1.51.5 9. Dimethicone9. Dimethicone 33 -- -- -- -- 10. Cyclomethicone10. Cyclomethicone 33 -- -- -- -- 11. Cetyl dimethicone11. Cetyl dimethicone 33 -- -- -- -- 12. Dimethicone/vinyl dimethicone crosspolymer12. Dimethicone / vinyl dimethicone crosspolymer 33 -- -- -- -- 13. cyclopentasiloxane13. cyclopentasiloxane -- 21.521.5 -- 21.521.5 21.521.5 14. C12-20 alkyl glucoside14. C12-20 alkyl glucoside -- -- 0.40.4 -- -- 15. Hydrogenated lecithin15. Hydrogenated lecithin -- -- 0.10.1 -- -- 16. D.I. Water16. D.I. Water To 100To 100 To 100To 100 To 100To 100 To 100To 100 To 100To 100 17. 1% EDTA-2Na solution17. Add 1% EDTA-2Na solution 22 22 22 22 22 18. Sodium PCA18. Sodium PCA 0.50.5 -- -- -- -- 19. Sodium glutamate19. Sodium glutamate -- 0.50.5 -- 0.50.5 0.50.5 20. Dipropylene glycol20. Dipropylene glycol -- 1010 -- 1010 1010 21. Butylene glycol21. Butylene glycol 22 -- -- -- -- 22. Glycerin22. Glycerin 55 1010 1515 1010 1010 23. 1% Carbomer solution23. 1% Carbomer solution -- -- 1212 -- -- 24. Triethanolamine24. Triethanolamine -- -- 0.10.1 -- -- 25. presevatives25. presevatives 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount 적량Suitable amount 26. Perfume26. Perfume 0.10.1 0.10.1 0.10.1 0.10.1 0.10.1 27. 압전물질(zinc oxide)27. Zinc oxide -- -- -- 44 -- 28. 압전물질(titanium dioxide)28. Titanium dioxide -- -- -- -- 44

1) 상기 표 1에서 1 ~ 15은 유용성 성분이고, 이 중 3, 4는 고급 지방알코올이고, 14, 15는 비(非) POE계 비이온 계면활성제이고, 16 ~ 24는 수용성 성분으로 이 중 20 ~ 22는 폴리올이고, 23, 24는 점도 조절제이고, 25은 보존제이며 26은 향 성분이고, 27, 28은 압전물질이다.1) In Table 1, 1 to 15 are oil-soluble components, 3 and 4 are higher fatty alcohols, 14 and 15 are non-POE nonionic surfactants, 16 to 24 are water- 20 to 22 are polyols, 23 and 24 are viscosity regulators, 25 are preservatives, 26 are fragrance components, and 27 and 28 are piezoelectric materials.

2) 상기 표 1에서 원료 1 ~ 15를 혼합하고, 70 ~ 80 ℃에서 용해하여 유상용액을 제조하였다. 2) Ingredients 1 to 15 were mixed in Table 1 and dissolved at 70 to 80 ° C to prepare an oil solution.

3) 별도의 용기에 상기 표 1의 원료 16 ~ 22를 혼합하고, 70 ~ 80 ℃까지 가온 용해하여 수상용액을 제조하였다.3) Ingredients 16 to 22 shown in Table 1 were mixed in a separate vessel and dissolved by heating to 70 to 80 ° C to prepare an aqueous solution.

4)-1 상기 2)의 유상용액을 상기 3)의 수상용액에 천천히 첨가하고, 호모 믹서로 교반하였다. (실시예 1)4) -1 The oily solution of 2) above was slowly added to the aqueous solution of 3) and stirred with a homomixer. (Example 1)

4)-2 상기 3)의 수상용액을 상기 2)의 유상용액에 천천히 첨가하고, 호모 믹서로 교반하였다. (비교예 1 및 2, 실시예 2 및 3)4) -2 The aqueous solution of the above 3) was slowly added to the oil solution of 2) and stirred with a homomixer. (Comparative Examples 1 and 2, Examples 2 and 3)

5) 상기 4)의 혼합용액에 표 1의 원료 23을 혼합하고 이어서 원료 24를 혼합하였다.5) The raw material 23 of Table 1 was mixed with the mixed solution of 4), and then the raw material 24 was mixed.

6) 실시예 1은 상기 5)의 과정 완료 후 10분 내에 40 ℃까지 급냉하였다. 이 후, 표 1의 원료 25와 26을 투입한 후 탈포하였다.6) Example 1 was quenched to 40 占 폚 within 10 minutes after the completion of the above step 5). Thereafter, the raw materials 25 and 26 shown in Table 1 were introduced and then defoamed.

7) 비교예 1 ~ 2는 상기 5)의 과정 완료 후 상온 방치하고 표 1의 원료 25와 26을 투입한 후 탈포하였다.7) Comparative Examples 1 and 2 were allowed to stand at room temperature after completion of the process of 5), and the raw materials 25 and 26 shown in Table 1 were introduced and then defoamed.

8) 실시예 2 ~ 3은 상기 5)의 과정 완료 후 상온 방치하고, 표 1의 원료 25와 26을 투입한 후 각각 27과 28의 압전물질을 분산하고 탈포하였다.8) Examples 2 and 3 were left at room temperature after completing the process of 5), and after feeding the raw materials 25 and 26 of Table 1, 27 and 28 piezoelectric materials were dispersed and defoamed, respectively.

간략히 비교예 1, 2는 일반 W/O 에멀젼이고, 실시예 1은 액정 에멀젼이며, 실시예 2, 3은 압전소자를 함유한 일반 에멀젼이다.Briefly, Comparative Examples 1 and 2 are general W / O emulsions, Example 1 is a liquid crystal emulsion, and Examples 2 and 3 are general emulsions containing piezoelectric elements.

상기 실시예 1의 액정 에멀젼은 비(非)POE계 비(非)이온성인 레시틴과 글루코사이드계 계면활성제를 혼합하여 제조하였으며, 급냉공정 적용 후 세포간지질을 함유하는 안정한 다층 라멜라 구조를 갖는 액정 에멀젼이고, 이를 편광 현미경으로 측정하여 액정상이 형성되었음을 확인하였다.The liquid crystal emulsion of Example 1 was prepared by mixing a non-POE non-ionic lecithin and a glucoside surfactant. After applying the quenching process, a liquid crystal emulsion having a stable multilamellar structure containing cell intercellular quality And it was confirmed by polarizing microscope that a liquid crystal phase was formed.

[시험예 2]: 압전 에멀젼의 압전성 테스트[Test Example 2]: Piezoelectricity test of piezoelectric emulsion

상기 시험예 1에서 제조한 실시예 1 및 비교예 1 ~ 3을 액상 압전 측정 장비를 이용하여 압전 물성을 다음과 같이 측정하여 표 2에 나타내었다. The piezoelectric properties of Example 1 and Comparative Examples 1 to 3 prepared in Test Example 1 were measured using a liquid-phase piezoelectric measuring instrument as shown in Table 2 below.

<측정 방법><Measurement method>

1) 각 샘플 55 μL를 전극사이에 넣고 모터 스테이지를 이동시켜 4 ~ 10 N의 하중을 반복하여 가한다. 1) Put 55 μL of each sample between the electrodes, move the motor stage, and apply a load of 4 ~ 10 N repeatedly.

2) 인가된 하중 및 샘플로부터 발생한 전하량을 계측한다.2) Measure the applied load and the charge generated from the sample.

실험항목Experiment Item 비교예 1Comparative Example 1 비교예 2Comparative Example 2 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 압전 물성 (pC/N)Piezoelectric properties (pC / N) -- -- 11.911.9 12.812.8 3.13.1

그 결과, 표 2에 나타난 바와 같이 일반 W/O 에멀젼인 비교예 1, 2의 경우 압전성이 나타나지 않았으며, 액정 에멀젼인 실시예 1의 경우 11.9로 고분자 압전소자 수준의 압전 상수값을 가지는 것으로 확인하였다. 실시예 2, 3의 경우 압전소자를 함유한 에멀젼으로 각각 12.8, 3.1의 값을 가지는 것으로 확인하였다. 따라서, 산화아연을 함유한 에멀젼에서 가장 높은 압전성을 갖는 것으로 확인하였다. As a result, as shown in Table 2, piezoelectric properties were not observed in Comparative Examples 1 and 2, which are general W / O emulsions, and 11.9 in Example 1, which is a liquid crystal emulsion, Respectively. In Examples 2 and 3, it was confirmed that the emulsion containing piezoelectric elements had values of 12.8 and 3.1, respectively. Therefore, it was confirmed that the emulsion having zinc oxide had the highest piezoelectric property.

[시험예 3]: 압전 에멀젼의 피부 안전성 테스트[Test Example 3]: Skin safety test of piezoelectric emulsion

피부 질환이 없는 성인 남녀 10명을 대상으로 하여 상기 실시예 1 ~ 3 및 비교예 1 ~ 2에 대하여 자극 정도를 다음과 같이 평가하였다. 시험자들의 팔 전박에 20 μL의 시료를 도포한 후, 시험 부위를 밀폐한 후 24시간 동안 첩포하고, 첩포를 제거한 후 30분, 24시간 후에 피부에서의 반응을 CTFA(Cosmetic, Toiletry and Fragrance Association) 가이드라인에 제시된 terminology에 의거하여 검사하였다. 판정기준은 시험자들의 점수를 평균하여 0이면 무자극, 1미만이면 저자극, 3미만이면 경자극, 5미만이면 중자극, 5이상이면 강자극으로 평가한다. 자극 평가를 하기 표 3에 나타내었다.10 adult males and females without skin disease were evaluated for the degree of stimulation according to Examples 1 to 3 and Comparative Examples 1 and 2 as follows. After applying 20 μL of the sample to each arm of the tester, the test site was closed, and the skin was applied for 24 hours. After 30 minutes and 24 hours after removing the skin patch, the skin reaction was analyzed by CTFA (Cosmetic, Toiletry and Fragrance Association) The test was conducted according to the terminology presented in the guidelines. The criterion is averaged score of 0, 0, 0, 1, 2, 3, 5, and 5, respectively. The stimulation evaluation is shown in Table 3 below.

실험항목Experiment Item 비교예 1Comparative Example 1 비교예 2Comparative Example 2 실시예 1Example 1 실시예 2Example 2 실시예 3Example 3 피부자극지수 (PII)Skin irritation index (PII) 무자극No stimulation 무자극No stimulation 무자극No stimulation 무자극No stimulation 무자극No stimulation

그 결과, 상기 표 3에 나타낸 바와 같이 실시예 1 ~ 3 및 비교예 1 ~ 2에서 모두 무자극으로 제품에 안전하게 사용가능함을 확인하였다.As a result, as shown in Table 3, it was confirmed that all of Examples 1 to 3 and Comparative Examples 1 and 2 can be safely used on products with no stimulation.

[시험예 4]: 압전 에멀젼의 피부 탄력 평가[Test Example 4] Evaluation of Skin Elasticity of Piezoelectric Emulsion

다음으로 상기 시험예 1에서 만든 비교예 2(일반 W/O 에멀젼)과 실시예 1의 피부 탄력도를 알아보기 위해 일반 남녀 5명을 대상으로 피부에 일정량 도포 후 2주 후 및 4주 후에 피부 탄력도를 측정한 결과를 표 4에 나타내었다.Next, in order to examine the skin elasticity of Comparative Example 2 (general W / O emulsion) prepared in Test Example 1 and the skin elasticity of Example 1, skin elasticity was measured after 2 weeks and 4 weeks after a certain amount of application to skin The results are shown in Table 4. &lt; tb &gt; &lt; TABLE &gt;

피부 탄력도Skin elasticity 비교예 2Comparative Example 2 실시예 1Example 1 2주2 weeks 3.73.7 4.44.4 4주4 weeks 5.35.3 8.88.8

피부 탄력도를 확인한 결과, 비교예 2의 경우 3.7이었던 2주에서 4주 피부 탄력도가 1.4배로 증가한 반면, 실시예 1(액정 에멀젼)의 경우 2주에서 4주 피부 탄력도가 2배로 증가한 것으로 나타났다. The skin elasticity was increased from 2 weeks to 4 weeks in Comparative Example 2 to 1.4 times in the case of Comparative Example 2, whereas in Example 1 (liquid crystal emulsion), skin elasticity increased from 2 weeks to 4 weeks.

따라서 본 발명에 따른 액정 에멀젼이 피부 활성에 도움을 주는 화장료로 사용될 수 있을 것으로 생각된다. Therefore, it is considered that the liquid crystal emulsion according to the present invention can be used as a cosmetic material that helps skin activity.

Claims (6)

피부에 적용하는 화장료 조성물에 있어서, 피부에 도포시 압력에 의해 미세전류를 발생할 수 있는 압전물질(piezoelectric material)로서 액정에멀젼 자체를 유효성분으로 포함하는 것을 특징으로 하는 압전 화장료 조성물.
A cosmetic composition for application to skin comprising a liquid crystal emulsion itself as an active ingredient as a piezoelectric material capable of generating a microcurrent by pressure upon application to skin.
제1항에 있어서, 상기 압전물질은 액상 압전 물성 측정 장치로 측정하였을 때 1 내지 20 pC/N의 압전상수를 나타내는 것을 특징으로 하는 압전 화장료 조성물.
The piezoelectric cosmetic composition according to claim 1, wherein the piezoelectric material exhibits a piezoelectric constant of 1 to 20 pC / N as measured by a liquid piezoelectric property measuring device.
삭제delete 제1항에 있어서, 상기 압전물질에 의해 발생된 미세전류는 화장료의 피부침투를 도와줄 뿐만 아니라 피부자극을 통해 피부탄력을 개선하는 것을 특징으로 하는 압전 화장료 조성물.
The piezoelectric cosmetic composition according to claim 1, wherein the microcurrent generated by the piezoelectric material not only assists penetration of the skin into the skin but also improves skin elasticity through skin irritation.
제1항에 있어서, 상기 압전 화장료 조성물은 물, 오일, 폴리올, 계면활성제, 및 보습제로 구성된 군에서 선택된 어느 하나 이상의 화장료를 더 포함하는 것을 특징으로 하는 압전 화장료 조성물.
The piezoelectric cosmetic composition according to claim 1, wherein the piezoelectric cosmetic composition further comprises at least one cosmetic selected from the group consisting of water, oil, polyol, surfactant, and moisturizer.
제1항에 있어서, 상기 화장료 조성물은 화장수, 스킨, 로션, 크림 또는 에센스의 제형을 갖는 것을 특징으로 하는 압전 화장료 조성물.The piezoelectric cosmetic composition according to claim 1, wherein the cosmetic composition has formulations of lotion, skin, lotion, cream or essence.
KR1020160109329A 2016-08-26 2016-08-26 Piezoelectric cosmetic composition KR101819467B1 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
KR1020160109329A KR101819467B1 (en) 2016-08-26 2016-08-26 Piezoelectric cosmetic composition
PCT/KR2017/000770 WO2018038333A1 (en) 2016-08-26 2017-01-23 Piezoelectric cosmetic composition
US16/082,421 US20190083368A1 (en) 2016-08-26 2017-01-23 Piezoelectric cosmetic composition
CN201780047568.0A CN109562028B (en) 2016-08-26 2017-01-23 Piezoelectric cosmetic composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020160109329A KR101819467B1 (en) 2016-08-26 2016-08-26 Piezoelectric cosmetic composition

Publications (1)

Publication Number Publication Date
KR101819467B1 true KR101819467B1 (en) 2018-01-18

Family

ID=61028829

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020160109329A KR101819467B1 (en) 2016-08-26 2016-08-26 Piezoelectric cosmetic composition

Country Status (4)

Country Link
US (1) US20190083368A1 (en)
KR (1) KR101819467B1 (en)
CN (1) CN109562028B (en)
WO (1) WO2018038333A1 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102022230B1 (en) * 2019-01-02 2019-09-18 코스맥스 주식회사 Structure of emulsions for enhancing the skin penetration and method of producing the same
KR102041748B1 (en) * 2019-02-26 2019-11-06 주식회사 잇츠한불 Cosmetic composition having piezoelectric performance
WO2021107427A1 (en) * 2019-11-25 2021-06-03 코스맥스 주식회사 Cosmetic composition for skin barrier enhancement or skin bioactive substance absorption promotion
KR20210074047A (en) * 2019-12-11 2021-06-21 코스맥스 주식회사 Cosmetic container including piezoelectric material
JP2021176835A (en) * 2020-05-08 2021-11-11 (株)イッツハンブルIt’S Hanbul Co., Ltd. Cosmetic composition having ferroelectricity and piezoelectricity
KR102491573B1 (en) * 2022-07-14 2023-01-27 농업회사법인 큐어팜바이오 주식회사 Sheet for skin containing piezoelectric material
KR102559008B1 (en) 2023-05-17 2023-07-25 주식회사 뉴앤뉴 Liquid crystal cosmetic composition that forms a microcurrent and has excellent electrical conductivity

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112641635A (en) * 2020-12-11 2021-04-13 西安邮电大学 Dental whitening and degerming coating material and preparation method and application thereof
CN115634166A (en) * 2022-10-25 2023-01-24 山东博科医用材料有限公司 Composition with inverse piezoelectric effect and application thereof in cosmetics

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040137026A1 (en) * 2002-12-04 2004-07-15 Karin Golz-Berner Cosmetic composition containing electric carriers

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4376634B2 (en) * 2002-03-29 2009-12-02 株式会社資生堂 Composite powder and cosmetics containing the same
AU2003284401A1 (en) * 2002-11-14 2004-06-03 Ube Industries, Ltd. Cosmetic composition
TW200512007A (en) * 2003-05-30 2005-04-01 Fullerene Internat Corp Cosmetic compositions containing fullerene clusters
US7754775B2 (en) * 2004-04-23 2010-07-13 Mercier Michel F Multi-lamellar liquid crystal emulsion system
CN101670147A (en) * 2009-09-22 2010-03-17 爱新觉罗·川 Oxygen-injection toxin-expulsion oxidation-resistance collagen micro electric current cosmetic method
CN102429826B (en) * 2010-09-29 2013-09-25 科丝美诗(中国)化妆品有限公司 Composition of impressive emulsified cosmetics and producing method thereof
KR20120042057A (en) * 2010-10-22 2012-05-03 서지환 Composition for treatment of atopic dermatitis containing tourmaline
KR20120122125A (en) * 2011-04-28 2012-11-07 (주) 아이원 엔터프라이즈 Face mask system for skin care improvement and skin care improving method using the same
KR102089420B1 (en) * 2013-11-29 2020-03-17 (주)아모레퍼시픽 Cosmetic composition for improving skin elasticity
JP6586554B2 (en) * 2014-04-15 2019-10-09 ジェイオーコスメティックス株式会社 Cosmetics
KR102394634B1 (en) * 2015-03-31 2022-05-09 (주)아모레퍼시픽 Colloid with self-iontophoresis,manufacturing method of the same and cosmetic composition containing the same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040137026A1 (en) * 2002-12-04 2004-07-15 Karin Golz-Berner Cosmetic composition containing electric carriers

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102022230B1 (en) * 2019-01-02 2019-09-18 코스맥스 주식회사 Structure of emulsions for enhancing the skin penetration and method of producing the same
CN111494245A (en) * 2019-01-02 2020-08-07 科丝美诗株式会社 Emulsion structure for enhanced skin absorption and method of making same
US11730687B2 (en) 2019-01-02 2023-08-22 Cosmax, Inc. Emulsion structure for enhancing skin absorption and method of preparing the same
KR102041748B1 (en) * 2019-02-26 2019-11-06 주식회사 잇츠한불 Cosmetic composition having piezoelectric performance
WO2021107427A1 (en) * 2019-11-25 2021-06-03 코스맥스 주식회사 Cosmetic composition for skin barrier enhancement or skin bioactive substance absorption promotion
KR20210074047A (en) * 2019-12-11 2021-06-21 코스맥스 주식회사 Cosmetic container including piezoelectric material
KR102298143B1 (en) * 2019-12-11 2021-09-06 코스맥스 주식회사 Cosmetic container including piezoelectric material
JP2021176835A (en) * 2020-05-08 2021-11-11 (株)イッツハンブルIt’S Hanbul Co., Ltd. Cosmetic composition having ferroelectricity and piezoelectricity
KR102491573B1 (en) * 2022-07-14 2023-01-27 농업회사법인 큐어팜바이오 주식회사 Sheet for skin containing piezoelectric material
KR102559008B1 (en) 2023-05-17 2023-07-25 주식회사 뉴앤뉴 Liquid crystal cosmetic composition that forms a microcurrent and has excellent electrical conductivity

Also Published As

Publication number Publication date
CN109562028B (en) 2023-03-28
CN109562028A (en) 2019-04-02
WO2018038333A1 (en) 2018-03-01
US20190083368A1 (en) 2019-03-21

Similar Documents

Publication Publication Date Title
KR101819467B1 (en) Piezoelectric cosmetic composition
JP4584991B2 (en) Skin cosmetics and wrinkle improvers
US5800835A (en) Preparation for improving the blood supply containing hard magnetic particles
JP2718639B2 (en) Cosmetic and / or dermatological composition for aging treatment containing ceramides and method of using the same
KR100452757B1 (en) Manufacturing Process of Skin-Care Containing Natural Ceramide, Phytosphingoshine, Colesterol and Lecithin
Ainurofiq et al. Pre-formulation study on the preparation of skin cosmetics
KR20080003910A (en) Cosmetic composition for skin and wrinkle improver
KR101361569B1 (en) Ｃｏｓｍｅｔｉｃ ｃｏｍｐｏｓｉｔｉｏｎ ｆｏｒ ｔｈｅ ｃａｌｍｉｎｇ ａｎｄ ａｐｐｌｙｉｎｇ ａｎ ｅｌｅｃｔｒｉｃ ｃｕｒｒｅｎｔ ｏｆ ｓｋｉｎｓ ａｎｄ ｍａｎｕｆａｃｔｕｒｉｎｇ ｔｈｅ ｓａｍｅ
Pinsky Efficacy and safety of an anti-aging technology for the treatment of facial wrinkles and skin moisturization
CN111494245A (en) Emulsion structure for enhanced skin absorption and method of making same
KR20170010499A (en) Cosmetic Compositions comprising Snail mucus fermentation filtrate for improving skin barrier function and having high skin absorption and Functional Cosmetic using this
DE10257240A1 (en) Cosmetic composition with electrical charge carriers
KR101690144B1 (en) A method of preparing cosmetic composition for moisturizing the skin and promoting the differenciation of keratinocyte cell comprising the agar and the cosmetic composition prepared therefrom
KR101598210B1 (en) transparent gel solubilization composition containing ceramide, peptide, and hyaluronic acid
EP4023206A1 (en) Dispersion of cerium oxide for enhancing skin barrier, skin moisturizing, and/or blocking fine dust, and cosmetic composition comprising same
KR100471359B1 (en) Skin Care Compositions containing crystalline inorganic minerals
KR101944716B1 (en) Cosmetic composition for anti-wrinkle and anti-aging comprising N-acetyl phytosphingosine-1-phosphate
KR102164583B1 (en) Oil in water in oil type cosmetic composition and cosmetic product including the same
KR102576692B1 (en) Liquid crystal composition comprising ceramide and method for manufacturing thereof
KR100501309B1 (en) Manufacturing Method of Nano-emulsified Cosmetic Composition Containing Arbutin
ITMI20091165A1 (en) COMBINATION OF STEM CELLS, AND / OR THEIR EXTRACTS, OF LIPPIA CITRIODORA AND LEONTOPODIUM ALPINUM, AND ITS USE IN COSMETIC PRODUCTS
JP4456918B2 (en) Wrinkle improving agent
JP2023553119A (en) Fermented product from structured aqueous medium and cosmetic composition containing the same
KR20230119476A (en) Nano niosome cosmetic composition
CN117942270A (en) Preparation method and application of high-stability repair anti-aging liposome

Legal Events

Date Code Title Description
E701 Decision to grant or registration of patent right
GRNT Written decision to grant