KR101799268B1 - Metal-surface treatment agent - Google Patents
Metal-surface treatment agent Download PDFInfo
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- KR101799268B1 KR101799268B1 KR1020170069536A KR20170069536A KR101799268B1 KR 101799268 B1 KR101799268 B1 KR 101799268B1 KR 1020170069536 A KR1020170069536 A KR 1020170069536A KR 20170069536 A KR20170069536 A KR 20170069536A KR 101799268 B1 KR101799268 B1 KR 101799268B1
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- 239000012756 surface treatment agent Substances 0.000 title claims abstract description 50
- 229910052751 metal Inorganic materials 0.000 claims abstract description 75
- 239000002184 metal Substances 0.000 claims abstract description 75
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims abstract description 53
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 21
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 12
- -1 poly (oxy-1,2-ethanediyl) Polymers 0.000 claims description 11
- 239000002904 solvent Substances 0.000 claims description 10
- 239000004115 Sodium Silicate Substances 0.000 claims description 9
- 239000001509 sodium citrate Substances 0.000 claims description 9
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 9
- 239000002738 chelating agent Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 7
- 239000012153 distilled water Substances 0.000 claims description 6
- COBPKKZHLDDMTB-UHFFFAOYSA-N 2-[2-(2-butoxyethoxy)ethoxy]ethanol Chemical compound CCCCOCCOCCOCCO COBPKKZHLDDMTB-UHFFFAOYSA-N 0.000 claims description 4
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 230000005484 gravity Effects 0.000 claims description 3
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 claims description 2
- 150000004686 pentahydrates Chemical class 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 15
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 14
- 239000011574 phosphorus Substances 0.000 abstract description 14
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 14
- 238000007254 oxidation reaction Methods 0.000 abstract description 11
- 230000003647 oxidation Effects 0.000 abstract description 10
- 239000003440 toxic substance Substances 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 6
- 238000004140 cleaning Methods 0.000 abstract description 5
- 238000012851 eutrophication Methods 0.000 abstract description 4
- 231100000481 chemical toxicant Toxicity 0.000 abstract description 3
- 230000002265 prevention Effects 0.000 abstract description 3
- 231100000331 toxic Toxicity 0.000 abstract description 3
- 230000002588 toxic effect Effects 0.000 abstract description 3
- 239000003344 environmental pollutant Substances 0.000 abstract description 2
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 231100000719 pollutant Toxicity 0.000 abstract description 2
- 238000006253 efflorescence Methods 0.000 abstract 1
- 206010037844 rash Diseases 0.000 abstract 1
- 239000002351 wastewater Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 18
- 238000005237 degreasing agent Methods 0.000 description 17
- 239000013527 degreasing agent Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
- 239000000356 contaminant Substances 0.000 description 10
- 239000003513 alkali Substances 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 238000005238 degreasing Methods 0.000 description 6
- 238000000550 scanning electron microscopy energy dispersive X-ray spectroscopy Methods 0.000 description 6
- 230000002087 whitening effect Effects 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 239000010731 rolling oil Substances 0.000 description 4
- 238000004381 surface treatment Methods 0.000 description 4
- 239000004111 Potassium silicate Substances 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 239000010730 cutting oil Substances 0.000 description 3
- 239000004088 foaming agent Substances 0.000 description 3
- 239000000383 hazardous chemical Substances 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 3
- 229910052913 potassium silicate Inorganic materials 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 231100000167 toxic agent Toxicity 0.000 description 3
- 238000004065 wastewater treatment Methods 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 235000019794 sodium silicate Nutrition 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000003064 anti-oxidating effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/14—Cleaning or pickling metallic material with solutions or molten salts with alkaline solutions
-
- C11D11/0029—
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/16—Metals
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 금속 표면 처리제에 관한 것으로, 보다 상세하게는 세정 및 탈지 효과 및 오염물질의 제거력이 높아 금속 표면의 산화방지 효과를 가지는 금속 표면 처리제 조성물에 관한 것이다.The present invention relates to a metal surface treatment agent, and more particularly, to a metal surface treatment agent composition having a cleaning and degreasing effect and a high removal power of a contaminant to prevent oxidation of a metal surface.
일반적으로, 공업용 금속 표면에는 동식물 유지, 그리이스, 광물유, 압연유, 절삭유, 프레스유 등의 유성 물질 등 오염물질이 부착되어 있고, 또한 금속가루 등이 상기 오염물질에 혼입되어 있는 경우도 있다. 이 오염물질들은 후공정을 통하여 제거해 둘 필요가 있으며, 일반적으로 금속용 알칼리성 세정제(금속 탈지제)로 상기 오염물질을 제거한다.In general, industrial metal surfaces are contaminated with pollutants such as animal or vegetable oil, grease, mineral oil, rolling oil, cutting oil, press oil and other oily substances, and metal powder or the like may be mixed into the contaminants. These contaminants need to be removed through a post-process, and generally the contaminants are removed with an alkaline detergent for metal (metal degreasing agent).
현재 일반적으로 사용 중인 금속 탈지제 조성들을 살펴보면 고농도의 수산화나트륨 및 수산화칼륨을 주제로 조성되어, 도유, 압연유, 절삭유 등의 지방과 결합하여 검화시켜 비누화로 만든 다음 제거하는 메카니즘 제품이 대부분이다. 그러나, 이러한 메커니즘을 사용하는 경우에는 탈지력은 있으나, 완전하게 제거하지 않으면 비누화에 의한 백태현상(white coating)이 발생되는 문제점이 있을 뿐 아니라, 이를 그대로 방치 시간이 경과되면 수산화 물질들이 수분을 흡수하여 금속표면에 산화를 발생시키는 단점이 있었다. 또한, 이를 제거하여 청결하게 하고자 하면 여러 차례 헹굼 작업을 실시해야 되기 때문에 용수의 사용량이 다량으로 소모되는 문제점도 있고 제품 생산의 원단위도 상승되는 문제점도 있었다.Most of the metal degreasing compositions currently in use are composed of high concentrations of sodium hydroxide and potassium hydroxide and are combined with fat such as castor oil, rolling oil and cutting oil to saponify and then remove them. However, when such a mechanism is used, there is a problem of degreasing force, but if not completely removed, white coating due to saponification may occur. In addition, when the time passes, the hydroxide absorbs moisture Thereby causing oxidation on the metal surface. Also, in order to clean the product, it is necessary to rinse the product several times, so that the amount of water consumed is large and the unit cost of product production is also increased.
또한, 현재 사용 중인 금속 탈지제 조성 중 인(P)을 함유한 제품들도 많이 존재하는데, 인(P)을 포함하면 폐수 처리장에서 부영양화 현상이 나타나게 되며 부하가 많이 걸려서 전체적으로 비용(cost) 상승을 야기하게 되는 문제점도 발생하였다.Also, there are many products containing P (P) in the composition of metal degreasing agent currently in use. If phosphorus (P) is included, eutrophication phenomenon appears in the wastewater treatment plant and the load is increased, There has also been a problem.
본 발명은 상기한 종래의 문제점을 해결하기 위하여 세정, 탈지 효과 및 오염물질의 제거력이 우수하여 금속 표면의 산화방지, 백태현상방지 효과를 가지고 수질환경의 녹조 발생 및 부영양화를 억제하는 금속 표면 처리제를 제공하는 것을 목적으로 한다.Disclosure of the Invention The present invention has been made to solve the above-mentioned problems of the prior art, and it is an object of the present invention to provide a metal surface treatment agent having an effect of preventing oxidation and prevention of whitening of a metal surface, The purpose is to provide.
본 발명에 따른 금속 표면 처리제는,In the metal surface treatment agent according to the present invention,
전체 조성물 100중량부를 기준으로 Based on 100 parts by weight of the total composition
1)활성 킬레이트제 5 ~ 6중량부, 2)계면활성제 2 ~ 3중량부, 3)알칼리제 11.5 ~ 15중량부, 4)용제 5.5 ~ 7.5중량부, 및 5)증류수 68.5 ~ 76중량부를 포함하는 것을 특징으로 한다.5 to 6 parts by weight of active chelating agent, 2 to 3 parts by weight of surfactant, 3 to 11.5 to 15 parts by weight of an alkali agent, 5.5 to 7.5 parts by weight of a solvent and 68.5 to 76 parts by weight of distilled water .
또한, 본 발명에 따른 금속 표면 처리제는, 전체 조성물 100중량부를 기준으로 상기 1)활성 킬레이트제로 EDTA(N,N-ETHYLENEDIAMINEDIACETIC ACID) 5 ~ 6중량부, 상기 2)계면활성제로 폴리(옥시-1,2-에탄디일), 알파포스포노-오메가-(메틸페녹시)-,디포타슘 염(Poly(oxy-1,2-ethanediyl), alphaphosphono-omega-(methylphenoxy)-, dipotassium salt) 2 ~ 3중량부, 상기 3)알칼리제로 구연산 나트륨(SODIUM CITRATE) 3 ~ 4 중량부, 메타규산소다(SODIUMMETASILICATE, PENTAHYDRATE) 8 ~ 10 중량부, 및 수산화칼륨(POTASSIUM HYDROXIDE) 0.5 ~ 1 중량부, 상기 4)용제로 BTG(TRIETHYLENE GLYCOL MONO BUTYL ETHER) 3 ~ 4 중량부 및 구연산(Citric acid) 2.5 ~ 3.5 중량부, 및 5)증류수 68.5 ~ 76중량부를 포함하는 것을 특징으로 한다.The metal surface treatment agent according to the present invention may further comprise 5 to 6 parts by weight of EDTA (N, N-ETHYLENEDIAMINEDIACETIC ACID) as the active chelating agent and 2 to 5 parts by weight of poly (oxy-1 , 2-ethanediyl), alpha phosphono-omega- (methylphenoxy) -, poly (oxy-1,2-ethanediyl), alphaphosphono-omega- 3 to 4 parts by weight of sodium citrate, 8 to 10 parts by weight of sodium silicate and 0.5 to 1 part by weight of potassium hydroxide as an alkali agent, 3 to 4 parts by weight of BTG (TRIETHYLENE GLYCOL MONO BUTYL ETHER) as a solvent, 2.5 to 3.5 parts by weight of citric acid, and 5 to 68.5 to 76 parts by weight of distilled water.
본 발명에 따르면 세정 및 탈지 효과 및 오염물질의 제거력이 우수하여 금속 표면의 산화방지 효과를 가지고, 백태 현상 방지효과도 우수한 금속 표면 처리제를 제공할 수 있다. 또한, 금속 표면 처리제에 포함되는 수산화칼륨의 양이 소량에 불과하여 유해화학물질관리법 상 유독물에 해당하지 않고 인(P)의 함유량이 낮아, 환경오염 방지에도 우수한 효과도 가지고, 폐수 처리장에서 부영양화 현상이 줄어들게 되고 수질환경 오염방지에도 기여하여 전체적인 비용(cost) 절감 효과도 얻을 수 있었다.According to the present invention, it is possible to provide a metal surface treatment agent having an anti-oxidation effect on a metal surface and an excellent anti-whitening effect, because of its excellent cleaning and degreasing effect and ability to remove contaminants. In addition, since the amount of potassium hydroxide contained in the metal surface treatment agent is only a small amount, the harmful chemical substances management law does not correspond to poisonous substances, and the content of phosphorus (P) is low and also has an excellent effect to prevent environmental pollution. And contributed to the prevention of pollution of the water quality environment, thereby achieving a total cost saving effect.
도 1은 비교예 1, 2에 기재된 금속 표면 처리제의 무기물 SEM-EDX(EDS) 분석결과를 나타낸 도면이다.
도 2는 실시예 1에 기재된 금속 표면 처리제의 무기물 SEM-EDX(EDS) 분석결과를 나타낸 도면이다.
도 3은 본 발명에 따른 실시예 및 비교예의 금속 표면 처리제를 사용하여 금속 표면의 산화현상을 테스트한 결과를 나타낸 것이다.
도 4는 본 발명에 따른 실시예 및 비교예의 금속 표면 처리제를 사용하여 금속 표면의 백태현상을 테스트한 결과를 나타낸 것이다.
도 5는 유해화학물질 관리법 기준에 따른 수산화칼륨(KOH)의 유독물질 함량 정보를 나타낸 것이다.1 is a graph showing the results of inorganic SEM-EDX (EDS) analysis of the metal surface treatment agents described in Comparative Examples 1 and 2.
2 is a graph showing the results of an inorganic SEM-EDX (EDS) analysis of the metal surface treatment agent described in Example 1. Fig.
FIG. 3 shows the results of the oxidation test of metal surfaces using the metal surface treatment agents of the examples and comparative examples according to the present invention.
4 is a graph showing the results of the whitening of metal surfaces using the metal surface treating agents of Examples and Comparative Examples according to the present invention.
FIG. 5 shows information on the content of toxic substances in potassium hydroxide (KOH) according to the Hazardous Chemical Substances Control Act.
본 발명은 다양한 변경을 가할 수 있고 여러 가지 형태를 가질 수 있는 바, 특정 실시예들을 본문에 상세하게 설명하고자 한다. 그러나, 이는 본 발명을 특정한 개시 형태에 대해 한정하려는 것이 아니며, 본 발명의 사상 및 기술 범위에 포함되는 모든 변경, 균등물 내지 대체물을 포함하는 것으로 이해되어야 한다. While the invention is susceptible to various modifications and alternative forms, specific embodiments thereof are further described in the text. It should be understood, however, that the invention is not intended to be limited to the particular forms disclosed, but includes all modifications, equivalents, and alternatives falling within the spirit and scope of the invention.
본 출원에서 사용한 용어는 단지 특정한 실시 예를 설명하기 위해 사용된 것으로, 본 발명을 한정하려는 의도가 아니다. 단수의 표현은 문맥상 명백하게 다르게 뜻하지 않는 한, 복수의 표현을 포함한다. 본 출원에서, "포함하다" 또는 "가지다" 등의 용어는 명세서 상에 기재된 특징, 숫자, 단계, 구성요소 등을 조합한 것이 존재함을 지정하려는 것이지, 하나 또는 그 이상의 다른 특징들이나 숫자, 단계, 구성요소 등을 조합한 것들의 존재 또는 부가 가능성을 미리 배제하지 않는 것으로 이해되어야 한다.The terminology used in this application is used only to describe a specific embodiment and is not intended to limit the invention. The singular expressions include plural expressions unless the context clearly dictates otherwise. In the present application, the term "comprises" or "having" is intended to specify that there is a combination of features, numbers, steps, , Components, and the like, unless specifically excluded from the scope of the invention.
다르게 정의되지 않는 한, 기술적이거나 과학적인 용어를 포함해서 여기서 사용되는 모든 용어들은 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에 의해 일반적으로 이해되는 것과 동일한 의미를 가지고 있다. 일반적으로 사용되는 사전에 정의되어 있는 것과 같은 용어들은 관련 기술의 문맥 상 가지는 의미와 일치하는 의미를 가지는 것으로 해석되어야 하며, 본 출원에서 명백하게 정의하지 않는 한, 이상적이거나 과도하게 형식적인 의미로 해석되지 않는다.Unless defined otherwise, all terms used herein, including technical or scientific terms, have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Terms such as those defined in commonly used dictionaries are to be interpreted as having a meaning consistent with the contextual meaning of the related art and are to be interpreted as either ideal or overly formal in the sense of the present application Do not.
이하, 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.
본 발명의 금속 표면 처리제는 특정의 활성 킬레이트제와 특정의 계면활성제를 주성분으로, 알카리제 및 무기물을 함유한 기재(기본재료)를 포함하는 것을 특징으로 한다.The metal surface treatment agent of the present invention is characterized by comprising a base material (base material) containing a specific active chelating agent and a specific surface active agent as main components, and an alkali agent and an inorganic material.
보다 상세하게 설명하면, 본 발명의 금속 표면 처리제는 전체 조성물 100중량부를 기준으로 1)활성 킬레이트제 5 ~ 6중량부, 2)계면활성제 2 ~ 3중량부, 3)알칼리제 11.5 ~ 15중량부, 4)용제 5.5 ~ 7.5중량부, 및 5)증류수 68.5 ~ 76중량부를 포함하는 것을 특징으로 한다.More specifically, the metal surface treatment agent of the present invention comprises 1) 5 to 6 parts by weight of an active chelate, 2) 2 to 3 parts by weight of a surfactant, 3) 11.5 to 15 parts by weight of an alkali agent, 4) 5.5 to 7.5 parts by weight of a solvent, and 5) 68.5 to 76 parts by weight of distilled water.
본 발명의 활성 킬레이트제는 주로 압연공정, 절삭공정, 프레스공정 등에서 발생되는 철분(鐵粉) 등의 파티클 금속분의 제거 작용 및 음이온성 계면활성제를 사용한 경우에 공업용수 중에 함유되는 칼슘, 마그네슘 등의 경수 성분이 음이온성 계면활성제와 불용성 염을 형성하여 계면활성제가 저하되는 것을 방지하는 작용을 할 수 있다. 또한, 세정 효율을 높일 수 있고, 스케일을 방지할 수 있으며, 무기오염물의 공격을 제어할 수 있다.The active chelating agent of the present invention is mainly used for the removal of particle metal components such as iron powder generated in a rolling process, a cutting process, a pressing process, and the like, and an effect of removing calcium, magnesium, etc. contained in industrial water when an anionic surfactant is used. The hard water component may form an insoluble salt with the anionic surfactant to prevent the deterioration of the surfactant. Further, the cleaning efficiency can be increased, the scale can be prevented, and the attack of the inorganic contaminants can be controlled.
본 발명의 활성 킬레이트제로는 EDTA(N,N-ETHYLENEDIAMINEDIACETIC ACID), 프탈로시아닌(Phthalocyanine), 글리세린(Glycerin), 에틸렌디아민(Ethylenediamine) 등을 사용할 수 있으나, 바람직하게는 EDTA를 사용할 수 있다. 특히, 본 발명에서 EDTA를 사용하면, 생산 원가가 저렴하며 금속이온성의 분산력이 강한 측면에서 장점을 가진다.The active chelating agent of the present invention may be EDTA (N, N-ethylanilinedilatedacetic acid), phthalocyanine, glycerin, ethylenediamine or the like, preferably EDTA. Particularly, the use of EDTA in the present invention is advantageous in that the production cost is low and the dispersibility of metal ionic strength is strong.
또한 본 발명의 활성 킬레이트제는 전체 조성물 100중량부를 기준으로 5 ~ 6 중량부, 바람직하게는 5.5 중량부를 사용할 수 있다. 5 중량부 미만으로 사용하면 피세척물에서 분산되거나 용해되었던 오염물질들이 피세척물 금속표면에 재 부착되는 문제점이 발생할 수 있고, 6 중량부를 초과하면 생산 원단위의 상승으로 공급 측면에서 약세를 면하기 어려운 문제점이 발생할 수 있다.The active chelating agent of the present invention may be used in an amount of 5 to 6 parts by weight, preferably 5.5 parts by weight, based on 100 parts by weight of the total composition. If it is used in an amount less than 5 parts by weight, contaminants which have been dispersed or dissolved in the material to be washed may be reattached to the surface of the object to be cleaned. If the amount is more than 6 parts by weight, A difficult problem may arise.
본 발명의 계면활성제는 금속 표면 처리제에 낮은 표면장력을 제공할 수 있고, 오염물의 침투, 유화, 재부착을 방지하고 억제할 수 있다. The surfactant of the present invention can provide a low surface tension to the metal surface treatment agent and can prevent and suppress the penetration, emulsification, and reattachment of contaminants.
본 발명의 계면활성제로는 폴리(옥시-1,2-에탄디일), 알파포스포노-오메가-(메틸페녹시)-, 디포타슘 염(Poly(oxy-1,2-ethanediyl), alphaphosphono-omega-(methylphenoxy)-, dipotassium salt), 글루타믹산(L-Glutamic acid), N,N-디아세틱 에시드 테트라소듐 염((N.N diaatic acid tetrasodium salt{GLDA- Na4}) 등을 사용할 수 있으며, 이들 중 선택하여 1종 또는 2종 이상 혼합 사용할 수 있다. Examples of the surfactant of the present invention include poly (oxy-1,2-ethanediyl), alpha phosphono-omega- (methylphenoxy), poly (oxy-1,2-ethanediyl), alphaphosphono-omega - (methylphenoxy) -, dipotassium salt, L-Glutamic acid, N, N-diacetic acid tetrasodium salt (GLDA-Na4) May be used alone or in combination of two or more.
또한 본 발명의 계면활성제는 전체 조성물 100중량부를 기준으로 2 ~ 3 중량부를 사용할 수 있다. 2 중량부 미만으로 사용하면 탈지 제거력이 약화되는 문제점이 발생할 수 있고, 3 중량부를 초과하면 기포(Foam)의 발생이 많아 추가로 소포제(Foaming agent)를 사용하여야 하는 문제점이 발생할 수 있다.The surfactant of the present invention may be used in an amount of 2 to 3 parts by weight based on 100 parts by weight of the total composition. If it is used in an amount of less than 2 parts by weight, the degreasing ability may be weakened. If it exceeds 3 parts by weight, a foaming agent may be generated.
종래의 금속표면 처리 탈지제는 전체 조성물 100중량부에 다기포성 계면활성제를 4 ~ 5 중량부로 포함하여, 기포(Foam)의 발생이 많아 추가로 다량의 소포제(Foaming agent)를 사용하여야 하는 문제점이 있었다. 이러한 문제점을 본 발명의 금속 표면처리제는 전체 조성물 100중량부에 저기포성 계면활성제를 2 ~ 3 중량부로 포함함으로써, 기포(Foam)의 발생이 미비하므로 소포제(Foaming agent)를 기존 사용량의 1/3로 기포발생의 문제점을 해결할 수 있었다.Conventional metal surface treatment degreasing agents contain 4 to 5 parts by weight of a polybasic surfactant in 100 parts by weight of the total composition, so that a large amount of foam is generated and a further large amount of foaming agent must be used . The metal surface treatment agent of the present invention has the problem that since foaming is not generated by containing 2 to 3 parts by weight of the low-surfactant in 100 parts by weight of the total composition, the foaming agent is reduced to 1/3 The problem of bubble generation could be solved.
본 발명의 알칼리제는 유기 오염물을 용해시키고, 연화 또는 분해시키는 효과를 가진다.The alkaline agent of the present invention has the effect of dissolving, softening or decomposing organic contaminants.
본 발명의 알칼리제로는 구연산 나트륨(SODIUM CITRATE), 메타규산소다(SODIUMMETASILICATE, PENTAHYDRATE), 수산화칼륨(POTASSIUM HYDROXIDE), 규산 나트륨(Sodium silicate) 등을 사용할 수 있으나, 반드시 이에 한정되지는 않는다. 특히, 구연산나트륨을 사용하면, 금속 표면에 발생할 수 있는 백태현상을 억제할 수 있는 측면에서 장점을 가진다. Examples of the alkali agent of the present invention include, but are not limited to, sodium citrate, sodium silicate, potassium silicate, potassium silicate, sodium silicate, and the like. Particularly, when sodium citrate is used, it has an advantage in that it can suppress the whitening phenomenon that may occur on the metal surface.
또한 본 발명의 알칼리제는 전체 조성물 100중량부를 기준으로 11.5 ~ 15 중량부, 바람직하게는 12.5 중량부를 사용할 수 있다. 11.5 중량부 미만으로 사용하면 세척력이 저하될 우려의 문제점이 있고, 15 중량부를 초과하면 피세척물 표면에 백태현상이 발생할 문제점이 있다.The alkali agent of the present invention may be used in an amount of 11.5 to 15 parts by weight, preferably 12.5 parts by weight, based on 100 parts by weight of the total composition. If it is used in an amount less than 11.5 parts by weight, there is a problem of deterioration of the detergency. If the amount exceeds 15 parts by weight, there is a problem that whitening may occur on the surface of the object to be washed.
바람직하게는 알칼리제를 2종 이상 혼합하여 사용할 수 있으며, 2종 이상 혼합하는 경우에는 전체 조성물 100중량부를 기준으로 알칼리제 1을 3 ~ 4 중량부, 알칼리제 2를 8 ~ 10중량부, 알칼리제 3을 0.5 ~ 1중량부로 혼합 사용할 수 있다.In case of mixing two or more kinds of them, 3 to 4 parts by weight of alkali agent 1, 8 to 10 parts by weight of alkali agent 2, and 0.5 to 10 parts by weight of alkaline agent 3, based on 100 parts by weight of the total composition, To 1 part by weight.
구체적으로 예를 들면, 바람직하게는 구연산 나트륨(SODIUM CITRATE), 메타규산소다(SODIUMMETASILICATE, PENTAHYDRATE), 수산화칼륨(POTASSIUM HYDROXIDE)을 혼합 사용할 수 있으며, 전체 조성물 100중량부를 기준으로 구연산 나트륨(SODIUM CITRATE) 3 ~ 4 중량부, 메타규산소다(SODIUMMETASILICATE, PENTAHYDRATE) 8 ~ 10 중량부, 수산화칼륨(POTASSIUM HYDROXIDE) 0.5 ~ 1 중량부로 혼합 사용할 수 있다. 이렇게 사용하는 경우, 유해화학물질 규정 이하의 취급안전성과 작업환경안전에 도움의 측면에서 장점이 있다.Specifically, for example, sodium citrate, sodium silicate, potassium silicate, potassium hydroxide and potassium hydroxide may be used in combination, and sodium citrate (sodium citrate) may be used based on 100 parts by weight of the total composition. 3 to 4 parts by weight, 8 to 10 parts by weight of sodium silicate (SODIUMMETASILICATE, PENTAHYDRATE), and 0.5 to 1 part by weight of potassium hydroxide (POTASSIUM HYDROXIDE). When used in this way, there are advantages in terms of handling safety below the Hazardous Chemical Substance regulations and in terms of working environment safety.
본 발명의 용제로는 BTG(TRIETHYLENE GLYCOL MONO BUTYL ETHER), 구연산(Citric acid), MTG(Triethylene Glycol mono Metyl) 등을 사용할 수 있으나, 반드시 이에 한정되지는 않는다. 특히, BTG와 구연산을 사용하면, 경화된 오염물질 용해 측면에서 장점을 가진다.As the solvent of the present invention, BTG (TRIETHYLENE GLYCOL MONO BUTYL ETHER), citric acid, MTG (Triethylene Glycol mono Metyl) and the like can be used, but not always limited thereto. In particular, the use of BTG and citric acid has advantages in terms of cured contaminant dissolution.
또한 본 발명의 용제는 전체 조성물 100중량부를 기준으로 5.5 ~ 7.5 중량부, 바람직하게는 6.5 중량부를 사용할 수 있다.The solvent of the present invention may be used in an amount of 5.5 to 7.5 parts by weight, preferably 6.5 parts by weight, based on 100 parts by weight of the total composition.
바람직하게는 용제를 2종 이상 혼합하여 사용할 수 있으며, 2종 이상 혼합하는 경우에는 전체 조성물 100중량부를 기준으로 용제 1을 3 ~ 4 중량부, 용제 2를 2.5 ~ 3.5 중량부로 혼합 사용할 수 있다.In case of mixing two or more kinds of solvents, 3 to 4 parts by weight of the solvent 1 and 2.5 to 3.5 parts by weight of the solvent 2 may be mixed based on 100 parts by weight of the total composition.
구체적으로 예를 들면, 전체 조성물 100중량부를 기준으로 글리콜계의BTG(TRIETHYLENE GLYCOL MONO BUTYL ETHER) 3 ~ 4 중량부, 및 구연산(Citric acid) 2.5 ~ 3.5 중량부로 혼합 사용할 수 있다. 이렇게 사용하는 경우, 피세척물질 금속 표면에 발생할 산화를 예방할 수 있는 측면에서 장점이 있다.Specifically, for example, 3 to 4 parts by weight of glycol-based BTG (TRIETHYLENE GLYCOL MONO BUTYL ETHER) and 2.5 to 3.5 parts by weight of citric acid may be mixed based on 100 parts by weight of the total composition. When used in this manner, there is an advantage in that oxidation of the surface of the material to be washed can be prevented.
본 발명에서 증류수는 전체 조성물 100중량부를 기준으로 68.5 ~ 76 중량부,바람직하게는 70중량부로 사용될 수 있다. 68.5 중량부 미만으로 사용하면 물질의 농도가 상승할 수 있고, 76 중량부를 초과하면 유지분 제거가 약화되는 문제점이 있다.In the present invention, distilled water may be used in an amount of 68.5 to 76 parts by weight, preferably 70 parts by weight, based on 100 parts by weight of the total composition. If it is used in an amount of less than 68.5 parts by weight, the concentration of the substance may be increased, and if it exceeds 76 parts by weight, the removal of the fat may be weakened.
본 발명의 금속 표면 처리제 조성물의 바람직한 예를 구체적으로 설명하면, 전체 조성물 100중량부를 기준으로 EDTA 5 ~ 6중량부, 계면활성제 2 ~ 3중량부, 구연산 나트륨 3 ~ 4 중량부, 메타규산소다 8 ~ 20 중량부, 수산화칼륨 0.5 ~ 1 중량부, BTG 3 ~ 4 중량부, 구연산 2.5 ~ 3.5 중량부, 증류수 68.5 ~ 76 중량부로 포함되는 것을 특징으로 하는 금속 표면 처리제일 수 있다.A preferable example of the metal surface treatment composition of the present invention is specifically exemplified by 5 to 6 parts by weight of EDTA, 2 to 3 parts by weight of a surfactant, 3 to 4 parts by weight of sodium citrate, 8 parts by weight of sodium metasilicate 8 To 20 parts by weight, potassium hydroxide 0.5-1 parts by weight, BTG 3-4 parts by weight, citric acid 2.5-3.5 parts by weight and distilled water 68.5 76 parts by weight.
본 발명의 금속 표면 처리제는, 킬레이트(Chelate compound) 다원자 이온 화합물과, 적절한 보조제(builder)로 무기물을 함유한 기재(기본재료)를 포함함으로써, 세정 및 탈지효과가 우수할 뿐만 아니라, 오염물질(도유-anointing, 압연유-rolling oil, 절삭유-cutting oil)을 분해, 용해, 분산시키는 효능과 제거력이 높아, 금속 표면에 발생하는 산화를 예방하는 효과를 가진다. The metal surface treatment agent of the present invention is excellent in cleaning and degreasing effects by containing a chelate compound polyatomic ionic compound and a substrate (basic material) containing an inorganic substance as an appropriate auxiliary builder, (Oil-anointing, rolling oil, rolling oil, cutting oil-cutting oil), and has an effect of preventing oxidization occurring on the metal surface.
뿐만 아니라, 본 발명의 금속 표면 처리제는 수산화칼륨(KOH)이 고농도로 포함되는 종래의 금속표면 처리제, 탈지제들과 다르게 수산화칼륨(KOH)이 저농도로 포함되기 때문에, 탈지력이 우수할 뿐 아니라 금속으로부터 완전하게 제거하는 것이 가능하여 비누화에 의한 백태현상(white coating)을 예방할 수 있다는 점에서도 우수하다. 또한, 금속 표면으로부터 처리제를 제거하기 위해 실시하는 헹굼 작업의 횟수도 종래의 처리제의 경우보다 더 적게 필요하므로, 헹굼작업에 소요되는 용수의 사용량도 줄일 수 있다는 점에서도 우수하다. In addition, since the metal surface treatment agent of the present invention contains potassium hydroxide (KOH) at a low concentration in contrast to conventional metal surface treatment agents and degreasing agents, which contain potassium hydroxide (KOH) at a high concentration, It is excellent in that white coating due to saponification can be prevented. In addition, since the number of rinsing operations performed to remove the treating agent from the metal surface is less than that of the conventional treating agent, it is also excellent in that the amount of the water used for the rinsing operation can be reduced.
뿐만 아니라, 본 발명의 금속 표면 처리제는 인(P) 함유량이 낮아, 종래에 인(P)을 다량 함유하는 금속 표면 처리제에 비하여 부영양화 현상이 현저히 줄어들게 되므로 전체적으로 비용(cost) 절감 효과도 얻을 수 있다.In addition, since the content of phosphorus (P) is low in the metal surface treatment agent of the present invention, the phenomenon of eutrophication is remarkably reduced compared to a metal surface treatment agent which conventionally contains phosphorus (P) in a large amount, .
본 발명의 금속 표면 처리제는 pH 12.0 ± 0.5의 특징을 가진다. 이는 종래의 금속 표면 탈지제들에 비하여 더 낮은 pH를 가지는 것으로서, 취급과 작업안전성 측면에서 장점을 가질 수 있다. The metal surface treatment agent of the present invention has a pH of 12.0 ± 0.5. This has a lower pH than conventional metal surface degreasing agents and can have advantages in handling and operational safety.
또한, 본 발명의 금속 표면 처리제는 고형분(%) 15 ~ 20%의 특징을 가진다. 이는 종래의 금속 표면 탈지제들에 비하여 더 낮은 고형분(%)를 가지는 것으로서, 폐수처리 비용을 낮추는 장점을 가질 수 있다. In addition, the metal surface treatment agent of the present invention has a solid content (%) of 15 to 20%. This has the advantage of lowering the cost of wastewater treatment, as it has lower solids (%) than conventional metal surface degreasing agents.
또한, 본 발명의 금속 표면 처리제는 비중(100%)는 1.05 - 1.08을 가진다. The metal surface treatment agent of the present invention has a specific gravity (100%) of 1.05 - 1.08.
본 발명의 금속 표면 처리제에 포함되는 수산화칼륨(KOH) 함량이 약 5% 미만에 해당한다(도 2). 수산화칼륨(KOH) 함량이 5%이상이 되면 유독물에 해당하게 되어 유해화학물질관리법에 준하여 환경청의 관리, 감독을 받아야 하는데, 본 발명의 금속 표면 처리제는 수산화칼륨(KOH) 함량이 5% 미만이므로 유독물에 해당하지 않는다.The content of potassium hydroxide (KOH) contained in the metal surface treatment agent of the present invention is less than about 5% (FIG. 2). When the content of potassium hydroxide (KOH) is 5% or more, it becomes a toxic substance and it is required to be managed and supervised by the Environmental Agency according to the Toxic Chemicals Control Act. The potassium hydroxide (KOH) content of the metal surface treatment agent of the present invention is less than 5% It is not toxic.
본 발명의 금속 표면 처리제에 포함되는 수산화칼륨(KOH) 함량이 약 5% 미만에 해당한다(도 2). 수산화칼륨(KOH)이 함량이 5%이상이 되면 유독물에 해당하게 되어 유해화학물질관리법에 준하여 환경청의 관리, 감독을 받아야 하는데(도 5 참고), 본 발명의 금속 표면 처리제는 수산화칼륨(KOH)이 함량이 5% 미만이므로 유독물에 해당하지 않는다.The content of potassium hydroxide (KOH) contained in the metal surface treatment agent of the present invention is less than about 5% (FIG. 2). When the content of potassium hydroxide (KOH) is 5% or more, it corresponds to a toxic substance, and it is required to be managed and supervised by the Environmental Agency according to the Toxic Chemicals Control Act (see FIG. 5) This content is less than 5%, so it is not toxic.
도 5에 기재된 바와 같이, 수산화칼륨(KOH, Potasium hydroxide)을 5% 이상 함유한 혼합물은 환경청의 규제대상 물질에 해당하게 된다 (출처-국립환경과학원 화학물질 정보시스템).As shown in FIG. 5, a mixture containing 5% or more of potassium hydroxide (KOH) corresponds to a substance to be regulated by the Environment Agency (source: Chemical Information System of National Institute of Environmental Science).
또한, 본 발명의 금속 표면 처리제의 구성성분 함량을 측정한 결과 인(P)에 해당하는 구성성분 함량 값이 단독으로 나타나지 않아 인(P)의 함유량이 낮은 것을 알 수 있다(도 2). 이에 따라, 폐수 처리장에서 부영양화 현상이 줄어들게 되어 전체적으로 비용(cost) 절감 효과도 얻을 수 있다. In addition, as a result of measuring the content of constituent components of the metal surface treatment agent of the present invention, it can be seen that the content of phosphorus (P) is low because the component content value corresponding to phosphorus (P) does not appear alone. As a result, the eutrophication phenomenon is reduced in the wastewater treatment plant, and the cost reduction effect can be obtained as a whole.
본 발명의 금속 표면 처리제는, 본 발명의 목적에 반하지 않는 한도 내에서, 통상의 첨가제 성분을 더욱 포함할 수 있고, 공지된 통상의 방법으로, 상기 각 성분을 충분히 혼합하여 제조할 수 있다. The metal surface treatment agent of the present invention may further contain usual additive components to the extent that it is not contrary to the object of the present invention and can be prepared by sufficiently mixing the respective components by a known ordinary method.
이하, 실시예에 의하여 본 발명을 더욱 상세히 설명하고자 한다.Hereinafter, the present invention will be described in more detail with reference to Examples.
단, 하기 실시예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기 실시예에 의해 한정되는 것은 아니다.However, the following examples are illustrative of the present invention, and the contents of the present invention are not limited by the following examples.
[[ 실시예Example 1] 금속 표면 1] Metal surface 처리제Treatment agent
증류수 75중량부에 EDTA 5 중량부, 폴리(옥시-1,2-에탄디일), 알파포스포노-오메가-(메틸페녹시)-,디포타슘 염 (Poly(oxy-1,2-ethanediyl), alphaphosphono-omega-(methylphenoxy)-, dipotassium salt) 3중량부를 상온상 온도에서 완전히 용해시키고, 구연산 나트륨 3 중량부 및 메타규산소다 8중량부, 수산화칼륨 0.5중량부를 순서대로 용해시키고 BTG 3중량부와 구연산 2.5중량부를 투입하여 완전히 혼합시킨 후 금속 표면 처리제를 제조하였다.5 parts by weight of EDTA, 75 parts by weight of poly (oxy-1,2-ethanediyl), alpha phosphono-omega- (methylphenoxy) 3 parts by weight of sodium citrate, 8 parts by weight of sodium metasilicate and 0.5 part by weight of potassium hydroxide were dissolved in this order, and 3 parts by weight of BTG, And 2.5 parts by weight of citric acid were added thereto to prepare a metal surface treatment agent.
상기 제조된 처리제에 대하여 5%수용액을 만들어 수용액의 온도를 25℃로 만들어 pH를 측정한 결과, pH 12.2(pH 12.0± 0.5)임을 알 수 있었다.As a result of measuring pH by making 5% aqueous solution of the treatment agent, the temperature of the aqueous solution was adjusted to 25 ° C, and it was found that the pH was 12.2 (pH 12.0 ± 0.5).
또한, 고형분(%)은 18이고, 비중(100%)은 1.07임을 확인하였다.It was confirmed that the solid content (%) was 18 and the specific gravity (100%) was 1.07.
[[ 비교예Comparative Example 1] A사 탈지제 1] Company A degreasing agent
종래의 금속 표면 처리 탈지제인 A사 탈지제에 대하여 pH를 측정한 결과, pH 12.8임을 알 수 있었다. 또한, 탈지제 수용액 중 무기물 함량(%)은 27임을 확인하였다. 상기 A사 탈지제의 무기물 SEM-EDX(EDS)를 측적한 분석 결과를 도 1에 나타내었다.The pH of the degreasing agent A, which is a conventional metal surface treatment degreasing agent, was measured, and it was found that the pH was 12.8. In addition, it was confirmed that the mineral content (%) in the degreasing agent aqueous solution was 27%. The analytical results of the inorganic material SEM-EDX (EDS) of the degassing agent A are shown in FIG.
[[ 비교예Comparative Example 2] B사 탈지제 2] Company B degreasing agent
종래의 금속 표면 처리 탈지제인 B사 탈지제에 대하여 pH를 측정한 결과, pH 13.1임을 알 수 있었다. 또한, 탈지제 수용액 중 무기물 함량 (%)은 28임을 확인하였다. 상기 B사 탈지제의 무기물 SEM-EDX(EDS)를 측적한 분석 결과를 도 1에 나타내었다.As a result of measuring the pH of the degreasing agent B as a conventional metal surface treatment degreasing agent, it was found that the pH was 13.1. In addition, it was confirmed that the mineral content (%) in the degreasing agent aqueous solution was 28%. The analytical result of the inorganic material SEM-EDX (EDS) of the degreasing agent B is shown in FIG.
[물성평가방법][Property evaluation method]
(1) 수산화칼륨(KOH)의 함량 계산(1) Calculation of potassium hydroxide (KOH) content
상기 실시예, 비교예의 금속 표면 처리제의 무기물 SEM-EDX(EDS)를 분석하여 그 구성성분의 함량을 확인할 수 있으며, 그 중에서도 특히 칼륨(K)의 함량을 측정할 수 있었다. K 함량 측정 결과로 하기 [표 1]과 같이 KOH(수산화 칼륨)의 함량을 계산하여 유독물의 해당여부를 알 수 있다. (SEM-EDX) (EDS) of the metallic surface treatment agent of the above Examples and Comparative Examples was analyzed to determine the content of the constituent components, and in particular, the content of potassium (K) was measured. As a result of the K content measurement, the content of KOH (potassium hydroxide) is calculated as shown in [Table 1], and it is possible to know whether or not the toxic substance is applicable.
[표 1][Table 1]
또한, 회화 방법을 이용하여 무기물 SEM-EDX(EDS) 분석을 하였으며, 그 분석결과를 도 1에 나타내었다.In addition, an inorganic SEM-EDX (EDS) analysis was performed using a painting method, and the analysis result is shown in FIG.
(2) 인(P)의 함량 측정(2) Measurement of content of phosphorus (P)
상기 실시예, 비교예의 금속 표면 처리제의 무기물 EDS를 분석하여 그 구성성분의 함량을 확인할 수 있으며, 그 중에서도 특히 인(P)의 함량을 측정할 수 있었다. 실시예 1의 경우 인(P)에 해당하는 함량 값이 단독으로 나타나지 않아 인(P)의 함유량이 낮은 것을 알 수 있으며, 비교예 1의 인(P) 함량은 10.08%이었고, 비교예 2의 인(P) 함량은 7.81%이었으며, 그 결과를 도 1, 도 2에 도시하였다. The content of the constituent components can be confirmed by analyzing the inorganic substance EDS of the metal surface treatment agents of the examples and comparative examples, and the content of phosphorus (P) in particular can be measured. The content of phosphorus (P) in Comparative Example 1 was 10.08%, the content of phosphorus (P) in Comparative Example 2 was lower than that of Comparative Example 1, The phosphorus (P) content was 7.81%, and the results are shown in FIGS. 1 and 2. FIG.
(3) 산화현상 테스트(3) Oxidation phenomenon test
상기 실시예 1, 비교예 1 및 2의 금속 표면 처리제를 이용하여 산화현상 테스트를 하였다. 상기 테스트는 금속표면에 알정한 함량을 도포시킨 후 15초 후 흐르는 물에 행굼을 2회 실시하고 완전 건조된 후 측정하였으며, 그 결과를 도 3에 나타내었다.Oxidation phenomenon tests were conducted using the metal surface treatment agents of Example 1 and Comparative Examples 1 and 2. The test was carried out after rinsing twice in running water after 15 seconds of applying a certain amount of metal on the surface of the metal, and after completely drying, the result was shown in FIG.
(4) 백태현상 테스트(4) Backstroke test
상기 실시예 1, 비교예 1 및 2의 금속 표면 처리제를 이용하여 백태현상 테스트를 하였다. 상기 테스트는 일정량의 탈지제를 금속표면에 부착시키고 자연 건조된 후 시료를 만들어 측정하였으며, 그 결과를 도 4에 나타내었다. The whitening phenomenon test was conducted using the metal surface treatment agents of Example 1 and Comparative Examples 1 and 2. The test was performed by attaching a certain amount of degreasing agent to a metal surface and naturally dried to prepare a sample. The results are shown in FIG.
상기 [표 1] 및 도 1을 살펴보면, 비교예 1 및 2의 종래의 금속 표면 처리제(탈지제)는 Na, K의 함량이 높아 유독물에 해당하므로 유해화학물질관리법에 준하여 환경청의 관리, 감독을 받아야 하지만(도 5의 유독물질 함량 정보 참고), 본 발명에 따른 실시예의 금속 표면 처리제의 경우에는 KOH가 5% 미만으로 유독물에 해당하지 않음을 알 수 있었다. 또한, 도 2를 살펴보면, 본 발명에 따른 실시예 1의 경우 비교예 1, 2와 다르게 인(P)의 함량이 단독으로 나타나지 않아 인(P)의 함유량이 낮은 것을 알 수 있다.As shown in Table 1 and FIG. 1, the conventional metal surface treating agents (degreasing agents) of Comparative Examples 1 and 2 are high in Na and K contents, and therefore, they are to be managed and supervised by the Environmental Agency according to the Hazardous Chemical Substances Management Act However, in the case of the metal surface treatment agent of the example according to the present invention, KOH is less than 5%, which means that it does not correspond to toxic substances. 2, in the case of Example 1 according to the present invention, the content of phosphorus (P) is not shown separately, unlike those of Comparative Examples 1 and 2, so that the content of phosphorus (P) is low.
도 3을 살펴보면, 비교예 1 및 비교예 2의 경우에는 금속표면에 산화현상이 발견되었으나, 본 발명에 따른 금속 표면 처리제를 사용한 경우에는 산화현상이 발견되지 않았다.Referring to FIG. 3, in the case of Comparative Example 1 and Comparative Example 2, an oxidation phenomenon was found on the metal surface, but no oxidation phenomenon was found when the metal surface treatment agent of the present invention was used.
또한, 도 4를 살펴보면, 비교예 1 및 비교예 2의 경우에는 금속표면에 백태현상(white coating)이 발견되었으나, 본 발명에 따른 금속 표면 처리제를 사용한 경우에는 백태현상이 발견되지 않았다.4, white coating was found on the metal surface in Comparative Example 1 and Comparative Example 2, but no white surface phenomenon was found in the case of using the metal surface treatment agent according to the present invention.
상기에서는 본 발명의 바람직한 실시예를 참조하여 설명하였지만, 해당 기술 분야에서 통상의 지식을 가지는 기술자라면 하기의 특허청구범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 다양한 변형 및 균등한 타 실시예가 가능하여 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다. It will be apparent to those skilled in the art that various modifications and variations can be made in the present invention without departing from the spirit and scope of the invention as defined in the appended claims. It is to be understood that the invention is capable of various modifications and alterations of the invention.
Claims (13)
1)활성 킬레이트제 5 ~ 6중량부, 2)계면활성제 2 ~ 3중량부, 3)알칼리제 11.5 ~ 15중량부, 4)용제 5.5 ~ 7.5중량부, 및 5)증류수 68.5 ~ 76중량부를 포함하고,
상기 1)활성 킬레이트제로 EDTA(N,N-ETHYLENEDIAMINEDIACETIC ACID) 5 ~ 6중량부,
상기 2)계면활성제로 폴리(옥시-1,2-에탄디일), 알파포스포노-오메가-(메틸페녹시)-,디포타슘 염(Poly(oxy-1,2-ethanediyl), alphaphosphono-omega-(methylphenoxy)-, dipotassium salt) 2 ~ 3중량부,
상기 3)알칼리제로 구연산 나트륨(SODIUM CITRATE) 3 ~ 4 중량부, 메타규산소다(SODIUMMETASILICATE, PENTAHYDRATE) 8 ~ 10 중량부, 및 수산화칼륨(POTASSIUM HYDROXIDE) 0.5 ~ 1 중량부, 및
상기 4)용제로 BTG(TRIETHYLENE GLYCOL MONO BUTYL ETHER) 3 ~ 4 중량부 및 구연산(Citric acid) 2.5 ~ 3.5 중량부를 포함하는 것을 특징으로 하는
금속 표면 처리제.
Based on 100 parts by weight of the total composition
5 to 6 parts by weight of active chelating agent, 2 to 3 parts by weight of surfactant, 11 to 15 parts by weight of alkaline agent, 5.5 to 7.5 parts by weight of solvent and 68.5 to 76 parts by weight of distilled water, ,
5 to 6 parts by weight of EDTA (N, N-ETHYLENEDIAMINEDIACETIC ACID) as the active chelating agent,
(2) a surfactant selected from the group consisting of poly (oxy-1,2-ethanediyl), alpha phosphono-omega- (methylphenoxy), poly (oxy- 1,2-ethanediyl), alphaphosphono-omega- 2 to 3 parts by weight of methylphenoxy-, dipotassium salt,
3 to 4 parts by weight of sodium citrate, 8 to 10 parts by weight of SODIUMMETASILICATE, PENTAHYDRATE and 0.5 to 1 part by weight of POTASSIUM HYDROXIDE as the alkaline agent,
(4) 3 to 4 parts by weight of BTG (TRIETHYLENE GLYCOL MONO BUTYL ETHER) as a solvent and 2.5 to 3.5 parts by weight of citric acid
Metal surface treatment agent.
상기 금속 표면 처리제는 pH 12.0 ± 0.5를 가지는 것을 특징으로 하는
금속 표면 처리제.
The method according to claim 1,
Characterized in that the metal surface treatment agent has a pH of 12.0 + - 0.5
Metal surface treatment agent.
상기 금속 표면 처리제는 고형분(%) 15 - 20%인 것을 특징으로 하는
금속 표면 처리제.
The method according to claim 1,
Wherein the metal surface treatment agent has a solid content (%) of 15 to 20%
Metal surface treatment agent.
상기 금속 표면 처리제는 비중(100%) 1.05 - 1.08인 것을 특징으로 하는
금속 표면 처리제.
The method according to claim 1,
Wherein the metal surface treatment agent has a specific gravity (100%) of 1.05 - 1.08
Metal surface treatment agent.
상기 금속 표면 처리제는 수산화칼륨(KOH)의 함량이 5% 미만인 것을 특징으로 하는
금속 표면 처리제.
The method according to claim 1,
Wherein the metal surface treatment agent is characterized in that the content of potassium hydroxide (KOH) is less than 5%
Metal surface treatment agent.
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| JP2006082253A (en) | 2004-09-14 | 2006-03-30 | Toyota Motor Corp | Mold washing method |
| JP2014111808A (en) | 2012-12-05 | 2014-06-19 | Kao Corp | Detergent for steel plate |
| JP2014518752A (en) | 2011-04-14 | 2014-08-07 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for dissolving and / or inhibiting scale deposits on the surface of a system |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006082253A (en) | 2004-09-14 | 2006-03-30 | Toyota Motor Corp | Mold washing method |
| JP2014518752A (en) | 2011-04-14 | 2014-08-07 | ビーエーエスエフ ソシエタス・ヨーロピア | Method for dissolving and / or inhibiting scale deposits on the surface of a system |
| JP2014111808A (en) | 2012-12-05 | 2014-06-19 | Kao Corp | Detergent for steel plate |
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