KR101739022B1 - Semiconductor gas sensor and manufacturing method thereof - Google Patents
Semiconductor gas sensor and manufacturing method thereof Download PDFInfo
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- KR101739022B1 KR101739022B1 KR1020150156569A KR20150156569A KR101739022B1 KR 101739022 B1 KR101739022 B1 KR 101739022B1 KR 1020150156569 A KR1020150156569 A KR 1020150156569A KR 20150156569 A KR20150156569 A KR 20150156569A KR 101739022 B1 KR101739022 B1 KR 101739022B1
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- 238000004519 manufacturing process Methods 0.000 title abstract description 17
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- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical group O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 6
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- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance
- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
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- G01N27/125—Composition of the body, e.g. the composition of its sensitive layer
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- G01N27/04—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance
- G01N27/12—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating impedance by investigating resistance of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid, for detecting components in the fluid
- G01N27/125—Composition of the body, e.g. the composition of its sensitive layer
- G01N27/126—Composition of the body, e.g. the composition of its sensitive layer comprising organic polymers
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- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
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- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28158—Making the insulator
- H01L21/28167—Making the insulator on single crystalline silicon, e.g. using a liquid, i.e. chemical oxidation
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- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
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Abstract
The present invention relates to a semiconductor gas sensor and a method of manufacturing the same, and more particularly, to a semiconductor gas sensor including a substrate including an oxide film in which a hollow space is formed in a tube shape; A heater electrode layer formed on the oxide film on which the tube-shaped hollow space is formed; An insulating layer formed on the heater electrode layer; A sensor electrode layer formed on the insulating layer and formed on both sides of the tube-shaped void space; And a gas sensing layer formed on the insulating layer and the sensor electrode layer, and a method of manufacturing the same.
Description
The present invention relates to a semiconductor gas sensor and a method of manufacturing the same.
There are various kinds of gas in living environment, and gas accidents, general equipments, construction sites, explosive accidents in petroleum combinat, coal mine, chemical plant, and pollution pollution are continuing. Human sensory organs can not quantify the concentration of the hazardous gas or can hardly distinguish the type. In order to cope with this problem, a gas sensor using physical and chemical properties of a material has been developed and used for gas leakage detection, concentration measurement record, and alarm.
The most widely used gas sensor is SnO 2 , and the SnO 2 semiconductor gas sensor is used for the detection of combustible gas such as city gas, methane gas, propane gas, alcohol, and reducing gas such as CO and H 2 . Since SnO 2 does not exist at a certain position, electrons in the oxygen vacancy acting as a donor move to the conduction band and act as a carrier when the heat energy is applied from the outside. - type semiconductor. It is a very sensitive factor to change the characteristics of the sensor because it changes the electric conductivity and changes the gas adsorption by changing the number and mobility of carriers moving from the electron supply level to the conduction band. Therefore, when thermal energy is given to the SnO 2 particles, electrons that can move freely are increased. When oxygen gas is adsorbed thereon, trapped by the oxygen gas on the surface of the particles, a potential barrier is formed in the SnO 2 grain boundary, The electrical conductivity is lowered. Since the reducing gas or the combustible gas is oxidized with the oxygen gas, when these gases are present, the oxygen gas adsorbed on the surface of SnO 2 is removed, and the free electrons trapped in the oxygen gas enter into the SnO 2 particles to lower the potential barrier The electrical conductivity between the particles becomes large. As a result, the adsorption amount and desorption amount of the oxygen gas determine the sensitivity of the sensor.
However, the conventional tin dioxide-based gas sensor has a disadvantage in that it is insensitive to trace gases and has a slow response and recovery speed. To overcome this problem, even when nanomaterials are used, uniformity And contact with the metal electrode is unstable, resulting in low reliability and low life expectancy.
As a prior art related to this, there is a method for manufacturing a gas sensor for detecting ammonia gas and a gas sensor thereof disclosed in Korean Patent Laid-Open Publication No. 10-2012-0101938 (published on September 17, 2012).
Accordingly, it is an object of the present invention to provide a semiconductor gas sensor that maximizes heat generation efficiency and sensing surface area to reduce power consumption, sensitivity to a trace gas, and reaction speed, and a method of manufacturing the same.
The problems to be solved by the present invention are not limited to the above-mentioned problem (s), and another problem (s) not mentioned can be understood by those skilled in the art from the following description.
According to an aspect of the present invention, there is provided a plasma display panel comprising: a substrate including an oxide film having a hollow space formed therein; A heater electrode layer formed on the oxide film on which the tube-shaped hollow space is formed; An insulating layer formed on the heater electrode layer; A sensor electrode layer formed on the insulating layer and formed on both sides of the tube-shaped void space; And a gas sensing layer formed on the insulating layer and the sensor electrode layer.
Further, the present invention provides a method of manufacturing a semiconductor device, comprising: forming an oxide film on a substrate by anisotropic dry etching and isotropically wet etching the oxide film; Forming a heater electrode layer on the oxide film on which the hollow space of the tube is formed by a chemical vapor deposition method or an atomic layer deposition method and then forming an insulating layer; And a sensor electrode layer is formed on the insulating layer to form a sensor electrode layer and then a gas sensing layer is formed by a chemical vapor deposition method or an atomic layer deposition method or a gas sensing layer is formed on the insulating layer by a chemical vapor deposition method or an atomic layer deposition method, And forming a sensor electrode layer by patterning a sensor electrode layer on the gas sensing layer.
According to the present invention, a hollow space in the form of a tube is formed in the oxide film included in the substrate, and the heater electrode layer is provided adjacent to the gas sensing layer to maximize the heating efficiency, thereby minimizing power consumption and driving at low power. The surface area can be maximized and the sensitivity to the trace gas and the reaction rate can be improved.
Further, since the insulating layer formed on the upper part of the oxide film on which the hollow space of the tube shape is formed is further comprised of one kind selected from the group consisting of metals, metal oxides and polymers for increasing the specific surface area for gas sensing, A high sensitivity sensor can be realized.
1 is a schematic view showing a semiconductor gas sensor according to an embodiment of the present invention.
2 is a schematic diagram showing a semiconductor gas sensor according to another embodiment of the present invention.
3 is a schematic view showing a semiconductor gas sensor according to another embodiment of the present invention.
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
BRIEF DESCRIPTION OF THE DRAWINGS The advantages and features of the present invention and the manner of achieving it will become apparent with reference to the embodiments described in detail below with reference to the accompanying drawings.
The present invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. To fully disclose the scope of the invention to those skilled in the art, and the invention is only defined by the scope of the claims.
In the following description, well-known functions or constructions are not described in detail since they would obscure the invention in unnecessary detail.
The present invention provides a plasma display panel comprising: a substrate including an oxide film having a tube-shaped void space formed therein;
A heater electrode layer formed on the oxide film on which the tube-shaped hollow space is formed;
An insulating layer formed on the heater electrode layer;
A sensor electrode layer formed on the insulating layer and formed on both sides of the tube-shaped void space; And
And a gas sensing layer formed on the insulating layer and the sensor electrode layer.
The semiconductor gas sensor according to the present invention has a hollow space in the form of a tube in the oxide film included in the substrate and the heater electrode layer is provided adjacent to the gas sensing layer to maximize the heating efficiency, Can be maximized to increase the sensitivity to the trace gas and the reaction rate. Further, since the insulating layer formed on the upper part of the oxide film on which the hollow space of the tube shape is formed is further comprised of one kind selected from the group consisting of metals, metal oxides and polymers for increasing the specific surface area for gas sensing, A high sensitivity sensor can be realized.
1 is a schematic view showing a semiconductor gas sensor according to an embodiment of the present invention. 1, a
FIG. 2 is a schematic view of a semiconductor gas sensor according to another embodiment of the present invention. In FIG. 2, the specific surface area for gas sensing is increased on the
In the semiconductor gas sensor according to the present invention, the substrate may be one selected from the group consisting of silicon, glass, and aluminum, which is easy to process and can reduce the cost, and the heater electrode layer is formed by adsorbing oxygen or a specific gas It is preferable to use a heat generating material capable of maintaining a high temperature of 300 DEG C or more so as to be easy to use. Specifically, one selected from the group consisting of Ru, Pt, W, TiN and TaN can be used.
The insulating layer may be formed of SiO 2 , Si 3 N 4 or the like as a layer for preventing electricity or heat input / output between the heater electrode layer and the sensor electrode layer formed on the insulating layer.
The sensor electrode layer is for measuring a change in electrical resistance in the gas sensing layer, and one kind selected from the group consisting of Au, W, and Pt can be used.
In addition, the gas sensing layer may use a semiconductor material whose resistance varies sensitively according to the gas, and specifically SO 2 may be used. Air from the oxygen adsorbed on the SnO 2 surface of the gas sensing layer is let in the SnO 2 e in combination with oxygen, the current to flow well through the SnO 2. On the other hand, methane, hydrogen, carbon monoxide, and the atmosphere is a reducing gas such as ammonia exists decrease the oxygen concentration to be adsorbed on the surface to SnO 2 in the electron density increases, the current through the SnO 2 flows well gas through the change in current Can be detected.
As described above, the semiconductor gas sensor according to the present invention may form one species selected from the group consisting of metals, metal oxides, and polymers on the insulating layer formed on the oxide film on which the hollow spaces are formed. The metal oxide may be SnO 2 , ZnO, FeO 2 , SnO 2 , SnO 2 , ZnO, or Sn. Examples of the metal may include Ag, Au, Pt, Ir, Ru, W, Fe, Ni, SiO 2 , Al 2 O 3 , NiO, WO 2 , TiO 2 , CeO 2 and ZrO 2 can be used. As the polymer, polyethylene, polyamide, polystyrene and polypropylene can be used.
According to another aspect of the present invention, there is provided a plasma display panel comprising: a substrate including an oxide film having a hollow space formed therein;
A heater electrode layer formed on the oxide film on which the tube-shaped hollow space is formed;
An insulating layer formed on the heater electrode layer;
A gas sensing layer formed on the insulating layer; And
And a sensor electrode layer formed on the gas sensing layer and formed on both sides of the tube-shaped void space.
3 is a schematic view showing a semiconductor gas sensor according to another embodiment of the present invention. As shown in FIG. 3, the
Further, the present invention provides a method of manufacturing a semiconductor device, comprising: forming an oxide film on a substrate by anisotropic dry etching and isotropically wet etching the oxide film;
Forming a heater electrode layer on the oxide film on which the hollow space of the tube is formed by a chemical vapor deposition method or an atomic layer deposition method and then forming an insulating layer; And
A sensor electrode layer is formed on the insulating layer to form a sensor electrode layer, and then a gas sensing layer is formed on the electrode layer by a chemical vapor deposition method or an atomic layer deposition method. Alternatively, a gas sensing layer may be formed on the insulating layer by chemical vapor deposition or atomic layer deposition And forming a sensor electrode layer by patterning a sensor electrode layer on the gas sensing layer after forming the sensing layer.
A method of manufacturing a semiconductor gas sensor according to the present invention is a method for manufacturing a semiconductor gas sensor, comprising: forming an inlet for manufacturing an empty space of a tube shape by anisotropic dry etching an oxide film of a substrate including an oxide film; It is possible to minimize sensor consumption power and to realize a high sensitivity sensor by reducing gas loss and gas entry.
As described above, the sensor electrode layer may be formed first on the insulating layer, and then the gas sensing layer may be formed. Alternatively, the sensor electrode layer may be formed after forming the gas sensing layer on the insulating layer.
In addition, in the method of manufacturing a semiconductor gas sensor according to the present invention, one selected from the group consisting of spray coating, spin coating, chemical vapor deposition, and spraying is used on an insulating layer formed on the oxide film on which the hollow space of the tube is formed Thereby forming one species selected from the group consisting of metals, metal oxides and polymers.
The types of the metal, the metal oxide and the polymer are as described above.
Example 1: Fabrication of semiconductor gas sensor 1
The silicon substrate on which the oxide film was formed was subjected to anisotropic dry etching to prepare an inlet for producing a hollow space of a tube shape, and then an isotropic wet etching was performed to form a tube-shaped hollow space inside the oxide film formed on the silicon substrate. Chemical vapor deposition (CVD) or atomic layer deposition (ALD) to the heater electrode of the interlayer insulation of the SiO 2 by chemical vapor deposition or atomic layer deposition after forming the Ru metal film on the oxide film and the oxide film above formed in the empty space of the tube-like Layer. An Au sensor electrode layer was patterned on both sides of the tube-shaped void space in which the interlayer insulating layer was formed, and a SnO 2 gas sensing layer was coated on the insulating layer and the sensor electrode layer by atomic layer deposition to form a semiconductor gas sensor.
Example 2: Fabrication of semiconductor gas sensor 2
The silicon substrate on which the oxide film was formed was subjected to anisotropic dry etching to prepare an inlet for producing a hollow space of a tube shape, and then an isotropic wet etching was performed to form a tube-shaped hollow space inside the oxide film formed on the silicon substrate. Chemical vapor deposition (CVD) or atomic layer deposition (ALD) to the heater electrode of the interlayer insulation of the SiO 2 by chemical vapor deposition or atomic layer deposition after forming the Ru metal film on the oxide film and the oxide film above formed in the empty space of the tube-like Layer. A SnO 2 gas sensing layer was coated on the interlayer insulating layer by atomic layer deposition and then patterned on both sides of the void space of the tube to form an Au sensor electrode layer to fabricate a semiconductor gas sensor.
Example 3: Fabrication of semiconductor gas sensor 3
A nanosecond to micro-sized ZnO particles are coated on the silicon substrate and the sensor electrode layer having a spherical space by a spray coating method, and then the Au sensor electrode layer is patterned and a SnO 2 sensor material is coated on the silicon substrate and the sensor electrode layer, A semiconductor gas sensor was manufactured in the same manner as in Example 1 above.
Although the semiconductor gas sensor according to the present invention and the method of manufacturing the same according to the present invention have been described above, it is apparent that various modifications can be made without departing from the scope of the present invention.
Therefore, the scope of the present invention should not be limited to the above-described embodiments, but should be determined by the scope of the appended claims and equivalents thereof.
It is to be understood that the foregoing embodiments are illustrative and not restrictive in all respects and that the scope of the present invention is indicated by the appended claims rather than the foregoing description, It is intended that all changes and modifications derived from the equivalent concept be included within the scope of the present invention.
100, 200, 300: semiconductor gas sensor
110, 310:
120, 320:
140, 350:
160: metal, metal oxide or polymer
Claims (9)
A heater electrode layer formed on the oxide film on which the tube-shaped hollow space is formed;
An insulating layer formed on the heater electrode layer;
A sensor electrode layer formed on the insulating layer and formed on both sides of the tube-shaped void space; And
And a gas sensing layer formed on the insulating layer and the sensor electrode layer,
Further comprising a metal oxide particle on an insulating layer formed on an oxide film on which the hollow space of the tube is formed,
The heater electrode layer is made of ruthenium (Ru)
The gas sensing layer is tin dioxide (SnO 2) of a semiconductor gas sensor, characterized in that.
Wherein the substrate is one selected from the group consisting of silicon, glass, and aluminum.
Wherein the insulating layer is SiO 2 or Si 3 N 4 .
Wherein the sensor electrode layer is one selected from the group consisting of Au, W, and Pt.
Forming a heater electrode layer on the oxide film on which the hollow space of the tube is formed by a chemical vapor deposition method or an atomic layer deposition method and then forming an insulating layer; And
A sensor electrode layer may be formed on the insulating layer to form a sensor electrode layer, and then a gas sensing layer may be formed by a chemical vapor deposition method or an atomic layer deposition method. Alternatively, a gas sensing layer may be formed on the insulating layer by a chemical vapor deposition method or an atomic layer deposition method. And forming a sensor electrode layer by patterning a sensor electrode layer on the gas sensing layer,
The heater electrode layer is made of ruthenium (Ru)
The gas sensing layer is a tin dioxide (SnO 2),
The method further comprises forming a metal oxide on the insulating layer formed on the oxide film on which the hollow space of the tube is formed by using one selected from the group consisting of spray coating, spin coating, chemical vapor deposition and spraying Wherein the semiconductor gas sensor is a semiconductor sensor.
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KR102393007B1 (en) | 2020-11-16 | 2022-05-03 | 강소영 | Server for providing target gas service and method thereof |
KR20220066545A (en) | 2020-11-16 | 2022-05-24 | 강소영 | Apparatus for sensing target gas and method thereof |
KR20220066544A (en) | 2020-11-16 | 2022-05-24 | 강소영 | Apparatus for monitoring target gas and method thereof |
KR20220103885A (en) | 2021-01-16 | 2022-07-25 | 강소영 | Surveillance apparatus using image |
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---|---|---|---|---|
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KR100721261B1 (en) | 2005-11-30 | 2007-05-25 | 전자부품연구원 | Micro gas sensor and manufactutring method thereof and micro gas sensor package and manufactutring method thereof |
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KR100721261B1 (en) | 2005-11-30 | 2007-05-25 | 전자부품연구원 | Micro gas sensor and manufactutring method thereof and micro gas sensor package and manufactutring method thereof |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102393007B1 (en) | 2020-11-16 | 2022-05-03 | 강소영 | Server for providing target gas service and method thereof |
KR20220066545A (en) | 2020-11-16 | 2022-05-24 | 강소영 | Apparatus for sensing target gas and method thereof |
KR20220066544A (en) | 2020-11-16 | 2022-05-24 | 강소영 | Apparatus for monitoring target gas and method thereof |
KR20220074844A (en) | 2020-11-16 | 2022-06-03 | 강소영 | Surveillance apparatus using sensor |
KR20220103885A (en) | 2021-01-16 | 2022-07-25 | 강소영 | Surveillance apparatus using image |
KR20220103871A (en) | 2021-01-16 | 2022-07-25 | 강소영 | Surveillance apparatus |
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