KR101616016B1

KR101616016B1 - The Eco-environment composition

Info

Publication number: KR101616016B1
Application number: KR1020160002454A
Authority: KR
Inventors: 신수연
Original assignee: 신수연
Priority date: 2016-01-08
Filing date: 2016-01-08
Publication date: 2016-04-27

Abstract

The present invention relates to a manufacturing method of a neutralizing agent for the toxicity of cement causing sick house syndrome. The neutralizing agent for the toxicity of cement is manufactured by: mixing 1,000 g of natural zeolite powder in 600 mesh and 200 g of silica gel powder in 600 mesh to obtain mixed powder; mixing 1,000 g of the mixed powder and 2,000-3,000 g of water, grinding a mixture composed of the mixed powder and the water by a ball mill, transferring the ground mixture to a filter press, and filtering and settling the ground mixture to obtain a mineral solution; fixing silver rods connected to positive and negative electrodes to an electrolyzer while maintaining an interval between the positive and negative electrodes at a level of 5-10 mm; electrolyzing an electrolyte which is a mixture composed of 20 kg of the mineral solution and 200 g of sodium hypochlorite in the electrolyzer to manufacture a nanosilver mineral composition; agitating 1,000 g of the nanosilver mineral solution and 200 g of colloidal silica to manufacture a nanosilver mixture; agitating 200 g of 1 N caustic soda and 1,000 g of aluminum powder, adding 1,000 g of water to the caustic soda and the aluminum powder, and performing filtration, drying and grinding processes to manufacture a powdered aluminum composition; mixing 1,000 g of the powdered aluminum composition, 500 g of sericite powder, 500 g of loess powder, 50 g of permanganate of potassium, 100 g of tumeric powder, and 100 g of zinc oxide to manufacture an aluminum and sericite mixture; and mixing 1,000 g of the aluminum and sericite mixture, 2,000 g of the nanosilver mixture, and 200 g of an acrylic binder to obtain a mixture, and grinding the mixture for 10 hours.

Description

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a coconut-

The present invention relates to a method for manufacturing a sick house syndrome cement toxic remover which prevents toxicity and mold from cement walls.

The residential living space in which we live has cement walls on all sides. According to reports, strong alkaline salts from the wall of the cement come into contact with the air, resulting in a strong alkaline salt of fine powder on the wall surface, which causes the wallpaper to enter the room air and enter the room air, which is very dangerous to the human body. It has been frequently reported that the fungus that has died due to the humidity inside the living room due to the condensation phenomenon due to the external temperature difference causes various respiratory diseases and atopic dermatitis and various dermatitis due to the influx of the fungal body such as alkali salt into the indoor air But there is no suggestion.

There are reports that cement contains not only toxic substances such as alkali salts but also various radioactive substances exceeding the standard value. Since it has been well-known for a long time, it has built a house that has been moved from loess, trees and minerals. It can be seen that there are various kinds of conventional technologies such as building materials using various mineral powders such as yellow loam, elvan stone and oxcamic white coal.

Various techniques for removing the odor of various organic compounds, which are the main cause of sick house syndrome, are disclosed.

For example, in Korean Patent Registration No. 1009782280000 (Aug. 20, 2010), there is disclosed a biodegradable material such as biotite, carly, iron oxide, ferric oxide, alumina, zircon, sericite, tourmaline, zircon, zirconium, charcoal powder, An eco-friendly composition for removing sick house syndrome consisting of manganese, magnesium oxide, talc, nickel, sulfur, copper oxide, calcium carbonate, magnetite, cererium, leucine, nephrite, magnesium, cerium, calcium oxide, A method for eliminating the syndrome is described,

In Korean Patent Registration No. 1008830530000 (2009.02.04), 100 g of aluminum hydroxide, 100 g of tourmaline, and 200 g of powder of 400 mesh of basalt were mixed with 600 g of powder obtained by crushing white coal produced by burning oak at 1000 ° C with 400 mesh, 200 g of water-soluble acrylic binder (55% solids) and 1000 ml of water were mixed and then an ordinary silver nano solution was mixed to prepare an antimicrobial binder. Then, the antibacterial binder thus prepared was added with the first mixture And then adding the resulting mixture to a viscosity of 200 poise. The method for producing a cedar sickness toxin-removing agent is disclosed,

Korean Patent Laid-Open Publication No. 10-2006-19081 discloses an artificial zeolite having excellent deodorization and adsorption effect, and a charcoal which is excellent in air purification and adsorption, far-infrared radiation, anion release ability, antibacterial, sterilization, odor and odor removal A composition for minimizing the phenomenon of sick house syndrome by synthesizing silver ions having superior ability is disclosed,

Korean Patent Publication No. 1012377000000 discloses a method of forming a molding material of a composition comprising a natural volatile acid powder inorganic antibacterial agent charcoal powder of 80-120 mesh and a composition of a volatile acid-producing raw material in this composition with a calcium chloride powder, A multi-functional sintering agent having a deodorizing and dehumidifying antibacterial function is obtained by drying and adjusting moisture under a time condition and sintering the sintered body using an electric furnace or a heating apparatus of a sintering furnace,

Korean Patent Publication No. 101462483000 discloses a method for producing a sericite deodorant by mixing a sericite powder and a vinegar which is easily dissolved by a deodorizing object.

1. Korean Patent Registration No. 1008830530000 (2009.02.04) 2. Korean Patent Laid-Open Publication No. 10-2006-19081 3. Korean Patent Publication No. 1012377000000 4. Domestic Patent Registration Patent No. 101462483000

Conventional techniques fail to obtain satisfactory results in eliminating cement toxicity, so that the toxicity of strong alkaline salts discharged from the cement wall causing the sick house syndrome and the various fungi living on the cement wall enter the room air and adversely affect the human body The problem to be solved by the present invention is a problem to be solved.

In order to solve the above-mentioned problems, the present invention relates to a process for producing a polyurethane foam, which comprises mixing 1000 g of 600-mesh natural zeolite powder and 200 g of 600-mesh silica gel powder, mixing 2000 g to 3000 g of water into 1000 g of the mixture,

Crushed with a ball mill, transferred to a filter press, filtered and precipitated to obtain a mineral solution,

+ And - poles were fixed to the electrolytic cell at intervals of 5 mm to 10 mm on the electrolytic cell, and then the electrolytic cell was charged with 20 kg of the mineral solution and 200 g of oxygenated oxygen, To prepare a nanosilver mineral composition,

1000 g of the nano-silver mineral solution and 200 g of colloidal silica were stirred to prepare a nano-silver mixture,

After 200 g of 1N caustic soda and 1000 g of aluminum powder were stirred, 1000 g of water was added, followed by filtration, followed by drying and pulverization to prepare a powdered aluminum composition,

The aluminum persimmon mixture was prepared by mixing 1000 g of the aluminum composition powder, 500 g of the sericite powder, 500 g of the loess powder, 50 g of the limestone powder, 100 g of the kaolin powder, and 100 g of zinc oxide,

It is a further object of the present invention to provide a method for manufacturing a sick building syndrome cigarette toxicity remover which is prepared by mixing 1,000 g of the above-mentioned aluminum rhinestone mixture, 2000 g of the nano-silver mixture, and 200 g of an acrylic binder, and pulverizing the mixture for 10 hours.

Disclosed is an antifungal composition which is excellent in deodorizing and adsorbing ability, excellent in air purification and adsorption, far infrared ray emission and anion releasing ability, excellent in antibacterial, antifungal, odor and odor removal ability, As a result,

In addition to being able to minimize hygienic and pleasant indoor environment by minimizing phenomena such as "Sickness Syndrome" which is a recent problem, "Chemical Hypersensitivity", it minimizes cement toxicity, has anti-fungal effect, It is possible to reduce the phenomenon remarkably by applying it to all the fields of concern.

In order to achieve the above object, the present invention relates to a process for producing a polyurethane foam, which comprises mixing 1000 g of 600-mesh natural zeolite powder and 200 g of 600-mesh silica gel powder, mixing 2000 g to 3000 g of water into 1000 g of the mixture,

The present invention relates to a method for producing a sick building syndrome cigarette toxicity remover prepared by mixing 1,000 g of the above-described aluminum rhinestone mixture, 2000 g of the nano-silver mixture, and 200 g of an acrylic binder, followed by pulverization for 10 hours.

The natural zeolite powder of the present invention is conventionally mined and is produced in powder form, i.e. in fine power form. Natural zeolites include clinoptillolite, mordenite, smectite, feldspar and quartz, which are highly thermally safe. Since the natural zeolite has a large surface area, a large cation substitution capacity, a molecular sieve structure, and a large surface charge, it is widely used for adsorbing and removing soil conditioner and various environmental pollutants have.

The silica gel of the present invention is a very low-density high-tech material having a nano-porous structure with a porosity of 90% or more and a specific surface area of several hundred to 1500 m2 / g. Therefore, the nanoporous silica gel can be applied to the fields of ultra-low dielectric materials, catalysts, electrode materials, and soundproofing materials.

The silver of the present invention has been used for royal family or nobles since it has been found that food is stored in a bowl for a long time and the food is not corroded and kept fresh for a long time and recently a silver filter . Recently, it has been reported that all germs or viruses on the ground come into contact with silver and there are no bacteria or viruses surviving for 6 minutes.

Many people use subways, work in underground shopping malls, buildings, etc., and many people live in markets, department stores, etc., and sunlight is cut off and many pathogenic bacteria such as moisture are growing. However, inorganic disinfectants are not yet developed as disinfectants.

In addition, if you look at the antimicrobial relationship of silver, it is the theory that silver acts on special enzymes that cause metabolism of single cell pathogens to sterilize germs and also that silver (AG +) ions of antimicrobial metals sterilize However, there is no systematic report on how to sterilize germs.

The colloidal silica of the present invention has advantages of uniform particle and very high stability.

Colloidal silica is obtained by dispersing silica fine particles in a medium such as water and is used not only as a physical property improving agent in the fields of paper, fiber, and steel but also as an abrasive for electronic materials such as semiconductor wafers.

As a method for producing colloidal silica so far, the two main methods are water glass method and alkoxide method.

In the water-free method, active silicic acid is prepared by ion-exchanging sodium silicate and then added to an aqueous solution containing seed particles adjusted with NaOH under heating to effect grain growth. According to this method, particles having a relatively dense structure can be obtained.

The alkoxide method is a so-called Stoeber method, and the silica particles are produced by hydrolysis of alkyl silicate (tetraalkoxysilane) in the presence of a basic catalyst, while condensation and particle growth are carried out. According to this method, it is possible to manufacture nanoscale colloid particles to micrometer-scale colloid particles.

For example, a mixture of methyl silicate (tetramethoxysilane) or methyl silicate and methanol is added dropwise to a mixed solvent containing water, methanol, ammonia or ammonia and an ammonium salt with stirring for 10 to 40 minutes, and methyl silicate and water To produce a colloidal silica having a short diameter of 10 to 200 nm and a long diameter / short width ratio of 1.4 to 2.2. A method of producing a cocoon-shaped colloidal silica is proposed.

Further, there is known a process for producing a cocoon type colloidal silica, characterized in that tetramethoxysilane tetramers are hydrolyzed while dropping them in a mixture of methanol, water and ammonia.

The aluminum of the present invention is made of powdered powder having excellent adsorptivity and porosity when it is reacted with a strong alkali and adsorbed without being neutralized when it is combined with the strong alkali coming from the cement. The aluminum composition is made into a powdered powder and has a far-infrared dehumidifying antibacterial deodorizing function

The sericite of the present invention is an important material of clay minerals, and it has an effect of discharging it to the outside of the body and preventing aging even if it is applied to the skin or the waste toxic substance of the human body, and it is known to emit anion and far-infrared rays.

The loess of the present invention was used by our forefathers in making houses, earthenware, etc. The loess gives a refreshment to the cold energy of the night and gives the coolness of the daytime warmth. This is called the energy of discussion.

In recent years, these loess have become increasingly easy to use everyday products in combination with human psychology, whose effectiveness is scientifically analyzed, proven and pursuing a healthy life.

In other words, loess is the most beneficial ray of life for all life.

The potassium permanganate of the present invention has a deodorizing and fungicidal antifungal function and does not cause a reaction when bound to a strong alkali,

The turmeric powder of the present invention was used as a Chinese medicine because of its excellent fungicidal function and safety.

The zinc oxide of the present invention has been used for a long time as an anti-rash drug and has a mold removal function.

The acrylic binder of the present invention functions as an adhesive.

The present invention is applied to a floor or a wall of a new building such as an apartment, a house, or a shopping mall by first drying it on a floor or a wall, and then works as an interior work such as wallpaper and floor construction to absorb harmful components emitted from various kinds of interior materials and cement Removal, mitigation, or neutralization, which can significantly reduce phenomena such as sick house syndrome, which can be used generally in construction and construction.

The present invention will be described in detail with reference to the following examples.

Example

The first step (preparation of a mineral solution)

1,000 g of 600-mesh natural zeolite powder and 200 g of 600-mesh silica gel powder were mixed, and 1000 g of the mixture was mixed with 2000 g to 3000 g of water,

Transferred to a ball mill and pulverized for 24 hours to 48 hours,

The pulverized material was transferred to a filter press and the filtered filtrate was settled for 24 hours to obtain a mineral solution,

The second step (electrolysis)

Two 100 g silver electrodes were selected and connected to the + and - poles of the electrolytic apparatus, respectively. The silver electrodes connected to the + and - poles were fixed to the electrolytic cell at intervals of 5 mm to 10 mm in the electrolytic cell, , A mixture of 20 kg of the mineral solution prepared in the above process and 200 g of oxygen chloride and oxygen was fixed to the electrolytic cell at an electric current of 3 volts and 13 amps and electrolysis was performed according to the electrolysis process, (Electrolysis) to produce a nano-silver mineral composition,

The third step (nano silver mixture manufacturing)

200 g of colloidal silica was added to 1000 g of the nano-silver mineral solution and stirred at a rotation speed of 120 rpm for 30 minutes to prepare a nano-silver mixture in which a nano-crystalline mineral solution and colloidal silica were mixed,

Fourth step (preparation of aluminum persimmon mixture)

200 g of 1N caustic soda and 1000 g of aluminum powder were put into a stirrer and stirred slowly to prepare a bulk solid. 1000 g of water was added to the mixture, and the mixture was filtered with a filter cloth,

Dried at 80 ° C to 90 ° C for 1 to 2 hours and then transferred to a ball mill to prepare a powdered aluminum composition,

Fifth Process (Manufacture of Sick House Syndrome Cement Toxicity Remover)

1000 g of the aluminum rhinestone mixture, 2000 g of the nano-silver mixture prepared in the third step and 200 g of the acrylic binder were mixed and transferred to a ball mill and pulverized for 10 hours to prepare a sick house syndrome cement toxicity remover.

Sixth step (applied to building)

The nano-silver mixture was first applied to the surface of a cement-based building with a thickness of 1 mm to 3 mm, and then applied to the top of the primary coating with a thickness of 1 mm to 3 mm.

Experimental Example 1 (Measurement of alkaline salt formation on cement wall)

The cement wall alkaline salt measurement laboratory was not available as well as the data.

Cement powder 80g 20% of sand was mixed at a weight ratio, a certain amount of water was added and mixed, and then extruded to a size of 10 mm in thickness and 5 mm in diameter to prepare two plate-like cement specimens

1) Samples were divided into No. 1 and No. 2, and the resultant was completely dried at a drier temperature of 25 ° C.,

2) Use sample 1 as it is

Sample No. 2 was prepared by first coating the nano silver mixture prepared in the example of the present invention on the surface of the cement-based building with a thickness of 1 mm-3 mm and then spraying the saggital syndrome cement toxicity remover with 1 mm-3 mm And then dried. Then,

3) pH 10 was measured when the pH was measured on the front surface of one cement sample which was not treated with chemicals.

The test pieces were immersed in 10 g of water on the back side of each of the test pieces 1 and 2, and the test pieces were thoroughly dried at a dryer temperature of 25 ° C

As a result of visual inspection of the front surface, alkali salt of white spot was formed in Sample 1,

As a result of pH measurement, it was confirmed that the pH value was 13,

On the other hand, in the specimen coated with the sample 2, the alkali salt was not visually observed. As a result, it was confirmed that the pH value was 8.5.

Room 2 (antibacterial experiment)

The antimicrobial test was conducted as follows using the cage toxin remover prepared from the sick building syndrome of the present invention.

E. coli reduction rate (%) Staphylococcus aureus reduction rate (%) Example 99.9 99.9

(Remark) The strains used are

Strain 1: Escherichia coli ATCC 25922

Strain 2: Staphylococcus aureus ATCC 6538 was used, and the test method was measured by the standard method of the Korea Testing and Research Institute.

Experimental Example 3 (Antifungal Experiment)

The antifungal test was carried out as follows using the caged sickness remover prepared from the example of the present invention.

Mold reduction rate (%) Example 99.9

Use Fungus strain 1: Aspergillus niger ATCC 6985,

Fungal strains were used and the test method was measured by the standard method of the Korea Testing and Research Institute.

Table 1 and Table 2 show the results of the antimicrobial activity test, respectively. The antimicrobial activity of the antimicrobial activity was 99.9% or more.

Experimental Example 4 (total volatile organic compound and formaldehyde test)

The total volatile organic compound test and the formaldehyde test were carried out as follows using the sickle-back syndrome cement toxic remover prepared in the example of the present invention.

Total volatile organic compounds
(TVOC)
(mg / m 2 h) Formaldehyde
(HCHO)
(mg / m 2 h) Example 0.001 trace

Remarks) The test method is the standard method of Korea far infrared ray association

It was measured by the indoor air quality process test method (Ministry of Environment Notification No. 2004-80).

As described above, the eco-friendly finishing material of the present invention eliminates harmful substances such as formaldehyde and volatile organic compounds, and has far-infrared radiation, antibacterial and antifungal functions, thus improving the residential environment and providing various functionalities .

Claims

A method for manufacturing a sick house syndrome cement toxicity remover,
The first step (preparation of a mineral solution)
1,000 g of 600-mesh natural zeolite powder and 200 g of 600-mesh silica gel powder were mixed, and 1000 g of the mixture was mixed with 2000 g to 3000 g of water,
Transferred to a ball mill and pulverized for 24 hours to 48 hours,
The pulverized material was transferred to a filter press and the filtered filtrate was settled for 24 hours to obtain a mineral solution,
The second step (electrolysis)
Two 100 g silver electrodes were selected and connected to the + and - poles of the electrolytic apparatus, respectively. The silver electrodes connected to the + and - poles were fixed to the electrolytic cell at intervals of 5 mm to 10 mm in the electrolytic cell, , A mixture of 20 kg of the mineral solution prepared in the above process and 200 g of oxygen chloride and oxygen was fixed to the electrolytic cell at an electric current of 3 volts and 13 amps and electrolysis was performed according to the electrolysis process, (Electrolysis) to produce a nano-silver mineral composition,
The third step (nano silver mixture manufacturing)
200 g of colloidal silica was added to 1000 g of the nano-silver mineral solution and stirred at a rotation speed of 120 rpm for 30 minutes to prepare a nano-silver mixture in which a nano-crystalline mineral solution and colloidal silica were mixed,
Fourth step (preparation of aluminum persimmon mixture)
200 g of 1N caustic soda and 1000 g of aluminum powder were put into a stirrer and stirred slowly to prepare bulk solid form. Then, 1000 g of water was added and mixed. Then, the mixture was filtered with a filter cloth and transferred to a dryer at 80 캜 to 90 캜 Dried for 1 to 2 hours, and then transferred to a ball mill to prepare a powdered aluminum composition,

The aluminum persimmon mixture was prepared by mixing 1000 g of the aluminum composition powder, 500 g of the sericite powder, 500 g of the loess powder, 50 g of the limestone powder, 100 g of the kaolin powder, and 100 g of zinc oxide,

Fifth Process (Manufacture of Sick House Syndrome Cement Toxicity Remover)
The method of manufacturing a sick building syndrome cigarette toxicity removing agent according to claim 1, wherein 1000 g of said aluminum rhinestone mixture, 2000 g of nano silver mixture prepared in the third step, and 200 g of acrylic binder are mixed and transferred to a ball mill and pulverized for 10 hours.