KR101198502B1 - Ceramic increasing Hydrogen ion concentration and releasing mineral - Google Patents
Ceramic increasing Hydrogen ion concentration and releasing mineral Download PDFInfo
- Publication number
- KR101198502B1 KR101198502B1 KR1020100107993A KR20100107993A KR101198502B1 KR 101198502 B1 KR101198502 B1 KR 101198502B1 KR 1020100107993 A KR1020100107993 A KR 1020100107993A KR 20100107993 A KR20100107993 A KR 20100107993A KR 101198502 B1 KR101198502 B1 KR 101198502B1
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- oxide
- water
- less
- ceramic
- Prior art date
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/22—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in calcium oxide, e.g. wollastonite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/64—Burning or sintering processes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
본 발명은 pH를 상승시키고 미네랄을 용출하여 정제 및 정수기 필터로 사용 할 수 있는 다공성 세라믹에 관한 것이다.
본 발명은 본 발명은 산화규소(SiO2) 33~39 중량%, 산화알루미나(Al2O3) 18~22 중량％, 산화칼슘(CaO) 22~26 중량%, 산화마그네슘(MgO) 11~16 중량%, 산화철(Fe2O3) 1~2 중량%, 산화나트륨(Na2O) 1 중량% 이하, 산화칼륨 (K2O) 1 중량% 이하, 산화티타늄(TiO2) 1 중량% 이하, 산화지르콘(ZrO2) 1 중량% 이하로 구성된 다공성 세라믹조성물에 관한 것이다.
1~10mm의 크기와 900~1,100℃에서 소성한 세라믹을 정수기 필터로 제작하여 물이 세라믹필터를 통과하여 pH를 상승시키고 미네랄을 용출시키는 원리를 활용한 것이다.The present invention relates to a porous ceramic that can be used as a tablet and water purifier filter by elevating pH and eluting minerals.
The present invention is a silicon oxide (SiO 2 ) 33-39% by weight, alumina oxide (Al 2 O 3 ) 18-22% by weight, calcium oxide (CaO) 22-26% by weight, magnesium oxide (MgO) 11- 16% by weight, 1-2 % by weight of iron oxide (Fe 2 O 3 ), 1% by weight or less of sodium oxide (Na 2 O), 1% by weight or less of potassium oxide (K 2 O), 1% by weight of titanium oxide (TiO 2 ) Hereinafter, a porous ceramic composition composed of zircon oxide (ZrO 2 ) 1 wt% or less.
It is made of ceramics calcined at 1 ~ 10mm and fired at 900 ~ 1,100 ℃ as water purifier filter and water is used to raise pH and elute minerals through ceramic filter.
Description
본 발명은 수소이온농도를 상승시키고 미네랄을 용출하여 정제 및 정수기 필터로 사용할 수 있는 세라믹에 관한 것이다. The present invention relates to a ceramic that can be used as a purification and water purifier filter by increasing the hydrogen ion concentration and eluting minerals.
'수소 이온농도(水素─濃度, Hydrogen ion concentration)'란 물질의 산성, 알카리성의 정도를 나타내는 수치로, 수소 이온 활용도의 척도이다. Hydrogen ion concentration is a measure of the acidity and alkalinity of a substance and is a measure of hydrogen ion utilization.
용액 1L 속에 존재하는 수소 이온(水素─, Hydrogen ion)의 몰수를 의미하며 [H+]로 나타낸다. 수소 이온이 많아질수록 용액은 산성에 가까워지며, 폐수처리를 할 경우 중화(中和, Neutralization)·응집(凝集, Coagulation) 등 화학적 처리를 할 때 중요한 구실을 한다. 순수한 물일 경우 1기압 25℃에서 수소 이온의 농도가 약 10-7M(몰농도, Molarity)이며, 이를 기준으로 산성도(酸性度, Acidity)를 측정한다. 하지만 수소이온의 몰수는 이처럼 매우 작은 값이므로 표현하기가 불편하다. 따라서 간단하게 표현하기 위해 수소이온량(ㅡ量, Ionic weight)의 역수에 상용로그(Common Logarithm)를 취한 값을 수소 이온농도지수 pH로 사용한다.It represents the number of moles of hydrogen ions present in 1 L of the solution and is represented by [H + ]. As the number of hydrogen ions increases, the solution becomes more acidic, and in the case of wastewater treatment, it plays an important role in chemical treatment such as neutralization and coagulation. In the case of pure water, the concentration of hydrogen ions is about 10 −7 M (molarity) at 1 atmosphere of 25 ° C., and acidity is measured based on this. However, since the number of moles of hydrogen ions is such a small value, it is inconvenient to express them. Therefore, for the sake of simplicity, the value obtained by taking the common logarithm to the inverse of the ionic weight is used as the pH concentration index.
수용액(水溶液, Aqueous Solution)속에서 물 분자의 일부는 수소 이온과 수산화 이온(水酸化─, Hydroxyl Ion)으로 이온화된다. 이때 같은 수소의 수소 이온과 수산화 이온이 생성되거나 사라지므로 수소 이온농도 [H+]와 수산화 이온의 농도 [OH-]의 합은 용액의 액성과 관계없이 항상 일정하다.In aqueous solutions, some of the water molecules are ionized into hydrogen ions and hydroxide ions. In this case, since hydrogen ions and hydroxide ions of the same hydrogen are generated or disappeared, the sum of the hydrogen ion concentration [H + ] and the hydroxide ion concentration [OH − ] is always constant regardless of the liquidity of the solution.
물과 pH의 관계는, 화학적으로 물이나 물질 성분이 알카리 이온화된 것의 측정 기준을 'pH'라 하며 학술명으로는 '수소 이온 농도'라고 한다. pH는 보통 1~14까지의 수치로 나타내며, pH값이 7이면 중성, 7 이하면 산성, 7 이상이면 알카리성이다. The relationship between pH and water is chemically known as the pH-based measure of alkali ionization of water and substance components, and the scientific name is called hydrogen ion concentration. The pH is usually expressed as a value from 1 to 14, with a pH of 7 being neutral, below 7 being acidic and above 7 being alkaline.
인간의 최적의 농도는 약 알카리성인데, 이 상태에서 효소 작용 및 항체 생성의 최적이다. 사람의 위액 산도는 pH 2.5(강산성)이므로, 이를 중화시키고 몸을 항상 최적의 상태로 유지시켜 줄 수 있는 약 알카리수가 좋은 물이다. The optimal concentration in humans is about alkaline, in which state the optimum for enzymatic action and antibody production. Since gastric acidity in humans is pH 2.5 (strongly acidic), it is a good alkaline water that can neutralize it and keep your body in optimal condition at all times.
인체는 하루에 3.8L의 물이 필요하다. 그중 1.9L는 물위 형태로 공급되고 나머지는 물질대사(物質代謝, Metabolism)와 음식에 함유된 수분에서 공급된다. 그러나 인간이 먹는 음식 중 알카리를 형성하는 것보다 산성을 형성하는 것이 더 많다. 우리가 마시는 수돗물 또한 pH 7.0~7.2이다. 그러고 우리의 주면 환경은 산성화되었다. The human body needs 3.8 liters of water a day. 1.9L of it is supplied in water form and the rest is supplied from metabolism and water in food. However, there is more acid in the food that humans eat than alkaline. The tap water we drink is also at pH 7.0-7.2. Then our environment was acidified.
생리학적 pH수치는 사람이 무얼 먹고 어떻게 행동하며 무엇을 느끼는가에 따라 달라진다. 혈액의 pH 수치는 7.36~7.42 정도이다. 그리고, 인체 세포 내부의 pH수치는 7.4이다. 이 상태에서 건강이 촉진되는 이유는 세포 내부에서 기능하는 효소에게 최적의 능률을 발휘기 때문이다. Physiological pH values depend on what a person eats, how he behaves, and what he or she feels. Blood pH levels range from 7.36 to 7.42. And pH value inside a human cell is 7.4. Health is promoted in this state because it is optimal for enzymes that function inside the cell.
알카리성 식품은 많은 적혈구 세포에 충분한 산소를 공급해준다. 이런 식품을 섭취하면 몸이 가뿐해지는 느낌을 가지며, 마음이 들뜨고, 기운이 나며, 자신감이 생기고, 즐겁고, 행복하고, 만족감을 느끼게 된다. Alkaline foods provide enough oxygen for many red blood cells. Eating these foods can make you feel relaxed, uplifted, energized, confident, joyful, happy, and satisfied.
알카리수의 채내 생리 보호 작용 실험을 통해 알카리수가 대상물질을 물보다 증가된 수소 결망을 통하여 안정화시킬 수 있다. 따라서 이것은 산화적 손상을 야기시키는 자유라칼디(Free Radical)에 대한 알카리수가 물보다 큰 반응성를 보일 수 있는 기본 원인으로 볼 수 있다. In-situ physiological protective action of alkaline water allows alkaline water to stabilize the target material through increased hydrogen resolution than water. Therefore, this can be regarded as the basic cause of alkalinity to free radicals that cause oxidative damage than water.
미네랄(無機鹽類, Mineral)은 생물체를 구성하는 원소 중에서 탄소, 수소, 산소 등의 3원소를 제외한 생물체의 무기적 구성요소이다. 또한, 미네랄은 광물질(鑛物質)이라고도 한다. 단백질·지방·탄수화물·비타민과 함께 5대 영양소의 하나이다. 인체 내에서 여러 가지 생리적 활동에 참여하고 있다. 무기염류 중 인체를 구성하는 원소인 칼슘(Ca), 인(P), 칼륨(K), 나트륨(Na), 염소(Cl), 마그네슘(Mg), 철(Fe), 아이오딘(I), 구리(Cu), 아연(Zn), 코발트(Co), 망가니즈(Mn) 등의 원소는 미량으로도 충분하지만 없어서는 안 되는 것들이다. 따라서 이들 무기염류의 섭취가 부족하면 각종 결핍증을 유발한다. 예를 들어, 칼슘은 뼈의 구성성분이며 근육 운동에 관여하기 때문에 칼슘이 부족하면 구루병이 생기거나 근육운동의 부조화가 일어난다. 또 나트륨은 우리 몸의 삼투압이나 pH를 조절하는 성분으로 부족하면 신경에 이상이 생기고, 망가니즈는 효소의 기능을 도와주는 역할을 하는 무기염류로서 부족할 경우 불임을 초래하기도 한다. 헤모글로빈의 성분인 철이나 적혈구를 만드는 데에 사용되는 구리, 코발트 등의 섭취가 부족하면 빈혈이 생길 수 있다. Minerals are inorganic components of living organisms, except for three elements such as carbon, hydrogen, and oxygen. Minerals are also called minerals. Along with protein, fat, carbohydrates and vitamins, it is one of the five major nutrients. It participates in various physiological activities in the human body. Among inorganic salts, calcium (Ca), phosphorus (P), potassium (K), sodium (Na), chlorine (Cl), magnesium (Mg), iron (Fe), iodine (I), Elements such as copper (Cu), zinc (Zn), cobalt (Co), and manganese (Mn) are sufficient in small amounts but are indispensable. Therefore, insufficient intake of these inorganic salts cause various deficiencies. For example, calcium is a constituent of bone and is involved in muscle movement, so lack of calcium can cause rickets or incongruence in muscle movement. In addition, sodium is a component that controls the osmotic pressure or pH of the body when the lack of nerves, and manganese is an inorganic salt that serves to help the function of the enzyme, when lacking it may cause infertility. Anemia can result from a lack of intake of hemoglobin, iron, copper, and cobalt, which are used to make red blood cells.
본 발명은 산화규소(SiO2) 33~39 중량%, 산화알루미나(Al2O3) 18~22 중량％, 산화칼슘(CaO) 22~26 중량%, 산화마그네슘(MgO) 11~16 중량%, 산화철(Fe2O3) 1~2 중량%, 산화나트륨(Na2O) 1 중량% 이하, 산화칼륨 (K2O) 1 중량% 이하, 산화티타늄(TiO2) 1 중량% 이하, 산화지르콘(ZrO2) 1 중량% 이하로 구성된 다공성 세라믹조성물에 관한 것이다.The present invention is 33 to 39% by weight of silicon oxide (SiO 2 ), 18 to 22% by weight of alumina oxide (Al 2 O 3 ), 22 to 26% by weight calcium oxide (CaO), 11 to 16% by weight magnesium oxide (MgO) , Iron oxide (Fe 2 O 3 ) 1 to 2% by weight, sodium oxide (Na 2 O) 1% by weight or less, potassium oxide (K 2 O) 1% by weight or less, titanium oxide (TiO 2 ) 1% by weight or less, oxidation Zircon (ZrO 2 ) relates to a porous ceramic composition composed of 1% by weight or less.
900~1,100℃
900 ~ 1,100 ℃
[표 1]의 특정 함량에 의한 구성으로 각 성분의 상승효과로 pH를 용출시키고, 우수한 미네랄 용출 효과를 얻을 수 있다. 또한, 상기 비율 외 가소성 첨가제와 탄소(炭素, Carbon)분말이나, 광물(鑛物, Mineral)을 파쇄하여 만든 광물 세립질(細粒質)입자를 사용할 수 있으며, 이들 첨가제로 세라믹 표면의 다공성 증가로 흡착하는 효율이 증가 되어 정수능력이 향상된다. 상기 광물입자는 단면적이 넓어 흡착력이 높아지므로 세균이나 바이러스 또는 각종 이물질을 빠른 속도로 흡착시킨다. The composition by the specific content of [Table 1] to elute the pH by the synergistic effect of each component, it can be obtained excellent mineral elution effect. In addition, it is possible to use plastic additives, carbon powder, or mineral fine particles made by crushing minerals, in addition to the above-mentioned ratios. The efficiency of adsorption is increased, and the water purification ability is improved. Since the mineral particles have a wide cross-sectional area, the adsorption force is increased, so that bacteria, viruses or various foreign substances can be rapidly adsorbed.
소성(燒成, firing) 가공이란 조합(調合)된 원료를 가열하여 경화성물질(硬化性物質)을 만드는 조작을 의미한다. 본 발명에 주요재료들의 서로 다른 녹는점과 끓는점을 이용하여 소성온도를 결정한다. Firing processing refers to an operation of heating a combined raw material to form a curable material. The firing temperature is determined by using different melting and boiling points of the main materials of the present invention.
본 발명은 무기 미네랄을 세라믹 볼로 만들어서 정수기 필터에 장착하여 물속에 일정한 미네랄을 용출시켜서 pH 8.0 이상을 유지하며 인체에 부족한 미네랄을 물로서 섭취하는 방법이다. 상술한 방법으로 제조한 "pH를 상승시키고 미네랄을 용출하는 세라믹"은 물을 알칼리화시키고 물 분자의 산화 / 환원 능력을 증가시고 미네랄을 물속으로 용출시킴으로써, 동식물의 주요성분인 물 분자의 침투력을 향상시키는 효과를 나타낸다. The present invention is a method of incorporating inorganic minerals into ceramic balls, eluting certain minerals in water to maintain a pH of 8.0 or more, and ingesting minerals deficient in the human body as water. The "ceramic for raising pH and eluting minerals" prepared by the above-described method improves the penetration of water molecules, which are the main components of plants and animals, by alkalizing water, increasing the oxidation / reducing ability of water molecules and eluting minerals into water. It makes an effect to make.
본 발명에 주요재료들의 서로 다른 녹는점과 끓는 점을 이용하여 소성온도를 결정한다. The firing temperature is determined by using different melting and boiling points of the main materials in the present invention.
[표 2]는 pH를 상승시키고 미네랄을 용출하는 세라믹에 사용되고 있는 주요재료는 서로 다른 녹는점과 끓는점을 가짐을 나타낸 것이다. [Table 2] shows that the main materials used in ceramics that raise pH and elute minerals have different melting and boiling points.
본 발명은 900~1,100℃에서 소성을 실시하는 것이다. 소성온도가 낮으면 세라믹은 물속에서 빨리 분해되고 불순물이 용출될 수 있다. 일정한 소결온도를 유지시키지 못한 세라믹의 조직체는 설탕이나 소금처럼 빨리 분해가 된다. 다시 말해,[표2]의 물질을 손상시키지 않는 온도에서 최대의 물질 간 구조결합(뮬라이트 형성 직전)을 가지게 하는 것이다. 이렇게 함으로서 세라믹 볼이 물과의 반응시간을 1년 이상 갖도록 하는 것이다. This invention performs baking at 900-1,100 degreeC. If the firing temperature is low, the ceramic may decompose quickly in water and impurities may elute. Ceramic structures that do not maintain a constant sintering temperature decompose as quickly as sugar or salt. In other words, at the temperature that does not damage the material of [Table 2] to have the largest structural bond between the materials (just before the mullite formation). This allows the ceramic balls to have a reaction time with water for at least one year.
상기 성분들의 입자의 크기는 모두 350 메쉬(mesh) 이상의 고운 정제입자이며 분말형태로 혼합 제조한다. The particle size of the components are all 350 mesh (fine mesh) or more fine purified particles are mixed and prepared in powder form.
본 발명의 세라믹의 제조방법은 상기 9가지 화합물을 주성분으로 하고, 여기에 가소성 첨가제를 혼합하여 혼합물을 제조하고, 혼합물을 성형한 후 건조 소성 및 가공하는 단계를 포함하여, pH를 상승시키고 미네랄을 용출하는 다공질 세라믹 을 제조할 수 있다. The method for producing a ceramic of the present invention comprises the above nine compounds as a main component, and a plastic additive is mixed therein to prepare a mixture, and the mixture is molded, followed by dry firing and processing, to raise the pH and minerals. The eluting porous ceramic can be produced.
이때, 서로 다른 물질이 잘 혼합되려면 오랜 시간의 교반이 필요하므로, 상기 혼합물의 제조는 볼밀(Ball Mill)에서 습식으로 48시간 이상 혼합을 수행하는 것이 바람직하다. At this time, since the mixing of different materials requires a long time of stirring, the preparation of the mixture is preferably carried out by mixing in a ball mill (wet ball mill) for more than 48 hours.
시험은 pH 통수(通水)시험, 미네랄 용출시험, 먹는물수질공정시험(환경부고시제2009-233호)을 ‘한국환경수도연구소’에서 실시하였다.
[도 1],[도 2]pH 통수(通水)시험
시험방법은 통수(通水)법으로 실시하였다. 통수조건은 1일 100L씩 수도압력으로 통수 하였으며, 분석절차는 100L 통수 직후 멸균팩 4L에 통과수를 채수하여 pH를 측정하였다.
세라믹 볼 400g을 정수기 필터에 장착(裝着)한 후 pH 7.2 원수(수돗물)를 수압( 1kgf/㎠)으로 하루 100L의 물을 통수하여 pH를 측정하였다. 시험 환경은 온도 17~25℃, 상대습도; 18~56％ R.H.였다. 시험기간은 2010년 1월 20일부터 4월 13일이었다.
통수시험 결과 연구에서 사용된 세라믹 400g은 원수 pH 7.2의 수돗물을 하루 100L, 51일 동안 5,100L의 물을 pH 8.0 이상 유지시켜주었다.
[도 3]미네랄 용출시험
미네랄 용출 시험은 ‘정수기의 기준규격 및 검사기관지정고시’로 한국수도환경연구소에서 2010년 5월 13일부터 2010년 5월 24일까지 실시하였다. 시험방법은 환경부고시 제2009-233호 먹는물수질공정시험기준으로 실시하였으며 시험환경은 온도 24~25℃, 상대습도 52~62% R.N.였다.
시험 조건은 세라믹 볼 1.2kg을 증류수를 이용 pH 7로 조정한 시험 수 2L에 침전시켜 1시간 용출 후 용출 액을 버리고 1회 반복한 후 3번째 용출 액을 시험수로 분석하였다.
[도 4][도 5]먹는물수질공정시험
먹는물수질공정시험은 ‘정수기의 기준규격 및 검사기관지정고시’로 한국수도환경연구소에서 2009년 12월 22일부터 2010년 1월 11일까지 실시하였다. 시험방법은 환경부고시 제2009-233호 먹는물수질공정시험기준으로 실시하였으며 시험환경은 온도 18~24℃, 상대습도 18~33% R.N.였다.
시험결과 환경부고시 제2008-45호, 정수기의 기준 및 검사기관지정고시에 적합판정을 받았다.
본 발명은 무기 미네랄을 세라믹 볼로 제조하고 이를 정제 및 정수기 필터에 장착하여 물속에 일정한 pH를 용출시켜서 의학, 농업, 공업, 축산업, 수산업, 환경 등 다양한 분야에서 사용할 수 있게 하는 것이다.The test was conducted by the Korea Institute for Environmental Waterworks, pH pass-through test, mineral dissolution test, and drinking water quality process test (No. 2009-233).
Fig. 1, Fig. 2 pH water flow test
The test method was carried out by the water passage method. The water flow conditions were passed through the water pressure 100L per day, and the analytical procedure was measured by taking the water passed through the sterilization pack 4L immediately after the 100L water flow.
400 g of ceramic balls were mounted on a water purifier filter, and pH 7.2 was measured by passing raw water (tap water) of pH 7.2 through 100 L of water at a pressure of 1 kgf /
Passage test results The ceramic 400g used in this study maintained 100L of tap water with raw water pH 7.2 and 5,100L of water over pH 8.0 for 51 days.
[Figure 3] Mineral Dissolution Test
The mineral dissolution test was conducted from May 13, 2010 to May 24, 2010 at the Korea Water Environment Institute as a 'Standard Specification for Water Purifier and Notification of Designation of Inspection Institutions'. The test method was conducted based on the 2009-233 Drinking Water Quality Process Test Standard. The test environment was 24 ~ 25 ℃ and relative humidity was 52 ~ 62% RN.
In the test conditions, 1.2 kg of ceramic balls were precipitated in 2 L of test water adjusted to pH 7 using distilled water, and the eluate was discarded after 1 hour of elution. The third eluate was analyzed with test water.
[Fig. 4] [Fig. 5] Eat water quality process test
The drinking water quality process test was conducted from December 22, 2009 to January 11, 2010 at the Korea Water Environment Institute as a 'standard for water purifiers and notification of inspection institution designation'. The test method was based on the 2009-233 Drinking Water Quality Process Test Standard. The test environment was 18 ~ 24 ℃ and 18 ~ 33% RH.
As a result of the test, the Ministry of Environment Notification No. 2008-45, the water purifier's standard and the inspection agency's designation decision were approved.
The present invention is to prepare an inorganic mineral in a ceramic ball and to equip it with a filter and a water purifier filter to elute a constant pH in the water to be used in various fields such as medicine, agriculture, industry, animal husbandry, fisheries, environment.
본 발명은 pH를 용출하는 세라믹의 제조방법의 일례를 설명하면 다음과 같다. The present invention will be described below as an example of a method for producing a ceramic eluting pH.
본 발명의 사용되는 재료는 각각 350mesh 이하의 산화규소(SiO2) 33~39 중량%, 산화알루미나(Al2O3) 18~22 중량％, 산화칼슘(CaO) 22~26 중량%, 산화마그네슘(MgO) 11~16 중량%, 산화철(Fe2O3) 1~2 중량%, 산화나트륨(Na2O) 1 중량% 이하, 산화칼륨 (K2O) 1 중량% 이하, 산화티타늄(TiO2) 1 중량% 이하, 산화지르콘(ZrO2) 1 중량% 이하로 구성된 다공성 세라믹조성물로서 탄소분말 5 중량% 및 광물입자 5 중량%는 필요에 따라서 첨가할 수도 있다.Materials used in the present invention are 33 to 39% by weight of silicon oxide (SiO 2 ) of 350mesh or less, 18 to 22% by weight of alumina oxide (Al 2 O 3 ), 22 to 26% by weight of calcium oxide (CaO), and magnesium oxide (MgO) 11-16 wt%, iron oxide (Fe 2 O 3 ) 1-2 wt%, sodium oxide (Na 2 O) 1 wt% or less, potassium oxide (K 2 O) 1 wt% or less, titanium oxide (TiO 2 ) A porous ceramic composition composed of 1% by weight or less and 1% by weight of zircon oxide (ZrO 2 ), 5% by weight of carbon powder and 5% by weight of mineral particles may be added as necessary.
제조방법으로는, 첫 번째, 혼합 위하여 볼밀(Ball Mill) 에 재료를 적당량 투입하여 48시간 이상 습식으로 혼합한다. 혼합이 충분해야만 성형이 용이하고 소성 후에 pH용출이 일정하게 된다. 혼합을 마친 원료(Slip상태)는 압력여과기(壓力濾過器, Filter Press)를 사용하여 케이크(Cake)형태로 만들어 건조 후 분쇄(粉碎, Grinding)하여 분말상태로 만든다. As a manufacturing method, first, an appropriate amount of material is added to a ball mill for mixing and wet mixing for at least 48 hours. Sufficient mixing is easy to mold and pH elution is constant after firing. The finished raw material (Slip state) is made into a cake form using a pressure filter (Filter Press), dried and ground to a powder state.
두 번째, 성형단계로 분말성형기(Palletizer)를 이용하여 볼을 성형한다. 볼의 크기는 1~8mm가 적당하다. 일정한 크기의 볼 보다는 다소 크기의 차이가 있것이 정수용 필터(통수)에 장착 시 용이하며 물과의 반응시간을 줄일 수 있어서 pH용출이 일정하게 된다. 세라믹은 볼 형태 이외에 타원, 다각형까지 포함할 수 있다. Second, in the molding step, the ball is molded by using a palletizer. The size of the ball is suitable 1 ~ 8mm. The difference in size rather than the size of a certain size ball is easy to install on the water filter (water) and the pH elution is constant because the reaction time with water can be reduced. In addition to the ball shape, the ceramic may include ellipses and polygons.
마지막으로, 성형을 마친 볼은 충분한 건조를 한 후 내화그릇에 담아서 소성한다. 소성온도는 700~1,100℃가 적당하다. 소성온도가 700℃ 이하이면 물속에서 세라믹은 다른 이물질을 용출할 수 있다. 또한 소성온도가 1,100℃ 이상이면 pH는 용출되지 않는다.
Finally, after the molding ball is sufficiently dried, it is put in a fireproof bowl and fired. The firing temperature is suitable to 700 ~ 1,100 ℃. If the firing temperature is 700 ° C. or lower, the ceramic may elute other foreign substances in water. If the firing temperature is 1,100 ° C or higher, the pH does not elute.
이상과 같이, 본 발명의 pH를 상승시키고 미네랄을 용출하는 세라믹은 물을 알칼리화 시키고 물 분자의 산화 / 환원 능력을 증가시고 미네랄을 물속으로 용출시킴으로서 동식물의 주요성분인 물 분자의 침투력을 향상시키는 특성을 나타낸다.As described above, the ceramics which increase the pH of the present invention and elute the minerals alkalinize the water, increase the oxidation / reduction ability of the water molecules, and elute the minerals into the water to improve the permeability of water molecules, which are the main components of the flora and fauna. Indicates.
Claims (4)
33 to 39% by weight of silicon oxide (SiO 2 ), 18 to 22% by weight of alumina oxide (Al 2 O 3 ), 22 to 26% by weight of calcium oxide (CaO), 11 to 16% by weight of magnesium oxide (MgO), iron oxide ( Fe 2 O 3 ) 1 to 2% by weight, sodium oxide (Na 2 O) 1% by weight or less, potassium oxide (K 2 O) 1% by weight or less, titanium oxide (TiO 2 ) 1% by weight or less, zircon oxide (ZrO 2 ) Porous ceramic composition, characterized in that composed of 1% by weight or less.
상기 다공성 세라믹조성물은 가소성 첨가제 5~10 중량% 및 탄소(유기물)분말입자 5~10 중량%를 더 첨가하여 구성되는 것을 특징으로 하는 다공성 세라믹조성물.
The method of claim 1,
The porous ceramic composition is a porous ceramic composition, characterized in that by adding 5 to 10% by weight of the plastic additive and 5 to 10% by weight of carbon (organic) powder particles.
Ceramics, characterized in that produced by firing the porous ceramic composition of claim 1 or 2.
상기 세라믹은 900~1,100 ℃의 소성 온도에서 소성하여 크기 1~10mm의 볼 형태로 제조되는 것을 특징으로 하는 세라믹. The method of claim 3,
The ceramic is ceramic, characterized in that the firing at a firing temperature of 900 ~ 1,100 ℃ produced in the form of a ball of size 1 ~ 10mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020100107993A KR101198502B1 (en) | 2010-11-02 | 2010-11-02 | Ceramic increasing Hydrogen ion concentration and releasing mineral |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020100107993A KR101198502B1 (en) | 2010-11-02 | 2010-11-02 | Ceramic increasing Hydrogen ion concentration and releasing mineral |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20120047330A KR20120047330A (en) | 2012-05-11 |
| KR101198502B1 true KR101198502B1 (en) | 2012-11-06 |
Family
ID=46266083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020100107993A KR101198502B1 (en) | 2010-11-02 | 2010-11-02 | Ceramic increasing Hydrogen ion concentration and releasing mineral |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR101198502B1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210026715A (en) | 2019-09-02 | 2021-03-10 | (주)바이오세라 | Ceramic balls for stable pH 8.5 drinking water production and manufacturing method thereof, and filer adapted to system comprising the same |
| KR20220069628A (en) | 2020-11-20 | 2022-05-27 | (주)바이오세라 | Ceramic ball having multi-compression strength for water purifier and water filter comprising this |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101592633B1 (en) * | 2013-08-12 | 2016-02-11 | 나노폴리(주) | Water purifier |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100808904B1 (en) | 2006-08-24 | 2008-03-03 | 손호익 | A ceramic ball having porosity |
| KR100927004B1 (en) | 2007-07-25 | 2009-11-17 | 손호익 | The preparing method of polygonal filter for cleaing and refining water |
-
2010
- 2010-11-02 KR KR1020100107993A patent/KR101198502B1/en active IP Right Grant
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100808904B1 (en) | 2006-08-24 | 2008-03-03 | 손호익 | A ceramic ball having porosity |
| KR100927004B1 (en) | 2007-07-25 | 2009-11-17 | 손호익 | The preparing method of polygonal filter for cleaing and refining water |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210026715A (en) | 2019-09-02 | 2021-03-10 | (주)바이오세라 | Ceramic balls for stable pH 8.5 drinking water production and manufacturing method thereof, and filer adapted to system comprising the same |
| KR20220069628A (en) | 2020-11-20 | 2022-05-27 | (주)바이오세라 | Ceramic ball having multi-compression strength for water purifier and water filter comprising this |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20120047330A (en) | 2012-05-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR100643047B1 (en) | Method of Producting of The Biovital-water using material Radiating Far Infared and Mineral | |
| CN104072084B (en) | Nano ore powder multiple-effect flexible ceramic vessel | |
| CN1810145A (en) | Production process of natural mineral feed additive | |
| KR100959667B1 (en) | Purified alkari water manufacturing method and the apparatus using loess ball having firing shell powder | |
| KR101198502B1 (en) | Ceramic increasing Hydrogen ion concentration and releasing mineral | |
| AU2017203723A1 (en) | Meeting management system and process | |
| US20210289790A1 (en) | Bioactive material | |
| CN106927854A (en) | A kind of tourmaline ceramic ball for purifying water and preparation method thereof | |
| KR20060101408A (en) | A ceramic ball for a rise in potential for hydrogen & occurrence of mineral | |
| KR101893639B1 (en) | Loessal water including mineral elements | |
| KR101403811B1 (en) | Method for preparing composition of supplemental feed for ruminant | |
| Yücel et al. | Synthesis and characterization of whitlockite from sea urchin skeleton and investigation of antibacterial activity | |
| CN110078192A (en) | A kind of mineral water and preparation method thereof | |
| EP3096634A1 (en) | Use of clay mineral as a food additive and/or as supplementary food for aquatic organisms | |
| KR100993571B1 (en) | Process for preparation of mineral-containing water and mineral-containing water prepared by the same | |
| CN102898120A (en) | Water filter material and preparation process thereof as well as corresponding water filter device | |
| KR20210030120A (en) | Antimicrobial or antifungal composition and method of manufacturing the same | |
| KR20150073326A (en) | Loessal water including mineral elements | |
| KR20030065918A (en) | Additives for waste-water treatment | |
| KR20060086245A (en) | Water treating material and method for production of alkaline reducing water using the same | |
| KR20100029803A (en) | The ceramic-ball, dividing water cluster smaller | |
| CN102126776A (en) | Method for removing fluorions from mineral water by using food grade alkaline magnesium carbonate | |
| KR101851994B1 (en) | Live mineral block and method of preparing the same | |
| CN102232761A (en) | Tourmaline, medical stone and bamboo charcoal health care cup | |
| KR20140093450A (en) | Feed Additive using Aleurolite and Functional Feed including the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20150909 Year of fee payment: 4 |
|
| FPAY | Annual fee payment |
Payment date: 20170925 Year of fee payment: 6 |
|
| FPAY | Annual fee payment |
Payment date: 20181028 Year of fee payment: 7 |
|
| FPAY | Annual fee payment |
Payment date: 20190926 Year of fee payment: 8 |