KR101067539B1 - 카르보닐 화합물의 수화를 위한 촉매 및 방법 - Google Patents
카르보닐 화합물의 수화를 위한 촉매 및 방법 Download PDFInfo
- Publication number
- KR101067539B1 KR101067539B1 KR1020057018011A KR20057018011A KR101067539B1 KR 101067539 B1 KR101067539 B1 KR 101067539B1 KR 1020057018011 A KR1020057018011 A KR 1020057018011A KR 20057018011 A KR20057018011 A KR 20057018011A KR 101067539 B1 KR101067539 B1 KR 101067539B1
- Authority
- KR
- South Korea
- Prior art keywords
- copper
- catalyst
- acid
- oxide
- weight
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/94—Use of additives, e.g. for stabilisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
촉매 | 측면 분쇄 강도 (산화 상태)/N |
측면 분쇄 강도 (환원 상태)/N |
측면 분쇄 강도 (제거 후)/N |
측면 분쇄 강도 (환원 및 물에 현탁된 상태)/N |
촉매 1 | 111 | 62 | 51 | 41 |
비교 촉매 | 70 | 45 | 20 | 26 |
촉매 | 반응온도/℃ | 디메틸 아디페이트 전환율/% | 방출물 중 헥산디올 함량/% |
촉매 1 | 220 240 |
98 99 |
57 62 |
비교 촉매 | 220 240 |
92 96 |
48 58 |
Claims (9)
- (ⅰ) 산화구리, 산화알루미늄, 및 란탄 산화물을 포함하는 산화 물질(oxidic material)을 제조하고,(ⅱ) 산화 물질에 분말화 금속성 구리, 구리 박편, 분말화 시멘트, 흑연 또는 이들의 혼합물을 첨가하고,(ⅲ) (ⅱ)로부터 생성된 혼합물을 성형품으로 성형하는 방법으로 제조될 수 있는 성형품과 유기 화합물을 수소의 존재 하에 접촉시키는,하나 이상의 카르보닐기를 갖는 유기 화합물의 수소화 방법.
- 제1항에 있어서, 산화 물질이 소성 후 산화 물질의 전체 중량을 기준으로(a) 50 중량%≤x≤80 중량% 범위의 함량의 산화구리,(b) 15 중량%≤y≤35 중량% 범위의 함량의 산화알루미늄,(c) 2 중량%≤z≤20 중량% 범위의 함량의 란탄 산화물을 포함(여기서, 80≤x+y+z≤100이며, 상기 의미에서 시멘트는 산화 물질에 포함되지 않음)하는 것인 방법.
- 제1항 또는 제2항에 있어서, 분말화 금속성 구리, 구리 박편, 분말화 시멘트, 또는 흑연 또는 이들의 혼합물이 산화 물질의 전체 중량 기준으로 1 내지 40 중량% 범위의 함량으로 첨가된 방법.
- 제1항 또는 제2항에 있어서, 흑연을 산화 물질의 전체 중량 기준으로 0.5 내지 5 중량% 범위의 함량으로 산화 물질 또는 (ⅱ)로부터 생성된 혼합물에 첨가하는 방법.
- 제1항 또는 제2항에 있어서, 유기 화합물이 카르복실산, 카르복실산 에스테르, 카르복실산 무수물 또는 락톤인 방법.
- 제5항에 있어서, 유기 화합물이 아디프산 또는 아디프산 에스테르인 방법.
- 소성 후 산화 물질의 전체 중량을 기준으로(a) 50 중량%≤x≤80 중량% 범위의 함량의 산화구리,(b) 15 중량%≤y≤35 중량% 범위의 함량의 산화알루미늄,(c) 2 중량%≤z≤20 중량% 범위의 함량의 란탄 산화물을 포함(여기서, 80≤x+y+z≤100임)하는 산화 물질,산화 물질의 전체 중량 기준으로 1 내지 40 중량% 범위의 함량의 금속성 구리 분말, 구리 박편 또는 시멘트 분말 또는 흑연 또는 이들의 혼합물, 및산화 물질의 전체 중량 기준으로 0.5 내지 5 중량% 범위의 함량의 흑연을 포함하며,산화 물질, 금속성 구리 분말 또는 시멘트 분말 또는 이들의 혼합물 및 흑연의 함량의 전체가 성형품의 95 중량% 이상을 차지하는 성형품.
- 삭제
- 삭제
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10313702.5 | 2003-03-27 | ||
DE2003113702 DE10313702A1 (de) | 2003-03-27 | 2003-03-27 | Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20050116830A KR20050116830A (ko) | 2005-12-13 |
KR101067539B1 true KR101067539B1 (ko) | 2011-09-27 |
Family
ID=32946217
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020057018011A KR101067539B1 (ko) | 2003-03-27 | 2004-03-20 | 카르보닐 화합물의 수화를 위한 촉매 및 방법 |
Country Status (12)
Country | Link |
---|---|
US (3) | US7510591B2 (ko) |
EP (1) | EP1613576B2 (ko) |
JP (1) | JP4664902B2 (ko) |
KR (1) | KR101067539B1 (ko) |
CN (1) | CN100345808C (ko) |
AT (1) | ATE469113T1 (ko) |
BR (1) | BRPI0408384B1 (ko) |
DE (2) | DE10313702A1 (ko) |
ES (1) | ES2344349T5 (ko) |
MX (1) | MXPA05009819A (ko) |
MY (1) | MY150679A (ko) |
WO (1) | WO2004085356A1 (ko) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004033556A1 (de) * | 2004-07-09 | 2006-02-16 | Basf Ag | Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen |
DE102005032726A1 (de) * | 2005-07-13 | 2007-01-18 | Basf Ag | Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen |
DE102005049135A1 (de) * | 2005-10-14 | 2007-04-19 | Basf Ag | Verfahren zur Hydrierung von Carbonylverbindungen |
WO2008064991A1 (de) * | 2006-11-27 | 2008-06-05 | Basf Se | Verfahren zur herstellung von 3-alkoxypropan-1-ole |
US7964114B2 (en) * | 2007-12-17 | 2011-06-21 | Sud-Chemie Inc. | Iron-based water gas shift catalyst |
EE200800009A (et) * | 2008-02-21 | 2009-10-15 | Nordbiochem OÜ | Katalsaator ja meetod hdrokskarbokslhapete estrite kataltiliseks redutseerimiseks glkoolideks |
DE102008026210B4 (de) | 2008-05-30 | 2012-06-28 | Süd-Chemie AG | Nanokristallines Kupferoxid und Verfahren zu dessen Herstellung |
RU2522761C2 (ru) | 2008-11-05 | 2014-07-20 | Басф Се | Способ получения n, n-замещенных 3-аминопропан-1-олов |
JP2012517333A (ja) | 2009-02-09 | 2012-08-02 | ビーエーエスエフ ソシエタス・ヨーロピア | モノリス触媒の触媒活性を改善する方法 |
US20110313187A1 (en) | 2009-02-09 | 2011-12-22 | Christof Wilhelm Wigbers | Method for improving the catalytic activity of monolithic catalysts |
US20110313186A1 (en) | 2009-02-09 | 2011-12-22 | Basf Se | Hydrogenation catalysts, the production and the use thereof |
CA2755696A1 (en) | 2009-04-07 | 2010-10-14 | Basf Se | Method for producing 1,6-hexanediol |
CA2755293A1 (en) | 2009-04-08 | 2010-10-14 | Basf Se | Method for producing 1,6-hexanediol by hydrogenation of oligo- and polyesters |
CN102438972B (zh) * | 2009-05-20 | 2015-09-09 | 巴斯夫欧洲公司 | 通过在含铜非均相催化剂上氢化甘油三脂肪酸酯而制备脂肪醇的方法 |
TWI490034B (zh) | 2009-11-17 | 2015-07-01 | Basf Se | 製備具有增強氫化活性之經承載氫化觸媒之方法 |
US8637668B2 (en) | 2010-06-15 | 2014-01-28 | Basf Se | Process for preparing a cyclic tertiary methylamine |
RU2571082C2 (ru) | 2010-09-08 | 2015-12-20 | Басф Се | СПОСОБ ПОЛУЧЕНИЯ ε-КАПРОЛАКТОНА И 1,6-ГЕКСАНДИОЛА |
US8933223B2 (en) | 2010-10-14 | 2015-01-13 | Basf Se | Process for preparing a cyclic tertiary amine |
WO2013056463A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
WO2013056459A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
WO2013056461A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
WO2013056400A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
IN2014DN05943A (ko) | 2012-01-11 | 2015-06-26 | Basf Se | |
US8884015B2 (en) | 2012-06-01 | 2014-11-11 | Basf Se | Process for the preparation of a mono-N-alkypiperazine |
JP6242878B2 (ja) | 2012-06-01 | 2017-12-06 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノ−n−アルキル−ピペラジンの製造方法 |
US8981093B2 (en) | 2012-06-06 | 2015-03-17 | Basf Se | Process for preparing piperazine |
DE102012012510B4 (de) | 2012-06-22 | 2018-12-06 | Clariant International Ltd. | Graphithaltiger Katalysatorformkörper, dessen Herstellverfahren sowie Verwendung |
EP3080063A1 (de) | 2013-12-13 | 2016-10-19 | Basf Se | Verfahren zur herstellung von 1,6-hexandiol |
TW201536734A (zh) * | 2014-03-12 | 2015-10-01 | Basf Se | 甲酸鹽的分解 |
DE102014004391A1 (de) * | 2014-03-26 | 2015-10-15 | Clariant International Ltd. | Verfahren zur Herstellung von Katalysatoren mit erhöhter Festigkeit und verringertem Volumenschwund |
US10343154B2 (en) * | 2014-11-25 | 2019-07-09 | Graver Technologies Llc | High capacity adsorbent for fluoride ion and oxyanions of phosphorous and arsenic and method for making the same |
US11583846B2 (en) | 2014-11-25 | 2023-02-21 | Graver Technologies Llc | High capacity adsorbent for oxyanions and cations and method for making the same |
BR112017020321B1 (pt) * | 2015-03-26 | 2021-01-26 | Basf Corporation | catalisador, método para fazer um catalisador, e, processo |
DE102016225172A1 (de) | 2016-12-15 | 2018-06-21 | Clariant International Ltd | Tablettierter Katalysator mit erhöhter Stabilität gegenüber Säureeinwirkung |
DE102016225171A1 (de) | 2016-12-15 | 2018-06-21 | Clariant International Ltd | Tablettierter Katalysator für die Methanolsynthese mit erhöhter mechanischer Stabilität |
EP3625199B1 (de) | 2017-05-16 | 2021-09-22 | Basf Se | Hydroformylierungsverfahren dienend der grosstechnischen herstellung von aldehyden und/oder alkoholen |
DE102019131569A1 (de) | 2019-11-22 | 2021-05-27 | Clariant International Ltd | Chromfreier wasser- und saeurestabiler katalysator fuer hydrierungen |
DE102020106964A1 (de) | 2020-03-13 | 2021-09-16 | Clariant International Ltd | Chromfreier hydrierkatalysator mit erhoehter wasser- und saeurestabilitaet |
KR20240072249A (ko) | 2021-10-07 | 2024-05-23 | 바스프 에스이 | 액체 상에서의 비스(피롤리디노)부탄의 제조 방법 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55145531A (en) * | 1979-04-27 | 1980-11-13 | Basf Ag | Preparation of catalyst and its use for changing acetylene alcohol into hydrogen |
JPH08229399A (ja) * | 1995-01-11 | 1996-09-10 | United Catalyst Inc | 助触媒を含む安定化酸化銅−酸化亜鉛触媒および製造方法 |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE256515C (ko) | 1911-07-04 | 1913-02-14 | ||
GB1296212A (ko) | 1969-03-04 | 1972-11-15 | ||
US4105590A (en) * | 1972-03-25 | 1978-08-08 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Catalysts and the process for their production |
US3870658A (en) * | 1973-03-02 | 1975-03-11 | Corning Glass Works | Copper chromite-alumina catalysts having high-temperature stability |
US4206150A (en) * | 1976-11-04 | 1980-06-03 | Shell Oil Company | Amine process using copper-molybdenum/tungsten catalyst |
US4350613A (en) * | 1980-03-11 | 1982-09-21 | Matsushita Electric Industrial Company, Limited | Catalyst for purifying exhaust gases and method for manufacturing same |
EP0130835B1 (en) * | 1983-07-01 | 1990-05-02 | Hitachi, Ltd. | High temperature stable catalyst, process for preparing same and process for conducting chemical reaction using same |
DE3403491A1 (de) * | 1984-02-02 | 1985-08-14 | Süd-Chemie AG, 8000 München | Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen |
US4666879A (en) * | 1985-09-11 | 1987-05-19 | Harshaw/Filtrol Partnership | Extruded copper chromite-alumina hydrogenation catalyst |
US4762817A (en) * | 1986-11-03 | 1988-08-09 | Union Carbide Corporation | Aldehyde hydrogenation catalyst |
US5008235A (en) * | 1989-12-21 | 1991-04-16 | Union Carbide Chemicals And Plastics Technology Corporation | Catalysts of Cu-Al-third metal for hydrogenation |
DE4037731C2 (de) * | 1990-11-27 | 1996-06-05 | Sued Chemie Ag | Kupferoxid und Chromoxid enthaltender Katalysator und seine Verwendung zur Hydrierung von Fettsäuren und -estern |
DE4244273A1 (de) * | 1992-12-28 | 1994-06-30 | Hoechst Ag | Kupferkatalysator |
DE19505347B4 (de) | 1994-03-02 | 2008-10-02 | Basf Se | Verfahren zur Herstellung von Katalysator-Tabletten mit hoher mechanischer Festigkeit |
US5475159A (en) * | 1994-11-07 | 1995-12-12 | Shell Oil Company | Process for the direct hydrogenation of methyl esters |
MY129140A (en) † | 1994-11-07 | 2007-03-30 | Shell Int Research | Process and a catalyst for the direct hydrogenation of carboxylic esters |
US5990040A (en) * | 1995-01-11 | 1999-11-23 | United Catalysts Inc. | Promoted and stabilized copper oxide and zinc oxide catalyst and preparation |
DE19647349A1 (de) | 1996-11-15 | 1998-05-20 | Basf Ag | Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton |
DE19607955A1 (de) | 1996-03-01 | 1997-09-04 | Basf Ag | Verfahren zur Herstellung von 1,6-Hexandiol mit einer Reinheit über 99 % |
DE19607954A1 (de) | 1996-03-01 | 1997-09-04 | Basf Ag | Verfahren zur Herstellung von 1,6-Hexandiol und Caprolacton |
DE19647348A1 (de) | 1996-11-15 | 1998-05-20 | Basf Ag | Verfahren zur Herstellung von 1,6-Hexandiol mit einer Reinheit über 99 % |
ES2395319T3 (es) * | 1996-03-21 | 2013-02-11 | Basf Catalysts Llc | Preparación de catalizadores de Cu/Al |
DE19809418A1 (de) | 1998-03-05 | 1999-09-09 | Basf Ag | Verfahren zur Hydrierung von Carbonylverbindungen |
DE19859776B4 (de) * | 1998-12-23 | 2008-06-19 | Basf Se | Verfahren zur Herstellung von Aminen |
DE19942895A1 (de) † | 1999-09-08 | 2001-03-15 | Basf Ag | Katalysator und Verfahren zur Hydrierung von Carbonylverbindungen |
DE10061553A1 (de) † | 2000-12-11 | 2002-06-13 | Basf Ag | Poröser Katalysator für die Hydrierung von Maleinsäureanhydrid zu Tetrahydrofuran |
DE10119719A1 (de) * | 2001-04-21 | 2002-10-24 | Basf Ag | Verfahren zur Hydrierung von Carbonylverbindungen |
DE10133054A1 (de) * | 2001-07-07 | 2003-01-16 | Basf Ag | Verfahren zur selektiven Herstellung von Tetrahydrofuran durch Hydrierung von Maleinsäureanhydrid |
US7176159B1 (en) * | 2001-08-15 | 2007-02-13 | Iowa State University Research Foundation, Inc. | Catalyst and sorbent material for the production of hydrogen |
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2003
- 2003-03-27 DE DE2003113702 patent/DE10313702A1/de not_active Withdrawn
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2004
- 2004-02-27 MY MYPI20040679A patent/MY150679A/en unknown
- 2004-03-20 AT AT04722176T patent/ATE469113T1/de active
- 2004-03-20 ES ES04722176T patent/ES2344349T5/es not_active Expired - Lifetime
- 2004-03-20 MX MXPA05009819A patent/MXPA05009819A/es active IP Right Grant
- 2004-03-20 KR KR1020057018011A patent/KR101067539B1/ko active IP Right Grant
- 2004-03-20 DE DE200450011209 patent/DE502004011209D1/de not_active Expired - Lifetime
- 2004-03-20 WO PCT/EP2004/002929 patent/WO2004085356A1/de active Application Filing
- 2004-03-20 EP EP04722176.7A patent/EP1613576B2/de not_active Expired - Lifetime
- 2004-03-20 BR BRPI0408384-9B1A patent/BRPI0408384B1/pt not_active IP Right Cessation
- 2004-03-20 JP JP2006504763A patent/JP4664902B2/ja not_active Expired - Lifetime
- 2004-03-20 US US10/549,140 patent/US7510591B2/en active Active
- 2004-03-20 CN CNB2004800083047A patent/CN100345808C/zh not_active Expired - Lifetime
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2007
- 2007-11-09 US US11/937,537 patent/US7663003B2/en not_active Expired - Lifetime
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2009
- 2009-10-29 US US12/608,125 patent/US7884046B2/en not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS55145531A (en) * | 1979-04-27 | 1980-11-13 | Basf Ag | Preparation of catalyst and its use for changing acetylene alcohol into hydrogen |
JPH08229399A (ja) * | 1995-01-11 | 1996-09-10 | United Catalyst Inc | 助触媒を含む安定化酸化銅−酸化亜鉛触媒および製造方法 |
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JP2006523186A (ja) | 2006-10-12 |
EP1613576B1 (de) | 2010-05-26 |
DE10313702A1 (de) | 2004-10-07 |
US20060178539A1 (en) | 2006-08-10 |
US7663003B2 (en) | 2010-02-16 |
EP1613576B2 (de) | 2013-10-16 |
ES2344349T5 (es) | 2014-01-03 |
CN1764621A (zh) | 2006-04-26 |
ATE469113T1 (de) | 2010-06-15 |
MXPA05009819A (es) | 2005-12-05 |
US7884046B2 (en) | 2011-02-08 |
MY150679A (en) | 2014-02-28 |
ES2344349T3 (es) | 2010-08-25 |
BRPI0408384B1 (pt) | 2014-11-11 |
KR20050116830A (ko) | 2005-12-13 |
DE502004011209D1 (de) | 2010-07-08 |
US7510591B2 (en) | 2009-03-31 |
US20080064882A1 (en) | 2008-03-13 |
CN100345808C (zh) | 2007-10-31 |
WO2004085356A1 (de) | 2004-10-07 |
JP4664902B2 (ja) | 2011-04-06 |
BRPI0408384A (pt) | 2006-03-21 |
US20100056364A1 (en) | 2010-03-04 |
EP1613576A1 (de) | 2006-01-11 |
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