KR101001112B1 - The compositoin of for concrete sealer - Google Patents

The compositoin of for concrete sealer Download PDF

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Publication number
KR101001112B1
KR101001112B1 KR1020090088892A KR20090088892A KR101001112B1 KR 101001112 B1 KR101001112 B1 KR 101001112B1 KR 1020090088892 A KR1020090088892 A KR 1020090088892A KR 20090088892 A KR20090088892 A KR 20090088892A KR 101001112 B1 KR101001112 B1 KR 101001112B1
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weight
concrete
agent
emergency repair
cement
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KR1020090088892A
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Korean (ko)
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김용석
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김용석
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/06Quartz; Sand
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/26Carbonates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/0006Alkali metal or inorganic ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/0006Alkali metal or inorganic ammonium compounds
    • C04B2103/0007K
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/0006Alkali metal or inorganic ammonium compounds
    • C04B2103/0008Li
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0004Compounds chosen for the nature of their cations
    • C04B2103/001Alkaline earth metal or Mg-compounds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/72Repairing or restoring existing buildings or building materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Working Measures On Existing Buildindgs (AREA)

Abstract

PURPOSE: An emergency repair agent for concrete capable of rapidly curing and improving the strength, and a manufacturing method thereof are provided to improve the surface intensity of concrete by using a water reducing agent and a silicate compound. CONSTITUTION: An emergency repair agent for concrete contains 25wt% of alumina cement, 3wt% of sodium carbonate, 4wt% of alunite, 2wt% of water reducing agent, 5wt% of silicate compound, 24wt% of portland cement, 36.9wt% of silica, and 0.1wt% of polyvinyl alcohol. The water reducing agent is selected from the group consisting of a condensated material obtained by condensing naphthalene sulfonic acid using formaldehyde, a condensated material of sulfonated melamine, and lignin sulfonic acid sodium salt.

Description

콘크리트 긴급보수제 및 그 제조방법{The compositoin of for concrete sealer}Concrete emergency repair agent and its manufacturing method {The compositoin of concrete sealer}

본 발명은 콘크리트 포장도로의 파손을 급하게 보수하며 , 콘크리트 구조물 측구, 방음벽, 벽체 및 표면 강도 저하부의 강도증진을 목적으로 개발된 것으로서, 침투성강화, 증진을 위하여 침투 및 미세균열부의 부착 및 방수층까지 형성 할 수 있는 조성물로서, 콘크리트의 표면강도를 증대시키고 마모를 감소시킬 수 있는 콘크리트 긴급보수제 및 그 제조방법에 관한 것이다.The present invention has been developed for the purpose of rapidly repairing the breakage of concrete pavement, and to increase the strength of concrete structure side openings, soundproof walls, walls and surface strength lowering parts, and to form penetration and microcracking parts as well as waterproof layers to enhance and enhance permeability. As a possible composition, the present invention relates to a concrete emergency repair agent and a method of manufacturing the same that can increase the surface strength of concrete and reduce wear.

시멘트 콘크리트도로의 패인부분, 각종공사후 복구 및 부수 등의 방법에 대해서는 복구범위와 파손의 크기, 상태를 고려해서 기존의 도로상태대로 원상복구를 해야 한다.In the case of the concave part of cement concrete road, recovery and crushing after various works, the original road condition should be restored in consideration of the recovery range, size and condition of damage.

여기서 도로포장부의 구조는 밑으로부터 상부로 준비하면 토사 및 흙의 다짐층인 노상 및 노반층, 차단층 및 동상방지층, 보조기층 및 기층, 중간층과 표층등으로 분리 구성되어 있다. Here, the road pavement structure is composed of a roadbed and subgrade layer, a barrier layer and an in-phase prevention layer, an auxiliary base layer and a base layer, an intermediate layer, and a surface layer, which are prepared from the bottom to the top.

그 시공방법도 그 층별로 달리하고 있으며, 일반적으로 중간층 및 표층등이 가열혼합가열포설 아스팔트혼합물(이하 고온아스콘)과 도로포장용 시멘트 콘크리트등의 소재를 사용해서 포장체를 이루고 있다.The construction method is also different for each floor. In general, the intermediate layer and the surface layer are made of pavement using materials such as hot mixed heating asphalt mixture (hereinafter referred to as hot asphalt) and cement for road paving.

일반적으로 콘크리트도로 긴급보수제는 콘크리트의 파손을 방지하는 것을 목적으로 사용한다. 그리고 재료에 따라서 표면에 막을 형성하여 이러한 작용을 증진시키기도 한다. 이러한 보호 및 방수작용과 더불어 보수조성물이 강성을 확보하는 급속한 경화특성을 갖게 되는 경우 표면을 강화하는 작용을 하기도 한다. In general, the emergency repair agent for concrete roads is used to prevent the breakage of concrete. And depending on the material, this may be enhanced by forming a film on the surface. In addition to such protection and waterproofing action, the repair composition also acts to strengthen the surface when it has a rapid curing property to secure rigidity.

일반적으로 시멘트 콘크리트 포장도로, 콘크리트 구조물 측구, 방음벽, 벽체의 표면의 결함을 제거하는 긴급 보수 방법으로 결함부위를 제거하거나, 별도의 덧씌우기 층의 형성을 통해 결함부위가 직접적인 차량하중을 받지 않도록 하는 방법, 그리고 결함부위의 파손 진전을 억제하는 방법이 있을 수 있다.In general, it is an emergency repair method that removes defects on the surface of cement concrete pavement, concrete structures, soundproof walls, and walls, or removes defects or forms a separate overlay layer so that the defects do not receive direct vehicle load. There may be a method, and a method of suppressing the progress of breakage of the defective part.

이러한 긴급 보수 공법 중에 결함부위의 파손 진전을 억제하는 방법은 상대적으로 파손의 정도가 작은 경우에 유용하게 적용될 수 있는 경제적인 방법으로 판단된다. In this emergency repair method, the method of suppressing the progress of the breakage of the defective part is considered an economical method that can be usefully applied when the degree of damage is relatively small.

즉 표면에 나타난 파손이나 결함을 인정하나, 이러한 파손에 추가적인 진전이 없으면 포장면을 주행하는 차량의 주행성에 대한 영향이 작다는 판단에 적용하는 공법이라고 할 수 있다.That is, it recognizes the damage or defect that appeared on the surface, but if there is no further progress on such damage, it can be said to be a method applied to the determination that the influence on the runability of the vehicle traveling on the pavement surface is small.

그러나 종래의 콘크리트 긴급 보수제는 경화시간이 장기화되고, 시공후 화물차 등의 대량 통행과, 장기간 사용시, 재파손되는 경향이 있어, 이러한 문제점을 해결하기 위하여 많은 연구가 있어 왔다.However, the conventional concrete emergency repair agent has a long time to harden, tends to re-break when a long-term use, such as a large amount of traffic, such as a truck after construction, has been a lot of research to solve this problem.

예를 들면, 국내등록특허공보 등록번호 제10-0089579호에는 컷 백 아스팔트 23~30%, 도로포장용 타르 51~62%, 아크릴계변성부타디엔 중합제 11~14%, 염화암모늄 4~5%를 혼합한 긴급도로보수용의 혼화제를, 쇄석골재와 포오틀랜드 시멘트에 혼합하여 제조함을 특징으로 하는 긴급도로보수용재가 공개되어 있고,For example, in Korean Patent Publication No. 10-0089579, 23-30% of cut back asphalt, 51-62% of tar for road paving, 11-14% of acrylic modified butadiene polymerizer, and 4-5% of ammonium chloride are mixed. An emergency road repair material is disclosed, which is prepared by mixing an admixture for road repair with crushed aggregate and Portland cement,

동 공보 10-0831688호에는 주제와 경화제가 이액형으로 분리 제조되는 보수제에 있어서,상기 주제는 폴리에테르 폴리올 수지, 2개의 아민기를 가진 폴리에테르계 아민폴리올 수지, 3개의 아민기를 가진 폴리에테르계 아민폴리올 수지, 아민화합물, 가소제를 포함하여 이루어지고,상기 경화제는 1.3-부탄디올, 이소시아네이트를 포함하여 이루어진 것을 특징으로 하는 아스팔트 또는 콘크리트 포장도로 균열보수제가 기술되어 있으며, 10-0831688 discloses a repair agent in which a main body and a curing agent are separately prepared in a two-part type, wherein the main body is a polyether polyol resin, a polyether amine polyol resin having two amine groups, and a polyether amine having three amine groups. It comprises a polyol resin, an amine compound, a plasticizer, wherein the curing agent is a crack repair agent is described on asphalt or concrete pavement, characterized in that comprises 1.3-butanediol, isocyanate,

동 공보 등록번호 제10-0770289호에는 일반 또는 특수시멘트 20~30중량부, 플라이 애쉬(FLY ASH) 5중량부, 메타 카올린(META-KAOLIN) 10중량부, 고로 슬래그 분말 5중량부, 천연 골재 분쇄물 48중량부, 분산제 0.5~1.0중량부, 소포제 0.1~0.5중량부, 증점제 0.1~0.5중량부, 스테아린산 칼슘 0.2~0.8중량부, 아질산 나트륨 0.6~1.0중량부 및 재분산성 분말수지 8~15중량부의 비율로 조성되는 것을 특징으로 하는 콘크리트 구조물 보호용 도포재가 알려져 있고,Publication No. 10-0770289 discloses 20-30 parts by weight of general or special cement, 5 parts by weight of FLY ASH, 10 parts by weight of META-KAOLIN, 5 parts by weight of blast furnace slag powder, natural aggregate 48 parts by weight of powder, 0.5 to 1.0 part by weight of dispersant, 0.1 to 0.5 part by weight of antifoaming agent, 0.1 to 0.5 part by weight of thickener, 0.2 to 0.8 part by weight of calcium stearate, 0.6 to 1.0 part by weight of sodium nitrite and redispersible powder resin 8 to 15 There is known a coating material for protecting a concrete structure, characterized in that the composition by weight part,

동 공보 등록번호 제10-0632089호에는 가) 에폭시 기본수지 A(당량100∼200 G/EQ) 30∼45중량%, 에폭시 기본수지 B(당량250~350 G/EQ) 5~10중량%, 비반응성 희 석제 25∼37중량%, 유화제 1∼4중량%, 응집제 1~3중량%, 소포제 0.01~0.1중량%, 물 15∼33중량%를 포함하는 수지성분의 제1조성물 100중량부와,나) 아민계 경화제 55~70중량%, 경화촉진제 1~11중량% 및 비반응성 희석제 20~40중량%를 포함하는 경화성분의 제2조성물 15~40중량부와,다) 시멘트 70~85중량%, 알루미나 시멘트 10~20중량% 및 수산화칼슘 1~10중량%를 포함하는 필러성분의 제3조성물 90~150중량부로 구성된 3성분계로 이루어진 것을 특징으로 하는 에폭시를 이용한 콘크리트 표면 보호 보수제 조성물가 기재되어 있으며,Publication No. 10-0632089 discloses: a) 30 to 45% by weight epoxy base resin A (equivalent to 100 to 200 G / EQ), 5 to 10% by weight epoxy base resin B (equivalent to 250 to 350 G / EQ), 100 parts by weight of the first composition of the resin component containing 25 to 37% by weight of the non-reactive diluent, 1 to 4% by weight of the emulsifier, 1 to 3% by weight of the flocculant, 0.01 to 0.1% by weight of the antifoaming agent, and 15 to 33% by weight of water. B) 15 to 40 parts by weight of a second composition of the cured component comprising 55 to 70% by weight of an amine curing agent, 1 to 11% by weight of a curing accelerator, and 20 to 40% by weight of a non-reactive diluent; c) Cement 70 to 85 It is based on a three-component system consisting of 90 to 150 parts by weight of the third composition of the filler component comprising a weight percent, 10 to 20% by weight of alumina cement and 1 to 10% by weight of calcium hydroxide based on the epoxy concrete surface protective repair agent composition It is

동 공보 등록번호 제10-0565268호에는 건축용 콘크리트 구조물의 표면의 공극을 침투하고 코팅하는 표면보호제에 관한 것으로, 보다 상세하게는 알콕시실란기를 가지는 공중합체와 알콕시실란을 함유하는 콘크리트 표면보호제가 기술되어 있고,Korean Patent Publication No. 10-0565268 relates to a surface protecting agent that penetrates and coats pores of a surface of a concrete structure for construction. More specifically, a concrete surface protecting agent containing an alkoxysilane group and an alkoxysilane is described. There is,

동 공보 등록번호 제10-354135호에는 누수를 방지하고 장기간 침수에 의해 열화부식된 콘크리트 표면을 보수보강 보호하는 지하구조물의 내부복합방수보수하는 방법으로서, 이물질을 제거하고, 바탕면에 폴리아미노(1-옥소-1,6-헥산디일)와, 2,2-(1-메틸에틸리덴)비스(4,1-페닐렌옥시메틸렌)와, 메틸페녹시메틸과 물로 혼합된 침투성접착강화제를 도포하여 표면강화 및 제1방수층을 형성하고, 상기 제1방수층 위에 이소시아네이트로 블록킹된 폴리우레탄과 비정형 실리콘다이옥사이드와 칼슘카보네이트와 트리메틸렌헥사메티렌디아민과 페놀의 알킬술포닉산 에스테르로 혼합된 표면보강붕수제를 도포하여 표면보강 및 제2방수층을 형성하는 단계 및 상기 제2방수층위에 폴리이미노(1-옥소-1,6-헥산디일)와, 2,2-(1-메틸에틸리덴)비 스(4,1-페닐렌옥시메틸렌)비스 호모폴리머와, 메틸페녹시 메틸과 물을 포함하는 표면보호 및 제3방수층으로 형성하는 콘크리트 내부 벽면의 복합방수 보수방법이 기술되어 있으며,Korean Patent Publication No. 10-354135 discloses a method for repairing internal complex waterproofing of underground structures that prevents leaks and repairs and protects concrete surfaces that have been corroded by prolonged flooding. 1-oxo-1,6-hexanediyl), 2,2- (1-methylethylidene) bis (4,1-phenyleneoxymethylene), and a permeable adhesion strengthening agent mixed with methylphenoxymethyl and water Surface reinforcing and coating to form a first waterproofing layer, and a surface reinforcing shelf mixed with an alkylsulfonic acid ester of polyurethane, amorphous silicon dioxide, calcium carbonate, trimethylene hexamethylenediamine and phenol blocked with isocyanate on the first waterproofing layer. Forming a surface reinforcement and a second waterproofing layer by applying a hand, and polyimino (1-oxo-1,6-hexanediyl) and 2,2- (1-methylethylidene) arsenide on the second waterproofing layer; (4,1-phenyleneoxymethylene) ratio And homopolymers, and the composite waterproof repair method the concrete walls are described for forming a surface protection and the third waterproof layer comprising a-methylphenoxymethyl and water,

국내공개특허공보 공개번호 특2003-74180호에는 탄산나트륨, 염화칼륨, 염화암모늄, 보락스, 증류수로 이루어진 무기경화첨가제와, 규산나트륨, 실리콘, 또는 불소성분이 함유된 계면활성제, 증류수로 이루어진 조성물로 균일하게 도포하며, 상기 도포된 표면에 질산,황산 또는 구연산을 균일하게 도포 하는 단계를 포함하는 콘크리트 무기경화 첨가제용 조성물 및 콘크리트 표면처리방법이 기재되어 있고,Korean Laid-Open Patent Publication No. 2003-74180 is a uniform composition consisting of an inorganic curing additive consisting of sodium carbonate, potassium chloride, ammonium chloride, borax, distilled water, a surfactant containing sodium silicate, silicon or a fluorine component, and distilled water. It is applied to the composition, and the composition for concrete inorganic hardening additive and concrete surface treatment method comprising the step of uniformly applying nitric acid, sulfuric acid or citric acid on the applied surface,

동 공보 공개번호 특2003-71231호에는 에폭시수지 또는 변성 에폭시 수지와, 알루미나 또는 수산화 알루미늄, 조강용 시멘트와, 용제를 포함하여 혼합된 혼합물과, 폴리아미드수지 또는 변성 아민수지 또는 변성방향족 아민수지와 이산화티탄과 알루미늄실리케이트와, 물을 포함하여 혼합된 경화제를 혼합하여 하도재를 콘크리트 표면에 도포한후, 아크릴 수지 또는 변성 아크릴 수지, 이산화티탄, 폴리에스테르 수지 또는 변성 폴리에스테르 수지 용제를 포함하여 혼합된 혼합물과 우레탄 수지 또는 변성 우레탄 수지와 용제를 포함하여 혼합된 경화제를 혼합하여 상도재를 상면에 도포하는콘크리트의 중성화 및 열화방지공법이 기술되어 있으며,Publication No. 2003-71231 discloses a mixture containing an epoxy resin or a modified epoxy resin, alumina or aluminum hydroxide, a crude steel cement, a solvent, a polyamide resin or a modified amine resin or a modified aromatic amine resin and a dioxide. Titanium and aluminum silicate and mixed curing agent including water was mixed to apply the primer to the concrete surface, and then mixed with acrylic resin or modified acrylic resin, titanium dioxide, polyester resin or modified polyester resin solvent. The neutralization and deterioration prevention method of concrete which mixes a mixture, a urethane resin or a modified urethane resin, and a mixed hardening agent including a solvent and apply | coats a top coat material to the upper surface is described,

동 공보 공개번호 10-2004-0058537호에는 콘크리트구조물의 보수시 구 콘크리트와 보수용 모르터간의 계면에 접착을 강화하고 구조물의 내구성을 장기간 유지하는 기능을 부여하는 나노합성기술을 이용한 침투성 알콕시 실란계 하이브리드형 계면접착강화제 코팅제로 금속알콕사이드와 탈알콜방능하여 제조된 무기질계폴리머 구조를 갖는 신구콘크리트의 계면접착강화를 위한, 유,무기가교형 복합폴리머계코팅제 조성물 및 제조방법이 기재되어 있음을 알 수 있다.Korean Patent Publication No. 10-2004-0058537 discloses a permeable alkoxy silane-based hybrid using nanosynthesis technology that enhances adhesion to the interface between concrete and repair mortar during repair of concrete structures and maintains the durability of the structure for a long time. It can be seen that there is described an organic / inorganic crosslinkable composite polymer coating agent composition and a preparation method for interfacial adhesion strengthening of old and new concrete having inorganic polymer structure prepared by dealcoholization with metal alkoxide as a type of interfacial adhesion enhancing agent coating agent. have.

종래의 기술들은, 콘크리트의 도로를 급하게 보수하기 위하여 사용되는 강화조성물이 있으나, 단시간내에 도로를 긴급하게 보수하지 못하여 왔으며, 콘크리트가 빠른 속도로 경화되지 못하고, 콘크리트 도로에 사용시 강도도 저하되면서 손쉽게 파손되는 빈도가 높으며 지속적으로 견디지 못하는 문제점을 해결하는 것이 본 발명이 해결하고자 하는 과제인 것이다.Conventional techniques have reinforcement compositions used to repair concrete roads urgently, but have not been able to repair roads urgently within a short time, and concrete is not hardened at high speed, and when used on concrete roads, it easily breaks down. It is a problem to be solved by the present invention to solve the problem that the frequency is frequently and does not endure continuously.

본 발명은 상기와 같은 문제점을 해결하기 위하여, 본 출원인이 선출원한 특허출원번호 제10-2004-0029049호, 발명의 명칭 균열방지시공방법 및 그에 사용되는 조성물, 특허출원번호/일자 10-2004-0075597 (2004.09.21) 콘크리트 표면강화제, 특허출원번호/일자 10-2005-0091923 (2005.09.30) 콘크리트 표면강화 및 열화(태양광선 및 화학적부식)방지시공방법, 특허출원번호 제10-2008-0111612호 (2008.11.11), 콘크리트 포장도로의 침투성을 강화시켜 급속 경화시킴과 동시에 강도 증진을 위하여 침투 및 미세균열부의 부착 및 방수층까지 형성 할 수 있도록, 알루미나시멘트, 탄산나트륨, 명반석, 감수제, 규산계화합물, 포트랜드시멘트, 규 사 및 폴리비닐알콜로 조성된 콘크리트 긴급보수제 및 그 제조방법을 제공하는 것을 목적으로 한다. The present invention, in order to solve the above problems, the patent application No. 10-2004-0029049 filed by the applicant of the present application, the name of the invention crack prevention construction method and composition used therein, patent application number / date 10-2004- 0075597 (2004.09.21) Concrete surface hardener, patent application number / date 10-2005-0091923 (2005.09.30) Construction method for preventing concrete surface hardening and deterioration (sunlight and chemical corrosion), patent application number 10-2008-0111612 No. 11 (2008.11.11), Alumina cement, sodium carbonate, alum, susceptor, silicic acid-based compounds to enhance the permeability of concrete pavement to rapidly cure and to form penetration and microcracking part and waterproof layer to enhance strength. To provide a concrete emergency repair agent composed of Portland cement, silica sand and polyvinyl alcohol and a method of manufacturing the same.

본 발명은 콘크리트 포장, 콘크리트 구조물 측구, 방음벽, 벽체 및 표면 강도 저하부의 강도증진과 함께 급속 경화시켜, 콘크리트 표면강도증대 및 마모성 증대의 효과가 있으며, 친수성이므로 물만 넣어 사용할 수 있고, 콘크리트의 도로 보수, 콘크리트 구축물의 토목 및 건축 시공 및 보수분야 등에 다양하게 이용될 수 있는 장점이 있는 것이다.The present invention is rapidly cured with increasing the strength of concrete pavement, concrete structure side, soundproof wall, wall and surface strength lowering portion, and has the effect of increasing the concrete surface strength and abrasion, and can be used only water because it is hydrophilic, road repair of concrete In addition, there is an advantage that can be used in a variety of fields, such as civil engineering of concrete construction, building construction and repair.

상기와 같은 목적을 달성하기 위한 본 발명은 알루미나시멘트, 탄산나트륨, 명반석, 감수제, 규산계화합물, 포트랜드시멘트, 규사 및 폴리비닐알콜로 조성된 콘크리트 긴급 보수제 및 그 제조방법에 관한 것이다.The present invention for achieving the above object relates to a concrete emergency repair agent composed of alumina cement, sodium carbonate, alum, water reducing agent, silicic acid-based compound, portland cement, silica sand and polyvinyl alcohol, and a method of manufacturing the same.

본 발명의 포트랜드시멘트나 알루미나시멘트는 무기접착제로 사용되며 알루미나시멘트는 팽창제 보조역할을 하며, 경제적이거나, 시멘트 특성상 포트랜트시멘트는 24중량%, 알루미나시멘트는 25중량%가 적당하다.Portland cement or alumina cement of the present invention is used as an inorganic adhesive and the alumina cement serves as a swelling agent, economical, 24% by weight of the cement cement, 25% by weight of the alumina cement is suitable.

본 발명의 규사는 경화제 역할을 하도록 하며 36.9중량% 가 넘으면 너무 경화되고, 36.9중량% 미만이면 너무 연화되어 36.9중량%가 적당하다.The silica sand of the present invention serves as a curing agent and is too hard to be more than 36.9% by weight, too soft to be less than 36.9% by weight, so 36.9% by weight is appropriate.

본 발명의 규산계 화합물은 소듐실리케이트, 포타슘실리케이트,리듐실리케이 트,칼슘실리케이트에서 선택된 어느 하나의 화합물을 사용하며, 콘크리트 도로의 균열 및 파손된 곳에 깊게 침투하도록 사용하였고, 너무 많으면 규산계화합물의 특성이 강하고 비경제적이며, 너무 적으면 성능이 저하되어 5중량%가 바람직하다.    The silicic acid compound of the present invention is any one selected from sodium silicate, potassium silicate, lithium silicate, calcium silicate, and used to penetrate deeply into cracks and breaks of concrete roads. The property is strong and uneconomical, and if too small, the performance is degraded and 5% by weight is preferable.

본 발명의 명반석은 백반석이라고 하며, 육방결정계 광물로, 조각모양, 흙모양으로 백색, 투명에서 반투명 화산암에 화산성 가스의 황이 작용하거나 지하수속에 들어 있는 황산이 알루미나질 암석에 작용하여 생기며, 화학조성은 KAl3(OH)6(SO4)2 으로 팽창제 역할을 하며, Alumite of the present invention is called alumite, and it is a hexagonal mineral, which is formed by white sulfur, volcanic gas, sulfuric acid, or sulfuric acid in groundwater acting on alumina rock. The composition is KAl 3 (OH) 6 (SO 4 ) 2 It acts as a swelling agent,

총량 대비 4중량%가 넘으면 방수기능이 저하되고, 4중량%보다 적으면 증발속도와 용해도가 부족하여 시공시 문제점이 발생하고,If more than 4% by weight of the total amount of water-resistant function is lowered, if less than 4% by weight evaporation rate and solubility is insufficient, the construction problem occurs,

본 발명의 감수제로서는 나프탈렌술폰산 단독화합물을 포름알데히드에 의하여 축합한 축합물(일본특허공개소61-83659호)이나 술폰화한 멜라민의 포름알데히드 축합물 또는 리그닌술폰산 나트륨염에서 선택된 어느 하나의 화합물이 사용되고 사용량은 2중량%가 넘으면, 너무 묽어지고 2중량%가 적어지면 감수제 기능이 떨어지므로 2중량%가 바람직하다.As the water reducing agent of the present invention, any compound selected from a condensate obtained by condensation of a naphthalenesulfonic acid homogeneous compound with formaldehyde (formerly Japanese Patent Application Laid-Open No. 61-83659), or a formaldehyde condensate of sulfonated melamine or sodium lignin sulfonic acid salt If the amount used is more than 2% by weight, too thin and 2% by weight is reduced, so that the water content of the reducing agent is deteriorated, so 2% by weight is preferable.

본 발명에서 사용되는 탄산나트륨은 무수물은 백색 분말의 흡습성이 강하며, 3중량% 가 넘으면 비경제적이며, 3중량% 이하이면 탄산나트륨의 특성이 저하되므로 3중량%가 적당하다.Sodium carbonate used in the present invention, the anhydride is strong hygroscopicity of the white powder, more than 3% by weight is uneconomical, if less than 3% by weight of sodium carbonate deteriorates 3% by weight is suitable.

본 발명의 폴리비닐알콜은 방수제가 시공하는 과정에서 시공체의 표면에 부착이 잘되도록 도와주며, 낮은 온도에서 증발하여 습기를 유인 제거하고, 알콕시실란의 화학반응을 촉진시키는 역할을 하며, 비극성인 탄화수소성분으로만 구성된 용제를 부분극성화 시킴으로서, 별도의 첨가제 없이 정전기 발생을 억제하기 위하여 사용되는 것이다.The polyvinyl alcohol of the present invention helps to adhere well to the surface of the construction during the construction of the waterproofing agent, evaporates at a low temperature to attract moisture, promotes the chemical reaction of the alkoxysilane, non-polar By polarizing a solvent composed only of hydrocarbon components, it is used to suppress the generation of static electricity without any additives.

본 발명의 구성성분의 총량대비 폴리비닐알콜 사용량은 0.1중량%보다 많을 경우에는 시공체의 표면에 너무 잘 부착되는 반면, 방수층이 묽어지는 반면 증발로 인한 습기제거 효과는 크고,When the amount of polyvinyl alcohol to the total amount of the constituents of the present invention is more than 0.1% by weight, it adheres well to the surface of the construction body, whereas the waterproofing layer is diluted, while the moisture removal effect due to evaporation is large,

상기 보다 적게 사용하면, 시공체의 표면에 잘부착되지 않는 반면 방수층이 진해지는 반면 증발로 인한 습기제거 효과가 적기 때문에, 바람직한 사용량은 구성성분의 총량대비 0.1중량%를 사용하는 것이다.When the less is used, the preferred amount is 0.1% by weight relative to the total amount of the constituents because it is less adhered to the surface of the construction while the waterproofing layer is thicker and the moisture removal effect due to evaporation is less.

본 발명을 실시예를 통하여 상세히 설명하면 다음과 같다.The present invention will be described in detail with reference to the following Examples.

실시예1Example 1

알루미나시시멘트25kg, 탄산나트륨3kg, 명반석4kg, 리그닌술폰산 나트륨염2kg, 소듐실리케이트5kg을 혼합하여 100RPM의 교반기에 투입하여 2시간 혼합한 다음, 상기 혼합물에 포트랜드시멘트 24kg, 규사36.9kg 및 폴리비닐알콜0.1kg을 200RPM의 교반기에 투입하여 상온에서 2시간 동안 충분히 혼합하여 콘크리트 긴급보수제를 제조하였다.25 kg of alumina cement, 3 kg of sodium carbonate, 4 kg of alumite, 2 kg of lignin sulfonic acid salt, 5 kg of sodium silicate were mixed and mixed in a 100RPM stirrer for 2 hours, and then mixed with the mixture, 24 kg of Portland cement, 36.9 kg of silica sand and polyvinyl alcohol 0.1 The kg was added to a 200RPM stirrer and sufficiently mixed at room temperature for 2 hours to prepare a concrete emergency repair agent.

실시예2Example 2

알루미나시시멘트25kg, 탄산나트륨3kg, 명반석4kg, 리그닌술폰산 나트륨 2kg, 포타슘실리케이트5kg을 혼합하여 100RPM의 교반기에 투입하여 2시간 혼합한 다음, 상기 혼합물에 포트랜드시멘트 24kg, 규사36.9kg 및 폴리비닐알콜0.1kg을 200RPM의 교반기에 투입하여 상온에서 2시간 동안 충분히 혼합하여 콘크리트 긴급보수제를 제조하였다.Alumina cement 25kg, sodium carbonate 3kg, alum stone 4kg, sodium lignin sulfonate 2kg, potassium silicate 5kg mixed in a 100RPM stirrer and mixed for 2 hours, the mixture was 24kg Portland cement, 36.9kg silica sand and 0.1kg polyvinyl alcohol Was added to a 200RPM stirrer and sufficiently mixed at room temperature for 2 hours to prepare a concrete emergency repair agent.

실시예3Example 3

알루미나시시멘트25kg, 탄산나트륨3kg, 명반석4kg, 리그닌술폰산 나트륨 2kg, 칼슘실리케이트 5kg을 혼합하여 100RPM의 교반기에 투입하여 2시간 혼합한 다음, 상기 혼합물에 포트랜드시멘트 24kg, 규사36.9kg 및 폴리비닐알콜0.1kg을 200RPM의 교반기에 투입하여 상온에서 2시간 동안 충분히 혼합하여 콘크리트 긴급보수제를 제조하였다.25 kg of alumina cement, 3 kg of sodium carbonate, 4 kg of alumite, 2 kg of sodium lignin sulfonate, 5 kg of calcium silicate were mixed and mixed in a 100RPM stirrer for 2 hours, and then mixed with the mixture, 24 kg of Portland cement, 36.9 kg of silica sand and 0.1 kg of polyvinyl alcohol. Was added to a 200RPM stirrer and sufficiently mixed at room temperature for 2 hours to prepare a concrete emergency repair agent.

상기와 같이 제조된 본 발명의 콘크리트 긴급보수제는 알루미나시시멘트25중량%, 탄산나트륨3중량%, 명반석 4중량%, 감수제2중량%, 규산계화합물 5중량%, 포트랜드시멘트 24 중량%, 규사36.9중량% 및 폴리비닐알콜0.1중량%로 조성된 콘크리트 긴급 보수제에 관한 것이다.Concrete emergency repair agent of the present invention prepared as described above 25% by weight of alumina cement, 3% by weight of sodium carbonate, 4% by weight of alumite, 2% by weight of reducing agent, 5% by weight of silicic acid-based compound, 24% by weight of Portland cement, 36.9% by weight of silica sand It relates to a concrete emergency repair agent composed of 0.1% by weight of polyvinyl alcohol.

실험예 1. Experimental Example 1.

압축강도시험Compressive strength test

접수번호 090901-CC993Reception number 090901-CC993

접수일자 2009.9.1Date of Receipt 2009.9.1

시료명 콘크리트 긴급보수제Sample Name Concrete Emergency Repair

의뢰인; 김용석(한일피엔티(주))client; Kim, Yong-Seok (Hanil P & T)

시험기관 ; 한국건자재시험연구원Test institute; Korea Building Materials Testing Institute

표1Table 1

종류Kinds 시험방법Test Methods 경과시간Elapsed time 시험결과Test result 비고Remarks 실시예1Example 1 실시예2Example 2 실시예3Example 3 압축강도
(kgf/㎤)
Compressive strength
(kgf / cm 3)
KSL 5105:1987KSL 5105: 1987 1시간1 hours 139139 147147 139139
5시간5 hours 223223 191191 177177 24시간24 hours 264264 237237 254254

실험예 2Experimental Example 2

실시예1과 같이 시공된 콘크리트구조물에 대한 강도시험 및 길이변화율에 대한 시험을 한 결과 다음과 같다.The results of the strength test and the rate of change of length of the concrete structure constructed as in Example 1 are as follows.

시험기관 한국화학시험연구원Testing Institute Korea Chemical Testing Institute

시료명 콘크리트 단면보수제(콘크리트긴급보수제;P&T모르터))Sample Name Concrete Section Repair Agent (Concrete Emergency Repair Agent; P & T Motor)

접수일자 2009년 6월9일Date of Reception June 9, 2009

시험완료일 2009년 8월 14일Exam completion date 14 August 2009

배합비(무게비): 물첨가제:수지:P&T모르터)Compounding ratio (weight ratio): Water additive: Resin: P & T mortar)

부착강도 도포두께10mmAdhesive strength Coating thickness 10mm

표2Table 2

시험항목Test Items 단위unit 실험결과Experiment result 시험방법Test Methods 비고Remarks 압축강도(1일)Compressive Strength (1 Day) MPaMPa 20.920.9 KS F 2438;2002KS F 2438; 2002 압축강도(3일)Compressive Strength (3 Days) MPaMPa 28.828.8 KS F 2438;2002KS F 2438; 2002 압축강도(7일)Compressive Strength (7 Days) MPaMPa 33.733.7 KS F 2438;2002KS F 2438; 2002 압축강도(28일)Compressive Strength (28 Days) MPaMPa 37.437.4 KS F 2438;2002KS F 2438; 2002 압축탄성계수(28일)Compression modulus (28 days) MPaMPa 2686026860 KS F 2438;2002KS F 2438; 2002 부착강도(표준상태28일)Adhesion strength (standard condition 28 days) N/mm2 N / mm 2 3.193.19 KS F 4716;2001KS F 4716; 2001 동결융해에 대한 저항성
(상대동탄성계수300cycle)
Resistance to freezing and thawing
(Relative elastic modulus of 300 cycles)
%% 9292 KS F 2456;2003KS F 2456; 2003
흡수율(1개월)Absorption rate (one month) %% 0.90.9 KS F 4004;2008KS F 4004; 2008 길이변화율Length change rate %% 1One KS F 2476;2003KS F 2476; 2003 굽힘강도(28일)Bending Strength (28 Days) MPaMPa 6.96.9 KS F 4916
:1999
KS F 4916
: 1999

상기와 같이 실험결과에 따라, 본 발명은 압축강도, 흡수율(내흡수성), 굽힙강도 등이 KS 표준규격 시험 기준치에 합격하는 것을 나타내고 있다.According to the experimental results as described above, the present invention indicates that the compressive strength, water absorption (absorption resistance), bending strength and the like pass the KS standard test standard.

시공예Construction example

차량을 통제한 후에, 콘크리트 포장도로의 파손된 부위를 깨끗이 브러쉬나 고압 분무기를 사용 청소하여 준 다음, 표면 이물질은 제거한 후에, 상기 실시예1내지 실시예3 중에서 제조된 어느 하나의 콘크리트 긴급보수제 80kg, 물 20kg을 교반기에 충분히 교반한 다음, 5Cm 두께로 충진하고, 약 30분에서 2시간 경과후, 완전히 건조되었을 때 차량을 개통시켜 준다.After controlling the vehicle, clean the damaged part of the concrete pavement using a brush or a high pressure sprayer, and then remove the surface foreign matter, 80kg of any one concrete emergency repair agent manufactured in Example 1 to Example 3 After stirring 20 kg of water in the stirrer sufficiently, it is filled to a thickness of 5 cm and after about 30 minutes to 2 hours, the vehicle is opened when it is completely dried.

(시공성)(Workability)

본 발명의 실시예1의 콘크리트 긴급보수제에 대한 시험시공을 현장에 수행한 결과에 의하면 시공상의 특이점을 발견되지 않았다. 비교적 시공이 간편하여 적은 인력으로도 작업을 수행할 수 있었다.According to the results of the test construction of the concrete emergency repair agent of Example 1 of the present invention on-site, no specificity in construction was found. It was relatively easy to construct, so it was possible to perform work with less manpower.

Claims (2)

콘크리트 긴급보수제에 있어서,In concrete emergency repair, 알루미나시시멘트25중량%, 탄산나트륨3중량%, 명반석 4중량%, 감수제2중량%, 규산계화합물 5중량%, 포트랜드시멘트 24 중량%, 규사36.9중량% 및 폴리비닐알콜0.1중량%로 조성되며,It is composed of 25% by weight of alumina cement, 3% by weight of sodium carbonate, 4% by weight of alumite, 2% by weight of water reducing agent, 5% by weight of silicic acid-based compound, 24% by weight of Portland cement, 36.9% by weight of silica sand and 0.1% by weight of polyvinyl alcohol. 상기 감수제는 나프탈렌술폰산 단독화합물을 포름알데히드에 의하여 축합한 축합물, 술폰화한 멜라민의 포름알데히드 축합물 또는 리그닌술폰산 나트륨염에서 선택된 어느 하나의 화합물이고,The sensitizing agent is any one compound selected from condensates obtained by condensing naphthalenesulfonic acid homogeneous compounds with formaldehyde, formaldehyde condensates of sulfonated melamine, or lignin sulfonic acid sodium salt, 상기 규산계화합물은 소듐실리케이트, 포타슘실리케이트, 리듐실리케이트, 칼슘실리케이트에서 선택된 어느 하나의 화합물임을 특징으로 하는 콘크리트 긴급 보수제.The silicic acid-based compound is a concrete emergency repair agent, characterized in that any one selected from sodium silicate, potassium silicate, lithium silicate, calcium silicate. 삭제delete
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KR101336673B1 (en) * 2012-03-21 2013-12-04 김용석 Concrete repair material and mending method using concrete
KR101446663B1 (en) 2014-05-13 2014-10-06 김용석 The concrete surface reinforcement and protect from burning construetion methodthereof
CN104310916A (en) * 2014-10-10 2015-01-28 张秀丽 Concrete for reinforcing building and preparation method thereof
KR20200105577A (en) 2019-02-28 2020-09-08 김윤아 Mortar composition using cement mixture and constructing method using it
KR20200105575A (en) 2019-02-28 2020-09-08 김윤아 Slip-resistant non-slip composition using cement mixture and slip-resistant construction method using it
KR20200117102A (en) 2019-04-02 2020-10-14 김윤아 Cement composition for section repair and construction method using it
KR102202727B1 (en) 2020-07-16 2021-01-15 주식회사 케이앤에이치테크 Reinforcement method for deterioration of concrete damage and concrete structure by self-healing agent of nano polymer concrete
KR102216939B1 (en) * 2020-04-23 2021-02-17 이상기 Surface strengthening chemical and concrete structure repairing method thereof
KR102227572B1 (en) 2020-05-02 2021-03-15 이주철 Concrete repair method using concrete self-recovering material, and Concrete repair method using Mortar composition with the material
KR102341746B1 (en) * 2021-05-28 2021-12-27 비제이엠텍 주식회사 The pneumatic method of chalammation minimizes vibration and damage to the structure matrix, and a repair method that can secure quality by using a premix-type emergency repair agent containing an appropriate amount of excellent concrete admixture
CN116178047A (en) * 2023-04-25 2023-05-30 石家庄市长安育才建材有限公司 Concrete surface hole sealing agent, preparation method thereof and concrete
KR102566380B1 (en) 2022-06-23 2023-08-14 테라텍 주식회사 the concrete repairing agent having excellent anti-pollution property

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101336673B1 (en) * 2012-03-21 2013-12-04 김용석 Concrete repair material and mending method using concrete
KR101446663B1 (en) 2014-05-13 2014-10-06 김용석 The concrete surface reinforcement and protect from burning construetion methodthereof
CN104310916A (en) * 2014-10-10 2015-01-28 张秀丽 Concrete for reinforcing building and preparation method thereof
KR20200105577A (en) 2019-02-28 2020-09-08 김윤아 Mortar composition using cement mixture and constructing method using it
KR20200105575A (en) 2019-02-28 2020-09-08 김윤아 Slip-resistant non-slip composition using cement mixture and slip-resistant construction method using it
KR20200117102A (en) 2019-04-02 2020-10-14 김윤아 Cement composition for section repair and construction method using it
KR102216939B1 (en) * 2020-04-23 2021-02-17 이상기 Surface strengthening chemical and concrete structure repairing method thereof
KR102227572B1 (en) 2020-05-02 2021-03-15 이주철 Concrete repair method using concrete self-recovering material, and Concrete repair method using Mortar composition with the material
KR102202727B1 (en) 2020-07-16 2021-01-15 주식회사 케이앤에이치테크 Reinforcement method for deterioration of concrete damage and concrete structure by self-healing agent of nano polymer concrete
KR102252539B1 (en) 2020-07-16 2021-05-17 주식회사 케이앤에이치테크 Reinforcement method for deterioration of concrete damage and concrete structure by self-healing agent of nano polymer concrete
KR102341746B1 (en) * 2021-05-28 2021-12-27 비제이엠텍 주식회사 The pneumatic method of chalammation minimizes vibration and damage to the structure matrix, and a repair method that can secure quality by using a premix-type emergency repair agent containing an appropriate amount of excellent concrete admixture
KR102566380B1 (en) 2022-06-23 2023-08-14 테라텍 주식회사 the concrete repairing agent having excellent anti-pollution property
CN116178047A (en) * 2023-04-25 2023-05-30 石家庄市长安育才建材有限公司 Concrete surface hole sealing agent, preparation method thereof and concrete
CN116178047B (en) * 2023-04-25 2023-08-04 石家庄市长安育才建材有限公司 Concrete surface hole sealing agent, preparation method thereof and concrete

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