KR100929837B1 - Building interior and exterior materials using volcanic ash and its manufacturing method - Google Patents

Building interior and exterior materials using volcanic ash and its manufacturing method Download PDF

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KR100929837B1
KR100929837B1 KR1020070093809A KR20070093809A KR100929837B1 KR 100929837 B1 KR100929837 B1 KR 100929837B1 KR 1020070093809 A KR1020070093809 A KR 1020070093809A KR 20070093809 A KR20070093809 A KR 20070093809A KR 100929837 B1 KR100929837 B1 KR 100929837B1
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volcanic ash
exterior materials
interior
building interior
manufacturing
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KR1020070093809A
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Korean (ko)
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KR20090028312A (en
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박근성
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박근성
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    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/12—Condensation polymers of aldehydes or ketones
    • C04B26/125—Melamine-formaldehyde condensation polymers
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068—Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0097—Anion- and far-infrared-emitting materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00439—Physico-chemical properties of the materials not provided for elsewhere in C04B2111/00
    • C04B2111/00456—Odorless cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54—Substitutes for natural stone, artistic materials or the like
    • C04B2111/542—Artificial natural stone
    • C04B2111/545—Artificial marble

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  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Civil Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Finishing Walls (AREA)

Abstract

본 발명은 건축용 내 ·외장재 및 그 제조방법에 관한 것으로, 보다 상세하게는 화산재를 주재로 하여 친환경적이고 내구성, 내화성이 뛰어난 화산재를 이용한 건축용 내 ·외장재 및 그 제조방법에 관한 것으로 화산재 67~87중량%, 멜라민수지 10~25중량%, 물 3~8중량%를 혼합·교반하여 혼합물을 제조하는 혼합공정, 상기 혼합물을 성형틀에 투입하는 투입공정, 상기 성형틀에 투입된 혼합물을 130~160℃의 온도, 260~430kg/㎠로 압력으로 9~12초 동안 가압하는 압축성형공정을 포함하는 것을 특징으로 한다.The present invention relates to a building interior and exterior materials and a method for manufacturing the same, and more particularly, to a building interior and exterior materials using volcanic ash, which is environmentally friendly, durable, and fire-resistant with a volcanic ash as a main material and a method of manufacturing the volcanic ash 67 ~ 87 weight %, Melamine resin 10-25 wt%, water 3-8 wt% by mixing and stirring to prepare a mixture, the mixing step of the mixture into the mold, the mixture into the mold 130 ~ 160 ℃ The temperature, characterized in that it comprises a compression molding process for pressurizing for 9 to 12 seconds at a pressure of 260 ~ 430kg / ㎠.

본 발명에 따른 화산재를 이용한 건축용 내·외장재는 높은 강도와 내수성, 내마모성, 내열성, 내구성이 뛰어나고 화산재의 원적외선, 음이온의 방출, 항균, 탈취의 뛰어난 성능으로 내장재로 화장실이나 목욕탕 등의 내벽에 마무리재로 사용되는 타일로 사용할 수 있고, 외장재로는 대리석의 대용으로 사용할 수 있다.Building interior and exterior materials using volcanic ash according to the present invention is excellent in high strength and water resistance, abrasion resistance, heat resistance, durability and excellent performance of far infrared rays, anion emission, antibacterial, deodorization of volcanic ash as interior materials, finishing materials on the interior walls of toilets and bathrooms It can be used as a tile, and can be used as a substitute for marble as an exterior material.

화산재, 내·외장재, 멜라민 수지 Volcanic ash, interior and exterior materials, melamine resin

Description

화산재를 이용한 건축용 내·외장재 및 그 제조방법{INSIDE AND OUTSIDE CONSTRUCTION MATERIAL USING VOLCANIC ASH AND MANUFACTURING METHOD THEREOF}Interior and exterior materials for construction using volcanic ash and its manufacturing method {INSIDE AND OUTSIDE CONSTRUCTION MATERIAL USING VOLCANIC ASH AND MANUFACTURING METHOD THEREOF}

본 발명은 건축용 내 ·외장재 및 그 제조방법에 관한 것으로, 보다 상세하게는 화산재를 주재로 하여 친환경적이고 내구성, 내화성이 뛰어난 화산재를 이용한 건축용 내 ·외장재 및 그 제조방법에 관한 것이다.The present invention relates to a building interior and exterior materials and a method of manufacturing the same, and more particularly to a building interior and exterior materials using volcanic ash, environmentally friendly, durable, fire-resistant, and a manufacturing method thereof.

일반적으로 건축물을 축조한 후 그 건축 구조물의 내벽, 외벽 및 바닥 등에는 마감재로 사용되는 여러 종류의 건축용 내·외장재가 부착되어 진다.In general, after the construction of a building, various types of interior and exterior materials for building, which are used as finishing materials, are attached to inner walls, outer walls, and floors of the building structure.

종래의 건축용 내·외장재는 뛰어난 내구성과 내수성 및 내마모성의 특징을 지니고 있기 때문에 건축물의 내, 외벽과 천장, 바닥면은 물론 화장실, 목욕탕, 아파트의 발코니 등에 주로 사용되고 있다.Conventional interior and exterior materials for buildings have excellent durability, water resistance, and wear resistance, so it is mainly used in the interior, exterior walls and ceilings, floors of buildings, as well as bathrooms, bathrooms, apartments and balconies.

상기 종래의 건축용 내·외장재는 대부분 석회 등의 무기질원료를 사용하여 고온에서 소성하여 제조하는 석재타일 형이거나 시멘트를 사용하여 양생시켜 제조되는 콘크리트형으로 내구성, 내수성, 내마모성을 건축용 내·외장재에 적합하도록 보강 또는 향상시키기 위해 화학물질을 첨가하거나, 합성수지류의 소재로 표면을 코팅 처리하여 제조되었다.The conventional building interior and exterior materials are mostly stone tile type manufactured by firing at high temperature using inorganic raw materials such as lime, or concrete type manufactured by curing using cement, which is suitable for building interior and exterior materials for durability, water resistance, and abrasion resistance. It was prepared by adding a chemical to reinforce or enhance the coating, or by coating the surface with a synthetic resin material.

하지만, 첨가된 화학물질이나 코팅된 합성수지류는 대부분 인체에 유해한 환경오염물질로 상기의 종래의 건축용 내·외장재가 시공된 후, 환경 호르몬을 발생시켜 피부병을 일으키는 원인이 되며, 화재시 유독가스를 발생시켜 인명사고를 일으키는 원인이 되는 문제점이 있다.However, added chemicals or coated synthetic resins are mostly environmental pollutants that are harmful to the human body, and after the conventional interior and exterior materials for construction are constructed, they generate environmental hormones and cause skin diseases. There is a problem that causes a personal accident.

본 발명은 상기와 같은 문제점을 해결하기 위한 것으로서, 본 발명에서는 몸에 이로운 원적외선을 발생하고 음이온을 방출하며 항균, 탈취기능이 뛰어난 화산재를 주원료로 하여 고온·고압에서 압축성형하여 불에 강하고 화산재가 치밀한 결합구조로 내구성 및 내수성이 뛰어난 화산재를 이용한 건축용 내·외장재를 제공하는 것을 목적으로 한다.The present invention is to solve the problems as described above, in the present invention by generating a far-infrared rays beneficial to the body, and releases negative ions, the main material is a volcanic ash with excellent antibacterial and deodorizing function as a main raw material to be resistant to fire and volcanic ash It is an object of the present invention to provide a building interior and exterior material using volcanic ash which has excellent durability and water resistance with a close coupling structure.

본 발명의 건축용 내·외장재의 제조방법은 화산재 67~87중량%, 멜라민수지 10~25중량%, 물 3~8중량%를 혼합·교반하여 혼합물을 제조하는 혼합공정, 상기 혼합물을 성형틀에 투입하는 투입공정, 상기 성형틀에 투입된 혼합물을 130~160℃의 온도, 260~430kg/㎠로 압력으로 9~12초 동안 가압하는 압축성형공정을 포함하는 것을 특징으로 한다.The manufacturing method of the building interior and exterior materials of the present invention is a mixing process of mixing and stirring 67 to 87% by weight of volcanic ash, 10 to 25% by weight of melamine resin, and 3 to 8% by weight of water, and mixing the mixture into a mold. Injecting step, characterized in that it comprises a compression molding process for pressurizing the mixture injected into the mold for 9 to 12 seconds at a temperature of 130 ~ 160 ℃, 260 ~ 430kg / ㎠.

본 발명에 따른 화산재를 이용한 건축용 내·외장재는 원적외선, 음이온의 방출, 항균 및 탈취의 기능을 가지는 화산재와 내수, 내열, 내약품성이 뛰어난 멜라민 수지를 사용하여 고온에서 고압력으로 압축성형하여 제조되므로 높은 강도와 내수성, 내마모성, 내열성, 내구성이 우수하여 내장재로 화장실이나 목욕탕 등의 내벽에 마무리재로 사용되는 타일로 사용할 수 있고, 외장재로는 대리석의 대용으로 사용할 수 있다.Building interior and exterior materials using volcanic ash according to the present invention is manufactured by compression molding at high pressure at high pressure by using a volcanic ash having a function of far infrared rays, anion release, antibacterial and deodorization, and melamine resin having excellent water resistance, heat resistance and chemical resistance. It has excellent strength, water resistance, abrasion resistance, heat resistance and durability, and can be used as a tile used as a finishing material on the inner wall of a bathroom or bathroom as an interior material, and can be used as a substitute for marble as an exterior material.

본 발명을 상세히 설명하면 다음과 같다.The present invention is described in detail as follows.

본 발명에 따른 화산재를 이용한 건축용 내·외장재는 화산재를 주원료로 하여 멜라민 수지를 접착제로 혼합하여 교반한 후, 성형틀에 투입하고 고온·고압으로 압축성형하여 제조된다.Building interior and exterior materials using volcanic ash according to the present invention is prepared by mixing the melamine resin with an adhesive with a volcanic ash as a main raw material, stirring it, and then putting it in a molding mold and compression molding at high temperature and high pressure.

화산재(volcanic ash)는 폭발적인 화산분출에 의해 생성된 2㎜ 이하 크기의 화산기원 입자로 입자감이 곱고 미세하며, 연속기공을 갖는 다공성 물질로서 원적외선 방사율이 92%를 넘고, 음이온을 방출하며, 항균, 탈취 성능이 매우 우수한 물질이다. 이산화규소(SiO2), 산화알루미늄(Al2O3), 산화철(Fe2O3)을 주요성분으로 하고 부성분으로는 나트륨(Na), 칼륨(K) 등의 알칼리금속, 칼슘(Ca), 마그네슘(Mg) 등의 알카리토금속, 티타늄(Ti), 망간(Mn), 인(P) 등이 소량 포함되어 있는 친환경적인 건축자재이다.Volcanic ash is a volcanic source particle of 2 mm or less produced by explosive volcanic eruptions, with a fine and fine grain, and a porous material with continuous pores. It is a very good deodorizing material. The main components are silicon dioxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), iron oxide (Fe 2 O 3 ), and the secondary components include alkali metals such as sodium (Na) and potassium (K), calcium (Ca), It is an environmentally friendly building material containing a small amount of alkali metal such as magnesium (Mg), titanium (Ti), manganese (Mn) and phosphorus (P).

본 발명에서 사용하는 화산재는 분쇄기에서 분쇄하여 150메시(mesh) 보다 작은 고운 입자상태로 분쇄하여 사용한다.The volcanic ash used in the present invention is pulverized in a pulverizer and used to be pulverized into fine particles smaller than 150 mesh.

상기 멜라민 수지는 무색 투명하여 아름다운 착색을 할 수 있으며, 내수성, 내약품성, 내열성이 뛰어나고, 전기적 성질도 뛰어나다. 식기·잡화·전기 기기 등의 성형재료로 사용되는 것으로 비중이 낮아 본 발명에 사용되는 화산재를 접착시키는데 적합하다. 또한, 멜라민 수지는 가사시간이 길어서 취급 및 사용이 용이하다.The melamine resin is colorless and transparent and can be beautifully colored, and excellent in water resistance, chemical resistance, heat resistance, and excellent electrical properties. It is used for molding materials such as tableware, sundries, and electrical equipment, and has a low specific gravity, and is suitable for bonding volcanic ash used in the present invention. In addition, melamine resin is easy to handle and use because of a long pot life.

본 발명에 의한 화산재를 이용한 건축용 내·외장재의 제조방법은 화산재와 멜라민 수지, 물을 성분비에 맞도록 혼합하여 혼합물을 제조하는 혼합공정, 상기 혼합물을 젓가락 형상의 금형에 투입하는 투입공정, 가열과 압력으로 압축성형하는 압축성형공정순으로 제조된다.The method of manufacturing interior and exterior materials for building using volcanic ash according to the present invention is a mixing process of preparing a mixture by mixing volcanic ash and melamine resin and water in accordance with the component ratio, an input process of injecting the mixture into a chopstick-shaped mold, heating and It is manufactured in the order of compression molding process by compression molding under pressure.

상기 혼합공정은 화산재 67~87중량%, 멜라민 수지 10~25중량%, 물 3~8중량%를 혼합·교반하여 혼합물을 제조하는 공정이다.The mixing step is a step of mixing and stirring 67 to 87% by weight of volcanic ash, 10 to 25% by weight of melamine resin, and 3 to 8% by weight of water to prepare a mixture.

상기 물은 화산재의 뭉침을 방지하고 화산재와 멜라민 수지가 균일하게 교반되도록 하는 작용을 한다.The water serves to prevent agglomeration of the ash and to uniformly stir the ash and the melamine resin.

또한, 상기 혼합물에 본 발명의 화산재를 이용한 건축용 내·외장재의 색상을 연출하기 위해 무기안료를 첨가할 수 있다.In addition, an inorganic pigment may be added to the mixture to produce the color of the building interior and exterior materials using the volcanic ash of the present invention.

상기 투입공정은 혼합공정에서 혼합된 혼합물을 일정 형상의 성형틀에 투입하는 공정으로 혼합물 투입 전, 상기 성형틀을 예열하면 공정처리 속도를 향상시킬 수 있다.The feeding step is a step of putting the mixture mixed in the mixing step into a mold having a predetermined shape, and preheating the mold before adding the mixture can improve the process speed.

상기 압축성형공정은 상기 성형틀에 투입된 혼합물을 130~160℃의 온도, 260~430kg/㎠로 압력으로 9~12초 동안 가압하는 공정으로 고온하에서 높은 압력으로 성형시켜 첨가된 물은 모두 증발하고 화산재들이 서로 치밀하게 밀착하여 접합 되어 고강도의 건축용 내·외장재가 제조된다.The compression molding process is a process of pressurizing the mixture introduced into the molding die at a temperature of 130 to 160 ° C. and 260 to 430 kg / cm 2 for 9 to 12 seconds under high temperature under high temperature. Volcanic ashes are closely adhered to each other to produce high strength building interior and exterior materials.

상기 압축성형공정 중에 높은 압력에 의해 멜라민 수지가 표면으로 흘러나와 코팅층을 형성하게 되어 건축용 내·외장재의 내수성 및 내구성 등의 물성을 더욱 향상시키게 된다.During the compression molding process, the melamine resin flows out to the surface to form a coating layer, thereby further improving physical properties such as water resistance and durability of building interior and exterior materials.

상기의 제조방법으로 제조되는 화산재를 이용한 건축용 내·외장재는 높은 강도와 내수성, 내마모성, 내열성, 내구성이 뛰어나고 화산재의 원적외선, 음이온의 방출, 항균, 탈취의 뛰어난 성능으로 내장재로 화장실이나 목욕탕 등의 내벽에 마무리재로 사용되는 타일로 사용할 수 있고, 외장재로는 대리석의 대용으로 사용할 수 있다.Building interior and exterior materials using volcanic ash produced by the above manufacturing method is excellent in high strength, water resistance, abrasion resistance, heat resistance, durability, and excellent performance of far infrared ray, anion release, antibacterial, and deodorization of volcanic ash. It can be used as a tile used for finishing, and as a substitute for marble as an exterior material.

앞에서 설명된 본 발명을 기술적 사상을 한정하는 것으로 해석되어서는 안 된다. 본 발명의 보호범위는 청구범위에 기재된 사항에 의하여만 제한되고, 본 발명의 기술분야에서 통상의 지식을 가진 자는 본 발명의 기술적 사상을 다양한 형태로 개량 변경하는 것이 가능하다. 따라서 이러한 개량 및 변경은 통상의 지식을 가진 자에게 자명한 것인 한 본 발명의 보호범위에 속하게 될 것이다.The invention described above should not be construed as limiting the technical spirit. The protection scope of the present invention is limited only by the matters described in the claims, and those skilled in the art can change and change the technical idea of the present invention in various forms. Therefore, such improvements and modifications will fall within the protection scope of the present invention, as will be apparent to those skilled in the art.

Claims (2)

화산재 67~87중량%, 멜라민수지 10~25중량%, 물 3~8중량%를 혼합·교반하여 혼합물을 제조하는 혼합공정;A mixing step of mixing and stirring 67 to 87% by weight of ash, 10 to 25% by weight of melamine resin, and 3 to 8% by weight of water; 상기 혼합물을 성형틀에 투입하는 투입공정;Injecting the mixture into a mold; 상기 성형틀에 투입된 혼합물을 130~160℃의 온도, 260~430kg/㎠로 압력으로 9~12초 동안 가압하는 압축성형공정을 포함하는 것을 특징으로 하는 화산재를 이용한 건축용 내·외장재 제조방법.Method for manufacturing interior and exterior materials for building using volcanic ash, characterized in that it comprises a compression molding process for pressing the mixture put into the mold for 9 to 12 seconds at a temperature of 130 ~ 160 ℃, 260 ~ 430kg / ㎠. 제1항의 제조방법으로 제조되는 것을 특징으로 하는 화산재를 이용한 건축용 내·외장재.Building interior and exterior materials using volcanic ash, characterized in that the production method of claim 1.
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KR20010096638A (en) * 2001-04-28 2001-11-08 장문환 Compounds for building using volcanic rock
KR100747619B1 (en) * 2006-09-15 2007-08-08 정갑철 Sound absorption type sound proofing panels using lightweight aggregate of bottom ash

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Publication number Priority date Publication date Assignee Title
KR20010096638A (en) * 2001-04-28 2001-11-08 장문환 Compounds for building using volcanic rock
KR100747619B1 (en) * 2006-09-15 2007-08-08 정갑철 Sound absorption type sound proofing panels using lightweight aggregate of bottom ash

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