KR100876076B1 - A composition of scouring agent with excellent stability for alkali and method of scouring/silketing a blended fabric comprising cotton by using the same - Google Patents
A composition of scouring agent with excellent stability for alkali and method of scouring/silketing a blended fabric comprising cotton by using the same Download PDFInfo
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- KR100876076B1 KR100876076B1 KR1020080077334A KR20080077334A KR100876076B1 KR 100876076 B1 KR100876076 B1 KR 100876076B1 KR 1020080077334 A KR1020080077334 A KR 1020080077334A KR 20080077334 A KR20080077334 A KR 20080077334A KR 100876076 B1 KR100876076 B1 KR 100876076B1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
- D06M15/27—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of alkylpolyalkylene glycol esters of unsaturated carboxylic acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/63—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing sulfur in the main chain, e.g. polysulfones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
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- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
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Abstract
Description
본 발명은 알칼리에 대한 안정성이 뛰어난 내알칼리성 정련침투제 조성물 및 이를 이용하여 면 교직물을 일욕처리 방식으로 정련/표백 전처리와 실켓가공(Silket) 가공을 동시에 실시하는 가공방법에 관한 것이다.The present invention relates to an alkali-resistant refining penetrant composition excellent in alkali stability and a processing method for simultaneously performing refining / bleaching pretreatment and a silk thread processing in a single bath treatment method using a cotton fabric.
제직된 면 교직물을 염색, 가공하기 위해서는 제직공정 등에서 묻은 각종 오염물을 정련침투제를 사용하여 제거하는 정련 및 표백 공정을 거쳐야하며, 면 교직물의 형태안정성 및 방축성을 향상시키고 주름제거를 위해서는 농도 50%의 수산화나트륨이 300~350g/ℓ 정도로 용해된 수산화나트륨 수용액으로 면 교직물을 처리해주는 실켓가공을 거쳐야 한다.In order to dye and process woven cotton fabrics, it is required to go through refining and bleaching processes to remove various contaminants from the weaving process using a refining penetrant, and to improve the form stability and shrinkage of cotton fabrics and to remove wrinkles. Sodium hydroxide in 300 ~ 350g / ℓ dissolved in sodium hydroxide aqueous solution should be subjected to the processing of the silk thread.
상기 면 교직물의 정련 및 표백공정은 고온에서 배치식 방법 또는 연속식 방법으로도 실시되지만, 최근에는 상온에서 정련 및 표백하는 방법(Cold Pad Batch Bleaching : 이하 "CPB 전처리"라고 한다)이 경제적이고 처리효과가 뛰어난 이유로 널리 사용된다.The refining and bleaching process of the cotton fabric is also carried out by a batch method or a continuous method at a high temperature, but recently, a method of refining and bleaching at room temperature (Cold Pad Batch Bleaching: hereinafter referred to as "CPB pretreatment") is economical and treated. It is widely used for its excellent effect.
실켓(Silket) 가공은 일명 머서라이징(Mercerizing) 가공이라고도 한다.Sealing is also known as mercerizing.
종래에는 도 2에 도시된 바와 같이 면 교직물의 CPB 전처리와 실켓가공 처리를 각각 정련침투제 용액과 수산화나트륨(농도 50%)이 300~350g/ℓ 정도로 용해된 수산화나트륨 수용액 각각에서 따로 실시하는, 즉 2욕처리 방식으로 실시되어 왔다.Conventionally, as shown in FIG. 2, the CPB pretreatment and the threading treatment of cotton fabrics are separately performed in the sodium hydroxide aqueous solution in which the scouring agent solution and the sodium hydroxide (concentration 50%) are dissolved at about 300 to 350 g / L, respectively. It has been carried out in a two bath treatment method.
그 이유는 지금까지 알려진 정련침투제들은 내알칼리성이 약하기 때문에 실켓가공 처리에 사용되는 상기 수산화나트륨 수용액에 첨가시 정련침투제의 침투성능과 세정성능이 크게 저하되기 때문이었다.The reason for this is that the refinement penetrants known so far have poor alkali resistance, and therefore, when added to the aqueous sodium hydroxide solution used for the processing of the sealant, the penetration and cleaning performance of the refiner penetrant is greatly reduced.
도 2는 종래방법에 따른 면 교직물의 정련 및 실켓 가공방법의 공정 플로우 차트이다.2 is a process flowchart of a method of refining and sealing a cotton fabric according to a conventional method.
종래 사용된 정련침투제 용액으로는 미국특허 4,426,203호 등에 기재된 바와 같이 아래 하기 (ⅰ) 구조식(Ⅰ)의 음이온계 계면활성제 (ⅱ) 무기산화제 및 (ⅲ) 실록산-옥시알킬렌 코폴리머를 포함하는 정련침투제 용액이 사용되어 왔다.The conventionally used refining penetrant solution is a refining comprising an anionic surfactant of formula (I) below (ii) an inorganic oxidizing agent and (iii) a siloxane-oxyalkylene copolymer as described in US Pat. No. 4,426,203 and the like. Penetrant solutions have been used.
R-O-(CH2CH2O)mX (Ⅰ)RO- (CH 2 CH 2 O) mX (Ⅰ)
[상기 식에서 R은 탄소수가 8~22개인 알킬 또는 알케닐이고, X는 아인산기(phosphoric acid radical)이고, m은 2~30의 정수이다][Wherein R is alkyl or alkenyl having 8 to 22 carbon atoms, X is phosphoric acid radical, and m is an integer of 2 to 30]
그러나, 상기의 정련침투제 용액은 실켓가공 처리용 약제, 즉 수산화나트륨(농도 50%)이 300~350g/ℓ로 용해된 수산화나트륨 수용액에 첨가시 침투성능과 세 정성능이 크게 저하되어 면 교직물을 일욕처리방식으로 CPB 전처리와 실켓가공하는 공정에는 사용이 불가능한 문제점이 있었다.However, the above-mentioned refining penetrant solution has a significant decrease in the permeation and cleaning performance when added to an aqueous solution for treating the quenching process, that is, sodium hydroxide (concentration 50%) dissolved in 300 ~ 350g / ℓ. CPB pretreatment and the process of processing the silk in a single bath treatment method had a problem that can not be used.
이와같은 문제점을 해결하기 위해서, 미국특허 5,385,681호에서는 (ⅰ) 알킬렌옥사이드를 가지며 탄소수가 8~16개인 2차 또는 분지된 알콜, (ⅱ) 탄소수가 6~18개인 지방산 및 (ⅲ) 탄소수가 13~17개인 2차 알칸 설포닉산의 염(Salt of a secondary alkane sulfonic acid)을 포함하는 내알칼성 정련침투제 용액을 게재하고 있으나 상기 정련침투제 용액 역시 실켓가공 처리용 약제, 즉 수산화나트륨(농도 50%)이 300~350g/ℓ로 용해된 수산화나트륨 수용액에 첨가시 침투성능과 세정성능이 크게 저하되어 면 교직물을 일욕처리방식 CPB 전처리와 실켓가공하는 공정에는 사용이 불가능한 문제점이 있었다.In order to solve this problem, U.S. Patent No. 5,385,681 discloses a secondary or branched alcohol having (i) alkylene oxide and having 8 to 16 carbon atoms, (ii) a fatty acid having 6 to 18 carbon atoms and (iii) carbon number. Alkali resistance penetrant solution containing 13 to 17 salts of a secondary alkane sulfonic acid has been disclosed, but the penetrant solution is also used for the treatment of the coating process, namely sodium hydroxide (concentration 50%). ), When added to the aqueous sodium hydroxide solution dissolved at 300 ~ 350g / ℓ greatly reduced the permeability and cleaning performance, there was a problem that can not be used in the process of CPB pre-treatment and the processing of the silk fabrics.
본 발명은 실켓가공용 약제, 즉 농도 50%의 수산화나트륨이 300~350g/ℓ로 용해된 수산화나트륨 수용액에 첨가하여도 침투성능과 세정성능이 손상되지 않고 그대로 유지될 수 있는 내알칼리성 정련침투제 조성물을 제공하고자 한다.The present invention provides an alkali-resistant refining penetrant composition which can be kept intact without impairing the cleaning performance even when added to a sodium hydroxide aqueous solution in which a sodium hydroxide having a concentration of 50% is dissolved at 300 to 350 g / l at a concentration of 50%. To provide.
또한, 본 발명은 상기 내알칼리성 정련침투제 조성물이 첨가된 상기 수산화나트륨 수용액에서 면 교직물의 CPB 전처리와 실켓가공을 동시에 실시하는 1욕처리방식인 면 교직물의 정련 및 실켓 가공방법을 제공하고자 한다.In addition, the present invention is to provide a method for refining and sealing a cotton fabric of a cotton bath, which is a one-bath treatment method of simultaneously performing CPB pretreatment and a sheet processing of cotton fabric in an aqueous sodium hydroxide refining penetrant composition.
본 발명은 상기의 과제들을 달성하기 위해서, 전체 조성물 100중량부를 기준으로 (ⅰ) 탄소수가 10~18개인 폴리에틸렌글리콜 알킬 에테르 4~20중량부, (ⅱ) 탄소수가 6~15개인 알킬 폴리에테르 설페이트, 알킬 폴리에테르 포스페이트 및 알킬 폴리에테르 카복실레이트로 이루어진 군에서 선택된 1종의 화합물 29~47중량부, (ⅲ) 부틸 셀로솔브(Butyl cellosolve : C6H4O2), 에탄올, 글리콜 에테르 및 이소프탈산으로 이루어진 군에서 선택된 1종의 용제 1~3중량부, (ⅳ) 탄소수가 6~13개인 미네날 오일(Mineral Oil), 옥탄올 및 트리부틸포스페이트로 이루어진 군에서 선택된 1종의 화합물 6~8중량부 및 (ⅴ) 물(Water) 36~46중량부로 이루어진 내알칼리성 정련침투제 조성물을 제공한다.In order to achieve the above objects, the present invention, based on 100 parts by weight of the total composition (i) 4 to 20 parts by weight of polyethylene glycol alkyl ether having 10 to 18 carbon atoms, (ii) alkyl polyether sulfate having 6 to 15 carbon atoms , 29 to 47 parts by weight of one compound selected from the group consisting of alkyl polyether phosphates and alkyl polyether carboxylates, (iii) Butyl cellosolve (C 6 H 4 O 2 ), ethanol, glycol ethers and iso 1 to 3 parts by weight of one solvent selected from the group consisting of phthalic acid, (iii) 1 to 6 compounds selected from the group consisting of mineral oil having 6 to 13 carbon atoms, octanol and tributyl phosphate It provides an alkali-resistant refining penetrant composition consisting of 36 parts by weight and (iii) 36 parts by weight of water.
본 발명에 따른 정련침투제 조성물은 실켓 가공용 약제, 즉 농도 50%의 수산화나트륨이 300~350g/ℓ로 용해된 수산화나트륨 수용액에 첨가하여도 침투성능과 세정성능이 손상되지 않고 그대로 유지될 수 있는 내알칼리성을 구비하기 때문에, 이를 면 교직물의 실켓 가공용 수산화나트륨 용액에 첨가하여 면 교직물을 1욕 방식으로 CPB 전처리와 실켓 가공을 동시에 실시하는 것이 가능하게 된다.The refining penetrant composition according to the present invention can be maintained intact without impairing the cleaning performance, even if added to the aqueous solution of sodium hydroxide dissolved in 300 ~ 350g / ℓ of the drug for the processing of the seal, 50% concentration Since it has alkalinity, it can be added to the sodium hydroxide solution for the processing of the cotton fabric of a cotton fabric, and it is possible to simultaneously perform CPB pretreatment and the coating of the cotton fabric in a one bath manner.
본 발명은 면 교직물을 1욕 방식으로 CPB 전처리와 실켓 가공을 동시에 실시할 수 있기 때문에, 종래 2욕 방식에 비해 에너지와 비용이 절감되고, 공정도 간소화되는 효과가 있다.According to the present invention, since the cotton textile fabric can be simultaneously subjected to CPB pretreatment and the silk thread processing in one bath method, energy and cost are reduced and the process is simplified as compared with the conventional two bath method.
이하, 첨부한 도면 등을 통하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
본 발명에 따른 내알칼리성 정련침투제 조성물은 전체 조성물 100중량부를 기준으로 (ⅰ) 탄소수가 10~18개인 폴리에틸렌글리콜 알킬 에테르 4~20중량부, (ⅱ) 탄소수가 6~15개인 알킬 폴리에테르 설페이트, 알킬 폴리에테르 포스페이트 및 알킬 폴리에테르 카복실레이트로 이루어진 군에서 선택된 1종의 화합물 29~47중량부, (ⅲ) 부틸 셀로솔브(Butyl cellosolve : C6H4O2), 에탄올, 글리콜 에테르 및 이소프탈산으로 이루어진 군에서 선택된 1종의 용제 1~3중량부, (ⅳ) 탄소수가 6~13개인 미네날 오일(Mineral Oil), 옥탄올 및 트리부틸포스페이트로 이루어진 군에서 선택된 1종의 화합물 6~8중량부 및 (ⅴ) 물(Water) 36~46중량부로 이루어진 것을 특징으로 한다.Alkali-resistant refining agent composition according to the present invention is based on 100 parts by weight of the total composition (i) 4 to 20 parts by weight of polyethylene glycol alkyl ether having 10 to 18 carbon atoms, (ii) alkyl polyether sulfate having 6 to 15 carbon atoms, 29 to 47 parts by weight of one compound selected from the group consisting of alkyl polyether phosphates and alkyl polyether carboxylates, (i) butyl cellosolve (C 6 H 4 O 2 ), ethanol, glycol ethers and isophthalic acid 1 to 3 parts by weight of one solvent selected from the group consisting of (i) 6 to 8 weights of one compound selected from the group consisting of mineral oil having 6 to 13 carbon atoms, octanol and tributyl phosphate Part and (iii) characterized in that consisting of 36 to 46 parts by weight of water (Water).
상기 폴리에틸렌글리콜 알킬 에테르는 3~20몰, 보다 바람직하기로는 6~10몰의 에틸렌옥사이드를 포함한다.The polyethylene glycol alkyl ether contains 3 to 20 moles, more preferably 6 to 10 moles of ethylene oxide.
상기 폴리에틸렌글리콜 알킬 에테르는 탄소수가 13개이고, 에틸렌 옥사이드가 10몰인 것이 가장 바람직하다.The polyethylene glycol alkyl ether has 13 carbon atoms and most preferably 10 mol of ethylene oxide.
상기 폴리에틸렌글리콜 알킬 에테르의 탄소수는 12~15개인 것이 보다 바람직하다.As for carbon number of the said polyethyleneglycol alkyl ether, it is more preferable that it is 12-15.
상기 미네날 오일, 옥탄올 및 트리부틸포스페이트로 이루어진 군에서 선택된 1종의 화합물의 함량이 상기 범위를 벗어나는 경우에는 침투력과 알칼리안정성이 크게 저하된다.When the content of one compound selected from the group consisting of the mineral oil, octanol and tributyl phosphate is outside the above range, the penetration and alkali stability are greatly reduced.
상기 알킬 폴리에테르 설페이트, 알킬 폴리에테르 포스페이트 및 알킬 폴리에테르 카복실레이트로 이루어진 군에서 선택된 1종의 화합물은 탄소수가 6~15개, 보다 바람직하기로는 8~12개이고, 에틸렌 옥사이드 몰수가 1~15몰, 보다 바람직하 기로는 8~12몰이다.The compound selected from the group consisting of alkyl polyether sulfate, alkyl polyether phosphate and alkyl polyether carboxylate has 6 to 15 carbon atoms, more preferably 8 to 12 carbon atoms, and 1 to 15 mol moles of ethylene oxide. More preferably, it is 8-12 mol.
다음으로는 본 발명에 따른 면 교직물의 정련 및 실켓 가공방법을 도 1을 참조하여 상세하게 설명한다.Next, the method of refining and sealing the cotton fabric according to the present invention will be described in detail with reference to FIG. 1.
도 1은 본 발명에 따른 면 교직물의 정련 및 실켓 가공방법의 공정 플로우 차트이다.1 is a process flow chart of a method for refining and sealing a cotton fabric according to the present invention.
먼저, 도 1에 도시된 바와 같이 면 교직물을 차례로 연폭 및 소모처리한 다음, 후술하는 CPB 전처리 및 실켓 가공용 1액형 약제에 20~40℃의 온도에서 5~15시간 침지한 다음, 상온에서 숙성 후 수세 및 건조하여 면 교직물을 일욕처리방식으로 CPB 전처리 및 실켓 가공을 동시에 실시한다.First, as shown in FIG. 1, the cotton fabrics are sequentially softened and consumed, and then immersed in a one-component medicine for CPB pretreatment and a squeezing process, which will be described later, at a temperature of 20 to 40 ° C. for 5 to 15 hours, and then aged at room temperature. After washing and drying, the cotton fabrics are subjected to CPB pretreatment and squeegee processing simultaneously in a single bath treatment.
본 발명의 면 교직물은 면이 혼합된 직물로서, 예를 들면 나일론/면 교직물 등이다.The cotton fabric of the present invention is a woven fabric of cotton, for example nylon / cotton fabric.
상기 CPB 전처리 및 실켓 가공용 1액형 약제는 50% 농도의 수산화나트륨이 300~350g/ℓ로 용해된 수산화나트륨 수용액에 전체 조성물 100중량부를 기준으로 (ⅰ) 탄소수가 10~18개인 폴리에틸렌글리콜 알킬 에테르 4~20중량부, (ⅱ) 탄소수가 6~15개인 알킬 폴리에테르 설페이트, 알킬 폴리에테르 포스페이트 및 알킬 폴리에테르 카복실레이트로 이루어진 군에서 선택된 1종의 화합물 29~47중량부, (ⅲ) 부틸 셀로솔브(Butyl cellosolve : C6H4O2), 에탄올, 글리콜 에테르 및 이소프탈산으로 이루어진 군에서 선택된 1종의 용제 1~3중량부, (ⅳ) 탄소수가 6~13개인 미네날 오일(Mineral Oil), 옥탄올 및 트리부틸포스페이트로 이루어진 군에서 선택된 1종의 화합물 6~8중량부 및 (ⅴ) 물(Water) 36~46중량부로 이루어진 내알칼리성 정련침투제 조성물을 15~25g/ℓ의 농도로 첨가된 조성을 구비한다.The one-component medicament for pretreatment and processing of the CPB is based on 100 parts by weight of the total composition in an aqueous sodium hydroxide solution in which 50% sodium hydroxide is dissolved at 300 to 350 g / l. ~ 20 parts by weight, (ii) 29-47 parts by weight of one compound selected from the group consisting of alkyl polyether sulfates having 6 to 15 carbon atoms, alkyl polyether phosphates and alkyl polyether carboxylates, (iii) butyl cellosolve (Butyl cellosolve: C 6 H 4 O 2 ), 1 to 3 parts by weight of one solvent selected from the group consisting of ethanol, glycol ether and isophthalic acid, (iii) a mineral oil having 6 to 13 carbon atoms, 6-8 parts by weight of one compound selected from the group consisting of octanol and tributyl phosphate and (iii) 36 to 46 parts by weight of water were added to the concentration of 15-25 g / l alkali Composition Equipped.
상기 수산화나트륨 수용액내 수산화나트륨(농도 50%)의 용해량이 300g/ℓ 미만인 경우에는 면 교직물의 실켓가공도(이하 "머서화도"라고 함)와 백도가 나빠지고, 350g/ℓ를 초과하는 경우에는 면 교직물이 손상되어 물성이 나빠진다.When the amount of dissolved sodium hydroxide (concentration 50%) in the aqueous sodium hydroxide solution is less than 300 g / l, the surface finish and the whiteness of the surface processing of the cotton fabric (hereinafter referred to as “mercer degree”) deteriorate, and when it exceeds 350 g / l, If the cotton fabric is damaged, the physical properties are bad.
상기 수산화나트륨 수용액내 상기 내알칼리성 정련침투제 조성물의 첨가량이 15g/ℓ 미만인 면직물의 백도가 나빠지고, 25g/ℓ를 초과하는 경우에는 면 교직물이 손상되어 물성이 나빠진다.The whiteness of the cotton fabric of which the addition amount of the alkali-resistant refining penetrant composition in the sodium hydroxide solution is less than 15 g / l worsens, and when it exceeds 25 g / l, the cotton fabric is damaged and its physical properties deteriorate.
또한 상기 CPB 전처리 및 실켓 가공용 1액형 약제의 온도가 20℃ 미만이거나 침지시간이 5시간 미만인 경우에는 백도 및 머서화도가 저하되고, 상기 약제의 온도가 40℃를 초과하거나 침지시간이 15시간을 초과하는 경우에는 에너지 소모량이 많아지고 공정시간이 길어져 제조원가가 상승되는 문제 등이 발생된다.In addition, when the temperature of the one-component medicament for CPB pretreatment and seal processing is less than 20 ° C. or immersion time is less than 5 hours, the degree of whiteness and mercerization decreases, and the temperature of the medicament exceeds 40 ° C. or immersion time exceeds 15 hours. In this case, the energy consumption is increased, the process time is long, and the manufacturing cost is increased.
이하, 실시예 및 비교실시예를 통하여 본 발명을 상세하게 설명한다.Hereinafter, the present invention will be described in detail through Examples and Comparative Examples.
정련침투제Refinery Penetrant 조성물의 제조 Preparation of the composition
실시예Example 1 One
전체조성물 100중량부를 기준으로, (ⅰ) 탄소수가 13개이고 에틸렌 옥사이드 몰수가 10몰인 폴리에틸렌글리콜 알킬 에테르 5중량부, (ⅱ) 탄소수가 10개이고 에틸렌 옥사이드 몰수가 7몰인 알킬 폴리에테르 설페이드 45중량부, (ⅲ) 부틸셀로솔브(용제) 2중량부 및 (ⅳ) 탄소수가 8개인 미네널 오일 6중량부를 (v) 물 42중량부에 혼합하여 정련침투제 조성물을 제조하였다.(I) 5 parts by weight of polyethylene glycol alkyl ether having 13 carbon atoms and 10 moles of ethylene oxide based on 100 parts by weight of the total composition, (ii) 45 parts by weight of alkyl polyether sulfate having 7 moles of ethylene oxide having 10 carbons. (V) 2 parts by weight of butyl cellosolve (solvent) and 6 parts by weight of mineral oil having 8 carbon atoms (v) were mixed with 42 parts by weight of water to prepare a scouring penetrant composition.
제조된 정련침투제 조성물의 알칼리안정성과 침투력을 측정한 결과는 표 1과 같았다.The alkali stability and penetration power of the prepared refiner penetrant composition were measured as shown in Table 1 below.
실시예Example 2 2
전체조성물 100중량부를 기준으로, (ⅰ) 탄소수가 13개이고 에틸렌 옥사이드 몰수가 10몰인 폴리에틸렌글리콜 알킬 에테르 5중량부, (ⅱ) 탄소수가 10개이고 에틸렌 옥사이드 몰수가 7몰인 알킬 폴리에테르 설페이드 44중량부, (ⅲ) 부틸셀로솔브(용제) 2중량부 및 (ⅳ) 탄소수가 8개인 미네널 오일 8중량부를 (v) 물 41중량부에 혼합하여 정련침투제 조성물을 제조하였다.(I) 5 parts by weight of polyethylene glycol alkyl ether having 13 carbon atoms and 10 moles of ethylene oxide based on 100 parts by weight of the total composition, (ii) 44 parts by weight of alkyl polyether sulfate having 7 moles of ethylene oxide having 10 carbons. (V) 2 parts by weight of butyl cellosolve (solvent) and 8 parts by weight of mineral oil having 8 carbon atoms (v) were mixed with 41 parts by weight of water to prepare a scouring penetrant composition.
제조된 정련침투제 조성물의 알칼리안정성과 침투력을 측정한 결과는 표 1과 같았다.The alkali stability and penetration power of the prepared refiner penetrant composition were measured as shown in Table 1 below.
비교실시예Comparative Example 1 One
전체조성물 100중량부를 기준으로, (ⅰ) 탄소수가 13개이고 에틸렌 옥사이드 몰수가 10몰인 폴리에틸렌글리콜 알킬 에테르 5중량부, (ⅱ) 탄소수가 10개이고 에틸렌 옥사이드 몰수가 7몰인 알킬 폴리에테르 설페이드 45중량부 및 (ⅲ) 부틸셀로솔브(용제) 2중량부를 물 48중량부에 혼합하여 정련침투제 조성물을 제조하였다.(I) 5 parts by weight of polyethylene glycol alkyl ether having 13 carbon atoms and 10 moles of ethylene oxide based on 100 parts by weight of the total composition, (ii) 45 parts by weight of alkyl polyether sulfate having 7 moles of ethylene oxide having 10 carbons. And (iii) 2 parts by weight of butyl cellosolve (solvent) were mixed with 48 parts by weight of water to prepare a scouring penetrant composition.
제조된 정련침투제 조성물의 알칼리안정성과 침투력을 측정한 결과는 표 1과 같았다.The alkali stability and penetration power of the prepared refiner penetrant composition were measured as shown in Table 1 below.
비교실시예Comparative Example 2 2
지방알콜 에톡시레이트 38중량%, 마그네슘 클로라이드 7중량%, 소디움 1-벤질-2-헵타테실-벤지미다졸디설포네이트 5중량% 및 지방산 디에탄올아미드 3중량%를 물 47중량%에 혼합하여 정련침투제 조성물을 제조하였다.38% by weight of fatty alcohol ethoxylate, 7% by weight of magnesium chloride, 5% by weight of sodium 1-benzyl-2-heptatesyl-benzimidazole disulfonate and 3% by weight of fatty acid diethanolamide were refined to 47% by weight of water. The penetrant composition was prepared.
제조된 정련침투제 조성물의 알칼리안정성과 침투력을 측정한 결과는 표 1과 같았다.The alkali stability and penetration power of the prepared refiner penetrant composition were measured as shown in Table 1 below.
표 1에서, 알칼리안정성은 10g/ℓ의 정련침투제 조성물이 안정한 수산화나트륨 수액내 수산화나트륨(농도 50%)의 첨가량(g/ℓ)을 측정하였고, 침투력은 수산화나트륨(농도 50%)이 320g/ℓ로 용해된 수산화나트륨 용액에서 가로 10㎝ × 세로 10㎝의 8겹 나일론/면 교직물이 가라앉는 시간을 측정하였다.In Table 1, alkali stability was measured by adding the amount of sodium hydroxide (concentration 50%) in sodium hydroxide sap (g / l) in which 10 g / l refining penetrant composition was stable, and the penetrating power was 320 g / l in sodium hydroxide (concentration 50%). The time taken for the 8-ply nylon / cotton fabric of 10 cm width x 10 cm length to sink in the sodium hydroxide solution dissolved in l was measured.
면 if 교직물의Teaching material CPBCPB 전처리 및 Pretreatment and 실켓Seal 가공 Processing
실시예Example 3 3
50% 농도인 수산화나트륨이 300g/ℓ로 용해된 수산화나트륨 수용액에 실시예 1에서 제조한 정련침투제 조성물을 15g/ℓ 첨가하여 CPB 전처리 및 실켓 가공용 약제를 제조하였다.15 g / L of the scouring penetrant composition prepared in Example 1 was added to an aqueous sodium hydroxide solution in which 50% sodium hydroxide was dissolved at 300 g / L to prepare a CPB pretreatment and a sealant.
다음으로, 나일론/면 교직물을 연폭처리 및 소모처리한 다음, 계속해서 이를 온도가 25℃인 상기 CPB 전처리 및 실켓 가공용 약제에 7시간 동안 침지한 다음, 상온에서 숙성하고 수세 및 건조하여 일욕처리 방식으로 상기 나일론/면 교직물의 CPB 전처리와 실켓 가공을 동시에 실시하였다.Next, the nylon / cotton fabric is subjected to a soft-width treatment and consumption treatment, and then immersed in the CPB pretreatment and sealant processing agent for 7 hours at a temperature of 25 ℃, then aged at room temperature, washed and dried at room temperature By the CPB pretreatment of the nylon / cotton fabric and the processing of the seal was carried out at the same time.
상기와 같이 CPB 전처리 및 실켓 가공된 나일론/면 교직물의 각종 물성을 평가한 결과는 표 2와 같았다.As described above, the results of evaluating various physical properties of nylon / cotton fabrics treated with CPB pretreatment and sealing were as shown in Table 2.
실시예Example 4 4
50% 농도인 수산화나트륨이 350g/ℓ로 용해된 수산화나트륨 수용액에 실시예 2에서 제조한 정련침투제 조성물을 23g/ℓ 첨가하여 CPB 전처리 및 실켓 가공용 약제를 제조하였다.23 g / L of the scouring penetrant composition prepared in Example 2 was added to an aqueous sodium hydroxide solution in which 50% sodium hydroxide was dissolved at 350 g / L to prepare a CPB pretreatment and a sealant.
다음으로, 나일론/면 교직물을 연폭처리 및 소모처리한 다음, 계속해서 이를 온도가 35℃인 상기 CPB 전처리 및 실켓 가공용 약제에 13시간 동안 침지한 다음, 상온에서 숙성하고 수세 및 건조하여 일욕처리 방식으로 상기 나일론/면 교직물의 CPB 전처리와 실켓 가공을 동시에 실시하였다.Next, the nylon / cotton fabric is subjected to a soft-width treatment and consumption treatment, and then it is immersed in the CPB pretreatment and sealant processing agent for 13 hours at a temperature of 35 ℃, then aged at room temperature, washed with water and dried to bathe By the CPB pretreatment of the nylon / cotton fabric and the processing of the seal was carried out at the same time.
상기와 같이 CPB 전처리 및 실켓 가공된 나일론/면 교직물의 각종 물성을 평가한 결과는 표 2와 같았다.As described above, the results of evaluating various physical properties of nylon / cotton fabrics treated with CPB pretreatment and sealing were as shown in Table 2.
비교실시예Comparative Example 3 3
50% 농도인 수산화나트륨이 300g/ℓ로 용해된 수산화나트륨 수용액에 비교실시예 1에서 제조한 정련침투제 조성물을 15g/ℓ 첨가하여 CPB 전처리 및 실켓 가공용 약제를 제조하였다.15 g / L of the scouring penetrant composition prepared in Comparative Example 1 was added to an aqueous sodium hydroxide solution in which 50% sodium hydroxide was dissolved at 300 g / L to prepare a CPB pretreatment and a sealant.
다음으로, 나일론/면 교직물을 연폭처리 및 소모처리한 다음, 계속해서 이를 온도가 25℃인 상기 CPB 전처리 및 실켓 가공용 약제에 7시간 동안 침지한 다음, 상온에서 숙성하고 수세 및 건조하여 일욕처리 방식으로 상기 나일론/면 교직물의 CPB 전처리와 실켓 가공을 동시에 실시하였다.Next, the nylon / cotton fabric is subjected to a soft-width treatment and consumption treatment, and then immersed in the CPB pretreatment and sealant processing agent for 7 hours at a temperature of 25 ℃, then aged at room temperature, washed and dried at room temperature By the CPB pretreatment of the nylon / cotton fabric and the processing of the seal was carried out at the same time.
상기와 같이 CPB 전처리 및 실켓 가공된 나일론/면 교직물의 각종 물성을 평가한 결과는 표 2와 같았다.As described above, the results of evaluating various physical properties of nylon / cotton fabrics treated with CPB pretreatment and sealing were as shown in Table 2.
비교실시예Comparative Example 4 4
50% 농도인 수산화나트륨이 350g/ℓ로 용해된 수산화나트륨 수용액에 비교실시예 2에서 제조한 정련침투제 조성물을 23g/ℓ 첨가하여 CPB 전처리 및 실켓 가공용 약제를 제조하였다.23 g / L of the scouring penetrant composition prepared in Comparative Example 2 was added to an aqueous sodium hydroxide solution in which 50% sodium hydroxide was dissolved at 350 g / L to prepare a CPB pretreatment and a sealant.
다음으로, 나일론/면 교직물을 연폭처리 및 소모처리한 다음, 계속해서 이를 온도가 35℃인 상기 CPB 전처리 및 실켓 가공용 약제에 13시간 동안 침지한 다음, 상온에서 숙성하고 수세 및 건조하여 일욕처리 방식으로 상기 나일론/면 교직물의 CPB 전처리와 실켓 가공을 동시에 실시하였다.Next, the nylon / cotton fabric is subjected to a soft-width treatment and consumption treatment, and then it is immersed in the CPB pretreatment and sealant processing agent for 13 hours at a temperature of 35 ℃, then aged at room temperature, washed with water and dried to bathe By the CPB pretreatment of the nylon / cotton fabric and the processing of the seal was carried out at the same time.
상기와 같이 CPB 전처리 및 실켓 가공된 나일론/면 교직물의 각종 물성을 평가한 결과는 표 2와 같았다.As described above, the results of evaluating various physical properties of nylon / cotton fabrics treated with CPB pretreatment and sealing were as shown in Table 2.
상기 표 2에서, 머서화도는 KS K 0111 2006(바륨활성법)으로 측정하였고, 인장강도는 KS K 0525 2004 방법으로 측정하였고, 백도는 미놀타 CR 300 컬러리메터(Colorimeter)를 사용하여 5회 측정한 값을 평균치로 하였다.In Table 2, mercerization degree was measured by KS K 0111 2006 (barium activity method), tensile strength was measured by KS K 0525 2004 method, whiteness was measured 5 times using Minolta CR 300 Colorimeter (Colorimeter) One value was made into the average value.
도 1은 본 발명에 따른 면 교직물의 정련 및 실켓 가공방법의 공정-플로우 챠트.1 is a process-flow chart of a method for refining and sealing a cotton fabric according to the present invention.
도 2는 종래방법에 따른 면 교직물의 정련 및 실켓 가공방법의 공정-플로우 챠트.2 is a process-flow chart of a method of refining and sealing a cotton fabric according to a conventional method.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103352365A (en) * | 2013-05-31 | 2013-10-16 | 浙江安诺其助剂有限公司 | Environmentally-friendly alkali resistant scouring agent and preparation method thereof |
| CN105040423A (en) * | 2015-08-25 | 2015-11-11 | 无锡市长安曙光手套厂 | Alkali-resisting spinning refining agent and preparation method thereof |
| CN114481651A (en) * | 2021-12-31 | 2022-05-13 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11131091A (en) | 1997-09-01 | 1999-05-18 | Kao Corp | Scouring agent composition for fiber |
| US20030162686A1 (en) | 1997-10-29 | 2003-08-28 | Ingegard Johansson | Highly alkaline compositions containing a hexyl glycoside as a hydrotrope |
| JP2006336134A (en) | 2005-05-31 | 2006-12-14 | Dai Ichi Kogyo Seiyaku Co Ltd | Scouring agent composition for fiber |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11131091A (en) | 1997-09-01 | 1999-05-18 | Kao Corp | Scouring agent composition for fiber |
| US20030162686A1 (en) | 1997-10-29 | 2003-08-28 | Ingegard Johansson | Highly alkaline compositions containing a hexyl glycoside as a hydrotrope |
| JP2006336134A (en) | 2005-05-31 | 2006-12-14 | Dai Ichi Kogyo Seiyaku Co Ltd | Scouring agent composition for fiber |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103352365A (en) * | 2013-05-31 | 2013-10-16 | 浙江安诺其助剂有限公司 | Environmentally-friendly alkali resistant scouring agent and preparation method thereof |
| CN105040423A (en) * | 2015-08-25 | 2015-11-11 | 无锡市长安曙光手套厂 | Alkali-resisting spinning refining agent and preparation method thereof |
| CN114481651A (en) * | 2021-12-31 | 2022-05-13 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
| CN114481651B (en) * | 2021-12-31 | 2024-02-02 | 中山市鸿盛生物科技有限公司 | Alkali-resistant penetrating agent and application thereof in sizing |
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