KR100848775B1 - The method of ability plastics thread - Google Patents
The method of ability plastics thread Download PDFInfo
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- KR100848775B1 KR100848775B1 KR1020060110190A KR20060110190A KR100848775B1 KR 100848775 B1 KR100848775 B1 KR 100848775B1 KR 1020060110190 A KR1020060110190 A KR 1020060110190A KR 20060110190 A KR20060110190 A KR 20060110190A KR 100848775 B1 KR100848775 B1 KR 100848775B1
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/02—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
- D10B2321/022—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polypropylene
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
본 발명은 폴리에스테르 또는 폴리프로필렌에 맥반석, 칼슘, 티타늄, 토루마린, 게르마늄, 인, 동 및 은 등의 조성물이 분쇄, 건조, 진공혼합되어 압출성형에 의하여 합성수지사를 얻을 수 있도록 하여, 합성수지사의 자체로부터의 원적외선의 방출로 분자간의 여기현상이 인체의 혈행(血行)과 대사활동의 촉진하여 특정파장을 흡수한 인체의 체내에 있는 물분자가 여기(歟起)작용과, 또한 향균 성분의 방출로 인하여, 유해한 균의 생성을 막아 언제나 청결한 환경을 유지하여 주위의 환경오염으로 인한 제2의 질병의 발병을 예방하는 기능성 요소를 높일 수 있는 기능성 합성수지사의 제조방법에 관한 것으로, 본 발명은 폴리에스테르 또는 폴리프로필렌 70～74 중량%에 맥반석5∼8중량%, 칼슘3∼5중량%, 티타늄4∼6중량%, 토루마린5∼8중량%, 게르마늄4∼6중량%, 인0.5∼0.8중량%, 동2∼3중량% 및 은2∼3중량%가 혼합하는 혼합단계와; 상기 혼합된 조성물을 12,700∼20,000메쉬로 분쇄하는 분쇄단계와; 분쇄된 조성물을 200∼350℃에서 건조하는 건조단계와; 상기 건조된 조성물을 180∼220℃에서 진공혼합하는 진공혼합단계와; 상기 진공혼합된 조성물을 압출하는 압출단계;로 구성됨을 기능성 합성수지사의 제조방법에 특징이 있다. The present invention is a composite resin of pulverulent, calcium, titanium, tourmaline, germanium, phosphorus, copper and silver in a polyester or polypropylene to obtain a synthetic resin by extrusion molding by grinding, drying, vacuum mixing, etc. The release of far-infrared radiation from itself stimulates the blood circulation and metabolism of the body, and the water molecules in the body that absorb certain wavelengths excite and release antibacterial components. Due to the above, the present invention relates to a manufacturing method of a functional synthetic resin that can prevent the formation of harmful bacteria and always maintain a clean environment to increase the functional elements that prevent the onset of a second disease due to environmental pollution, the present invention relates to a polyester Alternatively, 70 to 74% by weight of polypropylene, 5 to 8% by weight of elvanite, 3 to 5% by weight of calcium, 4 to 6% by weight of titanium, 5 to 8% by weight of tourmaline, and 4 to 6% of germanium. Mixing step of mixing%, 0.5 to 0.8% by weight, 2-3% by weight and 2-3% by weight of silver; Grinding the mixed composition into 12,700 to 20,000 mesh; Drying step of drying the ground composition at 200 ~ 350 ℃; A vacuum mixing step of vacuum mixing the dried composition at 180 to 220 ° C .; Extrusion step of extruding the vacuum mixed composition; is characterized in that the manufacturing method of the functional synthetic resin.
폴리에스테르, 폴리프로필렌, 맥반석, 칼슘, 티타늄, 토루마린, 게르마늄, 인, 동, 은 Polyester, polypropylene, elvan, calcium, titanium, tourmaline, germanium, phosphorus, copper, silver
Description
도 1 은 본 발명의 기능성 합성수지사의 제조방법의 공정 블록도. 1 is a process block diagram of a manufacturing method of a functional synthetic resin of the present invention.
본 발명은 폴리에스테르 또는 폴리프로필렌 등의 합성수지에 기능성 조성물을 혼합하여 압출하도록 한 기능성 합성수지사의 제조방법에 관한 것으로, 더욱 상세하게는 폴리에스테르 또는 폴리프로필렌에 맥반석, 칼슘, 티타늄, 토루마린, 게르마늄, 인, 동 및 은 등의 조성물이 분쇄, 건조, 진공혼합되어 압출성형에 의하여 합성수지사를 얻을 수 있도록 하여, 합성수지사의 자체로부터의 원적외선의 방출로 분자간의 여기현상이 인체의 혈행(血行)과 대사활동의 촉진하여 특정파장을 흡수한 인체의 체내에 있는 물분자가 여기(歟起)작용과, 또한 향균 성분의 방출로 인하여, 유해한 균의 생성을 막아 언제나 청결한 환경을 유지하여 주위의 환경오염으로 인한 제2의 질병의 발병을 예방하는 기능성 요소를 높일 수 있는 기능성 합성수지사의 제조방법에 관한 것이다. The present invention relates to a method for producing a functional synthetic resin company to mix and extrude a functional composition to a synthetic resin such as polyester or polypropylene, and more particularly, to alumina, calcium, titanium, tourmaline, germanium, polyester or polypropylene Phosphorus, copper, and silver are pulverized, dried, and vacuum mixed to obtain a synthetic resin by extrusion molding, and the excitation phenomenon between molecules is caused by the release of far-infrared rays from the synthetic resin itself. Water molecules in the body of the human body that have absorbed specific wavelengths by promoting the activity, and also by the release of antimicrobial components, prevent the formation of harmful bacteria and maintain a clean environment at all times. In the manufacturing method of the functional synthetic resin that can increase the functional element to prevent the onset of the second disease caused One will.
일반적으로, 의류나 매트 등에 사용되는 각종 원단은 제사, 방사, 연사 등을 원료로 사용하여 직물 가공한 것으로, 상기 원단에는 그 대부분 기계적 성능, 위생적 성능, 장식적 성능 및 감각적 성능을 갖추고 있다.In general, various fabrics used in clothing, mats, and the like are fabric processed by using yarn, spinning, twisted yarn, etc., and most of the fabrics have mechanical performance, hygienic performance, decorative performance, and sensory performance.
즉, 원단에 다양한 성능을 부여하기 위해서는 각종 공정을 거치면서 여러 환경을 조성하거나 첨가물을 투입하게 되며, 특히 옷감의 종류나 사용 용도에 따라 그 조건이나 환경 및 첨가물이 달라지게 된다.In other words, in order to impart various performance to the fabric, various environments or additives are added through various processes, and in particular, the conditions, environment, and additives vary depending on the type and use of the fabric.
그리고, 각종 원단에는 이에 기능성을 부여하기 위하여 적외선을 방출하는 황토, 옥 또는 바이오 세라믹 등을 표면에 코팅하게 된다.In addition, various fabrics are coated with ocher, jade, or bio-ceramic to emit infrared light in order to impart functionality thereto.
그러나, 종래의 원단에는 항취, 항균 등의 기능을 가진 첨가물을 그 자체에 첨가하지 않았기 때문에 근본적으로 폭넓은 기능성 원단을 제공하지 못하였다는 단점이 있었다.However, the conventional fabric has a disadvantage in that it did not provide a broad functional fabric fundamentally because the additives having the function of anti-odor, antibacterial, etc. were not added to itself.
그래서, 근자에는 섬유에 항균, 항취 기능을 부여하기 위하여 원사에 은(Ag) 을 코팅 또는 침투시킨 은사를 사용하기도 한다.Therefore, in order to give antimicrobial and anti-odor function to the fiber, a silver coated or penetrated silver (Ag) is sometimes used.
따라서, 최근에는 투명한 폴리에스테르 필름에 은을 증착하여 다른 한 장의 폴리에스테르 필름을 접착한 뒤, 이를 종방향으로 세절하여 제조되는 바, 이 은사는 폴리에스테르 필름으로 보호된 구조이므로 은이온이 연속해서 방출되어 반영구적인 항균성을 발휘하게 하는 이점은 있으나, 그 강도가 매우 약하기 때문에 이를 이용하여 은사원단을 직조하는 과정에서 자주 절단됨은 물론이고, 폴리에스테르 필름에 의해 음이온의 방사가 크게 약화되기 때문에 소기의 목적을 전혀 달성하지 못하는 등의 문제점이 있다.Therefore, in recent years, silver is deposited on a transparent polyester film to bond another polyester film, and then it is manufactured by cutting in the longitudinal direction. Since the silver is a structure protected by a polyester film, silver ions are continuously There is an advantage to release semi-permanent antibacterial properties, but because the strength is very weak it is often cut in the process of weaving silver yarn using it, as well as the radiation of negative ions by the polyester film is greatly weakened There are problems such as not achieving the purpose at all.
본 발명은 상기의 문제를 해소하기 위한 것으로, 폴리에스테르 또는 폴리프로필렌의 합성수지에 맥반석, 칼슘, 티타늄, 토루마린, 게르마늄, 인, 동 및 은 등의 조성물이 혼합되어 압출 성형됨을 목적으로 한다. 또한 본 발명은 폴리에스테르 또는 폴리프로필렌 70～74 중량%에 맥반석, 칼슘, 티타늄, 토루마린, 게르마늄, 인, 동 및 은 등의 혼합조성물 24∼30중량%가 혼합되어 압출 성형될 수 있도록 됨을 목적으로 한다. 또한, 본 발명은 기능성 합성수지사의 제조방법에 의한 합성수지의 원사로부터 향균, 음이온, 원적외선, 탈취 및 소취 등의 효율을 높일 수 있도록 됨을 목적으로 한다. The present invention is to solve the above problems, and an object of the present invention is to extrude and mix a composition of gannetite, calcium, titanium, tourmaline, germanium, phosphorus, copper and silver in a synthetic resin of polyester or polypropylene. In addition, an object of the present invention is to be 70 to 74% by weight of polyester or polypropylene mixed with a mixture of 24 to 30% by weight of a mixture of ganbanite, calcium, titanium, tourmaline, germanium, phosphorus, copper and silver. It is done. In addition, an object of the present invention is to be able to increase the efficiency of antibacterial, anion, far infrared rays, deodorization and deodorization from the yarn of the synthetic resin by the manufacturing method of the functional synthetic resin.
본 발명은 폴리에스테르 또는 폴리프로필렌 70～74 중량%에 맥반석5∼8중량%, 칼슘3∼5중량%, 티타늄4∼6중량%, 토루마린5∼8중량%, 게르마늄4∼6중량%, 인0.5∼0.8중량%, 동2∼3중량% 및 은2∼3중량%가 혼합하는 혼합단계와; 상기 혼합된 조성물을 12,700∼20,000메쉬로 분쇄하는 분쇄단계와; 분쇄된 조성물을 200∼350℃에서 건조하는 건조단계와; 상기 건조된 조성물을 180∼220℃에서 진공혼합하는 진공혼합단계와; 상기 진공혼합된 조성물을 압출하는 압출단계;로 구성됨을 특징으로 한다. The present invention is 70 to 74% by weight of polyester or polypropylene, 5 to 8% by weight of gannetite, 3 to 5% by weight of calcium, 4 to 6% by weight of titanium, 5 to 8% by weight of tourmaline, 4 to 6% by weight of germanium, A mixing step of mixing 0.5 to 0.8 wt% of phosphorus, 2-3 wt% of copper and 2-3 wt% of silver; Grinding the mixed composition into 12,700 to 20,000 mesh; Drying step of drying the ground composition at 200 ~ 350 ℃; A vacuum mixing step of vacuum mixing the dried composition at 180 to 220 ° C .; And extruding the vacuum-mixed composition.
삭제delete
본 발명의 구성 및 작용에 대하여 상세히 설명하면 다음과 같다.Hereinafter, the configuration and operation of the present invention will be described in detail.
도 1 은 본 발명의 기능성 합성수지사의 제조방법의 공정 블록도이다.1 is a process block diagram of a manufacturing method of a functional synthetic resin of the present invention.
본 발명은 폴리에스테르 또는 폴리프로필렌 등의 합성수지의 70∼74중량%에 기능성 조성물 24∼30중량%이 혼합되어 합성수지사를 구성한다.In the present invention, 24 to 30% by weight of the functional composition is mixed with 70 to 74% by weight of a synthetic resin such as polyester or polypropylene to form a synthetic resin yarn.
상시 기능성 조성물을 맥반석5∼8중량%, 칼슘3∼5중량%, 티타늄4∼6중량%, 토루마린5∼8중량%, 게르마늄4∼6중량%, 인0.5∼0.8중량%, 동2∼3중량% 및 은2∼3중량%이다. The functional composition is always 5 to 8% by weight of ganbanite, 3 to 5% by weight of calcium, 4 to 6% by weight of titanium, 5 to 8% by weight of tourmaline, 4 to 6% by weight of germanium, 0.5 to 0.8% by weight of phosphorus and 2 to 2% of copper. 3 weight% and silver 2-3 weight%.
상기 기능성 조성물은 원적외선의 방출로 분자간의 여기현상이 인체의 혈행(血行)과 대사활동의 촉진하여 특정파장을 흡수한 인체의 체내에 있는 물분자가 여기(歟起)작용으로 노폐물과 과잉염분 등이 밀려나오고 동시에, 피하 심부로부터 체취도 배출시키고 피부도 청결하게 유지할 수 있으며, 더욱, 운동부족, 육류의 과잉섭취로 체내에 노폐물이 축적되고 혈액이 혼탁하여 체질이 산성화되는 것을 방지할 수 있고, 또한 향균 성분의 방출로 인하여, 유해한 균의 생성을 막아 언제나 청결한 환경을 유지하여 주위의 환경오염으로 인한 제2의 질병의 발병을 예방하는 기능성 요소를 높인다. In the functional composition, the excitation phenomenon between molecules due to the emission of far infrared rays promotes blood circulation and metabolic activity of the human body, and water molecules in the human body absorbing specific wavelengths excite the waste and excess salts. At the same time, it is possible to discharge body odor from the subcutaneous core and keep the skin clean. Furthermore, lack of exercise and excessive ingestion of meat can prevent the accumulation of wastes in the body and turbidity of the blood and acidification of the constitution. In addition, due to the release of the antimicrobial component, it prevents the generation of harmful bacteria to maintain a clean environment at all times to increase the functional factors that prevent the onset of a second disease caused by environmental pollution around.
그리고, 외부에서 아주 좋은 파장을 가진 원적외선을 흡수하게 되면 우리 몸을 구성하고 있는 10조개의 체세포(體細胞)들 중 정상적으로 활동하지 못하는 세포를 자극시켜 정상적인 활동을 할 수 있도록 한다. 무엇보다도 중요한 자율신경(自律神經)의 밸런스를 정화되도록 조정해 준다. And, by absorbing far-infrared rays with a very good wavelength from the outside, the 10 trillion of somatic cells constituting our body stimulate the cells that do not work normally to allow normal activity. Above all, it regulates the balance of important autonomic nerves.
원적외선에 의하여 실내의 탈취, 제습, 공기정화 및 파장대에 의해 인체에 유익하게 한다.Far infrared rays are beneficial to human body by indoor deodorization, dehumidification, air purification and wavelength band.
본 발명은 혼합단계에서 폴리에스테르 또는 폴리프로필렌의 70∼74중량%에 맥반석5∼8중량%, 칼슘3∼5중량%, 티타늄4∼6중량%, 토루마린5∼8중량%, 게르마늄4∼6중량%, 인0.5∼0.8중량%, 동2∼3중량% 및 은2∼3중량%가 혼합한다.The present invention is 70 to 74% by weight of polyester or polypropylene in the mixing step, 5 to 8% by weight of gannetite, 3 to 5% by weight of calcium, 4 to 6% by weight of titanium, 5 to 8% by weight of tourmaline, and 4 to 4% of germanium. 6 weight%, phosphorus 0.5-0.8 weight%, copper 2-3 weight% and silver 2-3 weight% mix.
또한 분쇄단계에서 상기 혼합된 조성물을 상온에서 12,700∼20,000메쉬로 분쇄를 행한다.In the grinding step, the mixed composition is ground to 12,700 to 20,000 mesh at room temperature.
또한, 건조단계에서 상기 분쇄된 조성물을 200∼350℃에서 건조를 향한다.In addition, the pulverized composition in the drying step to dry at 200 ~ 350 ℃.
상기 건조단계를 거친 상기 건조된 조성물을 180∼220℃에서 진공혼합하는 진공혼합단계를 거치도록 한다.,After the drying step, the dried composition is subjected to a vacuum mixing step of vacuum mixing at 180 ~ 220 ℃.,
그리고, 상기 진공혼합단계에서 상기 진공혼합된 조성물을 압출하는 압출단계에서 압출되도록 하여 합성수지사를 얻을 수 있다.In addition, a synthetic resin can be obtained by being extruded in an extrusion step of extruding the vacuum mixed composition in the vacuum mixing step.
상기 압출단계에서 형성된 합성수지사는 연신 등을 거쳐 직기, 편기 등을 이용하여 제직 또는 편직되어 양말 또는 최종의 섬유로 만들어지게 된다.The synthetic resin formed in the extrusion step is woven or knitted using a weaving machine, knitting machine, etc., through drawing or the like, and is made of socks or final fibers.
따라서, 합성수지와 기능성 조성물이 혼합하여 용융 방사 등의 과정을 거쳐 원사를 형성시킴에 의해 항균제로서의 안정성이 우수하고, 항균력이 오랫동안 지속됨과 동시에 작업공정을 간략화할 수 있다.Therefore, the synthetic resin and the functional composition are mixed to form a yarn through a process such as melt spinning, so that the stability as an antimicrobial agent is excellent, and the antimicrobial activity lasts for a long time and the work process can be simplified.
이상과 같이, 본 발명은 폴리에스테르 또는 폴리프로필렌에 맥반석, 칼슘, 티타늄, 토루마린, 게르마늄, 인, 동 및 은 등의 조성물이 분쇄, 건조, 진공혼합되어 압출성형에 의하여 합성수지사를 얻을 수 있도록 하여, 합성수지사의 자체로부터의 원적외선의 방출로 분자간의 여기현상이 인체의 혈행(血行)과 대사활동의 촉진하여 특정파장을 흡수한 인체의 체내에 있는 물분자가 여기(歟起)작용과, 또한 향균 성분의 방출로 인하여, 유해한 균의 생성을 막아 언제나 청결한 환경을 유지하여 주위의 환경오염으로 인한 제2의 질병의 발병을 예방하는 기능성 요소를 높일 수 있다.As described above, the present invention is a composition such as ganban stone, calcium, titanium, tourmaline, germanium, phosphorus, copper and silver in the polyester or polypropylene is pulverized, dried, and vacuum mixed to obtain a synthetic resin by extrusion molding Therefore, the excitation phenomenon between molecules due to the release of far infrared rays from the synthetic resin itself promotes blood circulation and metabolic activity of the human body, and the water molecules in the human body that absorbs specific wavelengths, Due to the release of the antimicrobial component, it is possible to prevent the generation of harmful bacteria to maintain a clean environment at all times to increase the functional element that prevents the development of a second disease caused by environmental pollution around.
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| KR19990085370A (en) * | 1998-05-16 | 1999-12-06 | 석미수 | Yarn for copying pi-ray and its manufacturing method |
| KR20000031317A (en) * | 1998-11-05 | 2000-06-05 | 박주민 | Nonwoven fabric having radiation of far infrared ray and process for producing thereof |
| KR20010103958A (en) * | 2000-05-12 | 2001-11-24 | 김영준 | A method of producing multi-functional fiber having anti-bacterial, deodorizing, anti-electrostatic properties and emitting negative ions, far-infrared ray, and fiber produced using the same |
| KR20040098808A (en) * | 2003-05-16 | 2004-11-26 | 조병범 | Method for manufacturing of mult filament yarn with isolation function of antibacterial purifying, anrifouling, ultraviolet and electromagnetic waves |
| KR20040107192A (en) * | 2003-06-13 | 2004-12-20 | 전영호 | Composite of synthetic fiber yarn and the manufacture method to use pure silver, nature inorganic matter complex |
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| KR19990085370A (en) * | 1998-05-16 | 1999-12-06 | 석미수 | Yarn for copying pi-ray and its manufacturing method |
| KR20000031317A (en) * | 1998-11-05 | 2000-06-05 | 박주민 | Nonwoven fabric having radiation of far infrared ray and process for producing thereof |
| KR20010103958A (en) * | 2000-05-12 | 2001-11-24 | 김영준 | A method of producing multi-functional fiber having anti-bacterial, deodorizing, anti-electrostatic properties and emitting negative ions, far-infrared ray, and fiber produced using the same |
| KR20040098808A (en) * | 2003-05-16 | 2004-11-26 | 조병범 | Method for manufacturing of mult filament yarn with isolation function of antibacterial purifying, anrifouling, ultraviolet and electromagnetic waves |
| KR20040107192A (en) * | 2003-06-13 | 2004-12-20 | 전영호 | Composite of synthetic fiber yarn and the manufacture method to use pure silver, nature inorganic matter complex |
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