KR100739397B1 - An Manufacturing Method of Positive ion Ceramic Mixed Pigment including Nano-iron ion of An Aqueous Solufion - Google Patents
An Manufacturing Method of Positive ion Ceramic Mixed Pigment including Nano-iron ion of An Aqueous Solufion Download PDFInfo
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- KR100739397B1 KR100739397B1 KR1020050035339A KR20050035339A KR100739397B1 KR 100739397 B1 KR100739397 B1 KR 100739397B1 KR 1020050035339 A KR1020050035339 A KR 1020050035339A KR 20050035339 A KR20050035339 A KR 20050035339A KR 100739397 B1 KR100739397 B1 KR 100739397B1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE
- B09B2101/00—Type of solid waste
- B09B2101/02—Gases or liquids enclosed in discarded articles, e.g. aerosol cans or cooling systems of refrigerators
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/20—Animal feeding-stuffs from material of animal origin
- A23K10/26—Animal feeding-stuffs from material of animal origin from waste material, e.g. feathers, bones or skin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65G—TRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F9/00—Fertilisers from household or town refuse
Abstract
본 발명은 양이온 세라믹(Positive ion Ceramic)도료에 나노철이온 수용액(F2O3)을 포함시켜 화학적으로 활성인 친환경 양이온 세라믹 혼합도료를 제조하는 방법에 관한 것으로서 도포력과 접착력이 강하고 우수함은 물론 특히 이들로부터 원적외선과 음이온의 높은 발산력으로 각종의 냄새나 오염물질을 분해 제거할 수 있도록 양이온 합성수지(수성 아크릴수지)에멀젼 40용량％와 원적외선 파우더(자철광분말 50중량％, 회토류광석분말 25중량％, 목어석분말 25중량％)10용량％ 및 음이온 파우더(제올라이트분말 50중량％, 고령토분말 50중량％)20용량％와 철이온 촉매체인 이미다졸실란 화합물 5용량％와 모자나이트염(전기석분말 50중량％, 모자나이트분말 50중량％)의 혼합물로 소성한 기능성 세라믹분말 15용량％를 순서대로 믹서기에 투입하고 여기에 도료 전체 중량에 소포제 2용량％, 분산제2용량％, 착색제 5용량％ 및 증점제 1용량％를 혼합 믹싱하여 나노철이온 수용액(Fe2O3)을 포함하는 양이온 세라믹 혼합도료의 제조방법에 관한 발명이다.The present invention relates to a method for preparing a chemically active eco-friendly cationic ceramic mixed paint by including a nano-ion aqueous solution (F 2 O 3 ) in the positive ion ceramic paint (Positive ion Ceramic) paints, as well as strong and excellent coating and adhesion In particular, 40% by volume of cationic synthetic resin (aqueous acrylic resin) emulsions and far infrared powders (50% by weight of magnetite powder, 25% by weight of rare earth ore powder) can be used to decompose and remove various odors and contaminants by the high divergence of far infrared rays and anions. 10% by weight, 25% by weight of mudstone powder, 20% by weight of anionic powder (50% by weight of zeolite powder, 50% by weight of kaolin powder), 5% by weight of imidazolesilane compound as an iron ion catalyst, and a capite salt (50 tourmaline powder) 15% by volume of the functional ceramic powder calcined with a mixture of weight% and 50% by weight cinnamon powder was sequentially added to the blender. Anti-foaming agent 2% by volume to the total weight, the dispersing agent 2% by volume, a colorant, 5% by volume and thickeners 1% by volume to the invention relates to a process for the preparation of cation ceramic mixed paint containing the mixture mixed with an aqueous solution nano iron ions (Fe 2 O 3) .
나노철이온 수용액(Fe2O3), 이미다졸실란화합물, 수용성 합성수지(수성아크릴수지), 양이온 합성수지 에멀젼, 수용성 합성수지 고형분, 원적외선파우더, 음이온파우더, 기능성 세라믹 분말Nano iron ion solution (Fe2O3), imidazole silane compound, water soluble synthetic resin (aqueous acrylic resin), cationic synthetic resin emulsion, water soluble synthetic resin solids, far infrared powder, anion powder, functional ceramic powder
Description
본 발명은 나노금속 수용액이 포함된 양이온 세라믹(Positive ion Ceramic)도료에 관한 것으로 좀 더 상세하게는 양이온 세라믹 도료에 복합 나노금속 수용액을 혼합하여 화학적으로 활성인 친환경 양이온 세라믹 도료원료의 혼합물을 얻는 나노철이온 수용액을 포함하는 양이온 세라믹 혼합도료의 제조방법에 관한 것이다.The present invention relates to a positive ion ceramic (Positive ion Ceramic) paint containing a nano-metal solution, and more specifically, to obtain a mixture of chemically active environmentally friendly cationic ceramic paint material by mixing a composite nano-metal solution in a cationic ceramic paint It relates to a method for producing a cationic ceramic mixed paint containing an aqueous solution of iron ions.
종래의 음이온 세라믹(An ion Ceramic)도료들은 소지에 도장하면 피도장 대상물인 소지가 음으로 대전(帶電)되어 있어서 동일한 음이온(An ion)끼리의 반발력(反撥力)에 의한 접착력에 약화로 박리작용과 노화현상이 일어남에 따라 도료막의 기능을 제대로 발휘(發揮)하지 못 할 뿐만 아니라 색상도 쉽게 변색되는 문제점이 있어 왔다.Conventional An ion ceramic paints have a negative effect on the adhesion by the repulsive force between the same anions when they are coated on the substrate. As the phenomenon of aging occurs, not only the paint film does not function properly, but also has a problem of discoloring easily.
또한 살균용 도료들은 인체에 유해한 D.D.T와 같은 독성(毒性)이 강한 화학약품을 살균제에 혼합사용하고 있어서 도료로서 접착기능의 저하와 인체에도 피해를 주는 문제점이 있었다.In addition, disinfectant paints are used to mix strong chemicals, such as D.D.T, harmful to the human body in the disinfectant, there is a problem in the adhesive function degradation and damage to the human body.
본 발명의 목적은 양이온 세라믹 혼합도료를 제공함에 있어서, 도장시의 양호성과 접착력의 강화성 및 도장 된 도료로부터 원적외선과 음이온(An ion)의 발산력을 양호히 하여 살균작용과 탈취기능 및 오염물질을 분해 제거시켜주기 위해 양이온 합성수지 에멀젼과, 수용성 합성수지 고형분, 철이온 촉매제인 이미다졸실린 화합물, 원적외선 파우더, 음이온파우더 및 기능성 세라믹 분말인 세라믹 도료원료의 혼합물로 나노철이온 수용액을 포함하는 양이온 세라믹(Positive ion Ceramic) 혼합도료를 제공하는데 있고, 본 발명의 다른 목적은 나노철이온 수용액 100용량％에 같은량의 비타민 C액 5~10용량％가 존재하는 수용액이 포함되어 화학적으로 활성인 세라믹 도료원료의 혼합물로 나노철이온 수용액을 포함하는 양이온 세라믹 혼합도료를 제공하는데 있다.An object of the present invention is to provide a cationic ceramic mixed paint, to improve the goodness at the time of coating, the reinforcement of adhesion and the divergence of far-infrared rays and anions from the coated paint to improve sterilization, deodorizing function and contaminants. Cationic ceramic (Positive) containing an aqueous solution of nano-iron ion with a mixture of cation synthetic resin emulsion, water-soluble synthetic resin solids, imidazocillin compound as iron ion catalyst, far-infrared powder, anion powder and functional ceramic powder Ion Ceramic) To provide a mixed paint, another object of the present invention is to include the aqueous solution in which the same amount of vitamin C solution 5-10% by volume in 100% by volume of the nano-iron ion aqueous solution of the chemically active ceramic coating material It is to provide a cationic ceramic mixed paint comprising a nano-iron aqueous solution as a mixture.
본 발명의 또 다른 목적은 세라믹 도료원료의 혼합물을 양이온 합성수지 에멀젼과 원적외선 파우더 및 음이온 파우더와 같이 믹서기에 투입하고 여기에 나노철이온 수용액을 혼합하여 믹서 함으로써 나노철이온 수용액을 포함하는 양이온 세라믹 혼합도료를 제공하는데 있다.
본 발명의 또 다른 목적은 세라믹 도료의 혼합물로는 합성수지(예를 들면, 수용성 아크릴수지, 알키드수지, 실리콘수지, 불소수지, S.B.R 라텍스)와 이미다졸 실란화합물(Au, Ce, Mn, Ag Ct, Pt, 제올라이트, 아민계촉매)이 나노 상태로 존재하는 음이온 파우더와, 불순물의 제거용인 모자나이트염(전기석 분말, 모자나이트 분말)의 화합물을 소성한 기능성 세라믹 분말 및 원적외선 파우더(흑체 세라믹 = 코디에라이트, MnO2, Fe2O3, CuO2, CoO, 카오린, 제올라이트, 바인더)를 세라믹 도료원료의 혼합물로 사용할 수 있도록 하는데 있다.Still another object of the present invention is to add a mixture of ceramic paint material into a blender such as a cationic synthetic resin emulsion, a far infrared powder and an anion powder, and then mix and mix the aqueous solution of nano-iron ions to the mixed-cationic ceramic mixed paint including a nano-ion solution. To provide.
Still another object of the present invention is a mixture of ceramic paints such as synthetic resins (eg, water-soluble acrylic resins, alkyd resins, silicone resins, fluorine resins, SBR latex) and imidazole silane compounds (Au, Ce, Mn, Ag Ct, Functional ceramic powders and far-infrared powders (black body ceramics = Codye) obtained by firing compounds of anionic powders in which Pt, zeolites, and amine catalysts are present in a nano state, and a capite salt (a tourmaline powder, a capite powder) for removing impurities Lite, MnO 2 , Fe 2 O 3 , CuO 2 , CoO, Kaolin, Zeolite, Binder) can be used as a mixture of ceramic paint materials.
본 발명은 상기와 같은 종래의 문제점을 해소하고 목적 달성에 현저한 효과를 구현하기 위해 발명한 것으로서 상기의 기능성 세라믹 도료원료의 혼합물들은 본 발명에 적용되는 것 외에도 여러 가지 특이한 목적으로 사용이 가능하고 또 음이온 도료에도 적용을 용이하게 할 뿐만 아니라 특히 세라믹 혼합도료에 포함되는 이미다졸실란 화합물은 화학적으로 다양한 종류의 활성을 나타내고 있는데 이는 비타민 C액의 존재하에 있어서 나노철이온 작용에 의하여 철이온과 접촉되는 분자상태의 산소가 원래의 분자상태의 산소보다 산화력(酸化力)이 강한 슈퍼옥시드(Super Oxid)(O2) 로 변화하기 때문에 세라믹 혼합도료의 포함을 용이 하는 것이다.
따라서 본 발명은 나노철이온 수용액이 포함되고 화학적으로 활성인 수용성 합성수지와 아크릴수지 및 에폭시 수지 등의 수용성 합성수지인 에멀젼과; 철이온 촉매제인 이미다졸실란 화합물과: 산화류 계통의 세라믹광석을 소성하여 원적외선이 93％이상 방출되는 원적외선 파우더(흑체 세라믹)및 촉매 및 광물류의 화합물을 1200℃이상으로 소성한 음이온 파우더와; 모자나이트염의 화합물을 소성한 기능성 세라믹 분말을 순서대로 믹서기에 투입하고 여기에 도료 전체 중량에 소포제, 분산제, 착색제, 증점제를 혼합 믹싱하여 원적외선과 음이온 및 철이온의 방출로 살균과 탈취기능과 오염물질을 분해 제거시켜 주는 세라믹 도료원료의 혼합물로서 상기의 에멀젼은 수용성 합성수지인 고형분을 PH10에 대해 알킬베타인형 양성계면 활성제를 믹서기로 투입 믹싱하고 알킬아민 에폴리오키시 에틸렌을 결합한 양이온계면 활성제를 혼합하여 완전히 분산한 후 염산 또는 초산을 주입시켜 PH3을 PH2로 낮춘 수용성 합성수지와, 아크릴수지 및 에폭시수지인 세라믹 도료원료의 혼합물인 것과; 상기의 이미다졸실란 화합물은 Au촉매, Mn촉매, Cu촉매, Pt촉매, Ct촉매, 제올라이트촉매, 아민계촉매, Ag촉매를 믹서기에 차례로 투입 믹싱하여 얻은 높은 활성의 세라믹 도료원료의 혼합물인 것과; 상기의 원적외선 파우더는 코디에라이트(2MgO, 2Al2O3, 5SiO2), MnO2분말, Fe2O3분말, CuO2, 카오린(Al2O3가 38％이상인 것), 제올라이트, 바인더를 상온에서 건조 후 소성로에 넣고 1000~1200℃의 고온에서 10시간 소성하여 400~600메쉬로 분쇄 냉각 시킨 세라믹 도료원료의 혼합물인 것과; 상기의 음이온 파우더는 카오린(Al2O3가 38％이상인 것),제올라이트, 벤토나이트, 바인더를 혼합 믹싱하여 성형하고 상온에서 건조 후 1300~1500℃의 고온에서 소성시켜 325~400메쉬로 분쇄 냉각 시킨 제올라이트 및 고령토를 1200℃이상 소성한 세라믹 도료원료의 혼합물인 것과; 상기의 기능성 세라믹 분말은 불순물이 제거된 모자나이트염을 소성한 세라믹 도료원료의 혼합물로 나노철이온 수용액을 포함하는 양이온 세라믹 혼합도료를 제조함으로써 실내환경의 향상과 향균 및 탈취기능은 물론 오염물질을 분해하여 제거하는 작용도 매우 높이하고 화학적으로 활성인 혼합도료를 제조할 수 있음을 특징으로 한다.The present invention has been invented to solve the above-mentioned problems and to implement a remarkable effect in achieving the object, the mixture of the functional ceramic paint material can be used for various specific purposes in addition to being applied to the present invention In addition to facilitating application to anionic paints, especially imidazolesilane compounds in ceramic mixed paints exhibit various types of activity, which are in contact with iron ions by nanoiron ion in the presence of vitamin C solution. Since the oxygen in the molecular state is changed to Super Oxid (O 2 ), which is more oxidizing than the oxygen in the original molecular state, it is easy to include the ceramic mixed paint.
Therefore, the present invention is an emulsion containing a water-soluble synthetic resin, such as a water-soluble synthetic resin and chemically active water-soluble synthetic resin and epoxy resin containing a nano-iron aqueous solution; An imidazole silane compound which is an iron ion catalyst and: an far infrared powder (black body ceramic) which emits more than 93% of far infrared rays by firing an oxide-based ceramic ore, and an anionic powder which calcinates a compound of a catalyst and minerals at 1200 ° C. or higher; The functional ceramic powder calcined with the cadmium salt is added to the blender in order, and the antifoaming agent, dispersant, colorant, and thickener are mixed and mixed with the total weight of the paint to sterilize, deodorize, and pollutants by releasing far infrared rays, anions and iron ions. The above emulsion is a mixture of ceramic paint raw materials that decomposes and removes the solids, which are water-soluble synthetic resins, by mixing and mixing alkylbetaine-type amphoteric surfactants with a blender to PH 10 and mixing cationic surfactants with alkylamine ethoxykisiethylene. and water-soluble synthetic resin and then completely dispersed by injecting hydrochloric acid or acetic acid to lower the PH 3 to PH 2, an acrylic resin and an epoxy resin is a ceramic coating that is a mixture of raw materials; The imidazole silane compound is a mixture of a highly active ceramic paint material obtained by sequentially mixing and mixing an Au catalyst, a Mn catalyst, a Cu catalyst, a Pt catalyst, a Ct catalyst, a zeolite catalyst, an amine catalyst, and an Ag catalyst in a mixer; Said far-infrared powder is cordierite (2MgO, 2Al 2 O 3 , 5SiO 2 ), MnO 2 powder, Fe 2 O 3 powder, CuO 2 , kaolin (Al 2 O 3 is 38% or more), zeolite, binder After drying at room temperature and put in a kiln for 10 hours at a high temperature of 1000 ~ 1200 ℃ and a mixture of ceramic paint raw material which was pulverized and cooled to 400 ~ 600 mesh; The anionic powder is mixed by mixing kaolin (with more than 38% of Al 2 O 3 ), zeolite, bentonite, and binder, and dried at room temperature, calcined at a high temperature of 1300 ~ 1500 ° C, and then pulverized and cooled to 325 ~ 400 mesh. Zeolite and kaolin are mixtures of ceramic coating materials calcined at 1200 ° C. or higher; The functional ceramic powder is a mixture of ceramic paint materials calcined with a capite salt, in which impurities are removed, to produce a cationic ceramic mixed paint containing an aqueous solution of nano-iron ions, thereby improving indoor environment, antibacterial and deodorizing functions, and contaminants. Decomposition and removal is also very high and is characterized in that it is possible to produce a chemically active mixed paint.
이하 본 발명의 구성을 실시예에 의거 상세히 설명한다.Hereinafter will be described in detail with reference to the configuration of the present invention.
나노철이온 수용액이 포함되고 화학적으로 활성인 양이온 합성수지 에멀젼 40용량％와, 철이온 촉매제인 이미다졸실란 화합물 5용량％와, 산화류계통의 세라믹 광석을 소성하여 원적외선 93％이상 방출되는 원적외선 파우더(흑체 세라믹)10용량％와, 촉매 및 광물류 계통의 화합물을 1200℃ 이상으로 소성한 음이온 파우더 20용량％와, 모자나이트염의 화합물을 소성한 기능성 세라믹 분말 15용량％를 순서대로 믹서기에 투입하고 도료 전체 중량에 대해 소포제 2용량％, 분산제 2용량％ 착색제 5용량％, 증점제 1용량％를 혼합 믹싱하여 원적외선과 음이온 및 철이온의 방출로 살균과 탈취기능을 향상시키는 세라믹 도료원료의 혼합물로서 상기의 에멀젼은 수용성 합성수지 고형분 30용량％인 PH10에 대해 알킬베타인형 양성계면 활성제를 1.5용량％을 믹서기로 투입 믹싱하고 알킬아민 에폴리오키시 에틸렌 3.0용량％을 결합한 양이온 계면활성제 8.5용량％을 혼합하여 완전히 분산한 후 염산 또는 초산 17용량％를 주입시켜 PH3을 PH2로 낮춘 수용성 합성수지 및 에폭시수지인 세라믹 도료원료의 혼합물인 것과; 상기의 이미다졸실란 화합물은 Au촉매 7.0용량％, Ce촉매 8.0용량％, Cu촉매 15용량％, Mn촉매 10용량％, 제올라이트촉매 10용량％, Pt촉매 8.0용량％, Ct촉매 7.0용량％, Ag촉매 20용량％, 아민계촉매 15용량％를 순서대로 믹서기에 투입 믹싱하여 얻은 높은 활성의 세라믹 도료원료의 혼합물인 것과; 상기의 원적외선 파우더는 코디에라이트(2MgO, 2Al2O3, 5SiO2)15용량％와, MnO2분말 10용량％, Fe2O3분말 10용량％, CuO 10용량％, CoO 10용량％, 제올라이트 10용량％, 카오린(Al2O3가 38％이상인 것)20용량％ 및 바인더 15용량％를 상온에서 건조 후 소성로에 넣고 1000~1200℃의 고온에서 10시간 소성하여 400~600메쉬로 분쇄 냉각시킨 세라믹 도료원료의 혼합물인 것과; 상기의 음이온 파우더는 카오린(Al2O3가 38％이상인 것)20용량％와 제올라이트 10용량％, 벤토나이트 55용량％에 바인더 15용량％를 혼합 믹싱하여 성형하고 상온에서 건조 후 1300~1500℃의 고온에서 소성시켜 325∼400메쉬로 분쇄 냉각시킨 제올라이트 및 고령토를 1200℃ 이상 소성한 세라믹 도료원료의 혼합물인 것과; 상기의 기능성 세라믹분말은 전기석분말 30용량％와, 향화석 분말 20용량％ 및 맥화석분말 50용량％인 모자나이트염의 화합물을 소성한 세라믹 도료원료의 혼합물로 나노철이온 수용액을 포함하는 양이온 세라믹 혼합도료를 제조하였다.Far-infrared powder containing 40 vol.% Of a chemically active cation synthetic resin emulsion, 5 vol.% Of an imidazole silane compound, which is an iron ion catalyst, and an oxide-based ceramic ore by firing an aqueous solution of nano-iron ion. Black body ceramic) 10 volume%, 20 volume% of anion powder calcined catalyst and mineral compounds at 1200 ° C or higher, and 15 volume% functional ceramic powder calcined compound of a hatnitite salt were added to the blender in order. The above-mentioned emulsion as a mixture of ceramic coating material which improves sterilization and deodorization function by mixing and mixing 2% by volume of antifoam, 2% by volume, 5% by volume of colorant, and 1% by volume of thickener by weight. mixer is 1.5 vol.% of the alkyl beta doll amphoteric surfactants for the water-soluble resin having a solid content of 30% by volume of PH 10 In mixing and then completely dispersed by mixing polio shi ethylene 3.0 vol.% Of the cationic surface active agent 8.5 vol.% Of a combination of an alkyl amine was injected with hydrochloric acid or acetic acid 17% by volume of water-soluble synthetic resin and an epoxy resin to lower the PH 3 to PH 2 in the Being a mixture of ceramic paint raw materials; Said imidazole silane compound is 7.0 vol% Au catalyst, 8.0 vol% Ce catalyst, 15 vol% Cu catalyst, 10 vol% Mn catalyst, 10 vol% zeolite catalyst, 8.0 vol% Pt catalyst, 7.0 vol% Ct catalyst, Ag 20% by volume of catalyst and 15% by volume of amine catalyst as a mixture of highly active ceramic coating materials obtained by input mixing to a mixer; The far-infrared powder is cordierite (2MgO, 2Al 2 O 3, 5SiO 2) 15 % by volume and, MnO 2 powder 10 vol%, Fe2O3 powder 10 vol%, CuO 10% by volume, CoO 10% by volume, zeolite 10 vol %, Kaolin (with Al 2 O 3 38% or more) and 20% by volume of binder and 15% by volume of binder were dried at room temperature, put into a firing furnace and fired at a high temperature of 1000-1200 ° C for 10 hours, and then pulverized and cooled to 400-600 mesh. Being a mixture of paint raw materials; The anionic powder is mixed by mixing 20% by volume of kaolin (having Al 2 O 3 of 38% or more), 10% by volume of zeolite, and 55% by volume of bentonite to 15% by volume of binder, and dried at room temperature, and then dried at room temperature of 1300 to 1500 ° C. It is a mixture of the ceramic coating material which baked at 1200 degreeC and calcined zeolite and kaolin which were baked at high temperature and pulverized and cooled to 325-400 mesh; The functional ceramic powder is a mixture of a 30% by weight tourmaline powder, a ceramic coating material calcined with a compound of a hatnitite salt of 20% by volume of fennel stone powder and 50% by volume of calcite powder. The paint was prepared.
이와 같이 제조된 상기의 양이온 세라믹 혼합도료는 원적외선을 비롯하여 음이온과 향균 및 탈취기능에 대한 측정시험을 한국건자재 시험연구소에 의뢰하여 실시한 결과는 아래의 ＜표＞와 같다.The cationic ceramic mixed paint prepared as described above was subjected to a measurement test for anion, antibacterial, and deodorizing function including far-infrared light from the Korea Institute of Construction Materials.
[표 1]
원적외선
Far Infrared
상기 [표1]에 의한 원적외선 측정시험은 FT-IR Spectrometer(분광계)를 BLACK BODY 대비측정한 것이다.Far-infrared measurement test according to the above [Table 1] is to measure the FT-IR Spectrometer (spectrometer) compared to BLACK BODY.
[표 2]
음이온
Negative ion
상기 [표2]에 의한 음이온 측정시험은 KCM-FIR-1042, 시험편은 내경44(㎜), 높이 297(㎜)의 원기둥-12.1g의 전하입자 측정장치를 이용하여 온도 21℃, 습도 42％, 대기중 음이온수 73/CC조건에서 시험하였으며, 측정대상물에서 방출되는 음이온을 측정하여 단위체적당 10N수(이온水)로 표시한 것이다.The anion measurement test according to the above [Table 2] is KCM-FIR-1042, the test piece is a temperature of 21 ℃, 42% humidity by using a charge particle measuring device of a cylinder-12.1g of inner diameter 44 (mm), height 297 (mm) It was tested under the condition of 73 / CC anion water in the air. The anion released from the object was measured and expressed as 10N water per unit volume.
[표 3]
항균
Antibacterial
상기 [표3]에 의한 사용균주 Escherichia Coli ATCC 25922, Pseudomans aeruginosa ATCC 15442로 측정한 것이다.Using the strain Escherichia Coli ATCC 25922, Pseudomans aeruginosa ATCC 15442 according to the above [Table 3].
[표 4]
탈취
Deodorization
상기 [표4]에 의한 탈취측정 시험은 Blank(시료를 넣지 않은 상태로 측정)을 시험편 40×40×10(㎜)로 시험방법은 KICM-FIR-1085로 측정한 것이다.Deodorization test according to the above [Table 4] is a blank (measured in the state of no sample) test piece 40 × 40 × 10 (㎜) test method is measured by KICM-FIR-1085.
상기 [표1]~[표4]에 의한 시험결과를 요약해 보면 파워세라믹 기능성 도료(GLOBAL CATION GP ＃100)를 대장균(Escherichia Coli ATCC 25922)과 녹농균(Pseudomans aeruginosa ATCC 15442)에 대하여 세균감소율을 시험한 결과 대장균의 경우 BLANK는 24시간후 균수가 증가하였고, 파워세라믹 기능성 도료는 24시간후의 균수가 감소하여 99.7％의 세균감소율을 보였다.Summarizing the test results according to the above [Table 1] to [Table 4], the reduction rate of bacteria for the power ceramic functional paint (GLOBAL CATION GP # 100) for E. coli (Escherichia Coli ATCC 25922) and Pseudomans aeruginosa ATCC 15442) As a result, BLANK increased the number of bacteria after 24 hours and E. coli showed a 99.7% bacterial reduction rate after 24 hours.
한편 녹농균의 경우는 BLANK는 24시간 후 균수가 증가하였고, 파워세라믹 기능성 도료는 24시간 후 균수가 감소하여 99.7％의 세균감소율을 보였다.In the case of Pseudomonas aeruginosa, BLANK increased in number of bacteria after 24 hours, and power ceramic functional paints decreased in number of bacteria after 24 hours, resulting in 99.7% bacterial reduction.
이하 실시 예에 의하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the following examples.
{실시예 1}{Example 1}
음이온과 원적외선을 다량으로 방출하는 양이온 세라믹 도료는 H2O 20㎏과, 소포제(N-44S=일산)0.1㎏, 분산제(267-A=일산)0.2㎏에 모자나이트분말과 전기석분말과, 전기석분말의 음이온 파우더 12.1kg과, TiO2 10kg 및 원적외선을 다량으로 방출하는 세라믹 광석을 소성하여 분쇄한 원적외선 파우더 5kg을 믹서기로 투입 믹싱시켜 주면서 여기에 수성수지를 양이온화한 양이온 합성수지 에멀젼 40kg과, 철(Fe), 구리(Cu), 망간(Mn), 질소(N), 칼륨(K), 인(P), 황(S), 아연(Zn), 칼슘(Ca) 등의 원소를 이원화한 나노철이온 수용액 12kg과, 응착제(TEXnol)0.2kg을 믹서기로 투입하여 30분간 고속으로 믹싱시킨 혼합물 0.2kg을 증점제(9532=독일산)0.2kg으로 점도 조절하여 양이온 세라믹 혼합도료를 포장 제조하였다.Cationic ceramic paints that emit large amounts of anions and far infrared rays include 20 kg of H 2 O, 0.1 kg of antifoaming agent (N-44S = nitric acid), 0.2 kg of dispersant (267-A = nitric acid), and agateite powder, tourmaline powder, and tourmaline 12.1 kg of anionic powder of powder, 10 kg of TiO 2 , and 5 kg of far-infrared powder pulverized by firing and sintering ceramic ore that emits a large amount of far-infrared rays were mixed with a blender, and 40 kg of cationic synthetic resin emulsion, in which an aqueous resin was cationized, and iron Nanostructured elements such as (Fe), copper (Cu), manganese (Mn), nitrogen (N), potassium (K), phosphorus (P), sulfur (S), zinc (Zn) and calcium (Ca) 12 kg of an aqueous iron ion solution and 0.2 kg of an adhesive (TEXnol) were added to a blender to prepare a cationic ceramic mixed paint by adjusting a viscosity of 0.2 kg of the mixture mixed at high speed for 30 minutes with a thickener (9532 = Germany) of 0.2 kg.
따라서 산소의 폭(幅)도 주변보다 음이온(An ion)이 더 많다.Therefore, the width of oxygen also has more anions than the surroundings.
{실시예 2}{Example 2}
양이온 세라믹 살균도료는 양이온 합성수지 25㎏을 믹서기로 투입 믹싱시키면서 소포제(N-44S=일산)0.2kg과 분산제(267-A=일산)0.2kg, 원적외선 파우더 14kg, 음이온 파우더 10kg, 나노철이온 수용액 20kg을 순서대로 믹서기로 투입하여 30분간 믹싱한 후 다시 음이온 파우더 30kg과 응착제(TEXnol)0.2kg을 투입시켜 5분간 믹싱시킨 혼합물 0.2kg을 증점제(9532=독일산)0.2kg으로 점도 조절하여 양이온 세라믹 혼합도료를 포장 제조하였다.The cationic ceramic disinfectant paint is mixed with 25 kg of cationic synthetic resin with a blender while mixing 0.2 kg of antifoaming agent (N-44S = Ilsan) and 0.2 kg of dispersant (267-A = Ilsan), 14 kg of far-infrared powder, 10 kg of anion powder, 20 kg of nano iron ion solution To the mixer in order to mix for 30 minutes, and then 30kg of anion powder and 0.2kg of adhesive (TEXnol) were added to mix 0.2kg of the mixed mixture for 5 minutes with a viscosity of 0.2kg thickener (9532 = German) and cationic ceramic. The mixed paint was packaged.
{실시예 3}{Example 3}
양이온 탄성 세라믹 다체무늬 도료는 H2O 15㎏과 소포제(N-44S=일산)0.5㎏, 분산제(267-A=일산)0.3㎏, TiO2 20㎏ 및 합성수지 라텍스(S.B.R=Styrene-Butadiene Rubber=금호석유제품)양이온(수성 아크릴)수지 20㎏을 혼합하여 믹서기에 넣고 저속 믹싱하면서 양이온 알키드수지 15㎏과 원적외선 파우더 5㎏, 음이온 파우더 8.2㎏, 나노철이온 수용액 15.44㎏ 및 소포제(NOPCO-NDW)0.2㎏을 투입하고 30분간 고속으로 믹싱시켜 응착제(TEXnol)0.2kg을 증점제(9532=독일산)0.2kg으로 점도 조절하여 양이온 세라믹 혼합도료를 포장 제조하였다.The cationic elastic ceramic body pattern paint is 15 kg of H 2 O, 0.5 kg of antifoaming agent (N-44S = monic acid), 0.3 kg of dispersant (267-A = monic acid), 20 kg of TiO 2 and synthetic latex (SBR = Styrene-Butadiene Rubber = Kumho Petroleum Products) 20 kg of cationic (aqueous acrylic) resin is mixed into a blender and mixed at low speed while mixing at low speed with 15 kg of cationic alkyd resin, 5 kg of far-infrared powder, 8.2 kg of anion powder, 15.44 kg of nano-iron ion solution and antifoaming agent (NOPCO-NDW) 0.2 kg was added and mixed at high speed for 30 minutes to adjust the viscosity of 0.2 kg of the adhesive (TEXnol) to 0.2 kg of a thickener (9532 = Germany), thereby preparing a cationic ceramic mixed paint package.
이렇게 포장 제조된 양이온 세라믹 혼합도료는 인테리어(Interior) 및 벽지(壁紙)대용으로 벽에 도포하여 사용할 경우 원적외선과 음이온(An ion)의 방출(放出)로 살균과 탈취는 물론 유해전자파차단과 공기를 정화시키는 기능이 뛰어나다.The cationic ceramic mixed paint packaged in this way is applied to the wall for interior and wallpaper, so that it can be sterilized and deodorized due to the emission of far infrared rays and anions, as well as blocking harmful electromagnetic waves and air. Excellent cleansing function
{실시예 4}{Example 4}
양이온 세라믹 기능성 도료는 믹서기에 H2O 6㎏과 소포제(N-44S=일산)0.2kg, 분산제(267-A=일산)0.2kg, TiO2 16㎏ 및 양이온(수성아크릴)수지 41㎏을 투입 믹싱하여 완전히 분산한 후 알루미나 실리게이트(Alumina Silicate)15㎏과 탄소섬유 파우더 15㎏, 나노철이온 수용액 6㎏, 소포제(NOPCO-NDW)0.2㎏ 및 응착제(TEXnol)0.2kg을 서서히 투입하여 30분간 믹싱하고 증점제(9532=독일산)를 0.2kg으로 점도 조절하여 양이온 세라믹 혼합도료를 포장 제조함으로써, 차열(遮熱)과 보온(保溫) 및 결로(結露) 등을 방지하는 도료를 얻었다.In the cationic ceramic functional paint, 6 kg of H 2 O, 0.2 kg of antifoaming agent (N-44S = monoacid), 0.2 kg of dispersant (267-A = monoacid), 16 kg of TiO 2 and 41 kg of cationic (aqueous acrylic) resin were added to the blender. After mixing and dispersing completely, 15 kg of alumina silicate, 15 kg of carbon fiber powder, 6 kg of nanoiron ion solution, 0.2 kg of antifoaming agent (NOPCO-NDW) and 0.2 kg of adhesive (TEXnol) were added slowly. By mixing for a minute and adjusting the viscosity of the thickener (9532 = German) to 0.2 kg to prepare a cationic ceramic mixed paint, a coating material was obtained to prevent heat shielding, heat retention, condensation, and the like.
상기 도료의 열전도율(熱傳導率)을 시험한 결과는 [표5]와 같다.The results of testing the thermal conductivity of the paint are shown in Table 5.
[표 5]
{실시예 5}{Example 5}
수성 에폭시 양이온 세라믹(Positive ion Ceramic)도료는 H2O 15㎏과, 소포제(N-44S=일산)0.2kg, 분산제(267-A=일산)0.2kg, TiO2 15㎏ 및 양이온 수성에폭시 40㎏을 혼합하여 투입기에 넣고 완전히 분산한 후 기능성 세라믹 파우더 12.26㎏과 전기석분말 6.2㎏, 나노철이온 수용액 10.44㎏에 소포제(NOPCO-NDW) 0.2kg과 응착제(TEXnol)0.2kg을 서서히 투입하여 30분간 고속 믹싱하고 증점제(9532=독일산)0.3kg으로 점도 조절하여 양이온 세라믹 혼합도료를 포장 제조한 도료로서 수처리조(水處理槽) 및 APT 지하조(地下槽) 또는 양어장 등에 응용 가능하고, 또 물을 전기분해(電氣分解)하여, 물이끼의 클리닉과 물의 활성화(活性化) 기능도 제공하는 도료를 얻었다.Aqueous epoxy cationic ceramic paint contains 15 kg of H 2 O, 0.2 kg of antifoaming agent (N-44S = monoacid), 0.2 kg of dispersant (267-A = monoacid), 15 kg of TiO 2 and 40 kg of cationic aqueous epoxy. After mixing the mixture into the feeder and dispersing it completely, 12.26kg of functional ceramic powder, 6.2kg of tourmaline powder, 10.44kg of nanoiron ion solution were slowly added 0.2kg of defoamer (NOPCO-NDW) and 0.2kg of adhesive (TEXnol) for 30 minutes. It is a high-speed mixing, viscosity-adjusting agent (9532 = German), 0.3kg, packaged and manufactured with a cationic ceramic mixed paint, which can be applied to water treatment tanks, APT underground tanks, or fish farms. Was electrolyzed to obtain a paint that also provided a clinic of water moss and a water activating function.
{실시예 6}{Example 6}
양이온(수성 아크릴)수지 70중량％에 나노철이온 수용액 30중량％을 혼합하여 기능성 양이온 합성수지를 제조하고, 원적외선 세라믹 80~100목 50중량％에 백시멘트 43중량％와 산화크롬 5.5중량％ 및 시멘트 강도제(强度制) 0.5중량％, 분산제 0.5중량％, 셀프레벨링 파우더(Self-Leveling Powder)0.5중량％를 혼합 믹싱하여 바이오 세라믹(Bio Ceramic Powder)를 제조한 후, 상기의 양이온 합성수지 30중량％와 상기 바이오 세라믹 파우더 60중량％ 및 물 10중량％을 혼합시켜 공사현장에서 직접 믹서하여 시멘트가 포함된 양이온 세라믹 혼합도료를 제조하였다.70 wt% of cationic (aqueous acrylic) resin was mixed with 30 wt% of an aqueous solution of nanoiron ions to prepare a functional cationic synthetic resin, and 50 wt% of far-infrared ceramics, 50 wt% of white cement, 5.5 wt% of chromium oxide, and cement After mixing and mixing 0.5 wt% of the strength agent, 0.5 wt% of the dispersant, and 0.5 wt% of the self-leveling powder, 30 wt% of the above cationic synthetic resin was prepared. And 60 wt% of the bio-ceramic powder and 10 wt% of water were mixed directly at a construction site to prepare a cationic ceramic mixed paint including cement.
이와 같이 시멘트가 포함된 양이온 세라믹 혼합도료는 건물의 내외벽과 바닥 및 옥상 등에 몰탈에어리스로 스프레이하여 간단히 시공할 수 있고, 또 원적외선과 음이온 방출로 탈취, 살균작용은 물론 공기를 정화시켜 줌에 따라 장기간에 걸친 청결도와 신선도 및 안전도를 오래 유지할 수 있다.As such, the cationic ceramic mixed paint containing cement can be easily installed by spraying mortar airless on the inside and outside walls, floors, and rooftops of buildings, and deodorizing, disinfecting, and purifying air by emitting far infrared rays and anions. Long-term cleanliness, freshness and safety can be maintained for a long time.
{실시예 7}{Example 7}
H2O 15㎏과 소포제(N-44S=일산)0.2㎏, 분산제(267-A=일산)0.2㎏, TiO2 20㎏을 혼합하고 믹서기로 투입시켜 완전히 분산한 후 양이온 합성수지 라텍스(S.B.R=금호석 유제품)30㎏을 투입한 후 다시 음이온 세라믹 파우더(An ion Ceramic Powder) 25㎏과 탄소파우더(Carbon Powder) 8.9㎏에 소포제(NOPCO-NDW)0.2㎏을 서서히 투입하면서 30분간 고속으로 믹싱시켜 응착제(TEXnol)0.2kg을 증점제(9532=독일산)0.3kg으로 점도 조절하여 양이온 세라믹 혼합도료를 포장 제조함으로써 옥상 슬라브용 노출방수제로도 사용을 가능케 하였다.15 kg of H 2 O, 0.2 kg of antifoaming agent (N-44S = Ilsan), 0.2 kg of dispersant (267-A = Ilsan), and 20 kg of TiO 2 were mixed and completely dispersed by mixing in a blender, followed by cationic synthetic resin latex (SBR = Kumho). 30 kg of petroleum products were mixed, and then 25 kg of anion ceramic powder and 8.9 kg of carbon powder were slowly mixed with 0.2 kg of antifoaming agent (NOPCO-NDW) and mixed at high speed for 30 minutes. By adjusting the viscosity of 0.2 kg of the agent (TEXnol) with 0.3 kg of thickener (9532 = Germany), the cationic ceramic mixed paint was packaged to enable use as an exposure waterproofing agent for rooftop slabs.
이상에서 설명한 본 발명은 전술한 바와 같은 상세한 설명 및 실시예에 의하여 한정되는 것은 아니고 하기의 특허청구범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 해당기술분야의 당업자가 다양하게 수정 및 변형시킨 것 또한 본 발명의 범위 내에 포함됨은 물론이다.The present invention described above is not limited to the detailed description and examples as described above, and various modifications and changes made by those skilled in the art without departing from the spirit and scope of the present invention described in the claims below. Modifications are also included within the scope of the invention.
상기와 같은 방법으로 제조되는 양이온 세라믹 혼합도료는 양이온 합성수지 에멀져과, 이미다졸실란 화합물(철이온 촉매제) 및 원적외선 파우더(흑체 파우더), 음이온 파우더, 기능성 세라믹분말 순으로 혼합하여 제조함으로써 강력한 접착제에 의한 시공물의 하자발생을 방지하고 나노철이온 수용액을 도료에 혼합하여 장기간에 걸친 신선도와 음이온 및 원적외선의 방출로 공기의 정화작용을 높이 함으로서 환경을 쾌적하게 하는 효과가 있다.The cationic ceramic mixed paint prepared by the above method is prepared by mixing a cationic synthetic resin emulsion, an imidazole silane compound (iron ion catalyst), and a far infrared powder (black body powder), an anionic powder, and a functional ceramic powder. It prevents the occurrence of defects in the construction and mixes the aqueous solution of nano-iron ion to the paint to enhance the air purification effect by the release of freshness and anion and far-infrared radiation over a long period of time to make the environment comfortable.
또한 음이온 세라믹에 의한 높은 단열성과 음이온(An ion)의 방출(放出)로 건물의 외부로 시공할 경우 각종 유해물질의 분해(分解)도 쉽게 처리하여 주는 효과도 있다.In addition, the high thermal insulation by the anion ceramics and the release of anions (an ion) when the construction of the exterior of the building also has the effect of easily disassembling (harmful) of various harmful substances.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR19980068912A (en) * | 1997-02-25 | 1998-10-26 | 송병환 | Method for manufacturing antifouling and antifouling paints |
| KR20030017218A (en) * | 2001-08-24 | 2003-03-03 | (주)나눅스 | Water dispersible polyurethane emulsion for coating with ultraviolet blocking effect and moth repellency |
| JP2003172009A (en) | 2001-09-25 | 2003-06-20 | Fujimoto Tosoten:Kk | Wall facing construction method |
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| KR19980068912A (en) * | 1997-02-25 | 1998-10-26 | 송병환 | Method for manufacturing antifouling and antifouling paints |
| KR20030017218A (en) * | 2001-08-24 | 2003-03-03 | (주)나눅스 | Water dispersible polyurethane emulsion for coating with ultraviolet blocking effect and moth repellency |
| JP2003172009A (en) | 2001-09-25 | 2003-06-20 | Fujimoto Tosoten:Kk | Wall facing construction method |
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| KR100900475B1 (en) | 2008-11-05 | 2009-06-03 | 박기봉 | Thereof manufacturing method and paints containing a muyustone |
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