KR100633243B1 - The functional wallpaper coated natural composite minerals - Google Patents

The functional wallpaper coated natural composite minerals Download PDF

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KR100633243B1
KR100633243B1 KR1020060069374A KR20060069374A KR100633243B1 KR 100633243 B1 KR100633243 B1 KR 100633243B1 KR 1020060069374 A KR1020060069374 A KR 1020060069374A KR 20060069374 A KR20060069374 A KR 20060069374A KR 100633243 B1 KR100633243 B1 KR 100633243B1
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South Korea
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natural
wallpaper
mineral
mixed
friendly
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KR1020060069374A
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Korean (ko)
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김순호
성진경
김태영
권지숙
이상진
하재성
강창수
김재준
조근행
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주식회사 대동이엔씨
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    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/0082—Wall papers
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/38—Coatings with pigments characterised by the pigments
    • D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/36—Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18—Paper- or board-based structures for surface covering
    • D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/22—Fungicidal, bactericidal, insecticidal, disinfecting, antiseptic, or corrosion-inhibiting paper antistatic, antioxygenic paper

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Paper (AREA)

Abstract

A method for manufacturing functional wall paper containing a natural complex mineral is provided to prevent indoor air pollution due to finish wall paper used in an apartment house and on an indoor wall surface by mixing an environment-friendly mineral with wall paper, and realize an environment-friendly room by emitting negative ion good for the human body. 3A 0-45% of a filler including a natural complex mineral and a 55-70% of an environment-friendly binder aqueous solution are mixed with each other in an emulsion state. The mixed solution is coated on wall paper on which a watersoluble PVC(PolyVinyl chloride) is gelated. The filler is manufactured by mixing natural complex mineral powder having a grade scale in the range from 5 to 20mum by a ball-milling method, wherein a ratio of ball to powder is 10:1 and the natural complex mineral is mixed for 30 minutes at 150-200rpm of ballmill.

Description

천연복합광물질을 함유하는 기능성 벽지 제조방법{The functional wallpaper coated natural composite minerals}The functional wallpaper coated natural composite minerals

도 1은 본 발명에 따른 천연복합광물질을 함유하는 기능성 벽지의 제조 공정도,1 is a manufacturing process diagram of a functional wallpaper containing a natural composite mineral according to the present invention,

도 2는 본 발명에 따른 천연복합광물질을 함유하는 기능성 벽지의 코팅 단면도,2 is a cross-sectional view of a coating of a functional wallpaper containing a natural composite mineral according to the present invention;

본 발명은 천연광물질을 이용한 친환경 기능성 벽지 제조방법에 관한 것으로, 더욱 상세하게는 제올라이트, 규조토, 황토, 활성탄, 음이온석, 이산화티탄 등과 같은 천연기능성 광물질을 포함하는 충전제(filler)와 친환경바인더(Binder) 수용액이 에멀젼 상태의 액상형으로 혼합된 조성물을 수용성PVC가 겔화된 벽지 위에 탑코팅 및 엠보처리 하여 인체에 유익한 음이온 발생기능, 원적외선 방사기능, 휘발성 유기화합물(VOCs) 및 포름알데히드 흡착, 분해기능을 갖는 기능성 벽지를 제공하고자 한다.The present invention relates to a method for manufacturing an environmentally friendly functional wallpaper using natural minerals, and more particularly, a filler and an environmentally friendly binder including natural functional minerals such as zeolite, diatomaceous earth, loess, activated carbon, anion stone, titanium dioxide, and the like. ) Top-coating and embossing the composition mixed with aqueous solution in emulsion form on the gel-walled wallpaper with water-soluble PVC provides anion generation, far-infrared radiation, volatile organic compounds (VOCs) and formaldehyde adsorption, It is intended to provide a functional wallpaper having.

일반적으로 벽면 마감재의 일부인 벽지는 패턴과 재질이 다양하므로 인테리 어 내장재로서 빼놓을 수 없는 중요한 역할을 한다.In general, wallpaper, which is a part of the wall finishing material, plays an important role as an interior decoration material because of various patterns and materials.

벽지는 단순 마감재로써 사용되는 것 이외에 인간의 정서적인 성장과 변화에 큰 영향을 끼지며 실내환경의 보건, 위생창출에도 기여하고 있다.In addition to being used as a simple finishing material, wallpaper has a great influence on the emotional growth and change of human beings and contributes to the creation of health and hygiene in the indoor environment.

실내공기질개선 관련하여 휘발성 유기화합물(VOCs) 제거를 목적으로 하는 공기정화기 등 공기 순환 및 여과를 통하여 실내 공기의 청정도를 유지하고자 노력하고 있다.In order to improve indoor air quality, we strive to maintain the cleanliness of indoor air through air circulation and filtration such as air purifiers aimed at removing volatile organic compounds (VOCs).

상기한 방법은 단기적으로 효과를 거둘 수 있으나, 소모성 부품의 교체 및 고장 등의 이유로 지속적인 성능발현에 문제점이 있고, 에너지의 소모 및 소음의 발생 등과 같은 부가 2차 오염요소를 내포하고 있다.Although the above method may be effective in the short term, there is a problem in continuous performance expression due to replacement and failure of consumable parts, and includes additional secondary pollutants such as energy consumption and noise generation.

또한, 벽지는 통상적으로 직포나 종이로 된 배면지의 표면에 특정의 문향을 스크린인쇄, 또는 동판이나 그라비아 인쇄하게 되고, 이때 인쇄에 사용되는 잉크는 톨루엔, 에탄올, 아세톤 등을 소정 비율로 혼합한 것이 널리 사용되고 있다.In addition, the wallpaper is usually screen-printed, copper plated or gravure printed on the surface of the backing paper made of woven or paper, wherein the ink used for printing is a mixture of toluene, ethanol, acetone, etc. in a predetermined ratio. It is widely used.

하지만 벽지에 인쇄된 잉크에 포함된 톨루엔은 공해 물질로 알려져 있고, 최근에는 이것이 주거 환경에 휘산되어 천식의 원인으로 작용한다.However, toluene contained in the ink printed on the wallpaper is known as a pollutant, and in recent years it is volatilized in the living environment, causing asthma.

이와 같이 기존의 벽지는 자체로서 환경오염 물질을 방출하였음에도 불구하고, 부가적인 기능보다는 미려함과 시공성에 주안점을 두고 개발되고 있는 추세이고, 이러한 오염물질들은 실내 마감 후 시간이 갈수록 6~12개월 또는 그 이상 거주자에게 나쁜 영향인 새집 증후군으로 인해 머리가 아프거나 피곤함 등의 원인이 규명되지 않는 질병이 발생하는 빈도가 높아지고 있다.Thus, although the conventional wallpaper itself emits environmental pollutants, it is being developed with a focus on beauty and workability rather than additional functions, and these pollutants are 6-12 months or more after finishing the interior. Due to the sick house syndrome, which is a bad effect on abnormal residents, the frequency of the occurrence of diseases such as head ache or tiredness is increasing.

한편, 건축물은 주로 시멘트를 사용하기 때문에 시멘트 구축물에서 시멘트 독성이 배어나오고 전자파가 투과되어 좋지 않으며 신진대사 불안정으로 신경통, 류마티스, 만성 관절염의 질환에 시달리는 문제점을 야기하였다.On the other hand, because the building mainly uses cement, cement toxicity emanates from the cement structure, electromagnetic waves are not transmitted well, and metabolic instability causes neuralgia, rheumatism and chronic arthritis.

이러한 물질들은 건물을 신축한 후 6개월 때 가장 많이 배출된다는 지적이 있고, 최근 외국에서 발표된 보고서에 따르면 시공 후 최장 10년까지 유해 물질이 방출돼 건강을 위협하는 요인으로 작용되며 친환경재료를 사용한 벽지개발을 통한 실내공기질을 개선하고자 많이 노력하고 있다.It is pointed out that these substances are emitted the most in six months after the construction of a building. According to a recent report published in a foreign country, harmful substances are released up to 10 years after construction, which poses a threat to health. Many efforts are being made to improve indoor air quality through the development of wallpaper.

특히 고분자 유기화합물의 독성은 인체에 미치는 나쁜 영향이 완전히 규명되지 않았으나, 발암물질 등이 지속적으로 발생되고 있어 친환경 건축자재의 특성과 개발을 위한 촉매가 되었다.In particular, the toxicity of high molecular organic compounds has not been fully identified, but since carcinogens are continuously generated, it has become a catalyst for the characteristics and development of eco-friendly building materials.

이처럼 종래의 벽지는 환경오염 물질 발생원 역할을 하고 있어 환경부 실내공기질법내에서 '신축되는 공동주택의 시공자는 주민이 입주하기 전에 포름알데히드, 휘발성 유기화합물 등의 오염 물질을 측정하여 그 결과를 입주민에게 공고하도록 함.(제9조), 다중이용시설을 설치하는 자는 제1항의 규정에 의하여 환경부장관이 l고시한 오염물질 방출건축자재를 사용하여서는 아니된다.(제11조)'명시되어 있다.As such, the conventional wallpaper serves as a source of environmental pollutants.In the indoor air quality law of the Ministry of Environment, the contractor of a new apartment building measures the pollutants such as formaldehyde and volatile organic compounds before the residents move in and notify the residents of the results. (Article 9), A person who installs a multi-use facility shall not use the pollutant release building materials notified by the Minister of Environment in accordance with the provisions of paragraph (1) (Article 11).

따라서 건강을 위협하는 요인으로 작용되는 유해물질로부터 보호할 수 있도록 천연복합광물의 기능성 효능으로 건강을 증진을 꾀하기 위해서는 친환경재료를 사용한 벽지개발을 필요로 하고 있다.Therefore, it is necessary to develop wallpaper using eco-friendly materials in order to promote health with the functional effect of natural complex minerals to protect from harmful substances acting as a threat to health.

이에 본 발명은 상기한 바와 같은 종래의 문제점을 해소하고 하는 것으로, 본 발명은 실내 공기 환경의 개선에 대한 연구결과로써 공동주택 및 주거공간, 실내환경을 개선하기 위한 천연광물질을 이용한 환경친화형 벽지를 제공하는데 그 목적이 있다.Therefore, the present invention solves the conventional problems as described above, the present invention is an environmentally friendly wallpaper using natural minerals to improve the indoor environment, such as apartments and residential spaces as a result of the study on the improvement of the indoor air environment The purpose is to provide.

또한, 본 발명은 종래의 벽지제조공정에 적용 가능한 기능성 벽지를 제공하고자 하는데 또 다른 목적이 있는 것이다.Another object of the present invention is to provide a functional wallpaper applicable to a conventional wallpaper manufacturing process.

또한, 본 발명은 실내 마감재료인 벽지에 친환경 기능성 소재 즉, 친환경복합광물을 혼합하여 환경오염을 방지하며, 오염된 공기의 질을 향상시켜 쾌적한 실내환경을 유지 및 개선하고, 2차적으로 에너지 절약과 환경습도조절로 세균의 번식을 억제하는 부가적인 효과를 꾀하고자 하는데 또 다른 목적이 있는 것이다.In addition, the present invention is mixed with environmentally friendly functional material, that is, environmentally friendly composite minerals to the interior finishing material to prevent environmental pollution, improve the quality of the contaminated air to maintain and improve the pleasant indoor environment, secondary energy saving And to control the environmental humidity and the additional effect of suppressing the growth of bacteria is another purpose.

이하, 본 발명의 바람직한 실시 예를 상세하게 설명하면 다음과 같다.Hereinafter, preferred embodiments of the present invention will be described in detail.

상기의 목적을 달성하기 위해 본 발명의 친환경 기능성 벽지는, 조습기능과 탈취율, 항균, 항곰팡이 성능이 높은 친환경복합광물을 이용하여 실내 마감재료인 벽지의 코팅 조성물 및 그 제조방법을 제공함을 특징으로 한다.In order to achieve the above object, the eco-friendly functional wallpaper of the present invention is characterized by providing a coating composition of the interior finishing material and a manufacturing method using an environmentally friendly composite mineral having high humidity and deodorization rate, antibacterial and anti-mold performance. do.

이를 위해서 본 발명은 친환경벽지(wallpaper)를 제조함에 있어서, 천연복합광물을 포함하는 충전제(filler)30~45%, 친환경바인더수용액 55~70%(filler:Binder = 30:70 ~ 45:55)을 에멀젼 상태의 액상형으로 혼합하여 수용성PVC가 겔화된 벽지 원지 위에 상기 혼합물을 탑 코팅 인쇄하여 경화시키고,To this end, the present invention in the manufacture of eco-friendly wallpaper (wallpaper), filler (filler) containing a natural complex mineral 30 ~ 45%, environmentally friendly binder solution 55 ~ 70% (filler: Binder = 30:70 ~ 45:55) Was mixed into an emulsion liquid phase and cured by top coating printing the mixture on a wallpaper paper gelled with water-soluble PVC,

상기 충전제는 입도크기가 5~20㎛크기의 천연복합광물 미분말을 볼밀링법으로 혼합시키되, 볼:분말의 비는 10:1, 볼밀은 150~200rpm으로 30분간 혼합하여 각 재료별 혼합물에 따른 분말 분산성을 증가시키도록 구성되며,The filler is mixed with a ball milling method of natural fine mineral powder with a particle size of 5 ~ 20㎛ size, the ball: powder ratio is 10: 1, the ball mill is mixed for 30 minutes at 150 ~ 200rpm according to the mixture of each material Configured to increase powder dispersibility,

상기 천연복합광물질은 제올라이트, 황토, 규조토, 참숯. 이산화티탄을 주원료에 하고, 여기에 천연광물 20~30wt%, 황산칼슘 60~70wt%(천연광물:황산칼슘:기타 = 2:7:1~3:6:1), 음이온석 5~7wt%, 무기항균제 3~5wt% (기타 = 음이온석:무기향균 = 5:5~7:3)가 첨가제로 혼합되고, 상기 무기항균제는 음이온 코팅된 것을 사용하고, The natural composite mineral is zeolite, ocher, diatomaceous earth, charcoal. Titanium dioxide is used as the main raw material, and natural minerals 20-30 wt%, calcium sulfate 60-70 wt% (natural minerals: calcium sulfate: other = 2: 7: 1-3: 6: 1), anion stone 5-7 wt% , Inorganic antimicrobial agent 3 ~ 5wt% (Other = Anion stone: Inorganic antibacterial = 5: 5 ~ 7: 3) is mixed as an additive, The inorganic antimicrobial agent using an anion coating,

상기 친환경바인더 수용액은 친환경바인더(수용성폴리머)10~30wt%, 분산액 1~2wt%, 소포제 0.5~1wt%, 증점제 0.1~0.5wt%, 탈크 및 편운모 4~7wt%(친환경바인더:탈크및 편운도:그외 = 10:7:3 ~ 30:4:6 => 전체의 20~40%), 희석액(물) 60~80wt%(희석액:그외 = 6:4 ~ 8:2)로 구성되는 것을 특징으로 하는 천연복합광물질을 함유하는 기능성 벽지 제조방법을 제공한다.The eco-friendly binder aqueous solution is an eco-friendly binder (water-soluble polymer) 10 ~ 30wt%, dispersion 1 ~ 2wt%, defoaming agent 0.5 ~ 1wt%, thickener 0.1 ~ 0.5wt%, talc and soft wool 4-7wt% (Eco-friendly binder: talc and loose Figure: Others = 10: 7: 3 to 30: 4: 6 => 20 to 40% of the total), diluent (water) 60 to 80 wt% (diluent: other = 6: 4 to 8: 2) Provided is a method for producing a functional wallpaper containing a natural composite mineral.

이와 같이 본 발명은 인체에 유해한 화학물질 및 유기바인더 등을 전혀 사용하지 않은 자연 친화적인 천연복합광물을 볼밀링법(Ball Mill)을 사용하여 혼합하고, 첨가제는 교반기로 혼합시 천연 바인더에 첨가하여 약 30분간 혼합하여 제조한다.As described above, the present invention mixes a natural-friendly natural complex mineral that does not use any chemicals or organic binders harmful to the human body by using a ball milling method, and the additive is added to the natural binder when mixed with a stirrer. The mixture is prepared for about 30 minutes.

상기한 구성에 있어서, 천연복합광물중 제올라이트는 평균입도가 약 5㎛정도이며, 불규칙적인 다각형상을 띄고 있다.In the above-described configuration, the zeolite in the natural complex mineral has an average particle size of about 5 μm and has an irregular polygonal shape.

규조토의 평균입도는 20㎛이며, 여과보조제, 흡착재, 운반재로 사용된다.Diatomaceous earth has an average particle size of 20 µm and is used as a filter aid, adsorbent, and carrier.

황토의 평균입도는 15㎛이며, 원적외선을 방출하기 때문에 인체에 유익한 광물이며 탈취 및 분해요소로서 활성탄과 이산화티탄(anatase)이 있다.The average particle size of ocher is 15㎛, and it is a mineral that is beneficial to the human body because it emits far infrared rays, and there are activated carbon and titanium dioxide (anatase) as deodorization and decomposition elements.

음이온석의 평균입도는 10㎛이며, 종이의 저장성, 산화방지 및 종이로부터 음이온이 방사되도록 하는 것이다.The average particle size of the anion stone is 10 μm, which is to store the paper, prevent oxidation, and allow the anion to be emitted from the paper.

상기한 천연복합광물을 혼합하여 전체중량의 50%를 차지하며, 수용성 바인더는 10% 이내로 사용하며, 용매는 물을 사용하여 혼합물의 점도가 8000±500cps정도로 조절하여 반제품의 벽지에 균일하게 코팅한다. 50% of the total weight by mixing the above natural complex minerals, water-soluble binder is used within 10%, the solvent is uniformly coated on the wallpaper of the semi-finished product by adjusting the viscosity of the mixture to about 8000 ± 500cps using water .

벽지 원지 위에 코팅제를 도포하고, 겔링 건조를 거쳐서 경화가 이루어진 후 제조된 반제품을 상기와 같은 혼합물을 탑코팅 하여 벽지의 기능성을 부여한다.The coating agent is coated on the wallpaper paper, and the semi-finished product prepared after curing through gelling and drying is coated on the mixture as described above to impart the functionality of the wallpaper.

코팅된 벽지는 건조과정을 통하여 경화가 이루어진 후 예열공정을 거쳐서 엠보싱이 된 후 압축롤러에 의해 벽지의 무늬가 형성이 되어 최종 제품에 도달한다. 이 때 탑코팅시 천연재료의 혼합물의 점도상승, 안정성, 응고현상에 따라 코팅표면의 평활도와 건조시 발생될 코팅제의 표면 무너짐 현상이 야기될 수 있다.The coated wallpaper is cured through a drying process, then embossed through a preheating process, and then a pattern of the wallpaper is formed by a compression roller to reach the final product. At this time, depending on the viscosity increase, stability, solidification of the mixture of the natural material during the top coating may cause surface smoothness of the coating surface and surface collapse of the coating agent to be generated when drying.

그러므로 본 발명은 평활도를 위한 계면활성제, 표면 무너짐에 따른 소포제를 혼합 첨가하여 천연수지와 천연광물과의 배합시 발생될 문제점을 저감시키도록 구성하고 있다.Therefore, the present invention is configured to reduce the problems caused when mixing the natural resin and natural minerals by adding a surfactant for smoothness, a defoamer according to the surface collapse.

이를 기초로 하여 천연광물과 수지로 된 혼합물의 배합비는 혼합천연광물 30~45중량%, 바인더 10~20중량%, 물 30~50중량%, 기타혼화제 1.5~2중량%이며 배합된 조성물은 수용성 에멀젼 상태의 액상으로 조성한다.On the basis of this, the mixing ratio of the natural mineral and resin mixture is 30 to 45% by weight of mixed natural minerals, 10 to 20% by weight of binder, 30 to 50% by weight of water, and 1.5 to 2% by weight of other admixtures. Composition in the liquid phase of the emulsion state.

상기 수용성 수지는 에틸렌비닐알코올, 아크릴, 폴리우레탄계통의 단독 혹은 2종 이상이 혼합된 혼합물을 사용하고, 충전재(filler)로 사용되는 천연광물재료는 325~1200mesh를 사용하며 벽지의 무늬 및 질감을 연출하기 위해 적정재료를 선택한 다.The water-soluble resin is used alone or a mixture of two or more kinds of ethylene vinyl alcohol, acrylic, polyurethane, and the natural mineral material used as a filler (325 ~ 1200mesh) and the pattern and texture of the wallpaper Choose the right ingredients to produce.

제올라이트, 황토, 활성탄, 규조토, 이산화티탄을 혼입한 천연복합광물은 실내건축 마감재인 벽지 및 벽면 코팅재료로서 이용할 수 있으며, 휘발성 유기화합물의 흡수 및 제거, 음이온의 방출기능 및 원적외선 방사효능을 가지고 공동주택의 실내공기질개선을 위한 기능을 갖는다. Natural complex minerals mixed with zeolite, loess, activated carbon, diatomaceous earth and titanium dioxide can be used as wallpaper and wall coating material for interior construction finishes, absorbing and removing volatile organic compounds, releasing anions and having far infrared radiation. It has a function to improve indoor air quality of houses.

본 발명은 스프레이(Spray)와 나이프 type으로 활용할 수 있도록 농도 조절이 가능케 하고, 건조시간 및 시공조건인 온, 습도에 따라 발명 효과의 편차를 최소화하고자 최적의 배합조건을 실험을 통하여 획득하였다.The present invention allows the concentration control to be utilized as a spray (spray) and knife type, and obtained the optimum mixing conditions through experiments to minimize the variation of the invention effect according to the drying time and construction conditions, temperature, humidity.

본 발명에서 사용되는 재료의 정의 및 특성은 다음과 같다.Definitions and properties of materials used in the present invention are as follows.

[1] 제올라이트(Zeolite)[1] zeolites

구 분  division 특 성                         Characteristics 성인 및 산지  Adult and Mountain 클리놉틸로라이트(clinoptilolite)와 모데나이트(mordenite)와 같은 천연 제올라이트는 화학안정도, 기계적 성질이 우수하며, 정사면체 정점에 4개의 산소가 있고, 중심에 Si나 Al이 존재하는 기본구조에 각 꼭지점에 산소를 공유하고 있어 SiO4와 AlO4가 서로 연결되는 방법에 따라 여러 다른 크기와 모양의 동공을 형성하고 있다. Natural zeolites such as clinoptilolite and mordenite have excellent chemical stability and mechanical properties, and have four oxygens at the tetrahedral apex and Si or Al at the apex at their vertices. As they share oxygen, they form pupils of different sizes and shapes, depending on how SiO 4 and AlO 4 are connected to each other. 주 성 분Main component NaAlSi2O6·H2O : 35~50%, SiO2: 15~23%, Al2O3: 15~20%, Fe2O3:1~10% NaAlSi 2 O 6 · H 2 O : 35 ~ 50%, SiO 2: 15 ~ 23%, Al 2 O 3: 15 ~ 20%, Fe 2 O 3: 1 ~ 10% 범주 및 입자  Categories and Particles 무정형 규산 알루미늄에 비하여 내구성, 내산성 및 내열성이 강하다. 활성양이온 교환에 의하여 세공입구의 크기 조절도 가능하고 세공내 정전기장도 변화되어 흡착 및 촉매특성이 달라진다. 또 금속이온의 교환과 환원으로 금속성분의 담체로도 이용. 내부에 있는 나노크기의 세공 속에 보통 물 분자들이 가득 채우고 있는데 이 광석을 가열하면 내포된 물분자가 증발하여 수증기를 발생한다. Compared with amorphous aluminum silicate, it has higher durability, acid resistance and heat resistance. By active cation exchange, the pore size can be controlled, and the electrostatic field in the pore is changed, so that adsorption and catalytic properties are changed. It is also used as a carrier for metal components by exchange and reduction of metal ions. The nano-sized pores inside are usually filled with water molecules, and when the ore is heated, the contained water molecules evaporate to produce water vapor.

[2] 황토[2] loess

구 분  division 특 성                            Characteristics 성인 및 산지  Adult and Mountain 점토, 가는모래 및 탄산칼슘을 포함하는 흙, 국내황토는 연황색 퇴적물로써 황색토와 적색토가 있으며, 주로 남부해안지방과 서부해안지방 산지에 많이 퇴적되어 있으며, 경주 토함산 황토, 경남 고성, 김해, 산청지방과 전남 고흥, 화순지방(적색이 많은 진황토), 충남 부여, 논산, 익산, 강원도 홍천지방의 황토가 널리 분포되어 있다. Soil containing clay, fine sand and calcium carbonate, and yellow loess are light yellow sediments, yellow and red soil, mainly deposited in southern coastal region and western coastal region, Gyeongju, Tohamsan loess, Gyeongnam Goseong, Gimhae, The loess of Sancheong Province, Goheung, Jeonnam, Hwasun Province (red and red clay), Chungju Buyeo, Nonsan, Iksan, and Hongcheon, Gangwon-do are widely distributed. 주 성 분  Main component SiO2:60~65%, Fe2O3:5~6%, Al2O3:10~13%, MgO·Na2O:2%, CaCO3:8%내외이며, 광물구성요소로는 석영 60~70%, 장석과 운모 10~20%, 탄산염광물 5~35%, 2~5%의 실트는 각섬석, 인회석, 흑운모, 석류석, 휘석, 규선석, 전기석, 지르콘 등과 같은 중광물들로 구성된다. SiO 2 : 60 ~ 65%, Fe 2 O 3 : 5 ~ 6%, Al 2 O 3 : 10 ~ 13%, MgO · Na 2 O: 2%, CaCO 3 : around 8%. 60 ~ 70% of quartz, 10 ~ 20% of feldspar and mica, 5 ~ 35% of carbonate mineral, 2 ~ 5% of silt is composed of heavy minerals such as hornblende, apatite, biotite, garnet, pyrite, silicate, tourmaline, and zircon . 사 용 범 주  Category of use 황토의 구성요소로는 표면이 넓은 벌집구조로 수많은 공간이 복층구조를 이루고 있다. 이 스폰지같은 구멍안에는 원적외선이 다량흡수, 저장되어 있어 열을 받으면 발산하여 다른 물체의 분자활동을 자극한다. 즉 황토는 유수한 세월동안 태양에너지를 흡수하고 규소성광물로서 '태양에너지 저장고'라고 지칭되기도 하였다. As a component of ocher, a honeycomb structure with a wide surface has a large number of spaces forming a multi-layer structure. In this sponge-like hole, far-infrared rays are absorbed and stored in a large amount, and radiate when heated to stimulate molecular activity of other objects. In other words, ocher absorbed solar energy for many years and was called 'solar storage' as a silicon mineral.

[3] 이산화티탄(TiO2)[3] titanium dioxide (TiO 2 )

구 분  division 특 성                      Characteristics 성인 및 산지  Adult and Mountain 티탄철광(Ilmenite)형으로 산출 황산법, 염소법으로 TiO2제조.Yield to titanium iron (Ilmenite) Manufacture TiO 2 by sulfuric acid method and chlorine method. 주 성 분  Main component 주성분이 이산화티탄(TiO2)로서 결정상은 정방정으로 티탄철광(Ilmenite)형, 금홍석(Rutile)형과 예추석(Anataile)형이 있다.The main constituent is titanium dioxide (TiO 2 ) and the crystal phase is tetragonal, and there are titanium ore (Ilmenite), rutile (Rutile) and anatale (Anataile) type. 범주 및 입자  Categories and Particles 약 80nm의 구형입자로서 광촉매, 항균, 탈취, 산화분해 작용. 80nm spherical particles, photocatalyst, antibacterial, deodorant, oxidative decomposition.

[4] 음이온석(Anion)[4] anion stones

구 분division 특 성                           Characteristics 성인 및 산지 Adult and Mountain 6각 주형상의 결정을 갖는 붕규산염으로 천연광물의 육방정계 구조를 갖추고 있다. 음이온과 미약전류를 가지고 있으며 양극을 연결하면 0.06㎃의전류가 흐르며 외부로부터 전기장이 가해지지 않더라도 전기분극을 갖는 결정체이다. Borosilicate with crystals in hexagonal shape. It has hexagonal structure of natural minerals. It has an anion and a weak current. When the anode is connected, a current of 0.06㎃ flows and the crystal has electric polarization even if no electric field is applied from the outside. 주 성 분 Main component CeO2 : 28~32%, P2O5 : 18~22%, La2O3 : 10~14%, Nd2O3 : 8~10%CeO 2 : 28 ~ 32%, P 2 O 5 : 18 ~ 22%, La 2 O 3 : 10-14%, Nd 2 O 3 : 8 ~ 10% 사용 범주  Usage category 미약전류발생으로 수분이 닿으면 Activate H2O로 변화시키고 전기분해에 의해 H+, OH-가 되어 알카리 이온화가 된다. OH-는 산성화된 인체를 환원시키며 체내면역기능, 혈액정화등의 작용을 한다. 또한 수질 및 대기 환경의 개선에 효과가 있다.Slight touch of the water current is generated by changes in Activate H 2 O and H +, OH by electrolysis - is is an alkali ionized. OH - reduces acidified body and acts as an immune system, blood purification. It is also effective in improving the water quality and the atmospheric environment.

[5] 규조토[5] diatomaceous earth

구 분division 특 성                          Characteristics 성인 및 산지 Adult and Mountain 여과조제로 사용되고 있으며, 원광은 부드럽고 부서지기 쉬운 실리카계의 광물입니다. 현재 이용하는 규조토층은 약 1,500만년전부터 10만년전에 걸쳐서 바다나 호수의 바닥에 규조류의 단세포 생물이 퇴적되어 형성된 것입니다.  Used as a filtration aid, ore is a silica-based mineral that is soft and brittle. The current diatomaceous earth layer is formed by the accumulation of diatom single cell organisms on the bottom of the sea or lake from about 15 million to 100,000 years ago. 주 성 분 Main component SiO2:88~95%, Fe2O3:0.4~2.1%, Al2O3:0.8~3.2%, CaO:0.9~3%, Na2O:0.1~0.8%, MgO:0.16~0.8%SiO 2 : 88 ~ 95%, Fe 2 O 3 : 0.4 ~ 2.1%, Al 2 O 3 : 0.8 ~ 3.2%, CaO: 0.9 ~ 3%, Na 2 O: 0.1 ~ 0.8%, MgO: 0.16 ~ 0.8% 범주 및 입자 Categories and Particles 규조토는 일반적으로 10㎛보다 크고, 평균 20㎛정도로 전자현미경에 의해서 인지할 수 있으며, 이러한 물리적 구조를 이용하여 여과제, 필터, 증량제, 광택연마제, 보온단열제, 시멘트의 혼화제, 촉매용의 담체등으로 널리 이용된다. Diatomaceous earth is generally larger than 10 μm and can be recognized by electron microscopy with an average of about 20 μm. By using this physical structure, a filter agent, a filter, an extender, a polished abrasive, a heat insulating agent, a cement admixture, a catalyst carrier Widely used.

[6] 참숯[6] charcoal

구 분division 특 성                       Characteristics 성인 및 산지 Adult and Mountain 탄화된 숯의 가장 큰 특성인 흡착력을 더욱 활성화시키기 위해 특수하게 축조된 고압가마에서 600~900'C의 초고온의 수증기를 가하여 숯을 화학적, 물리적으로 열처리하여 재가공한 제품이다.  In order to further activate the adsorption power, which is the most charcoal charcoal, it is reprocessed by chemically and physically heat-treating charcoal by applying ultra-high temperature steam of 600 ~ 900'C in a specially constructed high pressure kiln. 주 성 분  Main component 대부분 탄소로 이루어짐 Mostly made of carbon 사용 범주  Usage category 수도물 정수장의 여과용이나 정수기의 필터뿐만 아니라 화학이나 도금공장, 농축산 폐수의 필터용으로 광범위하게 사용되고 있다. 단위 g당 1,000㎡ 이상의 표면적을 갖기도 하는데 표면에 존재하는 탄소원자의 관능기가 주위의 액체 또는 기체에 인력을 가하여 피흡착질의 분자를 흡착하는 성질이 있다. 따라서 활성탄은 환경, 수처리 등의 제반 산업분야에서 활용되고 있다. It is widely used for filtration of tap water purification plants and filters for water purifiers, as well as for filtration of chemicals, plating plants and concentrated wastewater. It also has a surface area of 1,000 m² or more per unit, and the functional group of the carbon atom on the surface adsorbs molecules of adsorbate by attracting the surrounding liquid or gas. Therefore, activated carbon is used in various industrial fields such as environment and water treatment.

[7] 발명에 따른 친환경 벽지의 탈취성능(암모니아 가스 탈취시험)[7] Deodorization performance of eco-friendly wallpaper according to the invention (ammonia gas deodorization test)

경과시간(분)Elapsed time (minutes) 3030 6060 9090 120120 Blank 농도(ppm)Blank concentration (ppm) 194194 152152 131131 116116 시료 농도(ppm)Sample concentration (ppm) 2121 1010 77 55 탈 취 율(%)Deodorization rate (%) 89.289.2 93.493.4 94.794.7 95.795.7

[8] 발명에 사용한 천연복합광물재료의 입자크기[8] particle size of natural composite mineral materials used in the invention

입자크기Particle size TiO2 TiO 2 규조토Diatomaceous earth ZeoliteZeolite AnionAnion 참숯Charcoal 황토ocher 최소값Minimum value 60㎚60 nm 10㎛10 μm 1㎛1 μm 1㎛1 μm 20㎛20 ㎛ 5㎛5 μm 최대값Value 100㎚100 nm 30㎛30 μm 10㎛10 μm 7㎛7㎛ 35㎛35 μm 15㎛15 μm

[9] 발명에 따른 친환경 벽지의 항균, 항곰팡이 성능(항균, 항곰팡이 시험)[9] antibacterial and antifungal performance of environmentally friendly wallpaper according to the invention (antibacterial and antifungal test)

시 험 항 목Test Items 시 험 결 과Test result 초기농도 (CFU/40p)Initial concentration (CFU / 40p) 24시간 후 농도 (CFU/40p)Concentration after 24 hours (CFU / 40p) 세균 감소율(%)Bacterial Reduction (%) 대장균에 의한 항균시험Antibacterial test by E. coli BlankBlank 381381 19261926 증가increase 친환경 벽지Eco friendly wallpaper 381381 1One 99.799.7 녹농균에 의한 항균시험Antibacterial test by Pseudomonas aeruginosa BlankBlank 400400 20262026 증가increase 친환경 벽지Eco friendly wallpaper 400400 22 99.599.5

시 험 항 목Test Items 항 곰 팡 이 시 험Antifungal test 배 양 시 험 의 기 간Period of culture test 1주후1 week later 2주후after 2 weeks 3주후3 weeks later 4주후4 weeks later 시 험 결 과Test result 00 00 00 00 0 : 시료에서 균의 성장을 인자할 수 없음0: Can't print growth of bacteria in sample

이처럼 천연복합광물을 적정비율 즉, 상기의 천연광물을 혼합분과 천연 바인더 수용액에 그 외 첨가재를 혼합하여 건시료의 40~50%의 중량비로 30분 이상 고속 교반기로 혼합하여 완성한다. As such, the natural composite mineral is mixed with a high speed stirrer for 30 minutes or more at an appropriate ratio, that is, the natural mineral is mixed with other additives in the mixed powder and the aqueous natural binder solution.

본 발명은 뿜칠과 붓칠로 하며 도포 두께는 0.2~0.5mm의 표면의 얇은 도포로 탈취효능, 항균·항곰팡이 효능, 휘발성 유기화합물 방출, 음이온 발생 및 원적외선 방사에 대한 시험을 실시하였다.The present invention was sprayed and brushed and the coating thickness was tested for the deodorizing effect, antibacterial and antifungal effect, volatile organic compound release, anion generation and far infrared radiation by thin coating of 0.2 ~ 0.5mm surface.

시험체의 시간경과에 따른 탈취율Deodorization rate with time 경과시간(분)Elapsed time (minutes) 3030 6060 9090 120120 Blank 농도(ppm)Blank concentration (ppm) 194194 152152 131131 116116 시료 농도(ppm)Sample concentration (ppm) 2121 1010 77 55 탈 취 율(%)Deodorization rate (%) 89.289.2 93.493.4 94.794.7 95.795.7

시험체의 음이온 발생 및 원적외선 방사특성Anion Generation and Far-Infrared Radiation Characteristics of Test Specimen 구 분division BlankBlank 친환경 벽지Eco friendly wallpaper 음이온 개수(ION/CC)Anion count (ION / CC) 7373 600600 원적외선 방사율(%)Far Infrared Emissivity (%) 7070 9292

시험체의 항균 특성Antimicrobial Properties of Test Specimens 시 험 항 목  Test Items 시 험 결 과Test result 초기농도 (CFU/40p)Initial concentration (CFU / 40p) 24시간후 농도 (CFU/40p)Concentration after 24 hours (CFU / 40p) 세균감소율 (%)Bacterial Reduction Rate (%) 대장균에 의한 항균시험  Antibacterial test by E. coli BlankBlank 381381 19261926 증가increase 친환경 벽지Eco friendly wallpaper 381381 1One 99.799.7 녹농균에 의한항균시험  Antibacterial test by Pseudomonas aeruginosa BlankBlank 400400 20262026 증가increase 친환경 벽지Eco friendly wallpaper 400400 22 99.599.5

시험체의 항곰팡이 특성Antifungal Properties of Test Specimens

시험항목  Test Items 항곰팡이시험Antifungal test 배양시험의 기간Period of culture test 1주후1 week later 2주후after 2 weeks 3주후3 weeks later 4주후4 weeks later 시험결과Test result 00 00 00 00 0 : 시료에서 균의 성장을 인지할 수 없음0: Growth of bacteria is not recognized in the sample

휘발성 유기화합물 방출 여부 검출 시험VOC release test 시 험 항 목Test Items 단 위unit 시험결과Test result 휘발성 유기 화합물 (VOCs)         Volatile Organic Compounds (VOCs) 아세톤Acetone g/L           g / L 불검출(검출한계 0.01)Not detected (detection limit 0.01) 메탄올Methanol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 메틸에틸케톤Methyl ethyl ketone 불검출(검출한계 0.005)Not detected (detection limit 0.005) 에탄올ethanol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 벤젠benzene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 2-프로판올2-propanol 불검출(검출한계 0.005)Not detected (detection limit 0.005) 메틸이소부틸케톤Methyl Isobutyl Ketone 불검출(검출한계 0.005)Not detected (detection limit 0.005) 이소부탄올Isobutanol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 톨루엔toluene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 아세트산부틸Butyl acetate 불검출(검출한계 0.005)Not detected (detection limit 0.005) 1-부틸알코올1-butyl alcohol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 셀로솔브Cellosolve 불검출(검출한계 0.01)Not detected (detection limit 0.01) o-자이렌o-xylene 불검출(검출한계 0.005)Not detected (detection limit 0.005) m-자이렌m-xylene 불검출(검출한계 0.005)Not detected (detection limit 0.005) p-자이렌p-xylene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 스티렌Styrene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 부틸셀로솔브Butyl Cellosolve 불검출(검출한계 0.01)Not detected (detection limit 0.01) 기타 VOCsOther VOCs 불검출(검출한계 0.005)Not detected (detection limit 0.005)

포름알데히드 방출 측정 결과Formaldehyde emission measurement result 시험항목  Test Items 시험결과Test result Blank(ppm)Blank (ppm) 친환경벽지(ppm)Eco-friendly wallpaper (ppm) 포름알데히드(HCHO)  Formaldehyde (HCHO) 0.01 0.01

본 발명은 제올라이트 및 천연 바인더를 사용한 실내공기의 질 향상을 위한 건축 도료로서 탈취율은 최대 90%이상, 음이온은 600개 이상 발생하고, 시공된 건물의 습도가 인간에 적합하게 조절되며, 탁월한 흡착력으로 냄새를 제거하고 우수한 항균성으로 곰팡이 등 세균의 번식을 억제하는 것으로 나타났으며, 포름알데히드 0.03ppm이하로 우리의 주거환경에 적합하고 쾌적한 실내공간을 제공할 수 있게 한다.The present invention is a building paint for improving the quality of indoor air using zeolites and natural binders, the deodorization rate is up to 90% or more, more than 600 anions are generated, and the humidity of the constructed building is controlled for humans, It has been shown to suppress odors and inhibit the growth of bacteria such as molds with excellent antimicrobial properties. Formaldehyde below 0.03ppm enables us to provide a comfortable and comfortable indoor space for our living environment.

전체조성물의 구성요소와 무게중량비Components and Weight to Weight Ratio of Total Composition 조성물의 구성요소Components of the Composition wt%wt% 천연복합광물(filler)Natural complex mineral filler 30~4530-45 filler:Binder= 30:70~45:55filler: Binder = 30: 70-45: 55 친환경바인더(Binder) 수용액Eco-friendly Binder Solution 55~7055-70 합계Sum 100100

천연복합광물의 구성요소와 구성비Components and Ratios of Natural Complex Minerals 천연복합광물의 구성요소Components of Natural Complex Minerals wt%wt% 천연광물Natural minerals 20~3020-30 천연광물:황산칼슘:기타 =2:7:1~3:6:1Natural Minerals: Calcium Sulfate: Others = 2: 7: 1 ~ 3: 6: 1 황산칼슘Calcium sulfate 60~7060-70 음이온석Anion stone 5~75 ~ 7 기타=음이온석:무기항균 =5:5~7:3Others: Anion stone: Inorganic antibacterial = 5: 5 ~ 7: 3 무기항균제Inorganic antimicrobial agents 3~53 ~ 5

친환경 바인더(Binder) 수용액의 구성요소와 구성비Components and Composition Ratios of Eco-friendly Binder Solution 친환경바인더(Binder) 수용액의 구성요소Components of Eco-Friendly Binder Solution wt%wt% 목적purpose 비고Remarks 친환경바인더Eco-friendly binder 10~3010-30 수용성폴리머Water Soluble Polymer 친환경바인더:탈크 및 편운모:그 외 = 10:7:3~30:4:6 => 전체의 20~40% Eco-friendly binder: Talc and mica: Others = 10: 7: 3 ~ 30: 4: 6 => 20 ~ 40% of the total 분산액Dispersion 1~21 ~ 2 계면활성향상Surfactant Enhancement 소포제Antifoam 0.5~10.5 ~ 1 파포력향상, 물에 대한 용해도 증가Improved breaking force, increased solubility in water 증점제Thickener 1~0.5`1 ~ 0.5` 점도유지Viscosity maintenance 탈크 및 편운모Talc and mica 4~74 ~ 7 내구성 및 난연성향상Durability and flame retardancy 희석액diluent 60~8060-80 물water 희석액:그 외 =6:4~8:2Diluent: Others = 6: 4-8: 2 합계Sum 100100

이상에서 살펴본 바와 같이 본 발명에 따른 천연복합광물질을 함유하는 기능성 벽지 제조방법에 의하면, 공동주택, 실내 벽면에 사용되는 마감재 벽지로 인한 실내 공기오염을 사전에 예방하고, 그 외 안료, 유기화합물, 최종코팅제에서 발 생되는 휘발성 유기화합물은 제거하는 한편 인체에 유익한 음이온을 다량 방출시킴으로써 친환경 실내 공간, 공동주택의 건축문화를 구현할 수 있는 장점이 있게 된다.As described above, according to the manufacturing method of the functional wallpaper containing the natural composite mineral according to the present invention, indoor air pollution caused by the wallpaper of the finishing material used for apartment houses, interior walls is prevented in advance, and other pigments, organic compounds, By removing volatile organic compounds generated from the final coating agent and releasing a large amount of negative ions, which are beneficial to the human body, there is an advantage that it can realize the eco-friendly interior space and the building culture of apartment houses.

또한, 천연광물 및 수용성 바인더를 사용하여 실내 공기의 질을 향상과 더불어 기능성 재료로 인한 인간이 거주하기에 적합한 습도를 유치하며 탁월한 흡착력으로 냄새 제거 및 항균성, 원적외선 방사효능으로 우리의 주거환경에 적합하고 쾌적한 실내공간을 제공할 수 있다는 등의 효과를 갖는 매우 유용한 발명인 것이다.In addition, natural minerals and water-soluble binders are used to improve the quality of indoor air, attract humidity suitable for human habitation due to functional materials, and odor removal, antibacterial and far-infrared radiation effects with excellent adsorption power. It is a very useful invention having the effect of providing a comfortable and comfortable interior space.

Claims (5)

친환경벽지(wallpaper)를 제조함에 있어서,In manufacturing eco-friendly wallpaper, 천연복합광물을 포함하는 충전제(filler)30~45%, 친환경바인더수용액 55~70%을 에멀젼 상태의 액상형으로 혼합하여 수용성PVC가 겔화된 벽지 원지 위에 상기 혼합물을 탑 코팅 인쇄하는 것을 특징으로 하는 천연복합광물질을 함유하는 기능성 벽지 제조방법.30 to 45% of a filler containing natural complex minerals and 55 to 70% of an environmentally friendly binder solution are mixed in an emulsion liquid form to form a top coating print on the mixture on a wallpaper paper gelled with water-soluble PVC. Method for producing a functional wallpaper containing a composite mineral. 제 1항에 있어서, 상기 충전제는 입도크기가 5~20㎛크기의 천연복합광물 미분말을 볼밀링법으로 혼합시키되, 볼:분말의 비는 10:1, 볼밀은 150~200rpm으로 30분간 혼합하여 각 재료별 혼합물에 따른 분말 분산성을 증가시키는 것을 특징으로 하는 천연복합광물질을 함유하는 기능성 벽지 제조방법. The method of claim 1, wherein the filler is a fine particle size of 5 ~ 20㎛ natural composite mineral powder is mixed by a ball milling method, the ball: powder ratio of 10: 1, ball mill 150 to 200rpm by mixing for 30 minutes Method for producing a functional wallpaper containing a natural composite mineral, characterized in that to increase the powder dispersibility according to the mixture for each material. 제 1항에 있어서, 상기 천연복합광물질은 제올라이트, 황토, 규조토, 참숯. 이산화티탄을 주원료에 하고, 여기에 천연광물 20~30wt%, 황산칼슘 60~70wt%, 음이온석 5~7wt%, 무기항균제 3~5wt% 가 첨가제로 혼합되는 것을 특징으로 하는 천연복합광물질을 함유하는 기능성 벽지 제조방법.The method of claim 1, wherein the natural composite mineral is zeolite, loess, diatomaceous earth, charcoal. Titanium dioxide is used as a main raw material, and natural mineral 20-20 wt%, calcium sulfate 60-70 wt%, anionic stone 5-7 wt%, and inorganic antimicrobial agent 3-5 wt% are mixed with additives. Functional wallpaper manufacturing method. 제 1항에 있어서, 친환경바인더 수용액은 친환경바인더 10~30wt%, 분산액 1~2wt%, 소포제 0.5~1wt%, 희석액 60~80wt%, 증점제 0.1~0.5wt%, 탈크 및 편운모 4~7wt%로 구성되는 것을 특징으로 천연복합광물질을 함유하는 기능성 벽지 제조방법.The environmentally friendly binder aqueous solution is an environmentally friendly binder 10 ~ 30wt%, dispersion 1 ~ 2wt%, defoamer 0.5 ~ 1wt%, diluent 60 ~ 80wt%, thickener 0.1 ~ 0.5wt%, talc and mica 4 ~ 7wt% Method for producing a functional wallpaper containing a natural complex mineral, characterized in that consisting of. 제 3항에 있어서, 상기 무기항균제는 음이온 코팅된 것을 특징으로 하는 천연복합광물질을 함유하는 기능성 벽지 제조방법.The method of claim 3, wherein the inorganic antimicrobial agent is a functional wallpaper containing a natural composite mineral, characterized in that the anionic coating.
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Cited By (12)

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KR100829163B1 (en) * 2006-11-28 2008-05-16 이재수 Noninflammable wallpaper made of mica and manufacturing method thereof
KR100876962B1 (en) * 2008-02-13 2009-01-07 세창화학 주식회사 Method for preparing wall paper
KR100899235B1 (en) 2008-12-26 2009-05-26 이상기 Pvc-based functional finishing composition for wall having reduced harmful components by absorption
KR100914935B1 (en) * 2008-12-26 2009-08-31 이상기 Method for preparation of pvc-based functional finishing material for wall having reduced harmful components by absorption
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KR100925544B1 (en) 2008-02-13 2009-11-05 신동인 Method for preparing wall paper
KR100989823B1 (en) 2010-03-26 2010-10-29 이윤영 Functional paint for wallpaper, method for manufacturing functional wallpaper and functional wallpaper
KR101099320B1 (en) 2011-06-07 2011-12-26 주식회사 더리빙 Wallpaper containing absorbing counteractive for removing volatile organic compounds and formaldehyde
KR20120035999A (en) * 2010-10-07 2012-04-17 금호석유화학 주식회사 The environmental-friendly wallpaper compositions which resolve the indoor polluted air environment and manufacturing method thereof
KR101236336B1 (en) 2010-10-25 2013-02-22 이상기 Synthetic leather based wall finishing composition and its preparation method
KR20210026266A (en) 2019-08-29 2021-03-10 (주)엘지하우시스 Silk wall covering and method for manufacturing the same
WO2023066883A1 (en) * 2021-10-18 2023-04-27 Marburger Tapetenfabrik J.B. Schaefer Gmbh & Co. Kg Wallcovering having mineral surface and process for production thereof

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100829163B1 (en) * 2006-11-28 2008-05-16 이재수 Noninflammable wallpaper made of mica and manufacturing method thereof
KR100876962B1 (en) * 2008-02-13 2009-01-07 세창화학 주식회사 Method for preparing wall paper
KR100925544B1 (en) 2008-02-13 2009-11-05 신동인 Method for preparing wall paper
KR100917688B1 (en) 2008-09-18 2009-09-21 신동인 Manufacturing method of wall paper
KR100899235B1 (en) 2008-12-26 2009-05-26 이상기 Pvc-based functional finishing composition for wall having reduced harmful components by absorption
KR100914935B1 (en) * 2008-12-26 2009-08-31 이상기 Method for preparation of pvc-based functional finishing material for wall having reduced harmful components by absorption
KR100989823B1 (en) 2010-03-26 2010-10-29 이윤영 Functional paint for wallpaper, method for manufacturing functional wallpaper and functional wallpaper
KR20120035999A (en) * 2010-10-07 2012-04-17 금호석유화학 주식회사 The environmental-friendly wallpaper compositions which resolve the indoor polluted air environment and manufacturing method thereof
KR101643001B1 (en) 2010-10-07 2016-08-11 금호석유화학 주식회사 The environmental-friendly wallpaper compositions which resolve the indoor polluted air environment and manufacturing method thereof
KR101236336B1 (en) 2010-10-25 2013-02-22 이상기 Synthetic leather based wall finishing composition and its preparation method
KR101099320B1 (en) 2011-06-07 2011-12-26 주식회사 더리빙 Wallpaper containing absorbing counteractive for removing volatile organic compounds and formaldehyde
KR20210026266A (en) 2019-08-29 2021-03-10 (주)엘지하우시스 Silk wall covering and method for manufacturing the same
WO2023066883A1 (en) * 2021-10-18 2023-04-27 Marburger Tapetenfabrik J.B. Schaefer Gmbh & Co. Kg Wallcovering having mineral surface and process for production thereof

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