KR100593531B1 - Aqueous Glass Cleaner Composition - Google Patents
Aqueous Glass Cleaner Composition Download PDFInfo
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- KR100593531B1 KR100593531B1 KR1020040027607A KR20040027607A KR100593531B1 KR 100593531 B1 KR100593531 B1 KR 100593531B1 KR 1020040027607 A KR1020040027607 A KR 1020040027607A KR 20040027607 A KR20040027607 A KR 20040027607A KR 100593531 B1 KR100593531 B1 KR 100593531B1
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- glass
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- aqueous
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- 239000011521 glass Substances 0.000 title claims abstract description 47
- 239000000203 mixture Substances 0.000 title claims abstract description 40
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 8
- 239000003623 enhancer Substances 0.000 claims abstract description 7
- 239000002904 solvent Substances 0.000 claims abstract description 6
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims abstract description 4
- GXVDVJQTXFTVMP-UHFFFAOYSA-N 4-methoxypentan-2-ol Chemical compound COC(C)CC(C)O GXVDVJQTXFTVMP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims abstract description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 4
- 239000008393 encapsulating agent Substances 0.000 claims abstract description 4
- 235000019441 ethanol Nutrition 0.000 claims abstract description 4
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims abstract description 4
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims abstract description 4
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims abstract description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 4
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 4
- 239000000565 sealant Substances 0.000 claims abstract description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000007864 aqueous solution Substances 0.000 claims abstract description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 4
- 239000000194 fatty acid Substances 0.000 claims description 4
- 229930195729 fatty acid Natural products 0.000 claims description 4
- 150000004665 fatty acids Chemical class 0.000 claims description 4
- -1 polyoxy ethylene Polymers 0.000 claims description 4
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 claims description 3
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 2
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 2
- 150000005215 alkyl ethers Chemical class 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 17
- 238000005406 washing Methods 0.000 abstract description 9
- 239000000356 contaminant Substances 0.000 abstract description 8
- 239000003599 detergent Substances 0.000 abstract description 6
- 239000012459 cleaning agent Substances 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 238000011109 contamination Methods 0.000 abstract description 2
- 239000000428 dust Substances 0.000 abstract description 2
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000008014 freezing Effects 0.000 description 7
- 238000007710 freezing Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000003205 fragrance Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 241000207199 Citrus Species 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 239000003002 pH adjusting agent Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- BKUYVGOACRJHQO-UHFFFAOYSA-N benzenesulfonic acid;sulfuric acid Chemical compound OS(O)(=O)=O.OS(=O)(=O)C1=CC=CC=C1 BKUYVGOACRJHQO-UHFFFAOYSA-N 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0047—Other compounding ingredients characterised by their effect pH regulated compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C11D2111/18—
Abstract
본 발명은 유리 표면에 접착된 먼지나 얼룩 등의 오염을 제거하기 위한 수계 유리 세정제 조성물에 관한 것이다. 본 발명의 수계 세정제 조성물은 조성물 총 중량을 기준으로, 폴리비닐알코올, 폴리비닐피롤리돈, 하이드록시프로필셀룰로오스 및 카보멀로 이루어진 군으로부터 선택된 하나 이상의 점도 증강제 0.01 내지 2.0 중량%; 비이온 계면활성제 0.05 내지 2 중량%; 금속이온 봉집제 0.01 내지 1 중량%; 및 디에틸렌글리콜-n-부틸에테르, 3-메톡시-메틸-1-부탄올, 에틸렌글리콜 모노부틸에테르, 에틸알코올, 부탄올, 아이소프로필알코올 및 폴리프로필렌글리콜메틸에테르로 이루어지는 군으로부터 선택된 하나 이상의 용제 0.5 내지 20 중량%;를 포함하는 수용액으로서, pH가 6 내지 11로 조절되어 있다. 본 발명의 수계 유리 세정제 조성물은 세정력이 우수하며 세정 후 잔유물이 거의 남지 않을 뿐만 아니라, 적절한 점도를 갖으므로서 세정시 오염물질을 포함하는 세정제가 쉽게 흘러내리지 않아 유리표면에 얼룩이 거의 발생되지 않으며 유리 밑부분에 세정제가 고이는 현상도 방지된다.The present invention relates to an aqueous glass cleaner composition for removing contamination such as dust and stains adhered to a glass surface. The aqueous detergent composition of the present invention comprises 0.01 to 2.0% by weight of one or more viscosity enhancing agents selected from the group consisting of polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropylcellulose and carbomal based on the total weight of the composition; 0.05-2% by weight of nonionic surfactant; 0.01 to 1 wt% metal ion sealant; And at least one solvent selected from the group consisting of diethylene glycol-n-butyl ether, 3-methoxy-methyl-1-butanol, ethylene glycol monobutyl ether, ethyl alcohol, butanol, isopropyl alcohol and polypropylene glycol methyl ether. To 20% by weight; containing an aqueous solution, the pH is adjusted to 6-11. The aqueous glass cleaner composition of the present invention has excellent cleaning power and hardly any residue remains after washing, and has an appropriate viscosity, so that the cleaning agent containing contaminants does not easily flow down during cleaning, so that stains hardly occur on the glass surface. The buildup of detergent at the bottom is also prevented.
점도 증강제*비이온 계면활성제*금속이온 봉집제*유리*세정제Viscosity Enhancer * Nonionic Surfactant * Metal Ion Encapsulant * Glass * Cleaner
Description
본 발명은 유리 표면에 접착된 먼지나 얼룩 등의 오염을 제거하기 위한 수계 유리 세정제 조성물에 관한 것이다.The present invention relates to an aqueous glass cleaner composition for removing contamination such as dust and stains adhered to a glass surface.
유리 표면에 접착된 오염물질들은 유리 세정제를 스프레이 건으로 분사하여 닦아냄으로서 제거하게 된다. 유리 세정제로서 요구되는 물성으로는 우수한 세정력과 함께, 유리의 투명성을 유지할 수 있도록 세정 후 잔유물을 남기지 않아야 한다. 또한, 겨울철에도 사용이 가능하도록 빙점이 낮아야 한다. 이러한 물성을 유지하기 위하여 유리 세정제는 물을 베이스로 하여 계면활성제와 수용성 용제 등이 첨가된 수계 세정제 조성물로 제조된다.Contaminants adhering to the glass surface are removed by wiping the glass cleaner with a spray gun. The physical properties required as the glass cleaner should be excellent in cleaning power and leave no residue after cleaning to maintain the transparency of the glass. In addition, the freezing point should be low so that it can be used in winter. In order to maintain such physical properties, the glass cleaner is prepared as an aqueous cleaner composition to which a surfactant, a water-soluble solvent, and the like are added based on water.
그런데, 통상적으로 사용되는 유리 세정제는 점성이 거의 없다. 유리 표면은 매끄러우며 통기성이나 흡수성이 전혀 없으므로 분사된 유리 세정제는 오염물질과 함께 쉽게 아래로 흘러내린다. 따라서 거실 유리창 등의 밑 부분에 세정제가 고이는 현상이 발생하여 사용에 불편함이 발생한다. By the way, the glass cleaner normally used has little viscosity. The glass surface is smooth and there is no breathability or absorption, so the sprayed glass cleaner flows down easily with contaminants. Therefore, a phenomenon that the cleaner is accumulated in the lower part of the living room glass window, etc. occurs, causing inconvenience to use.
또한, 종래의 유리 세정제는 휘산속도가 빨라 유리표면에 얼룩이 발생하기 쉬우므로, 제품 사용자는 세정제 내용물이 휘산되기 전에 세정을 서둘러서 해야 하 는 문제점이 있다.In addition, conventional glass cleaners have a high volatilization rate and are liable to cause stains on the surface of the glass. Thus, a product user has a problem of having to rush cleaning before the contents of the cleaner are volatilized.
따라서, 본 발명이 이루고자 하는 기술적 과제는 상기 문제점을 해결하여, 세정력이 우수하며 세정 후 잔유물이 거의 남지 않을 뿐만 아니라, 적절한 점도를 갖으므로서 세정시 오염물질을 포함하는 세정제가 쉽게 흘러내리지 않아 유리표면에 얼룩이 거의 발생되지 않으며 유리 밑부분에 세정제가 고이는 현상도 방지되는 수계 유리 세정제 조성물을 제공하는데 있다.Therefore, the technical problem to be achieved by the present invention is to solve the above problems, the cleaning power is excellent and there is little residue left after cleaning, as well as having a suitable viscosity, the cleaning agent containing contaminants during cleaning does not easily flow glass The present invention provides a water-based glass cleaner composition which hardly causes stains on the surface and prevents accumulation of a cleaner on the bottom of the glass.
상기 기술적 과제를 달성하기 위하여, 본 발명의 수계 세정제 조성물은 조성물 총 중량을 기준으로, 폴리비닐알코올, 폴리비닐피롤리돈, 하이드록시프로필셀룰로오스 및 카보멀로 이루어진 군으로부터 선택된 하나 이상의 점도 증강제 0.01 내지 2.0 중량%; 비이온 계면활성제 0.05 내지 2 중량%; 금속이온 봉집제 0.01 내지 1 중량%; 및 디에틸렌글리콜-n-부틸에테르, 3-메톡시-메틸-1-부탄올, 에틸렌글리콜 모노부틸에테르, 에틸알코올, 부탄올, 아이소프로필알코올 및 폴리프로필렌글리콜메틸에테르로 이루어지는 군으로부터 선택된 하나 이상의 용제 0.5 내지 20 중량%;를 포함하며, pH가 6 내지 11인 수용액으로 구성된다.In order to achieve the above technical problem, the aqueous detergent composition of the present invention, based on the total weight of the composition, at least one viscosity enhancer 0.01 to 2.0 selected from the group consisting of polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropyl cellulose and carbomal weight%; 0.05-2% by weight of nonionic surfactant; 0.01 to 1 wt% metal ion sealant; And at least one solvent selected from the group consisting of diethylene glycol-n-butyl ether, 3-methoxy-methyl-1-butanol, ethylene glycol monobutyl ether, ethyl alcohol, butanol, isopropyl alcohol and polypropylene glycol methyl ether. To 20% by weight; and composed of an aqueous solution having a pH of 6 to 11.
이하, 본 발명에 따른 수계 유리 세정제 조성물에 대하여 상세히 설명한다.Hereinafter, the water-based glass cleaner composition according to the present invention will be described in detail.
본 발명의 수계 유리 세정제 조성물은 물을 베이스로 하여 제조된 것으로서, 조성물 총 중량을 기준으로 0.01 내지 2.0 중량%, 바람직하게는 0.01 내지 0.5 중량%의 점도 증강제를 포함한다. 점도 증강제의 함량이 0.01 중량% 미만이면 점도 상승이 미미하고, 2.0 중량%를 초과하면 점도가 지나치게 상승하여 조성물 제조가 어려울 뿐만 아니라 유리 표면에 점도 증각제 잔류물이 많아 남아 유리의 투명이 떨어진다. 조성물의 바람직한 점도 범위는 30 ~ 400cps이다. 점도 증가제로는 폴리비닐알코올, 폴리비닐피롤리돈, 하이드록시프로필셀룰로오스, 카보멀(CTFA명, INCI명-아크릴레이트/C10-30 알킬 아크릴레이트 크로스폴리머)을 각각 단독으로 또는 이들을 1종 이상 혼합하여 사용한다.The aqueous glass cleaner composition of the present invention is prepared on the basis of water, and contains 0.01 to 2.0% by weight, preferably 0.01 to 0.5% by weight, based on the total weight of the composition. If the content of the viscosity enhancer is less than 0.01% by weight, the viscosity rise is insignificant, and if the content of the viscosity enhancer is more than 2.0% by weight, the viscosity is excessively increased, making the composition difficult, as well as a large amount of viscosity thickener residue on the glass surface, resulting in poor transparency of the glass. The preferred viscosity range of the composition is 30 to 400 cps. As the viscosity increasing agent, polyvinyl alcohol, polyvinylpyrrolidone, hydroxypropyl cellulose, carbomal (CTFA name, INCI name-acrylate / C10-30 alkyl acrylate crosspolymer) may be used alone or in combination of one or more thereof. Use it.
또한, 본 발명의 수계 유리 세정제 조성물은 조성물 총 중량을 기준으로 비이온 계면활성제를 0.05 내지 2 중량%, 바람직하게는 0.05 내지 1 중량%를 함유한다. 비이온 계면활성제의 함량이 0.05 중량% 미만이면 세정 효과를 기대할 수 없고, 2 중량%를 초과하면 계면활성제가 유리 표면에 부착되어 유리 표면이 흐려진다. 비이온 계면활성제로는 폴리옥시 에틸렌 알킬에테르, 폴리옥시 에틸렌 페닐에테르, 지방산 디에탄올 아미드 등을 각각 단독으로 또는 이들을 1종 이상 혼한하여 사용할 수 있다.In addition, the aqueous glass cleaner composition of the present invention contains 0.05 to 2% by weight, preferably 0.05 to 1% by weight of the nonionic surfactant based on the total weight of the composition. If the content of the nonionic surfactant is less than 0.05% by weight, the cleaning effect cannot be expected. If the content of the nonionic surfactant is more than 2% by weight, the surfactant adheres to the glass surface and the glass surface becomes cloudy. As a nonionic surfactant, polyoxy ethylene alkyl ether, polyoxy ethylene phenyl ether, fatty acid diethanol amide, etc. can be used individually or in mixture of 1 or more types, respectively.
본 발명의 수계 유리 세정제 조성물에 함유된 금속이온 봉집제는 지방산 금속염 등을 효과적으로 제거하기 위하여 첨가되는데, 디에틸렌트리아민 펜타 메틸렌 포스포릭산, 에틸렌 디아민 테트라아세테이트 등을 단독으로 또는 이들을 혼합하여 사용하는 것이 바람직하다. 금속이온 봉집제의 함량은 조성물 총 중량을 기준으로 0.01 내지 1 중량%인데. 그 함량이 0.01 중량% 미만에서는 효과를 기대할 수 없고, 1 중량%를 초과하면 경제성이 떨어진다.The metal ion sealant contained in the water-based glass cleaner composition of the present invention is added to effectively remove fatty acid metal salts, and the like. Diethylenetriamine pentamethylene phosphoric acid, ethylene diamine tetraacetate, or the like may be used alone or in combination thereof. It is preferable. The content of the metal ion encapsulant is 0.01 to 1% by weight based on the total weight of the composition. If the content is less than 0.01% by weight, no effect can be expected, and if it exceeds 1% by weight, economical efficiency is lowered.
또한, 본 발명의 수계 유리 세정제 조성물은 유리 표면의 세정보조 및 김서 림 방지 효과, 동절기 빙결방지를 위하여, 디에틸렌글리콜-n-부틸에테르, 3-메톡시-메틸-1-부탄올, 에틸렌글리콜 모노부틸에테르, 에틸알코올, 부탄올, 아이소프로필알코올 및 폴리프로필렌글리콜메틸에테르로 이루어지는 군으로부터 선택된 하나 이상의 용제를 0.5 내지 20 중량%, 바람직하게는 1 내지 15 중량% 함유한다. 전술한 용제의 함량이 0.5 중량% 미만이면 그 첨가 효과가 미미하고, 20 중량%를 초과하면 세정제 사용시 잔유물이 많이 남는 문제점이 있다.In addition, the water-based glass cleaning composition of the present invention, diethylene glycol-n-butyl ether, 3-methoxy-methyl-1-butanol, ethylene glycol mono 0.5 to 20% by weight, preferably 1 to 15% by weight of one or more solvents selected from the group consisting of butyl ether, ethyl alcohol, butanol, isopropyl alcohol and polypropylene glycol methyl ether. If the content of the above-described solvent is less than 0.5% by weight, the addition effect is insignificant, if it exceeds 20% by weight there is a problem that a lot of residues remain when using the detergent.
유리 세정제 조성물에는 수산화나트륨, 수산화칼륨, 모노에탄올아민 등의 pH 조절제를 첨가하여 세정제 조성물의 pH를 6 내지 11로 조절한다. 통상적으로 전술한 pH 조절제를 0.01 내지 1.0 중량% 첨가하면 pH를 상기 범위로 조절할 수 있다.The pH of the cleaning composition is adjusted to 6 to 11 by adding a pH adjusting agent such as sodium hydroxide, potassium hydroxide and monoethanolamine to the glass cleaning composition. Typically, the pH can be adjusted to the above range by adding 0.01 to 1.0% by weight of the above-described pH adjuster.
전술한 성분들 외에도, 본 발명의 수계 유리 세정제 조성물에는 본 발명의 목적을 저해하지 않는 범위 내에서 다른 성분들을 더 첨가할 수 있다. 예를 들어, 향은 세정제 사용시 신선한 향을 부여하기 위해 첨가할 수 있는데, 시트러스계 또는 과일 향, 꽃 향과 같은 천연 향 또는 화학적으로 합성된 향 등을 첨가할 수 있다. 통상적으로 향 성분의 첨가량은 0.01 내지 1.0 중량%이다.In addition to the above-described components, other components may be further added to the aqueous glass cleaner composition of the present invention within a range not impairing the object of the present invention. For example, the fragrance may be added to impart a fresh fragrance when using the cleaner, and natural or chemically synthesized fragrances such as citrus or fruit or floral fragrances may be added. Usually, the amount of the fragrance component added is 0.01 to 1.0 wt%.
이하, 본 발명을 구체적으로 설명하기 위해 실시예를 들어 상세하게 설명하기로 한다. 그러나, 본 발명에 따른 실시예들은 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 아래에서 상술하는 실시예들에 한정되는 것으로 해석되어져서는 안된다. 본 발명의 실시예들은 당업계에서 평균적인 지식을 가진 자에게 본 발명을 보다 완전하게 설명하기 위해서 제공되어지는 것이다.Hereinafter, the present invention will be described in detail with reference to Examples. However, embodiments according to the present invention can be modified in many different forms, the scope of the present invention should not be construed as limited to the embodiments described below. Embodiments of the present invention are provided to more completely explain the present invention to those skilled in the art.
실시예 1 내지 4 및 비교예 1 내지 3Examples 1-4 and Comparative Examples 1-3
하기 표 1에 기재된 성분과 함량에 따라 유리 세정제 조성물을 제조하였다. 단위는 중량%이다.A glass cleaner composition was prepared according to the ingredients and contents shown in Table 1 below. The unit is weight percent.
상기 표 1에서, 계면활성제(1)은 비이온 계면활성제인 지방산 디에탄올 아미드이고, 계면활성제(2)은 음이온 계면활성제인 황산벤젠솔포네이트 소디윰염이고, 금속이온 봉집제는 에틸렌 디아민 테트라아세테이트 4-소디윰(EDTA-4Na)이고, 향은 시트러스계의 JP-673이다.In Table 1, the surfactant (1) is a fatty acid diethanol amide which is a nonionic surfactant, the surfactant (2) is a benzenesulfonate sulfate salt of an anionic surfactant, and the metal ion encapsulant is ethylene diamine tetraacetate 4 -Sodium 윰 (EDTA-4Na), and the fragrance is citrus JP-673.
상기 실시예 1 내지 4 및 비교예 1 내지 3에서 제조된 유리 세정제 조성물에 대해서 다음과 같이 시험을 실시하였다.The glass cleaner compositions prepared in Examples 1 to 4 and Comparative Examples 1 to 3 were tested as follows.
점도 측정Viscosity measurement
Brookfield 점도계(spindle No. 3, 30rpm)를 이용하여 점도를 측정하였다.Viscosity was measured using a Brookfield viscometer (spindle No. 3, 30 rpm).
세정력 평가Detergency Evaluation
세정력을 평가하기 위해 조성물 원액을 가로 X 세로 30cm의 오염물질이 도포된 유리판에 일반적인 스프레이 건을 사용하여 3회 분사한 다음, 마른 휴지로 10회 닦아내었다. 유리표면의 투명도에 대한 소비자 조사(조사 인원 30명)를 통해 하기 5점 측정법에 따라 판정하도록 하였고, 그 결과를 표 2에 나타내었다.To evaluate detergency, the composition stock solution was sprayed three times using a common spray gun onto a glass plate coated with a 30 cm long by 30 cm contaminant, and then wiped ten times with a dry tissue. Consumer survey (30 people surveyed) on the transparency of the glass surface was determined according to the following five-point measurement method, the results are shown in Table 2.
(평가기준) (Evaluation standard)
1점 : 세정력이 전혀 없다. 2점 : 세정력이 없다.1 point | piece: There is no washing power at all. 2 points | pieces: There is no washing power.
3점 : 세정력이 조금 있다. 4점 : 세정력이 우수하다.3 points | pieces: There is a little washing power. 4 points | pieces: Excellent washing power.
5점 : 세정력이 매우 우수하다.5 points | pieces: The washing | cleaning power is very excellent.
유리 세정제 조성물의 잔유성 평가Residual Evaluation of Glass Detergent Composition
세정력을 평가하기 위해 조성물 원액을 가로 X 세로 30cm의 오염물질이 도포된 유리판에 일반적인 스프레이 건을 사용하여 3회 분사한 다음, 마른 휴지로 10회 닦아내었다. 유리표면의 투명도에 대한 소비자 조사를 통해 하기 5점 측정법에 따라 판정하도록 하였고, 그 결과를 표 2에 나타내었다.To evaluate detergency, the composition stock solution was sprayed three times using a common spray gun onto a glass plate coated with a 30 cm long by 30 cm contaminant, and then wiped ten times with a dry tissue. A consumer survey on the transparency of the glass surface was made according to the following five-point measurement method, and the results are shown in Table 2.
(평가기준)(Evaluation standard)
1점 : 잔유물이 매우 많다. 2점 : 잔유물이 많다.1 point | piece: There is a lot of residue. 2 points | pieces: There are many residues.
3점 : 잔유물이 조금 있다. 4점 : 잔유물이 거의 없다.3 points | pieces: There is a little residue. 4 points | pieces: There is little residue.
5점 : 잔유물이 전혀 없다.5 points | pieces: There is no residue at all.
빙결점 측정Freezing point measurement
조성물 원액을 250ml 용기에 투입하여 빙결점을 측정하였고 그 결과를 표 2 에 나타내었다. The composition free solution was added to a 250 ml container to measure the freezing point, and the results are shown in Table 2.
표 2를 참조하면, 본 발명에 따른 실시예 1 내지 4의 유리 세정제 조성물은 세정력이 우수하며 세정 후 잔유물이 거의 남지 않으며, 점도가 높아 세정시 오염물질을 포함하는 세정제가 쉽게 흘러내리지 않게 됨을 알 수 있다. 또한, -5℃ 이하의 낮은 빙결점을 갖는다.Referring to Table 2, it can be seen that the glass cleaner compositions of Examples 1 to 4 according to the present invention have excellent cleaning power and hardly any residues remain after washing, and the cleaning agent containing contaminants does not easily flow when cleaning due to its high viscosity. Can be. It also has a low freezing point of -5 deg.
한편, 점도 증강제의 첨가량이 본 발명의 범위에 미치지 않는 비교예 3의 유리 세정제 조성물은 점도가 낮아 세정제가 쉽게 흘러내리는 등의 문제점이 발생한다. 음이온 계면활성제가 첨가된 비교예 1은 실시예 3 및 4와 동량의 점도 증강제가 첨가되었음에도 불구하고 조성물의 점도가 매우 낮게 형성됨을 알 수 있다. 세정보조 및 동절기 빙결방지 기능을 하는 용제가 첨가되지 않은 비교예 2는 세정효과가 미약하며, 특히 빙결 온도가 높아 동절기에 쉽게 얼게 된다.On the other hand, the glass cleaner composition of the comparative example 3 in which the addition amount of a viscosity enhancer does not fall within the range of this invention has a low viscosity, and the problem that a detergent flows easily occurs. Comparative Example 1 with the addition of the anionic surfactant can be seen that the viscosity of the composition is formed very low despite the addition of the same amount of viscosity enhancer as Examples 3 and 4. Comparative Example 2, which does not contain the washing tank and the solvent that prevents the freezing of the winter, has a weak cleaning effect, and in particular, freezes easily in the winter due to the high freezing temperature.
이와 같이, 본 발명의 수계 유리 세정제 조성물은 적절한 점도를 갖으므로서 세정시 오염물질을 포함하는 세정제가 쉽게 흘러내리지 않아 유리표면에 얼룩이 거의 발생되지 않으며 유리 밑부분에 세정제가 고이는 현상도 방지된다. 또한, 세정 력이 우수하며 세정 후 잔유물이 거의 남지 않을 뿐만 아니라, 낮은 빙결점을 가지므로 동절기에도 사용이 가능하다.As described above, the water-based glass cleaner composition of the present invention has an appropriate viscosity, so that the cleaning agent containing contaminants does not easily flow down so that staining is hardly generated on the glass surface, and the phenomenon that the cleaner is accumulated on the bottom of the glass is also prevented. In addition, it has excellent cleaning power and almost no residue remains after washing, and has a low freezing point, so it can be used in winter.
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| KR101796373B1 (en) | 2016-03-09 | 2017-11-10 | 호서대학교 산학협력단 | Glass cleaner formulation using by washing water of comber noil de-waxing process |
| KR101887684B1 (en) | 2017-04-10 | 2018-08-10 | (주)윈도우샤인 | Eco-friendly organic detergent stock solution for glass cleaning |
| KR20240054567A (en) | 2022-10-19 | 2024-04-26 | 이호열 | detergent for removing scale |
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| KR101225723B1 (en) * | 2005-12-20 | 2013-01-23 | 에스케이케미칼주식회사 | Detergent composition for cleaning clean room |
| KR101507763B1 (en) * | 2013-04-22 | 2015-04-08 | 한국생산기술연구원 | Aquous detergent composition and cleaning method using the composition |
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| KR101796373B1 (en) | 2016-03-09 | 2017-11-10 | 호서대학교 산학협력단 | Glass cleaner formulation using by washing water of comber noil de-waxing process |
| KR101887684B1 (en) | 2017-04-10 | 2018-08-10 | (주)윈도우샤인 | Eco-friendly organic detergent stock solution for glass cleaning |
| KR20240054567A (en) | 2022-10-19 | 2024-04-26 | 이호열 | detergent for removing scale |
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