KR100588831B1 - The manufacturing method and cosmetics composition of shape-memory type hydrogel emulsions by associative polymers - Google Patents
The manufacturing method and cosmetics composition of shape-memory type hydrogel emulsions by associative polymers Download PDFInfo
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Abstract
본 발명은 형상 기억(shape-memory) 현상을 갖는 화장료 조성물 및 이의 제조 방법에 관한 것으로 더욱 상세하게는 일반적인 수성겔과는 달리 회합성 증점제인 피이지-150/스테아릴알콜/에스엠디아이 코폴리머와 비이온계면활성제인 피피지-26-부테스-26/피이지-40 하이드로제네이티드캐스터오일을 함유하여 우수한 탄력 및 보습 효과를 주는 형상 기억(shape-memory) 현상을 갖는 수성겔 에멀젼 조성물 및 그 제조 방법에 관한 것이다.The present invention relates to a cosmetic composition having a shape-memory phenomenon and a method for preparing the same. Aqueous gel emulsion composition having a shape-memory phenomenon which contains a sebum-26-butes-26 / fiji-40 hydrogenated castor oil which is a nonionic surfactant and has an excellent elasticity and moisturizing effect, and its It relates to a manufacturing method.
형상기억, 회합성 증점제, 계면활성제Shape memory, associative thickener, surfactant
Description
도 1은 회합성 증점제를 이용한 형상 기억 현상을 갖는 수성겔 에멀젼이 도찰되고 손으로 눌러진 후 다시 복원되는 현상을 연속적으로 촬영한 사진이다.FIG. 1 is a photograph continuously photographing a phenomenon in which an aqueous gel emulsion having a shape memory phenomenon using an associative thickener is drawn, pressed by hand, and then restored.
본 발명은 형상 기억 수성겔 에멀젼 조성물 및 그 제조 방법에 관한 것이다.The present invention relates to a shape memory aqueous gel emulsion composition and a method for producing the same.
화장품은 피부에 보습 및 탄력 등 간접적으로 영향을 미치므로 그 조성물에 대한 연구가 활발히 진행되고 있다.? 특히 기존의 화장품 중 에멀젼 조성물은 오일 및 왁스류등을 이용한 에멀젼으로서 사용감 및 성상이 한계를 이루고 피부에 흡수된 후에는 뻣뻣한 감촉을 주게 된다.? 또한 상기 뻣뻣한 감촉은 화장품을 사용하는 소비자들에게 불편함을 주게 된다.? 따라서, 피부에 도찰시 사용감이 좋으며 흡수 후에는 매트한 질감을 갖는 새로운 제형의 화장품의 개발이 요구되어 왔다.Since cosmetics indirectly affect the skin, such as moisturizing and elasticity, research on the composition is being actively conducted. Particularly, the emulsion composition of the existing cosmetics is an emulsion using oils and waxes, which gives a stiff texture after being absorbed into the skin by limiting the feeling of use and properties. In addition, the stiff texture is inconvenient for consumers using cosmetics. Therefore, there is a demand for the development of a cosmetic formulation of a new formulation having a good feeling when applied to the skin and having a matt texture after absorption.
본 발명은 이러한 사용자들의 요구를 충족하기 위해 이루어진 것으로 본 발 명의 목적은 성상의 형태가 복원되는 특이한 젤타입으로 손으로 펴바를시 특이한 느낌을 주는 형상기억 수성겔을 형성하는 형상 기억(shape-memory) 현상을 나타내는 종래의 화장품 제형과는 다른 새로운 제형의 화장료 조성물을 제공하는 것이다.The present invention has been made to meet the needs of these users, the object of the present invention is to form a shape memory (shape-memory) to form a shape memory aqueous gel that gives a unique feeling when spread by hand with a unique gel type that the shape of the appearance is restored It is to provide a cosmetic composition of a new formulation different from conventional cosmetic formulations exhibiting the phenomenon.
본 발명의 또하나의 목적은 수용성 회합성 증점제를 이용한 형상 기억(shape-memory) 현상을 갖는 화장료 조성물의 제조 방법을 제공하는 것이다.It is another object of the present invention to provide a method for producing a cosmetic composition having a shape-memory phenomenon using a water-soluble associative thickener.
본 발명은 상기와 같은 목적을 달성하기 위한 것으로서, 회합성 증점제로 피이지-150/스테아릴알콜/에스엠디아이 코폴리머와 비이온 계면활성제로 피피지-26-부테스-26/피이지-40 하이드로제네이티드 캐스터오일을 함유하고 피부에 도찰시 형상 기억(shape-memory) 현상을 나타내는 것을 특징으로 하는 수성겔 에멀젼 화장료 조성물을 제시한다.The present invention is to achieve the above object, Fiji-26-butes-26 / Fiji-40 as a non-ionic surfactant with Fiji-150 / stearyl alcohol / SMDI as an associative thickener An aqueous gel emulsion cosmetic composition containing a hydrogenated castor oil and exhibiting a shape-memory phenomenon when applied to the skin is presented.
또한 상기 수성겔 에멀젼 화장료 조성물에서 피이지-150/스테아릴알콜/에스엠디아이 코폴리머는 조성물 총 중량에 대하여 0.1 ~ 30.0 중량 %로 함유되는 것을 특징으로 한다.In addition, in the aqueous gel emulsion cosmetic composition, PIG-150 / stearyl alcohol / SM copolymer is characterized in that it contains 0.1 to 30.0% by weight based on the total weight of the composition.
또한 상기 수성겔 에멀젼 화장료 조성물에서 피피지-26-부테스-26/피이지-40 하이드로제네이티드 캐스터오일은 조성물 총중량에 대하여 0.01 ~ 5.0중량%로 함유되는 것을 특징으로 한다.In the aqueous gel emulsion cosmetic composition, sebum-26-butes-26 / fiji-40 hydrogenated castor oil may be contained in an amount of 0.01 to 5.0% by weight based on the total weight of the composition.
상기 수성겔 에멀젼 화장료 조성물을 제조하기 위한 본 발명에 따른 제조방법은, 비이온계면활성제인 피피지-26-부테스-26-/피이지-40 하이드로제네이티드 캐스터오일을 포함하는 유상성분 원료들을 균일하게 혼합하는 단계; 회합성 증점제인 피이지-150/스테아릴 알코올/ 에스엠디아이 코폴리머를 포함하는 수상성분들을 가열하여 균일하게 혼합하는 단계; 및 상기 균일하게 혼합된 수상성분 원료들에 상기 균일하게 혼합된 유상성분 원료들을 교반하면서 서서히 투입하는 단계를 포함하는 것을 특징으로 한다.The preparation method according to the present invention for preparing the aqueous gel emulsion cosmetic composition, the oil-based raw material containing a non-ionic surfactant, sebum-26-butes-26- / PJ-40 hydrogenated castor oil Mixing uniformly; Heating and uniformly mixing the water phase components including the PIG-150 / stearyl alcohol / SMDI copolymer which is an associative thickener; And gradually injecting the uniformly mixed oily ingredient materials into the uniformly mixed aqueous phase ingredients.
이하에서는 본 발명을 보다 상세하게 설명한다.Hereinafter, the present invention will be described in more detail.
본 발명에 의한 화장료 조성물은 수성겔 에멀젼이지만 기존의 수성겔 에멀젼과는 상이한 조성으로 형상 기억(shape-memory) 현상을 나타낸다.? 형상 기억 현상이란 피부에 도찰 후 손으로 눌렀을때 제품의 형태가 다시 복원되는 현상을 의미한다.? 도 1에서와 같이 본 발명의 수성겔 에멀젼 화장료 조성물은 회합성 증점제를 이용한 형상기억 수성겔 에멀젼의 조성물로서, 본 발명의 수성겔 에멀젼이 피부에 도찰되고 손으로 눌러진 후에 시간이 경과하면 다시 복원되는 현상을 나타낸다.The cosmetic composition according to the present invention is an aqueous gel emulsion, but exhibits a shape-memory phenomenon with a composition different from that of a conventional aqueous gel emulsion. Shape memory refers to a phenomenon in which the shape of a product is restored when it is pressed by hand after applying it to the skin. As shown in Fig. 1, the aqueous gel emulsion cosmetic composition of the present invention is a composition memory aqueous gel emulsion composition using an associative thickener, and restores again after time passes after the aqueous gel emulsion of the present invention is applied to the skin and pressed by hand. It is a phenomenon.
한편 본 발명인 수성겔 에멀젼 화장료 조성물에서 수성성분인 상기 피이지-150/스테아릴알콜/에스엠디아이 코폴리머는 상기 화장료조성물 총 중량에 대하여 0.1~50.0중량%, 바람직하게는 0.5~30.0% 양을 함유하며, 유성성분인 비이온 계면활성제인 피피지-26-부테스-26/피이지-40 하이드로제네이티드캐스터오일은 상기 화장료조성물 총 중량에 대하여 0.01~5.0중량%, 바람직 하게는 0.1~3.0%의 양을 함유한다.On the other hand, in the aqueous gel emulsion cosmetic composition of the present invention, the aqueous PIG-150 / stearyl alcohol / SMDI Co copolymer contains 0.1 to 50.0% by weight, preferably 0.5 to 30.0%, based on the total weight of the cosmetic composition. Fiji-26-butes-26 / Pig-40 hydrogenated castor oil, which is an oil-based nonionic surfactant, is 0.01-5.0% by weight, preferably 0.1-3.0% based on the total weight of the cosmetic composition. Contains the amount of.
상기 오일상을 이루는 오일은 사용감에 따라 가벼운 사용감을 원하면 실리콘계 오일을, 무거운 사용감을 원하면 에스테르계나 트리글리세라이드계 오일 함량을 조절하여 사용할수 있으며, 수상부분에 있어서 보습력 및 탄력감을 주는 성분으로 는 히아루론산, 콜라겐 수용액을 사용할 수 있으며, 총오일의 중량 및 수상성분의 보습제의 중량은 전체중량의 50%를 초과하지 않게 한다.The oil forming the oil phase can be used by adjusting the silicone-based oil, if you want a light feeling according to the feeling of use, the ester or triglyceride-based oil content if you want a heavy feeling, hyaluronic acid, as a component that gives moisture and elasticity in the water phase part, Collagen aqueous solution may be used, and the weight of the total oil and the weight of the water-based moisturizer should not exceed 50% of the total weight.
또한 본 발명인 수성겔 에멀젼 화장료 조성물은 유상성분으로서 에탄올, 초산, 토코페롤, 방부제, 피피지-26-부테스-26/피이지-40 하이드로제네이티드캐스터오일을 균일하게 혼합하고, 수상 성분인 정제수, 이디티에이-2엔에이,구연산, 구연산나트륨, 부틸렌글리콜, 수용성 콜라겐, 소듐알기네이트, 피이지-150/스테아릴알코올/에스엠디아이 코폴리머, 카보머, 트리에탄올 아민, 글리세린을 60℃에서 균일하게 혼합한다.? 그 후 상기 균일하게 혼합된 수상성분 원료들에 상기 균일하게 혼합된 유상성분 원료들을 교반하면서 50℃ 근처에서 서서히 투입하여 제조한다.In addition, the aqueous gel emulsion cosmetic composition of the present invention is uniformly mixed with ethanol, acetic acid, tocopherol, preservatives, sebum-26-butes-26 / PJ-40 hydrogenated castor oil as an oil phase component, purified water as an aqueous phase component, IDT-2N, Citric Acid, Sodium Citrate, Butylene Glycol, Water Soluble Collagen, Sodium Alginate, Fiji-150 / Stearyl Alcohol / SMD A Copolymer, Carbomer, Triethanol Amine, Glycerine Uniformly at 60 ° C Mix? Thereafter, the uniformly mixed aqueous phase raw materials are slowly added at about 50 ° C. while stirring to prepare the uniformly mixed aqueous phase raw materials.
이하, 실시예 및 비교예를 통해 본 발명을 좀더 구체적으로 설명한다.? 단, 이들 실시예 및 비교예는 본 발명의 예시적인 기재일 뿐이며 본 발명의 범위가 이들 실시예 및 비교예에 국한되는 것은 아니다.Hereinafter, the present invention will be described in more detail with reference to Examples and Comparative Examples. However, these Examples and Comparative Examples are only illustrative descriptions of the present invention, and the scope of the present invention is not limited to these Examples and Comparative Examples.
실시예 및 비교예Examples and Comparative Examples
표 1에 기재된 원료를 가지고 각각 실시예 1~2와 비교예 1~2를 제조하였다.With the raw material of Table 1, Examples 1-2 and Comparative Examples 1-2 were produced, respectively.
하기의 제형들은 모두 O/W 제형들이며, 단위는 중량 %이다.The formulations below are all O / W formulations and are in weight percent.
실시예의 1~2의 제조Preparation of Examples 1-2
(1) 유상성분들을 균일하게 혼합하였다.(1) The oily ingredients were uniformly mixed.
(2) 수상성분들을 가열(60℃)하여 균일하게 혼합하였다.(2) The aqueous phase components were heated (60 ° C.) and mixed uniformly.
(3) 상기 (2)에 상기 (1)을 교반하면서 50℃ 근처에서 서서히 투입후 겔상 에멀젼을 얻었다.(3) The gel emulsion was obtained after slowly adding to (2) at 50 degreeC, stirring said (1).
비교예 1~2의 제조Preparation of Comparative Examples 1-2
(1) 유상성분들을 균일하게 혼합하였다.(1) The oily ingredients were uniformly mixed.
(2) 수상성분들을 균일하게 혼합 용해시켰다.(2) The aqueous phase components were mixed and dissolved uniformly.
(3) 상기(2)에 상기(1)을 교반하면서 상온에서 투입한 후 냉각하여 겔상의 에멀젼을 얻었다.(3) In (2), (1) and (1) were added at room temperature while stirring, followed by cooling to obtain a gel emulsion.
실험예 1: 성상의 안정성 평가Experimental Example 1 Evaluation of Stability of Properties
상기 제조된 실시예 1~2 및 비교예 1~2의 수성겔형 에멀젼의 점도 및 pH를 측정하였으며, 실온, 4℃, 42℃의 온도에서 1개월 및 2개월 정치하여 성상의 변화 를 평가하여 안정성을 측정하고 그 결과를 표 2에 나타내었다.The viscosity and pH of the aqueous gel emulsion of Examples 1 to 2 and Comparative Examples 1 to 2 were measured, and the stability was evaluated by standing for 1 month and 2 months at room temperature, 4 ° C, and 42 ° C. Was measured and the results are shown in Table 2.
상기 표 2에서 알 수 있는 바와 같이 본 발명의 수성겔 에멀젼은 비교예 1, 2와 비교 결과 성상은 모두 안정함을 알 수 있다.As can be seen in Table 2, the aqueous gel emulsion of the present invention is compared with Comparative Examples 1 and 2, it can be seen that the properties are all stable.
실험예 2: 사용감 및 형상 기억 현상의 유무 평가Experimental Example 2: Evaluation of Usability and Shape Memory Phenomena
상기 실시예 및 비교예의 사용감 및 형상 기억 현상의 유무를 평가하기 위해 20~40 대 여성 40명을 대상으로 관능 평가법으로 상대비교 평가를 실시 하였다.? 그 결과를 표 3에 나타내었다.In order to evaluate the usability and shape memory phenomena of the examples and comparative examples, a relative comparative evaluation was performed using a sensory evaluation method for 40 women in their 20s and 40s. The results are shown in Table 3.
상기 표 3에서 알 수 있는 바와 같이 본 발명에 의한 수성겔 에멀젼은 비교 예 1, 2 와 비교 결과 사용감 면에서 우수하다는 것을 알 수 있으며, 또한 형상 기억 현상도 실시예 1, 2 에서만 일어남을 확인하였다.As can be seen from Table 3, the aqueous gel emulsion according to the present invention is found to be excellent in terms of feeling as compared with Comparative Examples 1 and 2, and also confirmed that the shape memory phenomenon occurs only in Examples 1 and 2. .
실험예 3: 탄력개선 효과 및 피부 보습 지속력 평가Experimental Example 3: Evaluation of Elasticity Improvement Effect and Skin Moisturizing Duration
상기 실시예 및 비교예의 탄력개선 효과 및 시간경과에 따른 피부 보습 지속력에 대하여 평가를 실시하였다.? 평가 방법은 100점을 만점으로 하고 하기의 등급 에 평균치를 내어 평가하였으며 그 결과를 표 4 에 나타내었다.The elasticity improvement effect of the said Example and the comparative example and the persistence of skin moisturizing with time were evaluated. The evaluation method was a perfect score of 100 points, the average of the following rating was evaluated and the results are shown in Table 4.
상기 표 4에서 알 수 있는 바와 같이 본 발명에 의한 수성겔 에멀젼은 비교예 1, 2 와 비교 결과 탄력 개선 효과가 우수함을 알 수 있으며, 또한 시간 경과에 따른 피부 보습 지속력도 비교예 1, 2 보다 우수함을 확인하였다.As can be seen in Table 4, the aqueous gel emulsion according to the present invention can be seen that the elasticity improvement effect is excellent as compared with Comparative Examples 1 and 2, and also the skin moisturizing persistence over time compared to Comparative Examples 1 and It confirmed that it is excellent.
이상에서 설명한 바와 같이 회합성 증점제와 계면활성제를 이용하여 수성겔 에멀젼 타입의 화장료 조성물의 제조가 가능하고 그에 따른 형상 기억 제형을 제조할 수 있다.As described above, it is possible to prepare an aqueous gel emulsion type cosmetic composition using an associative thickener and a surfactant, and to prepare a shape memory formulation accordingly.
또한 본 발명에 의해 피부에 도찰후 뻣뻣한 감촉을 주는 일반 수성겔 타입의 화장료에 비해, 훨씬 사용감이 부드러우며 흡수후에는 매트한 질감을 가짐과 동시에 탄력 개선 효과와 피부 보습 지속력이 뛰어난 제형의 수성겔 에멀젼 타입의 화장료 조성물을 얻을 수 있다.In addition, compared to the general aqueous gel-type cosmetics that give a stiff feel after applying to the skin, the present invention is softer in use and has a matte texture after absorption, and has an elasticity improvement effect and a sustained moisture retention effect. An emulsion type cosmetic composition can be obtained.
이상에서는 본 발명의 바람직한 실시예에 대해 설명하였으나 당해 기술분야에서 통상의 지식을 가진 자라면 본원 발명의 요지를 벗어남이 없이 다양한 변형실시가 가능할 것이며, 이러한 변형실시는 본원발명의 보호범위에 속하는 것으로서 본원발명의 보호범위는 특허청구범위에 기재된 바에 따라 해석되어야 할 것이다.In the above description of the preferred embodiment of the present invention, those skilled in the art will be able to perform various modifications without departing from the gist of the present invention, and such modifications are within the protection scope of the present invention. The protection scope of the present invention should be construed as described in the claims.
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KR101814379B1 (en) * | 2016-03-31 | 2018-01-04 | (주)셀트리온 | Oil-In-Water Cosmetic Composition with Shape-Memory Ability |
KR20210000456A (en) | 2019-06-25 | 2021-01-05 | (주)씨엔엔티 | Manufacturing method for natural thickener of beauty expenses based on nano-cellulose and natural thickener of beauty expenses based on nano-cellulose manufactured by the same |
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