KR100585360B1 - 에틸렌을 공기 또는 산소로 직접 산화시켜 에틸렌옥시드를 제조하는 방법 - Google Patents
에틸렌을 공기 또는 산소로 직접 산화시켜 에틸렌옥시드를 제조하는 방법 Download PDFInfo
- Publication number
- KR100585360B1 KR100585360B1 KR1020017003676A KR20017003676A KR100585360B1 KR 100585360 B1 KR100585360 B1 KR 100585360B1 KR 1020017003676 A KR1020017003676 A KR 1020017003676A KR 20017003676 A KR20017003676 A KR 20017003676A KR 100585360 B1 KR100585360 B1 KR 100585360B1
- Authority
- KR
- South Korea
- Prior art keywords
- steam
- pressure
- ethylene
- steam turbine
- ethylene oxide
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/32—Separation; Purification
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
- C07C29/10—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes
- C07C29/103—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers
- C07C29/106—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of ethers, including cyclic ethers, e.g. oxiranes of cyclic ethers of oxiranes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K27/00—Plants for converting heat or fluid energy into mechanical energy, not otherwise provided for
- F01K27/02—Plants modified to use their waste heat, other than that of exhaust, e.g. engine-friction heat
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F22—STEAM GENERATION
- F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
- F22B1/00—Methods of steam generation characterised by form of heating method
- F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
- F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
- F22B1/1807—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines using the exhaust gases of combustion engines
- F22B1/1815—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines using the exhaust gases of combustion engines using the exhaust gases of gas-turbines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Abstract
Description
스트림 번호 1 | 1 | 2 | 3 | 4 | 5 | 6 | |
전체 스트림 | t/h | 52.3 | 2.6 | 49.7 | 9.3 | 59 | 59 |
압력 | bar절대 | 53 | 21 | 21 | 41 | 21 | 21 |
온도 | ℃ | 268 | 215 | 215 | 400 | 242 | 215 |
g | 1 | g | g | g | 1 | ||
g: 기상 l: 액상 |
스트림 번호 1 | 1 | 2 | 3 | 4 | 5 | 6 | |
전체 스트림 | t/h | 31.4 | 2.8 | 28.6 | 12.6 | 16 | 16 |
압력 | bar절대 | 53 | 5 | 5 | 5 | 5 | 5 |
온도 | ℃ | 268 | 152 | 152 | 152 | 152 | 152 |
g | 1 | g | g | g | 1 | ||
g: 기상 l: 액상 |
스트림 번호 1 | 1 | 2 | 3 | 4 | 5 | 6 | |
전체 스트림 | t/h | 83.7 | 4.8 | 78.9 | 63.4 | 15.5 | |
압력 | bar절대 | 53 | 17 | 17 | 17 | 17 | |
온도 | ℃ | 268 | 204 | 204 | 204 | 204 | |
g | 1 | g | g | g | |||
g: 기상 l: 액상 |
Claims (5)
- 수증기의 팽창을 하나 이상의 배압 증기 터빈(들) (T)에서 수행하는 것을 포함하는, 반응열을 발산시키는 열매체로서 물을 사용하여 에틸렌을 공기 또는 산소로 직접 산화시키며 압력이 증가하는 운전 시간에 걸쳐 연속적으로 형성되는 수증기가 팽창되도록 하여 에틸렌 옥시드를 제조하는 방법.
- 제1항에 있어서, 증기 터빈(들) (T)이 하나 이상의 작동 기계 (M), 특히 공정 펌프 및 압축기, 및(또는) 하나 이상의 발전기 (G)를 작동시키는 방법.
- 제1항 또는 제2항에 있어서, 증기 터빈(들) (T)에 공급되는 수증기의 압력이 25 내지 70 bar, 바람직하게는 30 내지 65 bar인 방법.
- 제1항 또는 제2항에 있어서, 에틸렌 옥시드로부터 가수분해, 가압 탈수, 진공 탈수 및 이어서 증류에 의해 모노에틸렌 글리콜이 생성되며, 에틸렌의 직접 산화에서 생기는 수증기가 증기 터빈(들) (T)을 통해 가압 탈수 탑의 탑저 리보일러 (S) 또는 캐스케이드의 제1 가압 탈수 탑의 탑저 리보일러 (S)의 압력으로 팽창되고, 증기 터빈(들) (T)의 배출 증기는 가압 탈수 탑 또는 캐스케이드의 제1 가압 탈수 탑을 가열하는데 사용되는 방법.
- 제1항 또는 제2항에 있어서, 증기 터빈(들) (T)을 통해 증기 그리드 (N)의 압력 또는 소비자, 특히 증기 분사기 또는 탑저 리보일러의 운전 압력으로 팽창되는 방법.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19843654.8 | 1998-09-23 | ||
DE19843654A DE19843654A1 (de) | 1998-09-23 | 1998-09-23 | Verfahren zur Herstellung von Ethylenoxid durch Direktoxidation von Ethylen mit Luft oder Sauerstoff |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20010075292A KR20010075292A (ko) | 2001-08-09 |
KR100585360B1 true KR100585360B1 (ko) | 2006-06-01 |
Family
ID=7881988
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020017003676A KR100585360B1 (ko) | 1998-09-23 | 1999-09-20 | 에틸렌을 공기 또는 산소로 직접 산화시켜 에틸렌옥시드를 제조하는 방법 |
Country Status (20)
Country | Link |
---|---|
US (1) | US6397599B1 (ko) |
EP (1) | EP1115713B1 (ko) |
JP (1) | JP4582910B2 (ko) |
KR (1) | KR100585360B1 (ko) |
CN (1) | CN1150177C (ko) |
AR (1) | AR020499A1 (ko) |
AT (1) | ATE266014T1 (ko) |
AU (1) | AU5979799A (ko) |
BR (1) | BR9913938B1 (ko) |
CA (1) | CA2343767C (ko) |
DE (2) | DE19843654A1 (ko) |
ES (1) | ES2221477T3 (ko) |
ID (1) | ID27730A (ko) |
MY (1) | MY121093A (ko) |
PL (1) | PL196670B1 (ko) |
RU (1) | RU2229477C2 (ko) |
SA (1) | SA99200694B1 (ko) |
TW (1) | TWI235154B (ko) |
UA (1) | UA60382C2 (ko) |
WO (1) | WO2000017177A1 (ko) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101851020B (zh) * | 2010-04-29 | 2012-02-01 | 浙江省电力试验研究院 | 直流锅炉定向氧化给水处理工艺 |
JP2012214399A (ja) * | 2011-03-31 | 2012-11-08 | Nippon Shokubai Co Ltd | エチレンオキシドの製造方法 |
FR3001969B1 (fr) * | 2013-02-12 | 2015-08-21 | IFP Energies Nouvelles | Procede de production d'oxyde d'ethylene a partir d'un flux d'ethanol thermiquement integre |
JP6174352B2 (ja) * | 2013-03-29 | 2017-08-02 | 株式会社日本触媒 | エチレンオキシドの製造方法 |
JP6391913B2 (ja) * | 2013-03-29 | 2018-09-19 | 株式会社日本触媒 | エチレンオキシドの製造方法 |
WO2014184751A1 (en) * | 2013-05-14 | 2014-11-20 | Saudi Basic Industries Corporation | Method and apparatus for improved efficiency in an ethylene oxide/ethylene glycol process |
CN104819448B (zh) * | 2015-03-04 | 2017-04-05 | 中国天辰工程有限公司 | 一种环氧氯丙烷皂化工艺的能量供应*** |
CN104976671B (zh) * | 2015-06-26 | 2021-07-23 | 中国能源建设集团广东省电力设计研究院有限公司 | 背压式小汽机驱动给水泵的宽负荷供热节能*** |
KR101811561B1 (ko) * | 2017-09-29 | 2017-12-26 | 선테코 유한회사 | 복합화학공정 내의 증발스팀재압축기를 이용한 에너지 재활용 시스템 |
CN109395580A (zh) * | 2018-12-10 | 2019-03-01 | 中石化上海工程有限公司 | 环氧乙烷-乙二醇装置含氧尾气的处理方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
LU56620A1 (ko) | 1967-08-08 | 1968-11-14 | ||
JPS507574B1 (ko) * | 1968-05-10 | 1975-03-27 | ||
JPS514110A (en) * | 1974-04-30 | 1976-01-14 | Snam Progetti | Kisoniokeru jukikagobutsunobubunsankaho oyobi soreojitsushisurutamenosochi |
US4099383A (en) * | 1976-06-21 | 1978-07-11 | Texaco Inc. | Partial oxidation process |
US4074981A (en) * | 1976-12-10 | 1978-02-21 | Texaco Inc. | Partial oxidation process |
US4121912A (en) * | 1977-05-02 | 1978-10-24 | Texaco Inc. | Partial oxidation process with production of power |
JPS5767573A (en) * | 1980-10-16 | 1982-04-24 | Nippon Shokubai Kagaku Kogyo Co Ltd | Catalytic gas-phase oxidation of hydrocarbon and plant |
DE3935030A1 (de) | 1989-10-20 | 1991-04-25 | Linde Ag | Verfahren zur synthese von ethylenoxid |
JP2778878B2 (ja) * | 1991-09-12 | 1998-07-23 | 株式会社日本触媒 | エチレンオキシドの製造方法 |
-
1998
- 1998-09-23 DE DE19843654A patent/DE19843654A1/de not_active Withdrawn
-
1999
- 1999-09-17 TW TW088116105A patent/TWI235154B/zh not_active IP Right Cessation
- 1999-09-20 AT AT99969411T patent/ATE266014T1/de not_active IP Right Cessation
- 1999-09-20 BR BRPI9913938-3A patent/BR9913938B1/pt not_active IP Right Cessation
- 1999-09-20 DE DE59909416T patent/DE59909416D1/de not_active Expired - Lifetime
- 1999-09-20 UA UA2001042716A patent/UA60382C2/uk unknown
- 1999-09-20 ES ES99969411T patent/ES2221477T3/es not_active Expired - Lifetime
- 1999-09-20 RU RU2001111010/04A patent/RU2229477C2/ru active
- 1999-09-20 EP EP99969411A patent/EP1115713B1/de not_active Expired - Lifetime
- 1999-09-20 CA CA002343767A patent/CA2343767C/en not_active Expired - Lifetime
- 1999-09-20 KR KR1020017003676A patent/KR100585360B1/ko active IP Right Grant
- 1999-09-20 US US09/762,797 patent/US6397599B1/en not_active Expired - Lifetime
- 1999-09-20 JP JP2000574087A patent/JP4582910B2/ja not_active Expired - Lifetime
- 1999-09-20 PL PL346778A patent/PL196670B1/pl unknown
- 1999-09-20 AU AU59797/99A patent/AU5979799A/en not_active Abandoned
- 1999-09-20 MY MYPI99004060A patent/MY121093A/en unknown
- 1999-09-20 CN CNB998112852A patent/CN1150177C/zh not_active Expired - Lifetime
- 1999-09-20 ID IDW20010668A patent/ID27730A/id unknown
- 1999-09-20 WO PCT/EP1999/006941 patent/WO2000017177A1/de active IP Right Grant
- 1999-09-22 AR ARP990104763A patent/AR020499A1/es active IP Right Grant
- 1999-10-18 SA SA99200694A patent/SA99200694B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
ES2221477T3 (es) | 2004-12-16 |
BR9913938B1 (pt) | 2009-08-11 |
AR020499A1 (es) | 2002-05-15 |
SA99200694B1 (ar) | 2006-08-21 |
PL346778A1 (en) | 2002-02-25 |
DE59909416D1 (de) | 2004-06-09 |
EP1115713B1 (de) | 2004-05-06 |
PL196670B1 (pl) | 2008-01-31 |
MY121093A (en) | 2005-12-30 |
CN1319098A (zh) | 2001-10-24 |
US6397599B1 (en) | 2002-06-04 |
RU2229477C2 (ru) | 2004-05-27 |
CA2343767C (en) | 2008-04-15 |
WO2000017177A1 (de) | 2000-03-30 |
AU5979799A (en) | 2000-04-10 |
TWI235154B (en) | 2005-07-01 |
CA2343767A1 (en) | 2000-03-30 |
BR9913938A (pt) | 2001-06-12 |
CN1150177C (zh) | 2004-05-19 |
JP4582910B2 (ja) | 2010-11-17 |
KR20010075292A (ko) | 2001-08-09 |
ID27730A (id) | 2001-04-26 |
DE19843654A1 (de) | 2000-03-30 |
UA60382C2 (uk) | 2003-10-15 |
EP1115713A1 (de) | 2001-07-18 |
JP2003521454A (ja) | 2003-07-15 |
ATE266014T1 (de) | 2004-05-15 |
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