KR100549457B1 - 오일 조성물용 스타 중합체 점도지수 증진제 - Google Patents
오일 조성물용 스타 중합체 점도지수 증진제 Download PDFInfo
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- KR100549457B1 KR100549457B1 KR1020007009006A KR20007009006A KR100549457B1 KR 100549457 B1 KR100549457 B1 KR 100549457B1 KR 1020007009006 A KR1020007009006 A KR 1020007009006A KR 20007009006 A KR20007009006 A KR 20007009006A KR 100549457 B1 KR100549457 B1 KR 100549457B1
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/12—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing conjugated diene
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
- C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M143/00—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
- C10M143/10—Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aromatic monomer, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/251—Alcohol fueled engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/28—Rotary engines
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- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Lubricants (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
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Abstract
Description
중합체 | 단계 1 블록 | 단계 2 블록 | 단계 3 블록 | 단계 4 블록 | 단계 1 MW(실제) | 단계 2 MW(실제) | 단계 3 MW(실제) | 단계 4 MW(실제) | 폴리스티렌 함량, % 계산 암 MW 기준. | 용융 점도 120℃, Mpa-s | I1/I2 |
1 | I1 | S | B | I2 | 32,500 | 10,200 | 3,300 | 19,500 | 15.6 | 2.8 | 1.67 |
2 | I1 | S | B | I2 | 36,000 | 5,800 | 7,300 | 14,000 | 9.2 | 2.2 | 2.57 |
3 | S | I1 | B | I2 | 3,100 | 26,100 | 6,000 | 14,200 | 6.3 | 1.6 | 1.84 |
4 | I1 | B | I2 | -- | 31,500 | 4,400 | 21,400 | -- | 0 | 1.3 | 1.47 |
5 | I1 | B | I2 | -- | 37,600 | 3,600 | 13,600 | -- | 0 | 1.1 | 2.76 |
6a | I | S | na | na | 65,000 | 35,000 | na | na | 35 | 1.7 | -- |
7 | S | I | -- | -- | 3,500 | 51,000 | -- | -- | 6.4 | 1.7 | -- |
8 | I1 | S | I2 | -- | 34,200 | 9,100 | 14,300 | -- | 16.5 | 1.8 | 2.39 |
na = 적용 불가능하거나 이용 불가능. a = 직쇄 중합체. |
중합체 | 중합체 %wt | Kin Vis, 100℃, cSt | VI | TBSb, 150℃, cP | DIN Vis 손실, % | DIN P, MPa | CCSc -20℃ cP | TPId -30℃, cP |
1 | 1.02 | 13.92 | 163-200a | 3.67 | 10.4 | 14.2 | 2,740 | 22,900 |
2 | 0.96 | 14.02 | 161 | 3.67 | 10.9 | 14.2 | 2,980 | 32,800 |
3 | 1.08 | 13.92 | 161 | 3.69 | 4.0 | 14.2 | 2,890 | 24,400 |
4 | 0.93 | 13.97 | 163 | 3.51 | 11.0 | 14.7 | 2,800 | 24,100 |
5 | 0.94 | 13.87 | 161 | 3.59 | 8.8 | 13.4 | 2,850 | 23,300 |
6 | 1.21 | 13.47 | 164 | 3.37 | 2.0 | 13.4 | 2,750 | 37,200 |
7 | 0.95 | 14.00 | 162 | 3.58 | 11.8 | 17.0 | 2,970 | 36,600 |
8 | 1.06 | 13.93 | 169 | 3.58 | 8.2 | 14.5 | 2,980 | 30,200 |
na = 적용 불가능하거나 이용 불가능. a) 시간에 따라 VI 증진 b) HTHSR 점도 한계는 최하 2.9 cP이다(SAE 표준 J300) c) 크랭킹 점도 한계는 최고 3500 cP이다(SAE 표준 J300) d) 펌핑 점도 한계는 최고 60,000 cP이다(SAE 표준 J300) |
중합체 | 중합체 %wt | Kin Vis, 100℃, cSt | VI | TBS, 150℃, cP | CCS, -25℃, cP | TPI, -35℃, cP |
1 | 0.72 | 10.40 | 161a | 3.05 | 3,290 | 29,000 |
2 | 0.67 | 10.40 | 159 | 3.07 | 3,490 | 31,200 |
3 | 0.76 | 10.38 | 159 | 3.07 | 3,510 | 31,000 |
4 | 0.66 | 10.66 | 162 | 3.05 | 3,230 | 27,600 |
5 | 0.68 | 10.65 | 161 | 3.02 | 3,220 | 28,700 |
6 | 0.89 | 10.35 | 162 | 2.88 | 3,280 | 46,800 |
7 | 0.68 | 10.62 | 166 | 3.01 | 3,330 | 47,000 |
8 | 0.75 | 10.54 | 165 | 3.02 | 3,290 | 41,400 |
a) 이 경우에 시간 의존성 행동은 시간에 따른 동점도 모니터에 의해 입증되지 않았다. |
Claims (8)
- (Ⅰ) (S-EP-EB-EP')n-X(Ⅱ) (EP-S-EB-EP')n-X(Ⅲ) (EP-EB-S-EP')n-X로 이루어진 그룹에서 선택되는 구조를 가지고,EP가 수소화 전에 6,500 내지 85,000의 수평균 분자량(MW1)을 갖는 폴리이소프렌의 바깥쪽 수소화된 블록이고;EB가 수소화 전에 1,500 내지 15,000의 수평균 분자량(MW2)과 85% 이상의 1,4-중합율을 갖는 폴리부타디엔의 수소화된 블록이며;EP'가 수소화 전에 1,500 내지 55,000의 수평균 분자량(MW3)을 갖는 폴리이소프렌의 안쪽 수소화된 블록이며;S가 S 블록이 바깥쪽에 있을 경우에는(Ⅰ) 1,000 내지 4,000 및 S 블록이 안쪽에 있을 경우에는(Ⅱ 또는 Ⅲ) 2,000 내지 15,000의 수평균 분자량(MWs)을 갖는 폴리스티렌의 블록이며;스타 중합체 구조가 3 중량% 내지 15 중량%의 폴리부타디엔을 포함하고, MW1/MW3의 비는 0.75:1 내지 7.5:1이며, X는 폴리알케닐 커플링제의 핵이며, n은 리빙 블록 공중합체 분자 몰당 2몰 이상의 폴리알케닐 커플링제와 커플링될 때 스타 중합체에서 블록 공중합체 암의 수인 스타 중합체.
- 제 1 항에 있어서, 폴리알케닐 커플링제가 디비닐벤젠인 스타 중합체.
- 제 2 항에 있어서, n이 리빙 블록 공중합체 분자 몰당 3몰이상의 디비닐벤젠과 커플링될 때 암의 수인 스타 중합체.
- 제 1 항 내지 제 3 항 중 어느 한 항에 있어서, 수소화 전에 바깥쪽 폴리이소프렌 블록의 수평균 분자량(MW1)이 15,000 내지 65,000이고, 수소화 전에 플리부타디엔 블록의 수평균 분자량(MW2)이 2,000 내지 6,000이며, 수소화 전에 안쪽 폴리이소프렌 블록의 수평균 분자량(MW3)이 5,000 내지 40,000이며, 폴리스티렌 블록의 수평균 분자량(MWs)이 S 블록이 바깥쪽에 있을 경우에(Ⅰ) 2,000 내지 4,000이고 S 블록이 안쪽에 있을 경우에는 4,000 내지 12,000이며, 스타 중합체가 10 중량% 이하의 폴리부타디엔을 포함하며, MW1/MW3의 비가 0.9:1 내지 5:1인 스타 중합체.
- 제 1 항 내지 제 3 항 중 어느 한 항에 있어서, 폴리부타디엔 블록의 1,4-중합율이 89%이상인 스타 중합체.
- 제 1 항 내지 제 3 항 중 어느 한 항에 있어서, 폴리이소프렌 블록과 폴리부타디엔 블록이 95% 이상 수소화된 스타 중합체.
- 베이스 오일과:제 1 항 내지 제 3 항 중 어느 한 항의 스타 중합체의 점도지수 증진량을 포함하는 오일 조성물.
- 베이스 오일 75 중량% 이상과:제 1 항 내지 제 3 항 중 어느 한 항의 스타 중합체 5 중량% 내지 25 중량%를 포함하는 오일 조성물용 중합체 농축액.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US7523098P | 1998-02-19 | 1998-02-19 | |
US60/075,230 | 1998-02-19 |
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KR20010024941A KR20010024941A (ko) | 2001-03-26 |
KR100549457B1 true KR100549457B1 (ko) | 2006-02-06 |
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KR1020007009006A KR100549457B1 (ko) | 1998-02-19 | 1999-02-16 | 오일 조성물용 스타 중합체 점도지수 증진제 |
Country Status (13)
Country | Link |
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US (1) | US6034042A (ko) |
EP (1) | EP1064347B1 (ko) |
JP (1) | JP4234325B2 (ko) |
KR (1) | KR100549457B1 (ko) |
CN (1) | CN1114683C (ko) |
AU (1) | AU738659B2 (ko) |
BR (1) | BR9908068B1 (ko) |
CA (1) | CA2321006C (ko) |
DE (1) | DE69909265T2 (ko) |
ES (1) | ES2201684T3 (ko) |
RU (1) | RU2201939C2 (ko) |
TW (1) | TW428025B (ko) |
WO (1) | WO1999042542A1 (ko) |
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US9879201B2 (en) * | 2014-02-28 | 2018-01-30 | Cosmo Oil Lubricants Co., Ltd. | Engine oil composition |
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JP7066413B2 (ja) | 2015-06-12 | 2022-05-13 | クレイトン・ポリマーズ・ユー・エス・エル・エル・シー | ケーブル充填用途用熱活性化ゲル |
CN107848162B (zh) | 2015-06-12 | 2019-11-15 | 科腾聚合物美国有限责任公司 | 用于软皮的组合物及其用途 |
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-
1999
- 1999-02-16 KR KR1020007009006A patent/KR100549457B1/ko active IP Right Grant
- 1999-02-16 EP EP99911673A patent/EP1064347B1/en not_active Expired - Lifetime
- 1999-02-16 JP JP2000532489A patent/JP4234325B2/ja not_active Expired - Lifetime
- 1999-02-16 CA CA002321006A patent/CA2321006C/en not_active Expired - Lifetime
- 1999-02-16 WO PCT/EP1999/001003 patent/WO1999042542A1/en active IP Right Grant
- 1999-02-16 RU RU2000124095/04A patent/RU2201939C2/ru not_active IP Right Cessation
- 1999-02-16 DE DE69909265T patent/DE69909265T2/de not_active Expired - Lifetime
- 1999-02-16 BR BRPI9908068-0A patent/BR9908068B1/pt not_active IP Right Cessation
- 1999-02-16 AU AU30284/99A patent/AU738659B2/en not_active Ceased
- 1999-02-16 ES ES99911673T patent/ES2201684T3/es not_active Expired - Lifetime
- 1999-02-16 CN CN99803096A patent/CN1114683C/zh not_active Expired - Lifetime
- 1999-02-17 US US09/251,508 patent/US6034042A/en not_active Expired - Lifetime
- 1999-02-23 TW TW088102599A patent/TW428025B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
BR9908068A (pt) | 2000-10-24 |
WO1999042542A1 (en) | 1999-08-26 |
ES2201684T3 (es) | 2004-03-16 |
TW428025B (en) | 2001-04-01 |
CA2321006A1 (en) | 1999-08-26 |
CN1291223A (zh) | 2001-04-11 |
EP1064347A1 (en) | 2001-01-03 |
AU3028499A (en) | 1999-09-06 |
EP1064347B1 (en) | 2003-07-02 |
DE69909265D1 (de) | 2003-08-07 |
CA2321006C (en) | 2008-01-22 |
BR9908068B1 (pt) | 2009-12-01 |
AU738659B2 (en) | 2001-09-20 |
US6034042A (en) | 2000-03-07 |
CN1114683C (zh) | 2003-07-16 |
RU2201939C2 (ru) | 2003-04-10 |
DE69909265T2 (de) | 2004-02-05 |
JP4234325B2 (ja) | 2009-03-04 |
KR20010024941A (ko) | 2001-03-26 |
JP2002504589A (ja) | 2002-02-12 |
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