KR100548125B1 - Thinning fruit agent comprising sulfate as an effective component - Google Patents

Thinning fruit agent comprising sulfate as an effective component Download PDF

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KR100548125B1
KR100548125B1 KR1020010059227A KR20010059227A KR100548125B1 KR 100548125 B1 KR100548125 B1 KR 100548125B1 KR 1020010059227 A KR1020010059227 A KR 1020010059227A KR 20010059227 A KR20010059227 A KR 20010059227A KR 100548125 B1 KR100548125 B1 KR 100548125B1
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red
fruit
sulfate
znso
concentration
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KR20030026415A (en
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김명희
허병주
정일선
정일경
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주식회사 이즈텍
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/02Sulfur; Selenium; Tellurium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/06Aluminium; Calcium; Magnesium; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/08Alkali metal chlorides; Alkaline earth metal chlorides
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • A01N59/20Copper

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Cultivation Of Plants (AREA)

Abstract

본 발명은 황산염을 유효성분으로 하는 적과제에 관한 것으로서, 보다 상세하게는 약해가 적고, 처리시기에 제한 없이 적과율을 보다 향상시킬 수 있는 적과제에 관한 것이다. 상기 적과제를 사용하면 높은 적과 효과를 얻을 수 있기 때문에, 양분의 소모를 방지하여 과실의 발육을 증진시킬 수 있다.The present invention relates to a red object having a sulfate as an active ingredient, and more particularly, to a red object which can improve the red fruit rate without limiting the weakness and more particularly the treatment time. Since the use of the red object can achieve a high effect with the red, it is possible to prevent the consumption of nutrients to promote the development of the fruit.

적과제, 황산염Red task, sulfate

Description

황산염을 유효성분으로 하는 적과제{Thinning fruit agent comprising sulfate as an effective component}Thickening fruit agent comprising sulfate as an effective component

본 발명은 과실의 발육을 촉진시키기 위하여 필요 없는 꽃이나 과실은 떨어뜨리는 적과제에 관한 것으로서, 보다 상세하게는 약해가 적고, 살포시기에 제한없이 적과율을 보다 향상시킬 수 있는 적과제에 관한 것이다.The present invention relates to a red fruit that drops unnecessary flowers or fruits in order to promote fruit development. More particularly, the present invention relates to a red fruit which can improve the red fruit rate without limiting the spraying time.

과실의 발육은 전년에 수체(樹體)에 비축된 저장양분과 뿌리에서 흡수된 양분 및 수분, 잎에서 생산된 탄수화물 등의 원활한 공급에 의해 이루어진다. 저장양분과 뿌리에서 흡수되는 양분, 수분이 충분할 경우, 잎에서 생산된 탄수화물이 과실로 공급되는 양에 따라 과실의 크기가 결정된다. 따라서, 과실이 정상적으로 발육되기 위해서는 적과를 통해 과실수를 적당히 제한하는 것이 바람직하다.The fruit is developed by the smooth supply of stocks stored in water bodies last year, nutrients and moisture absorbed from roots, and carbohydrates produced from leaves. If there is sufficient nutrients and water absorbed from the stored nutrients and roots, the size of the fruit is determined by the amount of carbohydrate produced from the leaves. Therefore, in order for fruit to develop normally, it is preferable to limit fruit number appropriately through red fruit.

적과는 필요 없는 양분 소모를 막아 과실의 초기 생육을 돕기 위한 작업으로서, 개화전 꽃봉오리를 제거하는 적뢰와 적과전 개화기에 꽃을 솎아주는 적화를 모두 포함한다. 이론상으로 적뢰를 하는 것이 과실의 크기를 가장 크게 하지만 우리 나라의 사과개화기 전후의 기상은 아주 불안정하기 때문에 너무 일찍 적뢰 또는 적화를 통해 작업을 완료하면 작업에 의한 피해과가 발생하게 되고, 안정된 결실량을 확보하지 못해 목표 수량에 미달되는 경우가 발생하게 된다. 이러한 적뢰 및 적화는 과실이 결실되기 전에 실시되기 때문에 예비적 또는 보조적인 성격을 띠고 있으나, 적과의 노력 분산 차원에서도 필요한 작업이다.The red fruit works to prevent the unnecessary consumption of nutrients to help the early growth of the fruit, and includes both red mines that remove the buds before flowering and red flowers that bloom on the red flowers before flowering. In theory, the mine is the largest fruit, but the weather before and after the apple flowering period in our country is very unstable, so if you complete the work through the mine or reddening too early, the damage caused by the work will occur, and you will have a stable amount of fruit. Failure to meet the target quantity will occur. These mines and redundancies are preliminary or subsidiary because they are carried out before the fruit is cleared, but they are also necessary to disperse efforts with the enemy.

적과는 수작업에 의한 것과 약제에 의한 것으로 나뉘어 진다. 수작업에 의한 적과는 고용노력에 대한 의존도가 매우 높은 작업으로서 농촌의 노동 인구감소로 인한 노동력 부족, 노동의 질저화, 높은 인건비 등으로 생산비 부담이 가중되는 문제점을 갖고 있다. 따라서, 최근에는 수작업에 의한 적과 보다는 약제에 의한 적과가 활발히 이용되고 있는 실정이다. Red fruit is divided into manual and pharmaceutical. The antagonism by manual labor is highly dependent on the employment effort, and has a problem that the production cost burden is increased due to labor shortage, labor quality deterioration and high labor cost due to the declining labor force in rural areas. Therefore, in recent years, a red fruit with a drug rather than a manual fruit is actively used.

현재 이용되고 있는 약제에 의한 적과의 원리는 약제에 대한 꽃이나 과실의 감수성 차를 이용하여 적당량의 낙과를 유발시키는 것으로 다음의 세가지 원리를 이용하고 있다. 첫번째는, 꽃가루발아(pollen germination)를 억제하거나 암술머리(stigma)를 손상시켜 꽃가루가 암술머리에 수분되는 현상이나 화분관 신장을 방해함으로써 꽃을 탈락시키는 것으로 여기에 해당되는 약제로는 D-N 아세테이트제(2.4-dinitro-6-cyclohexyl acetate)가 있다. 두번째는, 종자내 생장조절물질의 불균형을 초래하여 수정과 종자의 정상적인 배발육을 저해함으로써 조기낙과를 유발하는 것으로 NAA(naphthalene acetate)와 NAA 유도체인 NAAm(naphthalene acetamide-m)이 여기에 속하나 살포농도와 살포당시의 기상조건에 상당히 민감한 반응을 하고 부작용이 발생하여 최근에는 사용하지 않고 있다. 세번째는, 결과지(結果枝)와 과실을 연결하는 괴경부 통도조직속의 유관속 조직을 붕괴시켜 동화물질과 양분 및 수분이 과실로 전달되는 것을 억제함으로써 과실 탈락을 유도하는 것으로 나크, 카바릴 및 기타 살충제가 여기에 해당된다.The principle of the red fruit by the medicine currently used is to induce an appropriate amount of fruit drop by using the sensitivity of the flower or fruit to the medicine, and the following three principles are used. The first is to prevent pollen germination or damage stigma, which causes pollen to pollinate the stigma, or to block pollen elongation. 2.4-dinitro-6-cyclohexyl acetate). Secondly, it causes imbalance of growth regulators in seeds, inhibiting fertilization and normal embryonic development of seeds, leading to early fallout. It has not been used recently because it reacts very sensitive to the concentration and weather conditions at the time of spraying and has side effects. The third is to induce fruit dropping by disrupting the flow of ducts in the tuber ductal tissue that connects the resultant paper with the fruit, thereby inhibiting the transfer of assimilation material, nutrients and water to the fruit. Nac, cabaryl and other insecticides This is the case.

현재 우리 농촌의 노동력 부족 현상이 날로 심화되고 있는 시점에서 약제 적과제에 대한 의존도는 더욱 증가되고 있다. 그러나, 현재까지 사용되고 있는 적과제는 독성이 강하기 때문에 수정을 돕기 위해 방사시키는 벌에 치명적인 영향을 끼친다. 또한, 과실의 표면이 거칠어진 동록과(銅綠果)를 발생시키기도 하며, 발아중인 신초엽에 약해를 유발시켜 원하는 만큼 알맞게 착과량을 조절하지는 못한다는 문제점이 있었다.At present, as the labor shortage in Korea is intensifying, the dependence on pharmaceutical projects is increasing. However, red targets used to date are highly toxic and have a lethal effect on bees that are released to aid fertilization. In addition, there is a problem that the surface of the fruit to produce a rough greenery (銅綠 果), and cause the damage to the germination of the new shoots, there was a problem that can not adjust the amount of fruiting as desired.

본 발명은 상기한 문제점을 해결하기 위하여 안출된 것으로서, 본 발명이 이루고자 하는 기술적 과제는 약해가 없으며, 살포시기에 제한 없이 고효율의 적과 효과를 얻을 수 있는 적과제를 제공하는 것이다.
The present invention has been made to solve the above problems, the technical problem to be achieved by the present invention is not weak, it is to provide a task that can achieve a high efficiency enemy and effect without limitation in the spraying time.

상기와 같은 목적을 달성하기 위하여, 본 발명은 황산염을 유효성분으로 하는 적과제를 제공한다.In order to achieve the above object, the present invention provides an antagonist having sulfate as an active ingredient.

상기에서 황산염은 Na2SO4, MgSO4, MnSO4, FeSO4, K2SO4, (NH4)2SO4, CuSO4, BaSO4, CaSO4 및 ZnSO4로 이루어진 군으로부터 선택되는 하나 이상인 것을 특징으로 한다.In the above sulfate is Na 2 SO 4 , MgSO 4 , MnSO 4 , FeSO 4 , K 2 SO 4 , (NH 4 ) 2 SO 4 , CuSO 4 , BaSO 4 , CaSO 4 and ZnSO 4 It is characterized in that at least one selected from the group consisting of.

이하 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail.

본 발명에 따른 적과제는 황산염을 유효성분으로 하는 것을 특징으로 한다. 상기에서 황산염은 Na2SO4, MgSO4, MnSO4, FeSO4, K2SO4, (NH4)2SO4, CuSO4, BaSO4, CaSO4 및 ZnSO4로 이루어진 군으로부터 선택되는 하나 이상인 것이 바람직하며, 구체적으로 황산염이 전체 적과제에 대해 0.08 내지 0.3%인 것이 바람직하다. 상기에서 황산염이 0.08% 미만이면 적절한 적과율을 확보하기가 어렵다는 문제점이 발생할 수 있으며, 0.3%를 초과하게 되면, 생식조직이 아닌 잎조직에 약해를 유발할 수 있기 때문에 상기 농도의 범위로 적과제에 함유되는 것이 바람직하다.Red fruit according to the invention is characterized in that the sulfate as an active ingredient. In the above sulfate is Na 2 SO 4 , MgSO 4 , MnSO 4 , FeSO 4 , K 2 SO 4 , (NH 4 ) 2 SO 4 , It is preferably at least one selected from the group consisting of CuSO 4 , BaSO 4 , CaSO 4 and ZnSO 4 , specifically it is preferred that the sulfate is 0.08 to 0.3% with respect to the total solution. If the sulfate is less than 0.08% may cause a problem that it is difficult to secure a proper red fruit rate, and if the amount exceeds 0.3%, it may cause damage to leaf tissues rather than reproductive tissues. It is desirable to be.

본 발명에 따른 적과제에는 전착제가 추가로 첨가되는 것이 바람직하다. 전착제는 살포액의 물리성을 향상시키는 물질로서, 그 자체는 약효를 가지지 않으므로 보조제라고도 한다. 상기 전착제는 헥사코나졸계(hexaconazole), 실록산계(siloxane) 또는 알킬아릴 폴리에톡실산계(alkylaryl polyethoxylate)가 사용되는 것이 바람직하나 이에 제한되는 것은 아니며, 구체적으로 실록산계를 0.5% 농도 이하로 첨가하는 것이 가장 바람직하다. 상기에서 전착제의 농도가 0.5%를 초과하게 되면 과실수의 잎조직에 황산염 화합물이 과도하게 흡수되어 잎마름 현상과 같은 문제점이 발생할 수 있으므로, 상기 농도를 초과하지 않도록 첨가 하는 것이 바람직하다.It is preferable that an electrodeposition agent is further added to the red object which concerns on this invention. The electrodeposition agent is a substance that improves the physical properties of the spraying liquid, and is also referred to as an adjuvant because it does not have a medicinal effect. The electrodeposition agent is preferably hexaconazole, siloxane, or alkylaryl polyethoxylate, but is not limited thereto. Most preferred. When the concentration of the electrodeposition agent exceeds 0.5%, since the sulfate compound is excessively absorbed into the leaf tissue of the fruit water, problems such as leaf dryness may occur, it is preferable to add so as not to exceed the concentration.

또한, 본 발명에 따른 적과제에는 대상 식물에 적절하게 살포하기 위하여 용매가 첨가되는 것이 바람직하며, 물을 용매로 사용하는 것이 바람직하다. 상기에서 물 이외에 다른 용매를 사용하는 경우 과수에 해가 될 우려가 있고, 적과제에 함유되는 황산염이 수용성인 특성을 갖고 있기 때문에 물을 용매로 사용하는 것이 가장 바람직하다.In addition, it is preferable that a solvent is added to the red fruits according to the present invention in order to properly spray the target plant, and water is preferably used as the solvent. In the case of using a solvent other than water as described above, water may be harmful to the fruit tree, and since the sulfate contained in the red fruit has water-soluble properties, water is most preferably used as the solvent.

한편, 동일한 약제, 동일한 농도라 하더라도 적과제를 살포할 당시의 여러 가지 상황에 따라 적과 효과가 다르게 나타날 수 있다. 즉, 적과제의 살포시기는 적과율에 많은 영향을 미치는데, 적절한 살포시기는 개화직전부터 만개직후까지로 매우 다양하다. 본 발명에서 후지사과와 홍로사과를 대상으로 하여 ZnSO4를 포함하는 적과제를 다양한 시기별로 살포한 결과, 개화직전부터 만개직후까지 70%이상의 적과율을 보였다. 따라서, 본 발명에 따른 적과제는 살포시기에 있어 특별한 제한 없이 사용될 수 있는 잇점이 있다. 한편, 본 발명의 일 실시예에서 만개시에 살포하였을 때 90% 이상의 적과율을 보임을 확인할 수 있는 바, 만개시에 살포하는 것이 가장 바람직함을 확인할 수 있었다.On the other hand, even if the same drug, the same concentration may be different from the enemy depending on various situations at the time of spraying the red object. In other words, the timing of spraying red fruits has a large effect on the rate of red fruits, and the proper spraying time varies from just before flowering to just after full bloom. In the present invention, as a result of spraying red fruits containing ZnSO 4 for various time periods for Fuji apple and red apple, it showed more than 70% of red fruits from just before flowering to just after full bloom. Therefore, the red object according to the present invention has the advantage that can be used without particular limitation in the timing of spraying. On the other hand, in one embodiment of the present invention can be confirmed that when spraying at full bloom show more than 90% red over rate, it was confirmed that the most preferred spraying at full bloom.

본 발명에 따른 적과제는 수화제, 액제, 액상수화제, 입제, 캡슐제, 도포제, 분제 또는 미분제의 형태로 과수에 살포될 수 있으며, 구체적으로 액상수화제의 형태로 살포되는 것이 바람직하다.The red fruit preparation according to the present invention may be applied to the fruit water in the form of a hydrating agent, a liquid, a liquid hydrating agent, a granule, a capsule, a coating agent, a powder or a powder, and in particular, preferably sprayed in the form of a liquid hydrating agent.

본 발명에 따른 적과제는 사과, 복숭아, 배, 살구, 감, 자두, 양앵두, 매실, 귤, 유자, 레몬, 아몬드, 커피, 가지과 식물의 적과 시 이용될 수 있다. Red fruits according to the present invention can be used for apples, peaches, pears, apricots, persimmons, plums, cherry tomatoes, plums, tangerines, citron, lemons, almonds, coffee, eggplants.

이하, 본 발명을 실시예에 의해 상세히 설명한다.Hereinafter, the present invention will be described in detail by way of examples.

단, 하기 실시예는 본 발명을 예시하는 것일 뿐, 본 발명의 내용이 하기 실시예에 한정되는 것은 아니다.However, the following examples are merely to illustrate the invention, but the content of the present invention is not limited to the following examples.

<제조예 1 내지 4><Production Examples 1 to 4>

황산염을 포함하는 적과제의 제조Preparation of Red Fruit Containing Sulfate

ZnSO4, MnSO4, Na2SO4 및 MgSO4 ZnSO4가 포함된 적과제를 하기 표 1 내지 표 4에서와 같은 함량으로 제조하였으며, 이때 전착제로는 실루엣(동부정밀화학 (주))을 사용하였다.ZnSO 4 , With MnSO 4 , Na 2 SO 4 and MgSO 4 ZnSO 4 red fruit was prepared in the same amount as in Table 1 to Table 4, wherein the electrodeposition agent was used as a silhouette (Eastern Fine Chemicals Co., Ltd.).

적과제 성분 함량Red component content ZnSO4의농도(mM)Concentration of ZnSO 4 (mM) ZnSO4(g)ZnSO 4 (g) 실루엣(㎖)Silhouette (ml) 물(ℓ)Water (ℓ) 1One 0.290.29 55 1One 22 0.580.58 55 1One 33 0.870.87 55 1One 55 1.451.45 55 1One 77 2.032.03 55 1One 1010 2.92.9 55 1One 2020 5.85.8 55 1One

적과제 성분 함량Red component content MnSO4의농도(mM)Concentration of MnSO 4 (mM) MnSO4(g)MnSO 4 (g) 실루엣(㎖)Silhouette (ml) 물(ℓ)Water (ℓ) 1One 0.170.17 55 1One 22 0.340.34 55 1One 33 0.510.51 55 1One 55 0.850.85 55 1One 77 1.191.19 55 1One

적과제 성분 함량Red component content Na2SO4의농도(mM)Concentration of Na 2 SO 4 (mM) Na2SO4(g)Na 2 SO 4 (g) 실루엣(㎖)Silhouette (ml) 물(ℓ)Water (ℓ) 1One 0.160.16 55 1One 22 0.320.32 55 1One 33 0.480.48 55 1One 55 0.80.8 55 1One 77 1.121.12 55 1One

적과제 성분 함량Red component content MnSO4+ZnSO4의 농도(mM)Concentration of MnSO 4 + ZnSO 4 (mM) MnSO4+ZnSO4(g)MnSO 4 + ZnSO 4 (g) 실루엣(㎖)Silhouette (ml) 물(ℓ)Water (ℓ) 1One 0.460.46 55 1One 22 0.920.92 55 1One 33 1.381.38 55 1One 55 1.841.84 55 1One 77 3.223.22 55 1One

<실시예 1><Example 1>

ZnSOZnSO 44 의 농도 및 시기에 따른 적과율 및 약해유무Red Overflow Rate and Weakness According to Concentration and Season

상기 제조예 1에서와 같이 제조한, ZnSO4를 포함하는 적과제를 한그루당 400㎖씩 후지사과 및 홍로사과에 각 시기별로 살포(1차 살포 및 2차 살포)한 후, 적과율 및 약해유무를 조사하였다.After spraying the red apples containing ZnSO 4 prepared as in Preparation Example 1 each time 400 ml per Fuji apple and red apples (primary spraying and secondary spraying), the red fruit ratio and the presence of harmful Investigate.

후지사과에서의 적과율(%)Redness rate at Fuji apple (%) ZnSO4 농도(mM)ZnSO 4 concentration (mM) 33 55 77 적과제 처리 시기When to redeem your assignments 만개직전Just before full bloom 1차 살포1st spray 3838 7070 7878 2차 살포Secondary spray 5454 8484 7878 만개시In full bloom 1차 살포1st spray 9292 9292 8484 2차 살포Secondary spray 8686 8888 9696

홍로사과에서의 적과율(%)Redness rate in red apples (%) ZnSO4 농도(mM)ZnSO 4 concentration (mM) 33 55 77 적과제 처리 시기When to redeem your assignments 만개직전Just before full bloom 1차 살포1st spray 5454 8484 7878 2차 살포Secondary spray 6868 7474 7474 만개시In full bloom 1차 살포1st spray 7272 7272 9292 2차 살포Secondary spray 6868 8888 7272

상기 표 5 및 표 6에 기재된 바와 같이, 후지사과에서는 ZnSO4의 농도가 7mM인 적과제를 만개시 2차 살포하였을 때 96%의 높은 적과율을 보였다. 또한, 홍로사과에서는 ZnSO4의 농도가 7mM인 적과제를 만개시 1차 살포하였을 때 92%의 높은 적과율을 보였다. As described in Table 5 and Table 6, the Fuji apple showed a high red filling rate of 96% when the second spraying of red apples with a concentration of 7 mM ZnSO 4 was in full bloom. In addition, the red apple showed a high red filling ratio of 92% when the first application of the red fruit with a concentration of 7 mM ZnSO 4 was applied at full bloom.

한편, ZnSO4의 농도가 2mM 이하로 포함된 적과제를 처리한 경우 적절한 적과율을 보이지 않았다.Meanwhile, the concentration of ZnSO 4 When the task was included less than 2mM did not show an appropriate red over rate.

또한, 후지사과 및 홍로사과에 ZnSO4의 농도가 10mM 이상으로 포함된 적과제를 살포한 경우, 잎의 황변, 갈변 현상이 발생하고 과다하게 낙과가 발생하는 등 약해가 나타남을 확인할 수 있었다.In addition, when the red apple was sprayed with a concentration of more than 10mM ZnSO 4 in Fuji and Hongro apple, yellowing of the leaves, browning phenomenon occurs excessively, it was confirmed that the weakness such as excessive fall.

따라서, 상기 결과들에서와 같이, 후지사과의 경우 ZnSO4의 농도가 7mM인 적과제를 만개시 2차 살포하였을 때, 90% 이상의 적과율을 얻을 수 있었고, 약해 또한 없음을 확인할 수 있었다. 또한, 홍로사과의 경우 ZnSO4의 농도가 7mM인 적과제를 만개시 1차 살포하였을 때, 약해가 없고 90% 이상의 적과율을 얻을 수 있음을 확인할 수 있었다.Thus, as in the above results, the concentration of ZnSO 4 in Fuji apple When the second application of 7mM red fruit in full bloom, over 90% red fruit rate was obtained, and it was confirmed that there is no weakness. In addition, in the case of the red apple, when the first spraying the red fruit with a concentration of 7mM ZnSO 4 at full bloom, it was confirmed that there is no harm and more than 90% red fruit rate.

<실시예 2><Example 2>

NaNa 22 SOSO 44 , MgSO, MgSO 44 , MnSO, MnSO 44 의 농도에 따른 적과율 및 약해유무 조사Investigation of Redundancy and Weakness According to Concentration

상기 제조예 2 내지 4에서 제조한, ZnSO4 이외의 황산염인 Na2SO4, MgSO 4 ZnSO4의 혼합물, MnSO4 각각 1, 2, 3, 5 및 7mM 농도로 포함된 적과제를 한그루당 400㎖씩 후지사과의 만개시에 살포한 후 적과율 및 약해유무를 조사하였다.Na 2 SO 4 , MgSO 4 and sulfates other than ZnSO 4 prepared in Preparation Examples 2 to 4 above; Mixture of ZnSO 4 , MnSO 4 each 400 ml of red fruits containing 1, 2, 3, 5 and 7 mM concentrations were sprayed at the time of full bloom of Fuji apples, and the red fruits were examined for their redness and presence.

적과율(%)% Overfill MnSO4 MnSO 4 Na2SO4 Na 2 SO 4 MgSO4+ZnSO4 MgSO 4 + ZnSO 4 황산염 농도 (mM)Sulfate Concentration (mM) 1One 5656 4949 6060 22 1919 9696 2929 33 4444 7272 6363 55 5858 7373 3232 77 5555 4747 4848

그 결과, Na2SO4, MgSO4 ZnSO4의 혼합물, MnSO 4 각각 1, 2, 3, 5 및 7mM 농도로 포함된 적과제를 처리한 경우, 모두에서 약해가 나타나지 않았으며, 상기 표 7에 기재된 바와 같이, Na2SO4의 농도가 2mM인 적과제를 살포하였을 때, 96%의 적과율을 보임을 확인할 수 있었다. As a result, Na 2 SO 4 , MgSO 4 and Mixture of ZnSO 4 , MnSO 4 each When the red fruits contained at 1, 2, 3, 5 and 7 mM concentrations were treated, no weakness appeared at all, and as shown in Table 7, red fruits having a concentration of 2 mM Na 2 SO 4 were sprayed. At that time, it was confirmed that 96% of overfilling rate was shown.

본 발명에 따른 황산염을 유효성분으로 하는 적과제는 약해가 없고, 살포시기에 제한 없이 높은 적과 효과를 얻을 수 있기 때문에, 양분의 소모를 방지하여 과실의 발육을 증진시킬 수 있다.The red fruits having sulfate as an active ingredient according to the present invention have no weakness and can achieve high redness and effect without limitation in the time of spraying, thereby preventing the consumption of nutrients and improving fruit development.

Claims (7)

1mM 내지 10mM의 황산염을 유효성분으로 하는 적과제.Red fruit containing 1mM to 10mM sulfate as an active ingredient. 제 1항에 있어서, 상기 황산염은 Na2SO4, MgSO4, MnSO4, FeSO4, K2SO4, (NH4)2SO4, CuSO4, BaSO4, CaSO 4 및 ZnSO4로 이루어진 군으로부터 선택되는 하나 이상인 것을 특징으로 하는 적과제.The method of claim 1, wherein the sulfate is Na 2 SO 4 , MgSO 4 , MnSO 4 , FeSO 4 , K 2 SO 4 , (NH 4 ) 2 SO 4 , Red fruit, characterized in that at least one selected from the group consisting of CuSO 4 , BaSO 4 , CaSO 4 and ZnSO 4 . 제 1항에 있어서, 살포시기는 개화직전부터 만개직후까지인 것을 특징으로 하는 적과제.The red object according to claim 1, wherein the spraying period is from immediately before flowering to just after full bloom. 삭제delete 제 1항에 있어서, 전착제가 추가로 첨가되는 것을 특징으로 하는 적과제.2. The red fruit of claim 1, wherein an electrodeposition agent is further added. 제 5항에 있어서, 상기 전착제는 헥사코나졸계(hexaconazole), 실록산계(siloxane) 또는 알킬아릴 폴리에톡실산계(alkylaryl polyethoxylate)인 것을 특징으로 하는 적과제. The antagonist of claim 5, wherein the electrodeposition agent is hexaconazole, siloxane, or alkylaryl polyethoxylate. 제 1항에 있어서, 사과, 복숭아, 살구, 자두, 양앵두, 매실에 적용될 수 있는 것을 특징으로 하는 적과제.The red fruit as claimed in claim 1, which can be applied to apples, peaches, apricots, plums, cherries and plums.
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KR101557886B1 (en) * 2015-03-25 2015-10-07 스티븐 용 장 Composition for falling seed of ginkgo tree and falling method using it
KR20180107430A (en) 2017-03-21 2018-10-02 주식회사 엔에스비 Blossom and fruit thinners, and manufacturing method thereof
CN110249835A (en) * 2019-07-12 2019-09-20 重庆市农业科学院 A kind of fertile mandarin orange green Labor-saving flower and fruit thinning method

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CN104291964A (en) * 2014-09-28 2015-01-21 定远县金胜农业开发有限公司 Flower and fruit thinning conditioning agent of peach tree and preparation method thereof
KR101629387B1 (en) * 2014-12-22 2016-06-10 주식회사 엔에스비 The insoluble calcium and magnesium as a active ingredient flower thinning agent

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KR101557886B1 (en) * 2015-03-25 2015-10-07 스티븐 용 장 Composition for falling seed of ginkgo tree and falling method using it
KR20180107430A (en) 2017-03-21 2018-10-02 주식회사 엔에스비 Blossom and fruit thinners, and manufacturing method thereof
CN110249835A (en) * 2019-07-12 2019-09-20 重庆市农业科学院 A kind of fertile mandarin orange green Labor-saving flower and fruit thinning method
CN110249835B (en) * 2019-07-12 2021-11-19 重庆市农业科学院 Green and labor-saving flower and fruit thinning method for Wo oranges

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