KR100484561B1 - The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification - Google Patents

The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification Download PDF

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KR100484561B1
KR100484561B1 KR10-2002-0056189A KR20020056189A KR100484561B1 KR 100484561 B1 KR100484561 B1 KR 100484561B1 KR 20020056189 A KR20020056189 A KR 20020056189A KR 100484561 B1 KR100484561 B1 KR 100484561B1
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zeolite
ocher
illite
water treatment
natural
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KR10-2002-0056189A
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KR20030027670A (en
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김순호
오대민
성진경
진상환
진순한
황영석
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주식회사 대동그린산업
가부시기가이샤 오쿠다구미
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/165—Natural alumino-silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00—Use of specific compounds during water treatment
    • C02F2305/10—Photocatalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)
  • Water Treatment By Sorption (AREA)
  • Glanulating (AREA)

Abstract

본 발명은 수(水)처리에 관한 것으로 특히 천연의 풍부한 제올라이트와 황토 일라이트를 이용하여 중금속 및 유기물의 흡착성능을 증가시키기 위한 제올라이트, 황토, 일라이트를 활용한 무기물 수처리재 조성물 및 제조방법에 관한 것이다. 이온능력과 탈취력을 갖춘 천연의 제올라이트, 황토의 특성은 알루미늄규산염 등의 미세한 광물의 집합체로서 콜로이드 성질을 가지며 가소성과 이온교환성을 나타내며 결정구조는 평면망상의 규산염이고, 탈취성능이 우수한 일라이트를 사용하여 무기질 수처리재로 개발하여 중금속 흡착성능이 높고 환경친화적이며, 천연의 원재료인 제올라이트와 황토, 일라이트의 특성을 최대한 갖춘 제품을 개발한 것이다. The present invention relates to water treatment, and in particular to the inorganic water treatment composition and manufacturing method using zeolite, ocher, illite to increase the adsorption performance of heavy metals and organic matter using natural rich zeolite and ocher illite It is about. Natural zeolite and ocher, which have ionic ability and deodorizing ability, is a collection of fine minerals such as aluminum silicate. It has colloidal properties, plasticity and ion exchangeability, and its crystal structure is a planar silicate silicate. It was developed as an inorganic water treatment material, and developed a product that has high adsorption performance of heavy metals, is environmentally friendly, and has the characteristics of zeolite, ocher and illite, which are natural raw materials.

천연의 제올라이트와 황토, 일라이트를 광산에서 채굴하여 수분제거하고, 조쇄한 후 100∼200℃로 건조과정을 거쳐 미분쇄기에서 200메쉬(Mesh) 이하의 입도로 분쇄하여 활용화한다. 이 분말을 이용하여 전체 중량부에서 제올라이트 20∼60중량부와 황토 10∼50중량부, 일라이트는 10∼40중량부 광촉매 이산화티탄을 1∼10중량부를 적정비율로 혼합하여 혼련한 후 볼(8mm, 15mm) 형태의 구형의 정수제와 막대형태(30×30×150mm, 30×150mm)로 물을 결합재로 성형한 후 110℃에서 12∼24시간 건조하여 건조로에서 300∼650℃로 1∼10℃/분의 승온속도로 승온하여 1∼6시간 유지 후 자연냉각하여 제조하였다. 본 발명으로 제품화된 수처리재의 특성은 원료자체 탈취율은 암모니아 가스시험실시 결과 제올라이트 98％, 황토 95％, 일라이트 98％로 나타났으며, 또한 이를 사용하여 제조한 정수제의 중금속 납의 흡착능이 96％와 99％로 나타났으며, 뛰어난 흡착력으로 악취를 제거하고 우수한 항균성으로 세균의 번식을 억제하는 것으로 나타났다.Natural zeolites, ochers and elites are mined in mines to remove moisture, pulverized and dried at 100-200 ° C, and then pulverized to a particle size of 200 mesh or less in a mill. Using this powder, 20 to 60 parts by weight of zeolite and 10 to 50 parts by weight of ocher and 10 to 40 parts by weight of illite were mixed and kneaded with 1 to 10 parts by weight of photocatalyst titanium dioxide at an appropriate ratio. 8mm, 15mm) spherical water purifier and rod-shaped (30 × 30 × 150mm, 30 × 150mm) were formed into a binder and then dried at 110 ° C for 12 to 24 hours, and then dried at 300 to 650 ° C in a drying furnace. The temperature was raised at a temperature increase rate of 10 ° C./min and maintained for 1 to 6 hours, followed by natural cooling. The characteristics of the water treatment material produced by the present invention showed that the deodorization rate of the raw material itself was 98% zeolite, 95% ocher, and 98% zeolite as a result of the ammonia gas test. It was found to be 99%, and it was found to remove odors with excellent adsorption power and to suppress bacterial growth with excellent antibacterial activity.

Description

무기질 수처리재 조성물과 그 제조방법{The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification}The composition and manufacturing method of inorganic materials using a waters purification

본 발명은 무기질수처리재와 그 제조방법에 관한 것이다.The present invention relates to an inorganic water treatment material and a method for producing the same.

종래의 무기물을 이용한 수처리에 관한 것으로는, 한국공개특허 제2000-0053716호, 공개특허 제2001-0037768호에서는 맥반석 탈황석고, 석탄재를 사용하여 무기물 수처리재를 제조하였다. Regarding the conventional water treatment using inorganic materials, Korean Patent Laid-Open Publication No. 2000-0053716 and 2001-0037768 disclose the preparation of inorganic water treatment materials using ganbanite desulfurized gypsum and coal ash.

그러나 탈황석고 및 석탄재에는 오히려 부산물에 포함되어 있는 중금속 및 인체에 유해한 물질을 함유하고 있으며 한국특허공개 2001-0036795호에는 황토와 고령토, 규조토를 사용하여 무기물 정수제를 1100∼1200℃ 이상의 고온으로 소성하여 제조하는 방법이 개시되어 있지만, 이 방법으로는 소성비용이 고비용으로 소결반응으로 인하여 수처리 효율이 떨어진다. However, desulphurized gypsum and coal ash contain heavy metals and harmful substances in human body, which are included in by-products. The production method is disclosed, but in this method, the firing cost is high and the water treatment efficiency is low due to the sintering reaction.

황토와 제올라이트, 일라이트의 천연광물을 사용한 무기물의 수처리재는 없으며, 또한 고령토 맥반석 무기물을 사용하여 제조하는 방법은 고온소성 처리하여 사용하는 것으로 많은 소성비용과 정수처리 효율이 낮은 것이다. 본 발명은 천연의 황토와 제올라이트, 일라이트 고유의 특성을 유지하면서 기존 방식으로 제조된 수처리재가 가지고 있는 문제점을 개선하여 수처리효율이 높고, 특히 중금속의 흡착이 뛰어난 흡착율이 높고 광촉매에 의한 수질정화로 저렴한 제품을 생산하는 것을 목적으로 삼고 있다.There is no inorganic water treatment material using natural minerals such as ocher, zeolite, and elite, and the method of manufacturing using kaolin machite mineral is to use high temperature baking and low firing cost and low water treatment efficiency. The present invention improves the water treatment efficiency by improving the problems of the water treatment material prepared by the conventional method while maintaining the characteristics of natural ocher, zeolite, and illite, in particular, the adsorption rate of the adsorption of heavy metals is excellent and the water purification by photocatalyst The aim is to produce inexpensive products.

본 발명은 상기의 목적을 달성하기 위하여, 전체 중량부 100%에서 제올라이트 20∼60%, 황토 10∼50%와 일라이트 10∼40%, 광촉매 이산화티탄을 1∼10%의 분말을 혼합하고 입상에 성형하여 이루어짐을 특징으로 한다.In order to achieve the above object, the present invention mixes 20 to 60% of zeolite, 10 to 50% of ocher, 10 to 40% of illite, and 1 to 10% of photocatalyst titanium dioxide in a total weight part of 100%. It is characterized by being formed in.

전체 중량부 100%에서 제올라이트 20∼60%, 황토 10∼50%와 일라이트 10∼40%, 광촉매 이산화티탄을 1∼10%의 분말에 물을 결합재로서 첨가하고 혼련한 후 볼 형태 또는 봉(팰릿)상으로 성형하고, 봉(30×30×150mm)으로 성형 후 110℃에서 12~24시간 예비적으로 건조하고, 건조로에서 300∼650℃로 1∼10℃/분의 승온속도로 승온건조하여 1∼6시간 유지후 자연냉각하여 제조하는 것을 특징으로 한다.100% by weight of zeolite 20 to 60%, ocher 10 to 50%, illite 10 to 40%, photocatalyst titanium dioxide was added to the powder of 1 to 10% as a binder and kneaded Pallet), after forming into a rod (30 × 30 × 150mm), preliminarily dried at 110 ° C for 12 to 24 hours, and dried at a heating rate of 1 to 10 ° C / min at 300 to 650 ° C in a drying furnace It is characterized in that it is produced by natural cooling after holding for 1 to 6 hours.

본 발명은 수(水)처리에 관한 것으로 특히 천연의 풍부한 제올라이트와 황토 일라이트를 이용하여 중금속 및 유기물의 흡착성능을 증가시키기 위한 제올라이트, 황토, 일라이트를 활용한 무기물 수처리재 조성물 및 제조방법에 관한 것이다. 이온교환능력과 탈취력을 갖춘 천연의 제올라이트, 황토의 특성은 알루미늄규산염 등의 미세한 광물의 집합체로서 콜로이드 성질을 가지며 가소성과 이온교환선을 나타내며 결정구조는 평면망상의 규산염이고, 탈취성능이 우수한 일라이트를 사용하여 무기질 수처리재로 개발하여 중금속 흡착성능이 높고 환경친화적이며, 천연의 원재료인 제올라이트와 황토, 일라이트의 특성을 최대한 활용한 수처리재로 된다.The present invention relates to water treatment, and in particular to the inorganic water treatment composition and manufacturing method using zeolite, ocher, illite to increase the adsorption performance of heavy metals and organic matter using natural rich zeolite and ocher illite It is about. Natural zeolite and ocher with natural ion exchange ability and deodorizing ability are aggregates of fine minerals such as aluminum silicate, which have colloidal properties, exhibit plasticity and ion exchange line, and crystal structure is planar silicate, and has excellent deodorizing performance. Developed as an inorganic water treatment material, it has high adsorption performance of heavy metals, is environmentally friendly, and utilizes the characteristics of zeolite, loess, and illite as natural raw materials to the maximum.

천연의 황토와 제올라이트, 일라이트를 광산에서 채굴하여 수분제거하고, 조쇄한 후 100∼200℃로 건조과정을 거쳐 미분쇄기에서 200mesh 이하의 입도로 분쇄하여 활용화한다. 본 발명의 배합비율(적정비율)은 황토 전체 복합물을 중량부 100%을 기준으로 볼 때, 전체 중량부에서 황토 10∼50%와 제올라이트 20∼60%, 일라이트는 10∼40% 광촉매 이산화티탄을 1∼10%로 하여 적정비율로 혼합하고 혼련한 후 볼(Φ8mm, 15mm) 형태의 구형의 정수제와 막대형태(30×30×150mm, Φ30×150mm)로 물을 결합재로 성형한 후, 110℃에서 12∼24시간 건조하여 건조로에서 300∼650℃로 1∼10℃/분의 승온속도로 가열하여 1∼6시간 유지 후 자연냉각한다. 본 발명으로 수처리재의 특성은 원료자체의 탈취력은, 암모니아가스 흡착시험실시 결과 제올라이트 98%, 황토 95%, 일라이트 98%로 나타났으며, 또한 이를 사용하여 제조한 정수제의 중금속 흡착능이 96%와 99%로 나타났으며, 뛰어난 흡착력으로 악취를 제거하고 우수한 항균성으로 세균의 번식을 억제하는 것으로 나타났다.광촉매반응에 가장 많이 사용되는 촉매는 하나는 티타늄산화물(Titanium oxide)이다. 일반적인 금속류 물질과는 전혀 달리 반도체 물질들은 에너지적으로 서로 겹쳐지지 않는 두가지의 벤드(bend)를 지니고 있는 것으로 특징지어진다. 금속산화물 반도체 성질의 촉매들은 그 표면에 각각의 에너지 벤드(energy bend) 이상에 해당하는 파장의 광에너지를 흡수하게 되면 자신이 지니고 있는 전자들로 채워져 있는 가전자대로부터 전자가 비어있는 전도대로 이용하여 가전자대와 전도대간에 전자-전공 분리하전쌍을 형성하면서 빠져나가게 된다. 이렇게 빠져나간 촉매는 자신의 표면에 흡착되어 있는 수용액중의 수산이온과 산화반응하여 강력한 산화제인 OH기를 생산한다. 이러한 OH기는 수용액상에 용해되어 있는 TCE, 페놀, 벤젠, PCB 등과 같은 유독성 유기물질, 방향족화합물, 염화탄소화합물의 분해반응을 유도하게 된다. 이러한 분해반응은 TCE의 경우 완전 분해시킴으로써 최종적으로 무해한 CO2와 HCL을 생성시킨다.이러한 이산화티탄늄의 특성은, 첫째; 광촉매반응의 과정에서 물이 분해될 때 발생하는 수산기와 과산소이온이 거의 모든 유기물을 산화시켜 이산화탄소와 물로 분해한다. 둘째; 광촉매는 자외선(UV)에 의해서만 활성을 나타내 사용할 수 있는 범위가 매우 협소했으나, 광촉매 재료에 철, 실리콘 등을 주입하면 파장이 긴 가시광선을 내놓는 형광등, 백열등 빛으로도 광촉매활성을 나타 낼 수 있게 되어 적용할 수 있는 범위가 매우 넓어졌다. 셋째; 이산화티타늄 광촉매의 경우 표면에 물분자가 흡착하여 친수성이 강한 표면을 형성하여 물이 떨어져도 방우로 맺혀있는 것이 아니라 물위에 물이 떨어지듯이 흩어져 버리는 친수성을 나타낸다.Natural loess, zeolite, and illite are mined in mines to remove moisture, and then pulverized and dried at 100 to 200 ° C. The blending ratio (proper ratio) of the present invention is based on 100% by weight of the whole ocher composite, 10 to 50% ocher and 20 to 60% zeolite, 10 to 40% photocatalyst titanium dioxide After mixing and kneading with 1 ~ 10% in proper ratio, after molding water into binder (ball of Φ8mm, 15mm) and spherical water and rod (30 × 30 × 150mm, Φ30 × 150mm), It is dried at 110 ° C. for 12 to 24 hours, heated to 300 to 650 ° C. at a heating rate of 1 to 10 ° C./min in a drying furnace, and is naturally cooled after 1 to 6 hours. According to the present invention, the deodorizing power of the raw material itself was 98% zeolite, 95% ocher, and 98% zeolite as a result of ammonia gas adsorption test, and the heavy metal adsorption capacity of the water purification agent prepared using the same was 96%. It was found to be 99%, and it has been shown to remove odors with excellent adsorption power and to suppress bacterial propagation with excellent antibacterial activity. One of the most used catalysts for photocatalytic reaction is titanium oxide. Unlike general metal materials, semiconductor materials are characterized by having two bends that do not overlap with each other energetically. Metal oxide semiconductor catalysts use the conduction band of electrons from the valence band filled with the electrons they have when they absorb light energy of wavelength corresponding to more than each energy bend on the surface. It escapes by forming an electron-electron isolated charge pair between the valence and conduction bands. The catalyst thus oxidized reacts with hydroxyl ions in the aqueous solution adsorbed on its surface to produce OH group, a powerful oxidant. The OH group induces decomposition reactions of toxic organic substances such as TCE, phenol, benzene and PCB dissolved in aqueous solution, aromatic compounds and carbon chloride compounds. This decomposition reaction results in complete decomposition in the case of TCE, resulting in harmless CO 2 and HCL. The properties of these titanium dioxides are: first; In the process of photocatalytic reaction, hydroxyl and peroxide ions, which are generated when water is decomposed, oxidize almost all organic matter and decompose it into carbon dioxide and water. second; Although the photocatalyst exhibits only a limited range of activity by ultraviolet rays (UV), injection of iron or silicon into the photocatalyst material can show photocatalytic activity even with fluorescent and incandescent lights that produce long wavelengths of visible light. The range of application is very wide. third; In the case of titanium dioxide photocatalyst, water molecules are adsorbed on the surface to form a strong hydrophilic surface, which is hydrophilic in that it is scattered as water falls on the water, rather than being confined by rain.

본 발명에서 사용되는 재료의 정의 및 특성은 다음과 같다. Definitions and properties of materials used in the present invention are as follows.

(1)제올라이트(1) zeolite

구 분division 제올라이트의 특성Zeolite Characteristics 성인 및 산지Adult and Mountain 경북 포항지역, 천연상태 산출Gyeongbuk Pohang area, natural state calculation 주성분chief ingredient SiO2 40∼75%, CaO : 0∼5%, Al2O3: 5∼20%SiO 2 40-75%, CaO: 0-5%, Al 2 O 3 : 5-20% 범주 및 입자Categories and Particles 200mesh이하200mesh or less

(2)황토(2) ocher

구 분division 황토의 특성Ocher properties 성인 및 산지Adult and Mountain 암석 풍화에 의해 생성되고, 주로 채굴되는 장소는 산(山)It is produced by rock weathering, and the main mining place is mountain 주성분chief ingredient SiO2: 35∼60%, Al2O3: 25∼40%, Fe2O3: 3∼20%SiO 2 : 35-60%, Al 2 O 3 : 25-40%, Fe 2 O 3 : 3-20% 범주 및 입자Categories and Particles 넓게는 1차 점토에 속하며, 입자크기는 조립Widely belongs to primary clays, particle size is assembled

(3)일라이트(3) illite

구 분division 일라이트의 특성Characteristics of the illite 성인 및 산지Adult and Mountain 암석 풍화에 의해 생성되고, 주고 채굴되는 장소는 산(山)The place where it is produced by rock weathering, giving and mining is mountain 주성분chief ingredient SiO2: 55∼80%, Al2O3: 5∼30%, Fe2O3: 3∼20%SiO 2 : 55-80%, Al 2 O 3 : 5-30%, Fe 2 O 3 : 3-20% 범주 및 입자Categories and Particles 넓게는 1차 점토에 속하며, 입자크기는 조립Widely belongs to primary clays, particle size is assembled

(4)이산화티탄(4) titanium dioxide

구 분division 이산화티탄의 특징Characteristics of titanium dioxide 성인 및 산지Adult and Mountain 티탄철광형으로 산출 황산법·염소법으로 제조Calculation by titanium iron ore Manufacture by sulfuric acid method and chlorine method 주성분chief ingredient 주성분이 이산화티탄으로 결정상은 정방정으로 티탄철광형 금홍석형과 애주석형이 있다.The main component is titanium dioxide, and the crystal phase is tetragonal, and there are titanium iron ore rutile and adiolite. 범주 및 입자Categories and Particles 4.1㎛∼0.1㎛로서 광촉매, 항균, 탈취, 산화분해 작용4.1 to 0.1㎛ photocatalyst, antibacterial, deodorant, oxidative decomposition

상기 실시상태에서는 황토, 제올라이트, 일라이트 등의 천연광석은 은, 채굴후분쇄, 분급, 건조하고, 이산화티탄과 드라이믹싱한 후, 물은 첨가하고 혼련하여, 볼 형태 또는 막대형태로 성형한다. 그 후 습윤건조, 고온건조를 거치고 제품화한다. In the above embodiment, natural ores such as ocher, zeolite, and illite are silver, mined after pulverization, classification, and drying, dry mixed with titanium dioxide, and then water is added and kneaded to form a ball or rod. After that, the product is subjected to wet drying and high temperature drying.

황토와 제올라이트, 일라이트를 사용한 수처리재의 특성은 다음과 같이 측정하였다. The properties of water treatment materials using ocher, zeolite and elite were measured as follows.

중금속 흡착시험은 위의 제조방법으로 제조된 8mm의 구상형 수처리재 시험편을 100㎖의 납용액이 들어있는 삼각플라스크에 넣고 교반기에서 교반시키면서 황토, 제올라이트, 일라이트를 이용한 수처리재의 납 흡착능을 1∼24시간까지의 변화를 측정하였다. In the heavy metal adsorption test, the 8 mm spherical water treatment material test specimen prepared by the above manufacturing method was put in a Erlenmeyer flask containing 100 ml of lead solution, and stirred with a stirrer. Changes up to 24 hours were measured.

실시예 1 내지 실시예 5는 본 발명과 종래기술의 성능 및 특성을 비교한 것이다. Examples 1 to 5 compare the performance and characteristics of the present invention with the prior art.

(실시예 1)(Example 1)

제올라이트 분말의 시간경과에 따른 탈취율(암모니아 가스)Deodorization Rate of Zeolite Powder Over Time (Ammonia Gas)

경과시간(분)Elapsed time (minutes) Blank농도(ppm)Blank concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 탈취율(%)Deodorization rate (%) 초기Early 500500 500500 -- 3030 480480 6060 8787 6060 470470 4040 9191 9090 450450 2020 9595 120120 440440 1010 9898

(실시예 2)(Example 2)

황토분말의 시간경과에 따른 탈취율(암모니아 가스) Deodorization rate with time of ocher powder (ammonia gas)

경과시간(분)Elapsed time (minutes) Blank농도(ppm)Blank concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 탈취율(%)Deodorization rate (%) 00 500500 500500 -- 3030 480480 8080 8383 6060 470470 5050 8989 9090 450450 3030 9393 120120 440440 2020 9595

(실시예 3)(Example 3)

일라이트분말의 시간경과에 따른 탈취율(암모니아 가스)Deodorization rate with time of illite powder (ammonia gas)

경과시간(분)Elapsed time (minutes) Blank 농도(ppm)Blank concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 탈취율(%)Deodorization rate (%) 00 500500 500500 -- 3030 490490 6060 8888 6060 470470 4040 9191 9090 450450 2020 9696 120120 420420 1010 9898

(실시예 4)(Example 4)

수처리 시험체의 중금속 흡착능 시험측정결과(pb용액 100㎖, 25℃ PH6.3)Heavy metal adsorption capacity test measurement result of water treatment test body (pb solution 100ml, 25 ℃ PH6.3)

경과시간(시간)Elapsed time (hours) Blank 농도(ppm)Blank concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 중금속 흡착율(%)Heavy metal adsorption rate (%) 00 9.329.32 9.329.32 -- 1.01.0 9.069.06 2.622.62 7171 3.03.0 8.858.85 1.411.41 8484 6.06.0 8.858.85 0.290.29 9696 8.08.0 8.828.82 0.690.69 9292 24.024.0 8.808.80 0.080.08 9999

(실시예 5)(Example 5)

수처리 시험체의 중금속 흡착능 시험측정결과(pb용액 100㎖, 25℃ PH6.3)Heavy metal adsorption capacity test measurement result of water treatment test body (pb solution 100ml, 25 ℃ PH6.3)

경과시간(시간)Elapsed time (hours) Blank농도(ppm)Blank concentration (ppm) 시료농도(ppm)Sample concentration (ppm) 중금속 흡착율(%)Heavy metal adsorption rate (%) 00 9.329.32 9.329.32 -- 1.01.0 9.069.06 4.484.48 5050 3.03.0 8.858.85 1.991.99 7777 6.06.0 8.858.85 1.031.03 8888 8.08.0 8.828.82 0.920.92 8989 24.024.0 8.808.80 0.370.37 9595

본 발명으로 개발된 제품인 수처리재의 특성은 원료자체 탈취율은 암모니아가스 시험실시 결과 제올라이트 98%, 황토 95%, 일라이트 98%로 나타났으며, 또한 이를 사용하여 제조한 정수제의 중금속 흡착능이 96%와 99%로 나타났으며, 뛰어난 흡착력으로 악취를 제거하고 우수한 항균성으로 세균의 번식을 억제하는 것으로 나타났다. 또한 환경오염의 주요인이 되는 중금속과 악취를 제거하는 정수제로서 활용함으로서 자연환경 친화성을 만족하는 것이다. The characteristics of the water treatment material, which is the product developed by the present invention, showed that the deodorization rate of the raw material itself was 98% zeolite, 95% ocher, and 98% illite as a result of the ammonia gas test. It was found to be 99%, and it was found to remove odors with excellent adsorption power and to inhibit the growth of bacteria with excellent antibacterial activity. In addition, it satisfies the natural environmental friendliness by utilizing it as a water purifying agent that removes heavy metals and odors that are the main causes of environmental pollution.

Claims (2)

전체 중량부 100%에서 제올라이트 20∼60%, 황토 10∼50%와 일라이트 10∼40%, 광촉매 이산화티탄을 1∼10%의 분말을 혼합하고 입상에 성형 하여 이루어짐을 특징으로 하는 무기질 수처리재 조성물.Inorganic water treatment material, characterized by mixing 20 to 60% of zeolite, 10 to 50% of ocher, 10 to 40% of illite, and 1 to 10% of photocatalyst titanium dioxide powder Composition. 전체 중량부 100%에서 제올라이트 20∼60%, 황토 10∼50% 일라이트 10∼40% 광촉매 이산화티탄을 1∼10% 분말에 물을 결합재로서 첨가하고 혼련한 후 볼 형태 또는 봉(팰릿)상으로 성형하고, 봉(30×30×150mm)으로 성형 후 110℃에서 12~24시간 예비적으로 건조하고, 건조로에서 300∼650℃로 1∼10℃/분의 승온속도로 승온건조하여 1∼6시간 유지후 자연냉각하여 제조하는 것을 특징으로 하는 무기물 수처리재 제조방법. 100% by weight of zeolite 20 to 60%, ocher 10 to 50% illite 10 to 40% photocatalyst Titanium dioxide 1 to 10% powder is added as a binder and kneaded After molding with a rod (30 × 30 × 150 mm) and preliminarily dried at 110 ° C. for 12 to 24 hours, and drying at a temperature increase rate of 1 to 10 ° C./min at 300 to 650 ° C. in a drying furnace. Method for producing an inorganic water treatment material, characterized in that the natural cooling to maintain after 6 hours.
KR10-2002-0056189A 2001-09-28 2002-09-16 The Composition and Manufacturing Method of Inorganic Materials using a Waters Purification KR100484561B1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010095825A2 (en) 2009-02-18 2010-08-26 Han Aisam Composition for decreasing hardness of water

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20050026838A (en) * 2003-09-09 2005-03-16 (주) 실버라이트 The method for manufacturing of advanced ion exchange illite(silverlite).
KR100779261B1 (en) * 2004-07-27 2007-11-28 부산대학교 산학협력단 Making method ceramic ball for keeping bubble and refining beer using zeolite
JP5174341B2 (en) * 2006-11-22 2013-04-03 武曽 繁和 Water quality improver, liquid water quality improver production method and liquid detergent
KR100886170B1 (en) * 2007-10-29 2009-02-27 위니아만도 주식회사 Preparation method of solid composition comprising ceramic and silver ion for bactericide
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20000006600A (en) * 1998-11-11 2000-02-07 정일만 Preparing method for wastewater purifying agent
KR100268128B1 (en) * 1998-03-09 2000-11-01 신형철 Manufacture method of water and soil improvement stuff
KR100317515B1 (en) * 1999-11-02 2001-12-24 김동진 Purifying medicine and manufacturing method thereof
KR20020021180A (en) * 2000-08-31 2002-03-20 김봉경 The Composites of Hwangtho Brick and Hwangtho Tile Activated With Hwangtho, Illite and Titanium Oxide and its Manufacturing Methods
KR20020093653A (en) * 2002-09-05 2002-12-16 차연선 Bentonite and zeolite and illite of molding
KR20030055854A (en) * 2001-12-27 2003-07-04 강철호 Organic waste cleanser and method of recycling organic waste

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100268128B1 (en) * 1998-03-09 2000-11-01 신형철 Manufacture method of water and soil improvement stuff
KR20000006600A (en) * 1998-11-11 2000-02-07 정일만 Preparing method for wastewater purifying agent
KR100317515B1 (en) * 1999-11-02 2001-12-24 김동진 Purifying medicine and manufacturing method thereof
KR20020021180A (en) * 2000-08-31 2002-03-20 김봉경 The Composites of Hwangtho Brick and Hwangtho Tile Activated With Hwangtho, Illite and Titanium Oxide and its Manufacturing Methods
KR20030055854A (en) * 2001-12-27 2003-07-04 강철호 Organic waste cleanser and method of recycling organic waste
KR20020093653A (en) * 2002-09-05 2002-12-16 차연선 Bentonite and zeolite and illite of molding

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010095825A2 (en) 2009-02-18 2010-08-26 Han Aisam Composition for decreasing hardness of water
WO2010095825A3 (en) * 2009-02-18 2010-11-25 Han Aisam Composition for decreasing hardness of water
CN102317221A (en) * 2009-02-18 2012-01-11 韩爱三 Composition for decreasing hardness of water

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