KR100461021B1 - An aromatic with a crystal form - Google Patents
An aromatic with a crystal form Download PDFInfo
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- KR100461021B1 KR100461021B1 KR1019970027217A KR19970027217A KR100461021B1 KR 100461021 B1 KR100461021 B1 KR 100461021B1 KR 1019970027217 A KR1019970027217 A KR 1019970027217A KR 19970027217 A KR19970027217 A KR 19970027217A KR 100461021 B1 KR100461021 B1 KR 100461021B1
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- fragrance
- crystalline
- water
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- 239000013078 crystal Substances 0.000 title claims abstract description 16
- 125000003118 aryl group Chemical group 0.000 title 1
- 239000003205 fragrance Substances 0.000 claims abstract description 51
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 25
- 239000011780 sodium chloride Substances 0.000 claims abstract description 13
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 8
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 8
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 239000002386 air freshener Substances 0.000 abstract description 3
- 239000002304 perfume Substances 0.000 description 11
- 235000002639 sodium chloride Nutrition 0.000 description 10
- 239000000499 gel Substances 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 235000019502 Orange oil Nutrition 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000010502 orange oil Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 1
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004520 water soluble gel Substances 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/012—Deodorant compositions characterised by being in a special form, e.g. gels, emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
- A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
- A61L9/12—Apparatus, e.g. holders, therefor
- A61L9/125—Apparatus, e.g. holders, therefor emanating multiple odours
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/04—Sodium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
- C07F1/06—Potassium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dispersion Chemistry (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
본 발명은 결정형 방향제에 관한 것으로, 더욱 상세하게는 염화나트륨(NaCl) 1-4중량%와 인산2수소칼륨(KH2PO4) 10-16중량%를 혼합하여 물에 녹이고 향료를 첨가한 후, 그 내용물을 용기에 붓고 다양한 형태의 흡지를 꽂아 흡지 주위에 미세한 결정이 다양하게 형성되도록 하는 결정형 방향제에 관한 것으로, 그 향취가 지속적으로 오랫동안 유지된다.The present invention relates to a crystalline fragrance, and more particularly, 1-4% by weight of sodium chloride (NaCl) and 10-16% by weight of potassium dihydrogen phosphate (KH 2 PO 4 ) are dissolved in water, and then flavored, The present invention relates to a crystalline air freshener which pours the contents into a container and inserts various types of blotting to form various fine crystals around the blotting. The odor is maintained for a long time.
Description
본 발명은 결정형 방향제에 관한 것으로, 더욱 상세하게는 염화나트륨(NaCl) 1-4중량%와 인산2수소칼륨(KH2PO4) 10-16중량%를 혼합하여 물에 녹이고 향료를 첨가한 후, 그 내용물을 용기에 붓고 다양한 형태의 흡지를 꽂아 흡지 주위에 미세한 결정이 다양하게 형성되도록 하는 결정형 방향제에 관한 것으로, 그 향취가 지속적으로 오랫동안 유지된다.The present invention relates to a crystalline fragrance, and more particularly, 1-4% by weight of sodium chloride (NaCl) and 10-16% by weight of potassium dihydrogen phosphate (KH 2 PO 4 ) are dissolved in water, and then flavored, The present invention relates to a crystalline air freshener which pours the contents into a container and inserts various types of blotting to form various fine crystals around the blotting. The odor is maintained for a long time.
방향제란 일정한 공간에 방향물질을 휘발시켜 향기를 발산시키는 것으로 제형에 따라 다음과 같이 분류된다.The fragrance is to emit the fragrance by volatilizing the fragrance in a certain space, which is classified as follows according to the formulation.
1) 액체 방향제 : 향료와 알코올, 계면활성제, 물 등을 사용하여 액상으로 제품화한 방향제로서 내용물을 흡수하는 심지와 내용물이 발산되도록 하는 흡지가 부가된다.1) Liquid fragrance: It is a fragrance that is made into liquid phase using fragrance, alcohol, surfactant, water, etc., and a wick to absorb the contents and a sorbent for dispersing the contents are added.
2) 젤 방향제 : 향료, 물, 계면활성제, 알코올 등에 젤화제를 첨가하여 젤타입으로 만든 방향제로서 젤화제가 오일성인지 수용성인지에 따라 오일젤 방향제, 수용성젤 방향제로 구분된다.2) Gel fragrance: A fragrance made by adding gelling agent to fragrance, water, surfactant, alcohol, etc. into gel type and classified into oil gel fragrance and water-soluble gel fragrance according to whether the gelling agent is oily or water-soluble.
3) 에어로졸 방향제 : 향료와 계면활성제, 알코올, 물 등을 사용한 액상의 내용물을 캔에 넣고 분사제로 액화석유가스(LPG)나 압축가스 등을 충전(充塡)하여 필요시 원하는 만큼 뿌려서 사용하는 방향제이다.3) Aerosol fragrance: A fragrance used by filling liquid contents using fragrance, surfactant, alcohol, water, etc. into cans and filling with LPG or compressed gas with propellant as needed. to be.
4) 세라믹 방향제 : 다공성 세라믹을 도자기 모양이나 기타 여러가지 모양으로 가공한 후 향료와 향료보류제를 넣은 내용물을 용기 안에 부어 향기를 발산시키는 방향제이다.4) Ceramic fragrance: It is a fragrance that emits fragrance by processing porous ceramics into porcelain shape or other shapes, and then pouring the contents containing fragrance and perfume retention agent into the container.
상기의 방향제들은 향료를 알코올에 녹이거나 보류제와 함께 사용하기 때문에 약간의 시간이 경과하면 향취 강도가 급속하게 떨어지는 문제점이 있었다.Since the fragrances are dissolved in alcohol or used together with retention agents, there is a problem that the fragrance intensity drops rapidly after some time.
이에 본 발명자는 방향제의 향기가 오래 지속되도록 하기 위해서, 결정형 원료인 염화나트륨과 인산2수소칼륨을 물에 녹인 후 공기 중에 노출시키면 결정화가 생긴다는 사실을 발견하고, 이 두 물질을 일정한 질량비로 혼합한 후 물에 녹이고 향료를 첨가하여 방향제를 만들어 향료가 흡지 주위의 결정체에 흡착되도록 하여 방향제의 지속성을 높인 본 발명에 따른 결정형 방향제를 완성하게 되었다.Therefore, the present inventors found that crystallization occurs when the crystalline raw materials sodium chloride and potassium dihydrogen phosphate are dissolved in water and exposed to air in order to maintain the fragrance of the fragrance for a long time. After dissolving in water and adding fragrance to make the fragrance is adsorbed to the crystal around the sorbent to complete the crystalline fragrance according to the present invention to increase the persistence of the fragrance.
따라서, 본 발명의 목적은 보관이 용이하고, 향기가 오래 지속되는 방향제를 제공하는 것이다.It is therefore an object of the present invention to provide a fragrance which is easy to store and which has a long lasting aroma.
이하, 본 발명을 상세하게 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, this invention is demonstrated in detail.
본 발명에 따른 결정형 방향제는 염화나트륨(NaCl) 1-4중량%와 인산2수소칼륨(KH2PO4) 10-16중량%를 혼합하여 물에 녹이고 향료를 첨가한 후, 그 내용물을 용기에 붓고 다양한 형태의 흡지를 꽂아 흡지 주위에 미세한 결정이 다양하게 형성되도록 한 것이다.The crystalline fragrance according to the present invention is mixed with 1-4% by weight of sodium chloride (NaCl) and 10-16% by weight of potassium dihydrogen phosphate (KH 2 PO 4 ), dissolved in water, and after the addition of perfume, the contents are poured into a container. By inserting various types of suction, a variety of fine crystals are formed around the suction.
본 발명에서 사용한 염화나트륨은 천연에서 암염(岩鹽)으로 다량 산출되어 직접 채굴한 것으로 융점은 800.4℃, 비등점은 1413℃, 비중은 2.164, 굴절률은 1.5443 이고 무수염(無水鹽)은 무색입방정계(無色立方晶系) 결정(結晶)이다. 물 100g 에 대한 용해도는 35.6g(0℃), 35.8g(20℃), 39.1g(100℃) 이며 알코올에는 녹지 않지만 글리세린에는 녹는다.Sodium chloride used in the present invention is directly extracted by a large amount of rock salt in nature, the melting point is 800.4 ℃, boiling point is 1413 ℃, specific gravity is 2.164, refractive index is 1.5443 and anhydrous salt is colorless cubic system立方 晶 系 Crystals. Solubility in 100g of water is 35.6g (0 ℃), 35.8g (20 ℃), 39.1g (100 ℃) and insoluble in alcohol but soluble in glycerin.
포화수용액은 0℃ 이하에서 무색단사정계(無色單斜晶系)의 2수염(水鹽)이 생기고 영하 21.3℃에서 함영정(含永晶)을 만든다. 그리고 인산2수소칼륨은 인산과 염화칼륨을 강열(强熟)해서 만든 인산칼륨을 금속판상에서 급냉한 다음 물에 녹여서 만든 무색정방정계주상결정(無色正方晶系柱狀結晶)으로 칼륨과 인산이 지르콘형으로 배열된 구조이며, 융점은 96℃, 비중은 2.238, 굴절률은 1.5095 이다. 물 100g 에 대한 용해도는 7℃에서 33g 이며 레이저의 광고주파를 발생시키거나 비료 등에도 이용된다.Saturated aqueous solution produces colorless monoclinic dihydrate at below 0 ℃, and makes Hamyeongjeong at below 21.3 ℃. Potassium dihydrogen phosphate is a colorless tetragonal columnar crystal made by quenching potassium phosphate produced by intensively heating phosphoric acid and potassium chloride on a metal plate, and then dissolving it in water. It is a structure arranged in a melting point of 96 ℃, specific gravity is 2.238, refractive index is 1.5095. The solubility in 100g of water is 33g at 7 ℃ and it is used to generate laser wave or fertilizer.
상기의 두 물질을 결정형 방향제로 사용함에 있어서, 염화나트륨 1-4중량%와 인산2수소칼륨 10-16중량%가 혼합되어 있을 때 결정이 미세하게 흡지 주위에 생기며, 상기 범위를 벗어날 경우에는 결정입자가 커지거나 결정이 잘 형성되지 않아 미관상 좋지 않게 된다.In using the above two substances as a crystalline fragrance, when 1-4% by weight of sodium chloride and 10-16% by weight of potassium dihydrogen phosphate are mixed, crystals are formed around the suction finely, and the crystal grains are out of the above range. May become large or crystals do not form well, resulting in poor aesthetic appearance.
본 발명에서 사용한 흡지는 특별한 제한은 없으나 흡수력이 좋은 두께1mm 의 종이로 나무, 동물 등과 같이 여러 가지 모양으로 디자인하여 사용하면 흡지 주위에 나무나 동물 모양의 결정이 생기기 때문에 다양하게 변경이 가능하다.Suction used in the present invention is not particularly limited, but can be variously changed because the crystal of the shape of the tree or animal around the blotting occurs when used in a variety of shapes such as trees, animals, etc. with a paper having a good absorption capacity of 1mm thick paper.
이하 실시예 및 시험예를 들어 본 발명의 구성 및 작용효과를 보다 구체적으로 설명한다.For the following examples and test examples will be described in more detail the configuration and effect of the present invention.
[실시예 1-6] 결정형 방향제Example 1-6 Crystalline Aroma
<제조방법><Production method>
표 1의 조성에 따라, 염화나트륨과 인산2수소칼륨을 막자사발에서 골고루 혼합한 후 물을 넣고 실온에서 완전히 녹인 다음 여기에 오렌지 오일을 넣고 충분히 교반한 후, 이 내용물을 용기에 붓고 흡지를 꽂아 두었다.According to the composition of Table 1, sodium chloride and potassium dihydrogen phosphate were evenly mixed in a mortar and then water was added and completely dissolved at room temperature. Orange oil was added thereto and stirred well. Then, the contents were poured into a container, and the suction was placed. .
실시예 1-4는 내용물이 흡착되면서 흡지 주위에 미세한 결정이 생겼으나, 실시예 5는 결정이 잘 형성되지 않았고 실시예 6은 결정입자가 너무 커서 미관상 좋지 않았다.In Example 1-4, fine crystals were formed around the suction as the contents were adsorbed, but in Example 5, the crystals were not well formed, and in Example 6, the crystal grains were too large to have aesthetic appearance.
[표 1]TABLE 1
결정형 방향제의 조성Composition of Crystalline Perfume
[비교예1] 액체타입 방향제Comparative Example 1 Liquid-type Fragrance
<제조방법><Production method>
표 2의 조성에 따라, 에탄올에 프로필렌 글라이콜과 오렌지오일을 40℃로 가열하여 완전히 녹인 후 물과 혼합하였다.According to the composition of Table 2, propylene glycol and orange oil in ethanol was heated to 40 ℃ completely dissolved and then mixed with water.
[표 2]TABLE 2
액체타입 방향제의 조성Composition of Liquid Type Perfume
[비교예2] 젤타입 방향제Comparative Example 2 Gel Type Fragrance
<제조방법><Production method>
표 3의 조성에 따라, 95℃로 가열된 정제수(성분 2)에 젤라틴(성분 1)을 첨가하여 완전히 녹인 다음, 80℃ 정도에서 성분 3, 4, 5, 6을 성분2에 첨가하고 60℃에서 용기에 방향제를 부어 젤화시켰다.According to the composition of Table 3, gelatin (component 1) was added to the purified water (component 2) heated to 95 ℃ completely dissolved, and then the components 3, 4, 5, 6 were added to the component 2 at about 80 ℃ and 60 ℃ The fragrance was poured into a container at and gelated.
[표 3]TABLE 3
젤타입 방향제의 조성Composition of gel type air freshener
[시험예1] 향취 지속성 평가 시험Test Example 1 Perfume Persistence Evaluation Test
본 발명에 따른 결정형 방향제의 향기 지속성이 액체타입의 방향제나 젤 타입의 방향제보다 우수하다는 것을 확인하기 위해 방향제 향료로서 많이 사용되는 오렌지오일을 결정형 방향제, 액체 방향제, 젤 방향제에 모두 동일한 양을 사용하여 각각 제형화하고 동일한 조건에서 평가자들에게 관능평가하도록 하였다. 평가방법은 후술하는 바와 같다.In order to confirm that the fragrance sustainability of the crystalline perfume according to the present invention is superior to the liquid or gel type perfume, orange oil, which is frequently used as a perfume fragrance, is used in the same amount in the crystalline perfume, liquid perfume, and gel perfume. Each was formulated and subjected to sensory evaluation by evaluators under the same conditions. The evaluation method is as mentioned later.
가로 50센티미터 , 세로 50 센티미터 , 높이 2미터의 밀폐된 스테인레스 쳄버(CHAMBER) 8개를 준비하여, 실시예1-6 및 비교예1, 2의 방향제 50그램을 각각의 쳄버에 넣고 1일 후, 4일 후, 7일 후에 선발된 관능평가요원 30명으로 하여금 아래의 표 4에 나타낸 6단계 취기 강도 표시법에 따라 향취강도를 평가하도록 하였으며, 그 결과에 대한 평균값을 표 5에 나타내었다.Eight sealed stainless chambers (CHAMBER) of 50 centimeters in width, 50 centimeters in height, and 2 meters in height were prepared, and 50 grams of the fragrances of Examples 1-6 and Comparative Examples 1 and 2 were placed in each chamber, and one day later, Four days later, seven sensory evaluation personnel were selected after seven days to evaluate the fragrance intensity according to the six-stage odor intensity labeling method shown in Table 4 below, and the average values of the results are shown in Table 5.
1-6번 챔버 : 실시예1-6 방향제 각각 50그램을 플라스틱용기에 붓고 두께1mm, 높이 7cm 나무모양의 흡지를 꽂았다.Chamber Nos. 1-6: Example 1-6 50 grams of fragrance each was poured into a plastic container, and a 1 mm thick and 7 cm high tree-shaped suction cup was inserted.
7번 챔버 : 비교예1 방향제 50그램을 플라스틱 용기에 붓고 지름 5mm, 길이 5cm 심지와 두께 1mm, 지름 3cm 흡지를 연결했다.Chamber No. 7: Comparative Example 1 50 g of fragrance was poured into a plastic container, and a wick of 5 mm in diameter, 5 cm in length, 1 mm in thickness, and 3 cm in diameter was connected.
8번 챔버 : 비교예2 방향제 50그램을 플라스틱 용기에 붓고 뚜껑을 닫지 않고 개방시켰다.Chamber 8: Comparative Example 2 50 grams of fragrance was poured into a plastic container and opened without closing the lid.
[표 4]TABLE 4
6단계 취기 강도 표시법Six levels of odor intensity notation
[표 5]TABLE 5
관능평가 결과표Sensory evaluation result table
이상에서와 같이, 본 발명에 따른 결정형 방향제는 종래의 액체 방향제, 젤 방향제, 에어로졸 방향제, 세라믹 방향제에 비하여 방향제의 향기가 오래 지속되는 효과가 있고, 또한 다양한 형태의 결정형을 갖는다. 또한, 고체 상태이기 때문에 보관이 편리하고 장식용 기능까지 겸비할 수 있다.As described above, the crystalline fragrance according to the present invention has the effect of long-lasting aroma of the fragrance compared to the conventional liquid fragrance, gel fragrance, aerosol fragrance, ceramic fragrance, and also has various forms of crystalline form. In addition, the solid state is convenient for storage and combines decorative functions.
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| KR102406007B1 (en) * | 2015-02-06 | 2022-06-08 | (주)아모레퍼시픽 | Perfume composition for expressing the fragrance of Citrus |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4666707A (en) * | 1984-04-12 | 1987-05-19 | Kao Corporation | Weakly acidic bath salt composition |
| KR920016108A (en) * | 1991-02-21 | 1992-09-24 | 최성규 | Aromatic deodorant composition and tag using same |
| US5188064A (en) * | 1991-10-07 | 1993-02-23 | Venture Innovations, Inc. | Clumping cat litter |
| KR0175566B1 (en) * | 1996-02-07 | 1999-03-20 | 김공수 | Process for preparing deodorizing agent of chitosan component |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4666707A (en) * | 1984-04-12 | 1987-05-19 | Kao Corporation | Weakly acidic bath salt composition |
| KR920016108A (en) * | 1991-02-21 | 1992-09-24 | 최성규 | Aromatic deodorant composition and tag using same |
| US5188064A (en) * | 1991-10-07 | 1993-02-23 | Venture Innovations, Inc. | Clumping cat litter |
| KR0175566B1 (en) * | 1996-02-07 | 1999-03-20 | 김공수 | Process for preparing deodorizing agent of chitosan component |
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