KR100418192B1 - The composition of ceramic coating material having function - Google Patents
The composition of ceramic coating material having function Download PDFInfo
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- KR100418192B1 KR100418192B1 KR10-2001-0041162A KR20010041162A KR100418192B1 KR 100418192 B1 KR100418192 B1 KR 100418192B1 KR 20010041162 A KR20010041162 A KR 20010041162A KR 100418192 B1 KR100418192 B1 KR 100418192B1
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/0045—Polymers chosen for their physico-chemical characteristics
- C04B2103/0046—Polymers chosen for their physico-chemical characteristics added as monomers or as oligomers
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/30—Water reducers, plasticisers, air-entrainers, flow improvers
- C04B2103/304—Air-entrainers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/50—Defoamers, air detrainers
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/54—Pigments; Dyes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00241—Physical properties of the materials not provided for elsewhere in C04B2111/00
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- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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Abstract
본 발명은 소성하여 급냉 분쇄한 견운모 분말을 주성분으로 하고 여기에 무기질로서 규사, 석회, CSA시멘트, 슬래그, 탄산칼슘, 프라이애쉬, 마이크로실라카, 백시멘트, 안료 그리고 유기질로서 수용성의 AE제(아크릴모노머), 메라민, 셀루로즈, 소포제(실리콘오일)를 첨가 조성한 기능성 세라믹 바름재 조성물에 관한 것임.The present invention is based on calcined quenched mica powder, which is composed of silica sand, lime, CSA cement, slag, calcium carbonate, fry ash, micro silica, white cement, pigment and organic soluble AE agent (acrylic). The functional ceramic coating material composition which added and added the monomer), a melamine, cellulose, and an antifoamer (silicone oil).
Description
본 발명은 원적외선 방사기능, 탈취 및 항균성을 갖는 바름재 조성물에 관한 것으로 구체적으로는 천연광물인 견운모를 주성분으로 하여 시멘트, 무기질 재료 및 유기질 재료로서 수용성포리머, 접착 및 유동화재 등을 배합하여서된 환경 친화적인 바름재 조성물에 관한 것이다.The present invention relates to a coating material composition having far-infrared radiation function, deodorization and antimicrobial properties. Specifically, it is an environment made by blending water-soluble polymer, adhesive and fluidizing material as cement, inorganic material and organic material with the main component of mica being natural mineral. It relates to a friendly coating material composition.
본 발명에서 사용되는 견운모는 충남 칠갑산 부근에서 체굴 되는 운기석이라 불려지는 여러 가지 기능성이 인정되는 견운모로서 일라이트(ILLITE)라는 학명으로도 불리어지는 견운모라할 수 있다.The biotite used in the present invention is a biotite recognized by various functionalities called a meteorite that is excavated in the vicinity of Chilgapsan, Chungnam, and may be referred to as the illite (ILLITE).
이와 같은 견운모는 용수중의 양이온의 부유입자와 전기적인 중화응집으로 침전을 유발하여 정수작용이 우수하며 자체함수 기능으로 보습효과가 크고 활성도가 높은 고유의 특성 이외에도 상온에서 5-20마이크로폰 파장의 원적외선을 90%이상 방사하는 특징이 있고 강력한 음이온을 발산하여 흡착력이 우수한 광물이다.Such biotite has excellent water purification action by causing precipitation by cation suspended particles and electric neutralization of water in water, and its own function makes moisturizing effect and high activity. It is a mineral that emits more than 90% and emits strong anions, so it is an excellent mineral.
이와 같은 특징을 이용하여 소성한 견운모 분말에 접착성을 갖는 아크릴모노머, 간극체움 기능과 시멘트 수화반응 촉진재의 역할을 하는 마이크로실리카, 수화반응을 주도하는 석회석, 수화과정에서 바늘모양의 결정구조를 가진 에트린자이트를 생성하고 이 과정에서 간극의 밀실화와 3차원적 구조의 팽창이 발생하므로서 바름재의 건조수축응력을 완축시키므로서 고결 후의 크랙발생을 방지하는 CSA시멘트, 이들의 상호 접착성과 몰탈 배합으로 유동성을 좋게 하는 유동화재 등의 조성물로 구성되므로서 바름재로서의 특성이 우수할 뿐만 아니라 다양한 기능성이 부여된 바름재 조성물에 관한 것이다.Acryl monomer having adhesion to calcined biotite powder using these characteristics, microsilica which acts as a function of the gap chemistry and cement hydration reaction, limestone which leads the hydration reaction, and needle-shaped crystal structure in the hydration process CSA cement, which prevents cracking after solidification by relieving dry shrinkage stress of the coating material by forming ethrinite and in this process, resulting in tight sealing of gaps and expansion of three-dimensional structure, and their mutual adhesion and mortar combination The present invention relates to a coating material composition which is not only excellent in properties as a coating material but also to which various functionalities are provided because it is composed of a composition such as a fluidizing material which improves fluidity.
종래 대표적인 바름재는 미장시에 바르는 시멘트 몰탈은 구조물의 마감처리재로서 실시하는 바름재로 거치른 구조물의 표면을 평활하게 하는 일종의 장식효과와 차후 벽지를 바르거나 장식용 도장재를 바를 수 있도록 바탕을 제공함에 불과하다.Conventional representative coating materials are cement mortar applied at the time of plastering is a kind of decorative effect that smoothes the surface of the structure, which is applied as a finishing material of the structure, and provides a base for applying wallpaper or decorative paint later on. Do.
또 해초(곤피)로부터 얻어지는 알긴산용액으로 반죽되는 회반죽 바름재가 있어 한옥, 사찰 등의 벽바름재등 특수용도로서 사용하고 있으나 내수성이 약하고 강도가 약한 결점을 갖고 있다.In addition, there is a plaster paste that is kneaded with alginic acid solution obtained from seaweed (konjac), and is used for special purposes such as hanok, wall coverings such as temples, etc., but it has weak water resistance and weak strength.
그밖에도 황토의 점성을 이용한 황토 바름재가 최근 원적외선을 방사하는 기능이 있다하여 한증막, 사우나, 찜질방 등의 벽체 바름재로 이용하고 있으나 이는 특수목적의 원적외선 방사기능 이외에는 내수성 및 강도가 약할 뿐만 아니라 내구성도 거의 없는 특수용도의 바름재라할 수 있다.In addition, ocher varnish using the viscosity of ocher has recently been used as a wall coating material such as steam room, sauna, and jjimjilbang because it has the function of emitting far infrared rays, but it has not only weak water resistance and strength but also durability, except for the special purpose far infrared radiation function. It can be said to be a special purpose rarely used.
본 발명은 종래 바름재의 주종을 이루는 시멘트 바름재가 갖지 못하는 기능과 특수용도로 사용되는 종래 바름재의 취약점을 해결할 수 있는 바름재 조성물을 제공함에 있으며 구체적으로는 종래 바름재의 일반적인 특성인 강도, 내구성을 확보하면서도 원적외선 방사기능, 항균성, 탈취기능 등 특수기능을 갖는 견운모 분말을 주재로 하는 환경 친화적인 바름재 조성물을 제공함에 목적이 있다.The present invention provides a coating material composition that can solve the weakness of the conventional coating material used for special functions and special coatings that do not have the cement coating material constituting the predominant of the conventional coating material, and in particular, to secure the strength, durability, which is a general characteristic of the conventional coating material Yet, an object of the present invention is to provide an environmentally friendly coating material composition based on mica powder having special functions such as far-infrared radiation function, antimicrobial activity, and deodorizing function.
본 발명에 의한 바름재 조성물에 사용되는 원료로서 주성분을 구성하며 특수기능을 갖는 견운모(운기석)의 성분 및 그 기능을 알아보면 먼저 그 성분은 표(1)과 같다.As a raw material used in the coating material composition according to the present invention, the components of the mica and the function of the mica that have a special function and the function thereof are first described in Table (1).
표(1) 견운모(운기석)분말의 성분표 Table (1) ingredient list of mica hair
(주) 한국건자재 시험연구원에서 실시한 성분성적서임.This is a component report performed by Korea Building Materials Testing & Research Institute.
또한 견운모 분말의 원적외선 반사율은 표(2)와 같다.In addition, the far-infrared reflectance of a mica powder is as Table (2).
표(2) 견운모(운기석)소정분말의 원적외선 방사율 Table (2) Far-Infrared Emissivity of Biotite (Meteorite) Predetermined Powder
비고)Remarks)
1) 본 시험은 40℃에서 시험하였으며 FT-IR Spectrometer를 이용한 Black Body 대비 측정결과임.1) This test was conducted at 40 ℃ and it is the result of measuring Black Body using FT-IR Spectrometer.
2) 한국건자재시험연구원에서 실시한 시험성적서임.2) Test report conducted by Korea Institute of Construction Materials.
그밖에 견운모(운기석)분말의 항균성 및 탈취성 시험결과는 각각 표(3) 및 표(4)와 같다.In addition, the antimicrobial and deodorant test results of mica hairs are shown in Tables (3) and (4), respectively.
표(3) 견운모(운기석)의 항균성 시험성적서 Table (3) Antimicrobial Test Report of Cicada
(주) 1) Blank : 시료를 넣지 않은 상태에서 측정한 것임.(Note) 1) Blank: Measured without sample.
2) 배지상의 균수는 희석배수를 곱하여 산출한 것임.2) The number of bacteria on the medium is calculated by multiplying the dilution factor.
3) 시험방법 : KICM-FIR-10033) Test Method: KICM-FIR-1003
4) 사용균주4) Use strain
Escherichia coli ATCC 25922Escherichia coli ATCC 25922
Pseudomonas aeruginosa ATCC 15442Pseudomonas aeruginosa ATCC 15442
표(4) 견운모(운기석) 분말의 탈취성 시험분석표 Table (4) Deodorization Test Analysis Table of Cicada (Meteorite) Powder
(주) Blank : 시료를 넣지 않은 상태에서 측정한 것임.(Note) Blank: Measured without sample.
1) 시험방법 : KICM-FIR-10041) Test Method: KICM-FIR-1004
2) 시험가스명 : 암모니아2) Test gas name: Ammonia
3) 가스농도측정 : 가스검지관3) Gas concentration measurement: gas detector
본 발명에 의한 바름재 조성물의 주성분인 견운모(운기석)의 성분과 기능은 상술한 바와 같고 이를 주재로한 바름재 조성물의 조성비는 다음과 같다.The components and functions of the chorionic mica (calfite), which is the main component of the coating material composition according to the present invention, are as described above, and the composition ratio of the coating material composition based on the same is as follows.
조성물 조성비Composition composition ratio
견운모(운기석)분말 15-35%Cicada (Meteorite) Powder 15-35%
규사 20-30%Silica sand 20-30%
석회(CaO) 3%Lime (CaO) 3%
CSA시멘트 3-5%CSA Cement 3-5%
슬래그(slag) 2-5%Slag 2-5%
탄산칼슘(CaCO3)10-20%Calcium Carbonate (CaCO 3 ) 10-20%
프라이애쉬(plyash) 4%Flyash 4%
마이크로실리카 5%Microsilica 5%
백시멘트 3%Back cement 3%
AE제(아크릴모노머) 8-13%AE agent (acrylic monomer) 8-13%
메라민(Melamine) 0.45%Melamine 0.45%
셀루로스(Cellulose) 0.05%Cellulose 0.05%
소포제(실리콘오일) 0.5%Antifoaming agent (silicone oil) 0.5%
산화티타늄(TiO2) 2%Titanium oxide (TiO 2 ) 2%
이상의 조성물에서 견운모(운기석)분말의 성분과 기능성에 대해서 전술한바 있고 그밖에 조성물로서 석회는 고화제로서 견운모 분말과 반응하고 반응생성물은 그 입자표면에 극히 미세한 활성의 겔(C-S-H)을 형성하며 이 겔은 수화광물로서 점점 경화되어가며 이렇게 형성된 반응생성물들은 견운모 분말입자들을 서로 연결시켜 주는 역할을 하게되고 CSA시멘트는 칼슘설포알루미네이트(calcium sulpho aluminate)로서 석회석, 알루미네이트광물, 석고 등을 혼합 분쇄한 재료를 1300℃에서 약 2-3시간 정도 소성한 후 공기 중에서 급냉하여 제조한 시멘트로서 아우인 광물의 결정구조와 매우 유사하기 때문에 아우인이라고도 부르며 분자식은 C4A3S(3CaO·3Al2O3·CaSO4)이고 이는 본 발명의 바름재 조성물로 사용되는 백시멘트나 견운모의 분말 및 수화물과 반응하여 바늘모양의 결정구조를 가진 에트린쟈이트를 생성하는데 이 과정에서 간극의 치밀화와 3차원적 팽창이 발생하므로 바름재의 건조 수축시 발생하는 응력을 완충시키므로 서 균열을 방지할 수 있다.In the above composition, the components and functionalities of the mica powder are described above. In addition, as a composition, lime reacts with the mica powder as a solidifying agent, and the reaction product forms an extremely fine active gel (CSH) on the surface of the particle. The gel is gradually hydrated as a hydrated mineral, and the reaction products thus formed serve to connect the mica powder particles to each other. The CSA cement is calcium sulpho aluminate, which is a mixture of limestone, aluminate minerals and gypsum. A cement produced by calcining a material at 1300 ° C. for about 2-3 hours and then quenching in air. It is also called Auin because it is very similar to the crystal structure of Auin mineral. The molecular formula is C 4 A 3 S (3CaO · 3Al 2). O 3 · CaSO 4 ), which reacts with powders and hydrates of white cement or mica that are used as the coating material composition of the present invention. Ethrinite with a needle-like crystal structure is produced. In this process, densification of gaps and three-dimensional expansion occur, so that the cracks can be prevented by buffering stress generated during dry shrinkage of the coating material.
또 용융슬래그는 급냉에 의하여 결정이 될 틈이 없이 결정화 에너지를 내부에 보존하여 유리상태가 된다.In addition, molten slag is in a glass state by storing crystallization energy therein without gaps to be crystallized by quenching.
이와 같은 처리에 의하여 슬래그는 잠재 수경성을 가지며, 본 발명 바름재 조성물인 석회, 시멘트 등의 알카리에 의한 자극작용에 의하여 수경성을 발휘한다.By such treatment, slag has latent hydraulic properties and exhibits hydraulic properties by stimulating action by alkali such as lime, cement, which is the present coating material composition.
슬래그가 물과 혼합할 때 초기수화반응은 시멘트가 유도하지만 슬래그는 시멘트보다 수화반응이 휠씬 느리기 때문에 장기강도의 발현과 내구성이 크고 슬래그의 수화반응은 시멘트에 비해 겔형상이므로 시멘트 페이스트의 조밀함을 증대시킨다.When slag is mixed with water, the initial hydration reaction is induced by cement, but since slag is much slower than cement, the long-term strength is expressed and durability, and the slag hydration reaction is gel form than cement, thus increasing the density of cement paste. Let's do it.
그리고 마이크로 실리카는 바름재 조성물로 사용할 경우 강도의 감소 없이 마이크로실리카의 단위 사용량당 3-4배의 시멘트를 대체할 수 있고 바름재의 구조에 채움 기능과 시멘트의 수화반응 촉진재의 역할을 하며 마이크로실리카는 입자의 크기가 수 ㎛ 이하의 구형입자이므로 간극을 매우는 역할을 한다.In addition, when used as a coating material composition, micro silica can replace 3-4 times the cement per unit usage of micro silica without decreasing the strength, and it functions as a filling function in the structure of the coating material and promotes the hydration reaction of cement. Since the particles are spherical particles having a size of several μm or less, they serve as a gap.
한편 시멘트 수화반응에서 포졸란반응은 수산화칼슘이 필요한데 마이크로실리카가 없는 경우에 수산화칼슘은 큰 덩어리로 존재하며 적은 입자에 비교적 강하게 붙어있어 다음 단계로의 화학반응이 저해 받는다.In the cement hydration reaction, the pozzolanic reaction requires calcium hydroxide. In the absence of microsilica, calcium hydroxide is present in large chunks and adheres to small particles relatively strongly, thus inhibiting the chemical reaction to the next step.
마이크로실리카가 존재하는 경우에는 마이크로실리카가 이 수산화칼슘 덩어리를 잘게 부수는 역할을 하여 수산화칼슘이 포졸라 반응에 좀더 활발하게 참여할 수 있도록 함으로써 전체적인 수화반응을 촉진시킬 수 있다.In the presence of microsilica, the microsilica can break down the calcium hydroxide mass, thus facilitating the overall hydration reaction by allowing calcium hydroxide to participate more actively in the pozzola reaction.
프라이애쉬는 주로 혼합시멘트용으로 첨가되는 재료로서 물을 첨가하면 시멘트와 반응하여 경화성을 나타내고 이는 시멘트에 새로운 특징을 부여하기 위하여 첨가되고 첨가시에는 경화성뿐만 아니라 시멘트가 갖고 있는 여러 가지 결점을 보완할 수 있는데 시멘트의 풍화에 대한 저항성, 가소성과 작업성, 응결중의 수축현상방지, 인장강도증대 화학적 저항성 등을 들 수 있고 값싼 재료로 경제성도 중요시되고 있다.Fry ash is a material that is mainly added for mixed cement, and when water is added, it reacts with cement, which is curable. It is added to give a new characteristic to cement. It is resistant to weathering of cement, plasticity and workability, prevention of shrinkage during condensation, increase of tensile strength and chemical resistance, and economical importance as a cheap material.
AE제(air entraiming)인 아크릴모노머는 시멘트 자체가 강도가 좋으나 가소성이 적고 응결한 다음 수축이 크며 경화된 다음 탄성이 적으므로 이러한 시멘트의 가소성과 수축을 보완하기 위해 석회석(CaCO3)과 함께 첨가되며 아크릴모노머는 접착성과 방수성이 뛰어나며 특히 미장시 가소성이 크고 작업성이 좋으며 이러한 성질이 일정시간 유지되므로 작업하기 쉽다.The acrylic monomer, which is an air entraiming, is added with limestone (CaCO 3 ) to compensate for the plasticity and shrinkage of cement, since the cement itself has good strength but low plasticity, condensation, then shrinkage, hardening and less elasticity. The acrylic monomer is excellent in adhesiveness and waterproofness. Especially, it is easy to work because plasticity is large and workability is good when it is plastered.
그밖에도 아크릴모노머는 본 바름재 조성물의 하나인 메라민과 함께 강력한 방수성을 가지며 백화현상방지, 우수한 접착력을 나타낸다.In addition, the acrylic monomer, together with the melamine of the present coating material composition has strong waterproofness, prevents whitening, and shows excellent adhesion.
또한 셀루로스(Cellulose)는 메라민과 함께 우수한 접착력을 나타내고 유동화제로서의 기능을 가지므로 작업성을 개선할 수 있으며 소포제로서 실리콘 오일은 몰탈제조시 생성되는 가스나 수화반응시에 팽창을 억제하여 팽창에서 수축의 차이를 줄일 수 있고 산화티탄은 백색안료로서 밝은 색상을 얻기 위함이다.Cellulose also exhibits excellent adhesion with meramine and has a function as a fluidizing agent, which improves workability.Silicone oil as an antifoaming agent inhibits expansion during gas or hydration reactions produced during mortar production, The difference in shrinkage can be reduced and titanium oxide is a white pigment to obtain a bright color.
그밖에 특징적인 것은 본 발명 바름재의 주성분이면서 특수기능을 갖게 하는 견운모 분말을 1100℃까지 소성처리한후 결정석출 시간을 주지 않고 급냉시켜 분쇄하므로 서 결정화 에너지를 보존하므로 서 잠재수경성을 갖게 한 분말을 사용한다.In addition, the main component of the present coating material and calcined mica powder having a special function is calcined to 1100 ° C. and then quenched by quenching without giving a crystallization time to preserve crystallization energy, thereby making it possible to use latent hydrophobic powder. do.
또한 본 발명 바름재의 조성비는 우선 견운모 소성분말의 원적외선 방사기능, 항균성, 탈취성등 특수기능의 효과적인 범위와 바름재로서의 일반적인 기능인 강도, 내구성, 무기물의 효과적인 수경화반응 이에 따른 응결후의 치밀성의 상태, 수축의 정도, 그리고 유기물첨가제에 따른 방수성, 접착성, 가소성에 따른 작업성 등을 고려하고 첨가되는 각 조성물 상호간의 보완효과 내지는 상승효과등 전체적인 효과를 감안한 적절한 조성비라할 수 있다.In addition, the composition ratio of the coating material of the present invention is the effective range of special functions such as far-infrared radiation function, antimicrobial activity, and deodorizing property of the small buckwheat buckwheat powder, and the strength, durability, and effective hydrocuring reaction of inorganic materials, which are general functions as the coating material, according to the dense state after condensation, Considering the degree of shrinkage, waterproofness, adhesion, plasticity, workability according to the organic additives, and the appropriate composition ratio in consideration of the overall effect, such as complementary or synergistic effect between each added composition.
이상의 바름재 조성물의 시공은 용도에 따라 약간의 차이는 있지만 바름재 조성물 총중량에 대하여 물 0.5-0.7배 범위로 첨가하여 몰탈을 제조하고 이를 로울러, 스프레이, 슬로건, 마블린, 에어콤프레샤등으로 도장할 수 있고 도장 두께는 0.1mm-2mm까지 도포할 수 있으며 물과 혼합후 2시간 이내에 사용해야한다.Although the construction of the above coating material composition is slightly different depending on the application, it is added to the total weight of the coating material composition in the range of 0.5-0.7 times of water to prepare mortar and apply it to a roller, spray, slogan, marlin, air compressor, etc. Coating thickness can be applied up to 0.1mm-2mm and should be used within 2 hours after mixing with water.
그밖에 주의사항은 가능한 한 4℃ 이하에서 시공하지 말아야하며 시공한 후 2시간 내에 습기에 방치하지 말아야하고 바름재 조성물 분말은 포장으로부터 개봉후 20일 이내로 전부 사용해야하며 유효기간은 제조일로부터 60일 이내로 해야하며 다른 종류의 도료와 함께 사용할 수 없으며 유기용제와 함께 사용해서도 안 된다.In addition, precautions should not be applied at temperatures below 4 ° C as far as possible, and should not be left to moisture within 2 hours after construction, and the powder of the coating material should be used within 20 days after opening from the packaging, and the expiration date should be within 60 days from the date of manufacture. It cannot be used with other types of paints or with organic solvents.
본 발명에 의한 세라믹 바름재 조성물의 물리적 성능, 화학적 성능, 특수기능을 알아보기 위하여 한국건자재시험연구원에서 시험한 시험성적결과가 기능성세라믹 도장재 규격 및 품질기준에 적합한 것으로 나타났다.In order to examine the physical performance, chemical performance, and special functions of the ceramic coating material composition according to the present invention, the test results tested by the Korea Institute of Building Materials and Materials were found to meet the functional ceramic coating material standards and quality standards.
기능성 세라믹 도장재 규격 및 품질기준 : 한국건자재시험연구원 규격Functional Ceramic Coating Material Standards and Quality Standards: Korea Institute of Construction Materials Standards
(KICM-FIR-1084)(KICM-FIR-1084)
- 시 험 성 적 결 과 --Test result-
(물리적 성능) (Physical performance)
(화학적 성능) (Chemical performance)
(원적외선 성능평가) Far Infrared Performance Evaluation
이상에서의 실험결과는 중량비로 견운모분말 30%, 규사 20%, 석회 3%, CSA시멘트 3%, 슬래그 4%, 탄산칼슘 15%, 프라이애쉬 4%, 실리카 5%, 백시멘트 3%, 수용성유기분말(AE제 : 아크릴모노머)10%, 메라민 0.45%, 셀루로즈 0.05%, 소포제 0.5%, 산화티탄 2% 비율로 조성한 조성물 중량에 대하여 물 0.6배로한 몰탈로 0.3mm 두께로 시공 완전 응결 경화한 다음 시험한 성적서임.The above test results showed that the weight ratio of stiff hair powder 30%, silica sand 20%, lime 3%, CSA cement 3%, slag 4%, calcium carbonate 15%, fry ash 4%, silica 5%, back cement 3%, water soluble 10% organic powder (AE: Acrylic monomer), Meramine 0.45%, Cellulose 0.05%, Antifoam 0.5%, Titanium oxide 2% And then tested.
이와 같은 본 발명에 의한 세라믹 바름재 조성물은 바름재로서 일반적인 물성이 우수하고 특히 특수기능인 원적외선 방사기능, 탈취율, 항균성이 뛰어나 아파트의 벽체 및 바닥도장, 지하주차장, 호텔, 병원, 음식점의 내부도장, 목욕탕, 찜질방, 사우나실 등의 벽체도장, 저수지, 물탱크, 저온창고 및 냉동식품창고 등의 내부도장에서 부터 선상 또는 선저도장재로서 폭넓게 사용할 수 있는 세라믹 바름재 조성물이라할 수 있다.Such a ceramic coating material composition according to the present invention is excellent in general physical properties as a coating material, in particular, far-infrared radiation function, deodorization rate, antimicrobial properties of special features, wall and floor coating of the apartment, underground parking lot, hotel, hospital, restaurant interior coating, It can be referred to as a ceramic coating material composition that can be widely used as a shipboard or a bottom coating material from interior coatings such as wall coatings of baths, jjimjilbangs, sauna rooms, reservoirs, water tanks, low temperature warehouses, and frozen food warehouses.
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| KR20000007111A (en) * | 1999-11-26 | 2000-02-07 | 이종헌 | Antibacterial molding composition for interior finish of building |
| KR20020032255A (en) * | 2000-10-26 | 2002-05-03 | 진금수 | Manufacture method of construction material make use of sewage sludge |
| KR20020072397A (en) * | 2001-03-09 | 2002-09-16 | 김명식 | Multi-fluid embrocation for build ing construction |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100803226B1 (en) | 2006-09-08 | 2008-02-18 | 이재환 | Powder paint composition of various function that is hardened by hychation |
| KR100875849B1 (en) | 2007-08-13 | 2008-12-26 | 양병주 | Making method and construction interior/facing materials of far infrared ray, minus ion emitting material |
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| KR20030005733A (en) | 2003-01-23 |
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