KR100397776B1 - Manufacture method for beer scale dissolution liquid and beer scale dissolution liquid thereof - Google Patents
Manufacture method for beer scale dissolution liquid and beer scale dissolution liquid thereof Download PDFInfo
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- KR100397776B1 KR100397776B1 KR10-2001-0021428A KR20010021428A KR100397776B1 KR 100397776 B1 KR100397776 B1 KR 100397776B1 KR 20010021428 A KR20010021428 A KR 20010021428A KR 100397776 B1 KR100397776 B1 KR 100397776B1
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- beer
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- sodium
- sodium carbonate
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- 235000013405 beer Nutrition 0.000 title claims abstract description 107
- 238000000034 method Methods 0.000 title claims abstract description 9
- 238000004090 dissolution Methods 0.000 title claims description 28
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000007788 liquid Substances 0.000 title 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 50
- 239000000203 mixture Substances 0.000 claims abstract description 40
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 claims abstract description 26
- AEQDJSLRWYMAQI-UHFFFAOYSA-N 2,3,9,10-tetramethoxy-6,8,13,13a-tetrahydro-5H-isoquinolino[2,1-b]isoquinoline Chemical compound C1CN2CC(C(=C(OC)C=C3)OC)=C3CC2C2=C1C=C(OC)C(OC)=C2 AEQDJSLRWYMAQI-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 25
- 235000012207 sodium gluconate Nutrition 0.000 claims abstract description 25
- 239000000176 sodium gluconate Substances 0.000 claims abstract description 25
- 229940005574 sodium gluconate Drugs 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- PHOQVHQSTUBQQK-SQOUGZDYSA-N D-glucono-1,5-lactone Chemical compound OC[C@H]1OC(=O)[C@H](O)[C@@H](O)[C@@H]1O PHOQVHQSTUBQQK-SQOUGZDYSA-N 0.000 claims abstract description 22
- 235000012209 glucono delta-lactone Nutrition 0.000 claims abstract description 21
- 229960003681 gluconolactone Drugs 0.000 claims abstract description 21
- 239000000182 glucono-delta-lactone Substances 0.000 claims abstract description 19
- 239000008213 purified water Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 14
- 229940074404 sodium succinate Drugs 0.000 claims abstract description 10
- 239000004575 stone Substances 0.000 claims abstract description 5
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 16
- 229940124274 edetate disodium Drugs 0.000 claims description 16
- 238000000855 fermentation Methods 0.000 claims description 10
- 230000004151 fermentation Effects 0.000 claims description 10
- 238000003860 storage Methods 0.000 claims description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 15
- 238000005260 corrosion Methods 0.000 abstract description 8
- 230000007797 corrosion Effects 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract description 5
- 229910017604 nitric acid Inorganic materials 0.000 abstract description 5
- 235000011121 sodium hydroxide Nutrition 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 4
- 230000006866 deterioration Effects 0.000 abstract description 3
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract description 2
- 238000011109 contamination Methods 0.000 abstract description 2
- 229920001971 elastomer Polymers 0.000 abstract description 2
- 239000003054 catalyst Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000021962 pH elevation Effects 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000003113 alkalizing effect Effects 0.000 description 1
- -1 ansan Chemical compound 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229950006191 gluconic acid Drugs 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000006166 lysate Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3209—Amines or imines with one to four nitrogen atoms; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/268—Carbohydrates or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Cleaning By Liquid Or Steam (AREA)
Abstract
맥주의 제조 또는 보관시에 맥주용기의 내부 표면에 맥주 때가 발생하게 되는데 이를 일컬어 비어 스케일(BEER SCALE 또는 BEER STONE이라고도 함)이라 한다.When the beer is manufactured or stored, beer grits are generated on the inner surface of the beer container, which is also called beer scale (also called BEER SCALE or BEER STONE).
이러한 비어 스케일(BEER SCALE)은 맥주의 변질 및 오염의 원인이 되어 제거의 필요가 있는데 이러한 제거작업은 가성소다, 안산, 질산 또는 이들의 복합물등을 사용하여 맥주용기에서 비어 스케일(BEER SCALE)을 브러쉬등으로 박리시키는 작업에 의하였으므로 항상 비어 스케일(BEER SCALE)의 찌꺼기가 잔존하고, 또한 위와 같은 가성소다, 안산, 질산 또는 이들의 복합물등은 강산 또는 강 알칼리어여서 세척 작업자가 상당한 주의 기울어 취급해야 하므로 방독면, 고무장갑등의 안전 용구를 사용해야하는 단점이 있고, 이러한 안전용구를 사용하여도 안전사고가 발생하는 등의 문제점이 그대로 노출되고 있는 실정이다.BEER SCALE causes deterioration and contamination of beer and needs to be removed. This removal process uses BEA SCALE in a beer container using caustic soda, an acid, nitric acid, or a combination thereof. Since it is peeled off with a brush or the like, the residue of BEER SCALE always remains, and the caustic soda, an acid, nitric acid, or a combination thereof is a strong acid or strong alkali, so the cleaning worker handles it with great care. Since there is a disadvantage that you must use safety equipment such as gas masks, rubber gloves, the situation such as the occurrence of a safety accident even when using these safety equipment is exposed.
본 발명은 이러한 문제점을 해결하기 위하여 글루콘산 나트륨(SODIUM GLUCONATE), 글루코노 델타 락톤(GLUCONO-δ-LACTONE) , 호박산 나트륨(DISODIUM SUCCINATE), 이디티에이 나트륨(EDETATE DISODIUM) 및 탄산 나트륨(SODIUM CARBONATE)를 정제수에 교반하면서 가열하여 완전히 용해한 다음, 교반하면서 냉각시키고, 여과하는 것에 의하여 맥주용기의 부식 및 비어 스케일의 생성을 방지하고, 생성된 비어 스케일을 용해시킬 수 있었다.In order to solve this problem, the present invention provides sodium gluconate (SODIUM GLUCONATE), glucono delta lactone (GLUCONO-δ-LACTONE), sodium succinate (DISODIUM SUCCINATE), EDIDATE DISODIUM and sodium carbonate (SODIUM CARBONATE). The mixture was heated in purified water while stirring to dissolve completely, then cooled while stirring and filtered to prevent corrosion of the beer vessel and generation of beer scales, and the resulting beer scales could be dissolved.
Description
본 발명은 맥주 제조공정에서 맥주의 발효 및 보관시에 사용하는 용기의 내측 표면상에 반드시 발생하는 비어 스케일(BEER SCALE; BEER STONE 이라고도 함)을 효과적으로 제거 및 방지하기 위한 비어 스케일(BEER SCALE) 용해 조성물의 제조 방법과 이에 의해 제조한 비어 스케일(BEER SCALE)용해 조성물에 관한 것이다The present invention dissolves beer scale (BEER SCALE) to effectively remove and prevent the beer scale (BEER SCALE, also known as BEER STONE) occurring on the inner surface of the container used for fermentation and storage of beer in the beer manufacturing process. The present invention relates to a method for preparing the composition and a BEER SCALE dissolving composition produced thereby.
일반적으로 맥주는 첨부한 도면 도 1에 도시하고 있는 바와 같이, 맥주원료를 발효 또는 숙성용기(1)에 투입하여 이를 발효 또는 숙성시키는 공정, 숙성된 맥주를 저장용기(2)에 저장하는 저정공정 및 공급라인(3)을 통하여 캔, 병 또는 생맥주통(4)에 주입하는 공정으로 이루어진다.In general, the beer is as shown in Figure 1 attached to the fermentation or fermentation or fermentation or fermentation vessel (1), the process of fermentation or aging, storage process for storing the matured beer in the storage vessel (2) And a step of injecting the can, the bottle, or the draft beer container 4 through the supply line 3.
이러한 맥주제조공정시에 상기한 바와 같이, 필수적으로 발효 또는 숙성용기(1), 저장용기(2), 공급라인(3) 및 생맥주통(4))이하 "맥주용기"라 통칭한다)을 사용하게 된다.As described above in the beer production process, essentially fermentation or maturation vessel (1), storage vessel (2), supply line (3) and draft beer barrel (4) or less "cold container" is used)) Done.
이때 상기한 맥주용기의 내부 표면에는 마치 물때가 생기는 것과 같은 맥주 때가 발생하게 되는데 이를 일컬어 비어 스케일(BEER SCALE 또는 BEER STONE이라고도 함)(이하 "비어 스케일(BEER SCALE)"으로 통칭한다)이라 한다.At this time, the inner surface of the beer container, such as the generation of beer occurs as if the scale occurs, also known as beer scale (BEER SCALE or BEER STONE) (hereinafter referred to as "beer scale (BEER SCALE)").
이러한 비어 스케일(BEER SCALE)은 맥주의 변질 및 오염의 원인이 될뿐만 아니라 맥주의 맛을 변질시키는 주 원인이 되므로 맥주 제조회사에서는 상기한 비어스케일(BEER SCALE)의 발생시 또는 일정 두께가 되면 반드시 세척을 통하여 이를 제거하기 위한 작업을 하게된다.BEER SCALE is not only a cause of beer deterioration and contamination, but also a major cause of deterioration of the taste of beer. Work to remove it through.
이러한 제거작업은 가성소다, 안산, 질산 또는 이들의 복합물등을 사용하여 맥주용기에서 비어 스케일(BEER SCALE)을 브러쉬등으로 박리시키는 정도의 제거 작업을 하게 되므로 항상 비어 스케일(BEER SCALE)의 찌꺼기가 잔존하고, 또한 위와 같은 가성소다, 안산, 질산 또는 이들의 복합물등은 강산 또는 강 알칼리어여서 세척 작업자가 상당한 주의 기울어 취급해야 하므로 방독면, 고무장갑등의 안전 용구를 사용해야하는 단점이 있고, 이러한 안전용구를 사용하여도 안전사고가 발생하는 등의 문제점이 그대로 노출되고 있는 실정이다.This removal process uses caustic soda, an acid, nitric acid, or a combination of these to remove the BE SCALE from the beer container with a brush, etc., so the residue of the BE SCALE is always removed. The remaining caustic soda, ansan, nitric acid, or a combination thereof is a strong acid or strong alkali, so the cleaning worker must handle it with great care, so there is a disadvantage of using safety tools such as gas masks and rubber gloves. Problems such as the occurrence of safety accidents are exposed even when using the tool.
또는 위와 같은 가성소다, 안산, 질산 또는 이들의 복합물등은 독성이 강하므로 반드시 비어스케일의 제거후에는 맥주용기에서 제거해야하므로 용수의 사용이그만큼 필요할 뿐만 아니라 사용된 용수는 다시 위와 같은 독성물질을 그대로 함유하고 있으므로 그대로 방류하게 되면 치명적인 수질오염의 원인이 되므로 별도의 폐수정화처리를 해야하는 문제점이 있고, 사용하는 용수도 70~80℃정도로 가열한 용수에 15~20시간 침적 사용해야만 세척이 되는 문제점이 있다.Or caustic soda, an acid, nitric acid, or a combination of these is highly toxic, so after removing beer scale, it must be removed from the beer container, so the use of water is not only necessary. As it is contained as it is, if discharged as it is, it causes fatal water pollution. Therefore, there is a problem that a separate waste water purification treatment has to be carried out, and the water to be used is also washed only after 15-20 hours of immersion in water heated to about 70 ~ 80 ℃. There is this.
그리고 맥주용기에서 제거한 비어스케일은 인체에 무해한 것임에도 불구하고 이를 건조하게 되면 돌처럼 딱딱해지므로 반드시 별도로 처리해야 하는 단점이 있다.And the beer scale removed from the beer container is harmless to the human body, but when it is dried, it becomes hard as a stone, so it must be treated separately.
이러함 문제점을 해결하기 위하여 본 발명인은 특허 출원 제2000-42057호를 발명하여 출원한 바 있다.In order to solve this problem, the present inventor has invented and applied for patent application No. 2000-42057.
이러한 선 출원 발명은 구연산소다(SODIUM CITRATE)와 정제수를 일차적으로 혼합한 다음, 이 혼합물에 선택적으로 맥주용기의 부식 및 비어스케일의 생성을 방지하기 위하여 글리콘산소다(SODIUM GLUCONATE) 및 글리코닉산 랙톤(GLUCONIC ACID LACTONE)을 첨가물로 사용한 것이였는데, 비어 스케일의 용해에 많은 시간을 요하는 단점이 있었다.This preliminary invention discloses a primary mixing of SODIUM CITRATE with purified water, and then to the mixture to selectively prevent corrosion of beer containers and generation of beer scales. SODIUM GLUCONATE and glyconic acid racton (GLUCONIC ACID LACTONE) was used as an additive, which had the disadvantage of requiring much time for dissolution of the beer scale.
본 발명은 위와같은 종래의 문제점을 근본적으로 해결하기 위하여 비어스케일을 맥주용기에서 완전히 용해시키는 것에 의하여 비어스케일을 제거할 수 있도록 함으로서 비어스케일의 제거작업후에 찌꺼기가 남지않도록 하고, 또한 비어스케일을 용해시키는 본 발명의 용해제는 약 알칼리성이여서 별도의 독성 중화공정 및 인체에 무해하므로 세척시에도 별도의 안전용구의 사용이 필요치 않을 뿐만 아니라비어스케일을 용해한 후에도 그 용해의 정도에 따라 재 사용할 수 있으므로 세척에 필요한 추가비용을 감축할 수 있으면서도 비어 스케일의 용해 시간을 단축하는데 있다.The present invention allows to remove the beer scale by completely dissolving the beer scale in the beer container in order to fundamentally solve the above-mentioned problems, so that no residue is left after the beer scale is removed, and also the beer scale is dissolved. Since the solubilizer of the present invention is weakly alkaline and harmless to a separate toxic neutralization process and human body, it does not require the use of a separate safety tool during cleaning, and can be reused depending on the degree of dissolution even after dissolving the beer scale. It is possible to reduce the additional cost required while shortening the dissolution time of the beer scale.
이러한 본 발명을 달성하기 위해 본 발명에서는 글루콘산 나트륨(SODIUM GLUCONATE), 글루코노 델타 락톤(GLUCONO-δ-LACTONE) , 호박산 나트륨(DISODIUM SUCCINATE), 이디티에이 나트륨(EDETATE DISODIUM) 및 탄산 나트륨(SODIUM CARBONATE)를 정제수에 교반하면서 가열하여 완전히 용해한 다음, 교반하면서 냉각시키고, 여과하는 것에 의하여 맥주용기의 부식 및 비어 스케일의 생성을 방지하고, 생성된 비어 스케일을 용해시킬 수 있었다.In order to achieve the present invention, in the present invention, sodium gluconate (SODIUM GLUCONATE), glucono delta lactone (GLUCONO-δ-LACTONE), sodium succinate (DISODIUM SUCCINATE), sodium editiate (EDETATE DISODIUM) and sodium carbonate (SODIUM CARBONATE) ) Was completely dissolved by heating with purified water, stirred, cooled, and filtered to prevent corrosion of beer vessels and generation of beer scales, and dissolution of the resulting beer scales.
도 1은 맥주 제조 공정의 개략도,1 is a schematic diagram of a beer manufacturing process,
<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>
1: 숙성용기 2: 저장용기1: Aging container 2: Storage container
3: 공급라인 4: 캔, 병 또는 생맥주통3: supply line 4: can, bottle or draft beer
이하 본 발명을 상세히 살펴보기로 한다.Hereinafter, the present invention will be described in detail.
글루콘산 나트륨(SODIUM GLUCONATE), 글루코노 델타 락톤(GLUCONO-δ-LACTONE) , 호박산 나트륨(DISODIUM SUCCINATE), 이디티에이 나트륨(EDETATE DISODIUM) 및 탄산 나트륨(SODIUM CARBONATE)의 혼합물 50 ~ 20.5wt%와 정제수 50 ~ 79.5wt%를 혼합하여 제조하는데 특징이 있다.50 ~ 20.5wt% of purified water of SODIUM GLUCONATE, GLUCONO-δ-LACTONE, DISODIUM SUCCINATE, EDIDATE DISODIUM and SODIUM CARBONATE It is characterized by manufacturing by mixing 50 ~ 79.5wt%.
이때 상기한 혼합물은 각각 다음과 같이 조성된다.In this case, the above mixtures are each formulated as follows.
글루콘산 나트륨(SODIUM GLUCONATE) 8.5 ~ 7wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 3.5 ~ 1.5wt%, 호박산 나트륨(DISODIUM SUCCINATE) 8 ~ 4wt%, 이디티에이 나트륨(EDETATE DISODIUM) 20 ~ 5wt%, 및 탄산 나트륨(SODIUM CARBONATE) 10 ~ 3wt%로 조성한다.SODIUM GLUCONATE 8.5 ~ 7wt%, GLUCONO-δ-LACTONE 3.5 ~ 1.5wt%, DISODIUM SUCCINATE 8 ~ 4wt%, EDETATE DISODIUM 20 ~ 5wt %, And sodium carbonate (SODIUM CARBONATE) 10 to 3wt%.
이러한 혼합물의 조성에서 이디티에이 나트륨(EDETATE DISODIUM)을 20 ~ 5wt%로 조성하게 된는데 이때 5wt% 이하로 조성되는 경우에는 비어 스케일을 용해시키기는 하나 용해정도가 느려 많은 작업시간을 요하므로 비 경제적인 단점이 있는 반면에 20wt%이상으로 조성하는 경우에는 정제수에 포화상태가 되어 완전한 용해가 이루어지지 않는 문제점이 있다.In the composition of this mixture, EDETATE DISODIUM is composed of 20 to 5 wt%. If the composition is 5 wt% or less, beer scale is dissolved, but the dissolution rate is slow and requires a lot of working time. On the other hand, when the composition is 20wt% or more, there is a problem in that it becomes saturated in purified water and does not completely dissolve.
그리고 이때 상기한 글리콘산 소다(SODIUM GLUCONATE)는 금속이온봉쇄제로서 맥주용기의 부식을 방지하기 위해 사용하게 되는데 이때 글루콘산 나트륨(SODIUM GLUCONATE)이 8.5wt%이상으로 조성하는 경우에는 다른 조성물의 조성비를 낮추게하여 용해의 속도를 저하시키면서도 과다 사용으로 인한 비 경제적인 문제점이 있다.In this case, the above-mentioned sodium gluconate (SODIUM GLUCONATE) is used as a metal ion blocking agent to prevent corrosion of the beer container. In this case, when sodium gluconate (SODIUM GLUCONATE) is composed of 8.5 wt% or more, By lowering the composition ratio, there is an uneconomical problem due to excessive use while lowering the rate of dissolution.
다시말해, 7wt%이하로 조성하는 경우에는 맥주 용기의 부식을 염격하게 방지를 못하여 부분적으로 부식이 발생하는 반면에 8.5wt%이하로 조성하여도 맥주용기의 부식이 발생하지 않으므로 그 이상으로 조성하는 것은 비 경제적이고, 다름 조성물의 조성비에 변화를 주는 문제점으로 인하여 그 본래의 목적을 달성할 수 없게 된다.In other words, if the composition is less than 7wt%, the corrosion of the beer container cannot be prevented in a violent manner, and partial corrosion occurs, whereas if the composition is less than 8.5wt%, the corrosion of the beer container does not occur. It is uneconomical and it is impossible to achieve its original purpose due to the problem of changing the composition ratio of the other composition.
그리고 글루코노 델타 락톤(GLUCONO-δ-LACTONE)은 비어 스케일의 부착억제를 위해 사용하는 것으로서, 본 발명에서는 3.5 ~ 1.5wt%로 조성이 되는데, 이때 1.5wt%이하로 조성하는 경우에는 비어 스케일이 쉽게 생성되어 용기에 쉽게 부착되는 문제점이 발견된다.Glucono-lactone (GLUCONO-δ-LACTONE) is used to inhibit adhesion of the beer scale, and in the present invention, the composition is composed of 3.5 to 1.5 wt%, in which case the beer scale is less than 1.5 wt%. The problem is found to be easily created and easily attached to the container.
그러나 3.5wt%이하로 조성하여도 충분한 비어스케일의 생성을 억제하는 역활을 하므로 그 이상으로 조성하는 것은 비경제적이다.However, even if the composition is less than 3.5wt%, it plays a role of suppressing the generation of sufficient beer scale.
호박산 나트륨(DISODIUM SUCCINATE)은 상기한 이디티에이 나트륨(EDETATE DISODIUM)이 정제수에 용해 및 비어 스케일 용해시에 촉매 역활을 하기 위하여 참가제로 사용하는 것인데, 이때 호박산 나트륨(DISODIUM SUCCINATE) 4wt%이하로 조성하는 경우에는 비어 스케일의 용해 속도가 느린 반면에 8wt%이하로 조성하여도 이디티에이 나트륨(EDETATE DISODIUM)와의 충분한 촉매 역할을 행하여 본 발명자가 원하는 시간내에 비어 스케일을 방지할 수 있었다.Sodium succinate (DISODIUM SUCCINATE) is the use of EDETATE DISODIUM as a catalyst to dissolve in purified water and to act as a catalyst for beer scale dissolution. At this time, the composition of sodium succinate (DISODIUM SUCCINATE) is less than 4wt%. In this case, while the dissolution rate of the beer scale was slow, the composition of 8 wt% or less could serve as a sufficient catalyst with EDETATE DISODIUM to prevent the beer scale within the desired time.
그리고 탄산 나트륨(SODIUM CARBONATE)을 조성하게 되는데, 이는 상기한 혼합물이 산성에 가까울 뿐만 아니라 비어 스케일이 산성이므로 이를 알칼리화하여 비어 스케일의 조속한 용해를 촉진하기 위하여 사용된다.And sodium carbonate (SODIUM CARBONATE), which is not only close to acidic but also used to promote rapid dissolution of the beer scale by alkalizing it because the beer scale is acidic.
이때 3wt%이하로 조성하는 경우에는 알카리화가 낮아 충분한 용해 속도를 나타내지 않는 반면에 10wt%이상으로 조성하면 원하는 페하(ph) 즉, 강 알칼리화되어 본 발명의 강 알칼리화에 의한 문제점이 야기된다.At this time, when the composition is less than 3wt%, the alkalinization is low and does not indicate a sufficient dissolution rate. On the other hand, if the composition is 10wt% or more, the desired pH (ph), that is, strong alkalinization, causes a problem due to the strong alkalinization of the present invention.
이러한 조성물을 정제수에서 충분히 교반을 행하면서 용해를 시키는데 이때 50이상의 온도에서 가열을 행하면서 용해시킨다.The composition is dissolved while stirring in purified water while being dissolved at a temperature of 50 or more.
이때 50℃ 이하의 온도에서 교반하게 되면 조성물의 용해 속도가 느린 문제점이 있다.At this time, if the stirring at a temperature below 50 ℃ there is a problem that the dissolution rate of the composition is slow.
이러한 용해과정에서 상기한 조성물을 정제수에서 완전히 용해시킨 다음 상온에서 냉각하고, 다시 여과하여 본 발명의 용해 조성물을 얻는다.During this dissolution, the composition is completely dissolved in purified water, cooled at room temperature, and filtered again to obtain the dissolution composition of the present invention.
실시예 1Example 1
생맥주 용기의 내측면 표면에 비어스케일이 약 0.1mm의 두께를 생성하고 있는 생맥주 용기에 글루콘산 나트륨(SODIUM GLUCONATE) 8wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 2.5wt%, 호박산 나트륨(DISODIUM SUCCINATE) 5wt%, 이디티에이 나트륨(EDETATE DISODIUM) 12.5wt%, 탄산 나트륨(SODIUM CARBONATE) 6wt%와 정제수 66wt%로 정량하여 혼합한 다음 55℃의 온도에서 충분히 교반시키면서 완전히 용해시킨 용해물 5ℓ를 생맥주용기에 투입하였다.8 wt% of sodium gluconate, 2.5 wt% of GLUCONO-δ-LACTONE, sodium succinate in a draft beer container having a beer scale of about 0.1 mm on the inner surface of the draft beer container. 5 wt% of DISODIUM SUCCINATE, 12.5 wt% of EDETATE DISODIUM, 6 wt% of SODIUM CARBONATE, and 66 wt% of purified water were mixed and mixed, and 5 liters of the completely dissolved lysate with sufficient stirring at a temperature of 55 ° C. Draft beer was put into the container.
35분정도의 시간이 지난 다음 생맥주통의 내부를 육안으로 살펴보았더니 상기 용해조성물이 잠겨있었던 생맥주 용기에 내측면 표면에 생성되었던 비어 스케일이 용해되어 비어 스케일을 확인할 수 없었으니 용해조성물이 잠기지 않은 부분에서는 비어 스케일이 그대로 잔존하고 있었다.After 35 minutes, the inside of the draft beer was visually inspected, and the beer scale generated on the inner surface of the draft beer container was dissolved and the beer scale could not be confirmed. In the part, the beer scale remained as it is.
실시예 2Example 2
맥주 저장용기에서 분리해낸 약 0.3mm의 두께를 가진 비어 스케일 30g을 글루콘산 나트륨(SODIUM GLUCONATE) 8wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 2.5wt%, 호박산 나트륨(DISODIUM SUCCINATE) 5wt%, 이디티에이 나트륨(EDETATE DISODIUM) 12.5wt%, 탄산 나트륨(SODIUM CARBONATE) 6wt%와 정제수 66wt%로 정량하여 혼합한 다음 55℃의 온도에서 충분히 교반시키면서 완전히 용해시킨 용해 조성물 3ℓ에 투입하였다.30 g of beer scale, separated from the beer container, was weighed about 30 grams of sodium gluconate (SODIUM GLUCONATE) 8 wt%, Glucono-lactone (GLUCONO-δ-LACTONE) 2.5 wt%, sodium succinate (5% wt) DISODIUM SUCCINATE 12.5 wt% of EDETATE DISODIUM, 6 wt% of sodium carbonate (SODIUM CARBONATE) and 66 wt% of purified water were mixed, mixed, and then added to 3 L of a dissolving composition that was completely dissolved with sufficient stirring at a temperature of 55 ° C.
완전히 용해될 때 까지의 시간을 확인하여 본 결과 35분간의 시간이 소요되었다.The time until complete dissolution was confirmed and the result was 35 minutes.
실시예 3Example 3
발효용기에서 분리해낸 약 0.3mm의 두께를 가진 비어스케일 50g을 글루콘산 나트륨(SODIUM GLUCONATE) 7.5wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 2.0wt%, 호박산 나트륨(DISODIUM SUCCINATE) 5wt%, 이디티에이 나트륨(EDETATE DISODIUM) 10wt%, 탄산 나트륨(SODIUM CARBONATE) 5.5wt%와 정제수 70wt%로 정량하여 혼합한 다음 55℃의 온도에서 충분히 교반시키면서 완전히 용해시킨 용해 조성물 5ℓ에 투입하였다.50 g of beer scale having a thickness of about 0.3 mm separated from the fermentation vessel was 7.5 wt% of sodium gluconate (SODIUM GLUCONATE), 2.0 wt% of GLUCONO-δ-LACTONE, and 5 wt% of sodium succinate (DISODIUM SUCCINATE). 10 wt% of EDETATE DISODIUM, 5.5 wt% of sodium carbonate (SODIUM CARBONATE) and 70 wt% of purified water were mixed, mixed, and then added to 5 L of a completely dissolved dissolution composition with sufficient stirring at a temperature of 55 ° C.
완전히 용해될 때 까지의 시간을 확인하여 본 결과 76분의 시간이 소요되었다.Checking the time until complete dissolution resulted in 76 minutes.
실시예 4Example 4
글루콘산 나트륨(SODIUM GLUCONATE) 7.5wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 2.0wt%, 호박산 나트륨(DISODIUM SUCCINATE) 5wt%, 이디티에이 나트륨(EDETATE DISODIUM) 10wt%, 탄산 나트륨(SODIUM CARBONATE) 5.5wt%와 정제수 70wt%로 정량하여 혼합한 다음 55℃의 온도에서 충분히 교반시키면서 완전히 용해시킨 용해 조성물 5ℓ를 얻었다.7.5 wt% of sodium gluconate, 2.0wt% of glucono delta-lactone (GLUCONO-δ-LACTONE), 5wt% of DISODIUM SUCCINATE, 10wt% of EDETATE DISODIUM, sodium carbonate ) 5 wt% of a dissolving composition was obtained by mixing 5.5 wt% and 70 wt% of purified water and completely dissolving the mixture at 55 ° C. with sufficient stirring.
맥주 저장용기에서 분리해낸 약 0.25mm의 두께를 가진 비어스케일 30g을 상기한 용해 조성물에 투입시켜 완전히 용해될 때 까지의 시간을 확인하여 본 결과 42분간의 시간이 소요되었다.30 g of beer scale having a thickness of about 0.25 mm separated from the beer storage container was added to the dissolution composition to check the time until complete dissolution. As a result, it took 42 minutes.
실시예 5Example 5
생맥주 용기에 내측면 표면에 비어스케일이 약 0.2mm의 두께를 생성하고 있는 생맥주 용기에 글루콘산 나트륨(SODIUM GLUCONATE) 7.5wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 2.0wt%, 호박산 나트륨(DISODIUM SUCCINATE) 5wt%, 이디티에이 나트륨(EDETATE DISODIUM) 15wt%, 탄산 나트륨(SODIUM CARBONATE) 6wt%와 정제수 65.5wt%로 정량하여 혼합한 다음 55℃의 온도에서 충분히 교반시키면서 완전히 용해시킨 용해물 5ℓ를 투입하였다.7.5 wt% of sodium gluconate (SODIUM GLUCONATE), 2.0 wt% of GLUCONO-δ-LACTONE, sodium succinate in a draft beer container having a beer scale of about 0.2 mm on the inner surface of the draft beer container (DISODIUM SUCCINATE) 5wt%, EDETATE DISODIUM 15wt%, 6wt% sodium carbonate (SODIUM CARBONATE) and 65.5wt% of purified water, mix and mix, and then completely dissolve the dissolved solution 5ℓ with sufficient stirring at the temperature of 55 ℃. Was added.
30분정도의 시간이 지난 다음 생맥주통의 내부를 육안으로 살펴보았더니 상기 혼합물이 잠겨있었던 생맥주 용기에 내측면 표면에 생성되었던 비어 스케일이 확연히 용해되어 비어스케일을 확인할 수 없다.After about 30 minutes, the inside of the draft beer was visually inspected, and the beer scale generated on the inner surface of the draft beer container in which the mixture was immersed was clearly dissolved so that the beer scale could not be confirmed.
실시예 6Example 6
글루콘산 나트륨(SODIUM GLUCONATE) 8wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 2.5wt%, 호박산 나트륨(DISODIUM SUCCINATE) 5wt%, 이디티에이 나트륨(EDETATE DISODIUM) 15wt%, 탄산 나트륨(SODIUM CARBONATE) 6wt%와 정제수 63.5wt%로 정량하여 혼합한 다음 55℃의 온도에서 충분히 교반시키면서 완전히 용해시킨 용해 조성물 5ℓ를 구하였다.SODIUM GLUCONATE 8wt%, Glucono-delta-lactone 2.5wt%, DISODIUM SUCCINATE 5wt%, EDETATE DISODIUM 15wt%, SODIUM CARBONATE 6 L and 63.5 wt% of purified water were mixed, and 5 L of a dissolving composition dissolved completely with stirring at a temperature of 55 ° C was obtained.
맥주 발효용기에서 분리해낸 약 0.3mm의 두께를 가진 비어스케일 30g을 투입시켜 완전히 용해될 때 까지의 시간을 확인하여 본 결과 20분간의 시간이 소요되었다.Into the beer scale 30g having a thickness of about 0.3mm separated from the beer fermentation vessel was added to confirm the time until complete dissolution, the result was 20 minutes.
실시예 7Example 7
글루콘산 나트륨(SODIUM GLUCONATE) 8wt%, 글루코노 델타 락톤(GLUCONO-δ-LACTONE) 2.5wt%, 호박산 나트륨(DISODIUM SUCCINATE) 5wt%, 이디티에이 나트륨(EDETATE DISODIUM) 17wt%, 탄산 나트륨(SODIUM CARBONATE) 6wt%와 정제수 61.5wt%로 정량하여 혼합한 다음 55℃의 온도에서 충분히 교반시키면서 완전히 용해시킨 용해 조성물 5ℓ를 구하였다.SODIUM GLUCONATE 8wt%, Glucono-delta-lactone 2.5wt%, DISODIUM SUCCINATE 5wt%, EDETATE DISODIUM 17wt%, SODIUM CARBONATE 6 L and 61.5 wt% of purified water were mixed and mixed. Then, 5 L of a dissolving composition dissolved completely with stirring at a temperature of 55 ° C. was obtained.
이러한 0.3mm의 두께를 가진 비어 스케일 30g을 투여하여 완전히 용해될 때 까지의 시간은 18분정도의 시간이 소요되었다.The time required to completely dissolve by administering 30 g of the beer scale having a thickness of 0.3 mm was about 18 minutes.
이상 상기의 실시예에서 살펴보았듯이 본 발명에 의한 용해 조성물은 이디티에이 나트륨(EDETATE DISODIUM)의 조성비가 많으면 많아 질수록 비어 스케일의 용해 시간이 짧았고, 특히 본 발명에 의한 제거제는 약 알칼리어여서 인체에 무해하고 비어 스케일의 제거작업이 종래의 방법과 달리 단지 투입하는 것에 의하여 비어스케일을 제거하므로 제거 작업이 용이함을 알 수 있다.As described in the above embodiments, the dissolution composition according to the present invention has a shorter dissolution time of beer scale as the composition ratio of EDETATE DISODIUM increases, and in particular, the remover according to the present invention is weakly alkaline. It can be seen that the removal operation of the beer scale is harmless, and the removal operation of the beer scale is easy, because the removal of the beer scale is performed by simply putting it in, unlike the conventional method.
이상 상기에서 살펴본 바와같이, 본 발명에서는 글루콘산 나트륨(SODIUM GLUCONATE), 글루코노 델타 락톤(GLUCONO-δ-LACTONE) , 호박산 나트륨(DISODIUM SUCCINATE), 이디티에이 나트륨(EDETATE DISODIUM) 및 탄산 나트륨(SODIUM CARBONATE)를 정제수에 교반하면서 가열하여 완전히 용해한 다음, 교반하면서 냉각시키고, 여과하는 것에 의하여 맥주용기의 부식 및 비어 스케일의 생성을 방지하고, 생성된 비어 스케일을 용해시킬 수 있었으며, 또한 비어스케일의 제거작업후에도 찌꺼기가 남지 않으며 약 알칼리성이여서 별도의 독성 중화공정 및 인체에 무해하므로 세척시에도 별도의 안전용구의 사용이 필요치 않을 뿐만 아니라 용해수의 온도(냉수 또는 온수)에 상관없이 사용할 수 있고, 비어 스케일을 용해한 후에도 그 용해의 정도에 따라 재 사용할 수 있으므로 세척에 필요한 추가비용을 감축할 수 있는 매우 유용한 발명임이 분명하다.As described above, in the present invention, sodium gluconate (SODIUM GLUCONATE), glucono delta lactone (GLUCONO-δ-LACTONE), sodium succinate (DISODIUM SUCCINATE), editiate sodium (EDETATE DISODIUM) and sodium carbonate (SODIUM CARBONATE) ) Was completely dissolved by heating in purified water with stirring, then cooled with stirring, and filtered to prevent corrosion of beer vessels and generation of beer scales, dissolving the generated beer scales, and removing beer scales. It does not leave any residue afterwards and is slightly alkaline, so it is not harmful to humans and neutralizes the process of toxic neutralization.Therefore, it does not require the use of a separate safety tool for cleaning and can be used regardless of the temperature of the melted water (cold water or hot water). After dissolving, it can be reused depending on the degree of dissolution. To be a very useful invention in a garbage can for reductions is clear.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05202392A (en) * | 1991-11-08 | 1993-08-10 | Daisan Kogyo Kk | Detergent composition |
| KR940014754A (en) * | 1992-12-08 | 1994-07-19 | 김현숙 | Pollution-Free Multi-Purpose Degreasing Cleaner |
| KR960041330A (en) * | 1995-05-26 | 1996-12-19 | 배순훈 | Dishwasher detergent |
| JP2000104096A (en) * | 1998-09-30 | 2000-04-11 | Kirin Brewery Co Ltd | Detergent for beer dispenser and cleaning method |
| JP2000319695A (en) * | 1999-05-12 | 2000-11-21 | Daisan Kogyo Kk | Beer dispenser cleaning aqueous solution |
| JP2001207190A (en) * | 2000-01-24 | 2001-07-31 | Daisan Kogyo Kk | Acidic detergent for beer brewing facility |
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2001
- 2001-04-20 KR KR10-2001-0021428A patent/KR100397776B1/en not_active IP Right Cessation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05202392A (en) * | 1991-11-08 | 1993-08-10 | Daisan Kogyo Kk | Detergent composition |
| KR940014754A (en) * | 1992-12-08 | 1994-07-19 | 김현숙 | Pollution-Free Multi-Purpose Degreasing Cleaner |
| KR960041330A (en) * | 1995-05-26 | 1996-12-19 | 배순훈 | Dishwasher detergent |
| JP2000104096A (en) * | 1998-09-30 | 2000-04-11 | Kirin Brewery Co Ltd | Detergent for beer dispenser and cleaning method |
| JP2000319695A (en) * | 1999-05-12 | 2000-11-21 | Daisan Kogyo Kk | Beer dispenser cleaning aqueous solution |
| JP2001207190A (en) * | 2000-01-24 | 2001-07-31 | Daisan Kogyo Kk | Acidic detergent for beer brewing facility |
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