KR100397682B1 - Ionized calcium and ionized calcium water made of pearl shell and preparation method of the same - Google Patents
Ionized calcium and ionized calcium water made of pearl shell and preparation method of the same Download PDFInfo
- Publication number
- KR100397682B1 KR100397682B1 KR10-2001-0009615A KR20010009615A KR100397682B1 KR 100397682 B1 KR100397682 B1 KR 100397682B1 KR 20010009615 A KR20010009615 A KR 20010009615A KR 100397682 B1 KR100397682 B1 KR 100397682B1
- Authority
- KR
- South Korea
- Prior art keywords
- ionized calcium
- pearl
- calcium
- water
- cylinder
- Prior art date
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- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 92
- 239000011575 calcium Substances 0.000 title claims abstract description 92
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 92
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims description 5
- 238000000034 method Methods 0.000 claims abstract description 67
- 230000008569 process Effects 0.000 claims abstract description 54
- 239000000047 product Substances 0.000 claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 claims abstract description 27
- 229910001018 Cast iron Inorganic materials 0.000 claims abstract description 22
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000012535 impurity Substances 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 238000001556 precipitation Methods 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 13
- 238000002485 combustion reaction Methods 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000010298 pulverizing process Methods 0.000 claims abstract description 10
- 239000006228 supernatant Substances 0.000 claims abstract description 10
- 238000001035 drying Methods 0.000 claims abstract description 8
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 7
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000001630 malic acid Substances 0.000 claims abstract description 7
- 235000011090 malic acid Nutrition 0.000 claims abstract description 7
- 239000012153 distilled water Substances 0.000 claims abstract description 6
- 230000001376 precipitating effect Effects 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 5
- 239000012530 fluid Substances 0.000 claims abstract description 4
- 238000000227 grinding Methods 0.000 claims abstract description 4
- 238000010304 firing Methods 0.000 claims description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 6
- 239000012452 mother liquor Substances 0.000 claims description 6
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 239000011049 pearl Substances 0.000 abstract description 80
- 239000001384 succinic acid Substances 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 2
- 238000001704 evaporation Methods 0.000 abstract description 2
- 210000003739 neck Anatomy 0.000 abstract description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 12
- 239000007788 liquid Substances 0.000 description 11
- 210000004027 cell Anatomy 0.000 description 10
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 9
- 239000000292 calcium oxide Substances 0.000 description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 8
- 108010006161 conchiolin Proteins 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000008280 blood Substances 0.000 description 7
- 210000004369 blood Anatomy 0.000 description 7
- 230000009471 action Effects 0.000 description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 description 6
- 230000000144 pharmacologic effect Effects 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 108090000623 proteins and genes Proteins 0.000 description 4
- 102000004169 proteins and genes Human genes 0.000 description 4
- 235000015170 shellfish Nutrition 0.000 description 4
- 210000003491 skin Anatomy 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000011573 trace mineral Substances 0.000 description 4
- 235000013619 trace mineral Nutrition 0.000 description 4
- 206010006956 Calcium deficiency Diseases 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 102000004190 Enzymes Human genes 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005903 acid hydrolysis reaction Methods 0.000 description 3
- 210000000988 bone and bone Anatomy 0.000 description 3
- 201000010099 disease Diseases 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- -1 organic acid calcium salts Chemical class 0.000 description 3
- 239000000199 parathyroid hormone Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 208000001132 Osteoporosis Diseases 0.000 description 2
- 102000003982 Parathyroid hormone Human genes 0.000 description 2
- 108090000445 Parathyroid hormone Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 210000004556 brain Anatomy 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 238000011033 desalting Methods 0.000 description 2
- 208000035475 disorder Diseases 0.000 description 2
- 230000003203 everyday effect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 229960001319 parathyroid hormone Drugs 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 208000024827 Alzheimer disease Diseases 0.000 description 1
- 206010003210 Arteriosclerosis Diseases 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- 101710205660 Calcium-transporting ATPase Proteins 0.000 description 1
- 101710134161 Calcium-transporting ATPase sarcoplasmic/endoplasmic reticulum type Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 235000019739 Dicalciumphosphate Nutrition 0.000 description 1
- 206010014970 Ephelides Diseases 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 208000003351 Melanosis Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000000202 analgesic effect Effects 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 208000011775 arteriosclerosis disease Diseases 0.000 description 1
- 235000013527 bean curd Nutrition 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 210000004958 brain cell Anatomy 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 206010012601 diabetes mellitus Diseases 0.000 description 1
- NEFBYIFKOOEVPA-UHFFFAOYSA-K dicalcium phosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])([O-])=O NEFBYIFKOOEVPA-UHFFFAOYSA-K 0.000 description 1
- 229940038472 dicalcium phosphate Drugs 0.000 description 1
- 229910000390 dicalcium phosphate Inorganic materials 0.000 description 1
- 230000001079 digestive effect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000020774 essential nutrients Nutrition 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000003779 hair growth Effects 0.000 description 1
- 235000013402 health food Nutrition 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000003834 intracellular effect Effects 0.000 description 1
- 238000000752 ionisation method Methods 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000011050 natural pearl Substances 0.000 description 1
- 210000004126 nerve fiber Anatomy 0.000 description 1
- 210000004498 neuroglial cell Anatomy 0.000 description 1
- 210000002569 neuron Anatomy 0.000 description 1
- 235000012149 noodles Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229940124595 oriental medicine Drugs 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 210000002990 parathyroid gland Anatomy 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 235000020991 processed meat Nutrition 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000009759 skin aging Effects 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 230000009469 supplementation Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/005—Preparation involving liquid-liquid extraction, absorption or ion-exchange
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/40—Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/80—Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/52—Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
Abstract
본 발명은 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수의 제조방법에 관한 것으로, 기 위하여 본 발명은 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수의 제조방법에 있어서, 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수의 제조방법에 있어서, 진주조개 내외부의 불순물을 제거하는 불순물 제거공정과, 상기 진주조개를 건조하는 건조공정과, 상기 진주조개를 직경 3∼9㎝ 정도의 크기로 파쇄하는 파쇄공정과, 상기 파쇄공정을 통한 진주조개 파쇄물을 무쇠솥에 장입하고 200∼300℃의 온도에서 5∼6시간 동안 가열한 후, 열원을 제거하고 상온에 될때까지 충분히 냉각시키는 초벌 연소공정과, 상기 초벌 연소공정을 마친 진주조개 연소물을 무쇠 원통에 장입하고, 약 600∼700℃의 온도에서 6∼7시간 가열한 후, 상온이 될때까지 충분히 냉각시키는 소성공정과, 상기 소성공정을 거친 진주조개 소성물을 160∼200목 정도의 고운 가루로 분쇄하는 분쇄공정과, 상기 분쇄공정을 통한 분쇄물을 분쇄물 1㎏당 증류수 4ℓ의 비율로 혼합하여 교반기에 장입하고 5∼6시간동안 교반하는 교반공정과, 상기 교반공정을 거친 결과물을 제1번통에 장입하고, 이동이 없는 상태에서 약 30시간동안 유지하면서 고형물을 침전시키는 1차 침전공정과, 상기 1차 침전공정을 거친 제1번통의 상등액을 제2번통에 장입하고, 이동이 없는 상태에서 약 24시간동안 유지하면서 고형물을 침전시키는 2차 침전공정과, 상기 2차 침전공정을 거친 제2번통의 상등액을 제3번통에 옮겨 진주액을 완성하는 진주액 공정과, 상기 진주액 공정을 통한 진주액 1ℓ당 구연산 6g, 사과산 2g, 호박산 2g을 첨가하여 교반시키며 화학반응시킨 후, 이산화탄소의 배출이 종료되면 교반을 중지하고 이동이 없는 상태에서 약 5∼6시간동안 유지하면서 고형물을 침전시킨 후 유체를 얻는 이온화 칼슘수 공정 및 상기 이온화 칼슘수 공정을 거친 이온화 칼슘수를 저온상태의 통풍이 잘되는 장소에서 보관하면서 수분을 증발시켜 이온화 칼슘을 얻는 이온화 칼슘 공정으로 이루어지며, 간단한 생산설비와 제조공정을 통하여 수율이 뛰어나고 품질이 우수한 제품을 만들 수 있도록 함으로써 생산비를 절감하여 효율을 극대화하는 효과와 다량으로 폐기되는 성형불가 진주와 진주조개껍질을 인체에 유효한 칼슘제로 제조할 수 있도록 함으로써 환경오염의 방지와 한정된 자원의 유효한 활용이란 효과를 얻을 수 있다.The present invention relates to a method for producing ionized calcium and ionized calcium water using a pearl clam, the present invention relates to a method for producing ionized calcium and ionized calcium water using a pearl shell, ionized calcium and ionized calcium using a pearl shell In the manufacturing method of water, an impurity removal step of removing impurities inside and outside the pearl clam, a drying step of drying the pearl clam, a shredding step of shredding the pearl clam to a size of about 3-9 cm in diameter, Put the pearl clam crushed product through the crushing process in a cast iron pot and heated for 5-6 hours at a temperature of 200 ~ 300 ℃, remove the heat source and cool sufficiently until it reaches room temperature, and the initial combustion process The finished pearl clam combusted product is charged into a cast iron cylinder, heated at a temperature of about 600 to 700 ° C. for 6 to 7 hours, and then cooled sufficiently until room temperature. The pulverization process, the pulverization process of grinding the pearl clam fired product through the said calcination process into fine powder of about 160-200 necks, and the pulverized material through the said crushing process are mixed in the ratio of 4 liter of distilled water per 1 kg of pulverized materials, and agitator. A stirring step of charging to the mixture and stirring for 5 to 6 hours, and charging the resultant through the stirring step into the first cylinder, and precipitating solids while maintaining for about 30 hours in the absence of movement; and Charge the supernatant of the first cylinder through the primary precipitation process into the second cylinder, and the secondary precipitation step of precipitating the solids while maintaining for about 24 hours without moving, and the second cylinder through the secondary precipitation step The supernatant of the solution was transferred to the third barrel to complete the pearl solution, and after the chemical reaction by stirring by adding 6 g of citric acid, 2 g of malic acid, and 2 g of succinic acid per 1 liter of the pearl solution through the pearl solution process, followed by chemical reaction. When the carbon discharge is completed, the stirring is stopped and the ionized calcium water process, which is obtained through the ionization calcium water process and the ionized calcium water process, which obtains a fluid after precipitating a solid while maintaining it for about 5 to 6 hours without moving, It consists of an ionized calcium process that obtains ionized calcium by evaporating water while storing it in a well-ventilated place, and by producing a product with high yield and high quality through a simple production facility and manufacturing process, it reduces production costs and maximizes efficiency. Effectiveness and non-molded pearls and pearl clam shells that are discarded in large quantities can be manufactured with calcium agents effective for the human body, thereby preventing environmental pollution and effectively utilizing limited resources.
Description
본 발명은 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수의 제조방법에 관한 것으로, 보다 상세하게는 일련된 생산공정을 통하여 수율이 높고 양질이며 인체 흡수가 양호한 진주조개를 이용한 산화칼슘과 산화칼슘수의 제조방법에 관한 것이다.The present invention relates to a method for producing ionized calcium and ionized calcium water using pearl shells, and more particularly, to the production of calcium oxide and calcium oxide water using pearl shells having high yield and good quality and good human absorption through a series of production processes. It relates to a manufacturing method.
진주는 예로부터 한방에서 널리 사용되어 왔으며, 중국에서는 2천년전부터 사용되어온 전통적인 약재이다. 또한 최고의 미용품, 최고의 자양건강보건약품으로 여러 문헌에 기재되어 있으며, 한국, 중국 및 일본의 역대 학자들은 진주분을 이용하여 인간의 질병을 치료하여 왔다. 본초강목(本草綱目)에 서술되어 있는 진주분의 약리적 효능을 살펴보면, 청열(淸熱), 진통작용, 혈중 지질 및 혈당 등을 감소시키는 작용을 하며, 간의 치료와 노쇠 현상을 막고, 피부의 각질을 제거하며, 피부의 죽은 세포를 재생시켜 준다고 한다. 또한 신농본초경(新農本草經)에 의하면, 얼굴에 바르면 기미, 주근깨가 없어지며, 피부가 윤택해지고,손발에 바르면 피부가 부드러워진다고 하였다.Pearl has been widely used in oriental medicine since ancient times, and is a traditional herb that has been used in China for 2,000 years. In addition, the best beauty products, the best nutritional health and health drugs are described in various literatures. Historical scholars in Korea, China and Japan have used pearl powder to treat human diseases. Looking at the pharmacological effects of pearl powder described in the herbaceous medicinal herb (本草綱目), it has the effect of reducing fever, analgesic, blood lipids and blood sugar, preventing liver and aging, and exfoliating skin. It is said to regenerate dead skin cells. In addition, according to Sinnonbyeonchobyeon (新 農 本草 經), when applied to the face, there is no blemish and freckles, the skin is moisturized, and when applied to the hands and feet, the skin is softened.
이러한 진주는 진주조개류 내부에서 생성되는 고형물질로서 비중이 2.238∼2.750, 경도는 4, 성분은 94%의 탄산칼슘과 6%의 유기물로 이루어져 있다. 이중 유기물의 대부분은 골격성 단백질(albuminoid)로 알려진 콘치올린(conchiolin)이 차지하고 있다. 상기 콘치올린은 단량체의 경우 분자량이687.14, 분자식이 C32H98N2O11인 물질로 진주내의 탄산칼슘을 서로 연결시켜 진주의 구조를 이루게 하는 자연결합물질이다.These pearls are solid materials produced inside the pearl shells, and the specific gravity is 2.238 ~ 2.750, the hardness is 4, and the components are 94% calcium carbonate and 6% organic matter. Most of these organisms are occupied by conchiolin, known as albuminoids. In the case of the monomer, the monomer has a molecular weight of 687.14 and a molecular formula of C 32 H 98 N 2 O 11 is a natural binding material that forms a structure of pearl by connecting calcium carbonate in the pearl to each other.
진주의 성분 가운데 약리작용을 나타내는 것은 크게 칼슘과 콘치올린으로 구분될 수 있다. 칼슘은 섭취할 경우 뼈를 강화하고 혈압을 저하시키며 항암작용까지 한다고 알려져 있다. 또한 얼굴이나 몸에 바를 경우는 화상의 치료제 또는 발모촉진제로도 사용이 가능하다. 콘치올린은 체내에 섭취될 경우 혈액 순환장애의 개선작용이 있으며 피부노화 방지작용도 탁월한 것으로 알려져 있다. 일본이나 중국에서는 고온에서 소결한 진주분말을 판매하고 있는데, 이 경우는 칼슘의 약리작용만이 효력을 발휘하여, 콘치올린 성분은 모두 파괴되어 이로 인한 약리작용의 도움을 기대할 수는 없다.Among the components of pearl, pharmacological action can be largely divided into calcium and conchiolin. Calcium is known to strengthen bones, lower blood pressure, and even fight cancer. In addition, if applied to the face or body can be used as a treatment for burns or hair growth promoting agent. Conchiolin is known to improve blood circulation disorders and to prevent skin aging when ingested in the body. In Japan and China, pearl powders sintered at high temperatures are sold. In this case, only the pharmacological action of calcium is effective, and all the conchiolin components are destroyed, so the pharmacological action cannot be expected.
진주의 성분인 탄산칼슘과 진주단백질은 물에 녹기 어려우며, 강산성 분위기인 위장에서 조차 매우 소량밖에 녹지 않기 때문에 체내에서 흡수되기가 어렵다. 즉, 진주에 포함된 칼슘이나 콘치올린은 그 상태로는 체내에 흡수되기 어려워 상술한 우수한 약리작용에도 불구하고 원하는 효과를 얻기가 곤란하다. 이러한 약리작용을 극대화하기 위해서 진주내의 유용한 성분을 수용성 형태로 변환시키는 연구가 요구되는 실정이다.Calcium carbonate and pearl proteins, which are the components of pearls, are difficult to dissolve in water and are difficult to be absorbed by the body because they are only dissolved in very small amounts even in the stomach, which is a strong acid atmosphere. In other words, calcium and conchiolin contained in pearls are difficult to be absorbed into the body in that state, and despite the excellent pharmacological action described above, it is difficult to obtain a desired effect. In order to maximize such pharmacological action, studies on converting useful components in pearls into water-soluble forms are required.
수용성 진주액은 진주내의 탄산칼슘과 산성물질이 반응하여 생성된 유기산 칼슘염과 가수분해된 수용성 콘치올린 단백질 등 일련의 처리과정으로 얻어지는 일종의 담황색의 액체이다. 이 액체의 유효성분은 수용성 칼슘염 및 콘치올린 단백질, 염기성 인산염 및 미량원소로서, 용도로서는 진주추출액을 함유한 화장수, 항염 및 피부보호작용이 있는 크림 및 연고, 콘치올린을 유효성분으로 하는 화장품, 산화방지제, 건강식품의 원료로 사용할 수 있다.Aqueous nacre fluid is a kind of pale yellow liquid obtained through a series of treatments, such as organic acid calcium salts produced by the reaction of calcium carbonate and acid in pearls and hydrolyzed soluble conchiolin proteins. The active ingredients of this liquid are water-soluble calcium salts and conchiolin proteins, basic phosphates and trace elements. For use, cosmetics containing cream extracts and ointments with anti-inflammatory and skin protection, cosmetics containing conchiolin as active ingredients, Can be used as a raw material for antioxidants and health foods.
이제까지의 패각류 등을 이용한 산화칼슘의 제조방법은 패각류를 분쇄하여 전기로에서 1500∼3000℃의 고온에서 1000∼3000V의 교류전압을 인가하여 패각분을 30∼120분 동안 전기분해하여 얻는 방법 등이 있었다. 또한 진주액의 제조방법은 불용성 단백질을 가수분해하는 방법에 따라 가열가압법, 산가수분해법, 효소법으로 구분되는데, 상기 가열가압법은 물에 침지된 진주가루에 여분의 물을 첨가하고 밀봉하여 온도 100∼130℃, 압력 50∼159Kpa, 반응시간 10∼30분으로 반응시켜 수용액에 녹아나오는 수용성 단백질을 탈색, 탈염하여 제조한다. 제조된 용액의 단위부피당 수율은 높으나, 생산되는 용액의 절대 부피가 작아 전체 생산성은 매우 낮다. 산가수분해법은 진주분말에 진한 염산 또는 황산을 이용하여 진주분말 내의 탄산염을 제거하고 세척한 후, 여과, 가수분해, 산의 제거, 탈색 및 탈염 등의 과정을 거쳐 진주액을 얻는다. 이 방법은 가수분해 조건이 매우 까다로와, 단백질의 변성이 심하고 반응 후에 잔류하는 산을 제거해야 한다는 번거로움이 있다.Conventional methods for producing calcium oxide using shells and the like are obtained by pulverizing shells and applying an alternating current of 1000 to 3000 V at a high temperature of 1500 to 3000 ° C. in an electric furnace to electrolyze shells for 30 to 120 minutes. There was this. In addition, the method of preparing a pearl liquid is classified into a heating press method, an acid hydrolysis method, and an enzyme method according to a method of hydrolyzing an insoluble protein. The heating press method is performed by adding extra water to a pearl powder immersed in water and sealing the temperature. It is prepared by decolorizing and desalting a water-soluble protein dissolved in an aqueous solution by reacting at 100 to 130 ° C, a pressure of 50 to 159 Kpa, and a reaction time of 10 to 30 minutes. The yield per unit volume of the prepared solution is high, but the overall productivity is very low due to the small absolute volume of the solution produced. Acid hydrolysis method removes the carbonate in the pearl powder using concentrated hydrochloric acid or sulfuric acid in the pearl powder and washes, and then obtains the pearl liquid through the process of filtration, hydrolysis, acid removal, bleaching and desalting. This method is very difficult to hydrolysis conditions, and the protein denaturation and the need to remove the acid remaining after the reaction is cumbersome.
효소법은 효소를 이용하는 가수분해법으로서, 강산으로 탄산칼슘을 제거한 후 잔류하는 불용성물질을 단백질분해효소로 가수분해하는 방법으로, 기존의 산에 의한 가수분해에 비해 반응조건이 온화하고 제조를 위한 시설이 간단하며 수율도 산가수분해법에 비해 동등이상의 우수한 방법이다.Enzyme method is a hydrolysis method using enzyme, which removes calcium carbonate with strong acid and then hydrolyzes the remaining insoluble substance with proteolytic enzyme. It is simple and the yield is superior to the acid hydrolysis method.
전술한 바와 같은 종래의 산화칼슘 제조방법이나 진주액의 제조방법은 적정수율 이상의 생산량을 얻기 위해서 제조설비에 대한 부담이나 제조과정의 번거로움을 수반하였으며, 생산되는 산화칼슘 또는 진주액의 품질이 열악한 단점이 있었다.As described above, the conventional method for preparing calcium oxide or the method for preparing pearl liquid has a burden on manufacturing facilities and the hassle of manufacturing process in order to obtain a yield higher than an appropriate yield, and the quality of the produced calcium oxide or pearl liquid is poor. There was a downside.
본 발명은 상기한 바와 같은 문제점을 해결하기 위하여 안출된 것으로, 본 발명의 목적은 간단한 생산설비와 제조공정을 통하여 수율이 뛰어나고 품질이 우수한 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수를 제조하는 방법을 제공하는데 있다.The present invention has been made to solve the above problems, an object of the present invention is to prepare a method for producing ionized calcium and ionized calcium water using a pearl shell excellent in yield and excellent quality through a simple production equipment and manufacturing process To provide.
도 1은 본 발명에 의한 이온화 칼슘과 이온화 칼슘수의 제조방법을 나타내는 흐름도,1 is a flowchart showing a method for producing ionized calcium and ionized calcium water according to the present invention;
도 2는 본 발명에 있어서의 소성공정에 적용되는 설비에 대한 단면도.2 is a cross-sectional view of equipment applied to the firing step in the present invention.
<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>
1...무쇠 원통, 2...진주조개 연소물,1 ... cast iron cylinder, 2 ...
3...화선지, 4...무쇠 뚜껑,3 ... drawing paper, 4 ... cast iron lid,
5...백상지, 6...철사줄,5 ... white paper, 6 ... wire,
7...진흙, 10...불순물 제거공정,7 ... mud, 10 ... impurities removal process,
20...건조공정, 30...파쇄공정,20 drying process, 30 crushing process,
40...초벌 연소공정, 50...소성공정,40 ... primary combustion process, 50 ... firing process,
60...분쇄공정, 70...교반공정,60 grinding process, 70 stirring process,
80...1차 침전공정, 90...2차 침전공정,80 ... 1st precipitation process, 90 ... 2nd precipitation process,
200...진주액 공정, 300...이온화 칼슘수 공정,200 ... pearl process, 300 ... ionized calcium water process,
400...이온화 칼슘 공정.400 ... Calcium ionization process.
상기한 바와 같은 목적을 달성하기 위하여 본 발명은 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수의 제조방법에 있어서, 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수의 제조방법에 있어서, 진주조개 내외부의 불순물을 제거하는 불순물 제거공정과, 상기 진주조개를 건조하는 건조공정과, 상기 진주조개를 직경 3∼9㎝ 정도의 크기로 파쇄하는 파쇄공정과, 상기 파쇄공정을 통한 진주조개 파쇄물을 무쇠솥에 장입하고 200∼300℃의 온도에서 5∼6시간 동안 가열한 후, 열원을 제거하고 상온에 될때까지 충분히 냉각시키는 초벌 연소공정과, 상기 초벌 연소공정을 마친 진주조개 연소물을 무쇠 원통에 장입하고, 약 600∼700℃의 온도에서 6∼7시간 가열한 후, 상온이 될때까지 충분히 냉각시키는 소성공정과, 상기 소성공정을 거친 진주조개 소성물을 160∼200목 정도의 고운 가루로 분쇄하는 분쇄공정과, 상기 분쇄공정을 통한 분쇄물을 분쇄물 1㎏당 증류수 4ℓ의 비율로 혼합하여 교반기에 장입하고 5∼6시간동안 교반하는 교반공정과, 상기 교반공정을 거친 결과물을제1번통에 장입하고, 이동이 없는 상태에서 약 30시간동안 유지하면서 고형물을 침전시키는 1차 침전공정과, 상기 1차 침전공정을 거친 제1번통의 상등액을 제2번통에 장입하고, 이동이 없는 상태에서 약 24시간동안 유지하면서 고형물을 침전시키는 2차 침전공정과, 상기 2차 침전공정을 거친 제2번통의 상등액을 제3번통에 옮겨 진주액을 완성하는 진주액 공정과, 상기 진주액 공정을 통한 진주액 1ℓ당 구연산 6g, 사과산 2g, 호박산 2g을 첨가하여 교반시키며 화학반응시킨 후, 이산화탄소의 배출이 종료되면 교반을 중지하고 이동이 없는 상태에서 약 5∼6시간동안 유지하면서 고형물을 침전시킨 후 유체를 얻는 이온화 칼슘수 공정 및 상기 이온화 칼슘수 공정을 거친 이온화 칼슘수를 저온상태의 통풍이 잘되는 장소에서 보관하면서 수분을 증발시켜 이온화 칼슘을 얻는 이온화 칼슘 공정으로 이루어지는 것을 특징으로 한다.In order to achieve the above object, the present invention provides a method for producing ionized calcium and ionized calcium water using pearl clam, and a method for producing ionized calcium and ionized calcium water using pearl clam, including impurities inside and outside the pearl clam. Loading impurities into the cast iron pot, removing the impurities, drying the pearl shells, grinding the pearl shells to a diameter of about 3 to 9 cm, and shredding pearl shells through the shredding process. After heating for 5 to 6 hours at a temperature of 200 to 300 ° C., a priming combustion step of removing the heat source and cooling it sufficiently to room temperature, and charging the shellfish combusted product having completed the priming combustion step to a cast iron cylinder, about 600 After heating for 6 to 7 hours at a temperature of ˜700 ° C., the firing step is sufficiently cooled until the temperature reaches room temperature, and the pearl-clad fired product passed through the firing step is A pulverizing step of pulverizing into fine powder of about 160 to 200 necks, a pulverizing step of mixing the pulverized product through the pulverizing process at a ratio of 4 L of distilled water per kg of pulverized material, charging it into a stirrer and stirring for 5 to 6 hours; Charge the resultant through the stirring step into the first cylinder, and the first precipitation step of precipitating the solids while maintaining for about 30 hours in the absence of movement, and the supernatant of the first cylinder through the first precipitation step The pearl which is charged into the barrel and maintained for 24 hours in a state of no movement, precipitates solids, and the supernatant of the second cylinder, which has undergone the secondary precipitation process, is transferred to the third cylinder to complete the pearl liquid. After the liquid process and the chemical reaction by adding 6g of citric acid, 2g of malic acid, 2g of succinic acid per 1 liter of the mother liquor through the mother liquor process, and after the discharge of carbon dioxide is finished, the stirring is stopped and there is no movement. The ionized calcium water process, which obtains a fluid after precipitating solids, while maintaining it for about 5 to 6 hours in a state, and the ionized calcium water that has undergone the ionized calcium water process is stored in a well-ventilated place at low temperature, and the water is evaporated to ionize calcium. It is characterized by consisting of an ionized calcium process to obtain.
이하, 본 발명의 바람직한 일실시예를 첨부된 도면을 참조하면서 보다 구체적으로 설명한다. 도 1은 본 발명에 의한 이온화 칼슘과 이온화 칼슘수의 제조방법을 나타내는 흐름도이다.Hereinafter, with reference to the accompanying drawings a preferred embodiment of the present invention will be described in more detail. 1 is a flowchart showing a method for producing ionized calcium and ionized calcium water according to the present invention.
본 발명에 따른 산화칼슘과 수용성 산화칼슘수의 제조방법에 사용되는 진주조개는 인근 해역에서 양식되는 바다 진주조개, 강에서 양식하는 민물 진주조개 또는 자연산 진주조개 등을 사용할 수 있지만, 경제적인 면을 고려하여 바다에서 양식되는 진주조개로 함이 바람직하며, 또한 일상적인 장신구나 보석으로 사용될 수 없을 정도의 형상적 불량을 가진 진주와 그 패각으로 하여도 무방하다.The pearl shell used in the method for producing calcium oxide and water-soluble calcium oxide water according to the present invention may be used for sea pearl shellfish cultured in nearby seas, freshwater pearl shellfish cultured in rivers, or natural pearl shellfish. It is preferable to use pearl shells that are cultured in the sea in consideration of consideration, and pearls and shells having a shape defect that cannot be used for everyday jewelry or jewelry.
우선 상기 진주와 진주조개껍질을 준비하여, 진주조개껍질의 내부에 남아있는 진주부착부위를 손질하여 제거한 다음, 수차례 수세(水洗)를 통하여 조개 내외부의 불순물을 제거한다(불순물 제거공정)(10). 상기 진주조개껍질의 내부에 남아있는 진주부착부위는 후술하는 산과의 반응시에 악영향을 미치므로 제거함이 바람직하다. 상기 불순물 제거공정을 통하여 패각과 진주를 제외한 여타의 불순물을 완전히 제거된다.First, the pearl and the pearl shell is prepared, and the pearl adhering parts remaining inside the pearl shell are trimmed and removed, and then impurities are removed from the inside and outside of the shell by washing with water several times (purity of impurities) (10). ). It is preferable to remove the pearl adhering portion remaining inside the pearl clam shell because it adversely affects the reaction with the acid described below. Through the impurity removal process, other impurities except shells and pearls are completely removed.
다음으로 상기 불순물 제거공정(10)을 통한 진주조개를 일광 또는 열풍으로 완전히 건조시킨다(건조공정)(20).Next, the pearl shell through the impurity removal process 10 is completely dried by daylight or hot air (drying process) 20.
상기 건조공정(20)을 통하여 수분이 제거된 진주조개를 자동파쇄기 등을 이용하여 직경 3∼9㎝ 정도의 크기로 파쇄한다(파쇄공정)(30).The pearly clam from which moisture is removed through the drying step 20 is crushed into a size of about 3 to 9 cm in diameter using an automatic crusher (crushing step) 30.
다음으로 상기 파쇄공정(30)을 통한 진주조개 파쇄물을 불순물이 혼입되지 아니하게 상부를 폐쇄한 무쇠솥에 장입한 후, 200∼300℃의 온도에서 5∼6시간 동안 가열한 후, 열원을 제거하고 상온에 될때까지 충분히 냉각시킨다(초벌 연소공정)(40). 상기 초벌 연소공정(40)을 통하여 진주조개 파쇄물은 회색의 성상을 갖는 연소물의 형태를 띠게 된다. 상기 초벌 연소공정(40)에서의 열원으로서는 불순물의 혼입방지와 균일한 가열조건을 위해서 전기로로 함이 바람직하나, 경제성 등을 고려하여 당해 온도를 낼 수 있는 열원은 어느 것이나 적용될 수 있다.Next, after charging the pearl clam crushed product through the crushing step 30 to the cast iron pot closed the upper portion so that impurities are not mixed, and heated at a temperature of 200 ~ 300 ℃ for 5-6 hours, then remove the heat source And cool sufficiently until it is at room temperature (primary combustion process) (40). Through the initial combustion process 40, the pearl clam crushed product takes the form of a combusted product having a gray color. As the heat source in the primary combustion process 40, it is preferable to use an electric furnace for preventing the incorporation of impurities and uniform heating conditions, but any heat source capable of producing the temperature in consideration of economical efficiency and the like may be applied.
초벌 연소공정(40)을 마친 진주조개 연소물은 소성공정(50)으로 이행된다.The pearl shell combusted product which has completed the initial combustion process 40 is transferred to the baking process 50.
도 2는 본 발명에 있어서의 소성공정에 적용되는 설비에 대한 단면도로서, 도면에서 도시하고 있는 바와 같이, 우선 두께 3∼4㎜, 높이 30㎝, 지름 10㎝인 무쇠 원통(1)에 상기 초벌 연소공정(50)을 마친 진주조개 연소물(2)을 2.5㎏ 장입한후, 무쇠 원통(1)의 개구상면을 화선지(3) 두 겹으로 폐쇄한 후, 두께 3∼4㎜, 지름 11㎝의 무쇠 뚜껑(4)을 상기 화선지(3) 위에 위치시키고, 그 상부에 지름 30㎝의 백상지(5) 두 겹을 위치시켜 상부를 폐쇄하고 나머지부분으로는 외주부를 포위하도록 한 후, 상기 무쇠 원통(1)의 상단 외주부를 1.15㎜ 두께의 철사줄(6)을 사용하여 결박시킨다. 상기 공정에 사용되는 화선지(3)와 백상지(5)는 두께가 얇을수록 바람직한 효과를 낸다.FIG. 2 is a cross-sectional view of equipment applied to the firing process of the present invention. As shown in the drawing, first, the cast iron cylinder 1 having a thickness of 3 to 4 mm, a height of 30 cm, and a diameter of 10 cm is applied to the cast iron cylinder 1. After charging 2.5 kg of pearl clam combusted products (2) having finished the combustion process (50), the upper surface of the cast iron cylinder (1) was closed with two layers of drawing paper (3), and the thickness was 3 to 4 mm and a diameter of 11 cm. The cast iron lid 4 is placed on the drawing paper 3, and two layers of white paper 5 having a diameter of 30 cm are placed on the upper portion thereof to close the upper portion and surround the outer circumferential portion with the remaining portion. The outer circumference of the top) is strapped using a 1.15 mm thick wire (6). The drawing paper 3 and the woodfree paper 5 used in the above process have a desirable effect as the thickness is thinner.
상기와 같은 소성공정(50)을 위한 준비작업을 마치면 무쇠 원통(1) 속에 장입된 진주조개 연소물(2)은 화선지(3), 무쇠 뚜껑(4) 및 백상지(5)에 의하여 밀폐되고, 철사줄(6)에 의하여 상기 밀폐가 고정되는 형태를 이루게 된다. 다음으로 상기 무쇠 원통(1)의 하면과 측면을 약 3∼4㎝의 진흙(7)으로 도포시킨다.Upon completion of the preparation for the firing process 50 as described above, the pearl shell combusted product 2 charged in the cast iron cylinder 1 is sealed by the drawing paper 3, the cast iron lid 4 and the woodfree paper 5, and the wire The seal 6 is fixed by the string 6. Next, the lower surface and the side surface of the cast iron cylinder 1 are coated with mud 7 of about 3 to 4 cm.
상기한 준비과정 후에 내화벽돌로 만들어진 화구 안에 상기 무쇠 원통이 직립된 상태로 장입하고, 충분히 건조된 석탄을 사용하여 약 600∼700℃의 온도에서 6∼7시간 가열한 후, 상온이 될때까지 충분히 냉각시킨다.After the preparation process, the cast iron cylinder is placed upright in a crater made of a refractory brick, heated at about 600 to 700 ° C. for 6 to 7 hours using sufficiently dried coal, and then sufficiently heated to room temperature. Cool.
상기한 바와 같은 소성공정(50)을 거치면 진주조개 연소물은 백색으로서 덩어리진 형태로 변형되며, 일부는 가루 형태로도 존재하는 진주조개 소성물이 된다. 또한 상기 소성물에는 약간의 불순물, 예컨대 진주조개 자체의 소성과정(50)을 통한 불순물, 상기 화선지나 백상지의 연소물 및 무쇠 원통으로부터 박리된 불순물 등이 존재하는데, 소성물에서 상기 불순물을 제거하면, 소성공정(50)의 장입 전에 2.5㎏의 진주조개 연소물이 소성공정을 통하여 약 1.5∼1.6㎏의 진주조개 소성물이 된다. 상기 진주조개 소성물은 진주조개껍질과 진주가 완전소결되어 얻어지는 것으로서, 산화칼슘과 진주조개껍질 유래의 미량 미네랄로 구성된다.After passing through the firing process 50 as described above, the pearl clam combusted product is transformed into a lumped form as white, and partly becomes a pearl clam fired product which is also present in powder form. In addition, there are some impurities in the fired product, for example, impurities through the firing process 50 of the pearl clam itself, impurities burned from the burned paper or woodfree paper, and impurities peeled from the cast iron cylinder. Prior to charging the firing step 50, 2.5 kg of pearl clam combusted product becomes about 1.5 to 1.6 kg of pearl clam fired product through the firing step. The pearl shell calcined product is obtained by completely sintering pearl shells and pearls, and is composed of trace minerals derived from calcium oxide and pearl shells.
상기 진주조개 소성물을 습기의 혼입이 적은 장소에서 분쇄기 등을 사용하여 160∼200목 정도의 고운 가루로 분쇄한다(분쇄공정)(60).The pearl clam fired product is pulverized into fine powder of about 160 to 200 throats using a grinder or the like in a place where moisture is not mixed (pulverization step) (60).
다음으로 상기 분쇄공정(60)을 통한 분쇄물 1.5㎏을 스테인레스 봉과 프로펠러를 구비하여 좌우로 회전토록 구성된 교반기에 장입한 후, 증류수 6ℓ를 부가하여(진주조개 1㎏당 증류수 4ℓ의 비율) 분당 150회의 속도로 좌우회전시키면서 5∼6시간동안 교반한다(교반공정)(70).Next, 1.5 kg of the pulverized product through the crushing process 60 was charged into a stirrer configured to rotate left and right with a stainless rod and a propeller, and then 6 liters of distilled water was added (a ratio of 4 liters of distilled water per 1 kg of pearl clam). It stirs for 5 to 6 hours, rotating left and right at the speed of a meeting (stirring process) (70).
다음으로 스테인레스 통 3개를 준비하여 각각에 1 내지 3의 번호를 붙인 후, 상기 교반공정(70)을 거친 결과물을 제1번통에 장입하고, 이동이 없는 상태에서 약 30시간동안 유지하면서 고형물을 침전시킨다(1차 침전공정)(80).Next, prepare three stainless steel barrels, numbering 1 to 3, and then charging the resultant through the stirring step 70 into the first barrel, and maintaining the solids for about 30 hours in the absence of movement. Precipitate (first precipitation) (80).
1차 침전공정(80)을 거친 제1번통의 상등액을 제2번통에 장입하고, 이동이 없는 상태에서 약 24시간동안 유지하면서 고형물을 침전시킨다(2차 침전공정)(90).The supernatant liquid of the first cylinder which passed through the primary precipitation process 80 is charged to the second cylinder, and solids are precipitated while maintaining for about 24 hours in the absence of movement (secondary precipitation process) (90).
상기 2차 침전공정(80)을 거친 제2번통의 상등액을 제3번통에 옮기면 고형물을 가지지 아니하는 희뿌연한 성상의 액체가 완성되는데(진주액 공정)(200), 소성물 2.5㎏, 증류수 6ℓ로 제조하는 경우 약 4ℓ의 진주액 최종 산물이 제조된다.Transfer the supernatant of the second cylinder through the secondary precipitation step 80 to the third cylinder to complete a rare, crystalline liquid that does not have a solid (pearl solution) (200), calcined product 2.5 kg, distilled water 6 l When prepared with about 4 L of the mother liquor final product is prepared.
다음으로 이온화 칼슘수 공정(300)을 시행하는데, 상기 진주액 최종 산물 1ℓ당 구연산 6g, 사과산 2g, 호박산 2g을 천천히 첨가하면서 교반한다. 이때 반응온도는 실온, 예컨대 15∼30℃ 정도가 바람직하다. 상기한 바와 같은 산의 첨가에 따라 진주액에서는 화학반응이 일어나며, 이산화탄소를 배출하게 되고, 이산화탄소의 배출이 종료될 때를 반응이 종료되는 시점으로 하여 그때까지 교반을 유지시킨다. 그리고 화학반응이 종료되면 교반을 중지하고 이동이 없는 상태에서 약 5∼6시간동안 유지하면서 고형물을 침전시킨 다음, 상등액을 체취하는데, 상기 상등액은 이온화된 산화칼슘염을 포함하는 투명한 성상의 액체(이온화 칼슘수)이다.Next, the ionized calcium water process 300 is performed, and 6 g of citric acid, 2 g of malic acid, and 2 g of succinic acid are slowly added while stirring per liter of the final product of the mother liquor. At this time, the reaction temperature is preferably room temperature, for example, about 15 to 30 ° C. With the addition of the acid as described above, a chemical reaction takes place in the nacre solution, and carbon dioxide is discharged, and the stirring is maintained until the reaction is terminated when the discharge of carbon dioxide is completed. When the chemical reaction is completed, the stirring is stopped and the solids are precipitated while maintaining about 5 to 6 hours in a state where there is no movement, and the supernatant is sieved. The supernatant is a transparent liquid containing ionized calcium oxide salt ( Ionized calcium water).
상기 이온화 칼슘수 공정(300)에 사용되는 구연산(枸祁酸, 시트르산, citric acid)은 히드록시기를 가지는 다염기(多鹽基) 카르복실산의 하나로서, 화학식이 C6H8O7이며, 가열하면 가열하면 무수물(無水物)이 되고 물이나 에탄올에 잘 녹는다. 또한 칼슘이온을 포착(捕捉)하는 성질을 가지고 있다. 사과산(沙果酸, 말산, malic acid)은 화학식이 C4H6O6이며, 무색의 침상결정(針狀結晶)으로 조해성을 가지며, 물이나 에탄올에 잘 녹는다. 또한 호박산(琥珀酸, 숙신산, succinic acid)은 사슬 모양인 디카르복시산의 일종으로, 끓는점에서 1분자의 물을 잃고 무수물이 된다.Citric acid (枸 祁 酸, citric acid, citric acid) used in the ionized calcium water process 300 is one of the polybasic carboxylic acid having a hydroxyl group, the formula is C 6 H 8 O 7 , When heated, it becomes anhydride and dissolves well in water or ethanol. It also has the property of trapping calcium ions. Malic acid (malic acid, malic acid) is a chemical formula of C 4 H 6 O 6 , a colorless needle crystal (침) is deliquescent, and soluble in water or ethanol. In addition, succinic acid (琥珀酸, succinic acid) is a kind of dicarboxylic acid in the form of a chain, it loses one molecule of water at boiling point and becomes anhydride.
마지막으로 상기 이온화 칼슘수 공정(300)의 산물인 이온화 칼슘수를 저온상태의 통풍이 잘되는 장소에서 보관하면서 수분을 증발시시키면 소량의 분말이 얻어지는데, 이것이 이온화 칼슘이다(이온화 칼슘 공정)(400).Finally, a small amount of powder is obtained by evaporating the water while storing the ionized calcium water, which is the product of the ionized calcium water process 300, in a well-ventilated place at low temperature, which is calcium ionized (calcium ionized process) (400 ).
상기한 구성을 갖는 본 발명에 의한 진주조개를 이용한 이온화 칼슘과 이온화 칼슘수의 작용과 효과를 설명한다.The action and effect of ionized calcium and ionized calcium water using the pearl shell according to the present invention having the above-described configuration will be described.
칼슘은 뼈나 치아 등을 형성하는 필수 영양소의 하나일 뿐만 아니라 가장 중요한 생명과 직결된 작용을 하는 심장이나 뇌를 움직이는 정보전달기능이란 중요한 기능을 한다. 따라서 칼슘이 부족하면 골다공증을 위시하여 체내에 여러 가지 이상을 일으키며, 약 60조에 달하는 인체의 세포는 작용을 할 수 없어 사멸하게 된다. 혈액 중의 칼슘량은 항상 일정하게 유지되는데, 이는 세포가 정상적으로 기능을 수행함에 있어서 중요한 조건이다. 혈액 중의 칼슘농도를 1만이라 가정하면, 세포 중에 겨우 1만 분의 1의 칼슘만 있어야 한다. 즉, 세포의 안과 밖(혈액 중)에서 1대 1만이란 칼슘의 농도차가 유지됨으로서 세포는 밖에서 정보를 받기도 , 발신할 수도 있게 된다. 그런데 칼슘이 부족하면 1대 1만의 농도차의 균형이 깨지게 된다.Calcium is not only one of the essential nutrients that form bones and teeth, but also plays an important role in the information transmission function that moves the heart and brain, which are directly linked to the most important life. Therefore, the lack of calcium, including osteoporosis, causing various abnormalities in the body, about 60 trillion cells of the human body can not function and die. The amount of calcium in the blood is always kept constant, which is an important condition for the cells to function normally. Assuming that the calcium concentration in the blood is 10,000, there should only be about 10,000 calcium in the cell. In other words, the concentration difference between one to one million calcium is maintained inside and outside the cell (in the blood), so that the cell can receive and send information from the outside. However, if calcium is insufficient, the balance of concentration difference between one and one million will be broken.
따라서 매일 칼슘을 필요량 섭취하지 않으면, 체내의 칼슘이 부족되어 혈액 중의 칼슘농도가 저하되며 칼슘의 정보에 의해 심장은 정지된다. 이를 방지하기 위해서 부갑상선(副甲狀腺)에 있는 칼슘센서가 정보를 포착하여 부갑상선 호르몬 (parathyroid hormone)을 분비하여 뼈에서 칼슘을 용출시켜 혈액 중의 부족분을 보충한다.Therefore, if you do not consume the required amount of calcium every day, the calcium in the body is insufficient, the calcium concentration in the blood is lowered, and the heart is stopped by the information of calcium. To prevent this, the calcium sensor in the parathyroid gland captures information and secretes parathyroid hormones to elute calcium from bones to compensate for deficiencies in the blood.
한편, 부갑성선 호르몬은 신체의 각 세포 내에 여분의 칼슘이 들어가게 하는 작용을 한다. 통상은 세포막에 칼슘통로가 있어서 여분의 칼슘이 들어가더라도 칼슘펌프에 의하여 세포 밖으로 압출되는데, 칼슘 부족이 계속되면, 계속되는 만큼 부갑성선 호르몬이 분비되고 엄격한 검사기능을 돌파하여 세포 내에 칼슘을 억지로 밀어 넣는다. 즉, 칼슘 부족이 역으로 세포 내의 칼슘을 증가시켜 "칼슘 파라독스"현상을 일으킨다.Parathyroid hormone, on the other hand, acts to get extra calcium into each cell of the body. Normally, even if extra calcium enters the cell membrane, the cell membrane is extruded out of the cell by a calcium pump. When calcium deficiency continues, parathyroid hormone is secreted as much as it goes on, and it breaks through the strict test function to force calcium into the cell. . In other words, calcium deficiency reversely increases the intracellular calcium, causing "calcium paradox".
뇌는 약 140억개의 신경세포의 집합체로서 이것이 글리아 세포에 둘러싸여 돌기나 신경섬유로 서로 연결되어 복잡한 작용을 하고 있다. 그러나 칼슘 파라독스가 일어나면 정보에 혼란이 일어나 세포의 형이 붕괴되고 기능을 멈추게 되며, 세포는 죽게 된다. 뇌 세포는 한번 죽으면 재생되지 않으므로, 칼숨 부족은 알츠하이머병을 유발하는 원인이 되기도 한다. 이 밖에 생활습관병인 고혈압, 동맥경화, 당뇨병, 골다공증 등도 모두 칼슘의 부족이 원인이라 할 것이다.The brain is a collection of about 14 billion neurons, which are surrounded by glia cells and are connected to each other by protrusions or nerve fibers to perform complex functions. But when calcium paradox occurs, information is disrupted, causing cell types to collapse, to stop functioning, and cells to die. Brain cells do not regenerate once they die, so lack of Calsum can also cause Alzheimer's disease. In addition, lifestyle-related diseases such as hypertension, arteriosclerosis, diabetes, and osteoporosis will all be attributed to the lack of calcium.
그러나 인체에 칼슘을 공급하는 경우에 있어서, 이온화되지 않은 칼슘을 공급하는 경우에는 칼슘이 인체에 잘 흡수되지 않음으로 인하여 효과도 적을 뿐만 아니라 소화 장애나 결석 등을 유발할 수 있다.However, in the case of supplying calcium to the human body, in case of supplying calcium that is not ionized, calcium is not absorbed well by the human body, which is less effective and may cause digestive disorders or stones.
본 발명에 의한 이온화 칼슘과 이온화 칼슘수는 인체 흡수가 용이한 이온화 칼슘과 미량 미네랄을 다량을 함유하고 있으며, 인체의 칼슘 부족으로 인한 질병을 미연에 방지할 수 있도록 한다.The ionized calcium and ionized calcium water according to the present invention contains a large amount of ionized calcium and trace minerals that are easily absorbed by the human body, and can prevent diseases due to calcium deficiency of the human body in advance.
본 발명에 의한 이온화 칼슘의 흡수성은 콜로이드성 탄산칼슘, 제2인산칼슘, 피트산칼슘, 수산칼슘 및 본 발명에 의한 이온화 칼슘 등의 각종 칼슘염의 흡수율이 각각 89, 56, 50, 11 및 100인것을 통해 보건대, 매우 우수함을 알 수 있다.The water absorption of the ionized calcium according to the present invention is that the absorption rate of various calcium salts such as colloidal calcium carbonate, dicalcium phosphate, calcium pitate, calcium hydroxide and calcium ionized according to the present invention is 89, 56, 50, 11 and 100, respectively. According to them, it is very excellent.
본 발명에 의한 이온화 칼슘은 칼슘과 미량 미네랄을 다량으로 함유할 뿐만 아니라 용해성이 대단히 높기 때문에 식품에의 칼슘 강화나 영양 보급과 함께 식품의 품질개량 목적으로 여러 가지 식품에 사용될 수 있다.Since the ionized calcium according to the present invention not only contains a large amount of calcium and trace minerals but also has a very high solubility, it can be used in various foods for the purpose of quality improvement of foods with calcium fortification or nutritional supplementation.
즉, 가공육제품, 수산연제품 등에서는 탄력성 향상을 위하여, 면류에서는 경화용으로, 빵이나 과자류에서는 풍미향상을, 그리고 유지류의 산화방지 등 보존성 향상의 목적으로도 사용될 수 있으며, 식육의 결착이나 곤약, 두부의 응고제로서 뿐만 아니라 각종 분말 제품의 뭉치는 현상을 방지하는데도 사용될 수 있다.In other words, it can be used to improve elasticity in processed meat products and seafood products, and for curing in noodles, improve flavor in breads and confectionery, and improve preservation such as preventing oxidation of fats and oils. It can be used not only as a coagulant of tofu but also to prevent agglomeration of various powder products.
또한 직접 섭취함으로써 일반적인 칼슘보급용으로 사용될 수 있음은 물론, 음료에의 응용등이 가능하다.In addition, by directly ingesting can be used for general calcium supply, as well as application to beverages is possible.
본 발명은 다량으로 폐기되는 성형불가 진주와 진주조개껍질을 인체에 유효한 칼슘제로 제조할 수 있도록 함으로써 환경오염의 방지와 한정된 자원의 유효한 활용이란 효과를 거둘 수 있다.The present invention can achieve the effect of the prevention of environmental pollution and the effective utilization of limited resources by enabling the production of non-molded pearls and pearl shells discarded in a large amount with a calcium agent effective for the human body.
또한 인체 흡수가 용이한 이온화 칼슘과 이온화 칼슘수의 제조에 있어서, 간단한 생산설비와 제조공정을 통하여 수율이 뛰어나고 품질이 우수한 제품을 만들 수 있도록 함으로써 생산비를 절감하여 효율을 극대화하는 효과를 얻을 수 있다.In addition, in the production of ionized calcium and ionized calcium water, which can be easily absorbed by the human body, it is possible to produce a product having excellent yield and high quality through a simple production facility and manufacturing process, thereby reducing the production cost and maximizing efficiency. .
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KR20020026914A (en) * | 2002-02-28 | 2002-04-12 | 백정광 | A furnace of manufacture of ionic ca with a shell |
KR102268307B1 (en) * | 2020-07-10 | 2021-06-23 | 주식회사 와우에스티 | Drinking water containging minerals extracted from pearls and method for manufacuring the same |
KR20230126906A (en) | 2022-02-24 | 2023-08-31 | 주식회사 마이크로젠 | Manufacturing Method for Soluble Ionized Organic Calcium Using Shell and Reaction Tank Thereof |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01199912A (en) * | 1988-02-04 | 1989-08-11 | Masatoshi Kato | Substance useful as medicine |
KR950023589A (en) * | 1994-01-27 | 1995-08-18 | 김상범 | Calcium ion production method using shells |
KR970058715A (en) * | 1996-01-17 | 1997-08-12 | 양지원 | Methods for the preparation of water-soluble pearlescent liquids using physical, chemical and biochemical methods |
KR100269031B1 (en) * | 1998-05-14 | 2000-10-16 | 김석훈 | Method for preparing lime milk using waste matter of shell |
KR20020031241A (en) * | 2000-10-23 | 2002-05-01 | 유종구 | Manufacturing method of alkaline calcium for class of shell |
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---|---|---|---|---|
JPH01199912A (en) * | 1988-02-04 | 1989-08-11 | Masatoshi Kato | Substance useful as medicine |
KR950023589A (en) * | 1994-01-27 | 1995-08-18 | 김상범 | Calcium ion production method using shells |
KR970058715A (en) * | 1996-01-17 | 1997-08-12 | 양지원 | Methods for the preparation of water-soluble pearlescent liquids using physical, chemical and biochemical methods |
KR100269031B1 (en) * | 1998-05-14 | 2000-10-16 | 김석훈 | Method for preparing lime milk using waste matter of shell |
KR20020031241A (en) * | 2000-10-23 | 2002-05-01 | 유종구 | Manufacturing method of alkaline calcium for class of shell |
Cited By (3)
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---|---|---|---|---|
KR20020026914A (en) * | 2002-02-28 | 2002-04-12 | 백정광 | A furnace of manufacture of ionic ca with a shell |
KR102268307B1 (en) * | 2020-07-10 | 2021-06-23 | 주식회사 와우에스티 | Drinking water containging minerals extracted from pearls and method for manufacuring the same |
KR20230126906A (en) | 2022-02-24 | 2023-08-31 | 주식회사 마이크로젠 | Manufacturing Method for Soluble Ionized Organic Calcium Using Shell and Reaction Tank Thereof |
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