KR100300514B1 - Slip Casting Ceramic Honeycomb Manufacturing Equipment - Google Patents
Slip Casting Ceramic Honeycomb Manufacturing Equipment Download PDFInfo
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- KR100300514B1 KR100300514B1 KR1019980031639A KR19980031639A KR100300514B1 KR 100300514 B1 KR100300514 B1 KR 100300514B1 KR 1019980031639 A KR1019980031639 A KR 1019980031639A KR 19980031639 A KR19980031639 A KR 19980031639A KR 100300514 B1 KR100300514 B1 KR 100300514B1
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- mold
- lower plate
- flanges
- honeycomb carrier
- rod
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/26—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
- B28B1/261—Moulds therefor
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16N—LUBRICATING
- F16N11/00—Arrangements for supplying grease from a stationary reservoir or the equivalent in or on the machine or member to be lubricated; Grease cups
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/26—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
- B28B1/268—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor by dipping moulding surfaces in the slip
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/0002—Auxiliary parts or elements of the mould
- B28B7/0014—Fastening means for mould parts, e.g. for attaching mould walls on mould tables; Mould clamps
- B28B7/002—Fastening means for mould parts, e.g. for attaching mould walls on mould tables; Mould clamps using magnets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/0029—Moulds or moulding surfaces not covered by B28B7/0058 - B28B7/36 and B28B7/40 - B28B7/465, e.g. moulds assembled from several parts
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/0006—Honeycomb structures
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2825—Ceramics
- F01N3/2828—Ceramic multi-channel monoliths, e.g. honeycombs
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16N—LUBRICATING
- F16N19/00—Lubricant containers for use in lubricators or lubrication systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16N—LUBRICATING
- F16N39/00—Arrangements for conditioning of lubricants in the lubricating system
- F16N39/002—Arrangements for conditioning of lubricants in the lubricating system by deaeration
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16N—LUBRICATING
- F16N7/00—Arrangements for supplying oil or unspecified lubricant from a stationary reservoir or the equivalent in or on the machine or member to be lubricated
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Toxicology (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
본 발명은 가솔린·디젤·LPG·LNG와 같은 화석연료를 사용하는 자동차·쓰레기 소각로·화력발전소·디젤기관차·선박·각종 보일러 및 난방용 난로 등의 배기가스에 포함된 NOx·SOx·CO·미반응 탄화수소(HC) 등 유해 물질들을 분해 정화시키는 촉매 하니컴 담체를 제조하는 장치에 관한 것이다.The present invention relates to NO x , SO x , CO, etc. contained in exhaust gases such as automobiles, garbage incinerators, thermal power plants, diesel locomotives, ships, various boilers and heating stoves using fossil fuels such as gasoline, diesel, LPG, and LNG. The present invention relates to a device for producing a catalytic honeycomb carrier for decomposing and purifying hazardous substances such as unreacted hydrocarbons (HC).
현재까지의 하니컴 담체는 압축 성형용 금형을 진공 압출기에 부착시켜 제작하고 있으나 압출 성형할 때 금형으로부터 소지가 부드럽게 빠져나와 원하는 형상을 유지하도록 하는 방법은 첨가제의 종류와 그 양에 의존하도록 되어 있어서 금형제작비와 진공압출기의 가격이 매우 비쌀 뿐 아니라 소지가 딱딱할 경우 금형으로 부터 압출이 잘 이루어지지 않아 금형의 구멍이 막히거나 압출 펌프의 부하 과다로 고열 및 불량이 발생되며, 소지가 너무 부드러우면 압출 후 원하는 형상을 유지하지 못하고 하니컴 담체는 붕괴되므로 진공 압출식 하니컴 담체 제작은 소지 제조의 어려움이 따르고 그에 따른 불량율이 비교적 높은 편이다.Until now, honeycomb carriers are manufactured by attaching a compression molding die to a vacuum extruder, but the method of smoothly releasing the substrate from the mold to maintain the desired shape during extrusion molding depends on the type and amount of the additive. The production cost and the price of the vacuum extruder are very expensive, and if the body is hard, the extrusion is not done well from the mold, so the hole of the mold is clogged or high heat and defects occur due to the excessive load of the extrusion pump. Since the honeycomb carrier is not maintained after the desired shape is collapsed, the vacuum extrusion honeycomb carrier production is difficult to produce the base material, and the defect rate is relatively high.
따라서, 본 발명에서는 석고로 만든 주형에 하니컴 담체 제조용 소지액(소지수용액)을 부어넣어 하니컴 담체를 주조하는 슬립 캐스팅(slip-casting) 하니컴 담체 제조장치를 발명하는 것을 목적으로 하며, 성형실(6)을 갖는 석고주형(10)의 개구부(2)(4)에 플렌지(18)(20)가 빙둘러 형성된 상부판(22)과 하부판(24)을 각각 설치하고, 상·하부판(22)(24)의 플렌지(18)(20) 부분에 수직 지지간(26)을 등 간격으로 설치하여 상부판(22)을 분리할 수 있도록 하고, 상부판(22)과 하부판(24)의 상·하부에 돌출부(27)(29)와 요입부(30)(32)를 각각 형성하고, 석고주형(10)과 플렌지(18)(20) 사이에 패킹(34)(36)을 설치하고, 요입부(30)의 상부에 깔대기 형상의 호퍼(38)를 설치하고, 요입부(30)의 가장자리 부분에 성형실(6)과 연결되는 주입공(40)과 배기관(44)을 복수 개 설치하거나 형성하고, 돌출부(27)에 조밀한 간격으로 삽입공(52)을 형성한 다음 철금속을 인발 가공하여 길이가 긴 성형봉(54)의 상단부를 평방 인치당 약 100-500셀(100-500ce11s/inch2)의 조밀한 간격을 갖도록 끼워 고정함으로서 성형봉(54)과 성형봉(54) 사이에 하나로 연결되는 좁은 간격의 공간부(56)를 형성하고, 하부판(24)에는 삽입공(58)을 형성하여 주조를 전·후하여 성형봉(54)의 하단부가 삽입 및 분리되도록 하고, 또한 하부판(24)의 요입부(32)에 영구자석이나 전자석(64)을 매입 설치하여 주조할 때 성형봉(54)의 하단부가 자력에 의해 고정되게 함으로서 그 간격들이 유지되도록 한 것이다.Accordingly, an object of the present invention is to invent a slip-casting honeycomb carrier manufacturing apparatus for casting a honeycomb carrier by pouring a holding liquid (holding solution) for manufacturing a honeycomb carrier into a mold made of gypsum. The upper plate 22 and the lower plate 24 in which the flanges 18 and 20 are formed in the openings 2 and 4 of the plaster mold 10 having the upper and lower plates 22 are respectively provided, and the upper and lower plates 22 ( Vertical support bars 26 are provided at equal intervals in the flanges 18 and 20 of the 24 to separate the upper plate 22, and the upper and lower portions of the upper plate 22 and the lower plate 24 are separated. Protrusions 27, 29 and recesses 30, 32 are formed in the recesses, and packings 34, 36 are provided between the plaster mold 10 and the flanges 18, 20, and the recesses A funnel-shaped hopper 38 is installed on the upper portion of the 30, and a plurality of injection holes 40 and exhaust pipes 44 connected to the molding chamber 6 are formed or formed at the edge portion of the concave inlet portion 30. And extrude 27, and then the iron metal drawing process to about 100 to 500 cells per inch square forming the upper end of the long rod (54) length (100-500ce11s / inch 2) formed in the insertion hole 52 in a dense spacing of the By inserting and fixing to have a tight gap, a spaced portion 56 is formed between the forming rod 54 and the forming rod 54 to be narrowly spaced, and an insertion hole 58 is formed in the lower plate 24 to form the casting. When the lower end of the forming rod (54) is inserted and separated by the front and rear, and the permanent rod or electromagnet (64) is embedded in the recess 32 of the lower plate (24), the forming rod (54) is cast. By allowing the lower end of the to be fixed by the magnetic force to maintain the gaps.
Description
따라서, 본 발명은 가솔린·디젤· LPG·LNG 와 같은 화석연료를 사용하는 자동차·쓰레기 소각로·화력발전소·디젤기관차·선박 각종 보일러 및 난방용 난로등의 배기가스에 포함된 NOx,SOx, CO·미반응 탄화수소(HC) 등 유해 물질들을 분해 정화시키는 촉매 하니컴 담체를 제조하는 장치에 관한 것이다.Accordingly, the present invention provides NO x , SO x , CO contained in exhaust gases such as automobiles, garbage incinerators, thermal power plants, diesel locomotives, various boilers and heating stoves using fossil fuels such as gasoline, diesel, LPG, and LNG. A device for producing a catalytic honeycomb carrier for decomposing and purifying hazardous substances such as unreacted hydrocarbons (HC).
현재까지의 하니컴 담체는 압축 성형용 금형 진공 압출기에 부착시켜 제작하고 있으나 압출 성형할 때 금형으로부터 소지가 부드럽게 빠져나와 원하는 형상을 유지하도록 하는 방법은 첨가제의 종류와 그 양에 의존하도록 되어 있어서 금형 제작비와 진공압출기의 가격이 매우 비싸 생산성이 떨어지는 편이다.Until now, honeycomb carriers have been manufactured by attaching them to a mold vacuum extruder for compression molding. However, the method of making the body smoothly escape from the mold to maintain the desired shape during extrusion molding depends on the type and amount of additives. And the cost of the vacuum extruder is very expensive, the productivity is low.
이때 소지가 딱딱할 경우 금형으로부터 압출이 잘 이루어지지 않아 금형의 구멍이 막히거나 압출펌프의 부하 증가로 고열 및 불량이 발생된다.At this time, if the body is hard, extrusion is not performed well from the mold, so the hole of the mold is clogged or high load and defect are caused by an increase in load of the extrusion pump.
또한, 소지가 너무 부드러우면 압출 후 원하는 형상을 유지하지 못하고 하니컴 담체는 붕괴되고 만다.Also, if the body is too soft, the honeycomb carrier may collapse while not retaining the desired shape after extrusion.
이와 같은 진공 압출식 하니컴 담체 제작은 소지 제조의 어려움이 따르고 그에 따른 불량율이 비교적 높은 편이다.The manufacture of such a vacuum extruded honeycomb carrier is difficult to produce the base material, the defect rate is relatively high.
본 발명에서는 석고로 만든 주형에 하니컴 담체 제조용 소지액(소지 수용액)을 부어넣어 하니컴 담체를 주조하는 슬립 캐스팅(slip-casting) 하니컴 담체 제조 장치를 발명함에 목적이 있다.An object of the present invention is to invent a slip-casting honeycomb carrier manufacturing apparatus for casting a honeycomb carrier by pouring a holding solution (aqueous solution of honeycomb) for producing a honeycomb carrier into a mold made of gypsum.
지금부터 이와 같은 방법으로 제조된 하니컴은 앞서 언급한 진공 압출식 하니컴과 구별되게 슬립 캐스팅 하니컴으로 부르기로 한다.The honeycomb manufactured in this way from now on will be referred to as slip casting honeycomb to be distinguished from the aforementioned vacuum extruded honeycomb.
슬립 캐스팅 하니컴 제작은 진공 압출 하니컴 제작보다 하니컴 담체 소지제조가 비교적 쉽고 불량율이 적을 뿐 아니라 다양한 형상의 세라믹 하니컴 담체를 비교적 저렴한 가격으로 만들 수 있는 장점을 가지고 있다.Slip-casting honeycomb fabrication has the advantage that it is relatively easy to manufacture a honeycomb carrier and produces a lower defect rate than a vacuum extrusion honeycomb fabrication, and that ceramic honeycomb carriers of various shapes can be made at a relatively low price.
자동차 및 공장 배기가스 정화처리에는 백금(Pt), 팔라듐(Pd)과 로듐(Rh) 같은 귀금속 촉매가 사용되고 있으나, 이와 같은 귀금속 촉매는 단가가 높고 가격이 비싸기 때문에 대체 촉매 개발이 활발히 진행되고 있다.Precious metal catalysts such as platinum (Pt), palladium (Pd) and rhodium (Rh) are used for the exhaust gas purification treatment of automobiles and factories, but alternative catalysts are actively being developed due to the high cost and high price of these precious metal catalysts.
특히, 퍼로브스카이트(perovskit) 촉매는 열 안정성이 뛰어나고 산화활성이 우수하여 완전연소 반응에서 귀금속 촉매에 필적하는 성능을 나타내면서도 가격이 저렴하기 때문에 많은 연구가 수행되고 있다.In particular, many studies have been carried out because perovskit catalysts have excellent thermal stability and excellent oxidation activity, which are comparable to noble metal catalysts in a complete combustion reaction, and are inexpensive.
순수 촉매의 제조보다는 산업화에 적용이 편리한 감마-알루미나 (T-A1203), 바륨-알루미나(Ba-A1203) 및 코디어라이트(cordierite)로 만든 하니컴 담체에 퍼로브스카이트(Perovskite, ABO3)를 담지시킨 담지 촉매 제조에 관심이 집중되고 있다.Perovskite is used in honeycomb carriers made of gamma-alumina (T-A1 2 0 3 ), barium-alumina (Ba-A1 2 0 3 ), and cordierite, which are more convenient for industrialization than the preparation of pure catalysts. Attention is focused on the production of supported catalysts supported on Perovskite, ABO 3 ).
따라서, 본 발명에서는 앞서 언급한 감마-알루미나(T-A1203)와 코디어라이트(cordierite, 2MgO·2A1205·5Si02)로 담체 하니컴을 만드는 장치 제작에 초점을 두기로 한다.Therefore, the present invention focuses on the production of a device for making a carrier honeycomb from the aforementioned gamma-alumina (T-A1203) and cordierite (cordierite, 2MgO · 2A1 2 0 5 · 5Si0 2 ).
상기목적을 달성하기 위하여 성형실을 갖는 석고주형의 개구부에 플렌지가 빙둘러 형성된 상부판과 하부판을 각각 형성하고, 상·하부판의 플렌지 부분에 수직 지지간을 등 간격으로 설치하여 상부판을 분리할 수 있도록 하고, 상부판과 하부판의 상·하부에 돌출부와 요입부를 각각 형성하고, 석고주형과 플렌지 사이에 패킹을 설치하고, 요입부의 상부에 깔대기 형상의 호퍼를 설치하고, 요입부의 가장자리 부분에 성형실과 연결되는 주입공과 배기관을 복수 개 설치하거나 형성하고, 돌출부에 조밀한 간격으로 삽입공을 형성한 다음 철금속을 인발 가공하여 길이가 긴 성형봉의 상단부를 평방 인치당 약 100-500셀(100-500CellS/inCh2)의 조밀한 간격을 갖도록 삽입 고정하여 성형봉과 성형봉 사이에 하나로 연결되는 좁은 간격의 공간부가 형성되도록 하고, 하부판에 삽입공을 형성하여 성형봉의 하단부가 주조를 전·후하여 삽입 및 분리되게 하고, 하부판의 요입부에 영구자석이나 전자석을 매입 설치하여 주조할 때 철금속으로 된 성형봉(54)의 하단부가 자력에 의해 그 간격들이 유지되게 한 것으로, 이하 본 발명의 바람직한 실시 예를 첨부한 도면에 따라 상세히 설명하면 다음과 같다.In order to achieve the above object, the upper plate and the lower plate each having a flange formed in the opening of the gypsum mold having the molding chamber are respectively formed, and the upper plate can be separated by equally spaced vertical supports between the flange portions of the upper and lower plates. The protrusions and the recesses are formed at the upper and lower portions of the upper plate and the lower plate, and a packing is installed between the gypsum mold and the flange, and a funnel-shaped hopper is installed at the upper portion of the recess. Install or form a plurality of injection holes and exhaust pipes connected to the seal, and form insertion holes at tight intervals on the protrusions, and then draw the ferrous metal to process the upper end of the long forming rod at about 100-500 cells per square inch (100-500CellS). / inCh 2 ) to have a tight gap between the forming rod and the forming rod to form a narrow spaced part connected to one, Insertion holes are formed in the lower plate so that the lower end of the forming rod can be inserted and separated by casting before and after casting, and the lower end of the forming rod 54 made of ferrous metal when the permanent magnet or electromagnet is inserted into the recess of the lower plate and cast. The intervals are maintained by the magnetic force, which will be described below in detail with reference to the accompanying drawings a preferred embodiment of the present invention.
제1도는 본 발명의 단면 구성도.1 is a cross-sectional configuration of the present invention.
제2도는 본 발명의 평면도.2 is a plan view of the present invention.
제3도는 본 발명의 상부판 평면도.3 is a top plan view of the present invention.
제4도는 본 발명 제2도의 부분 확대도.4 is a partially enlarged view of FIG. 2 of the present invention.
제5도는 본 발명의 상부판 부분 단면도.5 is a partial cross-sectional view of the top plate of the present invention.
제6도는 본 발명의 하부판 부분 단면도.6 is a partial cross-sectional view of the bottom plate of the present invention.
제7도는 본 발명 하부판 부분의 다른 실시 예 단면도.7 is a cross-sectional view of another embodiment of the lower plate portion of the present invention.
제8도는 본 발명 하부판의 또 다른 실시 예 단면도.8 is a cross-sectional view of another embodiment of the present invention lower plate.
제9도는 본 발명의 탈형 상태 정면도.9 is a front view of the demold state of the present invention.
제10도는 본 발명의 사용 상태 평면도.10 is a plan view of a state of use of the present invention.
* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
1 : 세라믹하니컴 제조장치 2,4 : 개구부1: Ceramic honeycomb manufacturing apparatus 2, 4: Opening
6 : 성형실 10 : 석고주형6: molding room 10: plaster mold
12 : 하니컴담체 제조용 소지액 14 : 세라믹하니컴12: holding liquid for manufacturing honeycomb carrier 14: ceramic honeycomb
16 : 용접부 18,20 : 플렌지16: welded part 18, 20: flange
22,24 : 상·하부판 26 : 지지간22,24: upper and lower plates 26: support interval
28 : 구멍 30,32 : 요입부28: hole 30,32: recessed part
34,36 : 패킹 40 : 주입공34,36 Packing 40 Injection hole
42 : 배기공 44 : 배기관42: exhaust hole 44: exhaust pipe
46 : 걸림턱 48 : 금속테46: hanging jaw 48: metal frame
50 : 걸고리 52 : 삽입공50: hook 52: insertion hole
54 : 성형봉 56 : 공간부54: forming rod 56: space part
58 : 삽입공 60 : 패킹58: insertion hole 60: packing
62 : 삽입홈 64,66 : 영구자석 또는 전자석62: insertion groove 64,66: permanent magnet or electromagnet
SW : 스위치 I : 전자석 구동전원SW: Switch I: Electromagnetic Driving Power
제1도는 본 발명 세라믹 하니컴 제조장치(1)의 단면 구성도로, 석고를 이용하여 상·하부에 개구부(2)(4)가 형성되고 내부에 성형실(6)이 형성되는 주형(10)을 만들어 하니컴 담체 제조용 소지액(소지 수용액)(12)을 부어넣어 슬립 캐스팅(slip-casting) 방법으로 하니컴 담체를 주조할 수 있도록 한다.1 is a cross-sectional configuration diagram of the ceramic honeycomb manufacturing apparatus 1 according to the present invention. The mold 10 having the openings 2 and 4 formed in the upper and lower parts thereof using a gypsum and the molding chamber 6 formed therein is shown in FIG. The honeycomb carrier is prepared by pouring a solution (holding solution) 12 for manufacturing a honeycomb carrier to be cast in a honeycomb carrier by a slip-casting method.
상기 석고주형(10)은 세라믹 소지 수용액(12)을 부어 넣게되면 모세관 현상에 의해 소지 수용액(12) 중의 수분을 흡수한 다음 석고주형(10)의 바깥으로 내뿜게 되며, 석고주형(10)의 형상은 성형하고자 하는 세라믹 하니컴(14)의 형상에 따라 원통형·정사각형·직사각형·타원형 또는 다각형 등으로 각각 형성할 수 있으며, 석고주형(10)의 상·하부에 형성된 개구부(2)(4)에는 플렌지(18)(20)가 빙둘러 형성된 상부판(22)과 하부판(24)을 각각 형성하고, 상·하부판(22)(24)의 플렌지(18)(20) 부분에는 제2도와 같이 상·하부판(22)(24)을 잡아주는 3개 내지 6개의 지지간(26)을 등 간격으로 설치하여 세라믹 하니컴(14)이 성형되는 동안 석고주형(10)이 견고히 고정되게 한다.When the gypsum mold 10 is poured into the ceramic holding solution 12, the gypsum mold 10 absorbs the moisture in the holding solution 12 by capillary action and then blows out of the gypsum mold 10. The shape may be formed into a cylindrical, square, rectangular, oval or polygonal shape according to the shape of the ceramic honeycomb 14 to be molded, and the openings 2 and 4 formed in the upper and lower portions of the plaster mold 10 may be formed. The upper plates 22 and the lower plates 24 each having the flanges 18 and 20 formed around each other are formed, and the flanges 18 and 20 portions of the upper and lower plates 22 and 24 are formed as shown in FIG. The three to six support sections 26 holding the lower plates 22 and 24 are provided at equal intervals so that the plaster mold 10 is firmly fixed while the ceramic honeycomb 14 is being molded.
상기에서 하부 플렌지(20)에 결합하는 지지간(26)의 하부는 나사식으로 체결하거나 용접하는 등의 방법으로 고정시키고, 상부 플렌지(18)에 결합하는 지지간(26)의 상부는 상부 플렌지(22)에 등 간격으로 형성되는 구멍(28)에 분리할 수 있는 정도로 결합하여 세라믹 하니컴(14)의 성형이 완료되면 제10도와 같이 석고주형(10)과 상부판(22)과 하부판(24)을 분리하여 성형된 세라믹 하니컴(14)을 탈형 시킬 수 있도록 한다.In the above, the lower portion of the support rod 26 coupled to the lower flange 20 is fixed by a screw fastening or welding method, and the upper portion of the support rod 26 coupled to the upper flange 18 is the upper flange. Gypsum mold 10, upper plate 22 and lower plate 24 as shown in FIG. ) So that the molded ceramic honeycomb 14 can be demolded.
상부판(22)과 하부판(24)에는 성형실(6)을 향하여 돌출되는 돌출부(27)(29)와, 돌출부(27)(29) 이면에 요입부(30)(32)를 각각 형성하여 석고주형(10)의 상·하부를 마구리하도록 하고, 석고주형(10)과 플렌지(18)(20) 사이에는 내열성 및 내화학성을 갖는 고무 패킹(34)(36)을 각각 설치하여 석고주형(10)과 플렌지(18)(20)사이에 수밀이 유지되도록 한다.In the upper plate 22 and the lower plate 24, protrusions 27 and 29 protruding toward the molding chamber 6, and recesses 30 and 32 are formed on the rear surfaces of the protrusions 27 and 29, respectively. The upper and lower parts of the gypsum mold 10 are to be rubbed, and rubber packing 34 and 36 having heat resistance and chemical resistance are respectively installed between the gypsum mold 10 and the flanges 18 and 20. 10) and watertightness is maintained between the flanges (18) and (20).
요입부(30) 상부에는 깔대기 형상의 호퍼(38)를 일체형으로 설치하고, 상기 요입부(30)의 가장자리 부분에는 제3도와 같이 성형실(6)과 연결되는 호 형상의 소지액 주입공(40)을 복수 개 형성하여 성형실(6)로 소지액(12)을 주입할 수 있도록 하고, 주입공(40)과 주입공(40) 사이에는 배기공(42)이 형성된 배기관(44)을 복수개 설치하여 성형실(6)로 소지액(12)을 주입할 때 성형실(6) 내에 잔류하는 공기가 상기 배기공(42)을 통하여 석고주형(10)의 바깥으로 배출되도록 한다.The funnel-shaped hopper 38 is integrally installed on the concave inlet portion 30, and an arc-shaped holding liquid injection hole connected to the shaping chamber 6 is formed at the edge of the concave inlet portion 30 as shown in FIG. A plurality of 40 are formed so that the holding liquid 12 can be injected into the molding chamber 6, and an exhaust pipe 44 having an exhaust hole 42 is formed between the injection hole 40 and the injection hole 40. When the holding liquid 12 is injected into the molding chamber 6 by installing a plurality, air remaining in the molding chamber 6 is discharged to the outside of the plaster mold 10 through the exhaust hole 42.
상기에서 소지액 주입공(40)은 제3도와 같이 길이를 길게 형성하여 많은 양의 소지액(12)이 성형실(6)로 주입되게 하여 생산성을 향상시키고, 배기관(44)은 호퍼(38)보다 더욱 상승시켜 소지액(6)이 배기공(42)으로 흘러 들어가지 않도록 함으로써 배기공(42) 막힘에 의한 배기 불량을 방지하도록 한다.The holding solution injection hole 40 is formed to have a long length as shown in FIG. 3 so that a large amount of the holding solution 12 is injected into the molding chamber 6 to improve productivity, and the exhaust pipe 44 is a hopper 38. Rather than rising so that the holding liquid 6 does not flow into the exhaust hole 42, it is possible to prevent the exhaust failure due to clogging of the exhaust hole 42.
석고주형(10)의 상부 외면에는 바깥으로 돌출되는 걸림턱(46)을 빙둘러 형성하고, 걸림턱(46)의 외면에는 "니은자" 형상으로 절곡된 금속테(48)를 빙둘러 가면서 덮어씌워 세라믹 하러컴(14)을 석고주형(10)으로부터 탈형 시킬 때 탈형도구를 상기 금속테(48)의 외면에 걸어 성형된 세라믹 하니컴(14)을 쉽게 탈형 시킬 수 있도록 한다.On the upper outer surface of the gypsum mold 10, a hanging jaw 46 is formed to protrude outwardly, and the outer surface of the hanging jaw 46 is covered with a rounded metal frame 48 bent in a "needle" shape. When demolding the ceramic haracom 14 from the gypsum mold 10, the demolding tool is attached to the outer surface of the metal frame 48 so that the molded ceramic honeycomb 14 can be easily demolded.
또한, 상부판(22)의 플렌지(18) 부분에제3도개 내지 4개의 걸고리(50)를 고른 간격으로 배열 고정시켜 탈형도구나 호이스트를 이용하여 상부판(22)을 수직으로 곧바로 들어올릴 수 있게 함으로서 탈형시 석고주형(10)이나 세라믹 하니컴(14)의 파손이나 손상을 방지하도록 한다.In addition, by arranging and fixing the third to four hooks 50 at even intervals on the flange 18 of the upper plate 22, the upper plate 22 can be lifted straight vertically using a release tool or a hoist. By doing so to prevent breakage or damage of the plaster mold 10 or the ceramic honeycomb 14 during demolding.
한편, 상부판(22)의 돌출부(27)에는 레이저 가공 등의 방법으로 제5도와 같이 평방 인치당 약 100-500셀(100-500ce11/inch2)의 조밀한 간격으로 삽입공(52)을 형성한 다음 철금속으로 인발 가공하여 길이가 긴 성형봉(54)의 상단부를 끼워 상부판(22)위로 돌출시킨 다음 용접(56)이나 납점 등의 방법으로 상부판(22)에 고정시켜 제2도와 같이 성형붕(54) 끼리 일정한 간격이 유지되도록 한다.On the other hand, in the protrusions 27 of the upper plate 22, the insertion hole 52 is formed at a tight interval of about 100-500 cells (100-500ce11 / inch 2 ) per square inch as shown in FIG. Then, drawn out of ferrous metal, the upper end of the long forming rod 54 is inserted to protrude onto the upper plate 22, and then fixed to the upper plate 22 by a welding method 56 or a soldering point. As such, the mold shelf 54 is maintained at a constant interval.
따라서, 제4도의 확대도와 같이 성형봉(54)과 성형봉(54) 사이에 하나로 연결되는 좁은 간격의 공간부(56)가 형성되며, 상기 공간부(56)로 소지액(12)을 침투시켜 세라믹 하니컴(14)을 성형할 수 있게된다Therefore, as shown in the enlarged view of FIG. 4, a space portion 56 having a narrow gap is formed between the forming rod 54 and the forming rod 54, and the holding liquid 12 penetrates into the space 56. To form the ceramic honeycomb 14
상기에서 성형봉(54)의 길이는 석고주형(10)의 높이와 거의 같은 길이로 구성하여 성형실(6)을 차지하도록 하고, 성형봉(54)의 단면 형상은 정사각형으로 도시하였으나 물론 육각형이나 마름모형·직사각형·원형·타원형·다각형 등으로 형성할 수 있으며, 성형봉(54)이 결합되는 삽입공(52) 역시 상기 성형봉(54)과 같은 육각형이나 마름모형·직사각형·원형·타원형 ·다각형 등의 형상으로 형성하면 될 것이다.In the above, the length of the forming rod 54 is configured to have a length substantially equal to the height of the plaster mold 10 to occupy the molding chamber 6, the cross-sectional shape of the forming rod 54 is shown as a square, but of course the hexagon It can be formed into a rhombus, a rectangle, a circle, an ellipse, a polygon, and the like, and the insertion hole 52 to which the forming rod 54 is coupled also has the same hexagonal shape as that of the forming rod 54, a rhombus, a rectangle, a circle, an ellipse, It may be formed in a shape such as a polygon.
또한, 제6도와 같이 하부판(24)의 돌출부(29)에도 성형봉(54)의 하단부가 삽입되는 삽입공(58)을 형성하여 세라믹 하니컴을 주조할 때 각각의 성형봉(54) 하단부가 상기 삽입공(58)에 끼워져 그 유동이 방지되게 함으로서 소지액(12)의 불균형적인 가압력이나 외압이 작용되더라도 성형봉(54)과 성형봉(54) 끼리의 간격이 평행을 유지하도록 하고, 탈형시에는 성형봉(54)이 상기 삽입공(58)으로부터 쉽게 분리되게 함으로서 고품질의 세라믹 하니컴(14)을 제작할 수 있도록 한다.In addition, as shown in FIG. 6, the lower end of each forming rod 54 is formed when the ceramic honeycomb is cast by forming an insertion hole 58 into the protrusion 29 of the lower plate 24, into which the lower end of the forming rod 54 is inserted. Inserted into the insertion hole 58 to prevent the flow, so that even if the imbalanced pressing force or the external pressure of the holding liquid 12 is applied, the spacing between the forming rod 54 and the forming rod 54 is parallel, and when demolding The molding rod 54 can be easily separated from the insertion hole 58 to produce a high-quality ceramic honeycomb (14).
상기의 삽입공(58)은 성형봉(54)이 삽입 및 분리될 수 있는 정도의 크기로 형성하고, 돌출부(29)를 관통하도록 함으로써 소지액(12)이 삽입공(58)으로 침투하더라도 세라믹 하니컴(14)을 탈형한 후 간편히 세척할 수 있도록 함이 바람직하다.The insertion hole 58 is formed to a size such that the forming rod 54 can be inserted and separated, and penetrates the protrusion 29 so that even if the holding liquid 12 penetrates into the insertion hole 58, It is preferable that the honeycomb 14 can be easily washed after demolding.
또한, 제1도와 같이 하부판(24)의 요입부(32)에 밀폐용 패킹(60)을 억지 끼움식으로 매입 설치하여 세라믹 하니컴(14)이 소성되는 동안 소지액(12)의 불필요한 유출을 방지할 수 있으며, 세라믹 하니컴(14)을 탈형시킨 다음 상기 패킹(60)을 요입부(32)로부터 분리시킨 다음 삽입공(58) 및 요입부(32)와 패킹(60) 사이로 침투한 소지액을 간편히 세척한 후 제조장치를 조립하여 세라믹 하니컴(14)을 새로 제조할 수 있도록 한다.In addition, as shown in FIG. 1, an airtight packing 60 is installed in the recess 32 of the lower plate 24 to prevent unnecessary leakage of the holding liquid 12 while the ceramic honeycomb 14 is fired. After demolding the ceramic honeycomb 14, the packing 60 is separated from the indentation 32, and then the holding liquid penetrated between the insertion hole 58 and the indentation 32 and the packing 60 is removed. After simple washing, the manufacturing apparatus is assembled to enable the ceramic honeycomb 14 to be newly manufactured.
제7도는 본 발명 하부판(24)에 형성되는 삽입공(58)의 다른 실시 예 단면도로, 제6도와 같이 돌출부(29)를 관통하도록 구성할 수도 있으나 제7도와 같이 관통하지 않는 삽입홈(62)을 형성하여 성형봉(54)의 하단부를 끼워 고정할 수도 있으며, 이러한 경우 세라믹 하니컴(14)이 소성되는 동안 소지액(12)의 불필요한 유출을 방지할 수 있을 것이다.7 is a cross-sectional view of another embodiment of the insertion hole 58 formed in the lower plate 24 of the present invention, but may be configured to penetrate the protrusion 29 as shown in FIG. It may also be fixed by inserting the lower end of the forming rod 54, in this case, it will be possible to prevent unnecessary leakage of the holding liquid 12 during the ceramic honeycomb 14 is fired.
한편, 성형봉(54)의 하단부가 삽입되는 삽입공(58)(62)은 평방 인치당 약 100∼500셀의 매우 조밀한 간격으로 가공 및 설치되므로 가공이 어렵고 설치간격의 정밀성이 요구되어 원가가 상승될 뿐 아니라 수백 수천 개의 성형봉(54)를 삽입공(58)과 삽입홈(62)에 일일이 또는 한꺼번에 삽입하기 힘든 형편이므로, 제8도와 같이 하부판(24)의 요입부(32)에 삽입공(58)(62) 대신 히토류계 또는 코발트계의 영구자석이나 전자석(64)을 매입 설치하여 철금속으로 된 성형봉(54)의 하단부가 자력(磁力)에 의해 일정한 간격으로 됩게 고정되도록 한다.On the other hand, the insertion holes 58 and 62 into which the lower end of the forming rod 54 is inserted are processed and installed at very close intervals of about 100 to 500 cells per square inch, which makes machining difficult and requires precision of installation intervals. As well as being raised, since it is difficult to insert hundreds or thousands of forming rods 54 into the insertion hole 58 and the insertion groove 62 one by one or all at once, it is inserted into the recess 32 of the lower plate 24 as shown in FIG. Instead of the balls (58) and (62), a permanent magnet or an electromagnet (64) of a magnetite type or a cobalt type is purchased and installed so that the lower ends of the forming rods 54 made of ferrous metal are fixed at regular intervals by magnetic force. do.
상기에서 하부판(24)은 자성체 금속 이를테면, 니켈이나 니켈과 철을 합금한 금속으로 사용하면 하부판(24)이 자력화되므로 철금속으로 된 성형봉(54)이 더욱 강하게 흡착되므로 더욱 견고히 고정되므로 고품질의 세라믹 하니컴을 제작할 수 있게 된다.When the lower plate 24 is a magnetic metal, for example, nickel or a metal alloyed with nickel and iron, the lower plate 24 is magnetized, so that the forming rods 54 made of ferrous metal are more strongly adsorbed and thus more firmly fixed. Ceramic honeycomb can be produced.
상기에서 전자석(64)으로 구성하는 경우 스위치(SW)와 구동전원(I)이 전자석(64)과 직렬로 접속되며, 탈형할 때 스위치(SW)를 오프(OFF)시키면 전자석(64)의 자력과 성형봉(54) 흡자력이 곧바로 제7되므로 쉽게 탈형할 수 있게 된다.In the case of the electromagnet 64, the switch SW and the driving power supply I are connected in series with the electromagnet 64. When the switch SW is turned off when demolding, the magnetic force of the electromagnet 64 is reduced. And the forming rod 54 can be easily demolded because the absorption force is immediately seventh.
제9도는 본 발명 일 실시 예로 도시한 평면도로, 스위치(SW)와 구동전원(I)이 직렬로 접속되고 평면적이 비교적 널은 평판형의 전자석(66)위에 복수 개의 세라믹 하니컴(1)을 얹어 설치한 다음 세라믹 하니컴(12)을 제작할 수 있음을 도시하고 있으며, 한 개의 전자석(66)을 이용하여 각각의 세라믹 하니컴 제조장치(1)에 설치된 성형봉(54)의 하단부를 자력으로 동시에 고정시킬 수 있는 효과가 있다.FIG. 9 is a plan view showing an embodiment of the present invention, in which a plurality of ceramic honeycombs 1 are placed on a flat electromagnet 66 in which a switch SW and a driving power source I are connected in series and whose planes are relatively large. After installation, it is shown that the ceramic honeycomb 12 can be manufactured, and by using one electromagnet 66, the lower ends of the forming rods 54 installed in each ceramic honeycomb manufacturing apparatus 1 can be simultaneously fixed by magnetic force. It can be effective.
이상에서와 같이 본 발명은 석고로 만든 주형에 하니컴 담체 제조용 소지액(소지 수용액)을 부어넣어 하니컴 담체를 주조하는 슬립 캐스팅(slip-casting) 하니컴 담체 제조장치를 이용하여 종래 진공 압출 하니컴 제작보다 하니컴 담체 소지 제조가 비교적 쉽고 불량율이 적을 뿐 아니라 다양한 형상의 세라믹 하니컴 담체를 비교적 저렴한 가격으로 만들 수 잇는 효자가 있다.As described above, the present invention uses a slip-casting honeycomb carrier manufacturing apparatus for casting a honeycomb carrier by pouring a holding solution (aqueous solution of honeycomb carrier) into a mold made of gypsum. Carrier carrying is relatively easy and has a low defect rate, and there are effects for making ceramic honeycomb carriers of various shapes at a relatively low price.
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