KR100272270B1 - Method for forming metal interconnection layer in semiconductor device - Google Patents
Method for forming metal interconnection layer in semiconductor device Download PDFInfo
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- KR100272270B1 KR100272270B1 KR1019970030368A KR19970030368A KR100272270B1 KR 100272270 B1 KR100272270 B1 KR 100272270B1 KR 1019970030368 A KR1019970030368 A KR 1019970030368A KR 19970030368 A KR19970030368 A KR 19970030368A KR 100272270 B1 KR100272270 B1 KR 100272270B1
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- contact hole
- mask pattern
- layer
- ion implantation
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 29
- 239000002184 metal Substances 0.000 title claims abstract description 29
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000004065 semiconductor Substances 0.000 title claims abstract description 12
- 239000010410 layer Substances 0.000 claims abstract description 44
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 20
- 238000005468 ion implantation Methods 0.000 claims abstract description 15
- 239000011229 interlayer Substances 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 6
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- 238000005530 etching Methods 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- 229910052745 lead Inorganic materials 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 abstract description 6
- 230000003746 surface roughness Effects 0.000 abstract description 4
- 239000004411 aluminium Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000151 deposition Methods 0.000 description 5
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 2
- 238000007517 polishing process Methods 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- TUTOKIOKAWTABR-UHFFFAOYSA-N dimethylalumane Chemical compound C[AlH]C TUTOKIOKAWTABR-UHFFFAOYSA-N 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000000206 photolithography Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76877—Filling of holes, grooves or trenches, e.g. vias, with conductive material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31144—Etching the insulating layers by chemical or physical means using masks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/3115—Doping the insulating layers
- H01L21/31155—Doping the insulating layers by ion implantation
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76802—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing by forming openings in dielectrics
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76801—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the dielectrics, e.g. smoothing
- H01L21/76822—Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc.
- H01L21/76825—Modification of the material of dielectric layers, e.g. grading, after-treatment to improve the stability of the layers, to increase their density etc. by exposing the layer to particle radiation, e.g. ion implantation, irradiation with UV light or electrons etc.
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Abstract
Description
본 발명은 반도체 소자의 금속 배선 형성 방법에 관한 것으로, 보다 구체적으로는, 상층배선과 하층 배선을 연결하는 콘택 금속막의 형성방법에 관한 것이다.BACKGROUND OF THE
반도체 소자가 미세화되고 고집적화됨에 따라, 폴리실리콘의 게이트 전극이나 소오스 및 드레인 확산 영역을 금속 배선과 접촉시켜 주기 위한 콘택홀의 폭이 점점 작아 지고, 또한 확산 영역의 PN 접합의 깊이도 점점 얇아지게 됨으로써, 배선의 접촉저항이 증대되며, 다층의 금속 배선 공정이 요구된다.As semiconductor devices become finer and more highly integrated, the width of the contact hole for contacting the gate electrode or the source and drain diffusion regions of polysilicon with the metal wiring becomes smaller and the depth of the PN junction of the diffusion regions becomes thinner. Contact resistance of the wiring is increased, and a multilayer metal wiring process is required.
여기서, 종래의 상층 배선(접합 영역)과 하층 배선을 연결하기 위한 콘택 방법은, 하층 배선이 형성된 기판상에 절연막을 증착하고, 하층 배선의 소정 부분이 노출되도록 절연막을 식각하여, 콘택홀을 형성한다. 종래의 콘택홀은 현재의 고집적 추세에 부응하여 매우 미세한 사이즈로 형성되어, 콘택홀 내부를 매립하기 위한 매립 금속층이 소정의 방식으로 형성된다. 그후, 이 매립된 금속충과 접촉되도록 상부 배선이 형성된다.Here, in the conventional contact method for connecting the upper layer wiring (junction region) and the lower layer wiring, an insulating film is deposited on the substrate on which the lower layer wiring is formed, and the insulating film is etched so that a predetermined portion of the lower layer wiring is exposed to form a contact hole. do. Conventional contact holes are formed in a very fine size in response to the current high integration trend, so that a buried metal layer for filling the inside of the contact holes is formed in a predetermined manner. Thereafter, the upper wiring is formed to be in contact with the buried metal worm.
이때, 매립 금속층을 형성하는 방법으로는, 매립 특성이 우수한 화학기상 증착 방식의 텅스텐 플러그, 고온 스퍼터링 방식에 의한 알루미늄 증착법 또는 화학 기상 증착 방식에 의한 알루미늄 증착법이 있다.At this time, the method of forming the buried metal layer includes a tungsten plug of a chemical vapor deposition method having excellent buried characteristics, an aluminum deposition method by a high temperature sputtering method or an aluminum deposition method by a chemical vapor deposition method.
그러나, 상술한 매립 금속층 형성방법은 다음과 같은 문제점을 지닌다.However, the above-described buried metal layer forming method has the following problems.
먼저, 텅스텐 플러그 방법은, 매립 특성은 우수한 반면, 텅스텐의 자체 저항이 크므로, 배선 저항이 증가되고, 금속 신뢰성이 저하되는 문제점이 있다.First, the tungsten plug method has a problem in that the buried property is excellent, while the tungsten self resistance is large, so that the wiring resistance is increased and the metal reliability is lowered.
또한, 상기 고온 스퍼터링 방식에 의한 알루미늄 증착법은 전도성은 우수하나, 매립 특성이 좋지않아, 재현성이 저하되는 문제점이 발생된다.In addition, the aluminum deposition method by the high temperature sputtering method is excellent in conductivity, but the buried property is not good, there is a problem that the reproducibility is lowered.
또한, 화학 기상 증착 방식에 의한 알루미늄 증착법은, 증착후 표면이 거칠게 증착되어, 추가적으로 화학적 기계적 연마 공정을 진행하여야 하는 번거러움 또한 상존하였다.In addition, the aluminum vapor deposition method by the chemical vapor deposition method also has a rough surface after the deposition, the cumbersome to further proceed with the chemical mechanical polishing process also existed.
따라서, 본 발명은, 하층 배선 또는 접합 영역과 상층 배선을 연결하는 콘택 금속을 전도 특성 및 매립 특성을 동시에 만족할 수 있도록하여 금속 신뢰성을 향상시킬 수 있는 반도체 소자의 금속 배선 형성방법을 제공하는 것을 목적으로 한다.Accordingly, an object of the present invention is to provide a method for forming a metal wiring of a semiconductor device which can improve the metal reliability by making the contact metal connecting the lower wiring or the junction region and the upper wiring at the same time satisfying the conductive and buried characteristics. It is done.
또한, 본 발명의 다른 목적은 추가적인 연마 공정없이 표면이 평탄한 금속 배선 형성방법을 제공하는 것이다.Another object of the present invention is to provide a method for forming metal wiring with a flat surface without an additional polishing process.
제1(a)도 내지 제1(c)도는 본 발명에 따른 반도체 소자의 금속 배선 형성방법을 설명하기 위한 공정 단면도.1 (a) to 1 (c) are cross-sectional views for explaining a method for forming a metal wiring of a semiconductor device according to the present invention.
* 도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
1 : 반도체 기판 2 : 하층 배선1: semiconductor substrate 2: lower layer wiring
3 : 층간 절연막 4 : 콘택용 마스크 패턴3: interlayer insulation film 4: mask pattern for contact
5 : 알루미늄막 100 : 콘택홀5: aluminum film 100: contact hole
200-1,200-2 : 이온 주입층200-1,200-2: ion implantation layer
상기한 본 발명의 목적을 달성하기 위하여, 본 발명은 전도 영역을 구비한 반도체 기판상에 층간 절연막을 형성하는 단계; 상기 층간 절연막 상부에 소정 부분이 노출되도록 마스크 패턴을 형성하는 단계; 상기 마스크 패턴의 형태로 전도 영역의 소정 부분이 노출되도록 층간 절연막을 식각하여, 콘택홀을 형성하는 단계; 상기 마스크 패턴 상부 및 상기 콘택홀내의 노출된 전도영역으로 불순물을 이온주입하여 이온주입층을 형성하는 단계; 상기 마스크 패턴을 제거하여 그의 상부에 형성된 이온주입층도 함께 제거하는 단계; 상기 콘택홀내의 이온주입층을 매개로 상기 콘택홀내에만 알루미늄으로된 매립 금속막을 형성하는 단계를 포함하는 반도체 소자의 금속 배선 형성방법을 제공하는 것을 특징으로 한다.In order to achieve the above object of the present invention, the present invention comprises the steps of forming an interlayer insulating film on a semiconductor substrate having a conductive region; Forming a mask pattern on the interlayer insulating layer to expose a predetermined portion; Etching the interlayer insulating film to expose a predetermined portion of the conductive region in the form of the mask pattern to form a contact hole; Forming an ion implantation layer by implanting impurities into the exposed conductive region in the upper portion of the mask pattern and the contact hole; Removing the mask pattern to remove the ion implantation layer formed thereon; And forming a buried metal film made of aluminum only in the contact hole through the ion implantation layer in the contact hole.
본 발명에 의하면, 콘택홀 매립 금속층 형성단계 이전에, 콘택홀 저면에 시드층을 형성한 후, 알루미늄 금속막을 매립하므로서, 콘택홀 내의 매립 특성을 향상시키게 되고, 표면 거칠음 현상이 방지된다.According to the present invention, before the contact hole filling metal layer forming step, the seed layer is formed on the bottom of the contact hole and then the aluminum metal film is embedded, thereby improving the embedding characteristics in the contact hole and preventing surface roughness.
아울러, 전도 특성이 우수한 알루미늄 금속막을 매립 금속막으로 이용하여, 금속 배선이 전도 특성이 개선된다.In addition, by using an aluminum metal film having excellent conductivity as a buried metal film, the metal wiring has improved conductivity.
[실시예]EXAMPLE
이하 첨부한 도면에 의거하여 본 발명의 바람직한 실시예를 자세히 설명하도록 한다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings.
첨부한 도면 제1(a)도 내지 제1(c)도는 본 발명에 따른 반도체 소자의 금속 배선 형성방법을 설명하기 위한 공정 단면도이다.1 (a) to 1 (c) are sectional views for explaining a method for forming metal wirings of a semiconductor device according to the present invention.
먼저, 제1(a)도에 도시된 바와 같이, 하층 배선(2)을 포함하는 반도체 기판(1) 상부에 층간 절연막(3)이 공지의 증착 방식에 의하여 형성된다. 여기서, 상기 하층 배선은 트랜지스터의 접합 영역이 될 수 있으며, 또는 접합 영역과 연결되는 제1금속 배선이 될 수 있다. 이 층간 절연막(3) 상부에는 콘택용 마스크 패턴(4)이 공지의 포토리소그라피 공정에 의하여 형성된다.First, as shown in FIG. 1 (a), an
이어, 제1(b)도에 도시된 바와같이, 콘택용 마스크 패턴(4)을 이용하여, 층간 절연막(3)은 하층 배선(2)의 표면이 노출되도록 에칭하여 콘택홀(100)이 형성된다. 이어, 콘택홀(100) 내부 및 마스크 패턴(4) 상부에는 소정의 불순물들이 이온 주입된다. 이때, 불순물들로는 F, P, BF2, As, Ge, Si, Pb, Ar 중 선택되는 하나 또는 두개의 불순물이 이용된다. 상기 불순물을 결과물상에 이온 주입하는 것은, 알루미늄이 용이하게 성장될 수 있도록 시드층(seed layer)을 형성하여 주기 위함이고, 본 발명에서는 예를들어, F 이온을 이온 주입하였다. 여기서, 미설명 부호 200-1, 200-2는 상기 불순물이 이온 주입된 이온주입 층을 나타낸다.Subsequently, as shown in FIG. 1 (b), using the
여기서, 상기와 같이 시드층을 형성하게 되면 다음과 같은 반응에 의하여 알루미늄이 용이하게 성장된다.Here, when the seed layer is formed as described above, aluminum is easily grown by the following reaction.
즉, 알루미늄 소오스로서 예를들어 DMAH(dimethylaluminumhydride : A1H(CH3)2)가 이용되면, 하기의 반응식에 의하여 알루미늄만이 성장되어진다.That is, when, for example, DMAH (dimethylaluminum hydride: A1H (CH 3 ) 2 ) is used as the aluminum source, only aluminum is grown by the following reaction formula.
AlH(CH3)2) +F →1 Al(CH3)2+ HF ↑AlH (CH 3 ) 2 ) + F → 1 Al (CH 3 ) 2 + HF ↑
→ Al + 3H2↑+ 2CF4↑→ Al + 3H 2 ↑ + 2CF 4 ↑
→ Al→ Al
그후, 제1(c)에 도시된 바와 같이, 마스크 패턴(4)은 공지의 제거 방식으로 제거되어 콘택홀(100)내에만 이온주입층(200-1)이 존재하게 된다. 이어서, 콘택홀(100)내의 이온주입층(200-1)을 시드층으로 하여 알루미늄을 성장시키면, 콘택홀(100)내에 알루미늄층(5)이 선택 성장된다. 이때, 알루미늄막은 상기의 반응식에 의하여 성장되며, 약 200 내지 400℃의 온도와, 10-3내지 10 Torr의 압력하에서 형성된다. 여기서, 알루미늄 소오스로는 TIBA(triisobutylaluminum), 또는 DMAH가 이용된다. 이와같이, 콘택홀(100)내의 하부배선층에 시드층을 형성하여, 알루미늄막(5)이 콘택홀(100)내에만 고르게 성장된다. 따라서, 매립 불량으로 인한 금속 신뢰성 저하가 개선된다. 아울러, 콘택홀내의 하부 배선층에 이온주입된 불순물 이온주입층을 시드층으로 하여 알루미늄막이 성장되므로, 성장후 알루미늄막(5) 표면에 댕글링 본드들이 존재하지 않아, 표면 거칠음 현상이 방지된다. 따라서, 추가적인 연마 공정이 배제되고, 알루미늄막의 자체 저항이 매우 낮으므로, 전도 특성이 우수하게 된다.Thereafter, as shown in the first (c), the
그후, 결과물은 약 200 내지 500℃에서 5 내지 10분 동안 금속 특성 향상을 위한 어닐링 공정이 실시될 수 있다.Thereafter, the resultant may be subjected to an annealing process for improving metal properties at about 200 to 500 ° C. for 5 to 10 minutes.
이상에서 자세히 설명된 바와 같이, 본 발명에 의하면, 콘택홀 매립 금속층에서 형성단계 이전에, 콘택홀내의 하부 배선층에 불순물을 이온주입하여 시드층을 형성한 후, 알루미늄 금속막을 성장시킴으로써, 콘택홀 내의 매립 특성을 향상시키게 되고, 표면 거칠음 현상이 방지된다.As described in detail above, according to the present invention, before forming the contact hole buried metal layer, an ion is implanted into the lower interconnection layer in the contact hole to form a seed layer, and then an aluminum metal film is grown to thereby form the inside of the contact hole. The buried property is improved, and surface roughness is prevented.
아울러, 전도 특성이 우수한 알루미늄 금속막을 매립 금속막으로 이용하여, 금속 배선이 전도 특성이 개선된다.In addition, by using an aluminum metal film having excellent conductivity as a buried metal film, the metal wiring has improved conductivity.
기타, 본 발명은 그 요지를 일탈하지 않는 범위에서 다양하게 변경하여 실시할 수 있다.In addition, this invention can be implemented in various changes within the range which does not deviate from the summary.
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JPH05259110A (en) * | 1992-03-12 | 1993-10-08 | Sony Corp | Formation method of metal plug in semiconductor device |
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