KR0173202B1 - The finishing method of antimicrobial and deodorizing for natural fiber material - Google Patents
The finishing method of antimicrobial and deodorizing for natural fiber material Download PDFInfo
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- KR0173202B1 KR0173202B1 KR1019960023400A KR19960023400A KR0173202B1 KR 0173202 B1 KR0173202 B1 KR 0173202B1 KR 1019960023400 A KR1019960023400 A KR 1019960023400A KR 19960023400 A KR19960023400 A KR 19960023400A KR 0173202 B1 KR0173202 B1 KR 0173202B1
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
- D06M14/04—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/127—Mono-aldehydes, e.g. formaldehyde; Monoketones
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
- D06M23/12—Processes in which the treating agent is incorporated in microcapsules
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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Abstract
본 발명은 섬유재료에 정향 액기스와 폴리우레탄 수지 또는 우레아 포름알데히드(Urea-formaldehyde) 수지로 제조된 마이크로 캡슐을 바인더 수지로 코팅시켜서 항균성, 소취성 및 방향성이 우수한 섬유재료를 제조하는 방법에 관한 것이다.The present invention relates to a method for producing a fiber material having excellent antimicrobial activity, deodorizing property and directionality by coating a clay mineral with a binder resin in a microcapsule made of a clay extract and a polyurethane resin or a urea formaldehyde resin .
항균성과 소취성 및 방향성을 갖는 정향 액기스는 천연 식물인 정향을 메탄올 중에서 처리하여 정향 성분을 추출한 후 이를 농축시켜 제조한다.The clove, which has antimicrobial activity, deodorization and direction, is prepared by treating the clove, a natural plant, in methanol to extract the clove and concentrate it.
바인더 수지로는 실리콘계 수지, 우레탄계 수지 또는 아크릴계 수지가 사용된다.As the binder resin, a silicone resin, a urethane resin or an acrylic resin is used.
본 발명의 가공방법은 천연 섬유 및 합성 섬유 등 모든 섬유에 적용 가능하며, 가공 처리된 섬유재료는 항균성 및 소취성및 방향성이 우수하여 이불솜, 메트리스, 쿠숀 등의 침장류, 의류 및 부직포 등의 산업 자재용품으로 사용된다.The processing method of the present invention can be applied to all kinds of fibers such as natural fibers and synthetic fibers. The processed fiber materials are excellent in antimicrobial properties, deodorization properties and directionality, and can be used for industrial applications such as bedding materials such as bedding materials, mattresses and cushions, It is used as material goods.
Description
본 발명은 섬유 재료에 항균성 및 소취성을 부여하는 가공방법에 관한 것이다. 더욱 상세하게는 본 발명은 항균성 및 소취성을 갖는 정향 액기스와 폴리우레탄 수지 또는 우레아 포름알데히드(Urea- formaldehyde)수지로 마이크로 캡슐을 제조한 후, 이를 바인더 수지와 같이 섬유재료에 코팅시킴으로서 섬유재료에 항균성 및 소취성을 부여하는 가공방법에 관한 것이다.The present invention relates to a processing method for imparting antibacterial and deodorizing properties to a fiber material. More particularly, the present invention relates to a method for producing a microcapsule, which comprises preparing a microcapsule with a clay extract having antimicrobial activity and deodorizing property, a polyurethane resin or a urea formaldehyde resin and then coating the same with a fiber material such as a binder resin, Antimicrobial activity and deodorizing property.
우리의 생활환경에는 각종 세균류, 곰팡이가 존재하고 있으며 이들은 섬유재료에 부착, 서식되고 있는바, 이들 가운데는 인체에 직접해는 주지 않지만 섬유재료의 변질, 취화, 착색오염 및 악취발생을 시키는 것도 있고, 병원성으로 인체에 직접 해를 주는 것도 있다. 따라서, 이러한 곰팡이류로 인하여 발생되고 있는 문제점을 해결하기 위해 항균, 소취 가공은 종래부터 많은 관심의 대상이 되어 왔으나, 타 가공과는 달리 가공결과가 눈에 보이지 않으므로 상품으로서의 가치가 크게 평가되지 못하다가 최근 소비자들의 생활수준이 향상되고, 보다 쾌적한 생활을 추구하려는 욕망이 증대되면서 공중위생의 중요성이 강조되는 사회적인 환경변화에 따라 현재는 일시적인 붐이 아닌 꼭 필요한 가공수단으로 자리잡아가고 있다.There are various kinds of bacteria and fungi in our living environment, and they are adhered and living in fiber materials. Among them, there is no direct harm to the human body, but it also causes alteration of fiber materials, embrittlement, , And some are directly harmful to the human body due to pathogenicity. Therefore, antimicrobial and deodorizing processes have been a subject of much interest in order to solve the problems caused by these molds, but unlike other processes, since the process results are not visible, the value as a product can not be appreciated Recently, as the living standards of consumers have improved and the desire to pursue a more comfortable life has increased, social environment changes, which emphasize the importance of public health, are now becoming a necessary means of processing, not a temporary boom.
종래의 섬유에 항균성을 부여하는 항균 가공제로서는 2,4,4' - 트리클로로 -2'- 하이드록시디페닐에테르(이르가산 DP-300 : 치바가기사 상품명)가 제안되어 있다. 그러나 최근 이러한 2,4,4' - 트리클로로 -2'- 하이드록시디페닐에테르를 사용하여 항균 가공된 섬유 재료를 연소시키면 아주 독성이 높은 다이옥신(dioxin : 2,3,7,8 - tetrachlorodibenzoparadioxin)등이 생기는 것이 확인되어 사용이 중지되고 있다. 그래서 이를 대신한 항균 가공제로서 예를 들어 디메틸 벤질 라우릴 암모늄 클로라이드와 같은 제4급 암모늄이나 3,5 - 디브로모살리실 아닐리드와 같은 페놀계 화합물이 제안되고 있으나, 세탁내구성이 떨어지고 특히 염소계 세제를 사용할 경우 황변되는 문제가 발생된다. 이러한 이유로 일본 특개소 제 54-38951 호에는 이온 교환성 공중합체를 제조하여 동염 및 은염의 수용액으로 처리하여 섬유표면에 금속 이온을 표출시켜 항균성을 부여한 경우도 있다. 그러나 이와 같은 방법도 금속이온이 고분자와 반응을 하여 물성이 저하되기 때문에 사제조 공정 및 염색 등의 후공정에서 공정 통과성이 떨어지는 문제점이 생기게 된다.2,4,4'-trichloro-2'-hydroxydiphenyl ether (Irgacan DP-300: product name of Chiba Gagaku) has been proposed as an antibacterial agent for imparting antimicrobial properties to conventional fibers. However, recently, when 2,4,4 '- trichloro - 2' - hydroxydiphenyl ether is used to burn antimicrobially processed fiber materials, dioxin (2,3,7,8 - tetrachlorodibenzoparadioxin) And the like have been confirmed to have been used. Therefore, phenol compounds such as quaternary ammonium or 3,5-dibromosalicyl anilide such as dimethylbenzyllauryl ammonium chloride have been proposed as an antibacterial processing agent in place thereof, however, the washing durability is poor and chlorine-based detergent A yellowing problem occurs. For this reason, Japanese Patent Laid-Open Publication No. 54-38951 discloses an ion-exchangeable copolymer prepared and treated with an aqueous solution of the same salt or silver salt to display metal ions on the fiber surface to impart antimicrobial properties. However, such a method also causes a problem that the processability in the post-process such as the production process and the dyeing is deteriorated because the metal ion reacts with the polymer and the physical properties are lowered.
또한 한국 공고 특허 93-12185 에서는 금속이온을 함유하는 무기세라믹을 방사원액에 첨가한 후 이를 방사하여 항균성을 갖는 폴리에스테르 원사를 제조한다. 이와 같은 방법은 방사공정 없이도 생산되는 천연섬유 재료에는 적용할 수 없는 방법이다.In Korean Patent Publication No. 93-12185, an inorganic ceramic containing a metal ion is added to a spinning solution and then spun to produce a polyester yarn having antimicrobial activity. This method can not be applied to natural fiber materials produced without a spinning process.
한국 공개 특허 95-27021 에서는 키틴과 셀룰로오스를 용매중에 용해시킨후 이를 습식 방사시켜서 항균성을 갖는 셀룰로오스계 섬유를 제조한다. 이와 같은 방법도 별도의 방사공정을 거쳐야 하므로 공정이 복잡한 문제점이 있다.In Korean Patent Laid-Open No. 95-27021, chitin and cellulose are dissolved in a solvent and wet-spinned to prepare cellulose-based fibers having antibacterial properties. Such a method also requires a separate spinning process, which complicates the process.
본 발명의 과제는 이상에서 설명한 종래 기술의 문제점을 해결함과 동시에 별도의 방사공정을 거치지 않는 천연섬유 재료에도 적용 가능한 항균 및 소취 가공 방법을 제공하는데 있다 .Disclosure of Invention Technical Problem [8] Accordingly, the present invention has been made in view of the above problems, and an object of the present invention is to provide an antibacterial and deodorant processing method which can be applied to natural fiber materials which are not subjected to a separate spinning process.
본 발명은 정향 액기스를 함유하는 마이크로 캡슐을 제조한 후, 이를 바인더 수지로 섬유재료에 코팅시켜서 항균성 소취성 및 방향성을 부여하는 섬유재료의 항균 및 소취가공 방법에 관한 것이다.The present invention relates to a method for antibacterial and deodorization of a fiber material which is produced by preparing a microcapsule containing a clove extract and then coating the fiber material with a binder resin to impart antimicrobial deodorization and directionality.
본 발명을 보다 구체적으로 설명한다.The present invention will be described in more detail.
본 발명에서 사용되는 정향 액기스는 항균성과 소취성 및 방향성을 갖는 천연 화합물이다. 이와 같은 정향 액기스는 천연식물인 정향을 메탄올에서 처리하여 정향 성분을 추출하고 그 추출물을 농축시켜 제조한다.The clove extract used in the present invention is a natural compound having antimicrobial activity, deodorizing property and directionality. Such clove extracts are prepared by treating cloves, which are natural plants, with methanol to extract the clove components and concentrating the extracts.
보다 구체적인 예로서는 정향을 1시간 동안 수증기로 증류한 후, 메탄올로 정향 성분만 추출한다. 추출된 정향 성분을 메탄올과 같이 콘덴서에 투입하여 메탄올이 끊는 온도에서 1∼2시간 동안 3회 이상 환류, 농축시킨다.As a more specific example, the clove is distilled with water vapor for 1 hour, and then only the clove component is extracted with methanol. The extracted clove components are added to a condenser such as methanol, and refluxed and concentrated at a temperature at which methanol is broken at least three times for 1 to 2 hours.
제조된 정향 액기스를 여과한다. 이와 같이 제조된 정향 액기스는 항균성 및 소취성이 우수한 천연 화합물이다.The prepared clove extract is filtered. The clove juice thus produced is a natural compound having excellent antibacterial and deodorizing properties.
다음으로는 제조된 정향 액기스를 함유하는 마이크로 캡슐의 제조에 대하여 구체적으로 설명한다.Next, the production of the microcapsules containing the cloven liquor produced will be described in detail.
마이크로 캡슐의 제조에는 폴리우레탄 수지 또는 우레아 포름알데히드 수지가 사용된다. 먼저 폴리우레탄 수지를 사용하여 마이크로 캡슐을 제조하는 공정은 다음과 같다. 톨루엔 -2,4-디이소시아네이트와 시클로헥사논을 질소분위기 하에서 30분간 혼합하고, 여기에 다시 에틸렌 글리콜을 첨가한 후 80℃에서 2시간 정도 반응시키고 생성물을 감압여과하여 폴리우레탄 예비증합체를 제조한다. 제조된 플리우레탄 예비중합체, 정향 액기스 및 시클로헥사논을 아라빅 검(Arabic gum)의 수용성 용액에서 혼합, 분산시켜서 혼합물을 제조하고, 제조된 혼합물에 에틸렌 글리콜의 수용성 용액을 첨가하면서 가온 및 교반하면 마이크로 캡슐 슬러리가 제조된다.For the production of microcapsules, polyurethane resin or urea formaldehyde resin is used. First, the process for producing microcapsules using a polyurethane resin is as follows. The toluene-2,4-diisocyanate and cyclohexanone were mixed in a nitrogen atmosphere for 30 minutes, ethylene glycol was added thereto, and the mixture was reacted at 80 ° C for about 2 hours. The product was filtered under reduced pressure to prepare a polyurethane pre- do. The prepared polyurethane prepolymer, clove extract, and cyclohexanone were mixed and dispersed in an aqueous solution of Arabic gum to prepare a mixture. When the mixture was warmed and stirred while adding an aqueous solution of ethylene glycol to the resulting mixture, A microcapsule slurry is prepared.
한편, 우레아-포름알데히드 수지를 사용하여 마이크로 캡슐을 제조하는 공정은 다음과 같다. 포르말린과 우레아를 혼합시키고, 혼합물에 트리에탄올아민을 첨가한 후 1시간 동안 반응시켜서 예비중합체를 제조한다. 제조된 예비중합체에 구연산 및 정향 액기스를 첨가하여 에멀젼을 제조하고, 여기에 다시 구연산 및 온수를 첨가하면서 이들을 반응시켜 반응물을 제조하고, 반응물을 여과 및 건조시키면 마이크로 캡슐이 제조된다.Meanwhile, a process for producing microcapsules using a urea-formaldehyde resin is as follows. Formalin and urea are mixed, triethanolamine is added to the mixture, and the mixture is reacted for 1 hour to prepare a prepolymer. Citric acid and clove extract are added to the prepared prepolymer to prepare an emulsion, citric acid and warm water are added thereto to react them to prepare a reaction product, and the reaction product is filtered and dried to prepare microcapsules.
이와 같이 제조된 마이크로 캡슐을 바인더 수지 중에 침지시켜 코팅액을 제조한 후, 코팅액으로 섬유재료를 코팅한다. 코팅 후 70℃정도에서 20분 정도 예비 - 큐어링하고, 150℃정도에서 2분 정도 큐어링 시킨다. 이때 사용되는 바인더 수지는 실리콘계 수지, 우레탄계 수지, 또느 아크릴계 수지이다. 이와 같이 제조된 섬유재료는 항균성, 소취성 및 방향성이 우수하여 이불솜 등의 침장류, 의류 및 부직포 등의 산업 자재용품으로 사용될 수 있다.The microcapsules thus prepared are immersed in a binder resin to prepare a coating liquid, and then the fiber material is coated with a coating liquid. After coating, pre-cure at about 70 ° C for about 20 minutes and cure at about 150 ° C for about 2 minutes. The binder resin used herein is a silicone resin, a urethane resin, or an acrylic resin. The fiber material thus produced is excellent in antimicrobial activity, deodorization property and directionality, and can be used as an industrial material such as a bedding material such as a futon cotton, clothing, and nonwoven fabric.
본 발명의 가공방법은 직물, 편물 및 부직포 등에 모두 적용 가능하다.The processing method of the present invention can be applied to fabrics, knitted fabrics and nonwoven fabrics.
또한 섬유재료에는 천연섬유와 합성섬유 모두가 포함된다.The fiber material also includes both natural and synthetic fibers.
본 발명에 있어서 사용된 항균 시험법 및 소취 시험법은 다음과 같다.The antibacterial test method and the deodorization test method used in the present invention are as follows.
⊙ 항균 시험법⊙ Antibacterial test method
시험규격 AATCC - 100 시험 방법에 의하여 황색포도상구균에 대하여 항균효과를 시험하였다. 한천배지에 배양군을 접종하여 37℃ 에서 24 시간 배양한 균을 접종원으로 하여 시험편에 접종한 후 일정량의 액체를 가하여 시험편으로부터 세균을 액중에 추출시킨다. 그 다음 처리포와 미처리포의 액중에 잔존하는 세균의 수를 측정하여 아래식에 의해 균 감소율을 산출하였다.Test Specification The antimicrobial effect of Staphylococcus aureus was tested by AATCC - 100 test method. The cultured group is inoculated on agar medium and cultured at 37 ° C for 24 hours. Inoculated on the test specimen, a certain amount of liquid is added to extract the bacteria from the test specimen. Then, the number of bacteria remaining in the liquid of the treated and non-treated liposomes was measured, and the microbial reduction rate was calculated by the following formula.
⊙ 소취 시험법⊙ Deodorizing test method
암모니아, 황화수소 등의 악취가스를 집어넣은 그래스증발관을 데시케이터 아래에 놓고, 연결되어 있는 통로의 판위에 시험편을 위치시킨 후 데시케이터를 밀봉하여 25℃ 에서 2 시간 방치한 후 그래스증발관의 악취 농도를 검지관에서 측정하여 아래의 식에 의해 악취농도 감소율을 산출하였다.Ammonia, hydrogen sulfide, etc., placed under a desiccator, place the specimen on the plate of the connected passage, seal the desiccator, leave it at 25 ° C for 2 hours, Was measured by a detector tube and the odor concentration reduction rate was calculated by the following equation.
이하 실시예 및 비교실시예를 통해 본 발명을 상세하게 설명한다. 한편, 이 실시예에 의해 본 발명이 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to Examples and Comparative Examples. However, the present invention is not limited by these examples.
[실시예 1][Example 1]
정향 100g을 수증기로 1시간 동안 수증기로 증류한 후 메탄올로 정향 성분만 추출하고, 추출된 정향 성분을 메탄올 700 cc와 같이 콘덴서에 투입한 후 메탄올이 끊는 온도까지 가온하면서 1∼2시간 동안 3회 환류시킨 후 여과하여 정향 액기스를 제조하였다.100 g of cloves were distilled with water vapor for 1 hour with water vapor, and then only the clove component was extracted with methanol. The extracted clove components were added to the condenser like 700 cc of methanol, and heated to the temperature at which the methanol was broken. After refluxing, the mixture was filtered to produce a clove extract.
한편, 톨루엔 -2,4 - 디이소시아네이트 19.16g과 시클로헥사논 122.7㎖를 질소분위기 하에서 30분간 혼합한 후, 혼합물에 에틸렌 글리콜 3.10g을 첨가하고 80℃에서 2시간 동안 반응시켜서 플리우레탄 예비중합체를 제조하였다. 제조된 예비중합체 4g, 정향 액기스 4g 및 시클로헥사논 12g을 1.5%의 아라빅 검 수용액 100g과 같이 혼합, 분산시키고, 여기에 에틸렌 글리콜 4g 과 물 20g으로 구성된 수용액을 첨가하면서 66℃로 가온과 동시에 교반시켜 마이크로 캡슐을 제조하였다.On the other hand, after 19.16 g of toluene-2,4-diisocyanate and 122.7 ml of cyclohexanone were mixed for 30 minutes in a nitrogen atmosphere, 3.10 g of ethylene glycol was added to the mixture, and the mixture was allowed to react at 80 ° C for 2 hours to obtain a prepolymer . 4 g of the prepared prepolymer, 4 g of clove extract, and 12 g of cyclohexanone were mixed and dispersed in 100 g of 1.5% aqueous arabic gum solution, and an aqueous solution composed of 4 g of ethylene glycol and 20 g of water was added thereto, Followed by stirring to prepare microcapsules.
제조된 마이크로 캡슐을 실리콘계 수지에 침지시켜서 코팅액을 제조하고, 코팅액으로 면직물을 코팅하였다. 코팅 후 70℃에서 20분간 예비 - 큐어링 하고, 계속해서 150℃에서 2분간 큐어링 처리하였다.The prepared microcapsules were immersed in a silicone resin to prepare a coating solution, and the cotton fabric was coated with the coating solution. After coating, pre-curing was carried out at 70 DEG C for 20 minutes, followed by curing at 150 DEG C for 2 minutes.
[실시예 2][Example 2]
실시예1과 동일한 조건으로 정향 액기스를 제조하였다. 한편 포르말린 488.5g과 우레아 240g을 혼합하고, 여기에 pH가 8인 트리에탄올 아민을 첨가한 후 이들을 1시간 동안 반응 시켜서 우레아-포름알데히드 예비 중합체를 제조한다.A clove was prepared under the same conditions as in Example 1. On the other hand, 488.5 g of formalin and 240 g of urea were mixed, triethanolamine having a pH of 8 was added thereto, and these were reacted for 1 hour to prepare a urea-formaldehyde prepolymer.
제조된 예비중합체 150㎖와 정향 액기스 50g을 구연산 중에서 혼합시켜서 에멀젼을 제조한 후 이들을 45℃에서 3시간 동안 반응시킨다. 제조된 반응물을 여과 및 건조시켜 마이크로 캡슐을 제조하였다. 제조된 마이크로 캡슐을 우레탄계 수지에 침지시켜서 코팅액을 제조하고, 코팅액으로 폴리아미드 부직포를 코팅하였다. 코팅 후 70℃에서 20분간 예비 - 큐어링하고, 계속해서 150℃에서 2분간 큐어링 처리하였다.150 ml of the prepared prepolymer and 50 g of the clove were mixed in citric acid to prepare an emulsion, which was then reacted at 45 ° C for 3 hours. The prepared reaction product was filtered and dried to prepare microcapsules. The prepared microcapsules were immersed in a urethane resin to prepare a coating liquid, and a polyamide nonwoven fabric was coated with the coating liquid. After coating, pre-curing was carried out at 70 DEG C for 20 minutes, followed by curing at 150 DEG C for 2 minutes.
실시예1 및 실시예 2 에서 제조된 제품의 항균성 및 소취성을 앞에서 설명한 측정법으로 측정하였고, 본 발명의 가공 방법으로 처리되지 않은 면직물 및 폴리아미드 부직포의 항균성 및 소취성과 비교해 본 결과는 표 1과 같다.The antibacterial and deodorant properties of the products prepared in Examples 1 and 2 were measured by the above-described measuring method, and the antimicrobial activity and the deodorization of the cotton fabric and the polyamide nonwoven fabric which were not treated by the processing method of the present invention were compared. same.
Claims (4)
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040001773A (en) * | 2002-06-28 | 2004-01-07 | 정문교 | Fragrant printing method |
| KR100415442B1 (en) * | 2001-02-15 | 2004-01-24 | 우리켐테크(주) | Health functional textile adhered by microcapsule containing muscone or natural oil |
| KR20040040044A (en) * | 2002-11-06 | 2004-05-12 | 임대우 | Microcapsule containing Vitamin E and/or natural oil for medical use, nonwoven fabric and absorbing core coated by the microcapsule, and absorbing product manufactured thereby |
| KR100722191B1 (en) * | 2006-04-19 | 2007-05-29 | 경북대학교 산학협력단 | Sustained release high durable aromatic adhesives and aromatic fibrous materials using the same |
| KR100726409B1 (en) * | 2005-08-31 | 2007-06-11 | (재)대구경북과학기술연구원 | Functional fabrics having antibacterial effects and its manufacturing method |
| KR100952124B1 (en) * | 2009-12-08 | 2010-04-08 | (주)몰리테크 | Preparation method of metallic glitter power for mininizing formaldehyde remainder |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20030012365A (en) * | 2001-07-31 | 2003-02-12 | 주식회사 한택 | Method for Flatting a Surface of Semiconductor and Optical Device |
| KR20030018625A (en) * | 2001-08-30 | 2003-03-06 | 주식회사 허브메디 | Preparing method of herb functional underclothes for menstrual pain using herbal medicine and herb functional underclothes for menstrual pain thereof |
-
1996
- 1996-06-25 KR KR1019960023400A patent/KR0173202B1/en not_active IP Right Cessation
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100415442B1 (en) * | 2001-02-15 | 2004-01-24 | 우리켐테크(주) | Health functional textile adhered by microcapsule containing muscone or natural oil |
| KR20040001773A (en) * | 2002-06-28 | 2004-01-07 | 정문교 | Fragrant printing method |
| KR20040040044A (en) * | 2002-11-06 | 2004-05-12 | 임대우 | Microcapsule containing Vitamin E and/or natural oil for medical use, nonwoven fabric and absorbing core coated by the microcapsule, and absorbing product manufactured thereby |
| KR100726409B1 (en) * | 2005-08-31 | 2007-06-11 | (재)대구경북과학기술연구원 | Functional fabrics having antibacterial effects and its manufacturing method |
| KR100722191B1 (en) * | 2006-04-19 | 2007-05-29 | 경북대학교 산학협력단 | Sustained release high durable aromatic adhesives and aromatic fibrous materials using the same |
| KR100952124B1 (en) * | 2009-12-08 | 2010-04-08 | (주)몰리테크 | Preparation method of metallic glitter power for mininizing formaldehyde remainder |
Also Published As
| Publication number | Publication date |
|---|---|
| KR980002414A (en) | 1998-03-30 |
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