JPS6450843A - Production of methacrylic acid ester - Google Patents

Production of methacrylic acid ester

Info

Publication number
JPS6450843A
JPS6450843A JP62207799A JP20779987A JPS6450843A JP S6450843 A JPS6450843 A JP S6450843A JP 62207799 A JP62207799 A JP 62207799A JP 20779987 A JP20779987 A JP 20779987A JP S6450843 A JPS6450843 A JP S6450843A
Authority
JP
Japan
Prior art keywords
acid
methacrylic acid
alcohol
catalyst
tantalic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP62207799A
Other languages
Japanese (ja)
Other versions
JPH0733351B2 (en
Inventor
Hirosuke Wada
Takashi Ushikubo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Kasei Corp
Original Assignee
Mitsubishi Kasei Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp filed Critical Mitsubishi Kasei Corp
Priority to JP62207799A priority Critical patent/JPH0733351B2/en
Publication of JPS6450843A publication Critical patent/JPS6450843A/en
Publication of JPH0733351B2 publication Critical patent/JPH0733351B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PURPOSE:To obtain the titled compound useful as a raw material for synthetic polymers, coatings, etc., in high yield, by reacting methacrylic acid with an alcohol in the vapor phase in the presence of tantalic acid. CONSTITUTION:Methacrylic acid is reacted with a 1-8C alcohol in the presence of tantalic acid catalyst at 120-300 deg.C under atmospheric pressure or several hundreds of mmHg-10kg/cm<2>G pressure in an inert gas atmosphere, such as nitrogen or helium, to afford the aimed substance. The tantalic acid is obtained by hydrolyzing a halide (e.g. TaCl5) of pentavalent tantalum to provide tantalum hydroxide which is a precursor, washing the resultant tantalum hydroxide with an acid and/or water and heat-treating the washed substance. The methacrylic acid and alcohol are used at 1:50-5 molar ratio. Since the catalyst has high activity, this reaction is carried out at a low temperature with a long catalyst life and stable operation can be performed for a long period. Since the selectivity is high, steps of separating and recovering the ester can be simplified.
JP62207799A 1987-08-21 1987-08-21 Method for producing methacrylic acid ester Expired - Fee Related JPH0733351B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62207799A JPH0733351B2 (en) 1987-08-21 1987-08-21 Method for producing methacrylic acid ester

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62207799A JPH0733351B2 (en) 1987-08-21 1987-08-21 Method for producing methacrylic acid ester

Publications (2)

Publication Number Publication Date
JPS6450843A true JPS6450843A (en) 1989-02-27
JPH0733351B2 JPH0733351B2 (en) 1995-04-12

Family

ID=16545685

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62207799A Expired - Fee Related JPH0733351B2 (en) 1987-08-21 1987-08-21 Method for producing methacrylic acid ester

Country Status (1)

Country Link
JP (1) JPH0733351B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998025876A1 (en) * 1996-12-12 1998-06-18 Sasol Technology (Proprietary) Limited Production of organic carboxylic acid esters
GB2396612A (en) * 2002-12-19 2004-06-30 Procter & Gamble Preparation of wax esters by esterifying acids with alcohols below atmospheric pressure

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998025876A1 (en) * 1996-12-12 1998-06-18 Sasol Technology (Proprietary) Limited Production of organic carboxylic acid esters
GB2396612A (en) * 2002-12-19 2004-06-30 Procter & Gamble Preparation of wax esters by esterifying acids with alcohols below atmospheric pressure

Also Published As

Publication number Publication date
JPH0733351B2 (en) 1995-04-12

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Legal Events

Date Code Title Description
LAPS Cancellation because of no payment of annual fees