JPS6392492A - Thermal transfer medium - Google Patents
Thermal transfer mediumInfo
- Publication number
- JPS6392492A JPS6392492A JP61238748A JP23874886A JPS6392492A JP S6392492 A JPS6392492 A JP S6392492A JP 61238748 A JP61238748 A JP 61238748A JP 23874886 A JP23874886 A JP 23874886A JP S6392492 A JPS6392492 A JP S6392492A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- base film
- thermal transfer
- recording paper
- ink layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 claims abstract description 63
- 239000012790 adhesive layer Substances 0.000 claims abstract description 14
- 239000012530 fluid Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 238000007740 vapor deposition Methods 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 239000000463 material Substances 0.000 abstract description 13
- 238000004040 coloring Methods 0.000 abstract description 7
- 239000002131 composite material Substances 0.000 abstract description 3
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 22
- 239000011347 resin Substances 0.000 description 22
- 239000010408 film Substances 0.000 description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000002844 melting Methods 0.000 description 8
- -1 polyethylene Polymers 0.000 description 7
- 239000000243 solution Substances 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- 239000000956 alloy Substances 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 150000002736 metal compounds Chemical class 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000000740 bleeding effect Effects 0.000 description 3
- 229910052804 chromium Inorganic materials 0.000 description 3
- 239000011651 chromium Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- 239000001293 FEMA 3089 Substances 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920000877 Melamine resin Polymers 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 229920002301 cellulose acetate Polymers 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- YIWGJFPJRAEKMK-UHFFFAOYSA-N 1-(2H-benzotriazol-5-yl)-3-methyl-8-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carbonyl]-1,3,8-triazaspiro[4.5]decane-2,4-dione Chemical group CN1C(=O)N(c2ccc3n[nH]nc3c2)C2(CCN(CC2)C(=O)c2cnc(NCc3cccc(OC(F)(F)F)c3)nc2)C1=O YIWGJFPJRAEKMK-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000004163 Spermaceti wax Substances 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000001883 metal evaporation Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000001454 recorded image Methods 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000019385 spermaceti wax Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
［技術分野］
本発明は、プリンタ、ファクシミリ、タイプライタ等の
感熱転写装置に用いられる感熱転写媒体に関し、更に詳
しくは、表面平滑性の悪い被記録紙に対しても良好な印
字品質の感熱転写記録像を記録できる様にした感熱転写
媒体に関する。Detailed Description of the Invention [Technical Field] The present invention relates to a thermal transfer medium used in thermal transfer devices such as printers, facsimiles, and typewriters, and more specifically, to a thermal transfer medium used for recording paper with poor surface smoothness. The present invention relates to a thermal transfer medium capable of recording thermal transfer recorded images with good print quality.
［従来の技術］
従来より、感熱転写媒体には、例えば３〜１２１厚さ程
度のベースフィルムの上に所定の温度で熱溶融する熱溶
融性インク層が設けられてできている。この感熱転写媒
体の記録動作を説明すると、ベースフィルムにはサーマ
ルヘッドが当接していて、サーマルヘッドか記録信号に
応じて駆動されその部分が発熱すると、ベースフィルム
の該当する部分の熱溶融性インクが溶融して被転写紙に
転写される。この転写インクにより被転写紙に記録信号
に応じた転写像が形成され、普通紙を用いた被転写紙へ
の記録かできる。[Prior Art] Conventionally, thermal transfer media have been made by providing a heat-melting ink layer that heat-melts at a predetermined temperature on a base film having a thickness of, for example, about 3 to 121 cm. To explain the recording operation of this thermal transfer medium, a thermal head is in contact with the base film, and when the thermal head is driven according to a recording signal and that part generates heat, the heat-melting ink is applied to the corresponding part of the base film. is melted and transferred to the receiving paper. A transfer image corresponding to the recording signal is formed on the transfer paper using this transfer ink, and recording can be performed on the transfer paper using plain paper.
しかしなから、上記のような感熱転写媒体は、熱溶融し
たインクを記録紙の表面に浸み込ませるものであるため
、被記録紙の表面の影響を受は易く、例えば被記録紙の
ベック平滑度か４０秒以下のボンド紙と成るとインクの
乗りか均一てなくなり、画質の低下は免れなかった。ま
た溶融粘度の小さい熱溶融性バインダーを使用したもの
にあっては転写像に滲みか生じ、熱溶融性インク層の厚
みを増大させると転写像の滲みの増大、印字速度の低下
などの問題点があった。またベースフィルムに熱溶融性
インク層、転写補助層を設けたものも提案されているが
（特開昭６１−１１４８８９号公報参照）転写補助層へ
の熱溶融性インク層中の色材の移行による滲みの発生、
画像濃度を上げるために熱溶融性インク層の厚みを上げ
る必要があり、そのため画像の切れか悪くなって画像の
再現性か悪くなったり、さらには熱伝導性か悪くなるた
め印字速度か低下するなどの問題点があった。However, since the thermal transfer medium described above allows thermally molten ink to soak into the surface of the recording paper, it is easily affected by the surface of the recording paper, such as the back of the recording paper. When using bond paper with a smoothness of 40 seconds or less, the ink application becomes uneven and the image quality inevitably deteriorates. In addition, if a hot-melt binder with a low melt viscosity is used, bleeding occurs in the transferred image, and increasing the thickness of the hot-melting ink layer causes problems such as increased bleeding in the transferred image and a decrease in printing speed. was there. In addition, a base film with a heat-melting ink layer and a transfer auxiliary layer has been proposed (see Japanese Patent Laid-Open No. 114889/1989), but the coloring material in the heat-melting ink layer transfers to the transfer auxiliary layer. Occurrence of bleeding due to
In order to increase the image density, it is necessary to increase the thickness of the heat-melting ink layer, which results in poor image sharpness and poor image reproducibility, and furthermore, poor thermal conductivity, which reduces printing speed. There were problems such as:
［発明の目的］
本発明は上記従来の問題点に鑑み、ボンド紙のような表
面平滑性の低い被記録紙てあってもその表面の影響を受
けることなく、極めて良好な画質の転写像等の記録が省
エネルギー、高速印字てきる感熱転写媒体を提供するこ
とにある。更にそのＪ二ＯＨＰシートへ印字した場合に
も遮光性が強いためにシャープなＯＨＰ画像が得られる
感熱転写媒体を提供することにある。[Object of the Invention] In view of the above-mentioned conventional problems, the present invention provides a transfer image, etc., with extremely good image quality, without being affected by the surface of recording paper such as bond paper, which has a low surface smoothness. Our goal is to provide a thermal transfer medium that saves energy and enables high-speed printing. Furthermore, it is an object of the present invention to provide a heat-sensitive transfer medium that has strong light-shielding properties and can produce sharp OHP images even when printed on the J2 OHP sheet.
［発明の構成］
即ち本発明は、ベースフィルムの上に直接または離型剤
層を介して、少なくとも非流動性インク層、金属蒸着層
、接着剤層を順次形成したことを特徴とする感熱転写媒
体に関するものである。[Structure of the Invention] That is, the present invention provides a thermal transfer characterized in that at least a non-fluid ink layer, a metal vapor deposition layer, and an adhesive layer are sequentially formed on a base film directly or via a release agent layer. It's about the medium.
即ち本発明の感熱転写媒体においては、従来感熱転写媒
体の熱溶融性インク層にかえて少なくとも非流動性イン
ク層、金属蒸着層および接着剤層とからなる複合層を用
いることによって、ボンド紙のような平滑性の低い被記
録紙てあってもその表面の影響を受けることなく、極め
て良好な画質の転写像等の記録ができる感熱転写媒体を
完成したもである。That is, in the thermal transfer medium of the present invention, a composite layer consisting of at least a non-flowable ink layer, a metal vapor deposition layer, and an adhesive layer is used in place of the heat-melting ink layer of conventional thermal transfer media, so that bond paper can be improved. The present invention has completed a thermal transfer medium that can record transferred images of extremely good image quality without being affected by the surface of such recording paper with low smoothness.
即ち本発明は、ベースフィルム（１）の上に直接または
離型剤層（２）を介して、少なくとも非流動性インク層
（３）、金属蒸着層（４）および接着剤層（５）とから
複合層を順次形成してたことによりボンド紙のような平
滑性の低い被記録紙であってもその表面の影響を受ける
ことなく、極めて良好な画質の転写像等の記録かできる
感熱転写媒体を提供することを可能としたものである。That is, the present invention provides at least a non-fluid ink layer (3), a metal vapor deposition layer (4) and an adhesive layer (5) on the base film (1) directly or via a release agent layer (2). By sequentially forming composite layers, thermal transfer is able to record transferred images with extremely good image quality, without being affected by the surface of recording paper with low smoothness, such as bond paper. This makes it possible to provide media.
本発明の感熱転写媒体におけるベースフィルム（１）と
しては充分な自己保持性を有するものてあればいずれも
用いられるか、たとえばポリエステル、ポリアミド、ポ
リアミドイミド、ポリエチレン、ポリプロピレン、セル
ロースアセテート、ポリカーボネート、ポリ塩化ビニル
、フッ素樹脂などの樹脂類またはセロハン紙、クラシン
紙などのフィルム状物またはシート状物や剥離紙または
剥離フィルムなどが適宜用いられる。特にベースフィル
ム（１）としては前記樹脂類のフィルム状物て厚さが２
．５〜１２に１程度のものを用いるのが、しわや亀裂な
どのない感熱転写媒体の製造が連続的に大量生産出来る
点から好ましい。また先に本出願人が出願した発明（特
願昭６０−２６０７７４号）に記載されている様な、プ
ラスチックフィルムの熱転写層を設ける側の反対側に無
機物の薄膜、例えば５ｉＯ２Ｓｉ０２、ＴｉＯ２、Ｚｎ
Ｏ，Ａｌ２Ｏ３等の酸化物、ＴｉＮ等のチッ化物、Ｔｉ
Ｃ等の炭化物、炭素、層、Ｎｉ、Ｃｒ、Ｔｉ、Ｎｉ−１
：ｒ合金等の金属の６〜１１００ｎ程度の薄膜を設けた
耐ホツトステイク性加工したものも好ましく用いられる
。As the base film (1) in the thermal transfer medium of the present invention, any material can be used as long as it has sufficient self-retention properties, such as polyester, polyamide, polyamideimide, polyethylene, polypropylene, cellulose acetate, polycarbonate, and polychloride. Resins such as vinyl and fluororesin, film-like materials or sheet-like materials such as cellophane paper and Krashin paper, and release paper or release films are used as appropriate. In particular, as the base film (1), the film-like material of the above resins has a thickness of 2
．． It is preferable to use about 1 in 5 to 12 from the viewpoint of continuous mass production of thermal transfer media without wrinkles or cracks. Furthermore, as described in the invention previously filed by the present applicant (Japanese Patent Application No. 60-260774), a thin film of an inorganic material such as 5iO2Si02, TiO2, Zn is formed on the opposite side of the plastic film to the side where the thermal transfer layer is provided.
O, oxides such as Al2O3, nitrides such as TiN, Ti
Carbide such as C, carbon, layer, Ni, Cr, Ti, Ni-1
It is also preferable to use a hot-stake resistant material with a thin film of metal such as :r alloy having a thickness of about 6 to 1100 nm.
尚、ベースフィルム（１）が非流動性インク層（３）と
の剥離性がよくない場合にはパラフィンワックス、シリ
コーン、フッ素樹脂、界面活性剤などを塗布して離型剤
層（２）を形成しておいてもよい。If the base film (1) does not have good releasability from the non-fluid ink layer (3), apply paraffin wax, silicone, fluororesin, surfactant, etc. to form a release agent layer (2). It may be formed in advance.
本発明の感熱転写媒体のにおける、非流動性インク層の
厚さは特に制限は無いが通常０．５〜２μの範囲から適
宜選ばれる。The thickness of the non-fluid ink layer in the thermal transfer medium of the present invention is not particularly limited, but is usually appropriately selected from the range of 0.5 to 2 .mu.m.
かかる非流動性インク層を形成するためのインクとして
は、たとえば熱可塑性樹脂、熱硬化性樹脂、電子線硬化
性樹脂、紫外線硬化性樹脂のいずれもが用いられ、たと
えばアクリル系樹脂、塩化ビニル−酢酸ビニル共重合体
、ポリビニルブチラール、ポリカーボネート、ニトロセ
ルロース、セルロースアセテート、ウレタン系樹脂、尿
素系樹脂、メラミン系樹脂、尿素−メラミン系樹脂、エ
ポキシ系樹脂、アルキッド系樹脂、アミノアルキッド系
樹脂、ロジン変性マレイン酸樹脂などの単独または混合
物に色材を混合したものか好ましく用いられる。As the ink for forming such a non-fluid ink layer, any of thermoplastic resins, thermosetting resins, electron beam curable resins, and ultraviolet curable resins may be used, such as acrylic resins, vinyl chloride resins, etc. Vinyl acetate copolymer, polyvinyl butyral, polycarbonate, nitrocellulose, cellulose acetate, urethane resin, urea resin, melamine resin, urea-melamine resin, epoxy resin, alkyd resin, aminoalkyd resin, rosin modification Preferably, a maleic acid resin or a mixture thereof mixed with a coloring material is used.
色材は印刷記録分野て広く用いられている各種の染料、
顔料が用いられる。通常のモノクロ用プリンター用ては
カーボンブラックか一般的であるか、カラープリンター
においてはいわゆる色の三原色（シアン、マゼンタ、イ
エロー）をはじめとして様々な色と性質をもった色材が
用いられる。Coloring materials include various dyes widely used in the printing and recording field.
Pigments are used. For regular monochrome printers, carbon black is used, and for color printers, coloring materials with various colors and properties are used, including the so-called three primary colors (cyan, magenta, and yellow).
これら色材は通常非流動性インクの２〜８０重量％添加
される。These coloring materials are usually added in an amount of 2 to 80% by weight of the non-flowable ink.
非流動性インク層の形成は、前記非流動性インクを形成
するための樹脂の有機溶剤溶液、水溶液などをロールコ
ーチインク法、グラビアコーティング法、リバースコー
ティング法、スプレィコーティング法などの通常のコー
ティング法により塗布し、乾燥（熱硬化性樹脂、電子線
硬化性樹脂、紫外線硬化性樹脂などの場合は硬化）する
ことによって行われるい。The non-fluid ink layer is formed by applying an organic solvent solution, aqueous solution, etc. of the resin to form the non-fluid ink using a conventional coating method such as a roll coach ink method, a gravure coating method, a reverse coating method, a spray coating method, etc. This is done by applying the resin and drying (curing in the case of thermosetting resins, electron beam curable resins, ultraviolet ray curable resins, etc.).
木発明の感熱転写媒体の金属蒸着層（４）は前記非流動
性インク層の上に常法により例えばアルミニウム、銅、
銀、金などの金属またはそれらの合金あるいは金属化合
物を蒸着して形成されるが、遮光性とコストの点からア
ルミニウムが最も好ましい。金属蒸着層は被記録紙から
の反射光を完全に遮光し非流動性インク層の画像濃度を
高める効果を有し、したかって非流動性インク層を比較
的薄膜とすることができるので印字の切れかよくなり、
熱伝導性を高めるという効果を奏する。The metal vapor deposited layer (4) of the thermal transfer medium of Wood's invention is formed on the non-flowing ink layer by a conventional method such as aluminum, copper, etc.
It is formed by vapor-depositing metals such as silver and gold, or their alloys or metal compounds, but aluminum is most preferable in terms of light-shielding properties and cost. The metal-deposited layer has the effect of completely blocking light reflected from the recording paper and increasing the image density of the non-flowing ink layer.Therefore, the non-flowing ink layer can be made relatively thin, which improves printing quality. It becomes sharper,
It has the effect of increasing thermal conductivity.
前記金属蒸着層としては、公知の真空蒸着法、スパッタ
リング法、イオンプレイティング法などの通常の金属（
合金および金属化合物も含む、以下同様）の薄膜形成方
法により、例えば亜鉛、アルミニウム、ガリウム、イン
ジウム、錫、ニッケル、銀、金、銅、珪素、クロム、チ
タン、白金、パラジウムなどの蒸着が可能な単体または
混合物あるいは合金や金属化合物等が厚さ１０〜１１０
０ｎ程度に蒸着形成される。厚さか１０ｎｍ程度以下の
場合には遮光性や金属光沢が殆ど認められず金属蒸着層
を設けた価値が無く、また１１００ｎ程度°以上に形成
しても遮光性や金属光沢に変化かなく経済的でない。尚
、金属蒸着層は一層とせず、複数層としても良く、その
場合には層毎に金属の種類をかえてもよい。The metal evaporation layer may be formed by using a conventional metal (
The method for forming thin films of alloys and metal compounds (including alloys and metal compounds, hereinafter the same) enables the vapor deposition of, for example, zinc, aluminum, gallium, indium, tin, nickel, silver, gold, copper, silicon, chromium, titanium, platinum, palladium, etc. Thickness of single substance, mixture, alloy, metal compound, etc. is 10 to 110
It is formed by vapor deposition to a thickness of about 0n. If the thickness is less than about 10 nm, there is almost no light shielding property or metallic luster, so there is no value in providing a metal vapor deposited layer, and even if it is formed to a thickness of about 1100 nm or more, there is no change in light shielding property or metallic luster, making it economical. Not. Note that the metal vapor deposition layer may not be one layer, but may be a plurality of layers, and in that case, the type of metal may be changed for each layer.
本発明の感熱転写媒体の接着剤層（５）は従来の熱溶融
性インク層に比べてカーボンブラック等の色材を含有さ
せる必要がないから充分に柔らかく被記録紙への接着性
のみを考慮して接着剤を選択使用てきるのて被記録紙の
表面が平滑度の低いものであっても凹凸部に忠実に付着
ないし浸透して加熱部に忠実な像形成かできる。また接
着剤層自身は滲んだとしても透明であるため画像への影
響はない。The adhesive layer (5) of the thermal transfer medium of the present invention does not need to contain a coloring material such as carbon black compared to a conventional heat-melting ink layer, so it is sufficiently soft and only the adhesiveness to the recording paper is considered. Since the adhesive can be selectively used, even if the surface of the recording paper has low smoothness, it can faithfully adhere to or penetrate into the uneven parts and form an image faithfully on the heated part. Furthermore, even if the adhesive layer itself bleeds, it will not affect the image because it is transparent.
本発明の感熱転写媒体の接着剤層（５）としては例えば
鯨ロウ、ミツロウ、ラノリン、カルバナワックス、キャ
ンデリラワックス、モンタンワックス等の天然ワックス
、パラフィンワックス、マイクロタリンワックス、酸化
ワックス、エステルワックス、低分子量ポリエチレン等
の合成ワックス、ラウリン酸、ミリスチン酸、パルミチ
ン酸、スデアリン酪、フロメン酸、ベヘニン酸等の高級
脂肪酸、ステアリルアルコール、ベヘニルアルコール等
の高級アルコール、ショ糖の脂肪酸エステル、ソルビタ
ンの脂肪酸エステル等のエステル類、ステアリンアミド
、オレインアミド等のアミド類、ポリアミ１く系樹脂、
ボロエステル系樹脂、エポキシ系樹脂、ポリウレタン系
樹脂、アクリル系樹脂、塩化ビニル系樹脂、セルロース
系樹脂、ポリビニール系樹脂、石油系樹脂、エチレン−
酢酸ビニル共重合体樹脂、フェノール系樹脂、スチレン
系樹脂、天然ゴム、スチレンツタジエンゴム、イソプレ
ンゴム、クロロプレンゴム等のエラストマー類、ロジン
及びその誘導体、テルペン樹脂、水添石油樹脂等のタッ
キファイヤ−１充填剤、可塑剤、酸化防止剤などの単独
又は混合されたものが用いられる。接着剤層（５）の厚
さは被転写紙の表面状態などにより適宜選択決定される
ものであるか通常は１〜ｌＯμ曹程度の範囲から選ばれ
、通常の被転写紙の表面か比較的平滑な場合には比較的
薄い１〜２μｍ程度である。Examples of the adhesive layer (5) of the thermal transfer medium of the present invention include natural waxes such as spermaceti wax, beeswax, lanolin, carvana wax, candelilla wax, and montan wax, paraffin wax, microtalin wax, oxidized wax, and ester wax. , synthetic waxes such as low molecular weight polyethylene, higher fatty acids such as lauric acid, myristic acid, palmitic acid, sudarinbutyric acid, fromenic acid, and behenic acid, higher alcohols such as stearyl alcohol and behenyl alcohol, fatty acid esters of sucrose, and fatty acid esters of sorbitan. esters such as, amides such as stearinamide and oleinamide, polyamide resins,
Boroester resin, epoxy resin, polyurethane resin, acrylic resin, vinyl chloride resin, cellulose resin, polyvinyl resin, petroleum resin, ethylene-
Tackifiers for vinyl acetate copolymer resins, phenolic resins, styrene resins, natural rubber, elastomers such as styrene rubber, isoprene rubber, chloroprene rubber, rosin and its derivatives, terpene resins, hydrogenated petroleum resins, etc. 1 Fillers, plasticizers, antioxidants, etc. may be used alone or in combination. The thickness of the adhesive layer (5) is selected depending on the surface condition of the transfer paper, etc., and is usually selected from a range of about 1 to 10 μm. If it is smooth, it is relatively thin, about 1 to 2 μm.
このように木発明は平滑度の低い非記録紙にも鮮明な画
像を形成てきるという特徴を持つか、さらには金属蒸着
層を有し、全体の層の厚みも比較的薄いということから
熱伝導性か良好となり、その結果印字速度か速い、省エ
ネルギーに役立つ等の特徴を有する。さらには画像に金
属蒸着層を有していることから、ＯＨＰシートに画像を
転写した際には非常に鮮明なＯＨＰ画像を得ることかで
きる。In this way, the wooden invention has the characteristic of being able to form clear images even on non-recording paper with low smoothness, and furthermore, it has a metal vapor deposition layer and the overall thickness of the layer is relatively thin, so it can be heated easily. It has good conductivity, resulting in high printing speed and energy saving. Furthermore, since the image has a metal vapor deposited layer, a very clear OHP image can be obtained when the image is transferred to an OHP sheet.
つぎに実施例をあげて本発明を説明する。Next, the present invention will be explained with reference to Examples.
［実施例］
実施例１
厚さ３．５ｇｍのポリエステルフィルム上にパラフィン
ワックス９部、およびケトン樹脂１部をトルエン７０部
、テレピン油１０部および石油ナフサ１０部からなる混
合溶剤に溶解して成るコーティング溶液を塗布、乾燥し
て厚さ０．５μｍの離型剤層を形成し、次いてその面」
二にスチレンマレイン酸樹脂２５部、およびカーポンプ
ラフクン２０部をメチルイソブチルケトン４５部および
シクロへキサ７２１０部からなる混合溶剤に溶解して成
るコーティング溶液を塗布、乾燥して厚さ１．５４の非
流動性インク層を形成し、その上にクロームを真空蒸着
法て６０部ｍの厚さに蒸着し、更にその上にパラフィン
ワックス８０部およびエチレン−酢酸ビニル共重合樹脂
１０部をテレピン油１０部に溶解してなるコーティング
溶液を塗布、乾燥して厚さ１．５ｇｍの接着剤層を形成
して本発明の黒色用感熱転写媒体を得た。[Example] Example 1 9 parts of paraffin wax and 1 part of ketone resin were dissolved in a mixed solvent consisting of 70 parts of toluene, 10 parts of turpentine oil and 10 parts of petroleum naphtha on a polyester film having a thickness of 3.5 gm. A coating solution is applied and dried to form a release agent layer with a thickness of 0.5 μm, and then the surface is coated.
Second, a coating solution made by dissolving 25 parts of styrene-maleic acid resin and 20 parts of carpon flake in a mixed solvent consisting of 45 parts of methyl isobutyl ketone and 7210 parts of cyclohexane is applied and dried to a thickness of 1.54 mm. A non-fluid ink layer is formed, and chromium is deposited on it to a thickness of 60 parts by vacuum deposition, and then 80 parts of paraffin wax and 10 parts of ethylene-vinyl acetate copolymer resin are added on top of it using turpentine oil. A coating solution prepared by dissolving 10 parts was applied and dried to form an adhesive layer with a thickness of 1.5 gm to obtain a black thermal transfer medium of the present invention.
実施例２
厚さ６１のポリエステルフィルム上にアクリル樹脂２０
部、塩化ゴム１０部、赤色顔料２０部をトルエン３０部
、メチルイソブチルケトン１０部およびシクロへキサ７
２１０部とからなる混合溶剤に溶解して成るコーチイン
ク溶液を塗布、乾燥して厚さ２ ｐ、ｍの非流動性イン
ク層を形成し、その上にアルミニウムを真空蒸着法て４
０部ｍの厚さに蒸着し、さらにその上にポリアミド樹脂
１０部およびカルナバワックス１．０部をトルエン７０
部、イソプロピルアルコール１０部とからなる混合溶剤
に溶解してなるコーチインタ溶液を塗布、乾燥して厚さ
１．５μｌの接着剤層を形成して本発明の赤色用感熱転
写媒体を得た。Example 2 Acrylic resin 20 mm on a 61 mm thick polyester film
parts, 10 parts of chlorinated rubber, 20 parts of red pigment, 30 parts of toluene, 10 parts of methyl isobutyl ketone and 7 parts of cyclohexane.
A coach ink solution prepared by dissolving in a mixed solvent consisting of 210 parts was coated and dried to form a non-fluid ink layer with a thickness of 2 pm and 2 pm, and aluminum was deposited on top of it by vacuum evaporation.
10 parts of polyamide resin and 1.0 part of carnauba wax were deposited on top of 70 parts of toluene.
A coachinter solution prepared by dissolving in a mixed solvent consisting of 1.5 parts and 10 parts of isopropyl alcohol was coated and dried to form an adhesive layer with a thickness of 1.5 μl to obtain a red heat-sensitive transfer medium of the present invention.
［発明の効果］
実施例１および実施例２て得られた感熱転写媒体を用い
てラフ紙に熱転写プリンタ キャノンＣ−４２５３（キ
ャノン株式会社製）で印字した。[Effects of the Invention] The thermal transfer media obtained in Examples 1 and 2 were used to print on rough paper using a thermal transfer printer Canon C-4253 (manufactured by Canon Co., Ltd.).
得られたラフ紙上の文字画像はそれぞれ黒色、赤色の極
めて美れいかつ繊細なものであった。The obtained character images on the rough paper were extremely beautiful and delicate in black and red, respectively.
第１図は本願発明の感熱転写媒体の基本構成を示す断面
図である。
（図面の符号）
（１）二ベースフィルム
（２）：ＩＩＩ型剤層
（３）：非流動性インク層
（４）：金属薄着層
（５）：接着剤層FIG. 1 is a sectional view showing the basic structure of the thermal transfer medium of the present invention. (Numbers in drawings) (1) Two-base film (2): Type III agent layer (3): Non-flowable ink layer (4): Thin metal layer (5): Adhesive layer
Claims (1)
、少なくとも非流動性インク層、金属蒸着層、接着剤層
を順次形成したことを特徴とする感熱転写媒体。1. A heat-sensitive transfer medium characterized in that at least a non-fluid ink layer, a metal vapor deposition layer, and an adhesive layer are sequentially formed on a base film either directly or via a release agent layer.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61238748A JP2637403B2 (en) | 1986-10-07 | 1986-10-07 | Thermal transfer media |
| EP19870114547 EP0263478B1 (en) | 1986-10-07 | 1987-10-06 | Heat-sensitive transfer medium |
| DE8787114547T DE3784431T2 (en) | 1986-10-07 | 1987-10-06 | HEAT SENSITIVE TRANSFER. |
| US07/105,283 US4875961A (en) | 1986-10-07 | 1987-10-07 | Heat-sensitive transfer medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61238748A JP2637403B2 (en) | 1986-10-07 | 1986-10-07 | Thermal transfer media |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6392492A true JPS6392492A (en) | 1988-04-22 |
| JP2637403B2 JP2637403B2 (en) | 1997-08-06 |
Family
ID=17034670
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61238748A Expired - Fee Related JP2637403B2 (en) | 1986-10-07 | 1986-10-07 | Thermal transfer media |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2637403B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6398490A (en) * | 1986-10-14 | 1988-04-28 | Oike Ind Co Ltd | Thermal transfer medium |
| JPH02162095A (en) * | 1988-12-16 | 1990-06-21 | Oike Ind Co Ltd | Thermal transfer medium |
| JPH06199059A (en) * | 1993-01-05 | 1994-07-19 | Dainichiseika Color & Chem Mfg Co Ltd | Heat-sensitive transfer recording sheet |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6362785A (en) * | 1986-09-04 | 1988-03-19 | Oike Ind Co Ltd | Matte thermal transfer medium |
-
1986
- 1986-10-07 JP JP61238748A patent/JP2637403B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6362785A (en) * | 1986-09-04 | 1988-03-19 | Oike Ind Co Ltd | Matte thermal transfer medium |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6398490A (en) * | 1986-10-14 | 1988-04-28 | Oike Ind Co Ltd | Thermal transfer medium |
| JPH02162095A (en) * | 1988-12-16 | 1990-06-21 | Oike Ind Co Ltd | Thermal transfer medium |
| JPH06199059A (en) * | 1993-01-05 | 1994-07-19 | Dainichiseika Color & Chem Mfg Co Ltd | Heat-sensitive transfer recording sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2637403B2 (en) | 1997-08-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |