JPS6385080A - Method of composting water filtration sludge - Google Patents

Method of composting water filtration sludge

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Publication number
JPS6385080A
JPS6385080A JP61225851A JP22585186A JPS6385080A JP S6385080 A JPS6385080 A JP S6385080A JP 61225851 A JP61225851 A JP 61225851A JP 22585186 A JP22585186 A JP 22585186A JP S6385080 A JPS6385080 A JP S6385080A
Authority
JP
Japan
Prior art keywords
sludge
fermentation
purified water
aid
dehydration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP61225851A
Other languages
Japanese (ja)
Other versions
JPH0717470B2 (en
Inventor
川崎 精雄
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP61225851A priority Critical patent/JPH0717470B2/en
Publication of JPS6385080A publication Critical patent/JPS6385080A/en
Publication of JPH0717470B2 publication Critical patent/JPH0717470B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Treatment Of Sludge (AREA)
  • Fertilizers (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、浄水場の濃縮汚泥から一次発酵品を連続的に
堆肥化する方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for continuously composting a primary fermentation product from concentrated sludge of a water purification plant.

〔従来の技術〕[Conventional technology]

浄水場の濃縮脱水汚泥は従来大部分が埋立用土等に供さ
れ、一部は土壌改良材として利用されてはいるが、堆肥
化までの加工をしている例は見当らない。
Conventionally, most of the concentrated dehydrated sludge from water treatment plants has been used as landfill soil, and some of it has been used as a soil improvement material, but there are no examples of it being processed to the point of composting.

一般に浄水場の脱水汚泥は大部分が無機物であり、有機
物の含有量が30重量%以下と低いので発酵し難い上、
含有する有機物がアオコ、珪藻類などの藻類を主として
いるのでこれを分解し堆肥化するのは困難であると言わ
れている。
In general, dehydrated sludge from water treatment plants is mostly inorganic, with a low organic content of less than 30% by weight, which makes it difficult to ferment.
It is said that it is difficult to decompose and compost the organic matter contained mainly in algae such as blue-green algae and diatoms.

しかし浄水場の脱水汚泥を堆肥化することができれば廃
食源の有効利用の面で好ましいことである。
However, if dehydrated sludge from water treatment plants could be composted, it would be preferable in terms of effective use of waste food sources.

有機性物質を発酵させて乾燥肥料化する方法として、発
酵物を種として発酵原料に移植してバッチ式に発酵させ
る方法(特開昭54−138183)、都市塵芥等の廃
棄物からの被処理堆肥物の10〜20%を発酵槽に残し
てバッチで操作する方法(#開開54−135156)
などが知られているが、バッチ式の方法では能率が悪く
、安価な製造ができない、また炭素/窒素の重量比C/
Nが10未満または20を越える有機物に易発酵性有機
物を添加して発酵させる方法(特開昭58−12059
5)が知られているが、この技術は浄化槽の余剰汚泥、
脱水汚泥、もみがら、樹皮、稲わら等の発酵に適用され
、浄水汚泥には適用できない。
As a method of fermenting organic substances and turning them into dry fertilizer, there is a method of batch fermentation by transplanting the fermented material as seeds to fermentation raw materials (Japanese Patent Application Laid-open No. 54-138183), and a method of converting waste such as urban garbage into processed materials. A method of batch operation with 10-20% of the compost remaining in the fermenter (#Kaikai54-135156)
However, batch-type methods are inefficient and cannot be produced at low cost, and the carbon/nitrogen weight ratio C/
Method of fermenting by adding easily fermentable organic matter to organic matter with N less than 10 or more than 20 (Japanese Patent Application Laid-Open No. 58-12059
5) is known, but this technology is used to remove excess sludge from septic tanks,
Applicable to fermentation of dehydrated sludge, rice husks, bark, rice straw, etc., and cannot be applied to purified water sludge.

また、浄水汚泥は水分が多いので脱水した上で堆肥化す
る必要があるが、し尿処理場または下水処理場から発生
する多量の有機物を含む汚泥を脱水する場合に、高分子
凝集剤をカチオン性とアニオン性の二液を用いて汚泥を
脱水し、脱水後他の有機物を添加せずに堆肥化する方法
(特開昭57−135790)が開示されている。浄水
汚泥は易発酵有機物が少ないのでこの方法を適用して堆
肥化することはできない。
In addition, since purified water sludge has a high water content, it needs to be dehydrated before being composted. However, when dewatering sludge containing large amounts of organic matter generated from human waste treatment plants or sewage treatment plants, it is necessary to use a cationic polymer flocculant. A method (Japanese Unexamined Patent Publication No. 57-135790) has been disclosed in which sludge is dehydrated using two anionic liquids and composted without adding other organic substances after dehydration. Purified water sludge cannot be composted using this method because it has little organic matter that is easily fermentable.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

本発明は、浄水汚泥を対象として、これを連続的に能率
よく堆肥化する方法を提供しようとするもので次の問題
を克服しなければならない。
The present invention aims to provide a method for continuously and efficiently composting purified water sludge, and the following problems must be overcome.

1)浄水汚泥を脱水助剤を用いてさらに脱水する必要が
あり、この脱水助剤は脱水濾液および堆肥中に残存して
も無害でなければならない。
1) It is necessary to further dewater the purified water sludge using a dewatering aid, and this dewatering aid must be harmless even if it remains in the dewatering filtrate and compost.

2)浄水汚泥は発酵しにくいので発酵を促進させる必要
がある。発酵中の一部の汚泥の上に新しい汚泥を載せる
ことによってこの問題の解決を図る。
2) Since purified water sludge is difficult to ferment, it is necessary to promote fermentation. This problem is solved by placing fresh sludge on top of some of the sludge that is being fermented.

3)有機物含有量が少ないので助剤を加え高温を得て発
酵させ、かつ殺菌する。
3) Since the organic matter content is low, auxiliary agents are added to obtain high temperature for fermentation and sterilization.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は浄水汚泥に天然系高分子脱水助剤を加えて反応
槽で攪拌した後脱水し、該脱水汚泥に発酵助剤を添加し
て混和し、該混和物を連続発酵槽中の一部の既発酵汚泥
上に供給し順次移送しつつ好気発酵させることを特徴と
する浄水汚泥の堆肥化方法である。
In the present invention, a natural polymer dehydration aid is added to purified water sludge, the mixture is stirred in a reaction tank and then dehydrated, a fermentation aid is added and mixed with the dehydrated sludge, and a portion of the mixture is transferred to a continuous fermentation tank. This is a method for composting purified water sludge, which is characterized by supplying the sludge onto fermented sludge and carrying out aerobic fermentation while sequentially transferring the sludge.

〔作用〕[Effect]

本発明のフローシートを第1図に示した。 A flow sheet of the present invention is shown in FIG.

貯槽1に貯蔵されている浄水汚泥をポンプ2により反応
槽5に送り、溶解槽3で水に溶解した天然系高分子脱水
助剤をポンプ4で反応槽5に送り、ここでこれらを十分
混合反応させ、その反応物を脱水機7に送って脱水する
。脱水機7から出た脱水汚泥9を混和機8に送り、発酵
助剤10を加え、また発酵ずみ製品17の一部を加えて
混和する。この混和物をベルトコンベア12により発酵
槽13に送る0発酵槽13には攪拌と移送のための攪拌
羽根を備え、モータ14により適時駆動する。一方発酵
槽には空気管15を介して空気を吹き込み好気発酵させ
、排気は排気管16から排出する。発酵槽内を移送され
た汚泥は発酵し、約7日で発酵槽から製品17として排
出される。
The purified water sludge stored in the storage tank 1 is sent to the reaction tank 5 by the pump 2, and the natural polymer dehydration aid dissolved in water in the dissolution tank 3 is sent to the reaction tank 5 by the pump 4, where they are thoroughly mixed. The reaction product is sent to a dehydrator 7 for dehydration. The dehydrated sludge 9 discharged from the dehydrator 7 is sent to the mixer 8, where a fermentation aid 10 is added and a portion of the fermented product 17 is added and mixed. The fermenter 13 which sends this mixture to the fermenter 13 by a belt conveyor 12 is equipped with stirring blades for stirring and transfer, and is driven by a motor 14 at appropriate times. On the other hand, air is blown into the fermentation tank through an air pipe 15 to effect aerobic fermentation, and exhaust gas is discharged through an exhaust pipe 16. The sludge transferred through the fermenter is fermented and discharged from the fermenter as a product 17 in about 7 days.

本発明はまず浄水場の濃縮汚泥に、天然高分子凝集剤(
キトサン)を用いて脱水する。すなわち凝集剤として、
キトサン(0,2%液)の適当量を注入して凝集させ脱
水する。この場合、脱水機の種類は問わない。
The present invention first uses a natural polymer flocculant (
dehydrate using chitosan). In other words, as a flocculant,
An appropriate amount of chitosan (0.2% liquid) is injected to cause coagulation and dehydration. In this case, the type of dehydrator does not matter.

前述の特開昭57−135790のように二液を用いて
脱水効率を上げる方法もあるが、本発明では、堆肥化の
前に、含水率の調整を行うので、含水率が高くても余り
問題はない、キトサンは無害であり、土中でも分解が早
く堆肥化に適している。
There is a method of increasing dehydration efficiency using two liquids as in the above-mentioned Japanese Patent Application Laid-Open No. 57-135790, but in the present invention, the moisture content is adjusted before composting, so even if the moisture content is high, there is no excess water content. No problem, chitosan is harmless, decomposes quickly in soil, and is suitable for composting.

本発明に用いる天然系高分子脱水助剤であるキトサンは
キチンのN−説アセチル化物であって、カニの甲皮等か
ら抽出した天然の高分子である。
Chitosan, which is a natural polymer dehydration aid used in the present invention, is an N-acetylated product of chitin, and is a natural polymer extracted from crab carapace and the like.

生産量の80%は水処理やねり製品加工場で廃棄される
タンパク質回収の凝集剤(1,500〜2.000円/
kg)として使用されている。水処理で凝集剤として使
用する場合、合成高分子凝集剤と比較したとき、 (1)土壌中での分解性試験でco2の発生量では、合
成高分子はむしろ発生の抑制傾向があるが、キトサンは
著しくGO2発生量が増大し、大きな分解率を示した。
80% of the production volume is made up of flocculants for protein recovery (1,500 to 2,000 yen /
kg). When used as a flocculant in water treatment, when compared with synthetic polymer flocculants, (1) Synthetic polymers tend to suppress CO2 generation in soil degradability tests; Chitosan significantly increased the amount of GO2 generated and showed a large decomposition rate.

(2)活性汚泥にて比較したとき、合成高分子に対し1
0倍以上、可溶性澱粉に対しても2倍以上の速さで分解
された。
(2) When compared with activated sludge, 1 for synthetic polymers
It was degraded more than 0 times faster than soluble starch, and more than twice as fast as soluble starch.

という結果が得られている。The result was obtained.

キトサンは製品用途として、土壌改良剤、有害微生物防
除、肥料、農薬等に用いられる。
Chitosan is used as a soil conditioner, harmful microorganism control agent, fertilizer, pesticide, etc.

脱水汚泥の含水率に応じて、水分調整材として製品の還
流を行い、混和機で混和する。
Depending on the moisture content of the dehydrated sludge, the product is refluxed as a moisture adjustment agent and mixed with a mixer.

浄水汚泥中の有機物含有量が少ないとき(一般に有機分
が40%以上でないと発酵しにくい)発酵はしにくい。
Fermentation is difficult when the organic matter content in purified water sludge is low (generally, fermentation is difficult unless the organic content is 40% or more).

浄水汚泥は一般に有機分の含有量が30%以下と低いの
で、93酵を容易に進行させるため他の有機分高含有の
材料として発酵助剤(鶏ふん等)を添加して、発酵させ
る。その結果、取り扱い易く、減菌されて浄水汚泥堆肥
を得る。
Since purified water sludge generally has a low organic content of 30% or less, in order to facilitate the progress of 93 fermentation, fermentation aids (chicken manure, etc.) are added as other materials with high organic content and fermentation is carried out. As a result, purified water sludge compost is obtained which is easy to handle and sterilized.

発酵助剤として他の有機質材料を添加することは、肥効
成分も増し、土壌改良材として付加価値が上がる。
Adding other organic materials as fermentation aids increases the fertilizing components and increases added value as a soil improvement material.

横軸固定型の発酵槽内で、発酵中の汚泥を第3図のよう
に移送し、その適当量(通常は10〜30%でよい)を
残しその上に新しい汚泥を投入することにより、発酵時
間を早める。
In a fermenter with a fixed horizontal shaft, the sludge undergoing fermentation is transferred as shown in Figure 3, leaving an appropriate amount (usually 10 to 30%) and adding new sludge on top. Speed up fermentation time.

以上の方法で堆肥化を実施することにより、無害で、取
り扱い易い浄水堆肥を得ることができる。一般的に行わ
れている脱水後、乾燥、造粒等の操作は省略でき、発酵
させて堆肥化するので。
By carrying out composting using the above method, purified water compost that is harmless and easy to handle can be obtained. The commonly performed operations such as dehydration, drying, and granulation can be omitted, and the material is fermented and composted.

畑土、水田に使用しても全く無害である。It is completely harmless even when used on field soil or paddy fields.

〔実施例〕〔Example〕

印旙沼浄水場の浄水汚泥を用いて第1図に示すフローに
より浄水汚泥の堆肥化を行った。実施例に用いた装置の
仕様は次の通りである。
Using purified water sludge from the Insanuma water treatment plant, the purified water sludge was composted according to the flow shown in Figure 1. The specifications of the device used in the examples are as follows.

浄水汚泥貯槽:容量5m’ 脱水助剤溶解槽:容量0.2 m’ 反応槽:容量0.5 m’ 攪拌機0.1kwスターラー 脱水fi:ミニ波布式フィルタプ レス@1,200mm 濾布速度2.1〜8.5 m / m i n圧縮圧力
1〜2kg/crrr’ 混和機:パドルニーダ2.2 k w 発酵1fj : 700 mmWX 800 mmWX
2,100mmL 空気吹込室4室構成 パドルホイール:f、5kw 1〜10 r、p、m  間欠運転 汚泥の性状、脱水助剤、発酵助剤の性状は次の通りであ
る。
Purified water sludge storage tank: Capacity 5 m' Dehydration aid dissolving tank: Capacity 0.2 m' Reaction tank: Capacity 0.5 m' Stirrer 0.1 kW Stirrer dehydration fi: Mini wave cloth type filter press @ 1,200 mm Filter cloth speed 2. 1-8.5 m/min Compression pressure 1-2 kg/crrr' Mixing machine: Paddle kneader 2.2 kW Fermentation 1fj: 700 mmWX 800 mmWX
2,100 mmL Paddle wheel with 4 air blowing chambers: f, 5 kW 1 to 10 r, p, m Intermittent operation The properties of the sludge, dehydration aid, and fermentation aid are as follows.

汚泥濃度二固形分2.8% 汚泥中の固形成分:無機固形分74重着%有機物26重
量% 脱水助剤:キトサン(0,2%溶液) 発酵助剤:乾燥部ふん 混合比17重量% (浄水汚泥中の固形分/鶏ふん=571)まず浄水汚泥
の凝集脱水試験についてへりオス脱水機を用いて、合成
ポリマー(カチオン)との比較試験を実施した。
Sludge concentration: solid content 2.8% Solid components in sludge: inorganic solid content 74% organic matter 26% by weight Dehydration aid: chitosan (0.2% solution) Fermentation aid: drying part feces mixing ratio 17% by weight (Solid content in purified water sludge/chicken droppings = 571) First, a comparison test with a synthetic polymer (cation) was conducted using a Helios dehydrator for a coagulation dehydration test of purified water sludge.

第1表に天然高分子キトサンと合成高分子との脱水比較
実験の結果を示す。注入量、汚泥の含水率とも全く差が
なくキトサンの効果が実証されている。
Table 1 shows the results of a comparative dehydration experiment between the natural polymer chitosan and the synthetic polymer. There was no difference in the amount of injection or the water content of the sludge, demonstrating the effectiveness of chitosan.

またセキスイRF型脱水機で、連続、凝集、脱水、コン
ポスト化実験を実施し、同様の効果を確認している。
We also conducted continuous, agglomeration, dehydration, and composting experiments using the Sekisui RF dehydrator, and confirmed similar effects.

第3図は発酵助剤として、乾燥鶏ふんを混合して発酵槽
で連続発酵実験したときの例を示すもので、発酵槽の原
料投入側(第1室)の底部近傍側壁から測定した発酵槽
内の測定温度変化である。
Figure 3 shows an example of a continuous fermentation experiment in a fermenter with dry chicken manure mixed as a fermentation aid. Measure the temperature change within.

第3図中に矢印で投入時期を示しているように毎日原料
投入し、1日に2〜3回槽内容物を前進移動させ、7〜
8日目に発酵槽から排出する。第3図の温度変化から明
らかなように最初の投入から10で発酵を開始して60
℃に達し、2日日以降は発酵が早く十分な温度が得られ
ている。
Input the raw materials every day as indicated by the arrows in Figure 3, and move the contents of the tank forward two to three times a day.
Drain the fermenter on the 8th day. As is clear from the temperature change in Figure 3, fermentation started at 10 minutes after the first addition and started at 60 minutes.
℃, and after the 2nd day, fermentation started quickly and a sufficient temperature was obtained.

次に比較のために、第4図に浄水脱水汚泥(有機物26
重量%)を単独で発酵実験した例を示した。発酵槽、投
入量、温度測定位置等は第3図の場合と同様である。汚
泥は、有機物含有量が少なく、その質も藻類が主である
ことから、高温(60℃以上)の発酵は得られなかった
。しかし、中温までの発酵は2日目以降早くなっており
、前日の投入物が種堆肥として作用する効果は認められ
た。
Next, for comparison, Figure 4 shows purified water dewatered sludge (organic matter 26
An example was shown in which a fermentation experiment was carried out using only 5% by weight). The fermenter, input amount, temperature measurement position, etc. are the same as in the case of FIG. 3. Since the sludge has a low organic matter content and is mainly composed of algae, fermentation at high temperatures (60° C. or higher) could not be achieved. However, fermentation to medium temperature became faster after the second day, and the effect of the input from the previous day acting as seed compost was recognized.

なお、有機成分が十分に含まれている浄水汚泥では発酵
助剤を加えないでも発酵させることができることは論を
俟たない。
It goes without saying that purified water sludge containing sufficient organic components can be fermented without adding a fermentation aid.

次に鶏ふんの混合率を変化した場合に本発明方法によっ
て得られる製品の肥効成分について実測した結果を第2
表に示す。鶏ふん混合率が0%(汚泥のみ)の場合に対
して、肥料として有効な肥効3成分がほぼ鶏ふん混合率
に比例して増加しており、好適な堆肥を得ることができ
る。
Next, the results of actual measurement of the fertilizing components of the product obtained by the method of the present invention when the mixing ratio of chicken manure was changed are shown in the second table.
Shown in the table. Compared to the case where the chicken manure mixing ratio is 0% (sludge only), the three components effective as fertilizer increase almost in proportion to the chicken manure mixing ratio, making it possible to obtain a suitable compost.

〔発明の効果〕〔Effect of the invention〕

本発明は次の優れた効果を奏する。 The present invention has the following excellent effects.

(イ) 本発明方法により、従来堆肥化することが困難
であった浄水汚泥を安価容易に連続的に堆肥化し有効利
用することができるようになった。
(a) By the method of the present invention, purified water sludge, which has conventionally been difficult to compost, can be continuously composted and effectively utilized at low cost and easily.

(ロ) 脱水時の助剤として用いる天然高分子脱水助剤
キトサンは、濾液および堆肥中に残存しても無害である
(b) Chitosan, a natural polymer dehydration aid used as an aid during dehydration, is harmless even if it remains in the filtrate and compost.

(ハ) 発酵中の一部の汚泥の上に、新しい汚泥をのせ
ることで、発酵を早くすることができる。
(c) Fermentation can be accelerated by placing new sludge on top of some of the sludge that is currently fermenting.

(ニ) 発酵助剤(鶏ふん等)を加えることで高温を得
て減菌すると共に肥効成分を増加させることができる。
(d) By adding fermentation aids (chicken manure, etc.), it is possible to obtain high temperatures, sterilize bacteria, and increase fertilizing ingredients.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例のフローシート、第2図は発酵
槽内の発酵汚泥の移送状況を説明する説明図、第3図は
実施例の温度推移を示すグラフ。 第4図は比較例の温度推移を示すグラフである。 5・・・反応槽 7・・・脱水機 8・・・混和機 13・・・発酵槽
FIG. 1 is a flow sheet of an example of the present invention, FIG. 2 is an explanatory diagram illustrating the transfer status of fermented sludge in a fermenter, and FIG. 3 is a graph showing temperature changes in the example. FIG. 4 is a graph showing the temperature transition of the comparative example. 5... Reaction tank 7... Dehydrator 8... Mixer 13... Fermentation tank

Claims (1)

【特許請求の範囲】[Claims] 1 浄水汚泥に天然系高分子脱水助剤を加えて攪拌した
後脱水し、該脱水汚泥に発酵助剤を添加して混和し、該
混和物を既に発酵中の汚泥上に供給し、順次移送しつつ
好気発酵させることを特徴とする浄水汚泥の堆肥化方法
1. A natural polymer dehydration aid is added to purified water sludge, stirred and then dehydrated, a fermentation aid is added to the dehydrated sludge and mixed, the mixture is supplied onto the sludge that is already undergoing fermentation, and transferred sequentially. A method for composting purified water sludge, which is characterized by aerobic fermentation.
JP61225851A 1986-09-26 1986-09-26 Composting method of purified water sludge Expired - Lifetime JPH0717470B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61225851A JPH0717470B2 (en) 1986-09-26 1986-09-26 Composting method of purified water sludge

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61225851A JPH0717470B2 (en) 1986-09-26 1986-09-26 Composting method of purified water sludge

Publications (2)

Publication Number Publication Date
JPS6385080A true JPS6385080A (en) 1988-04-15
JPH0717470B2 JPH0717470B2 (en) 1995-03-01

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
JP61225851A Expired - Lifetime JPH0717470B2 (en) 1986-09-26 1986-09-26 Composting method of purified water sludge

Country Status (1)

Country Link
JP (1) JPH0717470B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07223886A (en) * 1994-02-08 1995-08-22 Motomiyamachi Compost aging promoter, compost and production of compost
JP2002017158A (en) * 2000-06-30 2002-01-22 Sumitomo Forestry Co Ltd Material for plant-growing medium

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07223886A (en) * 1994-02-08 1995-08-22 Motomiyamachi Compost aging promoter, compost and production of compost
JP2002017158A (en) * 2000-06-30 2002-01-22 Sumitomo Forestry Co Ltd Material for plant-growing medium
JP4532683B2 (en) * 2000-06-30 2010-08-25 住友林業株式会社 Plant growth medium materials

Also Published As

Publication number Publication date
JPH0717470B2 (en) 1995-03-01

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