JPS638273A - Method of joining ceramic member to metal member - Google Patents

Method of joining ceramic member to metal member

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Publication number
JPS638273A
JPS638273A JP15068486A JP15068486A JPS638273A JP S638273 A JPS638273 A JP S638273A JP 15068486 A JP15068486 A JP 15068486A JP 15068486 A JP15068486 A JP 15068486A JP S638273 A JPS638273 A JP S638273A
Authority
JP
Japan
Prior art keywords
metal member
metal
ceramic member
joining
ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15068486A
Other languages
Japanese (ja)
Inventor
真治 大坪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NGK Insulators Ltd
Original Assignee
NGK Insulators Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NGK Insulators Ltd filed Critical NGK Insulators Ltd
Priority to JP15068486A priority Critical patent/JPS638273A/en
Publication of JPS638273A publication Critical patent/JPS638273A/en
Pending legal-status Critical Current

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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明はセラミックス部材と金属部材の結合方法に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method of joining a ceramic member and a metal member.

(従来の技術) 従来、セラミックスと金属とを焼ばめにより結合する場
合は、筒状金属部材を加熱膨張させ、その状態の筒状金
属部材に常温又は冷却した軸状セラミックス部材を嵌込
み、冷却することにより、両部材間に強固な結合を得て
いた。
(Prior art) Conventionally, when joining ceramics and metal by shrink fitting, a cylindrical metal member is heated and expanded, and a shaft-shaped ceramic member at room temperature or cooled is fitted into the cylindrical metal member in that state. By cooling, a strong bond was obtained between the two members.

(発明が解決しようとする問題点) しかしながら、上述した従来の焼ばめ方法では、高温高
圧にさらされる例えばエンジン部材として使用した場合
、セラミックスと金属との結合能は、締め何カの緩みか
ら、表面の凹凸よりガスがリークしたり、不均一な接触
状態によるクラックの発生などの欠点があった。また、
接合前の両部材の加工状態によって焼ばめ後の締め何カ
がばらつくため、10μm以下の加工寸法精度が必要と
なりその加工が難しい欠点もあった。
(Problems to be Solved by the Invention) However, in the conventional shrink fitting method described above, when used as an engine member exposed to high temperature and pressure, the bonding ability between ceramic and metal is limited due to loosening of the tightening parts. However, there were drawbacks such as gas leakage due to surface irregularities and cracks occurring due to uneven contact conditions. Also,
Since the amount of tightening after shrink fitting varies depending on the processing conditions of both members before joining, a processing dimensional accuracy of 10 μm or less is required, which also has the drawback of being difficult to process.

本発明の目的は上述した不具合を解消して、高温高圧下
で使用してもその結合おからガスがIJ−りせず、ろう
材の厚みを適度に与えることにょって、両部材接触部の
ひずみ応力や捩じり応力の集中を緩和させることができ
、また結合前の高い加工寸法精度を要求しないセラミッ
クス部材と金属部材の結合方法を提供しようとするもの
である。
The purpose of the present invention is to eliminate the above-mentioned problems, prevent the combined okara gas from leaking even when used under high temperature and high pressure, and provide an appropriate thickness to the brazing material to provide a contact area between both parts. The purpose of the present invention is to provide a method for joining ceramic members and metal members that can alleviate the concentration of strain stress and torsional stress of the ceramic member and does not require high processing dimensional accuracy before joining.

(問題点を解決するための手段) 本発明のセラミックス部材と金属部材の結合方法は金属
部材を該金属部材より熱膨張係数が小さいセラミックス
部材の外側に配置し、加熱下で両者間に所定の隙間を生
じせしめた状態で、該隙間中に溶融したろう材を浸透さ
せた後、冷却固化することを特徴とする。
(Means for Solving the Problems) The method of joining a ceramic member and a metal member of the present invention is to arrange the metal member outside the ceramic member whose coefficient of thermal expansion is smaller than that of the metal member, and to create a predetermined gap between the two under heating. The method is characterized in that a molten brazing filler metal is infiltrated into the gap with a gap formed therein, and then cooled and solidified.

(作 用) 上述した構成において、金属部材をこれより熱膨張係数
が小さいセラミックス部材の外側に配置した後、両者の
結合部上端にろう材を設置する。
(Function) In the above-described configuration, after the metal member is placed outside the ceramic member whose coefficient of thermal expansion is smaller than that of the metal member, a brazing material is placed at the upper end of the joint between the metal member and the ceramic member.

そして両者をろう材の融点以上の温度で加熱することに
より両者間に隙間が生じ、この隙間に溶融したろう材が
浸透するのである。その後、両部材を冷却固化すると前
記セラミックス部材と金属部材はろう材を介して外側の
金属部材が内側のセラミックス部材を締めつける、いわ
ゆる焼ばめ的効果を発して強固に結合されることとなる
。本発明の結合方法により得た結合体を高温高圧下にさ
らしても両部材間のろう材がクッションとなり、均一に
密着して接触しているため、ガスがリークすることなく
ひずみ応力や捩じり応力を緩和し、結合前の両部材の加
工寸法精度をそれほど厳しく管理しなくても結合後の締
め付方のばらつきをなくすことができる。
By heating both to a temperature higher than the melting point of the brazing material, a gap is created between the two, and the molten brazing material penetrates into this gap. Thereafter, when both members are cooled and solidified, the ceramic member and the metal member are firmly joined by the outer metal member tightening the inner ceramic member through the brazing filler metal, producing a so-called shrink fit effect. Even when the bonded body obtained by the bonding method of the present invention is exposed to high temperature and high pressure, the brazing material between the two members acts as a cushion and they are in even and close contact, so there is no strain stress or torsion without gas leakage. This makes it possible to reduce the stress caused by the process and eliminate variations in the tightening method after joining without having to control the machining dimensional accuracy of both members so strictly before joining.

さらに図面に基づいて本発明の詳細な説明する。Further, the present invention will be explained in detail based on the drawings.

第1図(a) 、 (b) 、 (C)は、本発明を用
いる前のセラミックス部材と金属部材の状態を示し、第
1図(d)。
FIGS. 1(a), (b), and (C) show the state of the ceramic member and the metal member before using the present invention, and FIG. 1(d) shows the state of the ceramic member and the metal member before using the present invention.

(e)、 (f)はそれぞれ第1図(a)、ら)、(C
)に本発明を適用した場合の状態を示している。以下、
順次説明する。まず、軸状セラミックス部材1と筒状金
属部材2とを、第1図(a)に示すように隙間をあけた
状態、第1図b)に示すようにはめ合った状態または第
1図(C)に示すようにあらかじめ焼ばめて結合力を持
たせた状態に組込む。次に、軸状セラミックス部材1と
筒状金属部材2の結合部上端にろう材3を設置し、組込
んだ両部材を、使用するろう材3の融点以上、好ましく
は融点より50〜100℃高いろう対温度で加熱する。
(e) and (f) are Fig. 1 (a), et al.) and (C), respectively.
) shows the state when the present invention is applied. below,
I will explain them one by one. First, the shaft-shaped ceramic member 1 and the cylindrical metal member 2 are placed in a state with a gap as shown in FIG. 1(a), in a fitted state as shown in FIG. As shown in C), it is assembled in a state in which it is shrink-fitted in advance to give it bonding strength. Next, a brazing material 3 is installed at the upper end of the joint between the shaft-shaped ceramic member 1 and the cylindrical metal member 2, and both assembled members are heated at a temperature higher than the melting point of the brazing material 3 to be used, preferably 50 to 100 degrees Celsius above the melting point. Heat at high wax temperature.

これにより、軸状セラミックス部材1と筒状金属部材2
との間に第1図(a)に示す場合はさらに広い隙間をま
た第1図ら)および第1図(C)に示す場合は隙間を生
じさせることにより、軸状セラミックス部材1と筒状金
属部材2との結合部上端のろう付設置部に設けたろう材
3が溶融してこれらの隙間に侵入する。その後結合体を
冷却すると、軸状セラミックス部材1と筒状金属部材2
とはろう材3を介した状態で焼ばめ結合的効果を発し結
合が完了する。
As a result, the shaft-shaped ceramic member 1 and the cylindrical metal member 2
By creating a wider gap in the case shown in FIG. 1(a) and a gap in the case shown in FIG. 1(C) between the shaft-shaped ceramic member 1 and the cylindrical metal The brazing material 3 provided at the brazing installation portion at the upper end of the joint with the member 2 melts and enters these gaps. After that, when the combined body is cooled, the shaft-shaped ceramic member 1 and the cylindrical metal member 2
With the brazing filler metal 3 interposed therebetween, a shrink fit-like bonding effect is produced and the bonding is completed.

第2図は第1図(b)のセラミックス部材と金属部材と
を、はめ合せた状態で両部材を加熱した時の加熱温度と
両部材の径の変化を示す図である。第2図かられかるよ
うに、輪状セラミックス部材の外径および筒状金属部材
の内径が等しい組付品を、使用するろう材の融点以上ま
で加熱後、冷却していくと、ろう材の融点T℃において
溶融して、両部材の隙間に侵入していたろう材が凝固し
て介在したまま収縮し、常温では締め代がdの状態で結
合が完了する。
FIG. 2 is a diagram showing changes in heating temperature and diameter of the ceramic member and metal member of FIG. 1(b) when both members are heated in a fitted state. As shown in Figure 2, when an assembled product in which the outer diameter of the ring-shaped ceramic member and the inner diameter of the cylindrical metal member are equal is heated to a temperature above the melting point of the brazing filler metal used and then cooled, the melting point of the brazing filler metal The brazing material melts at T° C., and the brazing material that has entered the gap between the two members solidifies and contracts while remaining therebetween. At room temperature, the joining is completed with an interference margin of d.

なお、本発明のセラミックス部材と金属部材間に加熱下
で生じせしめる隙間は通常の焼ばめ技術で設定する焼ば
め代に相当するものであるが、セラミックス部材と金属
部材を配置する時に予め両者の間に隙間を与えた場合は
、これが付加されることとなる。本発明の結合方法を実
施するうえで使用するセラミックス部材、金属部材とし
ては、セラミックス部材と金属部材との熱膨張係数が等
しくない限り熱膨張係数の大きい金属部材を外側に、熱
膨張係数の小さい方のセラミックス部材を内側に用いれ
ば、どのようなものでも使用できる。
Note that the gap created under heating between the ceramic member and the metal member of the present invention corresponds to the shrink fit allowance set by normal shrink fit technology, but If a gap is provided between the two, this will be added. As for the ceramic members and metal members used in carrying out the bonding method of the present invention, unless the coefficients of thermal expansion of the ceramic member and the metal member are equal, the metal member with the larger coefficient of thermal expansion is placed on the outside, and the metal member with the smaller coefficient of thermal expansion is placed on the outside. Any ceramic member can be used as long as it is used on the inside.

特に高温高圧にさらされるシリンダー、ピストン、ホッ
トプレート、バルブ等のエンジン部材に本発明方法で得
られた結合体を使用する場合は、セラミックス部材とし
てはSi3N、、 SiC,2r02.  サイアロン
のいずれかを、金属部材としては炭素鋼、ステンレス鋼
、ニッケル合金鋼、クロム鋼等を、またろう材としては
JIS Z 3261に示される銀ろうを使用すると好
適である。
In particular, when using the composite obtained by the method of the present invention for engine parts such as cylinders, pistons, hot plates, and valves that are exposed to high temperature and high pressure, the ceramic parts may be Si3N, SiC, 2r02. It is preferable to use any one of Sialon, carbon steel, stainless steel, nickel alloy steel, chrome steel, etc. as the metal member, and silver solder shown in JIS Z 3261 as the brazing material.

(実施例) 第3図および第4図は本発明の結合方法の実施例を示す
断面図である。
(Example) FIGS. 3 and 4 are cross-sectional views showing an example of the joining method of the present invention.

第3図に示す実施例では、第3図(a)に結合前の状態
を示したように軸状セラミックス部材11を、筒状金属
部材12に組込み後、結合部上端にろう材13を設置し
、加熱によって生じる隙間に毛細管現象によってろう材
13を侵入させ、第3図(b)に示す結合後の組付品を
得る方法を示している。
In the embodiment shown in FIG. 3, after the shaft-shaped ceramic member 11 is assembled into the cylindrical metal member 12 as shown in the state before joining in FIG. 3(a), a brazing material 13 is installed at the upper end of the joint. A method is shown in which the brazing filler metal 13 is allowed to enter the gap created by heating by capillary action to obtain the assembled product shown in FIG. 3(b).

第4図に示す実施例では、第4図(a)に結合前の状態
を示したように軸状セラミックス部材14と、あらかじ
め内部にろう材13を設置したスリーブ部16をもつ金
属軸17を同時に加熱して、ろう材13を溶融させた後
、機成的にスリーブ部16に軸状セラミックス部材14
を挿入し、第4図(b)に示す結合後の組付品を得る方
法を示している。
In the embodiment shown in FIG. 4, as shown in FIG. 4(a) before joining, a shaft-shaped ceramic member 14 and a metal shaft 17 having a sleeve portion 16 in which a brazing material 13 is installed in advance are used. After simultaneously heating and melting the brazing filler metal 13, the shaft-shaped ceramic member 14 is mechanically attached to the sleeve portion 16.
4(b) to obtain the assembled product shown in FIG. 4(b).

第5図〜第9図は本発明の結合法の別の実施例を示す断
面図である。
5 to 9 are cross-sectional views showing other embodiments of the bonding method of the present invention.

第5図に示す実施例では、軸状セラミックス部材11と
筒状金属部材12にそれぞれ段部を設けた構造により、
結合強度を高めることができる。
In the embodiment shown in FIG. 5, the shaft-shaped ceramic member 11 and the cylindrical metal member 12 each have a stepped portion, so that
Bond strength can be increased.

第6図に示す実施例では、軸状セラミックス部材11と
、筒状金属部材12にスリット部18を設け、このスリ
ット部18にもろう材13を満たすことにより結合強度
を高めることができる。
In the embodiment shown in FIG. 6, a slit portion 18 is provided in the shaft-shaped ceramic member 11 and the cylindrical metal member 12, and the slit portion 18 is filled with the brazing material 13, thereby increasing the bonding strength.

第7図に示す実施例では、軸状セラミックス部材11に
おネジを、筒状金属部材12にめネジを切り、組付は部
にろう材13を侵入させて、結合することにより、従来
以上に結合強度、シール性を高めることができる。
In the embodiment shown in FIG. 7, a screw is cut into the shaft-shaped ceramic member 11 and a female thread is cut into the cylindrical metal member 12, and the assembly is performed by inserting a brazing material 13 into the parts and joining them. The bonding strength and sealing performance can be increased.

第8図に示す実施例では、軸状セラミックス部材14の
軸端にテーパ一部15を設け、これを金属軸17のスリ
ーブ部16に挿入してろう材13を介して結合すること
により結合強度を高めることができる。
In the embodiment shown in FIG. 8, a tapered portion 15 is provided at the shaft end of the shaft-shaped ceramic member 14, and this is inserted into the sleeve portion 16 of the metal shaft 17 and bonded via the brazing material 13, thereby increasing the bonding strength. can be increased.

第9図に示す実施例では軸状セラミックス部材14の軸
端に段部19を設け、これを金属軸17のスリーブ部1
6に挿入して結合することにより結合強度を高めること
ができる。
In the embodiment shown in FIG. 9, a stepped portion 19 is provided at the shaft end of the shaft-shaped ceramic member 14, and this
By inserting and bonding into 6, the bonding strength can be increased.

第10図は本発明の結合方法をターボチャージ丁ロータ
に応用した例を示す断面図である。本実施例では、セラ
ミックス部材としてのセラミックロータ20の凸部21
を、金属軸22の凹B23とろう材24を介して結合し
ている。すなわち、予め作製したセラミックロータ20
の凸部21を、予め金属軸22の凹部23に一体に組込
んだ後、ろう材24を両部材の結合部に設け、ろう材の
融点より高い所定の温度に加熱することによりセラミッ
ククーボチャージャロータを得ている。
FIG. 10 is a sectional view showing an example in which the coupling method of the present invention is applied to a turbocharged rotor. In this embodiment, a convex portion 21 of a ceramic rotor 20 as a ceramic member is used.
are connected to the recess B23 of the metal shaft 22 via a brazing material 24. That is, the ceramic rotor 20 prepared in advance
After the convex part 21 of the metal shaft 22 is integrated into the concave part 23 of the metal shaft 22 in advance, a brazing material 24 is provided at the joining part of both parts and heated to a predetermined temperature higher than the melting point of the brazing material. You're getting a rotor.

なお、上述した本発明の結合方法によるターボチャージ
ャローフのセラミックス部材と金属部材の結合状態は、
従来のろうはを介在させないでセラミックス部材と金属
部材とを焼ばめで結合したものと比べて優れていた。
Note that the state of bonding between the ceramic member and the metal member of the turbocharger loaf by the above-described bonding method of the present invention is as follows:
This was superior to the conventional method in which a ceramic member and a metal member were joined by shrink fit without intervening a solder.

本発明は上述した実施例にのみ限定されるものではなく
、幾多の変形、変更が可能である。例えば、本実施例で
はセラミックス部材と金属部材との結合について説明し
たが、熱膨張の異なる部材を結合する場合すべてに本発
明の結合方法を応用できることはいうまでもない。
The present invention is not limited only to the embodiments described above, and numerous modifications and changes are possible. For example, although this embodiment describes the bonding of a ceramic member and a metal member, it goes without saying that the bonding method of the present invention can be applied to all cases in which members having different thermal expansions are bonded.

(発明の効果) 以上詳細に説明したところから明らかなように、本発明
のセラミックス部材と金属部材の結合方法によれば、結
合時にセラミックス部材と金属部材との間にろう材を介
して焼ばめ的効果をもたしているため、高温高圧下で結
合体を使用しても、その結合部からガスがリークしなく
なるとともに、ろう材の厚みを適度に与えることによっ
て、両部材接触部のひずみ応力や捩じり応力の集中を緩
和させることができる。又、結合前の両部材の加工寸法
精度をそれほど厳しく管理しなくても結合後の締約付力
のばらつきをなくすことができ、特別の装置を用いるこ
となく市販のろう材が使えるので、安価なコストで容易
に製作できる。本発明はセラミックローター、タービン
ブレード、ノズル等のガスタービン部品、セラミックシ
リンダー、ピストン、ホットプレート、バルブ等のエン
ジン部品等の製造法として利用でき産業上極めて有用な
方法である。
(Effects of the Invention) As is clear from the above detailed explanation, according to the method of joining a ceramic member and a metal member of the present invention, a brazing material is inserted between the ceramic member and the metal member during joining. As a result, gas will not leak from the joint even when the joint is used under high temperature and high pressure, and by giving the brazing filler metal an appropriate thickness, the contact area between the two parts will be reduced. Concentration of strain stress and torsional stress can be alleviated. In addition, it is possible to eliminate variations in the tightening force after joining without having to strictly control the machining dimensional accuracy of both parts before joining, and because commercially available brazing filler metal can be used without using special equipment, it is an inexpensive method. Easy to manufacture at low cost. The present invention is an industrially extremely useful method that can be used as a method for manufacturing gas turbine parts such as ceramic rotors, turbine blades, and nozzles, and engine parts such as ceramic cylinders, pistons, hot plates, and valves.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(a)〜(f)は、それぞれ本発明を用いる前お
よび用いた後の各部材の組付状態の一例を示す図、第2
図は第1図(b)の場合のセラミックス部材および金属
部材の温度と径の変化との関係を示す図、第3図(a)
、(b)および第4図(a)、(b)はそれぞれ本発明
のセラミックスと金属の結合構造を示す断面図、 第5図〜第9図は、それぞれ結合部の種々の形状例を示
す断面図、 第10図は本発明の結合方法をターボチャージャロータ
に応用した例を示す断面図である。 1、 11.14・・・軸状セラミックス部材2.12
・・・円筒状金属部材 3、13.24・・・ろう材   15・・・テーパ一
部16・・・スリーブ部    17.22・・・金属
軸18・・・スリット部    19・・・段部20・
・・セラミックロータ 21・・・凸部23・・・凹部 第1図 (a)    (b)    (C) (d)    (e)    (f) 第3図 (a)       (b) 第4図 (a−″(b) 第5図     第6図 第7図 第8図   第9図 第川図
FIGS. 1(a) to 1(f) are diagrams showing an example of the assembled state of each member before and after using the present invention, respectively, and FIG.
The figure shows the relationship between the temperature and diameter change of the ceramic member and the metal member in the case of Fig. 1(b), and Fig. 3(a).
, (b) and FIGS. 4(a) and (b) are sectional views showing the bonding structure of ceramics and metal of the present invention, respectively. FIGS. 5 to 9 each show examples of various shapes of the bonding part. Cross-sectional view FIG. 10 is a cross-sectional view showing an example in which the coupling method of the present invention is applied to a turbocharger rotor. 1, 11.14...Shaft-shaped ceramic member 2.12
... Cylindrical metal member 3, 13.24... Brazing metal 15... Taper part 16... Sleeve part 17.22... Metal shaft 18... Slit part 19... Step part 20・
...Ceramic rotor 21... Convex portion 23... Concave portion Fig. 1 (a) (b) (C) (d) (e) (f) Fig. 3 (a) (b) Fig. 4 (a) -''(b) Figure 5 Figure 6 Figure 7 Figure 8 Figure 9 River diagram

Claims (1)

【特許請求の範囲】 1、金属部材を該金属部材より熱膨張係数が小さいセラ
ミックス部材の外側に配置し、加熱下で両者間に所定の
隙間を生じせしめた状態で、該隙間中に溶融したろう材
を浸透させた後、冷却固化することを特徴とするセラミ
ックス部材と金属部材の結合方法。 2、前記ろう材が銀ろうである特許請求の範囲第1項記
載のセラミックス部材と金属部材の結合方法。 3、前記セラミックス原料がSi_3N_4、SiC、
ZrO_2、サイアロンのいずれかよりなる特許請求の
範囲第1項記載のセラミックス部材と金属部材の結合方
法。
[Claims] 1. A metal member is placed outside a ceramic member whose coefficient of thermal expansion is smaller than that of the metal member, and a predetermined gap is created between the two under heating, and the metal member is melted in the gap. A method for joining a ceramic member and a metal member, which comprises infiltrating a brazing material and then cooling and solidifying it. 2. The method of joining a ceramic member and a metal member according to claim 1, wherein the brazing material is silver solder. 3. The ceramic raw material is Si_3N_4, SiC,
A method for joining a ceramic member and a metal member according to claim 1, which are made of either ZrO_2 or Sialon.
JP15068486A 1986-06-28 1986-06-28 Method of joining ceramic member to metal member Pending JPS638273A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15068486A JPS638273A (en) 1986-06-28 1986-06-28 Method of joining ceramic member to metal member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15068486A JPS638273A (en) 1986-06-28 1986-06-28 Method of joining ceramic member to metal member

Publications (1)

Publication Number Publication Date
JPS638273A true JPS638273A (en) 1988-01-14

Family

ID=15502204

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15068486A Pending JPS638273A (en) 1986-06-28 1986-06-28 Method of joining ceramic member to metal member

Country Status (1)

Country Link
JP (1) JPS638273A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6390354B1 (en) 1998-02-18 2002-05-21 Ngk Insulators, Ltd. Adhesive composition for bonding different kinds of members
JP2011212577A (en) * 2010-03-31 2011-10-27 Ngk Insulators Ltd Honeycomb structure
WO2024105190A1 (en) * 2022-11-17 2024-05-23 Vitesco Technologies GmbH Device for heating an exhaust gas flow with a tolerance compensation

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6390354B1 (en) 1998-02-18 2002-05-21 Ngk Insulators, Ltd. Adhesive composition for bonding different kinds of members
US6742700B2 (en) 1998-02-18 2004-06-01 Ngk Insulators, Ltd. Adhesive composition for bonding different kinds of members
JP2011212577A (en) * 2010-03-31 2011-10-27 Ngk Insulators Ltd Honeycomb structure
WO2024105190A1 (en) * 2022-11-17 2024-05-23 Vitesco Technologies GmbH Device for heating an exhaust gas flow with a tolerance compensation

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