JPS6381766A - Manufacture of paste type cadmium anode for alkaline storage battery - Google Patents
Manufacture of paste type cadmium anode for alkaline storage batteryInfo
- Publication number
- JPS6381766A JPS6381766A JP61227770A JP22777086A JPS6381766A JP S6381766 A JPS6381766 A JP S6381766A JP 61227770 A JP61227770 A JP 61227770A JP 22777086 A JP22777086 A JP 22777086A JP S6381766 A JPS6381766 A JP S6381766A
- Authority
- JP
- Japan
- Prior art keywords
- cadmium
- active material
- polyamide fibers
- electrode plate
- current density
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052793 cadmium Inorganic materials 0.000 title claims abstract description 33
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- 239000011149 active material Substances 0.000 claims abstract description 19
- 239000004952 Polyamide Substances 0.000 claims abstract description 13
- 229920002647 polyamide Polymers 0.000 claims abstract description 13
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 11
- 239000000835 fiber Substances 0.000 claims abstract description 11
- 229910052751 metal Inorganic materials 0.000 claims abstract description 7
- 239000002184 metal Substances 0.000 claims abstract description 7
- 239000012779 reinforcing material Substances 0.000 claims abstract description 7
- CXKCTMHTOKXKQT-UHFFFAOYSA-N cadmium oxide Inorganic materials [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 claims abstract description 6
- CFEAAQFZALKQPA-UHFFFAOYSA-N cadmium(2+);oxygen(2-) Chemical compound [O-2].[Cd+2] CFEAAQFZALKQPA-UHFFFAOYSA-N 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000001661 cadmium Chemical class 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 abstract description 5
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 abstract 4
- 239000007789 gas Substances 0.000 description 9
- 206010040844 Skin exfoliation Diseases 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- XIEPJMXMMWZAAV-UHFFFAOYSA-N cadmium nitrate Inorganic materials [Cd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XIEPJMXMMWZAAV-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- NMHMNPHRMNGLLB-UHFFFAOYSA-N phloretic acid Chemical compound OC(=O)CCC1=CC=C(O)C=C1 NMHMNPHRMNGLLB-UHFFFAOYSA-N 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 1
- PLLZRTNVEXYBNA-UHFFFAOYSA-L cadmium hydroxide Chemical compound [OH-].[OH-].[Cd+2] PLLZRTNVEXYBNA-UHFFFAOYSA-L 0.000 description 1
- OJIJEKBXJYRIBZ-UHFFFAOYSA-N cadmium nickel Chemical compound [Ni].[Cd] OJIJEKBXJYRIBZ-UHFFFAOYSA-N 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/26—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
Description
【発明の詳細な説明】
（イ）産業上の利用分野
本発明はニッケルーカドミウム電池などのアルカリ蓄電
池に用いられるペースト式カドミウム陰極の製法に関す
るものである。DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application The present invention relates to a method for producing a paste-type cadmium cathode used in alkaline storage batteries such as nickel-cadmium batteries.
（ロ）従来の技術
一般的なアルカリ蓄′４池用ペースト式カドミウム陰極
は特開昭５１−６３１号公報に開示された如く、活物質
として酸化カドミウムと水酸化カドミウム、結着剤とし
てポリテトラプルオロエチレン？用い水き加えペースト
状とし、このペースト金電極芯体に塗着、乾燥するもの
であり、焼結式カドミウム陰極に比べる七、製造工程が
筒車であり、廉価でカドミウム陰ｉｆ全得ることができ
る。(b) Prior art A paste-type cadmium cathode for a general alkaline storage battery uses cadmium oxide and cadmium hydroxide as active materials and polytetra as a binder, as disclosed in JP-A No. 51-631. Pluoroethylene? The paste is made into a paste by adding water, and this paste is applied to a gold electrode core and dried.Compared to a sintered cadmium cathode, the manufacturing process is an hour wheel, and it is possible to obtain a complete cadmium negative electrode at a low cost. can.
しかしながらペースト式カドミウム陰極は、焼結式カド
ミウム陰極に比べると活物質の導電性が低いため過充電
時に陽極から発生する酸素ガスの吸収能力が低く、密閉
型電池にペースト式カドミウム陰極を用いると、内部ガ
ス圧が上昇し易いという欠点があっな。However, paste-type cadmium cathodes have lower conductivity of the active material than sintered-type cadmium cathodes, and therefore have a lower ability to absorb oxygen gas generated from the anode during overcharging. The drawback is that the internal gas pressure tends to rise.
一方、特開昭５８−８０２６８号公報において、補強材
としてポリアミドｆＩ！、維を用いることにより化成工
程が不要で酸素ガス吸収能力が優れたペースト式カドミ
ウム陰極が得られることが提案されているが、このカド
ミウム陰極においては酸素ガス吸収能力が向上するか、
焼結式カドミウム陰極や化成処理を施したペースト式カ
ドミウム陰極に比べると、やはり活物質の４電性は低く
内部ガス圧が上昇し易いという間原点がある。On the other hand, in JP-A-58-80268, polyamide fI! is used as a reinforcing material. It has been proposed that by using .
Compared to a sintered cadmium cathode or a paste-type cadmium cathode that has been subjected to chemical conversion treatment, the active material has a lower tetraelectricity and the internal gas pressure tends to increase.
これらの問題点を解決する九めに、特開昭５７−７０６
４９公報！’Ｉペ一スト式カドミウム陰極を化成処理す
ることが開示されている。ここで化成処理金施すことに
よって金属カドミウムがカドミウム陰極中に生成し、電
池内で発生した酸素ガスを吸収しやすくなるが、一方ペ
ースト式製法により得られた電極はカドミウム活物質の
保持力が弱いので、製造工程を高速化し大量生産を可能
にするという要求を満たすためにけ化成電流密度を２０
０〜５００ｍＡ／ｃｍ程度に設定する必要があり、この
ような条件で化成処理を行うと、芯体から発生する水素
ガスが急激に増加し、この応力により極板芯体とカドミ
ウム活物質との密着性が低下し、剥離しやすいという傾
向があっ九、（ハ）発明が解決しようとする問題点
本発明は前記間桓点に鑑みなされたものであって、その
意図とするところは、２００〜５００ｍ Ａ ／ ｃ
ｍ のような大電流密度で陰電解しても、極板の剥離
現象が生じにくいペースト式カドミウム陰極の製法を提
供することにある。As a ninth step to solve these problems,
49 bulletin! It has been disclosed to chemically treat a 'I-paste cadmium cathode. By applying chemical conversion treatment, metallic cadmium is generated in the cadmium cathode, making it easier to absorb oxygen gas generated within the battery, but on the other hand, electrodes obtained using the paste method have a weak retention force for the cadmium active material. Therefore, in order to meet the demands of speeding up the manufacturing process and enabling mass production, the chemical current density was increased to 20%.
It is necessary to set it to about 0 to 500 mA/cm, and if chemical conversion treatment is performed under such conditions, hydrogen gas generated from the core will rapidly increase, and this stress will cause the bond between the electrode plate core and the cadmium active material to increase. (c) Problems to be Solved by the Invention The present invention has been made in view of the above-mentioned problems, and its intention is to ~500m A/c
It is an object of the present invention to provide a method for producing a paste-type cadmium cathode that does not easily cause peeling of the electrode plates even when subjected to negative electrolysis at a high current density such as m2.
に）問題点を解決する九めの手段
本発明のアルカリ蓄電池用ペースト式カドミウム陰極の
製法は、酸化カドミウム全主体とする活物質と、補強材
としてのポリアミド繊ａｋ含むペーストｔ−櫃板芯体に
充填した後、１６０〜２００℃で加熱し、次いでカドミ
ウム塩水溶液中で２００〜５００ｍＡ／ｃｍ の電流
密度で陰電解して、表面に金属カドミウムを析出させる
ことを要旨とするものである。Ninth Means for Solving the Problem The method for manufacturing the paste-type cadmium cathode for alkaline storage batteries of the present invention consists of an active material consisting entirely of cadmium oxide and a paste T-shaped plate core containing polyamide fiber ak as a reinforcing material. The gist of the method is to deposit metal cadmium on the surface by heating at 160 to 200° C. and then electrolyzing it negatively at a current density of 200 to 500 mA/cm 2 in an aqueous cadmium salt solution.
（刺作 用
密閉型アルカリ蓄電池において、充電時に陽極から発生
した酸素ガス汀次に示す反応で消費される。(In a sealed alkaline storage battery for stimulation, oxygen gas generated from the anode during charging is consumed in the following reaction.
Ｃｄ ＋−０２＋Ｈ２０→Ｃｄ（ＯＨ）！このガス吸収
反応は特に陰極表面の金属カドミウムでおこるものであ
り、本発明製法によればカドミウム塩水溶液中でカドミ
ウム陰極全階電解しているので陰極表面全体に金属カド
ミウムが存在し、ガス吸収反応が容易に進行する。Cd +-02+H20→Cd(OH)! This gas absorption reaction occurs particularly in the metal cadmium on the cathode surface, and according to the production method of the present invention, cadmium cathode full-scale electrolysis is performed in a cadmium salt aqueous solution, so metal cadmium is present on the entire cathode surface, and the gas absorption reaction occurs. progresses easily.
また、補強材としてのポリアミド＊ａが混入されている
ので、カドミウム陰極ｔ１６０〜２００℃で加熱処理の
後２００〜５００ｍＡ／ｃｍ のハイレートで陰極電
解を行った場合、この加熱処理においてポリアミド繊維
の表層部か溶融し、ポリアミド繊維同志が結着し活物質
全保持するマ）９ツクスｒ構成する結果、活物質の保持
が強力となり活物質の保持が十分に行なわれるので極板
における活物質の剥離という問題全解消でき、製造工程
の高速化か計れ量産化が可能となる。In addition, since polyamide*a is mixed as a reinforcing material, when cathodic electrolysis is performed at a high rate of 200 to 500 mA/cm after heat treatment at a cadmium cathode t of 160 to 200°C, the surface layer of the polyamide fibers is As a result of the structure, the retention of the active material is strong and the active material is sufficiently retained, so that the active material is not peeled off at the electrode plate. This problem can be completely solved, and the manufacturing process can be sped up and mass production can be achieved.
尚、加熱温度が１６０℃よりも低いとポリアミド繊維が
溶融しないので効果がなく、一方２００℃よりも高いと
ポリアミド喰維が溶融分解してしまい活物質が脱落する
ので好ましくない。It should be noted that if the heating temperature is lower than 160°C, the polyamide fibers will not melt, so there is no effect, while if it is higher than 200°C, the polyamide fibers will melt and decompose and the active material will fall off, which is not preferable.
（へ）実施例
イ枦ｊ
実験Ａ１゜
生活物質としての酸化カドミウム１０００ｔに、糊料剤
としてのヒドロキシ１０ビルセルロース６を及び５ａ６
！Ｉン酸ナトリウム水溶液３００ｍｌを加え、更に補強
材のポリアミド繊維として長さ約１．５ ｍｍ 、
太さ１〜２デニールの６−ナイロン繊１ａ １０ ｔｐ
を加えて十分に混練してペースト状とし、これをパン
チングメタルよりなる極板芯体に塗布、乾燥して厚さ０
．７ｍｍのカドミウム陰極板？得た。この陰極板を長さ
２ｏｏｍｍ、幅３３．５ｍｍの大きさに切断した。これ
金５０枚用意して５重量彊の硝酸カドミウム水溶液中で
５０．１００．１５０，２００，３００，５００，６０
０ｍＡ／ｃｍ の電流密度で１０分分間型解したとき
、活物質が剥離した極板の枚数を第１表に表す。(f) Example I Experiment A1゜To 1000 tons of cadmium oxide as a living material, hydroxy-10-vinyl cellulose 6 as a thickening agent and 5a6
! 300 ml of sodium phosphate aqueous solution was added, and polyamide fibers with a length of about 1.5 mm were added as reinforcing material.
6-nylon fiber 1a 10 tp with a thickness of 1 to 2 denier
is added and thoroughly kneaded to form a paste, which is applied to the electrode plate core made of punched metal and dried to a thickness of 0.
．． 7mm cadmium cathode plate? Obtained. This cathode plate was cut into a size of 2 oomm in length and 33.5 mm in width. Prepare 50 pieces of gold and put them in a cadmium nitrate aqueous solution with a weight of 50,100,150,200,300,500,60.
Table 1 shows the number of electrode plates from which the active material was peeled off when the mold was disassembled for 10 minutes at a current density of 0 mA/cm 2 .
第 １ 表
尚、ここで剥離とは目で見て活物質の一部が明らかに極
板芯体からはがれているとわかるものである。Table 1 Note that peeling here means that a part of the active material is clearly separated from the electrode plate core when visually observed.
これにより、電流密度が２００ｍＡ／ｃｍ より小さ
いとき発生する水素ガスが微量のため剥離の発生数はわ
ずかであるが、２００ｍＡ／ｃｍ をこえると急激に増
加する。また２００ｍＡ／ｃｍ２より小さい電流密度で
は工程に要する時間が長くなり、高速化に対応できなく
、５００ｍＡ／ｃＪより大きい電流密度ではカドミウム
の析出が均一になりにくい。したがって陰電解時の電流
密度は２００〜５００ ｍＡ／ｃｍ２である事が望まし
いが、前述したように剥離の発生という問題がある。As a result, when the current density is less than 200 mA/cm 2 , the amount of hydrogen gas generated is small and the number of peelings is small, but when the current density exceeds 200 mA/cm 2 , the number of peelings increases rapidly. Further, if the current density is less than 200 mA/cm2, the time required for the process becomes longer and it is not possible to cope with higher speeds, and if the current density is more than 500 mA/cJ, it is difficult for cadmium to be deposited uniformly. Therefore, it is desirable that the current density during negative electrolysis is 200 to 500 mA/cm2, but as mentioned above, there is a problem in that peeling occurs.
実験例２
実験例１と同様にして製作した２００ｍｍＸ３３．５ｍ
ｍの極板１１００，１６０．１８０，２００．２４０℃
で加熱したもの及び全く加熱しないもの全用い、５重電
％の硝酸カドミウム水溶液中で３００ｍＡ／ｃｍ２の電
流密度で１０分［」陰電解したとき、活物質が剥離した
極板の板数を第２表に示す。Experimental example 2 200mm x 33.5m manufactured in the same manner as experimental example 1
m electrode plate 1100, 160, 180, 200, 240℃
The number of electrode plates from which the active material was peeled off was measured when negative electrolysis was carried out for 10 minutes at a current density of 300 mA/cm2 in a 5% cadmium nitrate aqueous solution, both heated at It is shown in Table 2.
この結果より１６０℃以上で加熱処理を行ったものは３
００ｍＡ／ｃｍ”というハイレートであっても極板の剥
離が抑制されている。From this result, those that were heat treated at 160℃ or higher were 3
Even at a high rate of 00 mA/cm'', peeling of the electrode plates is suppressed.
尚、２００℃よりも高い温度で加熱したものは剥離が発
生しやすい傾向にあった。これけ６−ナイロン繊維が溶
融し、酸化されて分解し之ためであると考えられる。Incidentally, those heated at a temperature higher than 200° C. tended to peel off easily. This is thought to be because the 6-nylon fibers melt, oxidize, and decompose.
実施例１
実験例１で得た２ ００ｍｍＸ ３３．５ ｍｍのカド
ミウム陰極板を用い１８０℃で加熱処理を行った後、５
重量％硝酸カドミウム水溶液中で３００ｍＡ／ｃｍ の
電流密度にて陰電解し、本発明による陰極板を得、ニッ
グμ陽極板と組み合わせて公称容量１３００ｍＡＨの密
閉型カドミウム蓄電池Ａを得た。Example 1 The 200 mm x 33.5 mm cadmium cathode plate obtained in Experimental Example 1 was heat-treated at 180°C, and then
A cathode plate according to the present invention was obtained by negative electrolysis in a wt % aqueous cadmium nitrate solution at a current density of 300 mA/cm 2 , and in combination with a Nig μ anode plate, a sealed cadmium storage battery A with a nominal capacity of 1300 mAH was obtained.
比峻例
実験例１で得た２ ００ｍｍＸ３３．５ｍｍのカドミウ
ム陰極板をそのまま用い、実施例１と同様に電池２組み
立て比較電池Ｂを得た。Comparative Example Using the 200 mm x 33.5 mm cadmium cathode plate obtained in Experimental Example 1 as it was, Battery 2 was assembled in the same manner as in Example 1 to obtain Comparative Battery B.
これらの電池Ａ、Ｂを用いて０℃において１３０ｍＡで
連続充電を行なったときの充電時間と内部ガス圧との関
係を図に示した。The figure shows the relationship between charging time and internal gas pressure when batteries A and B were continuously charged at 130 mA at 0°C.
本発明電池Ａは比ｌｌｌ１２電池Ｂに比べ、内部ガス圧
が低く、優れたガス吸収性能を示しているのがわかる。It can be seen that the battery A of the present invention has a lower internal gas pressure and exhibits superior gas absorption performance compared to the comparison battery B.
（ト） 発明の効果
本発明のペースト式カドミウム陰極の製法によれば、ガ
ス吸収性能の擾れたカドミウム陰極が提供できると共に
、ハイレートで陰電解しても極板の剥離が発生しに＜＜
、電極製造工程の高速化が計れ、量産化が可能なるもの
であり、その工業的価値はきわめて大きい。(g) Effects of the Invention According to the method for producing a paste-type cadmium cathode of the present invention, a cadmium cathode with poor gas absorption performance can be provided, and peeling of the electrode plate does not occur even when catholytically electrolyzed at a high rate.
, the electrode manufacturing process can be sped up and mass production is possible, and its industrial value is extremely large.
図は電池の充電時間と内部ガス圧との関係を示す図であ
る。
Ａ・・・本発明電池、Ｂ・・・比較電池。The figure is a diagram showing the relationship between battery charging time and internal gas pressure. A: Battery of the present invention, B: Comparative battery.
Claims (1)
してのポリアミド繊維を含むペーストを極板芯体に充填
した後、１６０〜２００℃で加熱し、次いでカドミウム
塩水溶成中で２００〜５００ｍＡ／ｃｍ＾２の電流密度
で陰電解して、表面に金属カドミウムを析出させること
を特徴とするアルカリ蓄電池用ペースト式カドミウム陰
極の製法。(1) After filling the electrode plate core with a paste containing an active material mainly composed of cadmium oxide and polyamide fibers as a reinforcing material, it is heated at 160 to 200°C, and then heated at 200 to 500 mA in cadmium salt water dissolution. A method for producing a paste-type cadmium cathode for an alkaline storage battery, characterized by carrying out negative electrolysis at a current density of /cm^2 to deposit metal cadmium on the surface.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61227770A JPS6381766A (en) | 1986-09-25 | 1986-09-25 | Manufacture of paste type cadmium anode for alkaline storage battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61227770A JPS6381766A (en) | 1986-09-25 | 1986-09-25 | Manufacture of paste type cadmium anode for alkaline storage battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6381766A true JPS6381766A (en) | 1988-04-12 |
Family
ID=16866105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61227770A Pending JPS6381766A (en) | 1986-09-25 | 1986-09-25 | Manufacture of paste type cadmium anode for alkaline storage battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6381766A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1763097A1 (en) | 2005-09-09 | 2007-03-14 | Saft | Positive electrode for alkaline battery |
-
1986
- 1986-09-25 JP JP61227770A patent/JPS6381766A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1763097A1 (en) | 2005-09-09 | 2007-03-14 | Saft | Positive electrode for alkaline battery |
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