JPS6377955A - Rubber composition containing lame piece - Google Patents
Rubber composition containing lame pieceInfo
- Publication number
- JPS6377955A JPS6377955A JP22230486A JP22230486A JPS6377955A JP S6377955 A JPS6377955 A JP S6377955A JP 22230486 A JP22230486 A JP 22230486A JP 22230486 A JP22230486 A JP 22230486A JP S6377955 A JPS6377955 A JP S6377955A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- lame
- molding
- piece
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 36
- 239000005060 rubber Substances 0.000 title claims abstract description 36
- 239000000203 mixture Substances 0.000 title abstract description 9
- 238000000151 deposition Methods 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 4
- 239000002184 metal Substances 0.000 claims abstract description 4
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract description 6
- 229910052717 sulfur Inorganic materials 0.000 abstract description 6
- 239000011593 sulfur Substances 0.000 abstract description 6
- 235000021355 Stearic acid Nutrition 0.000 abstract description 5
- 239000012190 activator Substances 0.000 abstract description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 abstract description 5
- 239000008117 stearic acid Substances 0.000 abstract description 5
- 239000000945 filler Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 238000004898 kneading Methods 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 229910052709 silver Inorganic materials 0.000 abstract description 2
- 239000004332 silver Substances 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract 3
- 238000010068 moulding (rubber) Methods 0.000 abstract 2
- 229910000960 colored gold Inorganic materials 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- 235000014692 zinc oxide Nutrition 0.000 description 4
- 239000004927 clay Substances 0.000 description 3
- 238000009408 flooring Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 230000003712 anti-aging effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229920003052 natural elastomer Polymers 0.000 description 2
- 229920001194 natural rubber Polymers 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- OWRCNXZUPFZXOS-UHFFFAOYSA-N 1,3-diphenylguanidine Chemical compound C=1C=CC=CC=1NC(=N)NC1=CC=CC=C1 OWRCNXZUPFZXOS-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N Glycerol trioctadecanoate Natural products CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/0057—Producing floor coverings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
- B29L2031/3017—Floor coverings
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Floor Finish (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、板状の２ノ片１とゴムの混合物により構成さ
れ、ゴム床材やゴム履物に使用可能なゴム成型物に関す
る。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a rubber molded product that is composed of a mixture of two plate-shaped pieces 1 and rubber and can be used for rubber flooring and rubber footwear.
従来、ラメ片１を配合した成型物として、塩化ビニル等
の成型物は存在しているが、ラメ片１をゴムに配合した
ゴム成型物は現存せず、本発明でその製造方法を確立し
たものである。Conventionally, molded products such as vinyl chloride have existed as molded products containing glitter pieces 1, but there are currently no rubber molded products containing glitter pieces 1 mixed with rubber, and the present invention has established a method for producing the same. It is something.
本発明におけるラメ片１を配合したゴム成型物の特徴と
して、ゴム成型物の表面はラメ片１により凸状部分が形
成され、ゴム成型物表面にスパイク的な特性があられれ
、ゴム本末のノンスリップ性とあいまって非常に滑りに
くく、さらには外観的にもラメ片１がゴム中で光りを反
射しメタリック調の７７ツシ１ン性の高いゴム成型物を
提供するものである。The characteristics of the rubber molded product containing the glitter piece 1 in the present invention are that the surface of the rubber molded product has a convex portion formed by the glitter piece 1, and the surface of the rubber molded product has spike-like characteristics, and the rubber powder is non-slip. To provide a rubber molded product which is extremely slip-resistant in combination with its properties, and also has a metallic appearance in which the glitter pieces 1 reflect light in the rubber and have high durability.
本発明におけるラメ片１について説明すると、ラメ片１
は、ポリエステルシート表面に金属粉末を蒸着して構成
されており、形状としては厚さが０．０１〜０．１０ｍ
ｍ前後で、大きさが０．１〜１０−筒内の板状であり、
ラメ片１の色調は金、銀、赤、青、ａ等任意に選択可能
である。To explain the glitter piece 1 in the present invention, the glitter piece 1
is constructed by depositing metal powder on the surface of a polyester sheet, and its shape is 0.01 to 0.10 m thick.
It is plate-shaped in the cylinder, with a size of around 0.1 to 10 m.
The color tone of the glitter piece 1 can be arbitrarily selected from gold, silver, red, blue, a, etc.
次に本発明における製造工程についで説明すると、ラメ
片ｌをゴムｉｏｏｇｆ１部に対して０．０１〜３０重量
部最適には０．１〜５重量部配合し、その他硫黄、促進
剤、ステアリン酸、充填材、活性剤等を配合し、オープ
ンロール又は密閉式混練り機で混練りし、カレンダーロ
ールで一定の厚さにシーテイングし、ホットプレス又は
加硫缶で加硫成型する８
以下本発明における配合寅施例、物性値及び製造工程に
ついて、ゴム履物の底材の一実施例にっいて説明すると
、ラメ片１は０．５ｍｍ前後のものを３重量部使用して
おり、ゴム配合としては、ゴムに天然ゴム、スチレンブ
タジェンゴム、ポリブタノエンゴムの３種類を使用し、
ゴム１００重量部に対して、充填剤に軽質炭酸カルシウ
ム７０重量部とホワイトカーボン３０重量部、硫黄２．
０重量部、促進剤１．８重量部、亜鉛華５．０１！ｆ１
部、ステアリン酸２．０重ｆｉ部、活性剤１．５重量部
等を使用し、オープンロールで混合練りし、カレンダー
ロールにおいて２〜５１厚さでシーテイングと底意圧づ
けを行い、一定形状に裁断後、接着剤により胛被と貼り
合わせて、加硫缶において温度１２０℃前後で５０〜６
０分かけて加硫成型する。Next, to explain the manufacturing process in the present invention, 0.01 to 30 parts by weight of lame pieces L are blended with 1 part of rubber ioogf, optimally 0.1 to 5 parts by weight, and other ingredients such as sulfur, an accelerator, and stearic acid are added. , fillers, activators, etc. are mixed, kneaded in an open roll or closed kneader, sheeted to a certain thickness with a calendar roll, and vulcanized and molded in a hot press or vulcanizer. Regarding the compounding examples, physical properties, and manufacturing process, we will explain one example of the sole material for rubber footwear.The lame piece 1 uses 3 parts by weight of about 0.5 mm, and as a rubber compound. uses three types of rubber: natural rubber, styrene-butadiene rubber, and polybutanoene rubber.
For 100 parts by weight of rubber, fillers include 70 parts by weight of light calcium carbonate, 30 parts by weight of white carbon, and 2.0 parts by weight of sulfur.
0 parts by weight, 1.8 parts by weight of accelerator, 5.01 parts by weight of zinc white! f1
1.5 parts by weight, 2.0 parts by weight of stearic acid, 1.5 parts by weight of activator, etc., were mixed and kneaded with an open roll, and sheeted and bottom-pressed with a calender roll to a thickness of 2 to 51 parts to give a certain shape. After cutting into pieces, it is pasted on the cover with adhesive and heated to 50 to 60 degrees at a temperature of around 120℃ in a vulcanizer
Vulcanize and mold for 0 minutes.
（配合実施例１）
Ｒ８Ｓ＃３ ５０
ツルプレン１２０５ ３０
ＢＲ−１５０２０
硫 黄 ２促進剤ＤＭ
０．５
促進剤 Ｆ １．２
促進剤ＴＳ Ｏ，１
亜鉛華 ５
ステアリン酸 ２
軽質炭酸カルシウム ７〇
ニップシールＡＱ ３０
アクチングＳＬ １．５
ラ メ 片
３計 ２１５．３（註
）配合物質は、スチレンブタノエンゴムにはツルプレン
１２０５（旭化成（社））、ポリブタジェンにはＢＲ−
１５０（宇部興産（社））、促進剤にはＤＭ、Ｆ、ＴＳ
（大向新興化学（社））、ホワイトカーボンにはニップ
シールＡＱ（日本シリカ（社））、活性剤にはアクチン
グＳＬ（吉富製薬（社））、ラメ片には土橋金粉工業（
社）を使用している。(Formulation Example 1) R8S#3 50 Turprene 1205 30 BR-15020 Sulfur 2 Accelerator DM
0.5 Accelerator F 1.2 Accelerator TS O,1 Zinc white 5 Stearic acid 2 Light calcium carbonate 70 Nip Seal AQ 30 Acting SL 1.5 Lame piece
Total of 3 215.3 (Note) The compounded substances are Turprene 1205 (Asahi Kasei Corporation) for styrene-butanoene rubber and BR- for polybutadiene.
150 (Ube Industries, Ltd.), accelerators include DM, F, and TS.
(Omukai Shinko Kagaku Co., Ltd.), Nip Seal AQ (Nippon Silica Co., Ltd.) for the white carbon, Acting SL (Yoshitomi Pharmaceutical Co., Ltd.) for the activator, Tsuchibashi Kinpaku Kogyo Co., Ltd. (Co., Ltd.) for the glitter piece.
company) is used.
（物性値）
引張り強さくｋＨ／ａｍ２） −１２６伸 び（％）
〜 ５８０硬 度（ＪＩＳＡ）
〜 ６５次にゴム床材の一実施例について説明
すると、２メ片１は０ 、３ ｍｓ＋前後のものを０．
５重量部使用しており、ゴム配合としては、ゴムに天然
ゴム、スチレンブタノエンゴムの２種類を使用し、ゴム
１００重１１部に対して、充填剤に軽質炭酸カルシウム
１２０重量部、クレー６０＠ｆ１部、ホワイトカーボン
２０重量部、硫［２，５重量部、促進剤２゜ｏｍｕ部、
亜鉛華５．０重量部、ステアリンＷ１２゜０重量部、活
性剤２．０重量部、老化防止剤２．０重量部等を使用し
、密閉式の混練り機のニーグーで混合練りし、カレンダ
ーロールで３ｍｍ前後にシーテイングし一定形状に裁断
し、金型にａｌｆｒされたシートをセットし、ホットプ
レスにおいて温度１５０℃前後で時間１０〜２０分かけ
て加硫成型する。(Physical property values) Tensile strength kH/am2) -126 elongation (%)
~580 hardness (JISA)
~ 65 Next, an example of the rubber flooring material will be described.The two pieces 1 have a time of 0.3 ms+ or so.
The rubber composition uses two types of rubber, natural rubber and styrene-butanoene rubber, and 120 parts by weight of light calcium carbonate and clay as fillers for 100 parts by weight of rubber and 11 parts by weight. 60@f1 part, white carbon 20 parts by weight, sulfur [2.5 parts by weight, accelerator 2゜omu parts,
Using 5.0 parts by weight of zinc white, 12°0 parts by weight of stearin W, 2.0 parts by weight of an activator, 2.0 parts by weight of an anti-aging agent, etc., were mixed and kneaded in a closed-type kneading machine, and calendered. The sheet is sheeted to about 3 mm with a roll and cut into a certain shape, the alfred sheet is set in a mold, and the sheet is vulcanized and molded in a hot press at a temperature of about 150° C. for 10 to 20 minutes.
（配合実施例２）
Ｒ８Ｓ＃４ ６０
ＳＢＲＩ ５０７ ４０
硫 ｆ ２．５促進剤Ｄ
Ｍ １．２
促進剤Ｆ Ｏ０７
促進剤ＴＳ ０．１
亜鉛華 ５
ステアリン酸 ２
軽質炭酸カルシウム １２０
デキシークレー ６０
ニップシールＡＱ ２０
アクチングＳＬ ２
サンタイトＳ２
ラ メ 片
０．５計 ３１６
（註）配合物質は、スチレンブタジェンゴムには５ＢＲ
１５０７（日本合成ゴム（社））、クレーにはデキシー
クレー（バング−ビルト（社））、老化防止剤にはサン
タイ）Ｓ（精工化学（社））、その池配合薬品は配合実
施例１と同じである。(Formulation Example 2) R8S#4 60 SBRI 507 40 Sulfur f 2.5 Accelerator D
M 1.2 Accelerator F O07 Accelerator TS 0.1 Zinc white 5 Stearic acid 2 Light calcium carbonate 120 Dixie clay 60 Nip Seal AQ 20 Acting SL 2 Suntite S2 Lame piece
0.5 total 316 (Note) The compounded substance is 5BR for styrene butadiene rubber.
1507 (Japan Synthetic Rubber Co., Ltd.), the clay is Dixie Clay (Bang-Bilt Co., Ltd.), the anti-aging agent is Santai) S (Seiko Kagaku Co., Ltd.), and the pond compounded chemicals are Blend Example 1. It's the same.
（物性値）
引張り強さくｋｇ／ｃｍ”） −１１０伸 Ｖ（％
） 〜 ３５０硬 度（ＪＩＳＡ
） 〜 ７５以上本発明におけるゴム成型物
は、ゴム中にラメ片１を配合する事により、機能性と７
７ツシタン性をかねそなえた製品を提供するものである
。(Physical property values) Tensile strength kg/cm”) -110 elongation V (%
) ~ 350 hardness (JISA
) ~ 75 or more The rubber molded product of the present invention has functionality and 75 or more by blending glitter piece 1 into the rubber.
The purpose is to provide a product that has 7 durable properties.
第１図は、本発明におけるゴム床材の一実施例の斜視図
を示しており、第２図は、同図のａ−ｂ＃！１断面図を
示している。
１、ラメ片
２、ゴム配合物
特許出願人 日満ゴム工業株式会社
第１図
第２図FIG. 1 shows a perspective view of an embodiment of the rubber flooring material according to the present invention, and FIG. 2 shows a-b# of the same figure. 1 shows a sectional view. 1. Laminate piece 2. Rubber compound patent applicant Nichiman Rubber Industries Co., Ltd. Figure 1 Figure 2
Claims (1)
の板状のラメ片を、ゴム１００重量部に対して、０．０
１〜３０重量部最適には０．１〜５重量部配合してなる
ゴム成型物。A 0.1 to 10 mm square plate-shaped lame piece made by vapor-depositing metal on a thermoplastic resin is added to 100 parts by weight of rubber at a rate of 0.0
A rubber molded product containing 1 to 30 parts by weight, most preferably 0.1 to 5 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22230486A JPS6377955A (en) | 1986-09-20 | 1986-09-20 | Rubber composition containing lame piece |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22230486A JPS6377955A (en) | 1986-09-20 | 1986-09-20 | Rubber composition containing lame piece |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6377955A true JPS6377955A (en) | 1988-04-08 |
Family
ID=16780260
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22230486A Pending JPS6377955A (en) | 1986-09-20 | 1986-09-20 | Rubber composition containing lame piece |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6377955A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6709732B1 (en) | 1999-04-08 | 2004-03-23 | Firma Carl Freudenberg | Web-type floor covering and method for its manufacture |
| EP1679171A1 (en) * | 2005-01-10 | 2006-07-12 | Tarkett SAS | Homogenous surface covering |
-
1986
- 1986-09-20 JP JP22230486A patent/JPS6377955A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6709732B1 (en) | 1999-04-08 | 2004-03-23 | Firma Carl Freudenberg | Web-type floor covering and method for its manufacture |
| EP1679171A1 (en) * | 2005-01-10 | 2006-07-12 | Tarkett SAS | Homogenous surface covering |
| WO2006072638A1 (en) * | 2005-01-10 | 2006-07-13 | Tarkett Sas | Homogenous surface covering |
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