JPS636496B2 - - Google Patents

Info

Publication number: JPS636496B2
Authority: JP; Japan
Prior art keywords: manganous; permanganate; temperature; manganese dioxide; salt
Prior art date: 1983-09-30
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP20547284A

Other languages

English (en)

Japanese (ja)

Other versions

JPS6090827A (ja

Inventor

Fuooton Meraazu Jefurii

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

EBAREDEII BATSUTERII CO Inc

Original Assignee

EBAREDEII BATSUTERII CO Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1983-09-30

Filing date

1984-09-29

Publication date

1988-02-10

1984-09-29 Application filed by EBAREDEII BATSUTERII CO Inc filed Critical EBAREDEII BATSUTERII CO Inc

1985-05-22 Publication of JPS6090827A publication Critical patent/JPS6090827A/ja

1988-02-10 Publication of JPS636496B2 publication Critical patent/JPS636496B2/ja

Status Granted legal-status Critical Current

Links

NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 135
238000000034 method Methods 0.000 claims description 33
150000003839 salts Chemical class 0.000 claims description 27
229910052783 alkali metal Inorganic materials 0.000 claims description 17
150000001340 alkali metals Chemical class 0.000 claims description 17
238000010438 heat treatment Methods 0.000 claims description 17
239000000463 material Substances 0.000 claims description 15
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 12
229910002651 NO3 Inorganic materials 0.000 claims description 12
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 12
239000011572 manganese Substances 0.000 claims description 12
238000006243 chemical reaction Methods 0.000 claims description 8
150000001875 compounds Chemical class 0.000 claims description 8
239000000203 mixture Substances 0.000 claims description 8
OQUOOEBLAKQCOP-UHFFFAOYSA-N nitric acid;hexahydrate Chemical compound O.O.O.O.O.O.O[N+]([O-])=O OQUOOEBLAKQCOP-UHFFFAOYSA-N 0.000 claims description 8
229910002096 lithium permanganate Inorganic materials 0.000 claims description 6
229910052748 manganese Inorganic materials 0.000 claims description 6
239000012286 potassium permanganate Substances 0.000 claims description 6
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
229910021380 Manganese Chloride Inorganic materials 0.000 claims description 5
GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 claims description 5
235000002867 manganese chloride Nutrition 0.000 claims description 5
239000011565 manganese chloride Substances 0.000 claims description 5
MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims description 4
SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 4
XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 claims description 4
JYLNVJYYQQXNEK-UHFFFAOYSA-N 3-amino-2-(4-chlorophenyl)-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(CN)C1=CC=C(Cl)C=C1 JYLNVJYYQQXNEK-UHFFFAOYSA-N 0.000 claims description 2
239000007864 aqueous solution Substances 0.000 claims description 2
238000001816 cooling Methods 0.000 claims description 2
150000002696 manganese Chemical class 0.000 claims 2
YMKHJSXMVZVZNU-UHFFFAOYSA-N manganese(2+);dinitrate;hexahydrate Chemical group O.O.O.O.O.O.[Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YMKHJSXMVZVZNU-UHFFFAOYSA-N 0.000 claims 2
239000007789 gas Substances 0.000 description 16
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 15
239000001301 oxygen Substances 0.000 description 15
229910052760 oxygen Inorganic materials 0.000 description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
239000000047 product Substances 0.000 description 11
239000002994 raw material Substances 0.000 description 9
238000004519 manufacturing process Methods 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
238000002441 X-ray diffraction Methods 0.000 description 4
238000010521 absorption reaction Methods 0.000 description 4
229910052744 lithium Inorganic materials 0.000 description 4
229910017604 nitric acid Inorganic materials 0.000 description 4
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
230000002411 adverse Effects 0.000 description 2
238000013459 approach Methods 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
238000007872 degassing Methods 0.000 description 2
239000012153 distilled water Substances 0.000 description 2
239000003792 electrolyte Substances 0.000 description 2
239000002360 explosive Substances 0.000 description 2
239000011255 nonaqueous electrolyte Substances 0.000 description 2
150000002978 peroxides Chemical class 0.000 description 2
-1 polypropylene Polymers 0.000 description 2
239000000243 solution Substances 0.000 description 2
WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 1
AKUSZFPCJFNRSZ-UHFFFAOYSA-N 3,4-dimethyl-1,2-oxazole Chemical compound CC1=CON=C1C AKUSZFPCJFNRSZ-UHFFFAOYSA-N 0.000 description 1
VWIIJDNADIEEDB-UHFFFAOYSA-N 3-methyl-1,3-oxazolidin-2-one Chemical compound CN1CCOC1=O VWIIJDNADIEEDB-UHFFFAOYSA-N 0.000 description 1
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
238000004438 BET method Methods 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
229910014689 LiMnO Inorganic materials 0.000 description 1
229910016978 MnOx Inorganic materials 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
239000006230 acetylene black Substances 0.000 description 1
239000002253 acid Substances 0.000 description 1
239000003929 acidic solution Substances 0.000 description 1
229910001413 alkali metal ion Inorganic materials 0.000 description 1
239000000908 ammonium hydroxide Substances 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
244000309464 bull Species 0.000 description 1
239000010406 cathode material Substances 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
238000000921 elemental analysis Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
229910002804 graphite Inorganic materials 0.000 description 1
239000010439 graphite Substances 0.000 description 1
238000000227 grinding Methods 0.000 description 1
150000004687 hexahydrates Chemical class 0.000 description 1
229940099607 manganese chloride Drugs 0.000 description 1
150000002697 manganese compounds Chemical class 0.000 description 1
229940099596 manganese sulfate Drugs 0.000 description 1
235000007079 manganese sulphate Nutrition 0.000 description 1
239000011702 manganese sulphate Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002739 metals Chemical class 0.000 description 1
238000002156 mixing Methods 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
DOEGOCZXAAGGFN-UHFFFAOYSA-N nitric acid;tetrahydrate Chemical compound O.O.O.O.O[N+]([O-])=O DOEGOCZXAAGGFN-UHFFFAOYSA-N 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
238000005554 pickling Methods 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920001343 polytetrafluoroethylene Polymers 0.000 description 1
239000004810 polytetrafluoroethylene Substances 0.000 description 1
239000007774 positive electrode material Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
238000005086 pumping Methods 0.000 description 1
238000000197 pyrolysis Methods 0.000 description 1
238000005096 rolling process Methods 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1

Classifications

- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/502—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese for non-aqueous cells
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides; Hydroxides
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/74—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by peak-intensities or a ratio thereof only
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Inorganic Compounds Of Heavy Metals (AREA)
Battery Electrode And Active Subsutance (AREA)

JP20547284A 1983-09-30 1984-09-29 第一マンガン塩から二酸化マンガンを製造するための過マンガン酸法 Granted JPS6090827A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US53756483A	1983-09-30	1983-09-30
US537564		1983-09-30

Publications (2)

Publication Number	Publication Date
JPS6090827A JPS6090827A (ja)	1985-05-22
JPS636496B2 true JPS636496B2 (da)	1988-02-10

Family

ID=24143150

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP20547284A Granted JPS6090827A (ja)	1983-09-30	1984-09-29	第一マンガン塩から二酸化マンガンを製造するための過マンガン酸法

Country Status (2)

Country	Link
JP (1)	JPS6090827A (da)
GB (1)	GB2147285B (da)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4604336A (en) *	1984-06-29	1986-08-05	Union Carbide Corporation	Manganese dioxide and process for the production thereof
US5604057A (en) *	1995-11-27	1997-02-18	General Motors Corporation	Secondary cell having a lithium intercolating manganese oxide
US6780347B2 (en) *	2002-02-04	2004-08-24	Rayovac Corporation	Manganese oxide based electrode for alkaline electrochemical system and method of its production
CN103920448B (zh) *	2014-04-17	2015-09-30	哈尔滨工程大学	一种二氧化锰铀吸附剂的制备方法及应用方法
JPWO2020050215A1 (ja) *	2018-09-07	2021-09-16	国立大学法人東京工業大学	β−二酸化マンガンを用いた酸化物の製造方法
CN113750988B (zh) *	2021-09-26	2023-11-17	华南理工大学	一种异相结锰氧化物催化剂及其制备方法与应用
CN115477328A (zh) *	2022-08-16	2022-12-16	山东利特纳米技术有限公司	过渡金属改性的二氧化锰-碳复合材料及其制备方法

1984
- 1984-09-28 GB GB8424599A patent/GB2147285B/en not_active Expired
- 1984-09-29 JP JP20547284A patent/JPS6090827A/ja active Granted

Also Published As

Publication number	Publication date
JPS6090827A (ja)	1985-05-22
GB2147285A (en)	1985-05-09
GB2147285B (en)	1987-04-01
GB8424599D0 (en)	1984-11-07

Publication	Publication Date	Title
US4476104A (en)	1984-10-09	Manganese dioxide and process for the production thereof
US4585718A (en)	1986-04-29	Lithium-manganese dioxide cell
EP1083614B1 (en)	2003-05-02	Lithium intercalating material containing oxygen, sulfur and a transition metal, electrode structure and production process thereof, and secondary lithium battery
US4590059A (en)	1986-05-20	Process for the production of manganese dioxide
JP3559720B2 (ja)	2004-09-02	リチウム二次電池及びその製造方法
US4405699A (en)	1983-09-20	Manganese dioxide electrode for lithium batteries
JP4801865B2 (ja)	2011-10-26	リチウム化された二酸化マンガン
JP5678482B2 (ja)	2015-03-04	マンガン酸化物及びその製造方法
JPH075318B2 (ja)	1995-01-25	二酸化マンガンとその製法
JPH0368507B2 (da)	1991-10-28
JPH04270125A (ja)	1992-09-25	酸化マンガン化合物
JPH0368506B2 (da)	1991-10-28
US5496664A (en)	1996-03-05	Process for producing a positive electrode for lithium secondary batteries
Bach et al.	1995	Effect of Bi-doping on the electrochemical behaviour of layered MnO2 as lithium intercalation compound
JPS636496B2 (da)	1988-02-10
JP3590178B2 (ja)	2004-11-17	電解二酸化マンガンおよびその製造方法、並びにマンガン乾電池
US3350198A (en)	1967-10-31	Cadmium metal sponge
US4016091A (en)	1977-04-05	Method of preparing high capacity nickel electrode powder
US3941614A (en)	1976-03-02	Method of preparing high capacity nickel electrode powder
JPH082921A (ja)	1996-01-09	リチウムマンガン複合酸化物およびその製造方法並びにその用途
JPH06295724A (ja)	1994-10-21	リチウム二次電池用マンガン酸リチウムの製造方法
Kumagai et al.	2000	Synthesis of ternary Li–Mn–O phase at a temperature of 260∘ C and electrochemical lithium insertion into the oxide
CA1218515A (en)	1987-03-03	Method of making a compound
JP4321000B2 (ja)	2009-08-26	リチウムマンガン系複合酸化物から成るリチウムイオン二次電池用正極活物質及びその製造方法並びにその用途
JPS6352747B2 (da)	1988-10-20