JPS6364713A - Manufacture of heat-resistance and pressure-resistant vessel made of synthetic resin - Google Patents

Manufacture of heat-resistance and pressure-resistant vessel made of synthetic resin

Info

Publication number
JPS6364713A
JPS6364713A JP21038886A JP21038886A JPS6364713A JP S6364713 A JPS6364713 A JP S6364713A JP 21038886 A JP21038886 A JP 21038886A JP 21038886 A JP21038886 A JP 21038886A JP S6364713 A JPS6364713 A JP S6364713A
Authority
JP
Japan
Prior art keywords
mold
inner mold
resin
molded
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP21038886A
Other languages
Japanese (ja)
Inventor
Noriko Mizushima
水島 紀子
Noboru Miki
三木 昇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
MIZUSHIMA KAGAKU KOGYO KK
Original Assignee
MIZUSHIMA KAGAKU KOGYO KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by MIZUSHIMA KAGAKU KOGYO KK filed Critical MIZUSHIMA KAGAKU KOGYO KK
Priority to JP21038886A priority Critical patent/JPS6364713A/en
Publication of JPS6364713A publication Critical patent/JPS6364713A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a seamless, heat-resistant and pressure-resistant vessel, by a method wherein a hollow inner mold is inserted and fixed within a cavity having an inner form of a bottlelike material at a gap identical with a thickness of a material to be molded, resin of a high-melting point is injected into the gap and after curing of the resin the inner mold is removed from the inside of the molded body by pulling out the same. CONSTITUTION:Half bodies 1a, 1b each of an outer mold 1 are broken to right and left, an inner mold 2 held by a pipe 5 is inserted into a cavity 3, and the half bodies are clamped together. Then simultaneously with casting of a resin material which is in a molten state into a cavity 3' between the outer mold and inner mold through a gate 8 of the bottom of the half body 1b, high-pressure cold water W is introduced into the inner mold 2 through small holes 6, 6,... of a pipe 5. Resin is cooled and cured by introducing the cold water through into water pipes 7,7,... of the outer mold 1 after injection, the inside of the inner mold 2 is decompressed through the small holes 6 of the pipe 5, the mold is contracted, deformed and a semiproduct C of a vessel within which the inner mold 2 is filled up is taken out. A completed vessel C' is obtained by pulling out the deformed inner mold 2 through the inside of the molded vessel C by pulling a catch part 4 of the inner mold 2.

Description

【発明の詳細な説明】 (発明の利用分野) 本発明は、合成樹脂製耐熱耐圧容器の新規な製造法に関
する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Application of the Invention) The present invention relates to a novel method for manufacturing a heat-resistant and pressure-resistant synthetic resin container.

(従来の技術) 従来の合成樹脂製瓶型容器は、通常、単純吹込成形法、
射出吹込成形法、コールドパリソン法、シートパリソン
法及び延伸吹込成形法など、使用樹脂の性質及び目的成
形品の形状などの要因に応じて種々の吹込成形手段を用
いて作られるが、これらの方法による樹脂の種類は、例
えばポリエチレン、ポリプロピレン、ポリスチロール、
ポリ塩化ビニル、ABS、ポリカーボネート、ポリアミ
ドなど比較的低融点のものに限られており、精々ポリエ
チレンテレフタレート(融点256℃)程度を限度とす
る。従って、一般に耐熱性樹脂と称される可使温度20
0℃以上の樹脂、例えば弗素樹脂、芳香族ポリアミド、
芳香族ポリエステル、ポリエーテルスルホン、シリコー
ン樹脂、ポリアミドイミド、ポリイミド、熱硬化性ポリ
ブタジェン又は耐熱性エポキシ樹脂等の高融点又は高温
硬化性樹脂に対しては吹込成形手段は適用できない。
(Prior art) Conventional synthetic resin bottle-shaped containers are usually manufactured using simple blow molding method,
Various blow molding methods are used depending on factors such as the properties of the resin used and the shape of the desired molded product, such as injection blow molding, cold parison, sheet parison, and stretch blow molding. Examples of resin types include polyethylene, polypropylene, polystyrene,
It is limited to materials with relatively low melting points, such as polyvinyl chloride, ABS, polycarbonate, and polyamide, and is limited to polyethylene terephthalate (melting point: 256° C.). Therefore, the usable temperature is 20, which is generally called heat-resistant resin.
Resins at 0°C or higher, such as fluororesins, aromatic polyamides,
Blow molding means cannot be applied to high melting point or high temperature curable resins such as aromatic polyester, polyether sulfone, silicone resin, polyamideimide, polyimide, thermosetting polybutadiene or heat resistant epoxy resin.

そこで、耐熱性の要求される瓶型容器の製作には、従来
容器、を肩部を境に上下に二倍して射出成形後1両部分
を熱溶接することにより製作されてきた。しかしかかる
方法によれば、操作自体面倒であることの他に、必然的
に接合部に継目線を発生し、この継目線は全体の耐圧強
度を著しく弱める。加えて、接合操作時局部的に高温に
加熱されるため、樹脂の分解、残留応力などが製品の品
質を劣化させ易い、因に、残留応力を除去するためのア
ニーリングは屡々行われることであるが、本操作は通常
全体の機械的性質を低下させる。
Therefore, in order to manufacture bottle-shaped containers that require heat resistance, conventional containers have been manufactured by doubling the container vertically with the shoulder as a boundary, injection molding, and then heat welding both parts. However, according to such a method, in addition to being troublesome to operate, a seam line is inevitably generated at the joint, and this seam line significantly weakens the overall pressure resistance strength. In addition, because the bonding process locally heats up to high temperatures, resin decomposition and residual stress tend to deteriorate the quality of the product. Incidentally, annealing is often performed to remove residual stress. However, this operation usually reduces the overall mechanical properties.

(発明の目的) 以上の事情に鑑み、本発明は優れた耐圧性を有すると共
に、耐熱性のある合成樹脂製容器を提供するのを目的と
する。
(Object of the Invention) In view of the above circumstances, an object of the present invention is to provide a synthetic resin container that has excellent pressure resistance and heat resistance.

(目的達成のための手段) 以上の目的を達成せんがため、本発明に係る合成樹脂製
#熱耐圧容器の製造法は、瓶状体の内形を有するキャビ
ティの内部に構成彫版状体の内形に相当する外形を有す
る肉厚の薄い中空の内型(中子)を該被成形体の肉厚に
等しい間隙を隔てて挿入固定した後、該内型内へ加圧流
体圧を作用させながら該間隙内へ高融点樹脂を射入し、
硬化後、被成形体内から内型を引出して除去することを
特徴とする。
(Means for Achieving the Object) In order to achieve the above object, the method for manufacturing a #heat and pressure resistant container made of synthetic resin according to the present invention includes an engraved body constructed inside a cavity having an inner shape of a bottle-shaped body. After inserting and fixing a thin-walled hollow inner mold (core) having an outer shape corresponding to the inner shape of the molded object with a gap equal to the wall thickness of the molded object, pressurized fluid pressure is applied into the inner mold. Injecting high melting point resin into the gap while acting,
After curing, the inner mold is pulled out and removed from the object to be molded.

第1図及び第2図は、本発明製造法の実施に利用される
外型及び内型の構造を示す概略断面図である。
1 and 2 are schematic cross-sectional views showing the structures of an outer mold and an inner mold used in implementing the manufacturing method of the present invention.

外型■は、被成形容器(C)の外形に相当するキャビテ
ィ■を備える前後各半体(la及びlb)に分割され、
両部会は被成形容器の肩部よりやや下寄りの位置で合一
して完全な外型を構成する(第1図参照)、また内型(
中子)■は、第2図のように、アルミニウム等の軟質金
属を用いて被成形容器(C)の内形に相当する外形を有
する薄い肉厚の成形体として作られ、その口部(2a)
の内径(d)は、固定用バイブ■(第3図参照)の外径
(do)より僅かに大きく定められる。
The outer mold ■ is divided into front and rear halves (la and lb) each having a cavity ■ corresponding to the outer shape of the container to be molded (C),
The two sections unite at a position slightly below the shoulder of the container to be molded to form a complete outer mold (see Figure 1), and the inner mold (
As shown in Figure 2, the core (core) ■ is made of a soft metal such as aluminum as a thin-walled molded body with an outer shape corresponding to the inner shape of the container to be molded (C), and its opening ( 2a)
The inner diameter (d) is set to be slightly larger than the outer diameter (do) of the fixing vibrator (see FIG. 3).

本内型は、後で説明するように、樹脂射入時の高温に耐
える一方では、成形完了後は引っ張りにより被成形容器
の口部から除去されなければならない、このため、本型
の材質は、討入時の樹脂温度に対して耐熱性を備えると
共に、除去に際し変形可能な程度の塑性を有していなけ
ればならない、具体的には、アルミニウム、銅、マグネ
シウムなどの軟質金材料例示されるが、アルミニウム及
び銅は、樹脂材料注入時に受ける加熱により焼鈍しを受
は易いので目的上特に好適である。なお、本内型の口部
は外型内へ侵入する引手部■を形成する。また1本内型
の肉厚は、製作及び取扱上支障がない限り可及的肉薄で
あるのが好ましいが、普通0.5+sm以上は必要であ
る。
As will be explained later, while the main mold can withstand high temperatures during resin injection, it must be removed from the mouth of the molded container by pulling after molding is completed.For this reason, the material of the main mold is In addition to being heat resistant to the resin temperature at the time of implantation, it must also have enough plasticity to be deformable during removal.Specifically, soft gold materials such as aluminum, copper, and magnesium are exemplified. , aluminum, and copper are particularly suitable for this purpose because they are easily annealed by the heat received during injection of the resin material. Note that the mouth of the inner mold forms a handle part (2) that enters into the outer mold. Further, the wall thickness of one inner mold is preferably as thin as possible as long as there is no problem in manufacturing and handling, but it is usually necessary to have a thickness of 0.5+sm or more.

以上の内型は、上記外型内に鎖車の内壁と一定の間隙を
隔てて確実に保持される必要がある。と同時に、樹脂の
射出時に生じる強大な圧力により、変形したり、押潰さ
れたり又は振動したりしてはならない、そこで木型は1
例えばその口部の内径と略々等径のパイプQにより支持
されると共に、該パイプに穿たれた小孔を経て本内型内
壁に及ぼされる加圧流体圧により樹脂圧と拮抗せしめら
れる。このため利用される流体は何でもよいが水は冷媒
を兼ねるので最も好ましい。
The inner mold described above needs to be reliably held within the outer mold with a certain gap between it and the inner wall of the chain wheel. At the same time, it must not be deformed, crushed or vibrated due to the enormous pressure generated during resin injection, so the wooden mold must be
For example, it is supported by a pipe Q having approximately the same diameter as the inner diameter of its mouth, and is counteracted by the pressurized fluid pressure applied to the inner wall of the inner mold through a small hole bored in the pipe. Any fluid may be used for this purpose, but water is most preferred since it also serves as a refrigerant.

第3図〜第6図は、上記第1図の外型と第2図の内型と
を使用した成形工程の概略を示す。
3 to 6 schematically show a molding process using the outer mold shown in FIG. 1 and the inner mold shown in FIG. 2.

最初、外型(1)の各半休(la及びlb)は左右に開
かれ、内部のキャビティ■内にパイプQで保持された内
型■が挿入された後、塁が閉じ合わされる(型締め工程
:第3図)。
First, each half (la and lb) of the outer mold (1) is opened to the left and right, and after the inner mold ■ held by the pipe Q is inserted into the internal cavity ■, the bases are closed together (mold clamping). Process: Figure 3).

次いで、半休(lb)の底部のゲート■を通じて熔融状
態にある樹脂材料が外型/内型間のキャビティ(3°)
内へ注入されると同時に、パイプ■の小孔(6、6、−
・)を経て内型(り内に高圧の冷水(W)が導入される
(射出工程;第4図)、この際、内型は予め200℃程
度に予熱されているのが好ましく、若し温度が該温度よ
り低いと樹脂が内型に密着しない、このため、冷水の導
入に先立ち、パイプ■の小孔■を経て熱媒体(例えば熱
風)が2内に吹き込まれて鎖車を予熱する。尤も、所望
により、熱媒体の導入に代え、型締め以前に内型■を火
炎で予熱してもよい、射出樹脂は、普通、400℃、2
50 kg/cm2程度の高温、高圧が必要である。
Next, the molten resin material enters the cavity (3°) between the outer mold and the inner mold through the gate at the bottom of the lb.
At the same time, the small hole (6, 6, -
・) High-pressure cold water (W) is introduced into the inner mold (injection process; Fig. 4). At this time, the inner mold is preferably preheated to about 200°C, or If the temperature is lower than this temperature, the resin will not adhere tightly to the inner mold. Therefore, before introducing cold water, a heat medium (for example, hot air) is blown into 2 through the small hole 2 of the pipe 2 to preheat the chain wheel. However, if desired, the inner mold (2) may be preheated with flame before mold clamping instead of introducing a heat medium.
High temperature and pressure of about 50 kg/cm2 are required.

射出が終れば外型(Oの木管(7、7、−・)内へ冷水
を導通して樹脂を冷却令硬化させた後、パイプ■の小孔
■を経て内壓■内を減圧し、鎖車を収縮、変形させた後
、内部に内型■の詰った容器半製品(C)を取り出す(
取出し工程:第5図)。
When the injection is completed, cold water is passed into the wooden pipe (7, 7, -) of the outer mold (O) to cool and harden the resin, and then the pressure inside the inner cylinder ■ is reduced through the small hole ■ of the pipe ■. After contracting and deforming the chain wheel, take out the semi-finished container (C) filled with the inner mold (C).
Removal process: Fig. 5).

最後に、取り出された被成形容器(C)内の変形した内
型■の引手部■を牽引してC内から抜き取り、完成容器
(Co)を得る(仕上げ工程:第6図)本発明における
容器の形状は所謂版型のate内で自由な変形を採るこ
とができ、所望により球形として最大の耐圧性を期待す
ることもできる。前六図の例における製品容器(Co)
は2ランジCC” f)付の標準的な箱型容器であるが
、第7図の金型で得られる容器は、螺子性の容器である
。なお本例の外型■は、被成形容器の底部と胴部との境
界部において分割されているので、゛製品容器にパーテ
ィングラインを生じ難いという特色がある。
Finally, the handle part ■ of the deformed inner mold ■ in the container to be molded (C) which has been taken out is pulled out from inside C to obtain a completed container (Co) (finishing process: Fig. 6). The shape of the container can be freely deformed within the so-called plate shape, and if desired, it can be made into a spherical shape to provide maximum pressure resistance. Product container (Co) in the example in the previous six figures
is a standard box-shaped container with a two-lunge CC" f), but the container obtained with the mold shown in Fig. 7 is a screw type container. In this example, the outer mold ■ is a container to be molded. Since the product container is divided at the boundary between the bottom and the body, it has the feature that it is difficult to form parting lines on the product container.

本発明における#熱樹脂としては、一般に耐熱性樹脂と
称される、可使温度200℃以上の樹脂。
The #thermal resin in the present invention is a resin that is generally referred to as a heat-resistant resin and has a usable temperature of 200°C or higher.

例えば弗素樹脂、芳香族ポリアミド、芳香族ポリエステ
ル、ポリエーテルスルホン、シリコーン樹脂、ポリアミ
ドイミド、ポリイミド、熱硬化性ポリブタジェン又は耐
熱性エポキシ樹脂等が好適に利用されるが、芳香族シア
ン酸エステル樹脂、ポリエステルイミド、ビスマレイミ
ドトリアジン樹脂、ポリベンズイミダゾール、ポリイミ
ダゾピロロンなどの他の耐熱性樹脂も随時利用されるこ
とができる。
For example, fluororesin, aromatic polyamide, aromatic polyester, polyether sulfone, silicone resin, polyamideimide, polyimide, thermosetting polybutadiene or heat-resistant epoxy resin, etc. are preferably used, but aromatic cyanate ester resin, polyester Other heat resistant resins such as imides, bismaleimide triazine resins, polybenzimidazole, polyimidazopyrrolones can optionally be utilized.

(作用) 本発明においては、耐熱性の樹脂について従来実施され
たことのない射出成形手段により全く継目線のない耐熱
樹脂製容器を製造することができるので、耐圧性の極め
て優れた耐熱性容器を工業的に能率良く生産することが
できる。
(Function) In the present invention, a heat-resistant resin container with absolutely no seam lines can be manufactured by an injection molding method that has never been used for heat-resistant resin, so the heat-resistant resin container has extremely excellent pressure resistance. can be produced industrially and efficiently.

(実施例) 以下、実施例を掲げ発明実施の一例を示すが、例示は勿
論説明用のものであって、発明精神の限定を意図するも
のではない。
(Example) Hereinafter, an example will be given and an example of implementing the invention will be shown, but the illustration is of course for illustrative purposes and is not intended to limit the spirit of the invention.

第1図の外型及び第2図類似の内型を用い、第3図乃至
第6図の工程に従って、鍔付耐圧容器を製造した。外型
(1)のキャビティの内径は174m/mφ、長径30
0 I!m、頚部の内径は80m■φ;アルミニウム製
内型■の外径は174 asφ、長径217 mm、頚
部の内径74”八Φ、肉厚1■であった。
Using the outer mold shown in FIG. 1 and the inner mold similar to that shown in FIG. 2, a flanged pressure container was manufactured according to the steps shown in FIGS. 3 to 6. The inner diameter of the cavity of the outer mold (1) is 174 m/mφ, and the major axis is 30
0 I! m, the inner diameter of the neck was 80 m.phi.; the outer diameter of the aluminum inner mold (2) was 174 as.phi., the major axis was 217 mm, the inner diameter of the neck was 74"8 Φ, and the wall thickness was 1.

以上の内型■をパイプ■で保持しながら200℃以上に
予熱した後、外型(O内に挿入して型締め圧200kg
/cm”で型締めし、内型■内に200kg/cm2の
水圧をかけながら直ちに約400℃に加熱されたテトラ
フルオロエチレンψパーフルオロプロピルビニルエーテ
ル(PFA)を250 kg/cm2の圧力でキャビテ
ィ(3゛)内へ射入した。
After preheating the above inner mold (■) to 200℃ or higher while holding it with a pipe (■), insert it into the outer mold (O) and apply a mold clamping pressure of 200 kg.
Immediately, tetrafluoroethylene ψ perfluoropropyl vinyl ether (PFA) heated to about 400°C was poured into the cavity ( 3゛).

次いで外型を冷却し、硬化後、パイプ■を通じて内型Q
内を減圧して鎖車を変形させた後、引手部■を牽引して
該内型を引き抜いた後、外型■を開いて完成した成形容
器を取り出し、最後にパリ取りして第8図(破断立面図
)及び第9図(平面図)に示す完成容器(Co)を得た
Next, the outer mold is cooled and after hardening, it is passed through the pipe ■ to the inner mold Q.
After depressurizing the inside and deforming the chain wheel, pull out the inner mold by pulling the pull part (■), open the outer mold (■) and take out the completed molded container, and finally remove the pars as shown in Figure 8. A completed container (Co) shown in (broken elevation view) and FIG. 9 (plan view) was obtained.

本容姦は、その鍔部(C’f)に取付用の螺子孔(c’
h、c’h、・争)を備え、−切の薬剤に対し耐薬品性
を有すると共に、200℃において約7 kg/cm2
の加圧に耐える。
The main case has a screw hole (c') for attachment in its collar (C'f).
h, c'h, ・c), has chemical resistance to -cutting chemicals, and has a chemical resistance of about 7 kg/cm2 at 200°C.
Withstands pressure.

(発明の効果) 本発明は、以上説明した如く、射出成形手段により耐熱
性樹脂材料からなる継目なしの耐熱耐圧容器を工業的に
生産する方法を提供しうることにより、関連産業に対し
多大の恵沢を与える。
(Effects of the Invention) As explained above, the present invention provides a method for industrially producing a seamless heat-resistant and pressure-resistant container made of a heat-resistant resin material by injection molding, thereby bringing great benefits to related industries. Give blessings.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の実施に使用しうる外型の一例を示す
やや模型的な断面図、第2図は、同じく内型の同様断面
図、第3図乃至第6図は、本発明の工程を示す模型的な
断面図、第7図は、発明の実施に利用しうる別の金型の
例を示−す第4図と同様の断面図、第8図は、本発明の
実施により得られる耐熱耐圧容器の一例の破断立面図、
第9図は、同じく平面図である0図中の主要な符号の意
味は以下の通り:□ 1:外型; @la、 lb: 1の各半休、3;1内のキャビティ
7: lの、木管、8:1bのゲート;2:内型: 中2a:2の頚部、8±壬母哉遥、4:2の引手部; 3“:l/2間のキャビティ; 5:内型0固定(保持)用のパイプ; C;被成形容器(半製品); C゛:製品容器; ・c’b:c’の底部、C’d : C”の胴部、c”
r:c”の鍔部; −@C’b : C’fの取付孔。 第2図
FIG. 1 is a somewhat schematic cross-sectional view showing an example of an outer mold that can be used to carry out the present invention, FIG. 2 is a similar cross-sectional view of an inner mold, and FIGS. FIG. 7 is a cross-sectional view similar to FIG. 4 showing an example of another mold that can be used for carrying out the invention, and FIG. A broken elevation view of an example of a heat-resistant and pressure-resistant container obtained by
In Figure 9, the meanings of the main symbols in Figure 0, which is also a plan view, are as follows: □ 1: Outer mold; @la, lb: each half of 1, 3; cavity 7 inside 1: l. , woodwind, 8: Gate of 1b; 2: Inner mold: Neck of 2a: 2, 8± Mibo Yaharuka, 4: Pull part of 2; 3": Cavity between l/2; 5: Inner mold 0 Pipe for fixing (holding); C: Container to be formed (semi-finished product); C゛: Product container; ・c'b: Bottom of c', C'd: Body of C", c"
r: Flange of c'';-@C'b: Mounting hole of C'f. Fig. 2

Claims (2)

【特許請求の範囲】[Claims] (1)瓶状体の内形を有するキャビティの内部に被成形
瓶状体の内形に相当する外形を有する肉厚の薄い中空の
内型(中子)を該被成形体の肉厚に等しい間隙を隔てて
挿入固定した後、該内型内へ加圧流体圧を作用させなが
ら該間隙内へ高融点樹脂を射入し、硬化後、被成形体内
から内型を引出して除去することを特徴とする合成樹脂
製耐熱耐圧容器の製造法。
(1) A thin hollow inner mold (core) having an outer shape corresponding to the inner shape of the bottle-shaped object to be molded is placed inside the cavity having the inner shape of the bottle-shaped object to the thickness of the object to be molded. After inserting and fixing with an equal gap, injecting a high melting point resin into the gap while applying pressurized fluid pressure into the inner mold, and after curing, pulling out and removing the inner mold from the molded object. A method for manufacturing a synthetic resin heat-resistant and pressure-resistant container characterized by:
(2)内型の固定が、該型内へ挿入され、かつ該内型の
口部の内径と略々等しい外径を有するパイプの挿入によ
り行なわれる特許請求の範囲第1項記載の製造法。
(2) The manufacturing method according to claim 1, wherein the inner mold is fixed by inserting a pipe that is inserted into the mold and has an outer diameter approximately equal to the inner diameter of the mouth of the inner mold. .
JP21038886A 1986-09-05 1986-09-05 Manufacture of heat-resistance and pressure-resistant vessel made of synthetic resin Pending JPS6364713A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21038886A JPS6364713A (en) 1986-09-05 1986-09-05 Manufacture of heat-resistance and pressure-resistant vessel made of synthetic resin

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21038886A JPS6364713A (en) 1986-09-05 1986-09-05 Manufacture of heat-resistance and pressure-resistant vessel made of synthetic resin

Publications (1)

Publication Number Publication Date
JPS6364713A true JPS6364713A (en) 1988-03-23

Family

ID=16588508

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21038886A Pending JPS6364713A (en) 1986-09-05 1986-09-05 Manufacture of heat-resistance and pressure-resistant vessel made of synthetic resin

Country Status (1)

Country Link
JP (1) JPS6364713A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5858295A (en) * 1996-12-30 1999-01-12 Johnson & Johnson Professional, Inc. Method of injection molding a part using an inflatable mold core
US6537484B2 (en) 1990-11-26 2003-03-25 Excell Corporation Method for manufacturing a multi-layer plastic pipe

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6537484B2 (en) 1990-11-26 2003-03-25 Excell Corporation Method for manufacturing a multi-layer plastic pipe
US5858295A (en) * 1996-12-30 1999-01-12 Johnson & Johnson Professional, Inc. Method of injection molding a part using an inflatable mold core

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