JPS6363634B2 - - Google Patents
Info
- Publication number
- JPS6363634B2 JPS6363634B2 JP60221632A JP22163285A JPS6363634B2 JP S6363634 B2 JPS6363634 B2 JP S6363634B2 JP 60221632 A JP60221632 A JP 60221632A JP 22163285 A JP22163285 A JP 22163285A JP S6363634 B2 JPS6363634 B2 JP S6363634B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- fatty acid
- type
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000005498 polishing Methods 0.000 claims description 29
- -1 polyoxyethylene Polymers 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 19
- 239000002253 acid Substances 0.000 claims description 16
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 12
- 239000002736 nonionic surfactant Substances 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 150000002826 nitrites Chemical class 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 150000001642 boronic acid derivatives Chemical class 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 235000019814 powdered cellulose Nutrition 0.000 claims description 4
- 229920003124 powdered cellulose Polymers 0.000 claims description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 claims description 2
- 230000000694 effects Effects 0.000 description 18
- 239000003082 abrasive agent Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 230000003139 buffering effect Effects 0.000 description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 5
- 230000001050 lubricating effect Effects 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000002265 prevention Effects 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 229910001369 Brass Inorganic materials 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000010951 brass Substances 0.000 description 4
- 230000003749 cleanliness Effects 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000009499 grossing Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 2
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 229930016911 cinnamic acid Natural products 0.000 description 2
- 235000013985 cinnamic acid Nutrition 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000008233 hard water Substances 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical group OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 229910000677 High-carbon steel Inorganic materials 0.000 description 1
- 229910000997 High-speed steel Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000639 Spring steel Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000003623 enhancer Substances 0.000 description 1
- DEFVIWRASFVYLL-UHFFFAOYSA-N ethylene glycol bis(2-aminoethyl)tetraacetic acid Chemical compound OC(=O)CN(CC(O)=O)CCOCCOCCN(CC(O)=O)CC(O)=O DEFVIWRASFVYLL-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- VMWYVTOHEQQZHQ-UHFFFAOYSA-N methylidynenickel Chemical compound [Ni]#[C] VMWYVTOHEQQZHQ-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 229960003330 pentetic acid Drugs 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F3/00—Brightening metals by chemical means
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- ing And Chemical Polishing (AREA)
Description
本発明は、バレル研摩液組成物に関するもので
ある。表面処理工業における鉄および特殊合金等
の表面研摩は、製品自身の商品価値を左右する大
きな役割を発揮している。従来から、研摩方法と
しては、
陽極溶解現象を利用し、炭素鋼、高炭素鋼、
特殊鋼、黄銅、アルミ合金18／８ステンレス、
銀、金、ニツケル、ニツケルクローム等合金、
バネ鋼、高速度鋼や、プラスチツク等を光沢、
超仕上、バリ取り効果をねらつた電解研摩、
酸等化学薬品溶液に対する金属の溶解性を利
用し、マグネシウム、亜鉛、カドミウム、黄
銅、銅、アルミニウムおよびアルミ合金、ニツ
ケル炭素鋼などの光沢、平滑効果をねらつた化
学研摩、
研摩材、酸化アルミニウム、酸化鉄などを使
用し、ほとんど人為によつて光沢ある平滑面を
得る羽布研摩、
酸またはアルカリおよび石鹸等界面活性剤を
使用し、研摩材を場合により、併用し、回転容
器中等で金属表面の研摩を行なうバレル研摩、
などが知られ、金属、プラスチツク等の製品の
目的、材質に応じ単独もしくは重ね使用されて
いる。
多くの研摩方法の中でバレル研摩法は、大量加
工性、省力、省人化加工性に優れ、さらに表面研
摩、平滑化、バリ取り効果、清浄化、場合により
防錆、除錆等の効果を有することから有用な研摩
法と言え、さらには被研摩物質も多彩なことで知
られている。
バレル研摩法には、回転バレル研摩法、振動バ
レル研摩法、遠心バレル研摩法、レシプロ研摩法
等があり、バレルと呼ばれる研摩槽に、被研摩物
質、水、研摩材（石）および研摩剤を装入し回
転、振動、遠心旋回等の運動を与え、被研摩物質
の処理を行なう。
バレル研摩法の特徴として、
(1) 研摩機の機種選定
(2) 研摩材（石）の種類とサイズの選定がある
が、さらに研摩剤の性能が重要な要素となつて
いる。研摩剤の具備すべき作用として
(1) 潤滑作用
(2) 緩衝作用
(3) 清浄作用
(4) 硬水軟化作用
(5) 防錆作用
等があり、被研摩物質の優れた研摩性と光沢性は
以上の作用の結果として多くの場合発揮される。
バレル研摩剤には、酸によるスケール除去を主目
的としたり、アルカリによる清浄を主目的とした
粗仕上げバレル研摩があるが、これ等はあくまで
前処理的性格で目的の光沢性の付与には直接、作
用しない。
光沢性付与における、バレル研摩剤には、従
来、各種脂肪酸塩、アルキルベンゼンスルホン酸
塩、高級アルコール硫酸エステル塩を主とするア
ニオン系界面活性剤が一部、ホウ酸塩、亜硝酸塩
と併用され研摩剤として、従来から使用されてい
る。しかしながら、従来の研摩剤において、その
光沢性を付与すべき具備条件からして、
潤滑作用および若干の緩衝作用はアニオン界面
活性剤により、防錆作用は亜硝酸塩等を添加すれ
ば、効果を期待できるが、緩衝作用、清浄作用お
よび硬水軟化作用において、充分な効果を発揮す
ることはできず、実用上、改善すべき問題点を有
している。
さらに、バレル研摩の特徴である多彩な被研摩
物質の処理が、できるという特性を従来の研摩剤
では、満足に発揮することが不可能である。
本発明者は、これら問題点を解消すべく、鋭意
研究の結果、本発明に到達したものである。即
ち、本発明は
ポリオキシアルキルエーテル型、ポリオキシ
アルキルフエニールエーテル型、ポリオキシエチ
レン脂肪酸エステル型、ソルビタン脂肪酸エステ
ル型、シヨ糖脂肪酸エステル型、およびグリセリ
ン脂肪酸エステル型非イオン系界面活性剤から選
らばれた１種以上を１〜30重量部、オキシカル
ボン酸または、その塩を２〜20重量部、アミノ
ポリカルボン酸または、その塩の１種以上を１〜
15重量部、アルカノールアミド型非イオン系界
面活性剤、粉末繊維素、カルボキシメチルセルロ
ースNa塩から選択された化合物の１種以上を10
〜80重量部、およびホウ酸塩、亜硝酸塩、芳香
族カルボン酸または、その塩の１種以上を２〜30
重量部を含有することを特徴とするバレル研摩液
組成物を提供するものである。
本発明において、前記非イオン系界面活性
剤、オキシカルボン酸またはその塩およびア
ミノカルボン酸またはその塩の組み合せにより清
浄作用を発揮する。
また、アミノポリカルボン酸または、その塩
及びオキシカルボン酸または、その塩の組み合
せにより硬水軟化作用が発揮される。
次に、アルカノールアミド型非イオン界面活
性剤、粉末繊維素、カルボキシメチルセルロース
Na塩から選らばれた化合物は緩衝作用および潤
滑作用向上剤としての作用効果を発揮をする。
また、脂肪酸塩、アルキルベンゼンスルホン酸
塩または高級アルコール硫酸エステル塩と併用す
ることにより、緩衝作用および潤滑作用を、さら
に向上することが可能である。
最後に、ホウ酸塩、亜硝酸塩または安息香
酸、桂皮酸等の芳香族カルボン酸もしくは、それ
らの塩から選択された化合物は防錆作用を発揮す
る。本発明バレル研摩液組成物は、必要により酸
またはアルカリと併用が可能で、、さらに発泡安
定剤の高級アルコール、ロジンまたは、その誘導
体およびアルカンスルホン酸塩を併用することも
できる。
本発明バレル研摩液組成物は多彩な被研摩物質
の全てにわたり、優れた処理性を示し、大量加
工、省力、省人化、加工性を可能にならしめ、表
面研摩、平滑効果、バリ取り効果、清浄効果、防
錆効果を有し優れた光沢を発現できるものであ
る。
次に本発明組成物の各構成成分について、さら
に具体的に説明する。非イオン系界面活性剤と
しては、ポリオキシアルキルエーテル型、ポリオ
キシアルキルフエニールエーテル型、ポリオキシ
エチレン脂肪酸エステル型、ソルビタン脂肪酸エ
ステル型、シヨ糖脂肪酸エステル型、グリセリン
脂肪酸エステル型等から選択される。
配合量は１〜30重量部、より好ましくは２〜20
重量部であり、１重量部未満では、清浄性が劣
り、また光沢性が発現しない。また、30重量部を
越えると、同じく光沢性が発現しない。
オキシカルボン酸または、その塩としては、
クエン酸、リンゴ酸、酒石酸、乳酸、グリコール
酸、グルコン酸等または、それらの塩等から選択
される。
配合量は２〜20重量部、より好ましくは５〜15
重量部であり、２重量部未満では、清浄性、硬水
軟化性が劣り、光沢性が発現しない。また、20重
量部を越えると同じく光沢性が発現しない。
アミノポリカルボン酸または、その塩として
は、エチレンジアミン四酢酸、ジエチレントリア
ミン五酢酸、ニトリロ三酢酸、グリコールエーテ
ルジアミン四酢酸等または、これらの塩等から選
択される。
配合量は１〜15重量部、より好ましくは２〜10
重量部であり、１重量部未満では、清浄性、硬水
軟化性が劣り、光沢性が発現しない。また、15重
量部を越えると同じく光沢性が発現しない。
アルカノールアミド型非イオン系界面活性
剤、粉末繊維素、カルボキシメチルセルロース
Na塩から選択された化合物の配合量は10〜80重
量部、より好ましくは20〜70重量部であり、10重
量部未満では、潤滑性、緩衝性が劣り、光沢性が
発現しない。また、80重量部を越えると、光沢性
が発現しない。
ホウ酸塩、亜硝酸塩、芳香族カルボン酸とし
ての安息香酸、桂皮酸または、それら塩の配合量
は２〜30重量部、より好ましくは５〜25重量部で
あり、２重量部未満では、特に金属研摩材（スチ
ールホール）や、被研摩物質に錆が発生し、光沢
性が発現しない。また、30重量部を越えると光沢
性が発現しない。
また、必要により、本発明バレル研摩液組成物
に、脂肪酸塩、アルキルベンゼンスルホン酸、高
級アルコール硫酸エステル塩等の潤滑主性能物
質、または酸、アルカリ、さらには発泡安定剤と
しての高級アルコール、ロジン、または、その誘
導体、およびアルカンスルホン酸塩を併用しても
何等さしつかえない。
前述の通り、各構成成分〜を前記配合割合
において構成された本発明バレル研摩液組成物
は、潤滑作用、緩衝作用、清浄作用、硬水軟化作
用、防錆作用等が円滑に発現され、光沢性をはじ
めとする、バリ取り性、平滑性、清浄性、防錆性
等のすべての効果が発揮され、バレル研摩法の特
徴である均一な大量加工性、省力、省人化、加工
性に優れ、かつ、多彩な被研摩物質の加工が可能
となる。
以下に本発明を実施例により具体的に説明す
る。
実施例 １
表−１に示した研摩剤組成物を用いて、下記試
験法に基づき各種金属の光沢性の発現比較試験を
行なつた。その結果を表−２に示した。
研摩方法［機］被研摩物［テストピース］……高
速遠心バレルアルミニウム、アルミダイガス
ト、亜鉛ダイガスト、真ちゆう、ステンレス、
鉄
研摩材［石］……高純度溶融酸化アルミニウム・
シリカ製微小切削および鏡面仕上用研摩材
［石］
研摩液組成物……表−１に示した研摩剤添加量
20g／
前処理……アルカリ洗浄剤で脱脂後、５％硝酸に
て表面活性化処理
評価方法……比較配合品(イ)を指数100とした時の
相対比較として肉眼判定した。遠心バレル30分
処理後の評価
表−２に示す通り、本発明組成物は、アルミニ
ウム、アルミダイガスト、亜鉛ダイガスト、真ち
ゆう、ステンレス、鉄に対して優れた潤滑作用、
緩衝作用、清浄作用、硬水軟化作用、防錆作用を
発揮し、その総合作用として光沢性を著しく発現
することが確認され、きわめて実用性の高いもの
である。
The present invention relates to barrel polishing fluid compositions. Surface polishing of iron and special alloys in the surface treatment industry plays a major role in determining the commercial value of the product itself. Traditionally, polishing methods have utilized the anodic dissolution phenomenon to polish carbon steel, high carbon steel,
Special steel, brass, aluminum alloy 18/8 stainless steel,
Alloys such as silver, gold, nickel, nickel chrome, etc.
Brighten spring steel, high-speed steel, plastic, etc.
Electrolytic polishing for ultra-finishing and deburring effects, utilizing the solubility of metals in chemical solutions such as acids, to achieve gloss and smoothing effects on magnesium, zinc, cadmium, brass, copper, aluminum and aluminum alloys, nickel carbon steel, etc. chemical polishing, which uses abrasive materials such as aluminum oxide, iron oxide, etc., to obtain a glossy, smooth surface almost entirely by hand; cloth polishing, which uses surfactants such as acid or alkali and soap, and In some cases, barrel polishing is used to polish the metal surface in a rotating container, etc.
These are known and are used alone or in layers depending on the purpose and material of the product, such as metal or plastic. Among many polishing methods, the barrel polishing method is superior in mass processing, labor saving, and labor saving processing, and is also effective in surface polishing, smoothing, deburring, cleaning, and in some cases rust prevention and rust removal. It can be said to be a useful polishing method because it has the following characteristics, and it is also known for its wide variety of materials to be polished. Barrel polishing methods include rotating barrel polishing, vibrating barrel polishing, centrifugal barrel polishing, reciprocating polishing, etc. The material to be polished, water, abrasive material (stone), and abrasive agent are placed in a polishing tank called a barrel. The material to be polished is processed by loading it and applying motion such as rotation, vibration, and centrifugal rotation. The characteristics of the barrel polishing method include (1) selection of the polishing machine model, and (2) selection of the type and size of the abrasive material (stone), but the performance of the abrasive material is an even more important factor. The functions that an abrasive should have include (1) lubricating effect, (2) buffering effect, (3) cleaning effect, (4) hard water softening effect, (5) rust prevention effect, etc., and improves the excellent abrasiveness and gloss of the material to be polished. is exhibited in many cases as a result of the above-mentioned effects.
Barrel abrasives include rough finishing barrel abrasives, which are mainly used to remove scale with acid and clean with alkali, but these are only pre-treatments and cannot be used directly to impart the desired gloss. , does not work. Conventionally, barrel abrasives used to impart gloss include anionic surfactants, mainly consisting of various fatty acid salts, alkylbenzene sulfonates, and higher alcohol sulfate ester salts, in combination with borates and nitrites. It has been traditionally used as an agent. However, considering the conditions that conventional abrasives have to provide gloss, it is expected that an anionic surfactant will provide lubrication and a slight buffering effect, and nitrites will be added to prevent rust. However, it cannot exhibit sufficient effects in terms of buffering, cleaning, and water softening, and has problems that need to be improved in practice. Furthermore, it is impossible for conventional abrasives to satisfactorily exhibit the characteristic of barrel polishing, which is the ability to treat a wide variety of materials to be polished. The present inventor has arrived at the present invention as a result of intensive research in order to solve these problems. That is, the present invention provides nonionic surfactants selected from polyoxyalkyl ether type, polyoxyalkyl phenyl ether type, polyoxyethylene fatty acid ester type, sorbitan fatty acid ester type, sucrose fatty acid ester type, and glycerin fatty acid ester type. 1 to 30 parts by weight of one or more of the discovered acids, 2 to 20 parts by weight of oxycarboxylic acids or salts thereof, and 1 to 30 parts by weight of one or more of aminopolycarboxylic acids or salts thereof.
15 parts by weight, 10 parts by weight of one or more compounds selected from alkanolamide type nonionic surfactants, powdered cellulose, and carboxymethyl cellulose Na salt.
~80 parts by weight, and 2 to 30 parts by weight of one or more of borates, nitrites, aromatic carboxylic acids, or salts thereof.
The present invention provides a barrel polishing composition characterized in that it contains parts by weight. In the present invention, the combination of the nonionic surfactant, oxycarboxylic acid or its salt, and aminocarboxylic acid or its salt exhibits a cleaning effect. In addition, a combination of aminopolycarboxylic acid or its salt and oxycarboxylic acid or its salt exhibits a water softening effect. Next, alkanolamide type nonionic surfactant, powdered cellulose, carboxymethyl cellulose
Compounds selected from Na salts act as buffering and lubrication enhancers. Furthermore, by using it in combination with a fatty acid salt, an alkylbenzene sulfonate, or a higher alcohol sulfate ester salt, it is possible to further improve the buffering effect and the lubricating effect. Finally, compounds selected from borates, nitrites or aromatic carboxylic acids such as benzoic acid, cinnamic acid, or their salts exhibit anticorrosive action. The barrel polishing composition of the present invention can be used in combination with an acid or an alkali, if necessary, and can also be used in combination with a foaming stabilizer such as a higher alcohol, rosin or a derivative thereof, and an alkanesulfonate. The barrel polishing liquid composition of the present invention exhibits excellent processing properties for all kinds of materials to be polished, and enables mass processing, labor saving, manpower saving, processability, surface polishing, smoothing effect, and deburring effect. It has a cleaning effect, a rust prevention effect, and can express excellent gloss. Next, each component of the composition of the present invention will be explained in more detail. The nonionic surfactant is selected from polyoxyalkyl ether type, polyoxyalkyl phenyl ether type, polyoxyethylene fatty acid ester type, sorbitan fatty acid ester type, sucrose fatty acid ester type, glycerin fatty acid ester type, etc. . The blending amount is 1 to 30 parts by weight, more preferably 2 to 20 parts by weight.
If it is less than 1 part by weight, the cleanliness will be poor and the gloss will not develop. Moreover, if it exceeds 30 parts by weight, glossiness will not be developed. As oxycarboxylic acid or its salt,
It is selected from citric acid, malic acid, tartaric acid, lactic acid, glycolic acid, gluconic acid, etc., or salts thereof. The blending amount is 2 to 20 parts by weight, more preferably 5 to 15 parts by weight.
If it is less than 2 parts by weight, cleanliness and water softening properties will be poor and gloss will not be developed. Moreover, if it exceeds 20 parts by weight, glossiness will not be developed. The aminopolycarboxylic acid or its salt is selected from ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, nitrilotriacetic acid, glycol etherdiaminetetraacetic acid, and salts thereof. The blending amount is 1 to 15 parts by weight, more preferably 2 to 10 parts by weight.
If it is less than 1 part by weight, cleanliness and water softening properties will be poor and gloss will not be developed. Moreover, if it exceeds 15 parts by weight, glossiness will not be developed. Alkanolamide type nonionic surfactant, powdered cellulose, carboxymethyl cellulose
The compounding amount of the compound selected from Na salts is 10 to 80 parts by weight, more preferably 20 to 70 parts by weight. If it is less than 10 parts by weight, lubricity and buffering properties are poor and glossiness is not developed. Moreover, if it exceeds 80 parts by weight, glossiness will not be developed. The amount of borate, nitrite, benzoic acid as aromatic carboxylic acid, cinnamic acid, or their salts is 2 to 30 parts by weight, more preferably 5 to 25 parts by weight, and less than 2 parts by weight, especially Rust occurs on the metal abrasive material (steel hole) and the material to be polished, resulting in no gloss. Moreover, if it exceeds 30 parts by weight, glossiness will not be developed. If necessary, the barrel polishing liquid composition of the present invention may contain main lubricating substances such as fatty acid salts, alkylbenzenesulfonic acids, higher alcohol sulfuric ester salts, acids, alkalis, higher alcohols as foaming stabilizers, rosin, etc. Alternatively, a derivative thereof and an alkanesulfonate salt may be used in combination. As mentioned above, the barrel polishing liquid composition of the present invention, which is composed of each component in the above-mentioned proportions, smoothly exhibits lubricating action, buffering action, cleaning action, hard water softening action, rust prevention action, etc., and has high glossiness. It exhibits all the effects including deburring, smoothness, cleanliness, and rust prevention, and is excellent in uniform mass processing, labor saving, labor saving, and processability, which are the characteristics of the barrel polishing method. , and it is possible to process a variety of materials to be polished. The present invention will be specifically explained below using examples. Example 1 Using the abrasive compositions shown in Table 1, a comparison test was conducted on the development of glossiness of various metals based on the following test method. The results are shown in Table-2. Polishing method [machine] Item to be polished [test piece]...High-speed centrifugal barrel aluminum, aluminum die-gust, zinc die-gust, brass, stainless steel,
Iron abrasive [stone]...High purity molten aluminum oxide.
Silica abrasive material for micro-cutting and mirror finishing [stone] Abrasive liquid composition: Addition amount of abrasive agent shown in Table 1
20g/Pretreatment: After degreasing with an alkaline detergent, surface activation treatment with 5% nitric acid.Evaluation method: Visual judgment was made as a relative comparison when the comparative formulation (A) was set as an index of 100. Evaluation after 30 minutes of centrifugal barrel treatment As shown in Table 2, the composition of the present invention has excellent lubricating effects on aluminum, aluminum diegast, zinc diegast, brass, stainless steel, and iron.
It has been confirmed that it exhibits a buffering effect, a cleaning effect, a water softening effect, and an antirust effect, and as a result of all these effects, it exhibits remarkable glossiness, making it extremely practical.
【表】【table】
【表】【table】
Claims (1)
シアルキルフエニールエーテル型、ポリオキシエ
チレン脂肪酸エステル型、ソルビタン脂肪酸エス
テル型、シヨ糖脂肪酸エステル型、およびグリセ
リン脂肪酸エステル型非イオン系界面活性剤から
選らばれた１種以上を１〜30重量部、オキシカ
ルボン酸または、その塩を２〜20重量部、アミ
ノポリカルボン酸または、その塩の１種以上を１
〜15重量部、アルカノールアミド型非イオン系
界面活性剤、粉末繊維素、カルボキシメチルセル
ロースNa塩から選択された化合物の１種以上を
10〜80重量部、およびホウ酸塩、亜硝酸塩、芳
香族カルボン酸または、その塩の１種以上を２〜
30重量部を含有することを特徴とするバレル研摩
液組成物。1 One type selected from polyoxyalkyl ether type, polyoxyalkyl phenyl ether type, polyoxyethylene fatty acid ester type, sorbitan fatty acid ester type, sucrose fatty acid ester type, and glycerin fatty acid ester type nonionic surfactant 1 to 30 parts by weight of the above, 2 to 20 parts by weight of oxycarboxylic acid or its salt, and 1 or more of aminopolycarboxylic acid or its salt.
~15 parts by weight of one or more compounds selected from alkanolamide type nonionic surfactants, powdered cellulose, and carboxymethyl cellulose Na salt.
10 to 80 parts by weight, and 2 to 80 parts by weight of one or more of borates, nitrites, aromatic carboxylic acids, or salts thereof.
A barrel polishing liquid composition containing 30 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22163285A JPS6280282A (en) | 1985-10-03 | 1985-10-03 | Composition for barrel polishing liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22163285A JPS6280282A (en) | 1985-10-03 | 1985-10-03 | Composition for barrel polishing liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6280282A JPS6280282A (en) | 1987-04-13 |
| JPS6363634B2 true JPS6363634B2 (en) | 1988-12-08 |
Family
ID=16769808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22163285A Granted JPS6280282A (en) | 1985-10-03 | 1985-10-03 | Composition for barrel polishing liquid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6280282A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI670140B (en) * | 2014-04-07 | 2019-09-01 | 日商新東工業股份有限公司 | Dry barrel grinding method and medium manufacturing method |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2715881B2 (en) * | 1993-12-28 | 1998-02-18 | 日本電気株式会社 | Photosensitive resin composition and pattern forming method |
| US6048595A (en) * | 1996-09-18 | 2000-04-11 | Tdk Corporation | Printed articiles having light-storing printed layers |
| WO2009034336A1 (en) * | 2007-09-14 | 2009-03-19 | Luxfer Group Limited | Stabilisation of stored gas |
| WO2009130248A1 (en) * | 2008-04-23 | 2009-10-29 | Martin-Nikolaus Meyn | Method for chemical deburring |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4839329A (en) * | 1971-09-25 | 1973-06-09 | ||
| JPS5090545A (en) * | 1973-12-13 | 1975-07-19 | ||
| JPS5324680A (en) * | 1976-08-20 | 1978-03-07 | Mitsubishi Electric Corp | Air conditioner |
| US4235051A (en) * | 1979-06-21 | 1980-11-25 | Fremont Industries, Inc. | Finishing compound for barrel and vibratory surface conditioning of ferrous and non-ferrous metals |
| JPS57149500A (en) * | 1981-03-12 | 1982-09-16 | Dai Ichi Kogyo Seiyaku Co Ltd | Degreasing detergent for metal |
| JPS5918782A (en) * | 1982-07-21 | 1984-01-31 | Dai Ichi Kogyo Seiyaku Co Ltd | Abrasive liquid composition |
| JPS6051792A (en) * | 1983-08-31 | 1985-03-23 | ライオン株式会社 | Detergent composition |
-
1985
- 1985-10-03 JP JP22163285A patent/JPS6280282A/en active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4839329A (en) * | 1971-09-25 | 1973-06-09 | ||
| JPS5090545A (en) * | 1973-12-13 | 1975-07-19 | ||
| JPS5324680A (en) * | 1976-08-20 | 1978-03-07 | Mitsubishi Electric Corp | Air conditioner |
| US4235051A (en) * | 1979-06-21 | 1980-11-25 | Fremont Industries, Inc. | Finishing compound for barrel and vibratory surface conditioning of ferrous and non-ferrous metals |
| JPS57149500A (en) * | 1981-03-12 | 1982-09-16 | Dai Ichi Kogyo Seiyaku Co Ltd | Degreasing detergent for metal |
| JPS5918782A (en) * | 1982-07-21 | 1984-01-31 | Dai Ichi Kogyo Seiyaku Co Ltd | Abrasive liquid composition |
| JPS6051792A (en) * | 1983-08-31 | 1985-03-23 | ライオン株式会社 | Detergent composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI670140B (en) * | 2014-04-07 | 2019-09-01 | 日商新東工業股份有限公司 | Dry barrel grinding method and medium manufacturing method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6280282A (en) | 1987-04-13 |
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