JPS6360791A - Transfer recording medium - Google Patents
Transfer recording mediumInfo
- Publication number
- JPS6360791A JPS6360791A JP61205607A JP20560786A JPS6360791A JP S6360791 A JPS6360791 A JP S6360791A JP 61205607 A JP61205607 A JP 61205607A JP 20560786 A JP20560786 A JP 20560786A JP S6360791 A JPS6360791 A JP S6360791A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- ink
- light
- adhesive layer
- transfer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000012546 transfer Methods 0.000 title claims abstract description 70
- 239000010410 layer Substances 0.000 claims abstract description 99
- 239000012790 adhesive layer Substances 0.000 claims abstract description 55
- 239000011230 binding agent Substances 0.000 claims abstract description 25
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 17
- 229920001971 elastomer Polymers 0.000 claims abstract description 11
- 239000005060 rubber Substances 0.000 claims abstract description 11
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 6
- -1 azide compound Chemical class 0.000 claims description 58
- 239000001993 wax Substances 0.000 claims description 17
- 150000008049 diazo compounds Chemical class 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 10
- 230000006378 damage Effects 0.000 claims description 4
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 93
- 238000000034 method Methods 0.000 description 26
- 229920000139 polyethylene terephthalate Polymers 0.000 description 24
- 239000005020 polyethylene terephthalate Substances 0.000 description 24
- 229920005989 resin Polymers 0.000 description 22
- 239000011347 resin Substances 0.000 description 22
- 238000006243 chemical reaction Methods 0.000 description 20
- 239000000203 mixture Substances 0.000 description 20
- 238000002844 melting Methods 0.000 description 16
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 15
- 239000003973 paint Substances 0.000 description 15
- 239000000049 pigment Substances 0.000 description 15
- 238000000859 sublimation Methods 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 230000008022 sublimation Effects 0.000 description 14
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000975 dye Substances 0.000 description 11
- 238000011156 evaluation Methods 0.000 description 10
- 239000007789 gas Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000003086 colorant Substances 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 235000019271 petrolatum Nutrition 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 240000004713 Pisum sativum Species 0.000 description 4
- 235000010582 Pisum sativum Nutrition 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 241000519995 Stachys sylvatica Species 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 239000004203 carnauba wax Substances 0.000 description 4
- 235000013869 carnauba wax Nutrition 0.000 description 4
- 230000015556 catabolic process Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 238000005562 fading Methods 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 230000031700 light absorption Effects 0.000 description 4
- 239000004200 microcrystalline wax Substances 0.000 description 4
- 235000019808 microcrystalline wax Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 238000006303 photolysis reaction Methods 0.000 description 4
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 229910052724 xenon Inorganic materials 0.000 description 4
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- CJPQIRJHIZUAQP-MRXNPFEDSA-N benalaxyl-M Chemical compound CC=1C=CC=C(C)C=1N([C@H](C)C(=O)OC)C(=O)CC1=CC=CC=C1 CJPQIRJHIZUAQP-MRXNPFEDSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 238000007757 hot melt coating Methods 0.000 description 3
- 239000012943 hotmelt Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000012170 montan wax Substances 0.000 description 3
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 3
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- FWLHAQYOFMQTHQ-UHFFFAOYSA-N 2-N-[8-[[8-(4-aminoanilino)-10-phenylphenazin-10-ium-2-yl]amino]-10-phenylphenazin-10-ium-2-yl]-8-N,10-diphenylphenazin-10-ium-2,8-diamine hydroxy-oxido-dioxochromium Chemical compound O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.O[Cr]([O-])(=O)=O.Nc1ccc(Nc2ccc3nc4ccc(Nc5ccc6nc7ccc(Nc8ccc9nc%10ccc(Nc%11ccccc%11)cc%10[n+](-c%10ccccc%10)c9c8)cc7[n+](-c7ccccc7)c6c5)cc4[n+](-c4ccccc4)c3c2)cc1 FWLHAQYOFMQTHQ-UHFFFAOYSA-N 0.000 description 2
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical compound Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 2
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 2
- 239000000986 disperse dye Substances 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 229920001249 ethyl cellulose Polymers 0.000 description 2
- 235000019325 ethyl cellulose Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- SSZBUIDZHHWXNJ-UHFFFAOYSA-N palmityl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCCCC SSZBUIDZHHWXNJ-UHFFFAOYSA-N 0.000 description 2
- 235000019809 paraffin wax Nutrition 0.000 description 2
- 230000015843 photosynthesis, light reaction Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002492 poly(sulfone) Polymers 0.000 description 2
- 229920000767 polyaniline Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000001052 yellow pigment Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- XMKLTEGSALONPH-UHFFFAOYSA-N 1,2,4,5-tetrazinane-3,6-dione Chemical compound O=C1NNC(=O)NN1 XMKLTEGSALONPH-UHFFFAOYSA-N 0.000 description 1
- FHDQFPCQZMLBFE-UHFFFAOYSA-N 1-[(4e)-4-diazo-2-methylcyclohexa-1,5-dien-1-yl]pyrrolidine Chemical compound C1=CC(=[N+]=[N-])CC(C)=C1N1CCCC1 FHDQFPCQZMLBFE-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- FFRXPGGSKOZZPD-UHFFFAOYSA-N 2-[(5-diazo-2-ethylcyclohexa-1,3-dien-1-yl)amino]ethanol Chemical compound CCC1=C(NCCO)CC(=[N+]=[N-])C=C1 FFRXPGGSKOZZPD-UHFFFAOYSA-N 0.000 description 1
- PHDUUMRDIHMMNC-UHFFFAOYSA-N 2-azidobenzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1N=[N+]=[N-] PHDUUMRDIHMMNC-UHFFFAOYSA-N 0.000 description 1
- JCBWQNLTYXTHBZ-UHFFFAOYSA-N 2-azidobenzoic acid Chemical compound OC(=O)C1=CC=CC=C1N=[N+]=[N-] JCBWQNLTYXTHBZ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- VVKHPAIJUBQTMQ-UHFFFAOYSA-N 4-(2,5-dibutoxy-4-diazocyclohexa-1,5-dien-1-yl)morpholine Chemical compound C1=C(OCCCC)C(=[N+]=[N-])CC(OCCCC)=C1N1CCOCC1 VVKHPAIJUBQTMQ-UHFFFAOYSA-N 0.000 description 1
- SCETWWDGKCBPMK-UHFFFAOYSA-N 4-[(4e)-4-diazocyclohexa-1,5-dien-1-yl]morpholine Chemical compound C1=CC(=[N+]=[N-])CC=C1N1CCOCC1 SCETWWDGKCBPMK-UHFFFAOYSA-N 0.000 description 1
- OAWPLNZPUZMDMF-UHFFFAOYSA-N 4-diazo-n,n-diethyl-3-methoxycyclohexa-1,5-dien-1-amine Chemical compound CCN(CC)C1=CC(OC)C(=[N+]=[N-])C=C1 OAWPLNZPUZMDMF-UHFFFAOYSA-N 0.000 description 1
- YZYFPMLAGIGAJJ-UHFFFAOYSA-N 4-diazo-n,n-diethylcyclohexa-1,5-dien-1-amine Chemical compound CCN(CC)C1=CCC(=[N+]=[N-])C=C1 YZYFPMLAGIGAJJ-UHFFFAOYSA-N 0.000 description 1
- LAXPFHMCFLHGKK-UHFFFAOYSA-N 4-diazo-n,n-dimethylcyclohexa-1,5-dien-1-amine Chemical compound CN(C)C1=CCC(=[N+]=[N-])C=C1 LAXPFHMCFLHGKK-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Natural products C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 108091005944 Cerulean Proteins 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 229920001612 Hydroxyethyl starch Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229930192627 Naphthoquinone Natural products 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920000265 Polyparaphenylene Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000004163 Spermaceti wax Substances 0.000 description 1
- ZIJKGAXBCRWEOL-SAXBRCJISA-N Sucrose octaacetate Chemical compound CC(=O)O[C@H]1[C@H](OC(C)=O)[C@@H](COC(=O)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1 ZIJKGAXBCRWEOL-SAXBRCJISA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000001344 [(2S,3S,4R,5R)-4-acetyloxy-2,5-bis(acetyloxymethyl)-2-[(2R,3R,4S,5R,6R)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxyoxolan-3-yl] acetate Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- HFVAFDPGUJEFBQ-UHFFFAOYSA-M alizarin red S Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=C(S([O-])(=O)=O)C(O)=C2O HFVAFDPGUJEFBQ-UHFFFAOYSA-M 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000010407 ammonium alginate Nutrition 0.000 description 1
- 239000000728 ammonium alginate Substances 0.000 description 1
- KPGABFJTMYCRHJ-YZOKENDUSA-N ammonium alginate Chemical compound [NH4+].[NH4+].O1[C@@H](C([O-])=O)[C@@H](OC)[C@H](O)[C@H](O)[C@@H]1O[C@@H]1[C@@H](C([O-])=O)O[C@@H](O)[C@@H](O)[C@H]1O KPGABFJTMYCRHJ-YZOKENDUSA-N 0.000 description 1
- 239000012164 animal wax Substances 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229940092738 beeswax Drugs 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical class FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229920003090 carboxymethyl hydroxyethyl cellulose Polymers 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Substances ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 210000001520 comb Anatomy 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 101150084411 crn1 gene Proteins 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- FDPIMTJIUBPUKL-UHFFFAOYSA-N dimethylacetone Natural products CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 1
- LTYMSROWYAPPGB-UHFFFAOYSA-N diphenyl sulfide Chemical compound C=1C=CC=CC=1SC1=CC=CC=C1 LTYMSROWYAPPGB-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920006015 heat resistant resin Polymers 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- DNZMDASEFMLYBU-RNBXVSKKSA-N hydroxyethyl starch Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@@H]1O.OCCOC[C@H]1O[C@H](OCCO)[C@H](OCCO)[C@@H](OCCO)[C@@H]1OCCO DNZMDASEFMLYBU-RNBXVSKKSA-N 0.000 description 1
- 229940050526 hydroxyethylstarch Drugs 0.000 description 1
- 229920002681 hypalon Polymers 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 239000000983 mordant dye Substances 0.000 description 1
- WIJIGKKVWSUYKJ-UHFFFAOYSA-N n,n-dibenzyl-4-diazocyclohexa-1,5-dien-1-amine Chemical compound C1=CC(=[N+]=[N-])CC=C1N(CC=1C=CC=CC=1)CC1=CC=CC=C1 WIJIGKKVWSUYKJ-UHFFFAOYSA-N 0.000 description 1
- XGHSCBCFEWUDQG-UHFFFAOYSA-N n-[(4-diazo-1-methylcyclohexa-2,5-dien-1-yl)methyl]aniline Chemical compound C=1C=CC=CC=1NCC1(C)C=CC(=[N+]=[N-])C=C1 XGHSCBCFEWUDQG-UHFFFAOYSA-N 0.000 description 1
- GKIGWMCWSLVNNQ-UHFFFAOYSA-N n-docosylbenzamide Chemical compound CCCCCCCCCCCCCCCCCCCCCCNC(=O)C1=CC=CC=C1 GKIGWMCWSLVNNQ-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 150000002791 naphthoquinones Chemical class 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000002165 photosensitisation Effects 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000172 poly(styrenesulfonic acid) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229940005642 polystyrene sulfonic acid Drugs 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940068984 polyvinyl alcohol Drugs 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000131 polyvinylidene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical compound O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 235000019385 spermaceti wax Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005504 styryl group Chemical group 0.000 description 1
- 229940013883 sucrose octaacetate Drugs 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 238000013518 transcription Methods 0.000 description 1
- 230000035897 transcription Effects 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
- 239000012178 vegetable wax Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/423—Intermediate, backcoat, or covering layers characterised by non-macromolecular compounds, e.g. waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Impression-Transfer Materials And Handling Thereof (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は高解像の文字或いは画像を印刷するに好適なモ
ノクロ及びカラー転写媒体に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to monochrome and color transfer media suitable for printing high-resolution characters or images.
（従来の技術）
近年オフィスオートメーションの発展により種種の端末
機が要求されており、中でも電気信号を可視像に変換す
る記録装置、いわゆるプリンタの需要は大きいものがあ
るが、性能的に満足のゆくものが少ない。例えば一般的
に用いられている記録方式として、インキジェット方式
、電子写真方式、熱転写方式等があるが、液体或いはト
ナー等の粉体を使用することによる装置の保守、操作性
の複雑さ、或いはサーマルヘッドを使用するため、ヘッ
ドの寿命が短かく、印字速度が遅い等の問題があった。(Prior art) In recent years, with the development of office automation, various types of terminal devices have been required. Among them, there is a large demand for recording devices that convert electrical signals into visible images, so-called printers. There is not much to go. For example, commonly used recording methods include the inkjet method, electrophotographic method, and thermal transfer method. Since a thermal head is used, there are problems such as a short head life and slow printing speed.
そこで高速で比較的解像度の良い文字或いは画像形成手
段として、放電転写法が知られており、これに関し例え
ば特公昭４５−１９８１９号公報に示されているサーモ
グラフ複写法、特公昭５７−２２０３０号公報の転写媒
体が開示されている。Therefore, the discharge transfer method is known as a means for forming characters or images at high speed and with relatively good resolution, and in this regard, for example, the thermographic copying method disclosed in Japanese Patent Publication No. 19819/1982, and the method of copying disclosed in Japanese Patent Publication No. 22030/1989. A transfer medium of the publication is disclosed.
以下、従来の放電転写法を図面に従って説明する。The conventional discharge transfer method will be explained below with reference to the drawings.
第５図はその方法で用いられる転写媒体の断面図で支持
体１の上面に光反射層２、下面に熱転写性固体インキ層
３が設けられている。なお図示してないが支持体１と光
反射層２との間に粗面化層を設ければ光反射層の放電破
壊を一層容易にし、かつ安定にさせることができる。FIG. 5 is a sectional view of a transfer medium used in this method, in which a light reflecting layer 2 is provided on the upper surface of a support 1, and a thermally transferable solid ink layer 3 is provided on the lower surface. Although not shown, if a roughened layer is provided between the support 1 and the light-reflecting layer 2, the light-reflecting layer can be more easily destroyed by discharge and stabilized.
第６図〜第８図は前記記録媒体を用いた印刷工程を示す
もので、第５図と同一部分には同じ符号が付されている
。４は受像紙、５はキセノンランプ、６は閃光を示す。6 to 8 show the printing process using the recording medium, and the same parts as in FIG. 5 are given the same reference numerals. 4 is a receiving paper, 5 is a xenon lamp, and 6 is a flash light.
印刷工程は第６図のように周知の放電破壊記録の手段に
より、光反射層２を情報の・千ターンに応じて除去し、
第７図のように熱転写性固体インキ層３を塗布した面と
受像紙４とを密着させ、光反射層２上からキセノンフラ
ッジ−ランプ５により紫外線、可視光線及び赤外線を含
む閃光６を全面に照射せしめる。In the printing process, as shown in FIG. 6, the light reflecting layer 2 is removed according to the number of turns of information by means of well-known discharge destruction recording.
As shown in FIG. 7, the surface coated with the thermally transferable solid ink layer 3 is brought into close contact with the image receiving paper 4, and a xenon flood lamp 5 is used to illuminate the entire surface with a flash of light 6 containing ultraviolet rays, visible light, and infrared rays. irradiate it.
すると光反射層２が残っている部分に照射された閃光は
反射され、光反射層が除去された部分に照射された閃光
は支持体１を通過して熱転写性固体インキ層３に到達す
る。この際、インキ層中の色料が例えばカーボンブラッ
クのような紫外域から赤外域にわたる光吸収性顔料であ
り、ざヒクルが例えばワックスのような熱溶融性バイン
ダーである場合、入射した閃光はカーボンブラックに吸
収される結果、この吸収光エネルギーが熱エネルギーへ
と有効に変換される。この熱エネルギーにより熱溶融性
インキ層が加熱溶融する結果、インキ層面に密着された
受像紙上へ転写・定着される。Then, the flashing light irradiated on the portion where the light-reflecting layer 2 remains is reflected, and the flashing light irradiating the portion where the light-reflecting layer has been removed passes through the support 1 and reaches the thermal transferable solid ink layer 3. At this time, if the coloring material in the ink layer is a light-absorbing pigment ranging from ultraviolet to infrared, such as carbon black, and the liquid is a heat-melting binder such as wax, the incident flash light is As a result of being absorbed by the black, this absorbed light energy is effectively converted into thermal energy. The heat-melting ink layer is heated and melted by this thermal energy, and as a result, the ink layer is transferred and fixed onto the image-receiving paper that is in close contact with the surface of the ink layer.
これにより白黒の転写画像７を得ることができる。As a result, a black and white transferred image 7 can be obtained.
第９図、第１０図はインキ層中の色料が、シアン、マゾ
エンタ、及びイエロウ色の特定の波長域にのみ光吸収量
を示す顔料である場合にして、入射した閃光の光吸収量
を増加させて、よシ有効に熱エネルギーに変換させるた
めに、カーボンブラック、黒鉛、アニリンブラック等の
紫外域から赤外域に亘る光吸収性顔料を含む光熱変換層
８を設けた構造のもので光熱変換層を設けたカラー転写
の場合も、白黒同様の工程で印刷できるようになりてい
る。Figures 9 and 10 show the light absorption amount of incident flash light when the colorant in the ink layer is a pigment that absorbs light only in specific wavelength ranges of cyan, mazoenta, and yellow. In order to increase the amount of light and convert it into thermal energy more effectively, the structure includes a light-to-heat conversion layer 8 containing a light-absorbing pigment ranging from the ultraviolet to the infrared range, such as carbon black, graphite, or aniline black. Color transfer with a conversion layer can also be printed using the same process as black and white.
（発明が解決しようとする問題点）
しかしながら上記のようか従来の放電破壊記録シートと
熱転写シートとが一体化されている構成では、表面平滑
性の高い受像紙を用いた場合には比較的鮮明で、かつ所
望の濃度を有し、放電破壊記録による・２ターンをほぼ
忠実に転写せしめることができるもののコピー用紙のよ
うな普通紙や欧米で業務用紙として用いられているポン
ド紙の如き、表面平滑度の低い受像紙を用いた場合には
、インキの転写が、インキシートと受像紙との接点、及
びその近傍のみに限定されるため、ペタ転写時の「白抜
けＪ及び細線転写時の「カケ」「ハヌケ」と呼ばれる転
写されない箇所が出現したり、細線の「トギレ」や「カ
スレ」が生じ易いという問題がある。(Problems to be Solved by the Invention) However, with the above-mentioned configuration in which the conventional discharge breakdown recording sheet and thermal transfer sheet are integrated, relatively clear images can be obtained when a receiving paper with a high surface smoothness is used. Although it has the desired density and can almost faithfully transfer two turns using discharge breakdown recording, it can be used on surfaces such as plain paper such as copy paper and pound paper used as business paper in Europe and America. When using image-receiving paper with low smoothness, ink transfer is limited to the contact point between the ink sheet and the image-receiving paper and the vicinity thereof. There are problems in that areas that are not transferred, called "kake" and "hanukke", tend to appear, and "togire" and "fading" in thin lines tend to occur.
又、転写記録品質の向上のために、熱溶融性バインダー
の融点や溶融粘度を低下させたり、熱昇華性塗料の昇華
開始温度を低下させることも考えられるが、この場合に
は「ブリッジ現象」と呼ばれている未解像転写が発生し
た勺、比較的低温に於ても転写が生じ易くなる結果、保
存性の低下及び非記録部分の地汚れ（カブリ）現象が別
の問題として出現する。Furthermore, in order to improve the transfer recording quality, it is possible to lower the melting point and melt viscosity of the heat-melting binder, or to lower the sublimation start temperature of the heat-sublimable paint, but in this case, the "bridge phenomenon" When unresolved transfer occurs, the transfer tends to occur even at relatively low temperatures, resulting in decreased storage stability and fogging in non-recorded areas as other problems. .
又、放電転写方式の最大の特長は放電記録による高解像
の文字や画像を忠実にかつ鮮明に転写させることである
が、先に述べた従来の構成に於ては転写像のエツジ部の
「ニジミ」や「Ｐヶ」による印字太りが見られることが
多く、従ってコントラストやシャープネスに欠けたいわ
ゆる「キレ」の悪い品質になり易いという問題があった
。In addition, the greatest feature of the discharge transfer method is that high-resolution characters and images can be faithfully and clearly transferred by discharge recording, but in the conventional configuration mentioned above, the edges of the transferred image are Print thickening due to "bleeding" or "P" is often seen, and therefore, there is a problem in that the quality tends to be so-called "sharp", lacking contrast and sharpness.
なお更に又、放電転写方式により、フルカラーの転写像
を得る際に要求される各原色の階調性表現に関すること
であるが、従来の構成に於ては放電破壊記録で得られた
階調性表現が忠実に転写され難いという問題点がある。Furthermore, regarding the gradation expression of each primary color required when obtaining a full-color transferred image using the discharge transfer method, in the conventional configuration, the gradation obtained by discharge breakdown recording is There is a problem that it is difficult to faithfully transcribe the expression.
即ち、ディデー法等による面積階調表現の放電破壊記録
、ｐＪ？ターンに於ては、インキ層又は光熱変換層に吸
収される閃光エネルギー照射面積を記録ドツト密度に対
応して制御することができるものの、充分な階調性を得
るためには転写時の解像性に無理が生じ、転写記録濃度
は一定値に飽和する傾向を有し、高いドツト密度での階
調表現は困難であった。That is, the discharge breakdown record of area gradation expression using the Dide method etc., pJ? In turn, the area irradiated with flash energy absorbed by the ink layer or photothermal conversion layer can be controlled in accordance with the recording dot density, but in order to obtain sufficient gradation, the resolution at the time of transfer must be adjusted. The transfer recording density tends to be saturated at a constant value, and it is difficult to express gradations with high dot density.
（問題点を解決するための手段）
本発明は上記の如き実情に鑑みその問題点を解決すべく
鋭意検討の結果なされたもので、その概要は以下のとお
りである。(Means for Solving the Problems) The present invention has been made as a result of intensive studies to solve the problems in view of the above-mentioned actual circumstances, and the outline thereof is as follows.
光透過性支持体上に放電破壊記録で除去可能な光反射層
を設けたマスクシートと、基体上に熱転写性固体インキ
層を設けたインキシートとを、重ね合せて構成される転
写記録媒体に於て、前記マスクシートの支持体とインキ
シートの基体とを光分解性化合物を含有する接着層によ
り貼シ合わせたことを特徴とする転写記録媒体である。A transfer recording medium consisting of a mask sheet having a light-reflecting layer removable by electrical discharge destruction recording on a light-transmitting support and an ink sheet having a heat-transferable solid ink layer on a substrate are superimposed. The transfer recording medium is characterized in that the support of the mask sheet and the base of the ink sheet are laminated together with an adhesive layer containing a photodegradable compound.
ここに接着層に用いられるバインダーは熱可塑性樹脂類
、ワックス類又はゴム類の中から選ばれた少なくとも１
種類であ夛、光分解性化合物の代表的なものはジアゾ化
合物及びアジド化合物である。The binder used in the adhesive layer is at least one selected from thermoplastic resins, waxes, and rubbers.
Among the many types of photodegradable compounds, representative ones are diazo compounds and azide compounds.
本発明の構造例について図面により説明する。A structural example of the present invention will be explained with reference to the drawings.
第１図〜第４図は本発明の実施例で、第１図は支持体１
ａの表面に光反射層２を設け、その下面に光分解性化合
物を含有する接着層１０を形成してなるマスクシートと
、基体１ｂの下面に熱転写性固体インキ層３を設けたイ
ンキシートとを前記接着層１０により接合したものにし
て、特に熱転写性固体インキ層３にはカーボンブランク
等を用いた黒色の熱溶融性インキ層とする場合に好適な
構成図である。1 to 4 show examples of the present invention, and FIG. 1 shows the support 1.
a mask sheet with a light reflective layer 2 provided on the surface of the substrate 1b and an adhesive layer 10 containing a photodegradable compound formed on the bottom surface thereof; and an ink sheet with a thermally transferable solid ink layer 3 provided on the bottom surface of the substrate 1b. This is a configuration diagram suitable for a case in which the thermally transferable solid ink layer 3 is a black heat-melting ink layer using a carbon blank or the like, in which the two are bonded together by the adhesive layer 10.
又、第２図〜第４図はマスクシート側の構成は第１図と
同様であるが、インキシート側の構成を変えた実施例で
、第２図はインキシートの基体の上面に光熱変換層８を
設けた場合、第３図はインキシートの基体の下面に光熱
変換層８を介して熱転写性固体インキ層３を設けた場合
、第４図は基体ｌｂ中に光熱変換材料を配合し、光熱変
換層８を兼ねた層とした場合を示し、熱昇華性インキ層
又はカラーの熱溶融性インキ層の場合である。なお第１
図と同一部分には同一符号が付されている。In addition, Figures 2 to 4 show examples in which the structure of the mask sheet side is the same as that of Figure 1, but the structure of the ink sheet side is changed. When the layer 8 is provided, FIG. 3 shows the case where the thermally transferable solid ink layer 3 is provided on the lower surface of the base of the ink sheet via the light-to-heat conversion layer 8, and FIG. , shows a case where the layer also serves as the light-to-heat conversion layer 8, and is a case of a heat-sublimable ink layer or a color heat-fusible ink layer. Note that the first
The same parts as in the figure are given the same reference numerals.
なお、図示してないが、光分解性化合物を含有する接着
層は基体側に設けてもよいことは勿論である。Although not shown, it goes without saying that an adhesive layer containing a photodegradable compound may be provided on the substrate side.
（作用） 本発明の構成に基づく作用について説明する。(effect) The effects based on the configuration of the present invention will be explained.
本発明者等の検討したところによれば、放電転写方式の
代表的プロセスは以下の順序で行なわれるものと仮定で
きる。According to the studies conducted by the present inventors, it can be assumed that a typical process of the discharge transfer method is performed in the following order.
１）光反射層上から閃光を照射する。1) Irradiate flash light from above the light reflective layer.
１１）放電破壊記録面へ閃光が入射し、非破壊記録面即
ち光反射層面から閃光が反射する。11) A flash of light is incident on the discharge-destructive recording surface, and is reflected from the non-destructive recording surface, that is, the light-reflecting layer surface.
ｉｉｉ ） 放電破壊記録面入射光の接着層中の光分
解性化合物による光吸収
１ｖ）光分解性化合物の光分解とこれに伴なうガスの発
生
）接着層透過元の固体インキ層及び又は光熱変換層での
光吸収
Ｖり 吸収光エネルギーの熱エネルギーへの変換ｖ１
１）固体インキ層温度の上昇と溶融温度（熱溶融性イン
キ層の場合）又は昇華開始温度（熱昇華性インキ層の場
合）への到達
ｖｉｉｏ 固体インキ層の溶融潜熱即ち融解熱（熱溶
融性インキ層の場合）又は昇華潜熱即ち昇華熱（昇華性
インキ層の場合）の吸収
ｉ×）固体インキ層の熱溶融（熱溶融性インキ層の場合
）又は熱昇華性色料の昇華（熱昇華性インキ層の場合）
の開始
Ｘ）受像紙面へのインキの滲透（熱溶融性インキ層の場
合）又は熱昇華性色料の付着（ｇＡ昇華性インキ層の場
合）
Ｘ＋） 固体インキ層の凝固潜熱即ち凝固熱（熱溶融
性インキ層の場合）又は昇華潜熱即ち昇華熱（熱昇華性
インキ層の場合）の基体側及び／又は受像紙側への熱量
放散
×１１）転写インキ層温度の室温への降下に伴なう基体
側及び／又は受像紙側への熱量放散
ｘｉｉ＋ ）媒体と受像紙との分離時に於て受像紙／固
体インキ間接着力が固体インキ／インキシート基体間接
着力より大であることにより、受像紙面への固体インキ
の転写
以上によって固体インキの受像紙への転写が完了する。iii) Light absorption by the photodegradable compound in the adhesive layer of the light incident on the discharge destruction recording surface 1v) Photodecomposition of the photodegradable compound and generation of gas accompanying this) Solid ink layer and/or photothermal from which the adhesive layer is transmitted Light absorption in the conversion layer Conversion of absorbed light energy to thermal energy v1
1) Increasing the temperature of the solid ink layer and reaching the melting temperature (in the case of a heat-fusible ink layer) or the sublimation start temperature (in the case of a heat-fusible ink layer) absorption of the latent heat of sublimation, i.e. heat of sublimation (in the case of a sublimable ink layer) or absorption of the latent heat of sublimation, i.e. heat of sublimation (in the case of a transparent ink layer)
X) Penetration of ink into the image-receiving paper surface (in the case of a heat-fusible ink layer) or adhesion of a heat-sublimable colorant (in the case of a gA sublimation ink layer) (in the case of a fusible ink layer) or latent heat of sublimation, that is, heat of sublimation (in the case of a thermal sublimation ink layer), dissipation of heat amount to the substrate side and/or the receiving paper side x 11) As the transfer ink layer temperature falls to room temperature. Dissipation of heat to the substrate side and/or to the receiving paper side The transfer of the solid ink to the image-receiving paper is completed by the above steps.
本発明は上記の作用に於て特に光分解性化合物を接着層
に含有させたことにあり、これに基いて以下の効果を生
ずる
１）インキ層面の受像紙面への押圧
プロセス１いに於て発生したガスにより、インキシート
支持体がマスクシートから分離又は押し上げられる結果
、放電記録面直下のインキ層面を受像紙面の粗さにそっ
て押圧させる。又、プロセス×のに於て、インキシート
基体側へ放散させる熱量により、接着層中のガスが熱膨
張する結果、抑圧効果が増幅される。このガスによる押
圧効果により、低い密着圧に於ても、表面平滑度の低い
受像紙に対して、ペタ転写時の白「ヌケ」、細線転写時
の「カケ」「トイレ」及び「カスレ」等が防止され、高
階像性かつ高濃度の転写が可能となる。The present invention achieves the above-mentioned effect by specifically incorporating a photodegradable compound into the adhesive layer, and based on this, the following effects are produced: 1) In the process of pressing the ink layer surface onto the image receiving paper surface 1. The generated gas separates or pushes up the ink sheet support from the mask sheet, and as a result, the ink layer surface directly below the discharge recording surface is pressed along the roughness of the image receiving paper surface. Furthermore, in process x, the gas in the adhesive layer thermally expands due to the amount of heat dissipated to the ink sheet substrate side, and as a result, the suppressing effect is amplified. Due to the pressure effect of this gas, even at low adhesion pressure, white "missing" during peta transfer, "chips", "toilet", and "smearing" occur during thin line transfer, etc. on receiving paper with low surface smoothness. This makes it possible to transfer images with high dimensional image quality and high density.
２）凝固熱又は昇華性のマスクシート支持体側への放散
抑制
プロセス×１）に於て従来の構成では基体側に放散され
ていた熱量が界面の接着層中に発生したガスの断熱効果
によりマスフシート支持体側へ放散が大幅に抑制される
。2) In the process of suppressing the dissipation of solidification heat or sublimation to the mask sheet support side, the amount of heat that would have been dissipated to the substrate side in the conventional configuration is reduced to the mask sheet due to the heat insulating effect of the gas generated in the adhesive layer at the interface. Diffusion toward the support side is significantly suppressed.
ここに断熱効果とはガス熱伝導度の値が一般の固体の値
に比べ遥かに小さいことを利用したものである。その結
果、抑制された分の熱量はインキ基体及びインキ層内に
蓄積され、インキ層温度を更に昇温させる。この結果イ
ンキが熱溶融性の場合には溶融粘度の低下、溶融状態の
保持時間の増加を促進させる。他方熱昇華性の場合には
、昇華性色料の昇華量を大幅に増加させる。又、蓄積さ
れた熱量により、インキシートの基体に一時的に軟化及
び伸びが生じるために、インキ層面が、受像紙面の粗さ
に沿りて密着し易くなる。このガスの断熱効果により低
い密着圧に於ても、表面平滑度の低い受像紙に対してペ
タ時の「白ヌケ」、細線転写時の「カケ」１「トイレ」
及び「カスレ」等が防止され、高階調性かつ高濃度の転
写が可能となる。The adiabatic effect here takes advantage of the fact that the value of gas thermal conductivity is much smaller than that of general solids. As a result, the suppressed amount of heat is accumulated in the ink substrate and the ink layer, further increasing the ink layer temperature. As a result, when the ink is hot-melting, the melt viscosity decreases and the molten state retention time increases. On the other hand, in the case of thermal sublimation, the amount of sublimation of the sublimable colorant is significantly increased. In addition, the accumulated heat temporarily softens and stretches the base of the ink sheet, making it easier for the ink layer surface to adhere to the roughness of the image-receiving paper surface. Due to the insulating effect of this gas, even at low adhesion pressure, "white spots" when printing on paper with low surface smoothness, "chips" and "toilet" when transferring thin lines, etc.
This prevents "fading" and the like, and enables high-gradation and high-density transfer.
以上列記した各作用効果は複合して、放電破ン記録によ
る高解像の文字や画像を「ニジミ」や「ボケ」のない「
キレＪの良い忠実な転写記録品質を得ることを可能なら
しめ、同時に階調性表現転写記録品質を著しく改善し、
カラーの場合はフルカラーへの適用を可能ならしめるも
のである。The functions and effects listed above combine to produce high-resolution characters and images with no blurring or blurring due to discharge rupture recording.
It makes it possible to obtain faithful transfer recording quality with good sharpness, and at the same time significantly improves the gradation expression transfer recording quality,
In the case of color, it is possible to apply it to full color.
以下接着層の形成について説明する。Formation of the adhesive layer will be explained below.
本発明で用いられる接着層には以下の特性のものが要求
される。The adhesive layer used in the present invention is required to have the following properties.
１）層中に光分解性化合物を均一に溶解もしくは分散す
ることが可能であること。1) It is possible to uniformly dissolve or disperse the photodegradable compound in the layer.
２）光照射時における光分解性化合物が効果的に光分解
し、かつガスの均一な発生が可能であること。2) A photodegradable compound can be effectively photodecomposed when irradiated with light, and gas can be uniformly generated.
３）光分解に基づくガスの発生に伴ない、インキシート
の基体を押し上げるだけの弾力性、柔軟性及び延伸性を
有すること。3) It must have elasticity, flexibility, and stretchability to push up the base of the ink sheet as gas is generated due to photolysis.
４）マスクシートとインキシートの貼シ合わせが可能な
程度に粘着性又は接着性を有すること。4) It must have tackiness or adhesion to the extent that the mask sheet and ink sheet can be pasted together.
５）光分解性化合物による光吸収を除き、光透過率が高
いこと。5) High light transmittance, excluding light absorption by photodegradable compounds.
上記の如き特性は主として接着層を形成するパイングー
の性質により支配されるが、本発明に好適な・々イング
ー材料系としては熱可塑性樹脂類、ワックス類又はゴム
類の中から選ばれた少くとも１種類を掲げることができ
る。Although the properties described above are mainly controlled by the properties of the adhesive layer forming the adhesive layer, the adhesive material system suitable for the present invention is at least one selected from thermoplastic resins, waxes, or rubbers. One type can be listed.
ここに用いられる熱可塑性樹脂の具体例としては、ポリ
エチレン、ポリプロピレン、ポリブチレン、ポリブタジ
ェン等のオレフィン系樹脂、ポリメタクリル酸メチル、
エチレン・アクリル酸エチル共重合体等のアクリル系樹
脂、ポリスチレン、ＡＳ樹脂、ＢＳ樹脂、ＡＢＳ樹脂等
のスチレン系樹脂、ポリ塩化ビニル、Ｉり塩化ビニリデ
ン、ポリ酢酸ビニル、エチレン・酢酸ビニル共重合体、
ポリビニルブチラール、塩化ビニリデン、アクリルニト
リル共重合体、塩化ビニル・酢酸ビニル共重合体、塩化
ビニル・塩化ビニリデン共重合体、プロピレン・塩化ビ
ニル共重合体等のビニル系樹脂、ナイロン６、ナイロン
６６、ナイロン１２等のポリアミド樹脂、飽和ポリエス
テル樹脂、ポリカーブネート樹脂、ポリアセタール樹脂
、ポリフェニレンオキシド樹脂、ポリスェニレンスル７
アイド樹脂、ポリスルホン樹脂、ポリウレタン樹脂、テ
トラフルオロエチレン、トリフルオロエチレン、ポリス
フ化ビニリデン等のフッ他樹脂、エチルセルロース、酢
酸セルロース、ニトロセルロース等の繊維素系樹脂、ニ
ブキシ樹脂、アイオノマー樹脂、ロジン誘導体樹脂等の
有機溶剤可溶性樹脂系、ゼラチン、ニカワ、カゼイン、
ヒドロキシエチルセルロース、カルゲキシメチルセルロ
ース、メチルセルロース、カルボキシメチルヒドロキシ
エチルセルロース、ヒドロキシエチルデンプン、アラビ
アゴム、サッカロースオクタアセテート、アルギン酸ア
ンモニウム、アルギン酸ソーダ、ポリビニルアルコール
、ポリビニルブチラール、ポリビニルピロリドン、ポリ
ビニルアミン、ポリエチレンオキシド、ポリスチレンス
ルホン酸、ポリアクリル酸、ポリアミド、イソブチレン
無水マレイン酸共重合体等の水溶性樹脂系及び前記した
有機溶剤可溶性樹脂系のエマルジヲン系樽をあげること
ができる。Specific examples of thermoplastic resins used here include olefin resins such as polyethylene, polypropylene, polybutylene, and polybutadiene, polymethyl methacrylate,
Acrylic resins such as ethylene/ethyl acrylate copolymer, styrene resins such as polystyrene, AS resin, BS resin, ABS resin, polyvinyl chloride, divinylidene chloride, polyvinyl acetate, ethylene/vinyl acetate copolymer ,
Vinyl resins such as polyvinyl butyral, vinylidene chloride, acrylonitrile copolymer, vinyl chloride/vinyl acetate copolymer, vinyl chloride/vinylidene chloride copolymer, propylene/vinyl chloride copolymer, nylon 6, nylon 66, nylon 12 etc. polyamide resin, saturated polyester resin, polycarnate resin, polyacetal resin, polyphenylene oxide resin, polyphenylene 7
Id resin, polysulfone resin, polyurethane resin, fluorocarbon resin such as tetrafluoroethylene, trifluoroethylene, polyvinylidene sulfide, cellulose resin such as ethyl cellulose, cellulose acetate, nitrocellulose, niboxy resin, ionomer resin, rosin derivative resin, etc. organic solvent soluble resin system, gelatin, glue, casein,
Hydroxyethylcellulose, calgeximethylcellulose, methylcellulose, carboxymethylhydroxyethylcellulose, hydroxyethylstarch, gum arabic, sucrose octaacetate, ammonium alginate, sodium alginate, polyvinyl alcohol, polyvinyl butyral, polyvinylpyrrolidone, polyvinylamine, polyethylene oxide, polystyrene sulfonic acid Examples include emulsion barrels made of water-soluble resins such as polyacrylic acid, polyamide, isobutylene maleic anhydride copolymer, and organic solvent-soluble resins mentioned above.
ワックス類の具体例としては、キャンデリラワックス、
カルナウバワックス、ライスワックス、木ヰウ、ホホバ
油等の植物系ワックス、密ろ゛う、ラノリン、鯨ろう等
の動物系ろうなど、モンタンワックス、オシケライト、
セレウン等の鉱物系ワックス、パラフィンワックス、マ
イクロクリスタリンワックス、ペトロラタム等の石油ワ
ックス、フィッシャー・トロフシ−ワックス、ポリエチ
レンワックス等の合成炭化水素、モンタンワックス誘導
体、パラフィンワックス誘導体、マイクロクリスタリン
ワックス誘導体等の変性ワックス硬化ひまし油、硬化ひ
まし油誘導体等の水素化ワックス、１２−ヒドロキシス
テアリン酸、ステアリン酸アミド、高級アルコール及び
これらワックス類同志、ワックス類と有機物、無機物と
の配合品等をあげることができる。Specific examples of waxes include candelilla wax,
Vegetable waxes such as carnauba wax, rice wax, wood wax, jojoba oil, animal waxes such as beeswax, lanolin, spermaceti wax, montan wax, osikerite, etc.
Mineral waxes such as cereune, paraffin wax, microcrystalline wax, petroleum waxes such as petrolatum, synthetic hydrocarbons such as Fischer Troffsey wax and polyethylene wax, modified waxes such as montan wax derivatives, paraffin wax derivatives, and microcrystalline wax derivatives. Examples include hydrogenated waxes such as hydrogenated castor oil and hydrogenated castor oil derivatives, 12-hydroxystearic acid, stearic acid amide, higher alcohols, combinations of these waxes, and mixtures of waxes and organic or inorganic substances.
ゴム類の具体例としては、天然ゴム、インプレンゴム、
スチレン−ブタジェンゴム（ＳＢＲ）、ブタジェンゴム
、アクリルニトリル・ブタジェンゴム、プチルフ９ム、
エチレンプロピレンゴム、クロロプレノコ９ム、アクリ
ルゴム、クロロスルホン化ポリエチレンゴム、ヒドリン
ゴム、ウレタンゴム、多硫化ゴム、シリコーンゴム、フ
ッ素系コム及びこれらのゴム類同志の配合物、ゴム類と
他の有機物や無機物の配合物等をあげることができる。Specific examples of rubber include natural rubber, impregnated rubber,
Styrene-butadiene rubber (SBR), butadiene rubber, acrylonitrile-butadiene rubber, Ptylph 9M,
Ethylene propylene rubber, chloroprenoco9, acrylic rubber, chlorosulfonated polyethylene rubber, hydrin rubber, urethane rubber, polysulfide rubber, silicone rubber, fluorine-based combs, and blends of these rubbers, rubbers and other organic and inorganic substances Examples include formulations of.
これら接着層を構成するバインダーは１種類の単独又は
２菰以上の混合として用いることもできる。なおバイン
ダーは前掲に限定されるものではない。These binders constituting the adhesive layer can be used alone or as a mixture of two or more binders. Note that the binder is not limited to those listed above.
次に光分解性化合物としては紫外線、可視光線及び赤外
線を含む光により、速やかに光分解する特性が要求され
、これに好適な材料系としてニジアゾ化合物及びアジド
化合物をあげることができる。Next, photodegradable compounds are required to have the property of being rapidly photodegraded by light including ultraviolet rays, visible rays, and infrared rays, and suitable material systems include didiazo compounds and azide compounds.
ここに光分解性化合物として要求される特性は以下のと
おりである。The properties required for the photodegradable compound are as follows.
１）接着層中に均一に溶解もしくは分散し得ること。1) Can be uniformly dissolved or dispersed in the adhesive layer.
２）光分解速度が速く、かつ有効に窒素ガスを発生させ
ること。2) High photodecomposition rate and effective generation of nitrogen gas.
３）熱的・機械的なｇＩ撃に対し、耐性を有すること。3) Must be resistant to thermal and mechanical shock.
このような特性を有するジアゾ化合物は、従来ジアゾ複
写材料分野で使用されているものであり、具体例として
は４−ジアゾ−１−ジメチルアミノへ／セン、４−ジア
ゾ−１−ジエチルアミノベンゼン、４−ジアゾ−１−ジ
プロピルアミノベンゼン、４−ジアゾ−１−メチルベン
ジルアミノベンゼン、４−ジアゾ−１−ジベンジルアミ
ノベンゼン、４−ジアゾ−１−エチルヒドロキシエチル
アミノベンゼン、４−ジアゾ−１−ジエチルアミノ−３
−メトキシベンゼン、４−ジアゾ−１−ジメチルアミン
−２−メチルベンゼン、４−シアソー１−ベンゾイルア
ミノ−２，５−ジェトキシベンゼン、４−ジアゾ−１−
モルホリノベンゼン、４−ジアシー１−モルホリノ−２
，５−ジェトキシベンゼン、４−ジアゾ−１−モルホリ
ノ−２，５−ジブトキシベンゼン、４−ジアゾ−１−モ
ルホリノ−２，５−ジインプロポキシベンゼン、４−シ
アソー１−アニリノベンゼン、４−ジアゾ−１−’、Ｉ
ｆルアミノー３−カルボキシベンゼン、４−ジアゾ−１
−トルイルメルカプト−２，５−ジェトキシベンゼン、
４−シアシー１．４−メトキシベンゾイルアミノ−２，
５−ジェトキシベンゼン、４−シアソー１−ジメチルア
ミン−２−（４’−クロロフェノキシ）−６−クロロベ
ンゼン、４−ジアゾ−１−ピロリジノ−２−メチルベン
ゼン等をあげることができる。Diazo compounds having such characteristics have been conventionally used in the field of diazo copying materials, and specific examples include 4-diazo-1-dimethylaminohe/cene, 4-diazo-1-diethylaminobenzene, and 4-diazo-1-dimethylaminobenzene. -Diazo-1-dipropylaminobenzene, 4-diazo-1-methylbenzylaminobenzene, 4-diazo-1-dibenzylaminobenzene, 4-diazo-1-ethylhydroxyethylaminobenzene, 4-diazo-1- diethylamino-3
-methoxybenzene, 4-diazo-1-dimethylamine-2-methylbenzene, 4-thiazo-1-benzoylamino-2,5-jethoxybenzene, 4-diazo-1-
Morpholinobenzene, 4-diacyl-morpholino-2
, 5-jethoxybenzene, 4-diazo-1-morpholino-2,5-dibutoxybenzene, 4-diazo-1-morpholino-2,5-diynepropoxybenzene, 4-thiaso-1-anilinobenzene, 4- Diazo-1-', I
f Ruamino-3-carboxybenzene, 4-diazo-1
-toluylmercapto-2,5-jethoxybenzene,
4-siacy 1,4-methoxybenzoylamino-2,
Examples include 5-jethoxybenzene, 4-thiaso-1-dimethylamine-2-(4'-chlorophenoxy)-6-chlorobenzene, and 4-diazo-1-pyrrolidino-2-methylbenzene.
以上のジアゾ化合物はその塩化物と、塩化亜鉛、塩化カ
ドミウム、塩化錫等のノ・ロダン化金属との複塩を形成
させて安定化させることができる。The above-mentioned diazo compounds can be stabilized by forming a double salt between the chloride and a metal rhodanide such as zinc chloride, cadmium chloride, and tin chloride.
又、前記ジアゾ化合物と、テトラフルオロホウ酸、ヘキ
サフルオロリン酸、フルオロ硫酸等の７フ化物の酸やテ
トラホウ素ナトリウム等の有機ホウ素塩との錯塩を形成
させて安定化させてもよい。Alternatively, the diazo compound may be stabilized by forming a complex salt with a heptafluoride acid such as tetrafluoroboric acid, hexafluorophosphoric acid, or fluorosulfuric acid, or an organic boron salt such as sodium tetraboronate.
他方、アジド化合物としては特に芳香族アジド化合物が
有効である。即ち、その具体例としては、以上の他４．
４′−ジアジドージフェニルスルホン、４．４′−ジア
ジドベンゾスルホン、４．４’−シアシトスチルベン、
４．４’−ジアジドジペンザルアセトン、２．６−ジー
（４−アジドペンデル）−４−メチルシクロヘキサノン
、４．４′−ジアジドジフェニルサルファイド、１．２
− （４，４’−ジアジドジフェニル）エタン、４．４
’−ジアジドジフェニルエーテル、アジドペンゾキサゾ
ールス、４．４’−・シアシト−ジフェニルメタン、４
．４’−ジアジドスチルベン７２．２’−ジスルホン酸
ナトリウム、アジド安息香酸、アジドベンゼンスルホン
酸等を掲げることができる。On the other hand, aromatic azide compounds are particularly effective as azide compounds. That is, as specific examples, in addition to the above, 4.
4'-diazido diphenyl sulfone, 4,4'-diazidobenzosulfone, 4,4'-cyasitostilbene,
4.4'-Diazido dipenzalacetone, 2.6-di(4-azidopendel)-4-methylcyclohexanone, 4.4'-diazido diphenyl sulfide, 1.2
- (4,4'-diazidiphenyl)ethane, 4.4
'-Diazidiphenyl ether, azidopenzoxazole, 4.4'-cyacyto-diphenylmethane, 4
．． 4'-Diazidostilbene 72. Sodium 2'-disulfonate, azidobenzoic acid, azidobenzenesulfonic acid, etc. can be mentioned.
これらアジド化合物は光学増感が可能なため、必要に応
じ増感剤を添加して実用的な光感度を向上させることも
できる。Since these azide compounds are capable of optical sensitization, a sensitizer can be added as needed to improve the practical photosensitivity.
以上のジアゾ化合物、アジド化合物は単独又は２種類以
上を混合して用いることもできる。なお、これら光分解
性化合物の使用量は、接着層中の全固形分１００重量部
に対し、０．１〜８０重量部、好ましくは５〜５０重量
部の範囲が適当である。The above diazo compounds and azide compounds can be used alone or in combination of two or more. The appropriate amount of these photodegradable compounds to be used is 0.1 to 80 parts by weight, preferably 5 to 50 parts by weight, based on 100 parts by weight of the total solid content in the adhesive layer.
そして光分解性化合物が０．１重量部よシ少ない場合は
感光効果が得られず８０重量部を越えた場合は接着力が
弱くなシ好ましくない。接着層は前記したバインダー中
にジアゾ化合物又はアジド化合物を含Ｍさせて、形成す
ることができるが、光群時に有効に発生するチッ素ガス
による抑圧効果を増幅させる目的のために必要に応じ熱
可融性物質を添加させてもよい。If the amount of the photodegradable compound is less than 0.1 part by weight, no photosensitizing effect will be obtained, and if it exceeds 80 parts by weight, the adhesive force will be weak, which is not preferable. The adhesive layer can be formed by incorporating a diazo compound or an azide compound into the above-mentioned binder, but heat treatment may be applied as necessary to amplify the suppressing effect of nitrogen gas that is effectively generated during light grouping. Fusible substances may also be added.
ここに熱可融性物質とは、ジアゾ化合物又はアジド化合
物と相溶し、熱エネルギーにより溶融又は軟化する結果
、光分解により発生した窒素ガスの熱膨張を助長させる
ものであればよい。その具体例をあげれば、ラウリン酸
アミド、ステアリン酸アミド、Ｎ−ベヘニルベンズアミ
ド等の高級脂肪酸アミド、芳香族カルボン酸アミド、ラ
ウリン酸、ステアリン酸、オレイン酸等の高級脂肪酸又
はそのエステル、ポリエチレングリコール、ポリエチレ
ンオキシド、ポリエチレンオキシド・ポリプロピレンオ
キシドグラフト共重合体等をあケルことができる。Here, the thermofusible substance may be any substance that is compatible with the diazo compound or azide compound, melts or softens due to thermal energy, and promotes thermal expansion of nitrogen gas generated by photolysis. Specific examples include higher fatty acid amides such as lauric acid amide, stearic acid amide and N-behenylbenzamide, aromatic carboxylic acid amide, higher fatty acids such as lauric acid, stearic acid and oleic acid or their esters, polyethylene glycol, Polyethylene oxide, polyethylene oxide/polypropylene oxide graft copolymers, etc. can be used.
又当該接着層に塑性を賦与する目的で、必要に応シフタ
ル酸エステル系、グリコールエステル系、エポキシ系、
ポリエステル系、ビニル重合体系等の可塑剤を添加して
もよい。In addition, for the purpose of imparting plasticity to the adhesive layer, cyphthalic acid ester, glycol ester, epoxy,
Plasticizers such as polyester-based and vinyl polymer-based plasticizers may be added.
更に又、分散状態、塗膜形成状態の向上を図る目的で必
要に応じ、分散剤や顔料を添加してもよい。Furthermore, a dispersant or a pigment may be added as necessary for the purpose of improving the dispersion state and coating film formation state.
以上のバインダー、ジアゾ化合物又はアジド化合物及び
必要に応じ加える添加剤を適当々弓剤中に溶解もしくは
分散させることにより、接着層用塗料を得ることができ
る。この塗料はコーティング法により以下のいずれかの
面に形成される。A paint for an adhesive layer can be obtained by appropriately dissolving or dispersing the above binder, diazo compound or azide compound, and additives added as necessary in a bowing agent. This paint is formed on any of the following surfaces by a coating method.
１）マスクシートの支持体面
２）インキシートの基体面
３）１）、２）の両者の面
接着層用塗料のコーティング方法はリバースロールコー
タ−、クラビアコーター、ロッドコーター、エアドクタ
ーコーター等を使用して実施することができる。接着層
の厚さは０．０１〜２０μｍ１好ましくは０．１〜１０
μｍが適当である。又、上記の３）のように両面に塗布
する場合は各面に用いられる接着層中の材料系及びジア
ゾ化合物又はアジド化合物の組成比率を変えてもよい。1) Support surface of the mask sheet 2) Base surface of the ink sheet 3) Coating method for both surface adhesion layers in 1) and 2) uses a reverse roll coater, Clavia coater, rod coater, air doctor coater, etc. It can be implemented by The thickness of the adhesive layer is 0.01 to 20 μm, preferably 0.1 to 10 μm.
μm is appropriate. Further, when coating on both sides as in 3) above, the material system and the composition ratio of the diazo compound or azide compound in the adhesive layer used on each side may be changed.
マスクシートとインキシートの貼シ合わせ方法は、前記
した１）〜３）の各面に塗工された接着層面と、所定の
接着面とを重ね合わせ、圧力及び又は加熱されたロール
間を通過させることにより一体化させることができる。The method of laminating the mask sheet and the ink sheet is to overlap the adhesive layer surface coated on each surface of 1) to 3) above with a predetermined adhesive surface, and then pass between pressurized and/or heated rolls. They can be integrated by doing so.
この場合印加させるロール間の圧力は０．１〜５０ゆ／
ｃｒｎ２、好ましくは１〜１０Ｋｇ／１Ｍ１、印加させ
る温度は２０〜１５０℃、好ましくは４０〜８０℃であ
る。In this case, the pressure applied between the rolls is 0.1 to 50 Yu/
crn2, preferably 1 to 10 Kg/1M1, and the applied temperature is 20 to 150°C, preferably 40 to 80°C.
前記した接着層の作用を有効に発揮させるためには、貼
シ合わせシート間の１８００剥離力は０．１〜５００Ｅ
／Ｃｒｎ１好ましくは０．５〜１００１／ａｎの範囲が
適当である。なお、必要に応じ、マスクシートとインキ
シートを以上により貼シ合わした後、光反射層側、又は
インキ層側から水銀灯等により紫外線に照射させること
により、あらかじめ接着層中の光分解性化合物の一部あ
るいは全部を光分解させて使用することもできる。In order to effectively exhibit the effect of the adhesive layer described above, the 1800 peel force between the laminated sheets must be 0.1 to 500E.
/Crn1 is preferably in the range of 0.5 to 1001/an. If necessary, after pasting the mask sheet and ink sheet together as described above, the photodegradable compounds in the adhesive layer can be removed in advance by irradiating the light reflective layer side or the ink layer side with ultraviolet light using a mercury lamp or the like. It is also possible to use a part or all of it by photodegrading it.
なお本発明で用いられるマスクシートの光透過性支持体
にはポリエチレンテレフタレート、ポリイミド、ポリカ
ーゴネート、セロファン等各種の耐熱性樹脂フィルムが
用いられる。又、光反射層には放電破壊し易いアルミニ
ウム、亜鉛等の金属蒸着膜が適用される。その際、放電
記鎌特性を良好にするために、シリカ、アルミナ、二酸
化部、水利アルミナ等の微粒子を含有した透明性の高い
粗面化層を支持体と光反射層との間に設けることが好ま
しい。Note that various heat-resistant resin films such as polyethylene terephthalate, polyimide, polycargonate, and cellophane are used as the light-transmitting support of the mask sheet used in the present invention. Further, a vapor-deposited film of a metal such as aluminum or zinc, which is easily damaged by discharge, is applied to the light-reflecting layer. At that time, in order to improve the discharge recording characteristics, a highly transparent roughened layer containing fine particles of silica, alumina, dioxide, water-containing alumina, etc. is provided between the support and the light-reflecting layer. is preferred.
インキシートの支持体はカラー転写の場合は特に光透過
性に拘わらないが、通常はマスクシートと同様にポリエ
チレンテレフタレート、ポリイミド、ポリカーボネート
、セロファン等が用いられる。又、光熱変換層中の光熱
変換物質とは、カーボンブラック、黒鉛、アニリンブラ
ック、金属の酸化物や硫化物等の光吸収性顔料又は染料
であシ、光熱変換層はこれら光熱変換物質をポリエステ
ル樹脂、？リウレタン樹脂、ポリビニル樹脂等（７）バ
インダー中に含有させて形成することができる。In the case of color transfer, the support of the ink sheet is not particularly concerned with light transmittance, but polyethylene terephthalate, polyimide, polycarbonate, cellophane, etc. are usually used like the mask sheet. In addition, the photothermal conversion material in the photothermal conversion layer is a light-absorbing pigment or dye such as carbon black, graphite, aniline black, metal oxide or sulfide, and the photothermal conversion layer contains these photothermal conversion materials using polyester. resin,? It can be formed by incorporating it into a binder (7) such as urethane resin or polyvinyl resin.
熱転写性固体インキ層は、熱石融性、熱昇華性ともに従
来、熱転写インキシートの分野で使用されているものを
そのまま掲げることができる。即ち熱溶融性の場合であ
るならば、その構成物質は主として低融点物質のバイン
ダー、着色剤、柔軟剤から成っている。低融点物質のバ
インダーはその融点が、４０〜１２０℃の範囲にある固
体又は半固体状物質であり、その具体例としてはカルナ
バワックス、パラフィンワックス、マイクロクリスタリ
ンワックス、エステルワックス、酸化ワックス、モンタ
ンワックス等のワックス類、ステアリン酸、ベヘン酸等
の高級脂肪酸、パルミチルアルコール、ステアリルアル
コール等の高級アルコール、ノチルミチン酸セチル、ス
テアリン酸セチル等の高級脂肪酸エステル、アセトアミ
ド、ステアリン酸アミド等のアミド、エステルガム、ロ
ジンフェノール樹脂等のロジン誘導体、チルイン樹脂、
シクロペンタ・ジエン樹脂等の高分子化合物、ステアリ
ルアミン、パルミチンアミン等の高級アミン、ポリエチ
レングリコール、ポリエチレンオキシド等をあげること
ができる。これら低融点物質は単独又は２種以上を混合
して用いることができる。The heat-transferable solid ink layer can be any of those conventionally used in the field of heat-transfer ink sheets, both of which have thermolithic properties and heat-sublimation properties. That is, in the case of heat-melting, the constituent materials mainly consist of a binder, a coloring agent, and a softening agent, which are low-melting substances. The binder of a low melting point substance is a solid or semisolid substance whose melting point is in the range of 40 to 120°C, and specific examples thereof include carnauba wax, paraffin wax, microcrystalline wax, ester wax, oxidized wax, and montan wax. Waxes such as stearic acid, higher fatty acids such as behenic acid, higher alcohols such as palmityl alcohol and stearyl alcohol, higher fatty acid esters such as cetyl notylmitate and cetyl stearate, amides such as acetamide and stearic acid amide, and ester gums. , rosin derivatives such as rosin phenol resin, chillin resin,
Examples include polymeric compounds such as cyclopentadiene resin, higher amines such as stearylamine and palmitinamine, polyethylene glycol, and polyethylene oxide. These low melting point substances can be used alone or in combination of two or more.
着色剤は従来公知の色素又は顔料の中から選ぶことがで
きる。その具体例としてシアン色色素としては、ダイア
セリトン７アストブリリアントプルーＲ（三菱化成社製
、商品名）、カヤロン、／リエステルプルーＢ−８Ｆコ
ンク（日本化系社製、商品名）等、マジンタ色色素とし
てはダイアセリトン７アストレツドＲ（三菱化成社製、
商品名）、ナヤロンポリエステルビンクＲＣＬ−Ｅ （
日本化薬社製、商品名）等、イエロウ色色素としては、
カヤロンポリエステルライトイエロー５Ｇ−８（日本化
薬社製、商品名）、アイセンスピロンイエローＧＲＨ（
保土谷化学社製、商品名）等をあげる。また、シアン色
顔料としては、セルリアンブルー、フタロシアニンブル
ー等、マジェンタ色顔料としてはブリリアントカルミン
、アリザリンレイク等、イエロウ色顔料としてはハンガ
イエロウ、ビスアゾイエロウ等、黒色顔料としてはカー
ゲンブラック、黒鉛、オイルブラック等をあげることが
できる。なお当インキ層中には必要に応じてエチレン酢
酸ビニル共重合体、ブチラール樹脂等の熱可塑性樹脂や
オイル等を添加して使用することもできる。The colorant can be selected from conventionally known dyes or pigments. Specific examples of cyan color pigments include Mazinta color pigments such as Diaceritone 7 Asto Brilliant Plue R (manufactured by Mitsubishi Kasei Co., Ltd., trade name), Kayalon, /Lyester Blue B-8F Conc (manufactured by Nippon Kakei Co., Ltd., trade name), etc. For example, Diaceritone 7 Astred R (manufactured by Mitsubishi Kasei Corporation,
Product name), Nayaron Polyester Bink RCL-E (
As a yellow pigment, such as Nippon Kayaku Co., Ltd. (trade name),
Kayalon Polyester Light Yellow 5G-8 (manufactured by Nippon Kayaku Co., Ltd., trade name), Isenspiron Yellow GRH (
Manufactured by Hodogaya Chemical Co., Ltd., product name), etc. In addition, cyan pigments include cerulean blue and phthalocyanine blue, magenta pigments include brilliant carmine and alizarin lake, yellow pigments include hangai yellow and bisazo yellow, and black pigments include cargen black, graphite, and Oil black etc. can be mentioned. Note that thermoplastic resins such as ethylene vinyl acetate copolymer and butyral resin, oil, etc. may be added to the ink layer as necessary.
次に熱昇華性インキの場合であるならば、その構成物質
は主としてバインダーと着色剤から成る。Next, in the case of heat-sublimable ink, its constituent materials mainly consist of a binder and a colorant.
バインダーは転写時の溶融転写を避けるために１その融
点又は軟化点が比較的高いものが望ましい。The binder preferably has a relatively high melting point or softening point in order to avoid melt transfer during transfer.
その具体例としてはポリスルフォン、ポリカーブニルア
ルコール、ポリビニルブチラール、ヒドロキシエチルセ
ルロース、カルゲキシメチルセルロース、水溶性又は水
分散性ポリエステル、水溶性又は水分散性アクリル樹脂
等の水溶性又は水分散性樹脂系、および前記した有機溶
剤可溶樹脂系のエマル・ジョン系等をあげることができ
る。Specific examples include water-soluble or water-dispersible resin systems such as polysulfone, polycarbyl alcohol, polyvinyl butyral, hydroxyethyl cellulose, calgeximethyl cellulose, water-soluble or water-dispersible polyesters, and water-soluble or water-dispersible acrylic resins. , and the above-mentioned organic solvent-soluble resin emulsion systems.
熱昇華性又は熱気化性染料は、一般に繊維類の転写捺染
や熱転写インキ中に使用される、分散染料、油溶染料、
酸性染料、媒染染料、バット染料、塩基性染料等の中か
ら選ぶことができる。その具体例としては、アゾ系、ア
ントラキノン系、ニトロ系、スチリル系、ナフトキノン
系、キノフタロン系、アゾメチン系、クマリン系、縮合
多環系等の染料をあげることができる。これら染料の昇
畢開始温度は１５０℃以下がのぞましい。なお、当イン
キ層中には、必要に応じて、ツロッキング防止剤、無機
及び有機顔料、酸化防止剤、紫外糾吸収剤、帯電防止剤
、架橋剤等を添加して使用することもできる。Heat-sublimable or heat-vaporizable dyes include disperse dyes, oil-soluble dyes, and
You can choose from acid dyes, mordant dyes, vat dyes, basic dyes, etc. Specific examples thereof include azo dyes, anthraquinone dyes, nitro dyes, styryl dyes, naphthoquinone dyes, quinophthalone dyes, azomethine dyes, coumarin dyes, and condensed polycyclic dyes. The starting temperature of these dyes is preferably 150°C or lower. In addition, antilocking agents, inorganic and organic pigments, antioxidants, ultraviolet aggregation absorbers, antistatic agents, crosslinking agents, and the like may be added to the ink layer as necessary.
（実施例）
以下実施例によυ本発明を更に具体的に説明するがこれ
に限定されるものではない。(Examples) The present invention will be explained in more detail below with reference to Examples, but the present invention is not limited thereto.
実施例１
１２μｍ厚のポリエチレンテレフタレートフィルムに、
平均粒径５μｍのシリカ（Ｓ１０□）を含有し九層厚６
μｍの粗面化層を設け、更に該粗面化層上に約５００Ｘ
のＡｔ蒸着層を設けてなるマスクシートを作成した。Example 1 A 12 μm thick polyethylene terephthalate film was coated with
Contains silica (S10□) with an average particle size of 5 μm and has a 9-layer thickness of 6
A roughened layer with a thickness of 500× is provided on the roughened layer.
A mask sheet having an At vapor-deposited layer was prepared.
次に以下の配合の接着層用塗料を調合した。Next, an adhesive layer paint having the following composition was prepared.
バインダー：塩化ビニル・酢酸ビニル共重合体樹脂（電
気化学工業社製商品名デンカビニル１０００ＡＳ）の２
０を量チのメチルエチルケトン ・
・・３２５重量部ジアゾ化合物：４−ジアゾ−１−モル
ホリノ−２，５−ジブトキシベンゼンジアゾニウム４７
ツ化ホウ素塩
３５重量部
溶剤二メチルエチルケトン ３０７重量部上記混合
液にガラスピーズを加え、ペイントシェイカーにて、１
００分間分散後、接着層塗料とした。当該塗料をマスク
シートを構成するポリエチレンテレフタレートフィルム
面上にワイヤーバーを用いて、７５℃、１分間乾燥後の
層厚が２μｍになるようにコーティングして接着層を形
成した。Binder: Vinyl chloride/vinyl acetate copolymer resin (trade name Denkabinyl 1000AS, manufactured by Denki Kagaku Kogyo Co., Ltd.) 2
Measure 0 of methyl ethyl ketone.
...325 parts by weight Diazo compound: 4-diazo-1-morpholino-2,5-dibutoxybenzenediazonium 47
Boron tsuride salt 35 parts by weight Solvent dimethyl ethyl ketone 307 parts by weight Add glass peas to the above mixture, and in a paint shaker,
After dispersing for 00 minutes, it was made into an adhesive layer paint. The paint was coated on the surface of the polyethylene terephthalate film constituting the mask sheet using a wire bar so that the layer thickness after drying at 75° C. for 1 minute was 2 μm to form an adhesive layer.
次に以下の配合の黒色熱溶融性インキを調合した。Next, a black thermofusible ink having the following composition was prepared.
バインダー：カルナバワックス（ｍ、ｐ、 ７３℃）１
２重量部
パラフィンワックス（ｍ、ｐ、 ６０℃）２０重量部
添加剤ニオレイン酸 ９重役部顔料二
カーがンブラック ９重量部上記混合物を
９５℃で溶融混合した後、ホモミキサーで６０分間攪拌
して熱溶融性インキとした。Binder: Carnauba wax (m, p, 73℃) 1
2 parts by weight Paraffin wax (m, p, 60°C) 20 parts by weight Additive nioleic acid 9 executive parts Pigment Nikon black 9 parts by weight After melt-mixing the above mixture at 95°C, the mixture was stirred for 60 minutes with a homomixer. It was made into a hot-melt ink.
当該インキの融点は６９℃、１００℃における溶融粘度
は１２０ ｃＰであった。当該インキを４μｍ厚のポリ
エチレンテレフタレートフィルム上にホットメルト塗工
法によりその層厚が４μｍになるようにコーティングし
てインキシートを得た。The ink had a melting point of 69°C and a melt viscosity of 120 cP at 100°C. The ink was coated on a 4-μm-thick polyethylene terephthalate film by a hot-melt coating method so that the layer thickness was 4 μm to obtain an ink sheet.
次に、接着層設定済のマスクシートの接着層面と上記イ
ンキシートのポリエチレンテレフタレートフィルム面と
を重ね合わせ之状態で、５０℃に設定されたヒートロー
ラ間を７ゆ／ｃｒｎ２のロール間圧力にて通過させるこ
とにより接着固定させ、マスクシートとインキシートと
をその界面にジアゾ化合物を含有した接着層を設けて一
体化させた転写記録媒体を得た。Next, while the adhesive layer side of the mask sheet with the adhesive layer set and the polyethylene terephthalate film side of the ink sheet are overlapped, heat rollers set at 50°C are heated at an inter-roll pressure of 7 Yu/crn2. A transfer recording medium was obtained in which the mask sheet and the ink sheet were bonded and fixed by passing through them, and an adhesive layer containing a diazo compound was provided at the interface to integrate the mask sheet and the ink sheet.
その後当該転写記録媒体を通常の放電記録装置を用いて
、ヘッド印加電圧４５Ｗにて文字パターン、ペタパター
ン及びディザ−法による階調パターンの各印字パターン
にて記録を行なった。次にインキ層面に受像紙を密着さ
せ、キセノンフラッジ−装置（理想科学社製ＦＸ−１５
０）を用いてマスクシートの光反射層側から閃光を全面
照射した。このときのインキ層面と受像紙面との密着圧
は５０ｇ／ｃｒｎ２及び１００ ｇ／ｃｍ２、閃光エネ
ルギーは１３ ｍＪ／ｍ２の一定値に調整した。更に受
像紙はその表面のベック平滑度が４〜６秒のプント紙、
５０〜６０秒のコピー用紙及び３００〜３２０秒の熱転
写用紙の３種類を用いた。閃光照射後、インキシートと
受像紙とを１８０°剥離法により剥離分離後、得られた
転写記録品質を以下の評価基準により判定した。即ち目
視及び拡大写真（２５像５０倍）により、ＮＵ線転写部
の「印字ガケ」、「トイレ」、「カスレ」、ヘタ転写部
の「白ヌケ」、階調性表現の程度を観察し、「印字ガケ
」、「トイレ」、「カスレ」、「白ヌケ」及び「カプリ
」が全くなくペタ部のマクベス反射濃度値が１以上であ
シ階調性表現も良好な高品質の場合を○、−部「印字ガ
ケ」、「トイレ」、「カスレ」及び「カプリ」が少しで
もある場合をΔ、「印字ガケ」、「トイレ」、「カスレ
」及び「カプリ」が目立ち、ペタ転写部の「白ヌケ」が
著るしく、濃度不足の場合を×とした。又、Ｙ、Ｍ、Ｃ
の色重ね順序で転写した場合の減法混色性についても評
価した。Thereafter, each printing pattern of a character pattern, a peta pattern, and a gradation pattern using a dither method was recorded on the transfer recording medium using an ordinary discharge recording device at a head applied voltage of 45 W. Next, the image receiving paper was brought into close contact with the ink layer surface, and a xenon flood device (FX-15 manufactured by Riso Kagakusha
0), the entire surface of the mask sheet was irradiated with flash light from the light-reflecting layer side. At this time, the contact pressure between the ink layer surface and the receiving paper surface was adjusted to a constant value of 50 g/crn2 and 100 g/cm2, and the flash energy was adjusted to a constant value of 13 mJ/m2. Furthermore, the receiving paper is Punto paper whose surface has a Bekk smoothness of 4 to 6 seconds.
Three types of paper were used: a 50-60 second copy paper and a 300-320 second thermal transfer paper. After irradiation with flash light, the ink sheet and image-receiving paper were peeled and separated by a 180° peeling method, and the resulting transfer recording quality was evaluated according to the following evaluation criteria. That is, by visual inspection and enlarged photographs (25 images, 50x), we observed "printing scratches", "toilet", "fading" in the NU line transfer area, "white spots" in the rough transfer area, and the degree of gradation expression, High quality with no "printing scratches", "toilet", "fading", "white spots" or "capri", Macbeth reflection density value of the peta part is 1 or more, and good gradation expression.○ , If there is even a small amount of "Printing scratches", "Toilet", "Scale" and "Capri" in the - section, Δ, "Printing scratches", "Toilet", "Scale" and "Capri" are noticeable and the peta transfer area is Cases where "white spots" were significant and the density was insufficient were rated as "×". Also, Y, M, C
We also evaluated the subtractive color mixing properties when the colors were transferred in the following color stacking order.
データは後述の第１表のとおりである。The data are shown in Table 1 below.
実施例２
調合を以下に変えた以外は、実施例−１と同様に接着層
を設定した。Example 2 An adhesive layer was prepared in the same manner as in Example-1, except that the formulation was changed as follows.
バインダー：エチレン・酢酸ビニル共重合体樹脂（日本
合成化学社製、商品名ソアレツクスＲ−ＢＩ（：酢酸ビ
ニル成分の含有率５５％）の２０重量％のトルエン溶液
３００重量部ジアゾ化合物： ４− Ｎ、Ｎ−ノ
エチルアミンー３−（４’−クロロフェノキシ）−６−
クロロベンゼン６フツ化リン塩
溶剤：メチルエチルケトン ３２７重量部その後
マスクシートを構成する？リエチレンテレ７タレートフ
イルム面に７５℃、１分間乾燥後の層厚が１．５μｍに
なるようにコーティングし、実施例１と同様にインキシ
ートと貼シ合わせ念。転写記録品質の評価も実施例−１
と同様に行なった。Binder: 20% by weight toluene solution of ethylene/vinyl acetate copolymer resin (manufactured by Nippon Gosei Kagaku Co., Ltd., trade name: Soarex R-BI (: content of vinyl acetate component 55%) 300 parts by weight Diazo compound: 4-N , N-noethylamine-3-(4'-chlorophenoxy)-6-
Chlorobenzene hexafluoride phosphorus salt solvent: Methyl ethyl ketone 327 parts by weight After that, form a mask sheet? The surface of the polyethylenetere 7 tallate film was coated to a layer thickness of 1.5 μm after drying at 75° C. for 1 minute, and laminated with the ink sheet in the same manner as in Example 1. Evaluation of transcription recording quality is also Example-1
I did the same thing.
実施例３
調合を以下に変えた以外は、実施例−１と同様に接着層
を設定した。Example 3 An adhesive layer was prepared in the same manner as in Example-1, except that the formulation was changed as follows.
バインダー二マイクロクリスタリンワックス（日本製蝋
社髪、商品名ハイミック１０７０、ｍ、ｐ、 ８０℃）
の１５重量％のトルエン溶液・・・４３３重量部
ジアゾ化合物：４−ジアゾ−１−モルホリノ−２，５−
ジブトキシベンゼンジアゾニウム４フツ化ホウ素塩
・・・３５重量部溶剤：メチルエチルケト
ン ・・・５３２重量部その後、マスクシートを構
成するポリエチレンテレフタレートフィルム面上に、８
５℃、１分間乾燥後の層厚が０．６μｍになるようにコ
ーティングし、実施例１と同様にインキシートと貼シ合
わせた。転写記録品質の評価も実施例１と同様に行なっ
た。Binder 2 Microcrystalline wax (Nippon Seisakusha Hair, trade name Himic 1070, m, p, 80°C)
15% by weight toluene solution...433 parts by weight Diazo compound: 4-diazo-1-morpholino-2,5-
Dibutoxybenzenediazonium boron tetrafluoride salt
...35 parts by weight Solvent: Methyl ethyl ketone ...532 parts by weight Then, on the surface of the polyethylene terephthalate film constituting the mask sheet, 8
It was coated to a layer thickness of 0.6 μm after drying at 5° C. for 1 minute, and laminated with an ink sheet in the same manner as in Example 1. Evaluation of transfer recording quality was also conducted in the same manner as in Example 1.
実施例４
調合を以下に変えた以外は、実施例−１と同様に接着層
を設定した。Example 4 An adhesive layer was prepared in the same manner as in Example-1, except that the formulation was changed as follows.
その後、マスクシートを構成するポリエチレンテレフタ
レートフィルム面上に７５℃、１分間乾燥後の層厚が０
．５μｍになるようにコーティングし、実施例−１と同
様にインキシートと貼シ合わせた。Thereafter, a layer thickness of 0 after drying at 75°C for 1 minute was applied to the surface of the polyethylene terephthalate film constituting the mask sheet.
．． It was coated to a thickness of 5 μm and laminated with an ink sheet in the same manner as in Example-1.
転写記録品質の評価も実施例１と同様に行なりた。Evaluation of transfer recording quality was also conducted in the same manner as in Example 1.
実施例５
調合を以下に変えた以外は、実施例１と同様に接着層を
設定した。Example 5 An adhesive layer was prepared in the same manner as in Example 1, except that the formulation was changed as follows.
バインダー：カルボキシ変性スチレン・ブタジェンゴム
（日本合成ゴム社製、商品名
ＪＳＲＯ６９３） −・１２５重景重
役アゾ化合物：４−ジアゾ−１−モルホリノ−２，５−
ノットキシベンゼンジアゾニウム塩化亜鉛塩
・・・４０重置部
溶剤： 水 ・・・２３５重量部その
後、マスクシートを構成するポリエチレンテレフタレー
トフィルム面上に８０℃、２分間乾燥後の層厚が３μｍ
になるようにコーティングし、！ｉｌ！施例１と同様て
インキシートと貼や合わせた。Binder: Carboxy-modified styrene-butadiene rubber (manufactured by Japan Synthetic Rubber Co., Ltd., trade name JSRO693) -・125 Heavy duty azo compound: 4-diazo-1-morpholino-2,5-
Notxybenzenediazonium zinc chloride salt...40 parts Solvent: Water...235 parts by weight Then, on the surface of the polyethylene terephthalate film constituting the mask sheet, a layer thickness of 3 μm after drying at 80°C for 2 minutes was applied.
Coat it so that it is! Il! In the same manner as in Example 1, it was pasted and combined with an ink sheet.
転写記録品質の評価も実施例１と同様に行なった。Evaluation of transfer recording quality was also conducted in the same manner as in Example 1.
実施例６
マスクシートを構成するポリエチレンテレフタレート面
上に実施例１の接着層を同様に形成した。Example 6 The adhesive layer of Example 1 was similarly formed on the polyethylene terephthalate surface constituting the mask sheet.
次に以下の配合の光熱変換層塗料を調合した。Next, a light-to-heat conversion layer paint having the following composition was prepared.
バインダー：ポリエステル樹脂（４０重量％のトルエン
／メチルエチルケトン溶ｉ）
・・・１７５重量部
顔料二カーゴンブラック分散液（５０重量％のトルエン
分散液） ・・・６０重量部溶剤：メチル
エチルケトン ・・・１８１重量部上記混合液にガ
ラスピーズを加え、ペイントシェイカーにて１００分間
分散後、光熱変換層塗料とした。この塗料を４μｍのポ
リエチレンテレフタレートフィルム上にワイヤーパーを
用いて９０℃、２分間乾燥後の層厚が３μｍになるよう
にコーティングした。Binder: Polyester resin (40% by weight toluene/methyl ethyl ketone solution)...175 parts by weight Pigment dicargon black dispersion (50% by weight toluene dispersion)...60 parts by weight Solvent: Methyl ethyl ketone...181 Parts by weight Glass peas were added to the above mixed solution and dispersed for 100 minutes in a paint shaker to obtain a light-to-heat conversion layer paint. This paint was coated onto a 4 μm polyethylene terephthalate film using a wire parser so that the layer thickness after drying at 90° C. for 2 minutes was 3 μm.
又、以下の配合のカラーの熱溶融性インキを調合した。In addition, a hot-melt color ink having the following composition was prepared.
バインダー：カルナバワックス（ｍ、ｐ、 ７３℃）・
・・１２重量部
ノラフインワックス（ｍ、ｐ、６０℃）・・・２０重量
部
添加剤ニオレイン酸 ・・・９重量部顔料
： ・・・９重量部上記混合
物を９５℃で溶融混合した後、ホモミキサーで６０分間
攪拌してカラーの熱溶融性インキとした。Ｙ、Ｍ、およ
びＣインキの各融点は７５．７４および７２℃、１００
℃における各溶融粘度は１２６．３４および２２ ｃＰ
であった。前記、各インキをポリエチレンテレフタレー
トフィルム上に設けた光熱変換層上にホットメルト塗工
法により層厚が各３．５μｍとなるようにコーティング
した。Binder: Carnauba wax (m, p, 73℃)・
...12 parts by weight Norahin wax (m, p, 60°C) ...20 parts by weight Additive nioleic acid ...9 parts by weight Pigment: ...9 parts by weight After melt-mixing the above mixture at 95°C The mixture was stirred for 60 minutes using a homomixer to obtain a colored hot-melt ink. The respective melting points of Y, M, and C inks are 75.74 and 72°C, 100
The respective melt viscosities at °C are 126.34 and 22 cP
Met. Each of the inks described above was coated onto a light-to-heat conversion layer provided on a polyethylene terephthalate film using a hot melt coating method so that each layer had a thickness of 3.5 μm.
この後実施例１と同様にマスクシートの接着層面と上記
インキシートのポリエチレンテレフタレートフィルム面
とを重ね合わせた状態で、５０℃に設定されたヒートロ
ーラー間を７ゆ／帰のロール間圧力にて通過させること
により接着固定させ、マスクシートとインキシートとを
その界面にジアゾ化合物塩含有した接着層を設けて一体
化させた転写記録媒体を得た。転写記録品質の評価も実
施例１と同様に行なった。After that, as in Example 1, with the adhesive layer surface of the mask sheet and the polyethylene terephthalate film surface of the ink sheet overlapped, the heat rollers set at 50°C were heated at 7 degrees of inter-roll pressure. A transfer recording medium was obtained in which the mask sheet and the ink sheet were bonded and fixed by passing through them, and an adhesive layer containing a diazo compound salt was provided at the interface to integrate the mask sheet and the ink sheet. Evaluation of transfer recording quality was also conducted in the same manner as in Example 1.
実施例７〜１０
接着層を実施例２．３．．４及び５の場合に変えた以外
は、実施例６と同様にカラーインキシートと貼シ合わせ
、転写記録品質の評価を行なりた。Examples 7-10 The adhesive layer was prepared in Examples 2.3. ．． A color ink sheet was laminated and the transfer recording quality was evaluated in the same manner as in Example 6, except that cases 4 and 5 were changed.
実施例１１
マスクシートを構成するポリエチレンテレフタレート面
上に実施例−１の接着層を同様に形成した。Example 11 The adhesive layer of Example 1 was similarly formed on the polyethylene terephthalate surface constituting the mask sheet.
次に実施例６と同様に４μｍのポリエチレンテレフタレ
ートフィルム上に光熱変換層を形成した。Next, in the same manner as in Example 6, a light-to-heat conversion layer was formed on a 4 μm polyethylene terephthalate film.
この後、実施例６で得たカラーの熱溶融性インキを各々
、光熱変換層の設定面とは別のポリエチレンテレフタレ
ートフィルム上にホットメルト塗工法によｌ）Ｎ厚が各
３．５μｍとなるようにコーティングした。この後、マ
スクシートの接着層面と上記インキシートの光熱変換層
面とを重ね合わせた状態で実施例１と同様に貼り合わせ
た。転写記録品質の評価も実施例１と同様に行なった。Thereafter, each of the color heat-melting inks obtained in Example 6 was applied by hot melt coating onto a polyethylene terephthalate film separate from the surface on which the light-to-heat conversion layer was set, so that the thickness of each layer was 3.5 μm. It was coated like this. Thereafter, the adhesive layer surface of the mask sheet and the light-to-heat conversion layer surface of the ink sheet were laminated together in the same manner as in Example 1 in a superposed state. Evaluation of transfer recording quality was also conducted in the same manner as in Example 1.
実施例１２
マスクシートを構成するポリエチレンテレフタレート面
上に実施例１の接着層を同様に形成した。Example 12 The adhesive layer of Example 1 was similarly formed on the polyethylene terephthalate surface constituting the mask sheet.
次に実施例６と同様に４踊のポリエチレンテレフタレー
トフィルム上に光熱変換層を形成した。Next, in the same manner as in Example 6, a light-to-heat conversion layer was formed on the four-layer polyethylene terephthalate film.
又、以下の配合のカラーの熱昇華性インキを調合した。In addition, heat sublimation inks of the following colors were prepared.
バインター：エチルセルロース ・・・ａｎｆ部添
加顔料：ホワイトカーボン（日本シリカ社製、商品名工
デシールＥ−２０ＯＡ） ・・・２重量部分散染料
（日本化系社製） ・・・１０重量部溶剤：イソ
プロビルアルコール ・・・４５５重量部上記混液に
ガラスピーズを・加え、４イントシエイカーにて１２０
分間分散後、カラーの熱昇華性インキ塗料とした。この
塗料をポリエチレンテレフタレートフィルム上に設けた
光熱変換層上にワイヤーバーを用いて、６０℃、２分間
乾燥後の層厚が３μｍになるようにコーティングした。Binder: Ethyl cellulose ... Anf part additive pigment: White carbon (manufactured by Nippon Silica Co., Ltd., trade name: Meiko Decir E-20OA) ... 2 parts by weight Disperse dye (manufactured by Nippon Kakei Co., Ltd.) ... 10 parts by weight Solvent: Isopro Building alcohol...455 parts by weight Add glass peas to the above mixture and mix with 4 int shakers to 120 parts by weight.
After dispersing for a minute, it was made into a color heat-sublimable ink paint. This paint was coated onto the light-to-heat converting layer provided on the polyethylene terephthalate film using a wire bar so that the layer thickness after drying at 60° C. for 2 minutes was 3 μm.
この後、実施例１と同様にマスクシートの接着層面と上
記インキシートのポリエチレンテレフタレート面とを重
ね合わせた状態で貼シ合わせた。Thereafter, in the same manner as in Example 1, the adhesive layer surface of the mask sheet and the polyethylene terephthalate surface of the ink sheet were laminated together in an overlapping state.
転写記録品質の評価も実施例１と１同様に行なった。Evaluation of transfer recording quality was also conducted in the same manner as in Example 1.
比較例１
マスクシートを構成するポリエチレンテレフタレート面
上に実施例−１で得た黒色熱溶融性インキを同様にコー
ティングし、従来の放電転写記録媒体を得た。転写記録
品質の評価は実施例１と同様に行なった。Comparative Example 1 The black thermofusible ink obtained in Example 1 was similarly coated on the polyethylene terephthalate surface constituting the mask sheet to obtain a conventional discharge transfer recording medium. Evaluation of transfer recording quality was performed in the same manner as in Example 1.
比較例２
接着層中にジアゾ化合物を含有させないこと以外は、実
施例１と同様にしてマスクシートとインキシートを貼り
合わせた。転写記録品質の評価も実施例１と同様に行な
った。Comparative Example 2 A mask sheet and an ink sheet were bonded together in the same manner as in Example 1, except that the diazo compound was not contained in the adhesive layer. Evaluation of transfer recording quality was also conducted in the same manner as in Example 1.
比較例３
調合を以下のように接着層のバインダーを熱硬化性樹脂
に変えた以外は、実施例１と同様に接着層を設定した。Comparative Example 3 An adhesive layer was prepared in the same manner as in Example 1, except that the binder of the adhesive layer was changed to a thermosetting resin as shown below.
バインダー二尿素・メラミン樹脂（日立化成社製商品名
メラン４４５） ・・・１１８重量部・ジアゾ化合
物：４−ジアゾー１−モルホリノ−２，５−ジブトキシ
ベンゼンジアゾニウム４７フ化ホウ素塩
・・・３５重量部溶剤：キンレン ・
・・２５７重量部ブタノール ・・・２５
７重景部上記混合液にガラスピーズを加え、ペイントシ
ェイカーにて１００分間分散後、接着層塗料とし、マス
クシートを構成するポリエチレンテレフタレートフィル
ム面上にワイヤーバーを用いて１５０℃１．５分間乾燥
後の層厚が２μｍになるようにコーティングして接着層
を形成した。この後、実施例１と同様にインキシートの
ポリエチレンテレフタレート面と重ね合わせた状態で貼
シ合わせを行なりたが、接着固定は不可能であった。転
写記録品質の評価は、接着層設定法のマスクシートとイ
ンキシートのポリエチレンテレフタレート面を単に重ね
合わせた状態で、実施例１と同様に行なった。Binder diurea/melamine resin (trade name: Melan 445, manufactured by Hitachi Chemical Co., Ltd.)...118 parts by weight/Diazo compound: 4-diazo 1-morpholino-2,5-dibutoxybenzenediazonium 47 boron fluoride salt
...35 parts by weight Solvent: Kinlen ・
...257 parts by weight Butanol ...25
7. Top view: Add glass peas to the above mixed solution, disperse for 100 minutes in a paint shaker, make an adhesive layer paint, and dry for 1.5 minutes at 150°C using a wire bar on the surface of the polyethylene terephthalate film that constitutes the mask sheet. An adhesive layer was formed by coating so that the subsequent layer thickness was 2 μm. Thereafter, in the same manner as in Example 1, the ink sheet was laminated with the polyethylene terephthalate surface overlapped, but adhesive fixation was not possible. The transfer recording quality was evaluated in the same manner as in Example 1, with the mask sheet of the adhesive layer setting method and the polyethylene terephthalate surface of the ink sheet simply superposed.
実施例及び比較例から得られた転写記録品質の結果を、
密着圧が５０１７ｃｍ２の場合、１００ｆ！／ｃｍ２の
場合にわけて、それぞれの結果を第１表、第２表に示し
である。The results of transfer recording quality obtained from Examples and Comparative Examples are as follows:
When the contact pressure is 5017cm2, it is 100f! /cm2, the respective results are shown in Tables 1 and 2.
（発明の効果）
本発明による効果は、上記の表から明らかなように、
１）表面平滑度の低いコピー用紙及び２７２紙への高い
転写記録品質が得られる。(Effects of the Invention) As is clear from the table above, the effects of the present invention are as follows: 1) High transfer recording quality can be obtained on copy paper and 272 paper with low surface smoothness.
２）「ニジミ」や「ボケ」のない「キレ」の良い転写記
録品質が得られる。2) Good transfer recording quality with no "bleeding" or "blurring" can be obtained.
３）階調性表現の向上に伴ない、優れたフルカラー転写
記録品質が得られる。3) Excellent full-color transfer recording quality can be obtained with improved gradation expression.
４）表には明示されていないが、カラーインキ転写の場
合、減法混色性は著しく向上した。4) Although not clearly shown in the table, in the case of color ink transfer, subtractive color mixing properties were significantly improved.
５）従来の構成に比べ、本発明の構成により高い転写記
録品質を得るのに要するインキ層面と受像紙面との密着
圧を大幅に軽減させることができ、従って記録装置の小
型化をはかることが可能である。5) Compared to conventional configurations, the configuration of the present invention can significantly reduce the contact pressure between the ink layer surface and the image-receiving paper surface required to obtain high transfer recording quality, thus making it possible to downsize the recording device. It is possible.
第１図〜４図は本発明の転写記録媒体の断面図、第５図
は従来の転写記録媒体の断面図、第６図〜第８図は前記
記録媒体を用いた印刷工程を示す断面図、第９図、第１
０図は光熱変換層８を設けた従来の記録媒体の断面図。
１轟・・・支持体、１ｂ・・・基体、１・・・支持体、
２・・・光反射層、３・・・熱転写性固体インキ層、４
・・・受像紙、５・・・キセノンランプ、６・・・閃光
、７・・・転写画像、８・・・光熱変換層、１０・・・
接着層。1 to 4 are cross-sectional views of a transfer recording medium of the present invention, FIG. 5 is a cross-sectional view of a conventional transfer recording medium, and FIGS. 6 to 8 are cross-sectional views showing printing steps using the recording medium. , Figure 9, 1st
FIG. 0 is a cross-sectional view of a conventional recording medium provided with a light-to-heat conversion layer 8. 1 Todoro...Support, 1b...Base, 1...Support,
2... Light reflective layer, 3... Thermal transferable solid ink layer, 4
... Image receiving paper, 5 ... Xenon lamp, 6 ... Flash light, 7 ... Transfer image, 8 ... Photothermal conversion layer, 10 ...
Adhesive layer.
Claims (3)
反射層を設けたマスクシートと、基体上に少なくとも熱
転写性固体インキ層を設けたインキシートとを重ね合せ
て構成される転写記録媒体に於て、前記マスクシートの
支持体とインキシートの基体とを光分解性化合物を含有
する接着層により貼り合わせたことを特徴とする転写記
録媒体。(1) Transfer consisting of a mask sheet in which a light-reflecting layer removable by discharge destruction recording is provided on a light-transmitting support and an ink sheet in which at least a thermally transferable solid ink layer is provided on the substrate. 1. A transfer recording medium, characterized in that the support of the mask sheet and the base of the ink sheet are bonded together with an adhesive layer containing a photodegradable compound.
可塑性樹脂類、ワックス類又はゴム類の中から選ばれた
少なくとも１種類であることを特徴とする特許請求の範
囲第１項記載の転写記録媒体。(2) The transfer according to claim 1, wherein the binder of the adhesive layer containing a photodegradable compound is at least one type selected from thermoplastic resins, waxes, and rubbers. recoding media.
であることを特徴とする特許請求の範囲第１項記載の転
写記録媒体。(3) The transfer recording medium according to claim 1, wherein the photodegradable compound is a diazo compound or an azide compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61205607A JPS6360791A (en) | 1986-09-01 | 1986-09-01 | Transfer recording medium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61205607A JPS6360791A (en) | 1986-09-01 | 1986-09-01 | Transfer recording medium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6360791A true JPS6360791A (en) | 1988-03-16 |
| JPH0566271B2 JPH0566271B2 (en) | 1993-09-21 |
Family
ID=16509666
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61205607A Granted JPS6360791A (en) | 1986-09-01 | 1986-09-01 | Transfer recording medium |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6360791A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH024570A (en) * | 1988-06-21 | 1990-01-09 | Tomoegawa Paper Co Ltd | Electric discharge transfer recording medium |
| JPH02121883A (en) * | 1988-10-31 | 1990-05-09 | Casio Comput Co Ltd | Copying method by flash |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6082389A (en) * | 1983-10-13 | 1985-05-10 | Seiko Epson Corp | Thermal transfer recording medium |
| JPS60174690A (en) * | 1984-02-21 | 1985-09-07 | Seiko Epson Corp | Thermal transfer recording sheet |
-
1986
- 1986-09-01 JP JP61205607A patent/JPS6360791A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6082389A (en) * | 1983-10-13 | 1985-05-10 | Seiko Epson Corp | Thermal transfer recording medium |
| JPS60174690A (en) * | 1984-02-21 | 1985-09-07 | Seiko Epson Corp | Thermal transfer recording sheet |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH024570A (en) * | 1988-06-21 | 1990-01-09 | Tomoegawa Paper Co Ltd | Electric discharge transfer recording medium |
| JPH02121883A (en) * | 1988-10-31 | 1990-05-09 | Casio Comput Co Ltd | Copying method by flash |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0566271B2 (en) | 1993-09-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5089372A (en) | Transfer recording medium utilizing diazo or azide compounds wherein light energy is converted to heat energy | |
| US4650494A (en) | Heat transfer printing sheet | |
| JPH057194B2 (en) | ||
| JPH0356919B2 (en) | ||
| JPS63161445A (en) | Transfer recording medium and transfer recording method | |
| JP2649350B2 (en) | Transfer recording medium and transfer recording method | |
| JPS6360791A (en) | Transfer recording medium | |
| JPS6360788A (en) | Electrosensitive transfer recording medium | |
| JP3531006B2 (en) | Melt type laser thermal transfer recording method | |
| JPS63165179A (en) | Discharge transfer recording medium | |
| JP3176675B2 (en) | Preparation method of image receiving material for thermal transfer and printing proof plate | |
| JP2686610B2 (en) | Manufacturing method of thermal transfer sheet | |
| JPS63197688A (en) | Transfer recording medium and method therefor | |
| JPH0548758B2 (en) | ||
| GB2273992A (en) | Thermal transfer sheet | |
| JPH09272265A (en) | Thermal transfer sheet | |
| JPS63293084A (en) | Transfer recording medium | |
| JPS63293083A (en) | Transfer recording medium | |
| JPH05162470A (en) | Hot-melt transfer ink sheet | |
| JPS63185678A (en) | Production of electric discharge transfer recording medium | |
| JPS6360789A (en) | Transfer recording medium | |
| JPS6399986A (en) | Thermal transfer material | |
| JPH06115256A (en) | Indirect transfer material | |
| JPH04216095A (en) | Thermal transfer dye donative material | |
| JPS63179790A (en) | Transfer recording medium and transfer recording method |