JPS6359042B2 - - Google Patents
Info
- Publication number
- JPS6359042B2 JPS6359042B2 JP53152138A JP15213878A JPS6359042B2 JP S6359042 B2 JPS6359042 B2 JP S6359042B2 JP 53152138 A JP53152138 A JP 53152138A JP 15213878 A JP15213878 A JP 15213878A JP S6359042 B2 JPS6359042 B2 JP S6359042B2
- Authority
- JP
- Japan
- Prior art keywords
- tube
- water
- catalyst
- oil
- flask
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 claims description 48
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 31
- 238000002485 combustion reaction Methods 0.000 claims description 26
- 229910052697 platinum Inorganic materials 0.000 claims description 15
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 9
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 7
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 239000011572 manganese Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 3
- 239000012071 phase Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 48
- 239000003921 oil Substances 0.000 description 39
- 239000007788 liquid Substances 0.000 description 11
- 239000000443 aerosol Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000005587 bubbling Effects 0.000 description 4
- 239000003502 gasoline Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- SGGOJYZMTYGPCH-UHFFFAOYSA-L manganese(2+);naphthalene-2-carboxylate Chemical compound [Mn+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 SGGOJYZMTYGPCH-UHFFFAOYSA-L 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229920004142 LEXAN™ Polymers 0.000 description 2
- 239000004418 Lexan Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052702 rhenium Inorganic materials 0.000 description 2
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- SNPHNDVOPWUNON-UHFFFAOYSA-J platinum(4+);tetrabromide Chemical compound [Br-].[Br-].[Br-].[Br-].[Pt+4] SNPHNDVOPWUNON-UHFFFAOYSA-J 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
- F02M27/00—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like
- F02M27/02—Apparatus for treating combustion-air, fuel, or fuel-air mixture, by catalysts, electric means, magnetism, rays, sound waves, or the like by catalysts
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
- F23L7/00—Supplying non-combustible liquids or gases, other than air, to the fire, e.g. oxygen, steam
- F23L7/002—Supplying water
- F23L7/005—Evaporated water; Steam
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B1/00—Engines characterised by fuel-air mixture compression
- F02B1/02—Engines characterised by fuel-air mixture compression with positive ignition
- F02B1/04—Engines characterised by fuel-air mixture compression with positive ignition with fuel-air mixture admission into cylinder
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Air Supply (AREA)
- Catalysts (AREA)
- Combustion Methods Of Internal-Combustion Engines (AREA)
Description
【発明の詳細な説明】
自動車用機関および油燃焼炉のいずれにおいて
も水が化石燃料の燃焼を改善するのに用いられて
きた。自動車用機関の場合、ガソリンを空気と混
合するに先だつて空気は加湿された。油燃焼炉の
場合は、油を霧化するのに蒸気が用いられた。燃
焼過程の構成物質を水と混合するために種々の手
法が用いられた。これらの手法はコツク（Cock）
の米国特許第3107657号に述べられているような
空気室内へ水を噴射するもの、トムリンソン
（Tomlinson）の米国特許第3724429号に述べら
れているような水をガソリン中に通過させるも
の、ミルス（Mills）の米国特許第3767172号に述
べられている細かい気泡の流れを水中に通すも
の、ベアカンプ（Varekamp）の米国特許第
3809523号に述べられているガス火焔中への細か
い水霧の噴射などがある。さらに最近の手法で
は、ウエントウオース（Wentworth）の米国特
許第3862819号に述べられているように、燃焼室
への取入れ空気の少量を分散しかつ油の層で覆わ
れた水を通して空気を泡立てるものがある。DETAILED DESCRIPTION OF THE INVENTION Water has been used to improve the combustion of fossil fuels in both automotive engines and oil-fired furnaces. In automotive engines, the air was humidified prior to mixing gasoline with the air. In the case of oil-fired furnaces, steam was used to atomize the oil. Various techniques have been used to mix the components of the combustion process with water. These methods are called Cock.
No. 3,107,657 to Tomlinson, which injects water into the air chamber; Tomlinson, US Pat. No. 3,724,429, which passes water into the gasoline; Mills, U.S. Pat. No. 3,767,172, which passes a stream of fine bubbles through water, and Varekamp, U.S. Pat.
Examples include spraying a fine water mist into a gas flame as described in No. 3809523. A more recent approach, as described in Wentworth U.S. Pat. No. 3,862,819, involves dispersing a small amount of intake air into the combustion chamber and bubbling the air through water covered with a layer of oil. There is something.
上述の特許のうち、最初に述べた４つの手法は
１つの問題を含んでおり、すなわち、これらは水
の供給を連続的に行わなければならない。ウエン
トウオース特許におけるシステムでは使用水は減
少するが、ウエントウオースによつて提供される
よりも一層高い範囲まで燃焼効率を増加すること
が望ましい。また、ウエントウオースによつて指
摘されるように、多量の水の使用を伴なう最初の
４つの手法は自動車用機関の寿命を短縮するよう
な損傷を起させる可能性がある。 Of the patents mentioned above, the first four approaches involve one problem: they require a continuous supply of water. Although the system in the Wentworth patent reduces water usage, it is desirable to increase combustion efficiency to a higher range than that provided by Wentworth. Also, as pointed out by Wentworth, the first four techniques, which involve the use of large amounts of water, can cause damage that shortens the life of the motor vehicle engine.
本発明は上記のような従来法の欠点を排除した
ものであつて、密閉容器中の水相およびその上の
油相の中に白金触媒およびマンガン触媒をそれぞ
れ溶解し、液相上の浮子に取り付けた管を通して
水相中に空気を泡立たせて前記容器の空間内に前
記酸化触媒を分子の形で放出し、そしてこの分子
状触媒を導入管を通つて燃焼室に送入することを
特徴とする酸化触媒を燃焼室に供給する方法を提
供するものである。 The present invention eliminates the above-mentioned drawbacks of the conventional method, and consists of dissolving a platinum catalyst and a manganese catalyst in an aqueous phase and an oil phase above the aqueous phase in a closed container, and placing them on a float above the liquid phase. characterized in that air is bubbled into the aqueous phase through an attached tube to release the oxidation catalyst in molecular form into the space of the vessel, and this molecular catalyst is passed through an inlet tube into the combustion chamber. The present invention provides a method for supplying an oxidation catalyst to a combustion chamber.
従来酸化反応に使用されている白金触媒または
レニウム触媒は固体担体の表面上に担持された固
体の形のものであつて、液体燃料燃焼装置に使用
すると、燃焼反応体、例えばガソリンおよび空気
は気体であるが、触媒は固体であるので、燃焼の
際の酸化触媒反応は不均一系で行われ、高い燃焼
効率を得ることが困難であつた。 The platinum or rhenium catalysts conventionally used in oxidation reactions are in solid form supported on the surface of a solid support, and when used in liquid fuel combustion devices, the combustion reactants, such as gasoline and air, are converted into gases. However, since the catalyst is solid, the oxidation catalytic reaction during combustion takes place in a heterogeneous system, making it difficult to obtain high combustion efficiency.
しかしながら、本発明によれば、密閉容器中の
水相およびその上の油相の中に白金触媒およびマ
ンガン触媒をそれぞれ溶解し、液相上の浮上に取
り付けた管を通して水相中に泡立たせて前記容器
の空間内に前記酸化触媒を分子の形で放出し、こ
の分子状触媒を燃焼室に供給したので、液体燃料
と触媒とが均一系において酸化触媒反応に附せら
れることになり、一層高い燃焼効率を達成するこ
とができる。 However, according to the present invention, a platinum catalyst and a manganese catalyst are respectively dissolved in an aqueous phase and an oil phase above it in a closed container and bubbled into the aqueous phase through a tube attached to a float above the liquid phase. Since the oxidation catalyst is released in the form of molecules into the space of the container and the molecular catalyst is supplied to the combustion chamber, the liquid fuel and the catalyst are subjected to the oxidation catalytic reaction in a homogeneous system, which further enhances the oxidation catalyst reaction. High combustion efficiency can be achieved.
本発明によれば、２種類の触媒が液体中に溶解
され、この溶液中をガスが泡立てられてから次に
化石燃料の燃焼のような化学反応が行なわれる室
内に流通される。触媒を含む微量の水を炉の油燃
焼器に送出する好ましい実施例においては、白金
触媒の塩化物が溶解されている水を入れたフラス
コを使用する。石油基油層がこの水の上に浮んで
いる。水に不溶な第２触媒ナフテン酸マンガンが
この油の中に溶解される。油燃焼器は強制空気取
入れポートを有し、このポートには油層の上方の
フラスコ内の空間から吸引管が取付けられてい
る。取入れ管から大気圧の空気をフラスコ内に取
入れ、取入れ管の一端は、吸引管の吸引作用に応
答して水および油を通して空気を泡立てるために
水面下に浸漬されている。所定の背圧を確立する
ように予め定めた深さに吸引管の未満を浮遊させ
るために１個の浮子が吸引管に取付けられ、水の
深さに関係なく吸引圧力と大気圧との差によつて
あわ立てが調整される。白金およびマンガン触媒
の溶解は、気泡中に細かく分散した微量の触媒の
吸収を許すような分子レベルの触媒の細かい分散
をもたらす。こうして、燃焼過程の構成成分と触
媒との密接な混合が得られる。浮遊入口管および
出口吸引管を備えたフラスコが他の触媒用として
も使用でき、アルコールのような水以外の液体も
使用できる。また、触媒燃焼金属として上記白金
およびマンガンに加えてバリウムもまた使用でき
る。４臭化白金のような白金のハロゲン化合物も
使用できる。本発明の実施例では60℃で分解する
６塩化２水素白金を使用する。この分解は燃焼燃
料に有用な分子状白金を生成し、燃焼を促進させ
ると考えられる。すなわち、金属白金は塩素と結
合され、水に溶解され、空気によつて搬送され、
燃焼温度よりも低い温度で燃焼場所において金属
として放出されることになる。 According to the invention, two types of catalysts are dissolved in a liquid, and a gas is bubbled through the solution before being passed into a chamber where a chemical reaction, such as the combustion of a fossil fuel, is to take place. A preferred embodiment for delivering a small amount of water containing the catalyst to the oil combustor of the furnace uses a flask containing water in which the chloride of the platinum catalyst is dissolved. A layer of petroleum base oil floats on top of this water. A second catalyst, manganese naphthenate, which is insoluble in water, is dissolved in this oil. The oil combustor has a forced air intake port to which a suction tube is attached from the space in the flask above the oil layer. Air at atmospheric pressure is drawn into the flask through an intake tube, one end of which is submerged under water to bubble the air through the water and oil in response to the suction action of the suction tube. A float is attached to the suction tube to suspend the suction tube to a predetermined depth to establish a predetermined back pressure, the difference between suction pressure and atmospheric pressure regardless of the depth of the water. The frothing is adjusted by. Dissolution of the platinum and manganese catalysts results in a fine dispersion of the catalyst at the molecular level, allowing absorption of trace amounts of finely dispersed catalyst in the air bubbles. In this way, intimate mixing of the components of the combustion process and the catalyst is obtained. Flasks with floating inlet and outlet suction tubes can also be used for other catalysts, and liquids other than water, such as alcohols, can also be used. In addition to the above-mentioned platinum and manganese, barium can also be used as a catalytic combustion metal. Halogen compounds of platinum such as platinum tetrabromide can also be used. Examples of the present invention use platinum dihydrogen hexachloride, which decomposes at 60°C. This decomposition is thought to produce molecular platinum, which is useful as a combustion fuel, and promotes combustion. That is, platinum metal is combined with chlorine, dissolved in water, transported by air,
It will be released as metal at the combustion site at a temperature below the combustion temperature.
以下、本発明を図面を参照しながら説明する。 Hereinafter, the present invention will be explained with reference to the drawings.
第１図において、触媒送出システム１０はフラ
スコ１２、下端附近に配設された浮子１６をもつ
管１４、しや断弁２０をもつ管１８、油燃焼器２
４を具備する炉２２、および燃焼器２４内に空気
を送り込む遠心式フアン２６からなる。管１８は
フアン２６のハウジング２９に設けられた孔を貫
通した末端２８をもち、該末端２８は空気流の下
流方向に面し、これによつて管１８に吸引作用を
与える。ポート３２において空気を吸入しかつポ
ート３４から空気を排出するため矢印３２の方向
に羽根３０が回転する。管１８はフラスコ１２の
出口として用いられ、かつフラスコの孔３６で固
定されている。管１４は、フラスコの孔４０に固
定された管状部品３８によつてフラスコ１２に滑
動可能に取付けられている。管１４の上端は大気
に開口している。 In FIG. 1, a catalyst delivery system 10 includes a flask 12, a tube 14 with a float 16 disposed near its lower end, a tube 18 with a bow valve 20, and an oil combustor 2.
4 and a centrifugal fan 26 that blows air into the combustor 24. The tube 18 has an end 28 passing through a hole in the housing 29 of the fan 26, the end 28 facing in the downstream direction of the air flow, thereby imparting suction to the tube 18. Vane 30 rotates in the direction of arrow 32 to intake air at port 32 and expel air from port 34. Tube 18 serves as an outlet for flask 12 and is secured in flask bore 36. Tube 14 is slidably attached to flask 12 by a tubular piece 38 secured to a bore 40 in the flask. The upper end of tube 14 is open to the atmosphere.
フラスコ１２は、表面に油層４４が存在する水
４２で部分的に満たされている。管１８の吸引作
用は、油４４および水４２の上方の空所内の空気
圧力を低減し、管１４内の水位を下降させる。浮
子１６は管１４の底端を水面下所定の距離に維持
する。管１４上の浮子の位置は、管１４内の水柱
の背圧が管１８内の吸引圧力よりも小さいように
調節され、大気が管１４を通つて下方に引入れら
れ、浮子１６を通つて泡立つて空所４６内に入る
この気泡は水に溶けている物質と微量の水蒸気お
よび油を吸収する。とくに、燃焼反応において触
媒として働く白金およびマンガンの可溶性化合物
は水４２および油４４それぞれに溶解されてい
る。 Flask 12 is partially filled with water 42 with an oil layer 44 on the surface. The suction action of tube 18 reduces the air pressure in the cavity above oil 44 and water 42, lowering the water level within tube 14. Float 16 maintains the bottom end of tube 14 a predetermined distance below the water surface. The position of the float on the tube 14 is adjusted such that the back pressure of the water column in the tube 14 is less than the suction pressure in the tube 18 and atmospheric air is drawn downwardly through the tube 14 and through the float 16. These bubbles that bubble up and enter the cavity 46 absorb substances dissolved in the water and trace amounts of water vapor and oil. In particular, soluble compounds of platinum and manganese that act as catalysts in the combustion reaction are dissolved in water 42 and oil 44, respectively.
フラスコ１２内に収容された液体中への触媒の
溶解は触媒の細かい分散物を提供し、触媒の分子
は沸き上る気泡によつて搬送され、管１８を通つ
て炉２２内の燃焼区域に送入される。フラスコ１
２内の液体中の物質は、空気を湿めらせる水蒸気
の吸収の場合と同様にして空気中に吸収される。
分子レベルでの吸収作用は、これによつて何等触
媒を浪費せずに正確に所望の微少量の触媒を計量
できるので、好ましいものである。これに反し
て、触媒のエーロゾル状の浮遊は、はるかに多量
の触媒が必要量以上に消費されるので一層無駄が
大きい。そのうえ、エーロゾルの浮遊は多量の水
を消費するので、フラスコ１２への補充はその所
要頻度が多くなる。従つて、水溶性の白金または
レニウム触媒を使用するときには上記のよう不利
益を免れず、また、水のような低粘性液体は泡立
ちによる飛沫発生が著しく、触媒の浪費が大き
く、燃焼条件の確保が困難であつた。 Dissolution of the catalyst in the liquid contained in flask 12 provides a fine dispersion of catalyst, and the catalyst molecules are carried by the rising bubbles and sent through tube 18 to the combustion zone in furnace 22. entered. flask 1
The substances in the liquid in 2 are absorbed into the air in a manner similar to the absorption of water vapor that moistens the air.
Absorption at the molecular level is preferred because it allows precise metering of the desired minute amounts of catalyst without wasting any catalyst. In contrast, floating the catalyst in an aerosol is more wasteful as much more catalyst is consumed than is required. Moreover, floating aerosol consumes a large amount of water, so refilling the flask 12 is required more frequently. Therefore, when using a water-soluble platinum or rhenium catalyst, the disadvantages mentioned above cannot be avoided.In addition, low viscosity liquids such as water generate a lot of droplets due to foaming, resulting in a large waste of catalyst, and it is difficult to ensure combustion conditions. was difficult.
これに反して、本発明においては水およびその
上にある油層にそれぞれ白金触媒およびマンガン
触媒を溶解させたので上記のような欠点を排除
し、一層高い燃焼効率が達成される。 On the other hand, in the present invention, the platinum catalyst and the manganese catalyst are dissolved in the water and the oil layer thereon, respectively, thereby eliminating the above-mentioned drawbacks and achieving even higher combustion efficiency.
液体の粘度は、液体と空気の界面での気泡の噴
出によるエーロゾルの発生を制限するうえで重要
な因子である。従つて、水のよう低粘性液体は活
発な泡立ちをして飛散し、かつエーロゾルを形成
するが、重油のような粘性液体は飛沫発生やエー
ロゾール形成を伴わずに、ゆつくりとした泡立ち
運動を行なう。油４４の層は充分な粘度を有して
いるから油４４或は水４２の飛沫発生も起らな
い。従つて本発明によれば、油および水ならびに
これらの中に溶解された触媒の良好な保存が常に
確保される。 The viscosity of a liquid is an important factor in limiting the generation of aerosols due to the ejection of bubbles at the liquid-air interface. Therefore, low-viscosity liquids such as water actively foam, scatter, and form aerosols, whereas viscous liquids such as heavy oil do not generate droplets or form aerosols, but emit slow bubbling movements. Let's do it. Since the layer of oil 44 has sufficient viscosity, no splashes of oil 44 or water 42 occur. According to the invention, therefore, good preservation of the oil and water and of the catalyst dissolved therein is always ensured.
フラスコ１２はその中に収納する液体に対し不
滲透性の剛性材料で作られる。油および水が用い
られる本発明の実施例において、フラスコはガラ
ス、若しくはレクサン（Lexan）の商品名で市販
されているポリカーボネート樹脂のような割れて
も飛散しないプラスチツクで造られる。浮子１６
は発泡ポリウレタンの直円筒状で、かつ管１４を
貫通させるための孔を有している。フラスコ１２
の組立時に、浮子１６はまず管１４に配設されて
から管がフラスコの開口した底から通されて管状
部品３８内を滑り動かされる。次いでカバー板４
８をフラスコ１２の底縁の周囲に設けられたリム
５０に接着取付ける。フラスコを例えば炉室の床
のような取付表面に固定するために、フラスコの
フランジ５４にボルト５２を通す。管１４の下端
は、管の底端がカバー板４８と接近し或いは接触
しても泡立ちを行なえるように約45゜の角度をも
つて切断されている。カバー板、管１４および１
８、ならびに管状部品３８はすべて、フラスコ１
２を製作するのに用いられたものと同じ材料で構
成される。 Flask 12 is made of a rigid material that is impervious to the liquid it contains. In embodiments of the invention in which oil and water are used, the flask is constructed of glass or shatterproof plastic, such as polycarbonate resin sold under the trade name Lexan. Float 16
is a right cylindrical shape made of foamed polyurethane, and has a hole for passing the tube 14 therethrough. flask 12
During assembly, the float 16 is first placed in the tube 14 and then the tube is slid through the open bottom of the flask and into the tubular part 38. Next, cover plate 4
8 is adhesively attached to a rim 50 around the bottom edge of flask 12. A bolt 52 is threaded through a flange 54 of the flask to secure the flask to a mounting surface, such as the floor of a furnace chamber. The lower end of the tube 14 is cut at an angle of about 45 DEG to allow bubbling even when the bottom end of the tube approaches or contacts the cover plate 48. Cover plate, tubes 14 and 1
8, as well as tubular part 38, all of flask 1
Constructed from the same materials used to make 2.
実際例において、管状部品３８は長さ2.54で、
内径は1.905cmである。管１４はその内径が1.588
cmである。管１４の外側面は研磨されて1.900cm
の外径を提供し、管１４のまわりに0.0025cmのす
き間を与える。これによつて、管１４と管状部品
３８との間において充分しつくりした嵌合が提供
されて、管１４と管状部品３８との間を通る空気
量は無視し得る程度であり、同時に管１４は管状
部品３８内を滑り動くことができる。フラスコ１
２は高さ22.86cmで底面直径は40.64cmである。
0.318cm厚のレクサン・シートがフラスコ１２を
組立てるのに用いられた。管１８の直径は管１４
の外径と等しいか、またはわずかに小さい寸法
で、たとえば外径1.27cmである。 In the practical example, the tubular part 38 has a length of 2.54 mm;
The inner diameter is 1.905cm. The inner diameter of tube 14 is 1.588
cm. The outer surface of tube 14 is polished to 1.900 cm
and a clearance of 0.0025 cm around the tube 14. This provides a sufficiently tight fit between the tube 14 and the tubular component 38 such that a negligible amount of air passes between the tube 14 and the tubular component 38 while the tube 14 can slide within the tubular part 38. flask 1
2 has a height of 22.86 cm and a bottom diameter of 40.64 cm.
0.318 cm thick Lexan sheet was used to assemble flask 12. The diameter of the tube 18 is the same as that of the tube 14.
A dimension equal to or slightly smaller than the outside diameter of, for example, an outside diameter of 1.27 cm.
第２図は第１図のフラスコ１２の上方部分の変
形実施例であつて、これを１２Ａで示し、また１
６Ａで示された変形浮子を有している。フラスコ
１２Ａ作つたものと同じ材料の板５６がフラスコ
の上部の内面に接着固定されている。第１図のし
や断弁２０のような弁５８が、1.27cm管用のねじ
が施されたパイプ６０の１部によつて板５６に取
付けられている。管１４の外側面を研磨する代り
に、管１４の直径は1.905cmに保たれ、なお板５
６は1.910cmにリーマ上げした孔を有している。
こうして得られたすき間は第１図のフラスコ１２
に対し上述したすき間と同じである。浮子１６Ａ
の下縁はこれを取囲んで泡が円滑に流動するよう
に彎曲している。 FIG. 2 shows a modified embodiment of the upper portion of the flask 12 of FIG.
It has a modified float indicated by 6A. A plate 56 made of the same material from which flask 12A was made is adhesively fixed to the inner surface of the upper part of the flask. A valve 58, such as the bow valve 20 of FIG. 1, is attached to the plate 56 by a section of pipe 60 threaded for 1.27 cm tubing. Instead of polishing the outside surface of tube 14, the diameter of tube 14 is kept at 1.905 cm and plate 5
6 has a hole reamed to 1.910 cm.
The gap thus obtained is the flask 12 in Figure 1.
This is the same as the gap mentioned above. Float 16A
The lower edge of the tube is curved around it to allow the bubbles to flow smoothly.
第３〜４図は第１図の浮子１６の別の実施例を
示し、１６Ｂであらわす。浮子１６Ｂの底面は泡
の円滑な流れを助長するためにその上面に向つて
上向きに緩徐な彎曲をもつている。油４４を通る
泡の伝播を遅らせるため、浮子１６Ｂの周縁に１
組の半径方向突出部６２を配置し、これによつて
さらに飛沫現象を抑止する。こうして、油４４の
増大した粘度および浮子１６Ｂの物理的構造は相
互に作用し合つて、水および油の飛散現象および
エーロゾルの形成を抑止する。 3-4 show another embodiment of the float 16 of FIG. 1, designated 16B. The bottom surface of the float 16B has a gentle upward curvature toward its top surface to promote smooth flow of bubbles. To retard the propagation of bubbles through the oil 44, a
A set of radial projections 62 are arranged, thereby further inhibiting the splash phenomenon. Thus, the increased viscosity of oil 44 and the physical structure of float 16B interact to inhibit water and oil splashing phenomena and aerosol formation.
第１図に戻り、油４４の層を通る泡の伝播時間
は油の層の厚さに左右され、かつ油の量を増減す
ることによつて調節できる。水中での伝播時間は
泡が流動する経路を長くするために浮子の直径を
拡大することによつて増大できる。このようにし
て、油、水およひこれらに溶解されている触媒の
相対量を調整できる。２サイクルガソリン機関に
使用されているような油が油４４の層用に用いら
れている。白金およびマンガン触媒が用いられ
る。水および油それぞれの中で溶液をつくるため
に塩化物およびナフテン酸塩が用いられた。すな
わち、塩化２水素白金は水に溶け、またナフテン
酸マンガンは油に溶ける。管１８によつて搬送さ
れた空気の中への触媒の吸収速度は泡立ち速度に
比例して、これは管１４内の水柱の高さによつて
調整される。この水柱の高さは管１４を大気に開
放すること、および管の末端に対する浮子１６の
位置決めによつて予め調節される。管１４を最初
に取付け、浮子１６を管の上の方に位置づけてか
ら、油および水が管の上部から注入される。油お
よび水がそれらの平衡した位置に達し、かつ管１
８からフアン２６によつて吸引作用を与えたのち
に、浮子１６がフラスコ１２の頂部に設けられた
孔から管１４を引き入れることによつて所定位置
に設定される。 Returning to FIG. 1, the propagation time of a bubble through the layer of oil 44 depends on the thickness of the layer of oil and can be adjusted by increasing or decreasing the amount of oil. The transit time in the water can be increased by increasing the diameter of the float to lengthen the path the bubbles travel. In this way, the relative amounts of oil, water and catalyst dissolved therein can be adjusted. An oil such as that used in two-stroke gasoline engines is used for the layer of oil 44. Platinum and manganese catalysts are used. Chlorides and naphthenates were used to form solutions in water and oil, respectively. That is, platinum dihydrogen chloride is soluble in water, and manganese naphthenate is soluble in oil. The rate of absorption of catalyst into the air conveyed by tube 18 is proportional to the bubbling rate, which is adjusted by the height of the water column within tube 14. The height of this water column is preadjusted by opening the tube 14 to the atmosphere and positioning the float 16 relative to the end of the tube. After the tube 14 is first installed and the float 16 is positioned higher up the tube, oil and water are injected from the top of the tube. When oil and water reach their equilibrium position and tube 1
After applying suction from 8 by fan 26, float 16 is set into position by drawing tube 14 through a hole in the top of flask 12.
例として、油燃焼器２４がほぼ56.775／hrの
速度で油を燃焼する場合、フラスコ１２は15.24
cmの水柱に水４ｇで充たされ、かつ油４４の層は
その深さを0.635cmとした。触媒H2PtCl6・6H2O
を水121.12中に1gr溶解しナフテン酸マンガン
を油層中に0.01ｇ溶解して用いた。また泡立ち速
度としては２〜４泡粒／sec.を用いた。こうして
極めて良好な燃焼状況が得られた。 As an example, if oil combustor 24 burns oil at a rate of approximately 56.775/hr, flask 12 will burn oil at a rate of approximately 56.775/hr.
cm water column was filled with 4 g of water, and the layer of oil 44 had a depth of 0.635 cm. Catalyst H 2 PtCl 6・6H 2 O
was dissolved in 121.12 g of water, and 0.01 g of manganese naphthenate was dissolved in the oil layer. Further, the foaming rate was 2 to 4 bubbles/sec. In this way, extremely good combustion conditions were obtained.
第１図は本発明による触媒送出システムの説明
図、第２図は第１図のフラスコの上方部分の別種
実施例、第３図および第４図はそれぞれ、第１図
の浮子の他の実施例の側面図および平面図であ
る。
図中；符号：10……触媒送出システム、１２…
…フラスコ、１４……管、１６……浮子、１８…
…管、２０……しや断弁、２２……炉、２４……
油燃焼器、２６……遠心フアン、２８……管末
端、２９……ハウジング、３０……羽根、３２…
…吸入ポート、矢印、３４……排出ポート、３６
……孔、３８……管状部品、４０……孔、４２…
…水、４４……油、４６……空所、４８……カバ
ー板、５０……リム、５２……ボルト、５４……
フランジ、５６……板、５８……弁、６０……パ
イプ、６２……突出部を示す。
1 is an illustration of a catalyst delivery system according to the invention, FIG. 2 is an alternative embodiment of the upper part of the flask of FIG. 1, and FIGS. 3 and 4 are respective embodiments of the float of FIG. 1. FIG. 3 is a side view and a top view of an example. In the figure; code: 10...catalyst delivery system, 12...
...Flask, 14...Tube, 16...Float, 18...
...Pipe, 20...Sheath valve, 22...Furnace, 24...
Oil combustor, 26... Centrifugal fan, 28... Tube end, 29... Housing, 30... Vane, 32...
...Suction port, arrow, 34...Exhaust port, 36
... hole, 38 ... tubular part, 40 ... hole, 42 ...
...Water, 44...Oil, 46...Vacancy, 48...Cover plate, 50...Rim, 52...Bolt, 54...
Flange, 56...plate, 58...valve, 60...pipe, 62...projection.
Claims (1)
白金触媒およびマンガン触媒をそれぞれ溶解し、
液相上の浮子に取り付けた管を通して水相中に空
気を泡立たせて前記容器の空間内に前記酸化触媒
を分子の形で放出し、そしてこの分子状触媒を導
入管を通つて燃焼室に送入することを特徴とする
酸化触媒を燃焼室に供給する方法。1 Dissolve a platinum catalyst and a manganese catalyst in an aqueous phase and an oil phase above it in a closed container,
Air is bubbled into the aqueous phase through a tube attached to a float above the liquid phase to release the oxidation catalyst in molecular form into the space of the vessel, and this molecular catalyst is introduced into the combustion chamber through an inlet tube. A method for supplying an oxidation catalyst to a combustion chamber, characterized in that the oxidation catalyst is introduced into a combustion chamber.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86241177A | 1977-12-20 | 1977-12-20 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5496836A JPS5496836A (en) | 1979-07-31 |
| JPS6359042B2 true JPS6359042B2 (en) | 1988-11-17 |
Family
ID=25338433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15213878A Granted JPS5496836A (en) | 1977-12-20 | 1978-12-11 | Catalyst delivery system for combustion chamber and its delivery method |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS5496836A (en) |
| AU (1) | AU4281778A (en) |
| CA (1) | CA1120849A (en) |
| DE (1) | DE2854126A1 (en) |
| DK (1) | DK568578A (en) |
| FR (1) | FR2412345A1 (en) |
| GB (1) | GB2010393B (en) |
| IL (1) | IL56145A0 (en) |
| NO (1) | NO784276L (en) |
| NZ (1) | NZ189018A (en) |
| SE (1) | SE7813002L (en) |
| ZA (1) | ZA786860B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4410467A (en) * | 1981-11-09 | 1983-10-18 | Wentworth Fred Albert Jr | Ion-vapor generator and method |
| US4475483A (en) * | 1983-04-15 | 1984-10-09 | Robinson Barnett J | Catalyst delivery system |
| JPS60207824A (en) * | 1984-04-02 | 1985-10-19 | バ−ネツト・ジエイ・ロビンソン | Catalyst delivery system |
| DE4018797C1 (en) * | 1990-06-12 | 1991-05-23 | Miltiathis Markou | |
| TR26566A (en) * | 1991-07-02 | 1995-03-15 | Miltiathis Markou | A METHOD AND REGULATION FOR IMPROVING COMBUSTION EFFICIENCY IN AN ICIN COMBUSTION ENGINE. |
| DE4129297C2 (en) * | 1991-09-03 | 1998-11-19 | Oberland Mangold Gmbh | Device for supplying a fuel additive for an internal combustion engine |
| DE29818498U1 (en) * | 1998-10-16 | 2000-02-24 | Celcat International Ltd | Device for introducing a composition containing cerium oxide into the combustion chamber of an internal combustion engine |
| AR074096A1 (en) * | 2009-11-10 | 2010-12-22 | Bortolussi Osvaldo Daniel | ECOLOGICAL DEVICE / FUEL OPTIMIZER FOR INTERNAL COMBUSTION ENGINES THAT INCREASES A MASS OF MOISTURE AIR THAT ENTERS SUCH ENGINE EITHER BY VACUUM SUCTION OR BY NORMAL ASPIRATION |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5097725A (en) * | 1974-01-02 | 1975-08-04 | ||
| JPS50154839A (en) * | 1974-06-04 | 1975-12-13 | ||
| JPS51128031A (en) * | 1975-05-01 | 1976-11-08 | Nippon Furnace Kogyo Kaisha Ltd | Process of preventing generation of no# |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2460700A (en) * | 1947-07-01 | 1949-02-01 | Leo Corp | Method of operating an internal-combustion engine |
| BE698505A (en) * | 1967-05-16 | 1967-11-03 | ||
| CH535896A (en) * | 1970-06-08 | 1973-04-15 | Maingeot Raymond | Process for improving the combustion of a fuel and for reducing the proportion of harmful elements in its residues |
| GB1364696A (en) * | 1970-12-04 | 1974-08-29 | Kleinig F L | Liquid injection apparatus for internal combustion engine |
| BE772389A (en) * | 1971-09-09 | 1972-01-17 | Colle Andre Gabriel | AIR CONDITIONING PROCESS AND APPARATUS. |
| US4014637A (en) * | 1976-03-01 | 1977-03-29 | Schena Kenneth R | Catalyst generator |
| SE7702213L (en) * | 1976-03-01 | 1977-09-02 | Schena Kenneth R | METHODS AND DEVICE TO IMPROVE COMBUSTION IN COMBUSTION PROCESSES |
| US4009984A (en) * | 1976-03-08 | 1977-03-01 | Morrison Charles F | Vapor injection system for fuel combustion |
-
1978
- 1978-11-24 CA CA000316837A patent/CA1120849A/en not_active Expired
- 1978-11-27 NZ NZ189018A patent/NZ189018A/en unknown
- 1978-12-01 GB GB7846964A patent/GB2010393B/en not_active Expired
- 1978-12-06 ZA ZA786860A patent/ZA786860B/en unknown
- 1978-12-07 IL IL56145A patent/IL56145A0/en unknown
- 1978-12-11 JP JP15213878A patent/JPS5496836A/en active Granted
- 1978-12-15 DE DE19782854126 patent/DE2854126A1/en active Granted
- 1978-12-18 DK DK568578A patent/DK568578A/en not_active Application Discontinuation
- 1978-12-18 SE SE7813002A patent/SE7813002L/en unknown
- 1978-12-19 FR FR7835642A patent/FR2412345A1/en active Granted
- 1978-12-19 NO NO784276A patent/NO784276L/en unknown
- 1978-12-21 AU AU42817/78A patent/AU4281778A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5097725A (en) * | 1974-01-02 | 1975-08-04 | ||
| JPS50154839A (en) * | 1974-06-04 | 1975-12-13 | ||
| JPS51128031A (en) * | 1975-05-01 | 1976-11-08 | Nippon Furnace Kogyo Kaisha Ltd | Process of preventing generation of no# |
Also Published As
| Publication number | Publication date |
|---|---|
| NZ189018A (en) | 1980-04-28 |
| DE2854126A1 (en) | 1979-06-21 |
| GB2010393A (en) | 1979-06-27 |
| AU4281778A (en) | 1980-06-26 |
| SE7813002L (en) | 1979-06-21 |
| GB2010393B (en) | 1982-06-30 |
| DK568578A (en) | 1979-06-21 |
| DE2854126C2 (en) | 1988-09-29 |
| CA1120849A (en) | 1982-03-30 |
| JPS5496836A (en) | 1979-07-31 |
| IL56145A0 (en) | 1979-03-12 |
| NO784276L (en) | 1979-06-21 |
| FR2412345B1 (en) | 1984-09-28 |
| FR2412345A1 (en) | 1979-07-20 |
| ZA786860B (en) | 1980-01-30 |
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