JPS6348350A - Vinyl chloride resin composition having improved heat resistance - Google Patents
Vinyl chloride resin composition having improved heat resistanceInfo
- Publication number
- JPS6348350A JPS6348350A JP19042686A JP19042686A JPS6348350A JP S6348350 A JPS6348350 A JP S6348350A JP 19042686 A JP19042686 A JP 19042686A JP 19042686 A JP19042686 A JP 19042686A JP S6348350 A JPS6348350 A JP S6348350A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- vinyl chloride
- chloride resin
- heat resistance
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 14
- 239000011342 resin composition Substances 0.000 title claims description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 24
- 229920000728 polyester Polymers 0.000 claims abstract description 18
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 5
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 239000003381 stabilizer Substances 0.000 abstract description 12
- 239000002253 acid Substances 0.000 abstract description 9
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 abstract description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000314 lubricant Substances 0.000 abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 abstract description 3
- -1 acetic acid) Chemical class 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 229910052681 coesite Inorganic materials 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract description 2
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 2
- 239000000377 silicon dioxide Substances 0.000 abstract description 2
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 2
- 229910052682 stishovite Inorganic materials 0.000 abstract description 2
- 150000005846 sugar alcohols Polymers 0.000 abstract description 2
- 229910052905 tridymite Inorganic materials 0.000 abstract description 2
- 239000000326 ultraviolet stabilizing agent Substances 0.000 abstract description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract 2
- 229940058015 1,3-butylene glycol Drugs 0.000 abstract 1
- 239000001361 adipic acid Substances 0.000 abstract 1
- 235000011037 adipic acid Nutrition 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- 235000019437 butane-1,3-diol Nutrition 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000004902 Softening Agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- KEMQGTRYUADPNZ-UHFFFAOYSA-N heptadecanoic acid Chemical compound CCCCCCCCCCCCCCCCC(O)=O KEMQGTRYUADPNZ-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 2
- ONUFRYFLRFLSOM-UHFFFAOYSA-N lead;octadecanoic acid Chemical compound [Pb].CCCCCCCCCCCCCCCCCC(O)=O ONUFRYFLRFLSOM-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- SZHOJFHSIKHZHA-UHFFFAOYSA-N tridecanoic acid Chemical compound CCCCCCCCCCCCC(O)=O SZHOJFHSIKHZHA-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- GYSCBCSGKXNZRH-UHFFFAOYSA-N 1-benzothiophene-2-carboxamide Chemical compound C1=CC=C2SC(C(=O)N)=CC2=C1 GYSCBCSGKXNZRH-UHFFFAOYSA-N 0.000 description 1
- BKUSIKGSPSFQAC-RRKCRQDMSA-N 2'-deoxyinosine-5'-diphosphate Chemical compound O1[C@H](CO[P@@](O)(=O)OP(O)(O)=O)[C@@H](O)C[C@@H]1N1C(NC=NC2=O)=C2N=C1 BKUSIKGSPSFQAC-RRKCRQDMSA-N 0.000 description 1
- AWQSAIIDOMEEOD-UHFFFAOYSA-N 5,5-Dimethyl-4-(3-oxobutyl)dihydro-2(3H)-furanone Chemical compound CC(=O)CCC1CC(=O)OC1(C)C AWQSAIIDOMEEOD-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-N Decanoic acid Natural products CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- GONOPSZTUGRENK-UHFFFAOYSA-N benzyl(trichloro)silane Chemical compound Cl[Si](Cl)(Cl)CC1=CC=CC=C1 GONOPSZTUGRENK-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000006084 composite stabilizer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- NZNMSOFKMUBTKW-UHFFFAOYSA-N cyclohexanecarboxylic acid Chemical compound OC(=O)C1CCCCC1 NZNMSOFKMUBTKW-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- YAQXGBBDJYBXKL-UHFFFAOYSA-N iron(2+);1,10-phenanthroline;dicyanide Chemical compound [Fe+2].N#[C-].N#[C-].C1=CN=C2C3=NC=CC=C3C=CC2=C1.C1=CN=C2C3=NC=CC=C3C=CC2=C1 YAQXGBBDJYBXKL-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 description 1
- DUWWHGPELOTTOE-UHFFFAOYSA-N n-(5-chloro-2,4-dimethoxyphenyl)-3-oxobutanamide Chemical compound COC1=CC(OC)=C(NC(=O)CC(C)=O)C=C1Cl DUWWHGPELOTTOE-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N n-hexanoic acid Natural products CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明は、耐熱性を改良した軟質塩化ビニル系樹脂組
成物に係わるものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Field of Application) The present invention relates to a soft vinyl chloride resin composition with improved heat resistance.
（従来の技術及びその問題点）
従来、軟質の塩化ビニル系樹脂において、耐熱性を付与
するためには、安定剤として三塩基性硫酸鉛、二塩基性
７タル酸鉛、二塩基性亜りん酸鉛等の鉛系安定剤が配合
されていた。また柔軟性付与剤としては、ジイソデシル
７タレート（Ｄ Ｉ ＤＰ）、ノｔンデシル７タレート
（Ｄ Ｕ Ｐ ）、ノドリプシル７タレート（ＤＴＤＰ
）、トリオクチルトリメリテート（ＴＯＴＭ）、テトラ
オクチルビロメリテー）（ＴＯＰＭ）等の可塑剤が配合
されていた。(Prior art and its problems) Conventionally, in order to impart heat resistance to soft vinyl chloride resin, tribasic lead sulfate, dibasic lead heptalate, and dibasic phosphorus were used as stabilizers. Contains lead-based stabilizers such as acid lead. In addition, as a softening agent, diisodecyl 7-talate (DI DP), not-decyl 7-tally (D U P ), nodolypsyl 7-tally (DTDP) are used as softening agents.
), trioctyl trimellitate (TOTM), and tetraoctyl viromellitate (TOPM).
上記の可塑剤の中で、ＤＩＤＰ、ＤＵＰ、ＤＴＤＰ等の
７タル酸エステルは中程度の耐熱性が要求される分野に
、またＴＯＴＭ、ＴＯＰＭ等は高度の耐熱性が要求され
る分野に使用されている。Among the above plasticizers, heptatarate esters such as DIDP, DUP, and DTDP are used in fields that require moderate heat resistance, while TOTM and TOPM are used in fields that require high heat resistance. ing.
即ちこれら可塑剤はその分子量によって使い分けられて
おり、蒸気圧の低い可塑剤程、ｉ−を熱性の高い分野用
として賞月されてきた。That is, these plasticizers are used depending on their molecular weights, and plasticizers with lower vapor pressures have been prized for use in fields with high heat resistance.
しかしてポリエステル系可塑剤は重合度により、上記可
塑剤よりはるかに高い高分子量体が得られるが、上記の
耐熱用安定剤と併用するときは、ポリエステル系可塑剤
の分解が促進され、高分子量の特長が生かされない結果
になる。However, depending on the degree of polymerization, polyester plasticizers can yield much higher molecular weight products than the above plasticizers, but when used in combination with the above heat-resistant stabilizers, the decomposition of the polyester plasticizers is accelerated, resulting in high molecular weight products. The result is that the characteristics of the company are not utilized.
ポリエステル系可塑剤の分解を抑制するためには、鉛系
安定剤以外のＢａ Ｚｎ系、Ｃｄ−Ｂａ等の複合安定
剤が有効であるが、これらの配合によるものでは充分な
耐熱性が得られない。In order to suppress the decomposition of polyester plasticizers, composite stabilizers other than lead-based stabilizers such as BaZn-based and Cd-Ba are effective, but sufficient heat resistance cannot be obtained with these combinations. do not have.
（問題、直を解決するための手段）
本発明は、ポリエステル系可塑剤の高温での分解を抑え
、その特長である高分子量を生かすべく鋭意研究を重ね
、上記従来技術における問題点を克服して完成されたも
のであって、本発明の要旨とするところは塩化ビニルｊ
ｌ脂にポリエステル系可塑剤及び塩基性珪酸鉛を配合し
てなることを特徴とする塩化ビニル系樹脂組成物に存す
る。(Means for solving problems and problems) The present invention has been made through extensive research to suppress the decomposition of polyester plasticizers at high temperatures and to take advantage of their characteristic high molecular weight, and has overcome the problems in the prior art described above. The gist of the present invention is that vinyl chloride j
The present invention relates to a vinyl chloride resin composition characterized by blending a polyester plasticizer and basic lead silicate with lubricant.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明組成物における塩化ビニル系樹脂とはポリ塩化ビ
ニルのほか、塩化ビニルを優位量成分とする共重合体を
包含する意味であり、塩化ビニルと共重合可能な単量体
としては、塩化ビニリデン、エチレン、プロピレン、ア
クリロニトリル、酢酸ビニル、マレイン酸、アクリル酸
、メタクリル酸又はマレイン酸、アクリル酸、或いはメ
タクリル酸のエステル類が挙げられる。In the composition of the present invention, the vinyl chloride resin includes not only polyvinyl chloride but also copolymers containing vinyl chloride as a predominant component. , ethylene, propylene, acrylonitrile, vinyl acetate, maleic acid, acrylic acid, methacrylic acid, or esters of maleic acid, acrylic acid, or methacrylic acid.
本発明で用いられるポリエステル系可塑剤としては、従
来知られているポリエステル系可塑剤（ポリメリックと
も呼ばれている。）はいずれも使用できる。即ち、７ジ
ビン酸、アゼライン酸、セバシン酸、７タル酸のような
多価カルボン酸とエチレングリコール、１，２−プロピ
レングリコール、１．２−ブチレングリコール、１．３
−ブチレングリコール、１，４−ブチレングリコールの
ような多価アルコールとの重縮合体（例えば分子散６０
０〜ａｏｏｏ）の末端を１価アルコール例えハフタノー
ル、ペンタノール、ヘキサ／−ル、ヘプタメール、ロー
オクタ／−ル、２−エチルヘキサノール、７ナノール、
デカノール、ウンデカノール、ドデカ７−ノ呟 トリデ
カノール等の１種或いは２種以上で、又は１価カルボン
酸例えば酢酸、プロパン酸、ブタン酸、２−メチルプロ
パン酸、ペンタン酸、ヘキサン酸、ヘプタン酸、オクタ
ン酸、ノナン酸、デカン酸、ウンデカン酸、ドデカン酸
、トリデカン酸、テトラデカン酸、ペンタデカン酸、ヘ
キサデカン酸、ヘプタデカン酸、オクタデカン酸、シク
ロヘキサン酸、安Ｑ香酸等の１種或いは２種以上で封鎖
したものである。As the polyester plasticizer used in the present invention, any conventionally known polyester plasticizer (also called polymeric) can be used. That is, polyhydric carboxylic acids such as 7-divic acid, azelaic acid, sebacic acid, 7-talic acid and ethylene glycol, 1,2-propylene glycol, 1,2-butylene glycol, 1.3
- Polycondensates with polyhydric alcohols such as butylene glycol and 1,4-butylene glycol (e.g. molecular dispersion 60
0 to aooo) to a monohydric alcohol such as haftanol, pentanol, hexyl, heptamel, low octyl, 2-ethylhexanol, 7nanol,
One or more of decanol, undecanol, dodecanol, tridecanol, etc., or monovalent carboxylic acids such as acetic acid, propanoic acid, butanoic acid, 2-methylpropanoic acid, pentanoic acid, hexanoic acid, heptanoic acid, octane Blocked with one or more acids, nonanoic acid, decanoic acid, undecanoic acid, dodecanoic acid, tridecanoic acid, tetradecanoic acid, pentadecanoic acid, hexadecanoic acid, heptadecanoic acid, octadecanoic acid, cyclohexanoic acid, benzoic acid, etc. It is something.
本発明の組成物において、ポリエステル系可塑剤は塩化
ビニル系！（脂１００重量部に対し、通常１０〜２００
重量部の割合で配合される。この配合量が１０重量部未
満ではポリエステル系可塑剤の添加効果が見られず、ま
た２００重量部を越えると、可塑剤の浸み出しが起こり
、好ましい製品が得られない。In the composition of the present invention, the polyester plasticizer is vinyl chloride! (Usually 10 to 200 parts per 100 parts by weight of fat.
It is blended in the proportion of parts by weight. If the amount is less than 10 parts by weight, the effect of adding the polyester plasticizer will not be observed, and if it exceeds 200 parts by weight, leaching of the plasticizer will occur, making it impossible to obtain a desirable product.
本発明組成物における塩基性珪酸鉛としては、鉛及び珪
素をそれぞれＰｂＯ及びＳｉＯ２で表わすとき、Ｐｂ０
９５〜３０重量％、５ｉ０２５〜７０重量％の範囲のも
のが好ましく、この範囲外の比率し
のらのとなると熱安定性が必ずも充分といえない面がで
てくる。As the basic lead silicate in the composition of the present invention, when lead and silicon are respectively represented by PbO and SiO2, Pb0
A ratio of 95 to 30% by weight and 5i to 70% by weight is preferable, and if the ratio is outside this range, the thermal stability may not necessarily be sufficient.
本発明組成物において、塩基性珪酸鉛は、塩化ビニル系
用１１００重量部に対し、通常０．１〜２０重量部の割
合で配合される。この配合量が０．１重量部未満では耐
熱性が充分でなく、また２０重ｆｆｔ−ＩＳを越えると
、比重の増大、製品のフストアップを米たし、好ましく
ない。In the composition of the present invention, basic lead silicate is usually blended in a proportion of 0.1 to 20 parts by weight to 1100 parts by weight for vinyl chloride. If the amount is less than 0.1 part by weight, the heat resistance will not be sufficient, and if it exceeds 20 weight fft-IS, the specific gravity will increase and the product will become stiffer, which is not preferable.
本発明の組成物においては、上記のポリエステル系可塑
剤及び塩基性珪酸鉛の配合は必須であるが、その他、塩
化ビニル系樹ＴＩ：対して通常使用さｒ、でいる可塑剤
、耐熱性安定剤を併用してもよく、また、通常使用され
ている紫外線安定剤、酸化防止剤、難燃剤、滑剤、充填
材、着色剤等を添加してもよい。In the composition of the present invention, the above-mentioned polyester plasticizer and basic lead silicate are indispensable. In addition, commonly used ultraviolet stabilizers, antioxidants, flame retardants, lubricants, fillers, colorants, etc. may be added.
（実施例）
次に実施例を説明するが、本発明は以下の実施例によっ
て制約を受けるものではない。なお、以下の実施例及び
比較例において、部とあるのは重量部を表わす。(Example) Next, an example will be described, but the present invention is not limited by the following example. In addition, in the following Examples and Comparative Examples, parts represent parts by weight.
実施例１及び２並びに比較例１及び２
ポリ塩化ビニル（ｐ＝１３５０）１００ｇに下記表１記
載の可塑剤５０部、安定剤５部、更に炭酸カルシウム２
０部、滑剤としてのステアリン酸鉛０．５部及び酸化防
止剤としてのビスフェノールＡ０．５ｆＢをミル・ロー
ルで混練し、しかる後、０．５ｕｕａ厚さとなるようプ
レス加工した。得られたシートを１３６℃のギヤーオー
ブン中に７日間保持し、試験前後の重量変化を測定した
。その結果の重量損失（％）を下記表１に示す。Examples 1 and 2 and Comparative Examples 1 and 2 To 100 g of polyvinyl chloride (p=1350), 50 parts of a plasticizer listed in Table 1 below, 5 parts of a stabilizer, and 2 parts of calcium carbonate were added.
0 parts of lead stearate as a lubricant, 0.5 parts of lead stearate as a lubricant, and 0.5 fB of bisphenol A as an antioxidant were kneaded using a mill roll, and then pressed to a thickness of 0.5 uua. The obtained sheet was kept in a gear oven at 136° C. for 7 days, and the weight change before and after the test was measured. The resulting weight loss (%) is shown in Table 1 below.
−＼λ
表 １
表１において、実施例１．２及び比較例１のポリエステ
ル可塑剤は酸成分が７ジビン酸、グリコール成分が１．
３−ブチレングリコールと１，４−プチレングリコール
との等景況合物、封鎖剤が２−エチルヘキサノールのポ
リエステルからなる分子量約２０００のものである。Ｔ
ＯＴＭはトリオクチル） ｌ）メリテート。安定剤の塩
基性珪酸鉛（Ａ）はＰ）＋０８５％、Ｓｉ０２１５％、
塩基性珪酸鉛（Ｂ）はＰ［ｙ０４５％、５ｉ０２５５％
の珪酸鉛である。-\λ Table 1 In Table 1, the polyester plasticizers of Example 1.2 and Comparative Example 1 have an acid component of 7 divic acid and a glycol component of 1.
It is a compound of 3-butylene glycol and 1,4-butylene glycol, and the blocking agent is a polyester of 2-ethylhexanol having a molecular weight of about 2000. T
OTM is trioctyl) l) Melitate. The stabilizer basic lead silicate (A) is P) +085%, Si0215%,
Basic lead silicate (B) is P[y045%, 5i0255%
lead silicate.
実施例３及び比較例３〜５
ポリ塩化ビニル１００部に、下記表２記載の可塑剤６０
部、安定剤５部（ただし比較例４においては表の注に記
載した通りの添加物とそれぞれの量使用）、炭酸カルシ
ウム２０部、酸化防止剤としてのビスフェノールＡ０．
５部を配合し、ミルロールで混練後、１０ｍｍ厚さとな
るようプレス加工した。得られたシートを１３６°Ｃの
ギヤーオーブン中に２８日問保持し、試験前後の重量変
化を測定した。その結果の重量損失（％）を下記表２に
示す。Example 3 and Comparative Examples 3 to 5 60 parts of the plasticizer listed in Table 2 below was added to 100 parts of polyvinyl chloride.
parts, 5 parts of stabilizer (however, in Comparative Example 4, additives and their respective amounts were used as described in the notes to the table), 20 parts of calcium carbonate, and 0.0 parts of bisphenol A as an antioxidant.
5 parts were blended, kneaded with a mill roll, and then pressed to a thickness of 10 mm. The obtained sheet was kept in a gear oven at 136°C for 28 days, and the weight change before and after the test was measured. The resulting weight loss (%) is shown in Table 2 below.
表 ２
表２において、実施例３、比較例３及び４のポリエステ
ル可塑剤は酸成分がアノビン酸、グリコール成分が１．
２−ブチレングリコール、封鎖剤が２−エチルヘキサノ
ールであって平均分子量が約２０００のポリエステルか
らなる。実施例３で使用した安定剤の塩基性珪酸鉛（Ｂ
）は前記実施例２で用いた塩基性珪酸鉛（Ｂ）と同じで
ある。比較例４で用いた安定剤はＢａ−Ｚｎ系安定剤２
部、キレータ−１部及びエポキシ安定剤５部よりなる。Table 2 In Table 2, the polyester plasticizers of Example 3 and Comparative Examples 3 and 4 had an acid component of anobic acid and a glycol component of 1.
It consists of 2-butylene glycol, the capping agent is 2-ethylhexanol, and a polyester having an average molecular weight of about 2000. The stabilizer basic lead silicate (B
) is the same as the basic lead silicate (B) used in Example 2. The stabilizer used in Comparative Example 4 was Ba-Zn stabilizer 2.
1 part chelator and 5 parts epoxy stabilizer.
（発明の効果）
上記実施例及び比較例の結果から明らかなように、本発
明によれば、高分子量のポリエステル系可塑剤を使用し
、その耐熱度を損なわない塩基性珪酸鉛を組み合わせる
ことにより、高度の耐熱分野へ利用できる軟質塩化ビニ
ル系樹脂組成物が得られるようになった。(Effect of the invention) As is clear from the results of the above examples and comparative examples, according to the present invention, by using a high molecular weight polyester plasticizer and combining it with basic lead silicate that does not impair its heat resistance, , a soft vinyl chloride resin composition that can be used in highly heat-resistant fields has become available.
そして本発明組成物は高度の耐熱性を要求される、例え
ば電線被覆用、シート、ホース等に有用である。The composition of the present invention is useful for applications requiring a high degree of heat resistance, such as electrical wire coatings, sheets, hoses, and the like.
Claims (1)
酸鉛を配合してなることを特徴とする塩化ビニル系樹脂
組成物A vinyl chloride resin composition characterized by blending a polyester plasticizer and basic lead silicate with a vinyl chloride resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19042686A JPS6348350A (en) | 1986-08-15 | 1986-08-15 | Vinyl chloride resin composition having improved heat resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19042686A JPS6348350A (en) | 1986-08-15 | 1986-08-15 | Vinyl chloride resin composition having improved heat resistance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6348350A true JPS6348350A (en) | 1988-03-01 |
Family
ID=16257930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19042686A Pending JPS6348350A (en) | 1986-08-15 | 1986-08-15 | Vinyl chloride resin composition having improved heat resistance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6348350A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03205441A (en) * | 1990-01-05 | 1991-09-06 | Yazaki Corp | Vinyl chloride resin composition excellent in retaining ratproofing agent contained therein |
| US5065195A (en) * | 1989-07-05 | 1991-11-12 | Konica Corporation | Color image forming apparatus having a freely installable and detachable process cartridge |
| JPH04359814A (en) * | 1991-06-05 | 1992-12-14 | Polyplastics Co | Thin coated electric cable |
| JPH0645797U (en) * | 1992-11-27 | 1994-06-21 | オカモト株式会社 | Desk mat made of soft vinyl chloride resin |
| KR20030002350A (en) * | 2001-06-28 | 2003-01-09 | 삼진프라스틱공업 주식회사 | Making method of p.v.c. film for packed food and the p.v.c. film for packed food thereof |
| JP2008131820A (en) * | 2006-11-24 | 2008-06-05 | Denso Trim Kk | Stator of magnetic generator |
-
1986
- 1986-08-15 JP JP19042686A patent/JPS6348350A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5065195A (en) * | 1989-07-05 | 1991-11-12 | Konica Corporation | Color image forming apparatus having a freely installable and detachable process cartridge |
| JPH03205441A (en) * | 1990-01-05 | 1991-09-06 | Yazaki Corp | Vinyl chloride resin composition excellent in retaining ratproofing agent contained therein |
| JPH04359814A (en) * | 1991-06-05 | 1992-12-14 | Polyplastics Co | Thin coated electric cable |
| JPH0645797U (en) * | 1992-11-27 | 1994-06-21 | オカモト株式会社 | Desk mat made of soft vinyl chloride resin |
| KR20030002350A (en) * | 2001-06-28 | 2003-01-09 | 삼진프라스틱공업 주식회사 | Making method of p.v.c. film for packed food and the p.v.c. film for packed food thereof |
| JP2008131820A (en) * | 2006-11-24 | 2008-06-05 | Denso Trim Kk | Stator of magnetic generator |
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