JPS63303177A - Method for processing of wool fiber - Google Patents
Method for processing of wool fiberInfo
- Publication number
- JPS63303177A JPS63303177A JP13720787A JP13720787A JPS63303177A JP S63303177 A JPS63303177 A JP S63303177A JP 13720787 A JP13720787 A JP 13720787A JP 13720787 A JP13720787 A JP 13720787A JP S63303177 A JPS63303177 A JP S63303177A
- Authority
- JP
- Japan
- Prior art keywords
- temperature plasma
- low
- wool fibers
- felting
- wool
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims description 39
- 210000002268 wool Anatomy 0.000 title claims description 33
- 238000000034 method Methods 0.000 title claims description 30
- 238000009832 plasma treatment Methods 0.000 claims description 17
- 229920005989 resin Polymers 0.000 claims description 16
- 239000011347 resin Substances 0.000 claims description 16
- 229920002379 silicone rubber Polymers 0.000 claims description 16
- 230000000694 effects Effects 0.000 description 21
- 238000009950 felting Methods 0.000 description 17
- 239000004744 fabric Substances 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- 230000002265 prevention Effects 0.000 description 6
- 239000002759 woven fabric Substances 0.000 description 5
- 208000028659 discharge Diseases 0.000 description 3
- 210000004209 hair Anatomy 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 polysiloxane Polymers 0.000 description 2
- 241000282836 Camelus dromedarius Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 238000012695 Interfacial polymerization Methods 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 210000000085 cashmere Anatomy 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000002752 cationic softener Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000005108 dry cleaning Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004669 nonionic softener Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- TXEYQDLBPFQVAA-UHFFFAOYSA-N tetrafluoromethane Chemical compound FC(F)(F)F TXEYQDLBPFQVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は羊毛繊維の加工方法に関するものであり、特に
羊毛繊維の欠点である洗濯による収縮やフェルト化を防
止するための加工方法を提供するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a method for processing wool fibers, and in particular provides a processing method for preventing shrinkage and felting caused by washing, which are disadvantages of wool fibers. It is something.
（従来の技術）
羊毛繊維はその繊維表面にスケール（ウロコ）があるこ
とから繊維表面摩擦係数に異方性があり。(Prior art) Wool fibers have scales on their fiber surfaces, so the fiber surface friction coefficient has anisotropy.
すなわち毛根から毛先方向への摩擦係数と毛先から毛根
方向への摩擦係数に差があり、このことが洗濯によって
、収縮したりフェルト化したりする原因となっている。That is, there is a difference in the coefficient of friction from the root to the tip and from the tip to the root, and this causes shrinkage and felting when washed.
従来からこの問題を解決するために各種の方法が試みら
れており、主なものは以下のようである。Various methods have been tried in the past to solve this problem, and the main ones are as follows.
（ｉ） スケールを取除く方法 次亜塩素酸、ジクロロイソシアヌール酸。(i) How to remove scale Hypochlorous acid, dichloroisocyanuric acid.
過硫酸などの化学薬品で処理する。Treat with chemicals such as persulfuric acid.
（ｉｉ） スケールの表面を樹脂で被覆する方法繊維
表面で界面重合を行ってポリアミド系樹脂を形成したり
、ポリウレタン系樹脂をパッド−ドライ法で付与したり
する。(ii) Method of coating the surface of the scale with a resin A polyamide resin is formed by interfacial polymerization on the fiber surface, or a polyurethane resin is applied by a pad-dry method.
（ｉｉｉ ） 上記（ｉ）と（ｉｉ）の併用方法次亜
塩素酸などで処理した後、ポリアミドエピクロルヒドリ
ン樹脂などの樹脂で被覆する。(iii) Combination method of the above (i) and (ii) After treating with hypochlorous acid or the like, the material is coated with a resin such as polyamide epichlorohydrin resin.
（ｉｖ） 摩擦係数の異方性を少なくする方法コロナ
放電処理や低温プラズマ処理により繊維表面の摩擦係数
が変化し、異方性が減少する。(iv) Method for reducing anisotropy of friction coefficient Corona discharge treatment or low-temperature plasma treatment changes the friction coefficient of the fiber surface and reduces the anisotropy.
（発明が解決しようとする問題点）
上記のごとく羊毛繊維の収縮やフェルト化を改良しよう
とする方法が種々実施されているが、これらの方法には
、羊毛繊維独特の良好な風合い。(Problems to be Solved by the Invention) As described above, various methods have been implemented to improve the shrinkage and felting of wool fibers, but these methods do not have a good texture unique to wool fibers.
すなわち適度な柔軟性とヌメリ感が損われること。In other words, appropriate flexibility and sliminess are lost.
防縮効果、フェルト化防止効果が不充分なこと（特に上
記（ｉ）、（ｉｖ）の方法）、染色性に大きく影響し均
一な処理が困難なことなどの問題があった０本発明はこ
れらの問題を解決し良好な風合を保ちつつ、なおかつ良
好な防縮、フェルト化防止効果をも有する羊毛繊維の加
工方法を提供することを目的とするものである。The present invention has problems such as insufficient shrink-proofing effect and felting prevention effect (especially methods (i) and (iv) above), and difficulty in uniform processing due to large influence on dyeability. It is an object of the present invention to provide a method for processing wool fibers that solves the problem and maintains a good feel while also having good anti-shrink and felting effects.
（問題点を解決するための手段）
零゛発明者はこのような問題点を解決するため検討の結
果、防縮効果として優れた効果が得られる低温プラズマ
処理にシリコンエラストマー樹脂処理を組合わせれば、
羊毛繊維の風合いの悪化を防ぎつつ良好な防縮、フェル
ト化防止効果が得られることを見出し１本発明に到達し
たのである。(Means for Solving the Problems) In order to solve these problems, the inventors have studied and found that if silicone elastomer resin treatment is combined with low temperature plasma treatment, which provides an excellent shrink-proofing effect,
The present invention was achieved by discovering that good shrink-proofing and felting-preventing effects can be obtained while preventing the deterioration of the texture of wool fibers.
すなわち１本発明は、羊毛繊維をシリコンエラストマー
樹脂処理し１次いで低温プラズマ処理することを特徴と
する羊毛繊維の加工方法を要旨とするものである。That is, one aspect of the present invention is a method for processing wool fibers, which is characterized in that the wool fibers are treated with a silicone elastomer resin and then subjected to low-temperature plasma treatment.
以下９本発明の詳細な説明する。Hereinafter, nine aspects of the present invention will be described in detail.
本発明方法では、まず、羊毛繊維をシリコンエラストマ
ー樹脂処理する。In the method of the present invention, wool fibers are first treated with a silicone elastomer resin.
本発明でいう羊毛繊維とは、羊毛、カシミヤ毛。The wool fibers referred to in the present invention include wool and cashmere wool.
ラクダ毛、アルバカ毛等の獣毛（以下、羊毛等という、
）単独又はこれらの羊毛等を少なくとも３０％含む繊維
集合体をいい、その形態は、織物９編物、不織布（以下
、この三者を総称して羊毛布帛という。）あるいはトッ
プ、ロービング、スライバー等、いかなる形態でもよい
が、実用的な加工の容易さから羊毛布帛の状態で処理す
ることが望ましい。また本発明で使用するシリコンエラ
ストマーはジメチルポリシロキサン、メチルハイドロジ
エンポリシロキサンを主体に、これらのポリマ−の末端
に一５ｉ−ＯＨ，−Ｓｉ −ＯＲ，（Ｒ：アルキル基）
ポリシロキサンであり、一般的には繊維加工用としてエ
マルジョンタイプで市販されている。Animal hair such as camel hair and albaca hair (hereinafter referred to as wool, etc.)
) alone or as a fiber aggregate containing at least 30% of these wools, etc., and its forms include woven fabrics, knitted fabrics, non-woven fabrics (hereinafter these three are collectively referred to as wool fabrics), tops, rovings, slivers, etc. Although it may be in any form, it is preferable to process it in the form of a woolen fabric from the viewpoint of ease of practical processing. Furthermore, the silicone elastomer used in the present invention is mainly composed of dimethylpolysiloxane and methylhydrodienepolysiloxane, and these polymers have -OH, -Si-OR, (R: alkyl group) at the terminal end.
It is a polysiloxane and is generally commercially available in emulsion type for fiber processing.
このポリシロキサンは、羊毛繊維に通常の方法で含浸、
搾液、乾燥し、必要によりエージング（常温で１〜１０
日放置）あるいは熱キユアー（１２０〜１７０℃で３０
秒〜２分処理）により架橋反応させて、シリコンエラス
トマーとして繊維を被覆する形状となる。This polysiloxane is impregnated into wool fibers in the usual way.
Squeeze, dry, and age if necessary (1 to 10 minutes at room temperature)
Leave in the sun) or heat cure (30°C at 120-170°C)
A cross-linking reaction is carried out by a process of 2 seconds to 2 minutes, resulting in a silicone elastomer that coats the fibers.
本発明ではこのようにしてシリコンエラストマー樹脂処
理を行った羊毛繊維を更に低温プラズマ処理する。In the present invention, the wool fibers thus treated with silicone elastomer resin are further subjected to low temperature plasma treatment.
低温プラズマ処理は既に公知の装置１例えば繊維機械学
会誌３８巻患４（１９８５年）Ｐ１８８に記載の装置を
使用することができる。この装置は、プラズマ発生器と
真空ポンプが取りつけられた耐圧性真空容器の内部に一
対のプラズマ電極を設けてなるもので、まずプラズマ処
理すべきシリコンエラストマー処理された羊毛繊維を上
記容器内に収容し、該容器を真空ポンプにより排気減圧
して容器内圧力を０．０１〜０．３Ｔｏｒｒに調整した
後。The low-temperature plasma treatment can be performed using a known apparatus 1, for example, the apparatus described in Journal of the Textile Machinery Society, Vol. 38, No. 4 (1985), p. 188. This device consists of a pair of plasma electrodes installed inside a pressure-resistant vacuum container equipped with a plasma generator and a vacuum pump. First, silicone elastomer-treated wool fibers to be plasma-treated are placed inside the container. Then, the container was evacuated and depressurized using a vacuum pump to adjust the pressure inside the container to 0.01 to 0.3 Torr.
酸素、窒素、アルゴン等のガス、あるいはこれらの混合
ガスを容器内に導入置換し、容器内圧力を０．１〜５
Ｔｏｒｒに調整する。このような状態で容器内に設置さ
れた電極に高周波電力を印加して電極間にグロー放電を
起こせば、導入したガスが低温プラズマ状態となり、こ
の低温プラズマ雰囲気中を先に収容しておいた羊毛繊維
を順次通過させていくことにより低温プラズマ処理を行
う０通常この処理時間は１〜３００秒、好ましくは３０
〜１８０秒である。また使用するガスも上記以外にヘリ
ウム、−酸化炭素、炭素ガス等非重合性のガスであれば
いずれも良好な効果が得られ、四弗化炭素等の重合性ガ
スでも効果があり、特に限定されない。Gas such as oxygen, nitrogen, argon, or a mixture of these gases is introduced into the container and the pressure inside the container is set to 0.1 to 5.
Adjust to Torr. If high-frequency power is applied to the electrodes installed in the container in this condition to cause a glow discharge between the electrodes, the introduced gas will become a low-temperature plasma state, and the gas that was previously contained in this low-temperature plasma atmosphere will become a low-temperature plasma. A low temperature plasma treatment is carried out by passing the wool fibers one after another. Usually the treatment time is 1 to 300 seconds, preferably 30 seconds.
~180 seconds. In addition to the above gases, non-polymerizable gases such as helium, -carbon oxide, and carbon gas can also be used, and good effects can be obtained. Polymerizable gases such as carbon tetrafluoride are also effective. Not done.
本発明は以上の構成を有するものであり２本発明によれ
ば良好な風合を保ちつつ、なおかつ良好な防縮、フェル
ト化防止効果を有してなる羊毛繊維を得ることができる
。The present invention has the above configuration, and according to the present invention, it is possible to obtain wool fibers that maintain a good texture and also have good shrink-proofing and felting prevention effects.
従来羊毛繊維を低温プラズマ処理すると防縮。Conventional wool fibers are shrink-proofed when treated with low-temperature plasma.
フェルト化防止効果が得られると報告されている（例え
ば Ｐａｖｌａｔｈ ： Ａｐｐｌｉｅｄ Ｐｏｌ
ｙｍｅｒＳｙｍｐｏｓｉｕｍ Ｐａｒｔ Ｕ第１８巻、
１３７１頁、 １９７１年）が、実用的な洗濯方法例
えばＪＩＳ−Ｌ−０２１７，１０３法などの洗濯方法で
繰返し洗濯すると防縮、フェルト化防止効果ともに不充
分であり、いまだに実用化されていない。さらにこの低
温プラズマ処理のみによる方法で問題となるのは風合が
不良となることである。羊毛繊維は低温プラズマ処理さ
れると繊維の表面摩擦係数が大きくなり、その結果繊維
相互間ですべり難くなる。このことが洗濯による防縮効
果に寄与しているが風合的には粗硬感が強くなり羊毛繊
維独特の柔軟なヌ／り感が損われてしまう。本発明者は
この点を改良すべく低温プラズマ処理繊維をシリコン系
、カチオン系、ノニオン系など各種の柔軟剤で処理する
方法について検討した。しかしこの方法では使用する柔
軟剤の種類と付与量によって風合は良好なものが得られ
るものがあるものの、低温プラズマ処理によって得られ
た防縮、フェルト化防止効果が大きく損なわれ、風合い
が良好で防縮、フェルト化防止効果の優れたものは得ら
れなかった。この方法とは逆に羊毛繊維を先に柔軟剤で
処理し９次いで低温プラズマ処理する方法についても検
討した結果、はとんどが防縮、フェルト化防止効果ある
いは風合いのいずれかで満足なものが得られなかった中
で、特異的にシリコンエラストマー樹脂処理して次いで
低温プラズマ処理したもののみが良好な風合と優れた防
縮、フェルト化防止効果を示すことが判明した。It is reported that the effect of preventing felting can be obtained (for example, Pavlath: Applied Pol
ymerSymposium Part U Volume 18,
1371, 1971), but when repeatedly washed using a practical washing method such as the JIS-L-0217, 103 method, both the shrink-proofing and felting-preventing effects are insufficient, and it has not been put to practical use yet. Furthermore, a problem with this method using only low-temperature plasma treatment is that the texture becomes poor. When wool fibers are treated with low-temperature plasma, the surface friction coefficient of the fibers increases, and as a result, it becomes difficult for the fibers to slip between each other. Although this contributes to the shrink-proofing effect when washed, the texture becomes more rough and hard, and the soft, stiff feel unique to wool fibers is lost. In order to improve this point, the present inventors have investigated methods of treating low-temperature plasma treated fibers with various softeners such as silicone, cationic and nonionic softeners. However, with this method, although a good texture can be obtained depending on the type and amount of softener used, the anti-shrinkage and felting effects obtained by low-temperature plasma treatment are greatly impaired, resulting in a poor texture. No product with excellent shrink-proofing and felting-preventing effects was obtained. Contrary to this method, we also investigated a method in which wool fibers are first treated with a softener and then treated with low-temperature plasma, and most of them were found to be satisfactory either in terms of shrink-proofing, felting prevention effect, or texture. Among the products that were not obtained, it was found that only those specifically treated with silicone elastomer resin and then treated with low-temperature plasma exhibited good hand feel and excellent anti-shrinkage and felting prevention effects.
（作 用）
本発明では、まず、羊毛繊維をシリコンエラストマー樹
脂で処理する。この処理により羊毛繊維は柔軟なヌメリ
惑が付与されるが、防縮。(Function) In the present invention, wool fibers are first treated with a silicone elastomer resin. This treatment gives wool fibers a soft, slimy appearance, but prevents them from shrinking.
フェルト化防止効果は不充分である。またこのままの状
態では風合はややヌメリ感が強すぎて。The effect of preventing felting is insufficient. Also, in its current state, the texture is a little too slimy.
ヌルヌルした感触となる。次いで低温プラズマ処理を行
うことにより本来の羊毛繊維と同等な良好な風合に復帰
すると同時に、低温プラズマ処理効果により良好な防縮
、フェルト化防止効果が付与される。これは低温プラズ
マ処理のみによる防縮、フェルト化防止効果より優れて
おり、シリコンエラストマー樹脂が羊毛繊維表面のスケ
ール（ウロコ）を覆って、これに更に低温プラズマ処理
効果が付加されてシリコンエラストマー樹脂の洗濯耐久
性が向上すことなどが作用していると考えられる。It feels slimy. Next, by performing a low temperature plasma treatment, the fiber returns to a good texture equivalent to that of the original wool fiber, and at the same time, the low temperature plasma treatment provides good anti-shrinkage and felting prevention effects. This is superior to the anti-shrinkage and felting effect achieved by low-temperature plasma treatment alone; the silicone elastomer resin covers the scales on the wool fiber surface, and the low-temperature plasma treatment effect is added to the silicone elastomer resin. This is thought to be due to improved durability.
（実施例）
次に本発明を実施例により更に具体的に説明するが、実
施例における織物の性能の測定評価は、試料をいずれも
標準状態で２４時間放置したものを用いて行った。(Example) Next, the present invention will be described in more detail with reference to Examples. In the Examples, the performance of the fabrics was measured and evaluated using samples that were left in standard conditions for 24 hours.
（１）風合 触感により判定した。(1) Texture Judgment was made by touch.
（２）洗濯収縮率 ゛
ＪＩＳ −Ｌ −０２１７（１０３法）にて連続２０回
洗濯後の収縮率をＪＩＳ −Ｌ −１０４２にて測定し
た。(2) Washing Shrinkage Rate The shrinkage rate after 20 consecutive washings was measured according to JIS-L-1042 according to JIS-L-0217 (103 method).
（３）洗濯によるフェルト化状態
ＪＩＳ −Ｌ −０２１７（１０３法）にて連続２０回
洗濯後の外観を視感判定した。(3) Condition of felting after washing The appearance after washing 20 times in a row was visually evaluated according to JIS-L-0217 (103 method).
実施例１
ウール１００％の綾織物（経糸２／６０’Ｓ緯糸２／６
０’Ｓ、経糸密度６１本／吋、緯糸密度５６本／吋）を
通常の方法で染色整理仕上したものを用意し、これをシ
リコンエラストマー樹脂ＤＰ−３１４１（アライド社製
）の８０ｇ／Ｊ濃度液に含浸し、マングルで絞り率８０
％にて搾液後、乾絨機で１２０℃×３分の条件で乾燥し
た。これを２０℃×６５％ＰＨの標準状態の恒温恒温室
に４日間放置したあと、下記低温プラズマ処理条件１に
より低温プラズマ処理を行って本発明方法による加工織
物を得た。Example 1 100% wool twill fabric (warp 2/60'S weft 2/6
0'S, warp density 61/inch, weft density 56/inch) was dyed and finished in the usual way, and this was coated with silicone elastomer resin DP-3141 (manufactured by Allied Co., Ltd.) at a concentration of 80 g/J. Impregnated with liquid and squeezed with a mangle of 80
After squeezing the liquid at 10%, it was dried in a drying machine at 120°C for 3 minutes. This was left in a thermostatic chamber under standard conditions of 20°C x 65% PH for 4 days, and then subjected to low temperature plasma treatment under the following low temperature plasma treatment conditions 1 to obtain a processed fabric according to the method of the present invention.
低温プラズマ処理条件１
使用ガス 酸素ガス
ガス流量 ２００ ｍ ｌ ／ｗｉｎ真空度 １．Ｑ
Ｔｏｒｒ
放電周波数 １３．５６ ＭＨｚ
放電電力 ０．３Ｗ／ｃＩ１１ （電極面積）本発
明方法との比較のため２本実施例において低温プラズマ
処理を削くほかは本実施例と金く同一の方法により比較
用の織物（比較例１とする。）を製造し、又本実施例に
おいてシリコンエラストマー樹脂処理を削くほかは本実
施例と全く同一の方法により比較用の織物（比較例２と
する。）を製造した。さらに本実施例において、低温プ
ラズマ処理を先に行い、その後にシリコンエラストマー
樹脂処理を行うほかは本実施例と全く同一の方法により
比較用の織物（比較例３とする。）を製造した。尚、参
考までに本実施例におけるシリコンエラストマー樹脂処
理直前の織物を採集し１合わせて比較用の織物（比較例
４）とした。Low-temperature plasma processing conditions 1 Gas used Oxygen gas Gas flow rate 200 ml/win Degree of vacuum 1. Q
Torr Discharge frequency 13.56 MHz Discharge power 0.3W/cI11 (electrode area) For comparison with the method of the present invention, comparison was made using the same method as this example except that the low temperature plasma treatment was omitted in this example. A woven fabric for comparison (referred to as Comparative Example 1) was manufactured, and a woven fabric for comparison (referred to as Comparative Example 2) was manufactured in exactly the same manner as in this example except that the silicone elastomer resin treatment in this example was omitted. was manufactured. Furthermore, a comparative fabric (referred to as Comparative Example 3) was manufactured in the same manner as in this example, except that the low-temperature plasma treatment was first performed and then the silicone elastomer resin treatment was performed. For reference, the woven fabrics of this example immediately before the silicone elastomer resin treatment were collected and combined to form a comparative woven fabric (Comparative Example 4).
以上のようにして得られた本発明織物および比較用の織
物について、その性能の測定評価を行い、その結果を第
１表に示した。The performance of the fabrics of the present invention and comparative fabrics obtained as described above was measured and evaluated, and the results are shown in Table 1.
第１表
第１表より明らかなように９本発明方法によって加工処
理された織物は洗濯による収縮やフェルト化がほとんど
なく、風合も良好であった。これに対して比較例の織物
には風合と防縮、フェルト化防止効果とも満足できるも
のはなかった。As is clear from Table 1, the fabric processed by the method of the present invention had almost no shrinkage or felting upon washing, and had a good feel. On the other hand, the fabrics of comparative examples were not satisfactory in terms of texture, shrink-proofing, and felting prevention effects.
（発明の効果）
本発明方法によれば羊毛繊維の風合を損ねずに防縮、フ
ェルト化防止効果が得られる。これを使用した被服は家
庭で洗濯することが可能となり。(Effects of the Invention) According to the method of the present invention, the effect of preventing shrinkage and felting can be obtained without impairing the feel of wool fibers. Clothes made with this material can be washed at home.
従来ドライクリーニングする必要のあったことを考えれ
ば経済的にも大きな効果が期待できる。Considering that dry cleaning was required in the past, we can expect great economic benefits.
Claims (1)
いで低温プラズマ処理することを特徴とする羊毛繊維の
加工方法。(1) A method for processing wool fibers, which comprises treating wool fibers with a silicone elastomer resin and then subjecting them to low-temperature plasma treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13720787A JPS63303177A (en) | 1987-05-29 | 1987-05-29 | Method for processing of wool fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13720787A JPS63303177A (en) | 1987-05-29 | 1987-05-29 | Method for processing of wool fiber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63303177A true JPS63303177A (en) | 1988-12-09 |
Family
ID=15193293
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13720787A Pending JPS63303177A (en) | 1987-05-29 | 1987-05-29 | Method for processing of wool fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63303177A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01174670A (en) * | 1987-12-28 | 1989-07-11 | Kouon Denki Kk | Non-shrink treatment of animal fiber product |
| US6103068A (en) * | 1996-04-26 | 2000-08-15 | Bayer Aktiengesellschaft | Process for antifelting finishing of wool using a low-temperature plasma treatment |
-
1987
- 1987-05-29 JP JP13720787A patent/JPS63303177A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01174670A (en) * | 1987-12-28 | 1989-07-11 | Kouon Denki Kk | Non-shrink treatment of animal fiber product |
| US6103068A (en) * | 1996-04-26 | 2000-08-15 | Bayer Aktiengesellschaft | Process for antifelting finishing of wool using a low-temperature plasma treatment |
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