JPS6330233A - Preparation of laminated body with covered edge face - Google Patents

Preparation of laminated body with covered edge face

Info

Publication number
JPS6330233A
JPS6330233A JP17422586A JP17422586A JPS6330233A JP S6330233 A JPS6330233 A JP S6330233A JP 17422586 A JP17422586 A JP 17422586A JP 17422586 A JP17422586 A JP 17422586A JP S6330233 A JPS6330233 A JP S6330233A
Authority
JP
Japan
Prior art keywords
laminate
thermoplastic resin
resin film
face
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP17422586A
Other languages
Japanese (ja)
Inventor
Shoichi Kubo
久保 昭一
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to JP17422586A priority Critical patent/JPS6330233A/en
Publication of JPS6330233A publication Critical patent/JPS6330233A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined

Landscapes

  • Lining Or Joining Of Plastics Or The Like (AREA)

Abstract

PURPOSE:To cover efficiently and surely an edge face of an laminate, by abutting a thermoplastic resin film for covering on the edge face of the laminate and irradiating it with a laser beam. CONSTITUTION:Thermoplastic resin films 7, 8 are contacted on edge faces of a laminated body 6 of continuous length and five layers comprising thermoplastic resin films 1, 2, 3, a paper 4 and a metal foil 5 by means of nip rolls 9, 10. The films 7, 8 are then irradiated with laser beams 11, 12 from the faces of the films 7, 8 and are fused on the edge faces of the laminated body 6. A laminated body 13 whose edge faces are covered can be thereby obtained.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は端面被覆が施された積層体の製造方法に関する
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for producing a laminate having end-face coatings.

〔従来の技術〕[Conventional technology]

アルミニウム箔等の金属箔や紙等を熱可塑性樹脂フィル
ム層間に含む積層体は例えば食品包装袋用等として近年
広く利用されている。しかしながらこの種の積層体は端
面部において金属箔や紙等の端縁が表面に露出した状態
となっているため、保管時等に端面部から金属箔が酸化
腐食されたり、紙が吸湿して膨張し積層体が劣化すると
いう問題がある。このためこの種の積層体の劣化を防止
するために端面を被覆する種々の方法が提案されており
、例えば■積層体端面に熱可塑性樹脂フィルムを当接し
、シールバー等の加熱手段に接触させて加熱し、熱可塑
性樹脂フィルムを融着させて端面被覆を行う方法、■積
層体の片側の略半分を削り取り、折り返すことにより端
面を被覆するスカイブ法、■接着剤、粘着剤等を予め塗
布した被覆用テープを端面に貼着して被覆する方法、■
熔融した熱可塑性樹脂を積層体端面に押出して端面を被
覆する方法等が知られている。
Laminated bodies containing metal foil such as aluminum foil, paper, etc. between thermoplastic resin film layers have been widely used in recent years, for example, for food packaging bags. However, in this type of laminate, the edge of the metal foil or paper is exposed on the surface at the end surface, so the metal foil may oxidize and corrode from the end surface during storage, or the paper may absorb moisture. There is a problem that the laminate deteriorates due to expansion. For this reason, various methods have been proposed to cover the end faces of this type of laminate to prevent deterioration. For example, 1) Skive method, in which approximately half of one side of the laminate is scraped off and folded back to cover the end face; 2) Adhesive, pressure-sensitive adhesive, etc. is applied in advance. How to apply coating tape to the end surface to cover it, ■
A method is known in which a molten thermoplastic resin is extruded onto the end faces of the laminate to cover the end faces.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

しかしながら■の方法は端面被覆用の熱可塑性樹脂フィ
ルムをシールバー等の加熱手段に接触させて加熱するた
め、シールバー等へ熔融した熱可塑性樹脂が付着し、作
業性の低下をきたすという問題があった。また■の方法
は比較的厚い積層体を折り返すため折り線や、折ったあ
との厚みが不安定となる欠点があり、■の方法では被覆
用テープを端面に貼着するための特殊で高価な装置が必
要となるとともに、接着剤、粘着剤等を予め傅布した被
覆用テープを用いるため製造コストが高くつくという問
題があった。更に押出しにより端面に熱可塑性樹脂被覆
膜を形成する■の方法では、被覆膜の膜厚にムラを生じ
易く、膜厚にムラをを生じると被覆膜の接着力にもムラ
を生じ、その結果被覆膜が剥離し易くなり保護性が低下
するという問題があった。
However, in method (2), the thermoplastic resin film for end face coating is heated by contacting it with a heating means such as a seal bar, so there is a problem that the molten thermoplastic resin adheres to the seal bar etc., resulting in a decrease in workability. there were. In addition, method (■) has the disadvantage that the fold line and the thickness after folding are unstable because a relatively thick laminate is folded back. There are problems in that a device is required and the manufacturing cost is high because a covering tape coated with an adhesive, pressure-sensitive adhesive, etc. is used in advance. Furthermore, method (2), in which a thermoplastic resin coating film is formed on the end face by extrusion, tends to cause unevenness in the thickness of the coating film, and unevenness in the film thickness also causes unevenness in the adhesive strength of the coating film. As a result, there was a problem in that the coating film was likely to peel off, resulting in a decrease in protective properties.

〔問題点を解決するための手段〕[Means for solving problems]

本発明は上記従来技術の問題点を解消すべくなされたも
ので、積層体端面を効率よくかつ確実に熱可塑性樹脂に
より被覆して、端面被覆が施された積層体を製造し得る
方法を提供することを目的とする。
The present invention has been made in order to solve the problems of the prior art described above, and provides a method for efficiently and reliably covering the end faces of a laminate with a thermoplastic resin and manufacturing a laminate having end faces coated. The purpose is to

即ち本発明は紙もしくは金属箔の少なくとも1層を熱可
塑性樹脂フィルムの層間に含む積層体の端面に被覆用熱
可塑性樹脂フィルムを当接し、次いでレーザー光線を照
射して被覆用熱可塑性樹脂フィルムを積層体端面に融着
せしめ端面を被覆ずろことを特徴とする端面被覆が施さ
れた積層体の製造方法を要旨とするものである。
That is, in the present invention, a thermoplastic resin film for coating is brought into contact with the end face of a laminate including at least one layer of paper or metal foil between layers of thermoplastic resin film, and then a laser beam is irradiated to laminate the thermoplastic resin film for coating. The gist of the present invention is to provide a method for manufacturing a laminate having an end face coated body, which is characterized in that the end face is fused to the body end face and the end face is coated.

本発明において用いる積層体は紙もしくは金属箔の少な
くとも1層を熱可塑性樹脂フィルムの層間に含む積層体
であり、例えば熱可塑性樹脂フィルム/祇または金属箔
/熱可塑性樹脂フィルムよりなる3層構成のもの、熱可
塑性樹脂フィルム/紙/熱可塑性樹脂フィルム/金属箔
/熱可塑性樹脂フィルムよりなる5層構成のもの等が挙
げられるが、紙の層を2N以上含むもの、金属箔の層を
2層以上含むもの、紙の層と金属箔の層を各々2層以上
含むもの等層構成は任意である。
The laminate used in the present invention is a laminate containing at least one layer of paper or metal foil between layers of thermoplastic resin film, for example, a three-layer structure consisting of thermoplastic resin film/Yi or metal foil/thermoplastic resin film. Examples include those with a five-layer structure consisting of thermoplastic resin film/paper/thermoplastic resin film/metal foil/thermoplastic resin film, etc., but those with a paper layer of 2N or more, and two metal foil layers The layer structure may be arbitrary, such as those containing the above, or those containing two or more paper layers and two or more metal foil layers.

上記積層体における金属箔としては金、銀、アルミニウ
ム、銅、鉄、白金等いかなる金属も用いることができる
が、通常はアルミニウムが用いられる。また熱可塑性樹
脂フィルムの材質としては例えばポリエチレン、ポリプ
ロピレン、ポリ塩化ビニル、ポリ塩化ビニリデン、ポリ
スチレン、エチレン−アクリル酸共重合体、エチレン−
メタクリル酸共重合体、エチレン−酢酸ビニル共重合体
、エチレン−酢酸ビニル共重合体ケン化物、エチレン−
α−オレフィン共重合体エラストマー、スチレン−ブタ
ジェン−アクリロニトリル共重合体、ポリアミド、ポリ
カーボネート、ポリスルホン、ポリアセタール、ポリメ
チルメタクリレート、ポリフェニレンオキシド、ポリウ
レタン、ポリエチレンテレフタレート、ポリブチレンテ
レフタレート等が挙げられる。
As the metal foil in the laminate, any metal such as gold, silver, aluminum, copper, iron, platinum, etc. can be used, but aluminum is usually used. Examples of materials for thermoplastic resin films include polyethylene, polypropylene, polyvinyl chloride, polyvinylidene chloride, polystyrene, ethylene-acrylic acid copolymer, and ethylene-acrylic acid copolymer.
Methacrylic acid copolymer, ethylene-vinyl acetate copolymer, saponified ethylene-vinyl acetate copolymer, ethylene-
Examples include α-olefin copolymer elastomer, styrene-butadiene-acrylonitrile copolymer, polyamide, polycarbonate, polysulfone, polyacetal, polymethyl methacrylate, polyphenylene oxide, polyurethane, polyethylene terephthalate, polybutylene terephthalate, and the like.

本発明方法では上記材質よりなる例えば第1図に示す如
き熱可塑性樹脂フィルム1.2.3と紙4及び金属箔5
とからなる5層構成の長尺な積層体6の端面に被覆用熱
可塑性樹脂フィルム7.8をニップロール9.10ぐよ
って当接せしめ、次いで被覆用熱可塑性樹脂フィルム7
.8面よりレーザー光線11.12を照射して被覆用熱
可塑性樹脂フィルム7.8を積層体6の端面に融着せし
めることにより第2図に示す如き、端面被覆が施された
積層体13を得ることができる。上記被覆用熱可塑性樹
脂フィルム7.8としては積層体6における熱可塑性樹
脂フィルム1.2.3と同様の樹脂よりなるものが用い
られる。またレーザーとしては気体レーザー、固体レー
ザー、液体レーザー、半導体レーザー、ラマンレーザー
、エキシマレーザ−等いかなるものでもよく、被覆用熱
可塑性樹脂フィルム7.8の材質に応じて被覆用熱可塑
性樹脂フィルム7.8を端面に融着せしめるのに適した
エネルギーのものを適宜選択して用いる。
In the method of the present invention, a thermoplastic resin film 1.2.3 made of the above-mentioned materials, for example as shown in FIG.
The coating thermoplastic resin film 7.8 is brought into contact with the end face of the elongated 5-layer laminate 6 consisting of the nip roll 9.10, and then the coating thermoplastic resin film 7
.. By irradiating the laser beam 11.12 from 8 sides to fuse the coating thermoplastic resin film 7.8 to the end faces of the laminate 6, a laminate 13 with end face coating as shown in FIG. 2 is obtained. be able to. The covering thermoplastic resin film 7.8 is made of the same resin as the thermoplastic resin film 1.2.3 in the laminate 6. The laser may be any type such as gas laser, solid laser, liquid laser, semiconductor laser, Raman laser, excimer laser, etc., depending on the material of the coating thermoplastic resin film 7.8. An energy suitable for welding 8 to the end face is appropriately selected and used.

以上のようにして長手方向に沿う両端面が熱可塑性樹脂
フィルムにより被覆された長尺な積層体が得られるが、
幅方向に沿う両端面も上記と同様にして被覆することが
できる。
As described above, a long laminate having both end faces in the longitudinal direction covered with a thermoplastic resin film is obtained.
Both end faces along the width direction can also be coated in the same manner as above.

〔実施例〕〔Example〕

以下、実施例を挙げて本発明を更に詳細に説明する。 EXAMPLES Hereinafter, the present invention will be explained in more detail with reference to Examples.

実施例1〜3、比較例1〜3 第1表に示す構成の積層体に、実施例1〜3は端面に1
00μ厚のポリエチレンフィルムを当接して該フィルム
を500W型炭酸ガスレーザー照射により融着せしめた
。次いでこれら端面被覆を施した積層体と、比較例1〜
3の端面被覆を施していない積層体とを、3力月間水中
に浸漬して積層体の剥離の有無及び紙アルミニウム箔等
の腐食状態を観察し、以下の基準により判定した結果を
第1表に示す。
Examples 1 to 3, Comparative Examples 1 to 3 In Examples 1 to 3, 1 was added to the end face of the laminate having the structure shown in Table 1.
A polyethylene film having a thickness of 0.00 μm was brought into contact with the film, and the film was fused by irradiation with a 500 W carbon dioxide gas laser. Next, these end face coated laminates and Comparative Examples 1-
Table 1 shows the results of immersing the laminate without edge coating in step 3 in water for 3 months and observing the presence or absence of peeling of the laminate and the state of corrosion of the paper aluminum foil, etc., and judging based on the following criteria. Shown below.

判定基準 ○・・・積層体の剥離がなく、紙やアルミニウム箔の腐
食もない。
Judgment Criteria ○: No peeling of the laminate and no corrosion of paper or aluminum foil.

△・・・積層体の剥離や、紙、アルミニウム箔の腐食が
ややある。
△: There is some peeling of the laminate and some corrosion of paper and aluminum foil.

×・・・積層体の剥離や、紙、アルミニウム箔の腐食が
激しい。
×: Peeling of the laminate and severe corrosion of paper and aluminum foil.

第1表 尚、第1表の積層体の構成のうちPEはポリエチレンフ
ィルム、PETはポリエチレンテレフタレートフィルム
、^1はアルミニウム箔である。
Table 1 In the composition of the laminate in Table 1, PE is a polyethylene film, PET is a polyethylene terephthalate film, and ^1 is an aluminum foil.

〔発明の効果〕〔Effect of the invention〕

以上説明したように本発明製造方法は、レーザー光線照
射により積層体端面に被覆用熱可塑性樹脂フィルムを融
着して端面を被覆するものであり、被覆用熱可塑性樹脂
フィルムを非接触加熱により融着することができるため
、シールバー等の加熱手段による接触加熱により融着さ
せる従来の方法のように加熱手段に溶融した熱可塑性樹
脂が付着して作業性低下をきたす虞れがなく、しかも熱
可塑性樹脂フィルムを確実に融着し得るため、端面から
紙や金属箔が侵される虞れもなく、優れた積層体を確実
かつ効率良く製造することができる。
As explained above, in the manufacturing method of the present invention, a thermoplastic resin film for coating is fused to the end face of the laminate by laser beam irradiation to cover the end face, and the thermoplastic resin film for coating is fused by non-contact heating. This eliminates the risk of molten thermoplastic resin adhering to the heating means and reducing workability, unlike the conventional method of fusing by contact heating using a heating means such as a seal bar. Since the resin film can be reliably fused, there is no fear that the paper or metal foil will be corroded from the end surface, and an excellent laminate can be manufactured reliably and efficiently.

また本発明方法では予め接着剤や粘着剤が塗布されてい
る被覆用テープを積層体端面に貼着する方法のように特
殊で高価な装置を必要とせず、また本発明で用いる被覆
用熱可塑性樹脂フィルムは、予め接着剤や粘着剤が塗布
された被覆用テープに比して安価であるため優れた積層
体を安価に提供することができる等、種々の効果を有す
る。
In addition, the method of the present invention does not require special and expensive equipment unlike the method of pasting a covering tape coated with an adhesive or pressure-sensitive adhesive on the end face of the laminate, and the thermoplastic coating used in the present invention does not require special and expensive equipment. Resin films have various effects such as being able to provide excellent laminates at low cost since they are cheaper than covering tapes coated with adhesives or pressure-sensitive adhesives in advance.

【図面の簡単な説明】[Brief explanation of the drawing]

図面は本発明の一実施例を示し、第1図は本発明製造方
法の工程を示す斜視図、第2図は本発明方法により得ら
れる積層体の縦断面図である。 1.2.3・・・熱可塑性樹脂フィルム4・・・紙  
5・・・金属箔  6・・・積層体  7.8・・・被
覆用熱可塑性樹脂フィルム11.12・・・レーザー光
線  13・・・端面被覆が施された積層体
The drawings show an embodiment of the present invention, and FIG. 1 is a perspective view showing the steps of the manufacturing method of the present invention, and FIG. 2 is a longitudinal sectional view of a laminate obtained by the method of the present invention. 1.2.3...Thermoplastic resin film 4...Paper
5... Metal foil 6... Laminate 7.8... Thermoplastic resin film for coating 11.12... Laser beam 13... Laminate with end face coating applied

Claims (1)

【特許請求の範囲】[Claims] 紙もしくは金属箔の少なくとも1層を熱可塑性樹脂フィ
ルムの層間に含む積層体の端面に被覆用熱可塑性樹脂フ
ィルムを当接し、次いでレーザー光線を照射して被覆用
熱可塑性樹脂フィルムを積層体端面に融着せしめ端面を
被覆することを特徴とする端面被覆が施された積層体の
製造方法。
A thermoplastic resin film for coating is brought into contact with the end surface of a laminate containing at least one layer of paper or metal foil between layers of thermoplastic resin film, and then a laser beam is irradiated to melt the thermoplastic resin film for coating onto the end surface of the laminate. 1. A method for producing a laminate with end face coating, the method comprising covering the dressed end face.
JP17422586A 1986-07-24 1986-07-24 Preparation of laminated body with covered edge face Pending JPS6330233A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17422586A JPS6330233A (en) 1986-07-24 1986-07-24 Preparation of laminated body with covered edge face

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17422586A JPS6330233A (en) 1986-07-24 1986-07-24 Preparation of laminated body with covered edge face

Publications (1)

Publication Number Publication Date
JPS6330233A true JPS6330233A (en) 1988-02-08

Family

ID=15974910

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17422586A Pending JPS6330233A (en) 1986-07-24 1986-07-24 Preparation of laminated body with covered edge face

Country Status (1)

Country Link
JP (1) JPS6330233A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1065728C (en) * 1992-01-23 2001-05-16 利乐拉瓦尔集团及财务有限公司 A method of producing a soya drink
WO2005014265A1 (en) * 2003-07-18 2005-02-17 Solvay (Société Anonyme) Method for assembling elements of a structure comprising a honeycomb core

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1065728C (en) * 1992-01-23 2001-05-16 利乐拉瓦尔集团及财务有限公司 A method of producing a soya drink
WO2005014265A1 (en) * 2003-07-18 2005-02-17 Solvay (Société Anonyme) Method for assembling elements of a structure comprising a honeycomb core

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