JPS6328882A - Transparent resin coated enamelware - Google Patents
Transparent resin coated enamelwareInfo
- Publication number
- JPS6328882A JPS6328882A JP61172451A JP17245186A JPS6328882A JP S6328882 A JPS6328882 A JP S6328882A JP 61172451 A JP61172451 A JP 61172451A JP 17245186 A JP17245186 A JP 17245186A JP S6328882 A JPS6328882 A JP S6328882A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- transparent resin
- enamelware
- enamel
- coated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 32
- 239000011347 resin Substances 0.000 title claims abstract description 32
- 210000003298 dental enamel Anatomy 0.000 claims abstract description 47
- 238000005452 bending Methods 0.000 abstract description 5
- 229920002050 silicone resin Polymers 0.000 abstract description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 abstract description 3
- 239000004925 Acrylic resin Substances 0.000 abstract description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 3
- 229920001225 polyester resin Polymers 0.000 abstract description 3
- 239000004645 polyester resin Substances 0.000 abstract description 3
- 150000007513 acids Chemical class 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract description 2
- 238000005553 drilling Methods 0.000 abstract description 2
- 230000035939 shock Effects 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 2
- 238000000576 coating method Methods 0.000 abstract 2
- 238000005336 cracking Methods 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910001018 Cast iron Inorganic materials 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229910000975 Carbon steel Inorganic materials 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000010962 carbon steel Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009503 electrostatic coating Methods 0.000 description 2
- 238000004534 enameling Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910000680 Aluminized steel Inorganic materials 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C27/00—Elastic or yielding bearings or bearing supports, for exclusively rotary movement
- F16C27/06—Elastic or yielding bearings or bearing supports, for exclusively rotary movement by means of parts of rubber or like materials
- F16C27/066—Ball or roller bearings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C19/00—Bearings with rolling contact, for exclusively rotary movement
- F16C19/02—Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows
- F16C19/04—Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for radial load mainly
- F16C19/06—Bearings with rolling contact, for exclusively rotary movement with bearing balls essentially of the same size in one or more circular rows for radial load mainly with a single row or balls
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はホーロー層の表面を透明な樹脂で被覆して、ホ
ーロー層焼付は後の切断、折曲げ加工、または在庫保管
中の取扱いにおいて、ホーロー層のチッピングまたは傷
などの損傷を受けることを防止した、透明な樹脂で被覆
したホーロー製品に関するものである。Detailed Description of the Invention (Industrial Application Field) The present invention covers the surface of the enamel layer with a transparent resin, and the enamel layer is baked during subsequent cutting, bending, or handling during inventory storage. This relates to an enamel product coated with a transparent resin that prevents damage such as chipping or scratches to the enamel layer.
（従来の技術とその問題点）
ホーロー製品は、ホーロー層が硬く、耐久性に憬れ、熱
にも強く１色彩をカラフルにすることができ褪色しない
などの多くの利点を有するけれども、ホーロー層が剛直
性であるため、その後の取扱いの注意をしないと、衝撃
によりチッピングを起したり、ホーロー掛けの後の折曲
げ加工で割れまたは剥離を起したりする。(Conventional technology and its problems) Enamel products have many advantages such as having a hard enamel layer, being durable, being resistant to heat, being able to make one color colorful, and not fading. Because of its rigidity, if care is not taken when handling it afterwards, it may chip due to impact, or crack or peel when bent after being enameled.
特公昭４７−５９５８号公報に記載されるような、極薄
のアルミニウム箔にホーロー掛けして矯正ローラにてシ
ワ伸ばしするような場合には、優れた技術をもって行わ
ないと剥離を生ずる。In the case of enameling an extremely thin aluminum foil and smoothing out wrinkles using a straightening roller, as described in Japanese Patent Publication No. 47-5958, peeling will occur unless excellent technique is used.
鋳鉄製浴槽にホーロー掛けした浴槽は据付時などに衝撃
を与えないようにしないとホーロー層にチッピングが発
生する。If a cast iron bathtub is made of enamel and is not subjected to shocks during installation, chipping will occur in the enamel layer.
高価であるため代替製品の購入が困難であったり、再施
工も困難であるような製品では、例えば特公昭５４−２
５５２５号公報に記載されるような、ホーロー欠陥箇所
の補修方法により補修しなければならなかった。For products that are expensive and difficult to purchase as substitutes or difficult to reinstall, for example,
It had to be repaired using a method for repairing enamel defects as described in Japanese Patent No. 5525.
また、ホーロー掛は製品を切断したりすると、その端部
に微細な亀裂を生口、欠陥のない面が希望の面積よりも
小さくなり、端部の処理をして端部を完全なものにする
ことも困難である。In addition, when enamel products are cut, minute cracks may develop at the edges, and the defect-free surface becomes smaller than the desired area, so the edges must be treated to make them perfect. It is also difficult to do so.
（問題点を解決するための手段）
本発明の透明な樹脂で被覆したホーロー製品は上記のよ
うな問題点を解決するためになされたもので、ホーロー
層の表面を厚さ５ないし５００ｇｍの透明な樹脂で被覆
したことを必須の構成とするものである。(Means for solving the problem) The enamel product coated with a transparent resin of the present invention was made to solve the above problems, and the surface of the enamel layer is coated with a transparent resin coated with a thickness of 5 to 500 gm. It is an essential structure to be coated with a resin.
そして、形状が平板状である透明な樹脂で被覆したホー
ロー製品、および、形状がコイル状である透明な樹脂で
被覆したホーロー製品を好ましい実施悪様とするもので
ある。Preferred embodiments include enamel products coated with a transparent resin that have a flat plate shape, and enamel products that are coated with a transparent resin and have a coil shape.
適用する透明な樹脂は、フッ素樹脂、シリコン樹脂のほ
か、ホーロー製品の使用目的に応じて。Transparent resins that can be used include fluororesin and silicone resin, depending on the purpose of the enamel product.
ウレタン樹脂、塩化ビニール樹脂、アクリル樹脂および
ポリエステル樹脂など汎用の樹脂を用いても良い。General-purpose resins such as urethane resin, vinyl chloride resin, acrylic resin, and polyester resin may be used.
着色した透明ないし半透明の樹脂を用いると、ホーロー
層の色彩に変化を与えることができる。By using a colored transparent or translucent resin, the color of the enamel layer can be changed.
樹脂の塗布方法は、はけ掛け、ロール掛け、スプレー掛
け、静電塗装、浸漬塗装、粉体溶射塗装などにより、清
浄なホーロー面に塗装する。The resin is applied to a clean enamel surface by brushing, rolling, spraying, electrostatic coating, dipping, powder spraying, etc.
（作用）
素地は一般のもので、炭素鋼、ホーロー用脱炭鋼、アル
ミニウムメッキ鋼、アルミニウム板または箔、銅板また
は箔、鋳鉄製品などにホーロー掛けしたものに適用する
。(Function) The base material is general, and it is applicable to carbon steel, decarburized steel for enameling, aluminum plated steel, aluminum plate or foil, copper plate or foil, cast iron products, etc.
アルミニウムメッキ鋼の場合を例にとると、炭素鋼の両
面にアルミニウムメッキ層があり、そのアルミニウムメ
ッキ層の上の一面または両面にホーロー層が設けられ、
そのホーロー層の上に透明なフッ素樹脂、シリコン樹脂
のほか、ホーロー製品の使用目的に応じて、ウレタン樹
脂、塩化ビニール樹脂、アクリル樹脂またはポリエステ
ル樹脂など汎用の樹脂の皮膜が５〜ｓｏｏｇｍの厚さに
塗装固化されている。Taking the case of aluminized steel as an example, there is an aluminum plating layer on both sides of carbon steel, and a enamel layer is provided on one or both sides of the aluminum plating layer.
On the enamel layer, in addition to transparent fluororesin and silicone resin, there is a film of general-purpose resin such as urethane resin, vinyl chloride resin, acrylic resin, or polyester resin with a thickness of 5 to soogm, depending on the purpose of the enamel product. The paint has been hardened.
固化した皮膜の厚さが５ｇ＋ｎ未満では多くの場合皮膜
を設けた効果がない、また、５００Ｂｍを越えると、樹
脂膜の諸性能の影響が強くなり、ホーロー製品の特質が
失われる。ときには、樹脂膜の変色がホーローの色調を
損なうほか、曲げ加工のときに樹脂にクラックを生ずる
。If the thickness of the solidified film is less than 5 g+n, the film is often ineffective, and if it exceeds 500 Bm, the effects of the resin film on various properties become stronger, and the characteristics of the enamel product are lost. In some cases, discoloration of the resin film impairs the color tone of the enamel, and also causes cracks in the resin during bending.
適正な厚さの樹脂膜が施されているときは、ホーロー製
品を切断したり、曲げ加工しても、加工部分にホーロー
の欠陥を生ぜず、切断した端部付近も完全で鋭利である
。When a resin film of appropriate thickness is applied, even if the enamel product is cut or bent, there will be no enamel defects in the processed parts, and the area around the cut edges will be perfect and sharp.
（実施例）
実施例１
鋳鉄製ホーロー浴槽のホーロー面に焼付後３００ｇｍの
厚さとなるように透明ウレタン樹脂塗料をスプレーコー
ティングし、 １５０℃の温度で焼付けた。この浴槽の
２■上から２００ｇの鉄球を落下させてホーロー層の剥
離の有無を調べたところ、剥離はなく、また、その浴槽
の側面に直径８０ｍｍの孔をあけたが、孔の周りのホー
ロー面に大きなりラックの発生もなく、ホーロー片の飛
散もなかった。(Examples) Example 1 A transparent urethane resin paint was spray coated on the enamel surface of a cast iron enamel bathtub to a thickness of 300 gm after baking, and baked at a temperature of 150°C. When we dropped a 200g iron ball from above 2cm above this bathtub to check for peeling of the enamel layer, there was no peeling.Furthermore, a hole with a diameter of 80mm was drilled in the side of the bathtub, but the area around the hole There were no large racks on the enamel surface, and no enamel pieces were scattered.
実施例２
アルミニウムメッキ鋼板の片面に４０ｇｍのホーロー層
を焼付けた０、５ ｍｍＸ ９１４ｉ＋ｍＸ １８１
０ｍ履のホーロー板のホーロー面に焼付後２５ｕＬｍの
厚さとなるように、透明なシリコン樹脂を静電塗装によ
り塗布した後、 １４０℃で焼付けた。Example 2 0.5 mmX 914i+mX 181 with a 40gm enamel layer baked on one side of an aluminum plated steel plate
Transparent silicone resin was applied by electrostatic coating to the enamel surface of a 0 m shoe enamel plate to a thickness of 25 μLm after baking, and then baked at 140°C.
このホーロー板を曲げ曲率が２■となるようにブレーキ
プレスで折曲げた後、折曲げ部を拡大鏡で観察したとこ
ろ、ホーロー膜に極微細なりラックが多少あるものの、
表面は樹脂で被覆されていた。この部分を５０ｍｍＸ
１００ｍｍの寸法の試料として切取り、ＪＩＳ Ｚ
２３７１に準拠した塩水噴霧試験を１０００Ｆ＃Ｐｌｉ
Ｊｆｆ実施しても発錆はなかった。After bending this enamel plate with a brake press so that the bending curvature is 2cm, I observed the bent part with a magnifying glass. Although there were some very fine racks on the enamel film,
The surface was coated with resin. This part is 50mm
Cut out a sample with a size of 100 mm, JIS Z
1000F#Pli salt spray test in accordance with 2371
No rust occurred even after Jff was carried out.
また、このホーロー板より １００ｍｍＸ ＩＱＯｍ
ｍノ試片を数枚切取り、１枚毎に、２０Ｘフフ化水素酸
、３６駕塩酸、王水、２０％硝酸、１０％硫酸、２０Ｘ
ＩＪ ン酸、２８％アンモニア水、２ｏｚ力性ソーダ
の各０．２層文を滴下し、時計皿で覆い室温で２４時間
放置した後、水で洗い落して観察したが、異常はなかっ
た嗜
実施例３
ホーロー掛けした鋳鉄製ホーロ鍋をトリクレン蒸気で脱
脂した後、焼付は後の皮膜の厚さが２０壁ｍ程度となる
ように透明なフッ素樹脂をスプレー塗布して１００℃、
２０分間で焼付けたものの、２３上から２００ｇの鉄球
を落下させる耐衝撃試験ではホーロー層の剥離はなかっ
た。Also, from this enamel board 100mmX IQOm
Cut out several m samples and add 20X hydrofluoric acid, 36% hydrochloric acid, aqua regia, 20% nitric acid, 10% sulfuric acid, 20X to each sample.
0.2 layers each of IJ acid, 28% ammonia water, and 2 oz hydric soda were added, covered with a watch glass, and left at room temperature for 24 hours. After washing off with water and observing, no abnormalities were found. Example 3 After degreasing an enameled cast iron pot with Triclean steam, baking was carried out by spraying a transparent fluororesin so that the thickness of the film was approximately 20 m at 100°C.
Although it was baked for 20 minutes, there was no peeling of the enamel layer in an impact test in which a 200 g iron ball was dropped from above.
（発明の効果）
本発明の透明な樹脂で被覆したホーロー製品においては
、機械的な衝撃が加わっても、ホーロー層が剥離するこ
となく、折り曲げ加工を施してもチアピングを起すこと
なく、また、孔あけ加工を施しても加工部周辺にクラッ
クが伝播することなく、加工に際してホーロー片が飛散
することもなく、強酸に対しても耐蝕性が良好であり、
加工部とその周辺部において外観の差異が小さいという
利点もあって、本発明は業界の発展に資するところ極め
て大なるものがある。(Effects of the Invention) In the enamel product coated with the transparent resin of the present invention, the enamel layer does not peel off even when subjected to mechanical impact, and chiaping does not occur even when bent. Even after drilling, cracks do not propagate around the processed area, enamel pieces do not scatter during processing, and it has good corrosion resistance even against strong acids.
There is also the advantage that there is little difference in appearance between the processed part and the surrounding area, and the present invention greatly contributes to the development of the industry.
Claims (3)
明な樹脂で被覆したことを特徴とする透明な樹脂で被覆
したホーロー製品。(1) An enamel product coated with a transparent resin, characterized in that the surface of the enamel layer is coated with a transparent resin having a thickness of 5 to 500 μm.
の透明な樹脂で被覆したホーロー製品。(2) The enamel product coated with a transparent resin according to claim 1, which has a flat plate shape.
載の透明な樹脂で被覆したホーロー製品。(3) The enamel product coated with a transparent resin according to claim 1, which has a coiled shape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61172451A JPS6328882A (en) | 1986-07-22 | 1986-07-22 | Transparent resin coated enamelware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61172451A JPS6328882A (en) | 1986-07-22 | 1986-07-22 | Transparent resin coated enamelware |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6328882A true JPS6328882A (en) | 1988-02-06 |
Family
ID=15942229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61172451A Pending JPS6328882A (en) | 1986-07-22 | 1986-07-22 | Transparent resin coated enamelware |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6328882A (en) |
-
1986
- 1986-07-22 JP JP61172451A patent/JPS6328882A/en active Pending
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