JPS6328409B2 - - Google Patents
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- Publication number
- JPS6328409B2 JPS6328409B2 JP59021370A JP2137084A JPS6328409B2 JP S6328409 B2 JPS6328409 B2 JP S6328409B2 JP 59021370 A JP59021370 A JP 59021370A JP 2137084 A JP2137084 A JP 2137084A JP S6328409 B2 JPS6328409 B2 JP S6328409B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- health
- additive
- hot water
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 239000000654 additive Substances 0.000 claims description 21
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 14
- 230000000996 additive effect Effects 0.000 claims description 14
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 7
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 239000003205 fragrance Substances 0.000 claims description 5
- 239000000049 pigment Substances 0.000 claims description 5
- 238000004040 coloring Methods 0.000 claims description 4
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000000047 product Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 11
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 10
- 239000000243 solution Substances 0.000 description 8
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 6
- 235000011613 Pinus brutia Nutrition 0.000 description 6
- 241000018646 Pinus brutia Species 0.000 description 6
- 238000005187 foaming Methods 0.000 description 5
- 239000002244 precipitate Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 229960003511 macrogol Drugs 0.000 description 4
- 230000001954 sterilising effect Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 208000034656 Contusions Diseases 0.000 description 2
- 206010027627 Miliaria Diseases 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 2
- 229910001626 barium chloride Inorganic materials 0.000 description 2
- 238000012790 confirmation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002075 main ingredient Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 208000004296 neuralgia Diseases 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 description 2
- DHRLEVQXOMLTIM-UHFFFAOYSA-N phosphoric acid;trioxomolybdenum Chemical compound O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.O=[Mo](=O)=O.OP(O)(O)=O DHRLEVQXOMLTIM-UHFFFAOYSA-N 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- FRPHFZCDPYBUAU-UHFFFAOYSA-N Bromocresolgreen Chemical compound CC1=C(Br)C(O)=C(Br)C=C1C1(C=2C(=C(Br)C(O)=C(Br)C=2)C)C2=CC=CC=C2S(=O)(=O)O1 FRPHFZCDPYBUAU-UHFFFAOYSA-N 0.000 description 1
- 208000010445 Chilblains Diseases 0.000 description 1
- 206010008528 Chillblains Diseases 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 208000010201 Exanthema Diseases 0.000 description 1
- 208000008930 Low Back Pain Diseases 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 206010040849 Skin fissures Diseases 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 208000010040 Sprains and Strains Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 208000010668 atopic eczema Diseases 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 201000005884 exanthem Diseases 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000007407 health benefit Effects 0.000 description 1
- 208000014617 hemorrhoid Diseases 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000013094 purity test Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Devices For Medical Bathing And Washing (AREA)
- Bathtub Accessories (AREA)
- Percussion Or Vibration Massage (AREA)
Description
〔産業上の利用分野〕
本発明は、健康風呂用の添加剤に関する。さら
に詳しくは、炭酸水素ナトリウム（NaHCO3）
無水硫酸ナトリウム（Na2SO4）、色素、香料を
ポリエチレングリコールに混合させて微細な気泡
を発生させる健康風呂用の添加剤に関する。
〔従来の技術〕
これまでに家庭用、営業用を含めて、あせも、
荒れ症、うちみ、冷え症、疲労回復、肩こり、神
経痛などに対する効能を有するものとして数多く
の種類の風呂の添加剤が市販されている。これら
はいずれも相応の効果を上げていることは周知の
通りである。
本出願人は、これら添加剤とは全く無関係に、
温泉と同じか、あるいはそれ以上の効力のある健
康風呂装置を特願昭58―93594（特開昭60―12063
号公報）および実願昭58―111686（実開昭60―
20226号公報）にて出願した。これは放射線源か
ら人体の健康上効力のある放射線同位元素を安全
な水準以内で圧縮空気を利用して微細な多数の気
泡に含ませ浴槽底部から放散させ、さらに浴槽内
の湯水を循環噴射させることによつて健康上の効
果を高めようとしたものである。
〔発明が解決しようとする問題点〕
本発明者は、この健康風呂装置の人体への効力
をさらに高めるためには、健康風呂装置と風呂の
添加剤とを併用することにより、さらに期待でき
る効果が得られることに着目し、この健康風呂装
置に使用すると最も効果的である添加剤の成分と
分量を研究開発し、本発明を完成するに至つた。
本発明は、湯水が循環噴射する装置を有する健
康風呂において、温熱、マツサージ、殺菌、洗浄
の作用を発揮し、さらに発泡作用を促進させて、
病気療養あるいは健康維持の効果をより高めるこ
とができる健康風呂用の添加剤を提供することを
目的とする。
〔問題点を解決するための手段〕
本発明の特徴は、親水性の基剤であるポリエチ
レングリコールを主体として、これにナトリウム
化合物と小量の色素および香料が混合され、湯水
中に投入されたときに発泡、温熱、マツサージ、
殺菌、洗浄の作用を発揮し、病気の治療と疲労の
回復をはかり、健康を増進させることができると
ころにある。
すなわち、本発明はポリエチレングリコールを
主体とし、炭酸水素ナトリウム、無水硫酸ナトリ
ウム、微量の色素および微量の香料が添加混合さ
れ、微細な気泡の発生が促進されることを特徴と
する。
炭酸水素ナトリウムは10〜35重量％、無水硫酸
ナトリウムは５〜15重量％、色素は0.1〜２重量
％添加混合させることができ、好ましくは炭酸水
素ナトリウムは25〜30重量％、無水硫酸ナトリウ
ムは10〜13重量％、色素は0.1〜１重量％混合さ
せるのがよい。
以下本発明の添加剤について補足的に説明す
る。親水性であり、発泡性の強いポリエチレング
リコールを基剤とした本発明添加剤は、通常家庭
で使用されている浴槽に投入した場合には発泡現
象はわずかであるが、ジエツトノズルを有し、湯
水を激しく噴出する健康風呂ではその発泡現象が
顕著に現われる。
すなわち、ジエツトノズルから噴出する湯水が
湯面に突入する際に、その衝撃により周囲の大気
圧を低下させ、大気中の酸素を浴槽内の湯水に導
入する。このような状態の浴槽に本発明添加剤が
適量投入されると、添加剤のもつ性質と湯水中の
酸素の泡が作用し、浴槽全域にわたつて超微粒の
泡の層が形成される。
これら無数の泡が入浴者の皮膚に接すると瞬間
的に弾け割れ、そのとき発生する超音波が皮膚に
影響を与え、温熱、マツサージ、殺菌、洗浄の効
果を発揮するところに本発明の特徴がある。
次にその性状が橙色の粉末で無臭である本発明
添加剤の各種試験は次によつて行われる。
（確認試験）
(1) 本品の炎色反応では黄色を呈する（ナトリウ
ム塩）。
(2) 本品の少量を試験管にとりこれにあらかじめ
冷却した希塩酸２〜３mlを注いで静かに加熱す
るとき気体の発生を認める。発生した気体に水
酸化バリウム溶液でぬらしたガラス棒を挿入す
るときぬれた部分が白濁する（重炭酸塩）。
(3) 本品を水溶液にし、少量のその水溶液に塩化
バリウム溶液を滴下するとき白色の沈澱を生じ
る。生じた沈澱の一部は酢酸に溶け気体を発生
するが、大半の沈澱は不溶である（硫酸塩）。
(4) 本品0.2gをとり出し、それにクロロホルム10
mlを加え撹拌した後、ろ過した液を50℃以下で
クロロホルムを蒸発させ、残留物の0.05gに希
塩酸５mlを加えて溶かした液にリンモリブデン
酸溶液を１mlを加えるとき黄緑色の沈澱を生じ
る（マクロゴール）。
（示性値）
本品0.1gを10mlの水に溶かしたときPH6.5〜7.5
を示す。
（純度試験）
(1) 本品1.0gに新たに煮沸した冷却水20mlを加え
て溶かし、フエノールフタレエイン試験２滴を
加えるとき、液は赤色を呈しないか、赤色を呈
しても極めて薄い（炭酸塩との区別）。
(2) 本品1.0gを10mlの水に溶かし、１mlの希塩酸
を加えても白濁せず（チオ硫酸塩との区別）、
また二酸化イオウの臭を発しない（亜硫酸塩と
の区別）。
(3) 本品1.0gを取り出し加熱する。そのとき発生
するガスはぬらした赤色リトマス試験紙を青変
しない（アンモニウム塩の混入の有無）。
（定量法）
(1) 炭酸水素ナトリウム
本品6.0gを精密に量り、水50mlを加えて容か
し指示薬としてブロムクレゾールグリーン試液
２滴を加え、1N―硫酸で滴定する。液の緑黄
色が黄色に替わつたところを終点とする。
1N―硫酸１ml＝84.01mg NaHCO3
(2) 無水硫酸ナトリウム
本品3.0gを精密に量り水100mlを加えて溶か
し希塩酸２mlを加えて煮沸し、熱時1N―塩化
バリウム８mlを徐々に加える。この液を水浴上
で１時間加熱した後沈澱をろ取し、洗液に硝酸
銀試液を加えても混濁を生じなくなるまで水で
洗い乾燥後坩堝に容れて恒量になるまで強熱し
重量を量り、硫酸バリウム（BaSO4：233.40）
の量とする。
無水硫酸ナトリウム（Na2SO4）の量１mg＝
硫酸バリウム（BaSO4）の量×0.6086
(3) マクロゴール6000
本品1.0gを精密に量りクロロホルム10mlを加
えて溶解させ、ガラスろ過板のあるガラスろ過
器（G3）（グーチ坩堝）でろ過し、容器ろ過器
をクロロホルム５mlずつ用いて３回洗い、ろ液
洗液を重量既知のビーカに集め、50℃以下でク
ロロホルムを蒸発させ、シリカゲル乾燥器に１
時間放冷した後秤量し、さらに１時間乾燥器に
放置した後秤量し、その重量差が±５％以内に
なつたときを恒量としてマクロゴールの量とす
る。
W2−W1／Ｓ×100
W1：ビーカ重量
W2：マクロゴール＋ビーカ重量
Ｓ ：試料採取量（ｇ）
〔発明の効果〕
以上のべたように、本発明による添加剤を入浴
時に湯水150〜180に対し15g程度投入するこ
とによつて、温熱、マツサージ、殺菌、洗浄の各
作用が発揮され、特に湯水が循環噴射する装置を
有する健康風呂においては発泡作用が促進され、
皮膚に微細なマツサージ効果が得られ血行がよく
なる。これにより、あせも、荒れ症、冷え症、肩
こり、神経痛、腰痛、湿疹、しもやけ、あかぎ
れ、ただれ、くじき、うちみ、痔、疲労回復など
の病気療養あるいは健康維持に優れた効果があ
る。
〔実施例〕
以下に実施例を掲げて本発明をさらに詳しく説
明するが、本発明はこれにより制限を受けるもの
ではない。
本発明実施例添加剤は、総重量が１Kgになるよ
うに、ポリエチレングリコール＃6000を60重量％
を準備し、これに炭酸水素ナトリウム
（NaHCO3）28重量％を混入させ、撹拌粉砕し、
さらに無水硫酸ナトリウム（Na2SO4）を11.5重
量％加え均一にした後、厚生省令で定めた医薬品
に使用することができるタール色素別表（第２
表）の黄色202号の(1)の色素を0.5重量％、香料を
微量加えて均一に撹拌して製造した。
図示の揚水ポンプ１によつて揚水パイプ２から
浴槽３の湯水４を吸入し、ノズル５から湯水面４
ａに激しく噴射する装置を有する浴槽３の226
の湯中に、この添加剤を所定量Xgを取り分けて
投下混入した。
湯はわずかに黄緑色になり香料の芳香が感じら
れた。ここで揚水ポンプ１を駆動させると浴槽３
中の湯水面４ａには細かい多数の気泡６がみら
れ、この気泡６は湯水面４ａ上に盛り上がるよう
に現れた。
この発泡状態について、試験を行つた結果を第
１表に示す。
[Industrial Field of Application] The present invention relates to additives for health baths. For more information, see Sodium Bicarbonate (NaHCO 3 )
This invention relates to an additive for health baths that generates fine bubbles by mixing anhydrous sodium sulfate (Na 2 SO 4 ), coloring matter, and fragrance with polyethylene glycol. [Conventional technology] Until now, heat rash,
Many types of bath additives are commercially available that are effective against skin irritation, bruises, sensitivity to cold, recovery from fatigue, stiff shoulders, neuralgia, and the like. It is well known that all of these have achieved a certain degree of effectiveness. The applicant has no relation whatsoever to these additives,
Japanese Patent Application No. 58-93594 (Japanese Unexamined Patent Publication No. 60-12063) for a health bath device that is as effective as or more effective than hot springs.
Publication No. 111686) and Utility Application No. 111686 (Sho 60)
The application was filed under Publication No. 20226). This method uses compressed air to contain radioactive isotopes that are effective for human health within a safe level in a large number of fine bubbles from the radiation source, and radiates them from the bottom of the bathtub.Then, the hot water in the bathtub is circulated and sprayed. The idea was to increase the health benefits of this product. [Problems to be Solved by the Invention] In order to further enhance the effectiveness of this health bath device on the human body, the present inventor believes that further effects can be expected by using the health bath device together with bath additives. Focusing on the fact that this can be obtained, we researched and developed the ingredients and amounts of additives that would be most effective when used in this health bath device, leading to the completion of the present invention. The present invention provides a health bath equipped with a device that circulates and sprays hot water, exerts the effects of heating, pine surge, sterilization, and cleaning, and further promotes the foaming effect.
The purpose of the present invention is to provide an additive for health baths that can further enhance the effects of disease treatment or health maintenance. [Means for Solving the Problems] The present invention is characterized in that polyethylene glycol, which is a hydrophilic base material, is used as a main ingredient, and a sodium compound and a small amount of coloring matter and fragrance are mixed therein, and the mixture is added to hot water. Sometimes foaming, heat, pine surge,
It has sterilizing and cleaning properties, can treat illnesses, relieve fatigue, and improve health. That is, the present invention is characterized in that polyethylene glycol is the main ingredient, and sodium bicarbonate, anhydrous sodium sulfate, a trace amount of coloring matter, and a trace amount of fragrance are added and mixed to promote the generation of fine bubbles. Sodium hydrogen carbonate can be added in an amount of 10 to 35% by weight, anhydrous sodium sulfate can be added in an amount of 5 to 15% by weight, and pigment can be added in an amount of 0.1 to 2% by weight. Preferably, sodium hydrogen carbonate can be added in an amount of 25 to 30% by weight, and anhydrous sodium sulfate should be added in an amount of 25 to 30% by weight. It is preferable to mix 10 to 13% by weight, and 0.1 to 1% by weight of the pigment. The additives of the present invention will be supplementarily explained below. The additive of the present invention, which is based on polyethylene glycol, which is hydrophilic and has strong foaming properties, causes only a slight foaming phenomenon when added to a bathtub commonly used at home. The bubbling phenomenon is noticeable in health baths where bubbles are violently squirted. That is, when the hot water ejected from the jet nozzle rushes into the hot water surface, its impact lowers the surrounding atmospheric pressure and introduces oxygen from the atmosphere into the hot water in the bathtub. When an appropriate amount of the additive of the present invention is added to a bathtub in such a state, the properties of the additive and the oxygen bubbles in the hot water interact to form a layer of ultrafine bubbles throughout the bathtub. The unique feature of this invention is that when these countless bubbles come into contact with the bather's skin, they instantly burst and break, and the ultrasonic waves generated at that time affect the skin, producing heat, pine surge, sterilization, and cleaning effects. be. Next, various tests on the additive of the present invention, which is an odorless orange powder, are conducted as follows. (Confirmation test) (1) This product exhibits a yellow color in the flame reaction (sodium salt). (2) Take a small amount of this product in a test tube, pour 2 to 3 ml of pre-chilled dilute hydrochloric acid into it, and when gently heated, notice the evolution of gas. When a glass rod wetted with barium hydroxide solution is inserted into the generated gas, the wetted area becomes cloudy (bicarbonate). (3) When this product is made into an aqueous solution and a barium chloride solution is dropped into a small amount of the aqueous solution, a white precipitate is produced. A portion of the resulting precipitate dissolves in acetic acid and generates gas, but most of the precipitate is insoluble (sulfate). (4) Take out 0.2g of this product and add 10g of chloroform to it.
After adding 1 ml of phosphomolybdic acid solution and stirring, evaporate the chloroform from the filtered solution at below 50°C, add 5 ml of diluted hydrochloric acid to 0.05 g of the residue, and add 1 ml of phosphomolybdic acid solution to the solution, producing a yellow-green precipitate. (macrogol). (Indicative value) When 0.1g of this product is dissolved in 10ml of water, the pH is 6.5 to 7.5.
shows. (Purity test) (1) When 1.0 g of this product is dissolved in 20 ml of freshly boiled cooling water and 2 drops of phenolphthalein test are added, the liquid does not turn red, or even if it does turn red, it is very faint. (distinguished from carbonates). (2) Even if you dissolve 1.0g of this product in 10ml of water and add 1ml of diluted hydrochloric acid, it will not become cloudy (distinguished from thiosulfate).
It also does not emit the odor of sulfur dioxide (distinguished from sulfites). (3) Take out 1.0g of this product and heat it. The gas generated at that time does not turn wet red litmus paper blue (presence of ammonium salt contamination). (Assay method) (1) Sodium hydrogen carbonate Weigh accurately 6.0 g of this product, add 50 ml of water, add 2 drops of bromcresol green test solution as an indicator, and titrate with 1N sulfuric acid. The end point is when the green-yellow color of the liquid changes to yellow. 1ml of 1N sulfuric acid = 84.01mg NaHCO 3 (2) Anhydrous sodium sulfate Weigh accurately 3.0g of this product, add 100ml of water, dissolve, add 2ml of diluted hydrochloric acid, boil, and when hot, gradually add 8ml of 1N barium chloride. After heating this solution on a water bath for 1 hour, the precipitate was collected by filtration, washed with water until no turbidity appeared even when silver nitrate test solution was added to the washing solution, dried, placed in a crucible, ignited until it reached a constant weight, and weighed. Barium sulfate (BaSO 4 :233.40)
The amount shall be . Amount of anhydrous sodium sulfate (Na 2 SO 4 ) 1 mg =
Amount of barium sulfate (BaSO 4 ) x 0.6086 (3) Macrogol 6000 Weigh 1.0g of this product accurately, add 10ml of chloroform to dissolve it, and filter it with a glass filter (G3) (Gooch crucible) equipped with a glass filter plate. , wash the container filter three times with 5 ml of chloroform each time, collect the filtrate wash in a beaker with a known weight, evaporate the chloroform at below 50°C, and place it in a silica gel dryer.
After being left to cool for an hour, it was weighed, and after being left in a dryer for another hour, it was weighed, and when the difference in weight was within ±5%, the constant weight was taken as the amount of macrogol. W 2 −W 1 /S×100 W 1 : Beaker weight W 2 : Macrogol + beaker weight S : Sample amount (g) [Effects of the invention] As described above, the additive according to the present invention is added to hot water when taking a bath. By adding about 15g to 150 to 180, the effects of heating, pine surge, sterilization, and cleaning are exhibited, and the foaming effect is particularly promoted in health baths that have a device that circulates and sprays hot water.
A fine pine surge effect is obtained on the skin and blood circulation is improved. This has an excellent effect on treating illnesses such as heat rash, rash, sensitivity to cold, stiff shoulders, neuralgia, lower back pain, eczema, chilblains, chapped skin, sores, sprains, bruises, hemorrhoids, recovery from fatigue, and maintaining health. [Examples] The present invention will be explained in more detail with reference to Examples below, but the present invention is not limited thereto. The additive according to the present invention contains 60% by weight of polyethylene glycol #6000 so that the total weight is 1 kg.
was prepared, 28% by weight of sodium hydrogen carbonate (NaHCO 3 ) was mixed therein, and the mixture was stirred and ground.
Furthermore, after adding 11.5% by weight of anhydrous sodium sulfate (Na 2 SO 4 ) to make it homogeneous, the tar pigments that can be used in pharmaceuticals specified by the Ministry of Health and Welfare Ordinance (Appended Table 2)
It was produced by adding 0.5% by weight of the pigment (1) of Yellow No. 202 in Table) and a trace amount of fragrance, and stirring uniformly. The illustrated lift pump 1 sucks hot water 4 from the bathtub 3 through the lift pipe 2, and the hot water level 4 from the nozzle 5.
226 of bathtub 3 with a device that violently sprays a
A predetermined amount of Xg of this additive was mixed into the hot water. The water had a slightly yellow-green color and I could smell the aroma of spices. Here, when the water pump 1 is driven, the bathtub 3
A large number of fine air bubbles 6 were seen on the hot water surface 4a inside, and these air bubbles 6 appeared so as to rise above the hot water surface 4a. Table 1 shows the results of tests regarding this foamed state.
【表】
この結果、本添加剤を少量使用することにより
浴槽内の気泡は、きわめて多量に発生するように
なり、入浴者の皮膚に当り、この泡が砕けること
により生じるマツサージ効果が著しく増大してい
ることがわかる。
この実施例添加剤から試料Ａ、Ｂ、Ｃを取り出
し、性状、確認、示性値、純度、定量値の各試験
を行つた結果を第２表、第３表、第４表に示す。[Table] As a result, by using a small amount of this additive, an extremely large amount of air bubbles will be generated in the bathtub, and the pine surge effect caused by the bubbles collapsing when they hit the skin of the bather will be significantly increased. It can be seen that Samples A, B, and C were taken from this Example additive and tested for properties, confirmation, demonstrative value, purity, and quantitative value. The results are shown in Tables 2, 3, and 4.
【表】【table】
【表】【table】
【表】【table】
【表】【table】
図は本発明実施例添加剤の試験を行つた健康風
呂装置の一部断面構成図。
１…揚水ポンプ、２…揚水パイプ、３…浴槽、
４…湯水、４ａ…湯水面、５…ノズル、６…気
泡。
The figure is a partial cross-sectional configuration diagram of a health bath device in which additives according to examples of the present invention were tested. 1... Lifting pump, 2... Lifting pipe, 3... Bathtub,
4... Hot water, 4a... Hot water surface, 5... Nozzle, 6... Air bubbles.
Claims (1)
気泡を発生させる健康風呂用の添加剤。 ２ 上記炭酸水素ナトリウムが10〜35重量％、無
水硫酸ナトリウムが５〜15重量％、色素が0.1〜
２重量％である特許請求の範囲第１項に記載の健
康風呂用の添加剤。 ３ 上記炭酸水素ナトリウムが25〜30重量％、無
水硫酸ナトリウムが10〜13重量％である特許請求
の範囲第１項に記載の健康風呂用の添加剤。[Claims] 1. A health bath made mainly of polyethylene glycol, to which sodium bicarbonate, anhydrous sodium sulfate, a trace amount of coloring matter, and a trace amount of fragrance are added and mixed, and mixed into the gushing hot water to generate fine air bubbles. Additive. 2 The above sodium bicarbonate is 10-35% by weight, anhydrous sodium sulfate is 5-15% by weight, and the pigment is 0.1-35% by weight.
2% by weight of the additive for health baths according to claim 1. 3. The additive for a health bath according to claim 1, wherein the sodium bicarbonate is 25 to 30% by weight and the anhydrous sodium sulfate is 10 to 13% by weight.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2137084A JPS60166607A (en) | 1984-02-08 | 1984-02-08 | Bath additive |
| JP1106273A JPH01303149A (en) | 1984-02-08 | 1989-04-26 | Health bath |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2137084A JPS60166607A (en) | 1984-02-08 | 1984-02-08 | Bath additive |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1106273A Division JPH01303149A (en) | 1984-02-08 | 1989-04-26 | Health bath |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60166607A JPS60166607A (en) | 1985-08-29 |
| JPS6328409B2 true JPS6328409B2 (en) | 1988-06-08 |
Family
ID=12053205
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2137084A Granted JPS60166607A (en) | 1984-02-08 | 1984-02-08 | Bath additive |
| JP1106273A Granted JPH01303149A (en) | 1984-02-08 | 1989-04-26 | Health bath |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1106273A Granted JPH01303149A (en) | 1984-02-08 | 1989-04-26 | Health bath |
Country Status (1)
| Country | Link |
|---|---|
| JP (2) | JPS60166607A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2763242B1 (en) * | 1997-05-16 | 2000-10-13 | Jean Francois Marcilly | FORMULA FOR THE SOLUBILIZATION OF PERFUMING COMPOSITIONS IN POOL WATER |
| ES2209630B2 (en) * | 2002-07-25 | 2005-08-16 | Elecarfon S.L.U. | REGULATORY FORMULATION OF COLOR INTENSITY IN BATH WATER. |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4935525A (en) * | 1972-08-11 | 1974-04-02 | ||
| JPS5444013A (en) * | 1977-08-15 | 1979-04-07 | Kuroisutaa Kemikaruzu Kk | Production of foamable tablet |
| JPS58105910A (en) * | 1981-12-17 | 1983-06-24 | Mai Sukinkeaa Lab:Kk | Solid bath composition |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5129655U (en) * | 1974-08-23 | 1976-03-03 |
-
1984
- 1984-02-08 JP JP2137084A patent/JPS60166607A/en active Granted
-
1989
- 1989-04-26 JP JP1106273A patent/JPH01303149A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4935525A (en) * | 1972-08-11 | 1974-04-02 | ||
| JPS5444013A (en) * | 1977-08-15 | 1979-04-07 | Kuroisutaa Kemikaruzu Kk | Production of foamable tablet |
| JPS58105910A (en) * | 1981-12-17 | 1983-06-24 | Mai Sukinkeaa Lab:Kk | Solid bath composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0365987B2 (en) | 1991-10-15 |
| JPS60166607A (en) | 1985-08-29 |
| JPH01303149A (en) | 1989-12-07 |
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