JPS63275697A - Enzyme-containing bleaching agent composition - Google Patents
Enzyme-containing bleaching agent compositionInfo
- Publication number
- JPS63275697A JPS63275697A JP11037587A JP11037587A JPS63275697A JP S63275697 A JPS63275697 A JP S63275697A JP 11037587 A JP11037587 A JP 11037587A JP 11037587 A JP11037587 A JP 11037587A JP S63275697 A JPS63275697 A JP S63275697A
- Authority
- JP
- Japan
- Prior art keywords
- fragrance
- enzyme
- perfume
- mixed
- salicylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 102000004190 Enzymes Human genes 0.000 title claims abstract description 32
- 108090000790 Enzymes Proteins 0.000 title claims abstract description 32
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000007844 bleaching agent Substances 0.000 title claims description 12
- 239000003205 fragrance Substances 0.000 claims abstract description 44
- 150000002978 peroxides Chemical class 0.000 claims abstract description 18
- 238000004061 bleaching Methods 0.000 claims abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 6
- 229930003658 monoterpene Natural products 0.000 claims abstract description 6
- 235000002577 monoterpenes Nutrition 0.000 claims abstract description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims abstract description 5
- 229930004725 sesquiterpene Natural products 0.000 claims abstract description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims abstract description 3
- -1 monoterpene alcohols Chemical class 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 150000003902 salicylic acid esters Chemical class 0.000 claims description 4
- 150000003934 aromatic aldehydes Chemical class 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000002304 perfume Substances 0.000 abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004365 Protease Substances 0.000 abstract description 4
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 abstract description 4
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 abstract description 4
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 abstract description 4
- 229940045872 sodium percarbonate Drugs 0.000 abstract description 4
- 108091005804 Peptidases Proteins 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 abstract description 2
- CDOSHBSSFJOMGT-JTQLQIEISA-N (R)-linalool Natural products CC(C)=CCC[C@@](C)(O)C=C CDOSHBSSFJOMGT-JTQLQIEISA-N 0.000 abstract description 2
- 239000012190 activator Substances 0.000 abstract description 2
- HIGQPQRQIQDZMP-UHFFFAOYSA-N geranil acetate Natural products CC(C)=CCCC(C)=CCOC(C)=O HIGQPQRQIQDZMP-UHFFFAOYSA-N 0.000 abstract description 2
- HIGQPQRQIQDZMP-DHZHZOJOSA-N geranyl acetate Chemical compound CC(C)=CCC\C(C)=C\COC(C)=O HIGQPQRQIQDZMP-DHZHZOJOSA-N 0.000 abstract description 2
- 229930007744 linalool Natural products 0.000 abstract description 2
- 239000002075 main ingredient Substances 0.000 abstract description 2
- 229960001047 methyl salicylate Drugs 0.000 abstract description 2
- 150000002773 monoterpene derivatives Chemical class 0.000 abstract description 2
- 229960001860 salicylate Drugs 0.000 abstract description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 abstract description 2
- 150000004354 sesquiterpene derivatives Chemical class 0.000 abstract description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 229940088598 enzyme Drugs 0.000 description 27
- 235000019645 odor Nutrition 0.000 description 10
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 230000000873 masking effect Effects 0.000 description 5
- GLZPCOQZEFWAFX-UHFFFAOYSA-N Geraniol Chemical compound CC(C)=CCCC(C)=CCO GLZPCOQZEFWAFX-UHFFFAOYSA-N 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 4
- 108010056079 Subtilisins Proteins 0.000 description 3
- 102000005158 Subtilisins Human genes 0.000 description 3
- 229940022663 acetate Drugs 0.000 description 3
- 230000002255 enzymatic effect Effects 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- IKDIJXDZEYHZSD-UHFFFAOYSA-N 2-phenylethyl formate Chemical compound O=COCCC1=CC=CC=C1 IKDIJXDZEYHZSD-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- UYWQUFXKFGHYNT-UHFFFAOYSA-N Benzylformate Chemical compound O=COCC1=CC=CC=C1 UYWQUFXKFGHYNT-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- FPCCDPXRNNVUOM-UHFFFAOYSA-N Hydroxycitronellol Chemical compound OCCC(C)CCCC(C)(C)O FPCCDPXRNNVUOM-UHFFFAOYSA-N 0.000 description 2
- BTJXBZZBBNNTOV-UHFFFAOYSA-N Linalyl benzoate Chemical compound CC(C)=CCCC(C)(C=C)OC(=O)C1=CC=CC=C1 BTJXBZZBBNNTOV-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- KGEKLUUHTZCSIP-HOSYDEDBSA-N [(1s,4s,6r)-1,7,7-trimethyl-6-bicyclo[2.2.1]heptanyl] acetate Chemical compound C1C[C@]2(C)[C@H](OC(=O)C)C[C@H]1C2(C)C KGEKLUUHTZCSIP-HOSYDEDBSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- HQKQRXZEXPXXIG-VJOHVRBBSA-N chembl2333940 Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@H]1[C@@](OC(C)=O)(C)CC2 HQKQRXZEXPXXIG-VJOHVRBBSA-N 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- QMVPMAAFGQKVCJ-UHFFFAOYSA-N citronellol Chemical compound OCCC(C)CCC=C(C)C QMVPMAAFGQKVCJ-UHFFFAOYSA-N 0.000 description 2
- JOZKFWLRHCDGJA-UHFFFAOYSA-N citronellol acetate Chemical compound CC(=O)OCCC(C)CCC=C(C)C JOZKFWLRHCDGJA-UHFFFAOYSA-N 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- OSORMYZMWHVFOZ-UHFFFAOYSA-N phenethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCC1=CC=CC=C1 OSORMYZMWHVFOZ-UHFFFAOYSA-N 0.000 description 2
- DTUQWGWMVIHBKE-UHFFFAOYSA-N phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000007586 terpenes Nutrition 0.000 description 2
- FQTLCLSUCSAZDY-UHFFFAOYSA-N (+) E(S) nerolidol Natural products CC(C)=CCCC(C)=CCCC(C)(O)C=C FQTLCLSUCSAZDY-UHFFFAOYSA-N 0.000 description 1
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical compound C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 1
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- REPVLJRCJUVQFA-UHFFFAOYSA-N (-)-isopinocampheol Natural products C1C(O)C(C)C2C(C)(C)C1C2 REPVLJRCJUVQFA-UHFFFAOYSA-N 0.000 description 1
- CRDAMVZIKSXKFV-FBXUGWQNSA-N (2-cis,6-cis)-farnesol Chemical compound CC(C)=CCC\C(C)=C/CC\C(C)=C/CO CRDAMVZIKSXKFV-FBXUGWQNSA-N 0.000 description 1
- 239000000260 (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol Substances 0.000 description 1
- 239000001306 (7E,9E,11E,13E)-pentadeca-7,9,11,13-tetraen-1-ol Substances 0.000 description 1
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 1
- QMVPMAAFGQKVCJ-SNVBAGLBSA-N (R)-(+)-citronellol Natural products OCC[C@H](C)CCC=C(C)C QMVPMAAFGQKVCJ-SNVBAGLBSA-N 0.000 description 1
- WUOACPNHFRMFPN-SECBINFHSA-N (S)-(-)-alpha-terpineol Chemical compound CC1=CC[C@@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-SECBINFHSA-N 0.000 description 1
- QQLIGMASAVJVON-UHFFFAOYSA-N 1-naphthalen-1-ylethanone Chemical compound C1=CC=C2C(C(=O)C)=CC=CC2=C1 QQLIGMASAVJVON-UHFFFAOYSA-N 0.000 description 1
- VVUMWAHNKOLVSN-UHFFFAOYSA-N 2-(4-ethoxyanilino)-n-propylpropanamide Chemical compound CCCNC(=O)C(C)NC1=CC=C(OCC)C=C1 VVUMWAHNKOLVSN-UHFFFAOYSA-N 0.000 description 1
- RJASFPFZACBKBE-UHFFFAOYSA-N 2-Methylpropyl phenylacetate Chemical compound CC(C)COC(=O)CC1=CC=CC=C1 RJASFPFZACBKBE-UHFFFAOYSA-N 0.000 description 1
- PCABPXZHKAGHFR-UHFFFAOYSA-N 2-ethylbutyl 2-hydroxybenzoate Chemical compound CCC(CC)COC(=O)C1=CC=CC=C1O PCABPXZHKAGHFR-UHFFFAOYSA-N 0.000 description 1
- RIWRBSMFKVOJMN-UHFFFAOYSA-N 2-methyl-1-phenylpropan-2-ol Chemical compound CC(C)(O)CC1=CC=CC=C1 RIWRBSMFKVOJMN-UHFFFAOYSA-N 0.000 description 1
- YWXALCBWOUVZOE-UHFFFAOYSA-N 2-methylpentyl 2-hydroxybenzoate Chemical compound CCCC(C)COC(=O)C1=CC=CC=C1O YWXALCBWOUVZOE-UHFFFAOYSA-N 0.000 description 1
- BDCFWIDZNLCTMF-UHFFFAOYSA-N 2-phenylpropan-2-ol Chemical compound CC(C)(O)C1=CC=CC=C1 BDCFWIDZNLCTMF-UHFFFAOYSA-N 0.000 description 1
- 239000001629 3,7-dimethylocta-2,6-dienyl benzoate Substances 0.000 description 1
- HMNKTRSOROOSPP-UHFFFAOYSA-N 3-Ethylphenol Chemical compound CCC1=CC=CC(O)=C1 HMNKTRSOROOSPP-UHFFFAOYSA-N 0.000 description 1
- INIOTLARNNSXAE-UHFFFAOYSA-N 4,8-dimethyl-2-propan-2-ylidene-3,3a,4,5,6,8a-hexahydro-1h-azulen-6-ol Chemical compound CC1CC(O)C=C(C)C2CC(=C(C)C)CC12 INIOTLARNNSXAE-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- MBZRJSQZCBXRGK-UHFFFAOYSA-N 4-tert-Butylcyclohexyl acetate Chemical compound CC(=O)OC1CCC(C(C)(C)C)CC1 MBZRJSQZCBXRGK-UHFFFAOYSA-N 0.000 description 1
- 102000004400 Aminopeptidases Human genes 0.000 description 1
- 108090000915 Aminopeptidases Proteins 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102100035024 Carboxypeptidase B Human genes 0.000 description 1
- 108010080937 Carboxypeptidases A Proteins 0.000 description 1
- 102000000496 Carboxypeptidases A Human genes 0.000 description 1
- 108090000317 Chymotrypsin Proteins 0.000 description 1
- JOZKFWLRHCDGJA-LLVKDONJSA-N Citronellyl acetate Natural products CC(=O)OCC[C@H](C)CCC=C(C)C JOZKFWLRHCDGJA-LLVKDONJSA-N 0.000 description 1
- 108060005980 Collagenase Proteins 0.000 description 1
- 102000029816 Collagenase Human genes 0.000 description 1
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 1
- 241000402754 Erythranthe moschata Species 0.000 description 1
- 108090000371 Esterases Proteins 0.000 description 1
- GYCKQBWUSACYIF-UHFFFAOYSA-N Ethyl salicylate Chemical compound CCOC(=O)C1=CC=CC=C1O GYCKQBWUSACYIF-UHFFFAOYSA-N 0.000 description 1
- 239000005792 Geraniol Substances 0.000 description 1
- GLZPCOQZEFWAFX-YFHOEESVSA-N Geraniol Natural products CC(C)=CCC\C(C)=C/CO GLZPCOQZEFWAFX-YFHOEESVSA-N 0.000 description 1
- DUKPKQFHJQGTGU-UHFFFAOYSA-N Hexyl salicylic acid Chemical compound CCCCCCOC(=O)C1=CC=CC=C1O DUKPKQFHJQGTGU-UHFFFAOYSA-N 0.000 description 1
- 101000946524 Homo sapiens Carboxypeptidase B Proteins 0.000 description 1
- 102000004157 Hydrolases Human genes 0.000 description 1
- 108090000604 Hydrolases Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PMGCQNGBLMMXEW-UHFFFAOYSA-N Isoamyl salicylate Chemical compound CC(C)CCOC(=O)C1=CC=CC=C1O PMGCQNGBLMMXEW-UHFFFAOYSA-N 0.000 description 1
- 102000004317 Lyases Human genes 0.000 description 1
- 108090000856 Lyases Proteins 0.000 description 1
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- YDVXYTIIPGKIJP-UHFFFAOYSA-N O-Benzoyl-geraniol Natural products CC(C)=CCCC(C)=CCOC(=O)C1=CC=CC=C1 YDVXYTIIPGKIJP-UHFFFAOYSA-N 0.000 description 1
- 102000004316 Oxidoreductases Human genes 0.000 description 1
- 108090000854 Oxidoreductases Proteins 0.000 description 1
- 108090000526 Papain Proteins 0.000 description 1
- 102000057297 Pepsin A Human genes 0.000 description 1
- 108090000284 Pepsin A Proteins 0.000 description 1
- YNMSDIQQNIRGDP-UHFFFAOYSA-N Phenethyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCCC1=CC=CC=C1 YNMSDIQQNIRGDP-UHFFFAOYSA-N 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 108010022999 Serine Proteases Proteins 0.000 description 1
- 102000012479 Serine Proteases Human genes 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 108090000787 Subtilisin Proteins 0.000 description 1
- 102000004357 Transferases Human genes 0.000 description 1
- 108090000992 Transferases Proteins 0.000 description 1
- 108090000631 Trypsin Proteins 0.000 description 1
- 102000004142 Trypsin Human genes 0.000 description 1
- AXMVYSVVTMKQSL-UHFFFAOYSA-N UNPD142122 Natural products OC1=CC=C(C=CC=O)C=C1O AXMVYSVVTMKQSL-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- OOCCDEMITAIZTP-UHFFFAOYSA-N allylic benzylic alcohol Natural products OCC=CC1=CC=CC=C1 OOCCDEMITAIZTP-UHFFFAOYSA-N 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- OVKDFILSBMEKLT-UHFFFAOYSA-N alpha-Terpineol Natural products CC(=C)C1(O)CCC(C)=CC1 OVKDFILSBMEKLT-UHFFFAOYSA-N 0.000 description 1
- GUUHFMWKWLOQMM-NTCAYCPXSA-N alpha-hexylcinnamaldehyde Chemical compound CCCCCC\C(C=O)=C/C1=CC=CC=C1 GUUHFMWKWLOQMM-NTCAYCPXSA-N 0.000 description 1
- GUUHFMWKWLOQMM-UHFFFAOYSA-N alpha-n-hexylcinnamic aldehyde Natural products CCCCCCC(C=O)=CC1=CC=CC=C1 GUUHFMWKWLOQMM-UHFFFAOYSA-N 0.000 description 1
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 1
- 229940088601 alpha-terpineol Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229940095076 benzaldehyde Drugs 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- JGQFVRIQXUFPAH-UHFFFAOYSA-N beta-citronellol Natural products OCCC(C)CCCC(C)=C JGQFVRIQXUFPAH-UHFFFAOYSA-N 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- CKDOCTFBFTVPSN-UHFFFAOYSA-N borneol Natural products C1CC2(C)C(C)CC1C2(C)C CKDOCTFBFTVPSN-UHFFFAOYSA-N 0.000 description 1
- 229940116229 borneol Drugs 0.000 description 1
- 229940115397 bornyl acetate Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- SVURIXNDRWRAFU-OGMFBOKVSA-N cedrol Chemical compound C1[C@]23[C@H](C)CC[C@H]3C(C)(C)[C@@H]1[C@@](O)(C)CC2 SVURIXNDRWRAFU-OGMFBOKVSA-N 0.000 description 1
- 229940026455 cedrol Drugs 0.000 description 1
- PCROEXHGMUJCDB-UHFFFAOYSA-N cedrol Natural products CC1CCC2C(C)(C)C3CC(C)(O)CC12C3 PCROEXHGMUJCDB-UHFFFAOYSA-N 0.000 description 1
- 229960002376 chymotrypsin Drugs 0.000 description 1
- 229940117916 cinnamic aldehyde Drugs 0.000 description 1
- KJPRLNWUNMBNBZ-UHFFFAOYSA-N cinnamic aldehyde Natural products O=CC=CC1=CC=CC=C1 KJPRLNWUNMBNBZ-UHFFFAOYSA-N 0.000 description 1
- 235000000484 citronellol Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229960002424 collagenase Drugs 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 229940019836 cyclamen aldehyde Drugs 0.000 description 1
- LDZPTHZJZNILDL-UHFFFAOYSA-N cycloheptyl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1CCCCCC1 LDZPTHZJZNILDL-UHFFFAOYSA-N 0.000 description 1
- NUQDJSMHGCTKNL-UHFFFAOYSA-N cyclohexyl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1CCCCC1 NUQDJSMHGCTKNL-UHFFFAOYSA-N 0.000 description 1
- OPEVZOJQZWISHQ-UHFFFAOYSA-N cyclooctyl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1CCCCCCC1 OPEVZOJQZWISHQ-UHFFFAOYSA-N 0.000 description 1
- WTXUSAZCTQAQMR-UHFFFAOYSA-N cyclopentyl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1CCCC1 WTXUSAZCTQAQMR-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- DTGKSKDOIYIVQL-UHFFFAOYSA-N dl-isoborneol Natural products C1CC2(C)C(O)CC1C2(C)C DTGKSKDOIYIVQL-UHFFFAOYSA-N 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 150000002168 ethanoic acid esters Chemical class 0.000 description 1
- 229940005667 ethyl salicylate Drugs 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229930002886 farnesol Natural products 0.000 description 1
- 229940043259 farnesol Drugs 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 229940113087 geraniol Drugs 0.000 description 1
- FQMZVFJYMPNUCT-UHFFFAOYSA-N geraniol formate Natural products CC(C)=CCCC(C)=CCOC=O FQMZVFJYMPNUCT-UHFFFAOYSA-N 0.000 description 1
- YDVXYTIIPGKIJP-QINSGFPZSA-N geranyl benzoate Chemical compound CC(C)=CCC\C(C)=C/COC(=O)C1=CC=CC=C1 YDVXYTIIPGKIJP-QINSGFPZSA-N 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229930002839 ionone Natural products 0.000 description 1
- 150000002499 ionone derivatives Chemical class 0.000 description 1
- SVURIXNDRWRAFU-UHFFFAOYSA-N juniperanol Natural products C1C23C(C)CCC3C(C)(C)C1C(O)(C)CC2 SVURIXNDRWRAFU-UHFFFAOYSA-N 0.000 description 1
- 108010059345 keratinase Proteins 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- SDQFDHOLCGWZPU-UHFFFAOYSA-N lilial Chemical compound O=CC(C)CC1=CC=C(C(C)(C)C)C=C1 SDQFDHOLCGWZPU-UHFFFAOYSA-N 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- UWKAYLJWKGQEPM-UHFFFAOYSA-N linalool acetate Natural products CC(C)=CCCC(C)(C=C)OC(C)=O UWKAYLJWKGQEPM-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- WASNIKZYIWZQIP-AWEZNQCLSA-N nerolidol Natural products CC(=CCCC(=CCC[C@@H](O)C=C)C)C WASNIKZYIWZQIP-AWEZNQCLSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229940055729 papain Drugs 0.000 description 1
- 235000019834 papain Nutrition 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- 229940111202 pepsin Drugs 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 229940100595 phenylacetaldehyde Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- CRDAMVZIKSXKFV-UHFFFAOYSA-N trans-Farnesol Natural products CC(C)=CCCC(C)=CCCC(C)=CCO CRDAMVZIKSXKFV-UHFFFAOYSA-N 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- 229960001322 trypsin Drugs 0.000 description 1
- ZFNVDHOSLNRHNN-UHFFFAOYSA-N xi-3-(4-Isopropylphenyl)-2-methylpropanal Chemical compound O=CC(C)CC1=CC=C(C(C)C)C=C1 ZFNVDHOSLNRHNN-UHFFFAOYSA-N 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Fats And Perfumes (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は香気を有し使用感に優れた酵素含有漂白剤組成
物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to an enzyme-containing bleach composition that has an aroma and is comfortable to use.
無機過酸化物である過炭酸ナトリウム、過ホウ酸ナトリ
ウム等のような水に溶解して過酸化水素を遊離する漂白
基剤は、次亜塩素酸のような塩素系漂白剤に比べ色・柄
物に対する影響が少ないなどの特徴のある漂白作用によ
り幅広く利用されるに至っている。Bleaching bases that release hydrogen peroxide by dissolving in water, such as inorganic peroxides such as sodium percarbonate and sodium perborate, have a lower color and pattern effect than chlorine bleaches such as hypochlorous acid. It has come to be widely used due to its unique bleaching action, which has little effect on the environment.
しかし、これら無機過酸化物を主成分とする酵素系漂白
剤で衣料を漂白すると活性酸素によるある種の生ぐさい
臭いが生じ、処理した衣料を扱う時、著しい不快感を与
えてしまい好ましくない。However, when clothing is bleached using enzymatic bleaches containing inorganic peroxides as the main ingredients, a kind of fishy odor is generated due to active oxygen, which is undesirable as it causes extreme discomfort when handling the treated clothing. .
一方、これら無機過酸化物は次亜塩素酸のような塩素系
漂白剤に比べ漂白刃が充分でないため、漂白刃の向上が
試みられ、特に、油脂、蛋白質、炭水化物等と混合され
た色素汚れに対しては、各種酵素を無機過酸化物と併用
し蛋白汚れ等を除去し漂白する方法がとられている。On the other hand, these inorganic peroxides do not have sufficient bleaching properties compared to chlorine-based bleaches such as hypochlorous acid, so attempts have been made to improve the bleaching properties of these inorganic peroxides. For this purpose, various enzymes are used in combination with inorganic peroxides to remove protein stains and bleach.
しかしながら、酵素には酵素臭という独特の異臭があり
、特に酵素を過酸化物の存在下で保存するときに異臭が
著しくなるという問題が生じた。そこで、香料を添加し
て酵素臭をマスキングすると共に使用窓を高めることが
必要となるが、酵素臭のマスキングは困難であり、しか
も、香料が保存中に酵素と作用して香りが変質したり、
過酸化物により分解してしまう問題があった。However, enzymes have a unique odor called enzyme odor, and a problem has arisen in that the odor becomes particularly pronounced when enzymes are stored in the presence of peroxide. Therefore, it is necessary to add fragrances to mask the enzyme odor and increase the usability window, but masking the enzyme odor is difficult, and moreover, the fragrance may interact with enzymes during storage and the fragrance may deteriorate. ,
There was a problem that it decomposed due to peroxide.
このような酵素臭のマスキングについては一部特公昭６
１−１１９９６号公報に開示されているが、無機過酸化
物配合系では一部の香料は分解され、香調のバランスが
崩れ、マスキング性が悪くなる。Regarding masking of such enzyme odor, some
As disclosed in Japanese Patent Publication No. 1-11996, in a system containing an inorganic peroxide, part of the fragrance is decomposed, the balance of the fragrance is lost, and the masking properties are deteriorated.
そこで上記の問題点を解決すべく鋭意研究を行った結果
、驚（べきことに特公昭６１−１１９９６号公報で安定
性の悪いとされているフェノール系の香料であるサリチ
ル酸エステルを多量配合することにより、香調の安定性
が良く、漂白処理時に発生する過酸化物特有の不快臭が
なく、しかもフェノール系香料に見られる黄変も生じな
い酵素含有漂白剤が得られることを見出し、本発明を完
成した。Therefore, as a result of intensive research in order to solve the above problems, we surprisingly decided to incorporate a large amount of salicylic acid ester, a phenolic fragrance that is said to have poor stability according to Japanese Patent Publication No. 61-11996. It was discovered that an enzyme-containing bleaching agent with good fragrance stability, no unpleasant odor peculiar to peroxide generated during bleaching treatment, and no yellowing seen in phenolic fragrances can be obtained, and the present invention has been made. completed.
すなわち、本発明は、無機過酸化物、酵素および香料を
含有する漂白剤組成物において、香料として
（Ａ）モノテルペンアルコール、セスキテルペンアルコ
ールおよび炭素数７〜１０の芳香族アルコールの群から
選ばれる少なくとも１種の香料と
（Ｂ）炭素数８〜１７のギ酸エステルまたは酢酸エステ
ル、炭素数１０〜１５の炭化水素および炭素数７〜１５
の芳香族アルデヒドの群から選ばれる少なくとも１種の
香料
とを主成分として含有し、かつサリチル酸エステル系香
料を香料中の４〜１２重量％含有する混合香料を用いる
ことを特徴とする酵素含有漂白剤組成物を提供するもの
である。That is, the present invention provides a bleach composition containing an inorganic peroxide, an enzyme, and a fragrance, in which (A) the fragrance is selected from the group of monoterpene alcohols, sesquiterpene alcohols, and aromatic alcohols having 7 to 10 carbon atoms. At least one fragrance and (B) a formate or acetate having 8 to 17 carbon atoms, a hydrocarbon having 10 to 15 carbon atoms, and 7 to 15 carbon atoms.
Enzyme-containing bleaching characterized by using a mixed fragrance containing as a main component at least one fragrance selected from the group of aromatic aldehydes, and containing 4 to 12% by weight of a salicylic acid ester fragrance based on the fragrance. The present invention provides a drug composition.
以下、本発明についてさらに詳細に説明する。The present invention will be explained in more detail below.
本発明に於いて、無機過酸化物としては過炭酸塩、過ホ
ウ酸塩、芒硝／食塩／Ｈ２０□付加体、尿素１０ｚｏｚ
／石こう付加体及び２ＫＨＳＯｓ ・ＫｚＳＯａ、にＨ
ＳＯ４等が挙げられる。中でも好ましいものは過炭酸ソ
ーダである。無機過酸化物の配合量は５０〜９９重量％
が好ましく、更に好ましくは６５〜９０重量％である。In the present invention, inorganic peroxides include percarbonate, perborate, mirabilite/salt/H20□ adduct, and urea 10z
/gypsum adducts and 2KHSOs ・KzSOa, to H
Examples include SO4. Among them, preferred is sodium percarbonate. The amount of inorganic peroxide added is 50 to 99% by weight.
is preferable, and more preferably 65 to 90% by weight.
本発明の漂白剤組成物に配合される酵素としては、水の
付加、除去を促進する加水分解酵素、酸化還元を促進す
る酸化還元酵素、基を１つの分子から他の分子へ転移し
汚れを変質させて除去を促進する転移酵素、分子間の結
合を切断し汚れを分解して除去を促進するりガーゼ、リ
アーゼ、汚れを化学的に変質して除去を促進する酵素が
適当であり、これらの中でも加水分解酵素が好ましく、
加水分解酵素の中でもプロテアーゼが特に好ましい。プ
ロテアーゼの具体例としては、セリンプロテアーゼ、ペ
プシン、トリプシン、キモトリプシン、コラ−ゲナーゼ
、ケラチナーゼ、エステラーゼ、スブチリシン、パパイ
ン、カルポキシペプチターゼＡおよびＢ１アミノペプチ
ターゼが挙げられ、これらの酵素は、たとえば以下の市
販品として入手することもできる。Enzymes to be incorporated into the bleach composition of the present invention include hydrolytic enzymes that promote the addition and removal of water, oxidoreductases that promote redox, and enzymes that transfer groups from one molecule to another to remove stains. Appropriate examples include transferases that denature and promote removal; gauze and lyase that cleave intermolecular bonds and decompose dirt to promote removal; and enzymes that chemically denature dirt and promote removal. Among them, hydrolytic enzymes are preferred;
Among hydrolases, proteases are particularly preferred. Specific examples of proteases include serine protease, pepsin, trypsin, chymotrypsin, collagenase, keratinase, esterase, subtilisin, papain, carboxypeptidase A and B1 aminopeptidase, and these enzymes include, for example, the following: It can also be obtained as a commercial product.
アルカラーゼ二ノボ・インダストリー社エスベラーゼ：
ノポ・インダストリー社ピロプラーゼ：長瀬産業■
マクサターゼ：ギスト・プロゲデス社
ＡＬＤ−２：明治製菓側
スペラーゼ：ファイザー社
ＡＰＩ−２１：昭和電工針
これら酵素は単独であるいは併用して漂白剤組成物に配
合され、その配合量は０．０１〜５重量％が適当であり
、好ましくは０．１〜３重量％である。Alcalase Ninovo Industry Esverase:
Nopo Industries Co., Ltd. Piroplase: Nagase Sangyo ■ Maxatase: Gist Progedes Co., Ltd. ALD-2: Meiji Seika Co., Ltd. Sperase: Pfizer Inc. API-21: Showa Denko Needle These enzymes are blended into the bleach composition alone or in combination, The appropriate amount is 0.01 to 5% by weight, preferably 0.1 to 3% by weight.
本発明のＡ群の香料の具体例としては以下のものが例示
され、この中でもモノテルペンアルコールがマスキング
性および安定性の点で好ましい。Specific examples of the fragrance of Group A of the present invention include the following, and among these, monoterpene alcohols are preferred in terms of masking properties and stability.
（１） モノテルペンアルコール
リナロール、ゲラニオール、ネロール、シトロネロール
、ジメチルオクタツール、ヒドロキシシトロネロール、
テトラヒドロリナロールナトの鎖状テルペンアルコール
、および、α−テルピネオール、ｌ−メントール、ボル
ネオールなどの鎖状テルペンアルコール。(1) Monoterpene alcohol linalool, geraniol, nerol, citronellol, dimethyl octatool, hydroxycitronellol,
Chain terpene alcohols such as tetrahydrolinaloolnato, and chain terpene alcohols such as α-terpineol, l-menthol, and borneol.
（２）セスキテルペンアルコール
ファルネソール、ネロリドール、サンタロール、セドロ
ール、ベチベロール。(2) Sesquiterpene alcohols farnesol, nerolidol, santalol, cedrol, vetiverol.
（３） Ｃ？〜１゜の芳香族アルコールベンジルアル
コール、β−フェニルエチルアルコール、シンナミック
アルコール、ジメチルベンジルカルビノール、ジメチル
フェニルカルビノール。(3) C? ~1° aromatic alcohols benzyl alcohol, β-phenylethyl alcohol, cinnamic alcohol, dimethylbenzyl carbinol, dimethylphenyl carbinol.
また、Ｂ群の香料の具体例としては以下のものが例示さ
れ、この中でも炭素数８〜１７のギ酸エステルまたは酢
酸エステルがマスキング性および安定性の点で好ましい
。Moreover, the following are illustrated as a specific example of the fragrance|flavor of the B group, Among these, formic acid ester or acetic acid ester with 8-17 carbon atoms is preferable in terms of masking property and stability.
（ｉ） Ｃｓ−１７のギ酸または酢酸エステルギ酸ゲ
ラニル、ギ酸ベンジル、ギ酸フェニルエチル、酢酸シト
ロネリル、酢酸ゲラニル、酢酸リナリル、酢酸ボルニル
、酢酸チルビニル、酢酸ベンジル、酢酸セドリル、酢酸
−ｐ−ｔブチルシクロヘキシル。(i) Cs-17 formic acid or acetate geranyl formate, benzyl formate, phenylethyl formate, citronellyl acetate, geranyl acetate, linalyl acetate, bornyl acetate, tyvinyl acetate, benzyl acetate, cedryl acetate, p-t-butylcyclohexyl acetate.
＋２１ ＣＩ。〜１．の炭化水素
α−ピネン、β−ピネン、リモネン、テルビノーレンな
どのモノテルペン炭化水素、β−カリオレフィンなどの
セスキテルペン炭化水素。+21 CI. ~1. hydrocarbons such as α-pinene, β-pinene, limonene, monoterpene hydrocarbons such as terbinolefin, and sesquiterpene hydrocarbons such as β-caryoolefin.
（３） ｃｔ〜７．の芳香族アルデヒドベンズアルデ
ヒド、フェニルアセトアルデヒド、シンナミックアルデ
ヒド、α−ヘキシルシンナミックアルデヒド、シクラメ
ンアルデヒド、リリーアルデヒド。(3) ct~7. Aromatic aldehydes of benzaldehyde, phenylacetaldehyde, cinnamic aldehyde, α-hexyl cinnamic aldehyde, cyclamen aldehyde, lily aldehyde.
これらＡ群の香料とＢ群の香料は併用して組成物に配合
され、重量比でＡ群／Ｂ群＝９７１〜１／９の割合で配
合するのが適当であり、好ましくは７７３〜３／７であ
る。These group A fragrances and group B fragrances are blended together in a composition, and it is appropriate to mix them in a weight ratio of group A/group B = 971 to 1/9, preferably 773 to 3. /7.
本発明では配合される全香料中に、フェノール系香料物
質にカルボキシル基を導入したサリチル酸エステル系香
料が４〜１２重景％重量配合される。配合量が４重量％
未満であると衣料が心地良い残り香を有さす、不快感を
与え好ましくない。サリチル酸エステル系香料の具体例
としては、サリチル酸メチル、サリチル酸エチル、サリ
チル酸イソブチル、サリチル酸イソアミル、サリチル酸
ｎ−ヘキシル、サリチル酸ベンジル、サリチル酸フェニ
ルエチル、サリチル酸２−メチルペンチル、サリチル酸
２−エチルブチル、サリチル酸シクロペンチル、サリチ
ル酸シクロヘキシル、サリチル酸シクロヘプチル、サリ
チル酸シクロオクチルなどが挙げられる。In the present invention, 4 to 12 percent by weight of a salicylic acid ester fragrance, which is a phenolic fragrance substance into which a carboxyl group has been introduced, is blended into the total fragrance. Contains 4% by weight
If it is less than that, the clothing will have a pleasant residual fragrance, which is undesirable as it will give an unpleasant feeling. Specific examples of salicylate fragrances include methyl salicylate, ethyl salicylate, isobutyl salicylate, isoamyl salicylate, n-hexyl salicylate, benzyl salicylate, phenylethyl salicylate, 2-methylpentyl salicylate, 2-ethylbutyl salicylate, cyclopentyl salicylate, and cyclohexyl salicylate. , cycloheptyl salicylate, cyclooctyl salicylate, and the like.
さらに、上記以外の香料成分も必要により配合すること
が可能であり、これらとしてはｎ −オクチルアルコー
ル、ｎ−ラウリルアルコールなどの脂肪族アルコール、
ベンゾフェノン、ヨノン、メチルナフチルケトンなどの
ケトン、ムスク系香料、安息香族メチル、安息香酸エチ
ル、安息香酸ゲラニル、安息香酸リナリル、安息香酸フ
ェニルエチル、フェニル酢酸イソブチルなどが挙げられ
る。Furthermore, fragrance ingredients other than those mentioned above can be added if necessary, such as aliphatic alcohols such as n-octyl alcohol and n-lauryl alcohol,
Examples include ketones such as benzophenone, ionone, and methylnaphthyl ketone, musk fragrances, methyl benzoate, ethyl benzoate, geranyl benzoate, linalyl benzoate, phenylethyl benzoate, and isobutyl phenylacetate.
香料は合計で０．０１〜１重量％組成物中に配合するの
が適当であり、好ましくは０．０５〜０．５重量％であ
る。It is appropriate that the total amount of fragrance is 0.01 to 1% by weight in the composition, preferably 0.05 to 0.5% by weight.
本発明の混合香料は、Ａ群およびＢ群のそれぞれ１種を
併用することによっても所期の効果を得ることができる
が、数種あるいは数十種の香料を調合して目的とする芳
香を発現せしめるのが一般的である。The mixed fragrance of the present invention can achieve the desired effect by using one type of each of Group A and Group B, but the desired aroma can be obtained by blending several or even dozens of types of fragrance. It is common to let it appear.
すでに説明したように酵素系漂白剤の汚れ除去能の増進
に酵素は有用であるが、一方において、酵素系漂白剤に
酵素を配合すると保存下に酵素が失活して所期の効果が
得られないという問題がある。そこで、保存安定剤を添
加し酵素の失活を防止して保存安定性を改善しうろこと
が好ましい、このような保存安定剤として特に好ましい
ものは特開昭５７−７３１００号公報に開示されている
無水クエン酸ナトリウム、無水硫酸マグネシウム、無水
塩化カルシウム等であり、これらを少なくとも一種配合
することにより酵素の失活を有効に防止することができ
る。これら酵素の安定剤の配合量は０．１〜２０重景％
重量当であり、好ましくは、０．５〜５重景重量ある。As explained above, enzymes are useful in enhancing the stain removal ability of enzymatic bleaches, but on the other hand, when enzymes are added to enzymatic bleaches, the enzymes become deactivated during storage and the desired effect is not achieved. The problem is that it cannot be done. Therefore, it is preferable to add a storage stabilizer to prevent enzyme deactivation and improve storage stability.A particularly preferred storage stabilizer is disclosed in JP-A-57-73100. These include anhydrous sodium citrate, anhydrous magnesium sulfate, anhydrous calcium chloride, etc., and by incorporating at least one of these, deactivation of the enzyme can be effectively prevented. The amount of stabilizers for these enzymes is 0.1 to 20%
It is preferably 0.5 to 5 times the weight.
本発明の漂白剤組成物には上記成分の他に任意に必要に
応じて公知の漂白剤成分が配合される。即ち、トリポリ
リン酸ナトリウム、炭酸ナトリウム、ビロリン酸ナトリ
ウム、硫酸ナトリウム、ホウ酸ナトリウム、炭酸水素ナ
トリウム、ケイ酸ナトリウム、ニトリロトリ酢酸ナトリ
ウム、エチレンジアミンテトラ酢酸ナトリウム等の無機
・有機ビルグー成分、カルボキシメチルセルローズ、ポ
リビニルアルコール、ポリエチレングリコール等の高分
子物質、香料、顔料、螢光染料、活性化剤等が例示され
る。また、これらを洗浄剤組成物と併用することもでき
る。In addition to the above-mentioned components, the bleach composition of the present invention may optionally contain known bleach components as required. Namely, inorganic and organic building blocks such as sodium tripolyphosphate, sodium carbonate, sodium birophosphate, sodium sulfate, sodium borate, sodium bicarbonate, sodium silicate, sodium nitrilotriacetate, sodium ethylenediaminetetraacetate, carboxymethyl cellulose, and polyvinyl alcohol. , polymeric substances such as polyethylene glycol, fragrances, pigments, fluorescent dyes, activators, and the like. Moreover, these can also be used together with a cleaning composition.
本発明の漂白剤組成物は、特定の香料系を用いることに
より、酵素無機過酸化物系において、長期保存等によっ
ておこる香りの変化を防止することができ、また、衣料
の漂白処理時に発生する無機過酸化物特有の生ぐさい臭
いをおさえ、衣料に心地良い残り香を有し快適な使用域
を与えることができる。By using a specific fragrance system, the bleach composition of the present invention can prevent changes in fragrance that occur during long-term storage in enzyme-inorganic peroxide systems. It can suppress the fishy odor characteristic of inorganic peroxides, leave a pleasant residual fragrance on clothing, and provide a comfortable range of use.
以下に実施例を挙げて本発明の詳細な説明するが、本発
明はこれらの実施例に限定されるものではない。尚、実
施例中の％は重量基準である。The present invention will be described in detail below with reference to Examples, but the present invention is not limited to these Examples. Note that the percentages in the examples are based on weight.
実施例１
配 合
過炭酸ソーダ ８０ ％炭酸ソーダ
１３．９
酵素（アルカラーゼ２．０Ｔ） １無水硫酸マグネ
シウム ５
香料（表１） ｏ、ｉ上記の配合物を
ポリ容器ボトルに密封保存し、４０℃、３０日間放置保
存したのち、香気安定性、過炭酸ソーダの色について下
記の様に評価した。Example 1 Blend Soda percarbonate 80% Sodium carbonate
13.9 Enzyme (Alcalase 2.0T) 1 Anhydrous magnesium sulfate 5 Fragrance (Table 1) o, i The above formulation was stored tightly in a plastic container bottle and left to stand at 40°C for 30 days. The color of sodium percarbonate was evaluated as follows.
結果を表２に示す。The results are shown in Table 2.
香気安定性
５；殆ど変化が認められない
４；わずかに変化が認められる
３；変化が認められる
２；変化がかなり認められる
１；変化が著しく認められる
過炭酸ソーダの色
○；変化なしく着色せず）
△；着色する
×；著しく着色する
表 １ 香料の組成
表 ２
実施例２
漂白剤処理時に発生する過酸化物による不快臭の抑制効
果を調べるため、以下の実験を行った。Flavor stability 5; Hardly any change observed 4; Slight change observed 3; Change observed 2; Considerable change observed 1; Significant change observed Color of soda percarbonate ○; No change in color Δ: Colored ×: Significantly colored Table 1 Composition table of perfume 2 Example 2 The following experiment was conducted to investigate the effect of suppressing unpleasant odors caused by peroxide generated during bleach treatment.
即ち、過炭酸ソーダ８０．０％、炭酸ソーダ１８．９％
、酵素１％、表３記載の混合香料０．１％の配合物１０
ｇを４０℃、２１の水に入れ、直ちに木綿メリヤスを３
０分間浸漬処理した。木綿メリヤスを軽くしぼり、残存
する香りについて評価した。That is, 80.0% soda percarbonate, 18.9% soda carbonate.
, 1% enzyme, 0.1% mixed fragrance according to Table 3 Formulation 10
Put 3 g of cotton stockinette into 21 water at 40℃ and immediately
It was immersed for 0 minutes. The cotton stockinette was lightly squeezed and the remaining fragrance was evaluated.
結果は表３に示した。The results are shown in Table 3.
評価 ○；快怒を有する △；どちらともいえない ×；不快感を有する 表 ３evaluation ○: have pleasure and anger △; Can't say either way ×; Feeling uncomfortable Table 3
Claims (1)
成物において、香料として （Ａ）モノテルペンアルコール、セスキテルペンアルコ
ールおよび炭素数７〜１０の芳香族アルコールの群から
選ばれる少なくとも１ 種の香料と （Ｂ）炭素数８〜１７のギ酸エステルまたは酢酸エステ
ル、炭素数１０〜１５の炭化水素および炭素数７〜１５
の芳香族アルデヒドの群から選ばれる少なくとも１種の
香料 とを主成分として含有し、かつサリチル酸エステル系香
料を香料中の４〜１２重量％含有する混合香料を用いる
ことを特徴とする酵素含有漂白剤組成物。[Scope of Claims] 1. In a bleach composition containing an inorganic peroxide, an enzyme, and a fragrance, the fragrance is (A) selected from the group of monoterpene alcohols, sesquiterpene alcohols, and aromatic alcohols having 7 to 10 carbon atoms; At least one selected fragrance and (B) a formate or acetate having 8 to 17 carbon atoms, a hydrocarbon having 10 to 15 carbon atoms, and 7 to 15 carbon atoms.
Enzyme-containing bleaching characterized by using a mixed fragrance containing as a main component at least one fragrance selected from the group of aromatic aldehydes, and containing 4 to 12% by weight of a salicylic acid ester fragrance based on the fragrance. agent composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62110375A JPH075913B2 (en) | 1987-05-06 | 1987-05-06 | Enzyme-containing bleach composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62110375A JPH075913B2 (en) | 1987-05-06 | 1987-05-06 | Enzyme-containing bleach composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63275697A true JPS63275697A (en) | 1988-11-14 |
| JPH075913B2 JPH075913B2 (en) | 1995-01-25 |
Family
ID=14534210
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62110375A Expired - Fee Related JPH075913B2 (en) | 1987-05-06 | 1987-05-06 | Enzyme-containing bleach composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH075913B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4923631A (en) * | 1987-07-09 | 1990-05-08 | Lever Brothers Company | Perfume and bleach compositions |
| EP0430315A2 (en) * | 1989-09-29 | 1991-06-05 | Unilever N.V. | Perfumed laundry detergents |
| JPH03197921A (en) * | 1989-12-26 | 1991-08-29 | Kuraray Co Ltd | Detergent for contact lens |
| EP0834550A1 (en) * | 1996-10-01 | 1998-04-08 | The Procter & Gamble Company | Laundry detergent compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54102309A (en) * | 1978-01-12 | 1979-08-11 | Unilever Nv | Deodorant and cleaning products |
| JPS6111996A (en) * | 1984-06-27 | 1986-01-20 | Toshiba Corp | Semiconductor memory device |
-
1987
- 1987-05-06 JP JP62110375A patent/JPH075913B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54102309A (en) * | 1978-01-12 | 1979-08-11 | Unilever Nv | Deodorant and cleaning products |
| JPS6111996A (en) * | 1984-06-27 | 1986-01-20 | Toshiba Corp | Semiconductor memory device |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4923631A (en) * | 1987-07-09 | 1990-05-08 | Lever Brothers Company | Perfume and bleach compositions |
| EP0430315A2 (en) * | 1989-09-29 | 1991-06-05 | Unilever N.V. | Perfumed laundry detergents |
| JPH03131696A (en) * | 1989-09-29 | 1991-06-05 | Unilever Nv | Aromatized laundry detergent |
| EP0430315A3 (en) * | 1989-09-29 | 1992-03-04 | Unilever Nv | Perfumed laundry detergents |
| JPH03197921A (en) * | 1989-12-26 | 1991-08-29 | Kuraray Co Ltd | Detergent for contact lens |
| EP0834550A1 (en) * | 1996-10-01 | 1998-04-08 | The Procter & Gamble Company | Laundry detergent compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH075913B2 (en) | 1995-01-25 |
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