JPS63260993A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JPS63260993A JPS63260993A JP9496287A JP9496287A JPS63260993A JP S63260993 A JPS63260993 A JP S63260993A JP 9496287 A JP9496287 A JP 9496287A JP 9496287 A JP9496287 A JP 9496287A JP S63260993 A JPS63260993 A JP S63260993A
- Authority
- JP
- Japan
- Prior art keywords
- group
- weight
- monomer
- methacrylate
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims description 19
- 239000003599 detergent Substances 0.000 title claims description 16
- 239000000203 mixture Substances 0.000 title claims description 16
- 229920000642 polymer Polymers 0.000 claims description 22
- 239000004816 latex Substances 0.000 claims description 20
- 229920000126 latex Polymers 0.000 claims description 20
- 239000002736 nonionic surfactant Substances 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 11
- 125000002091 cationic group Chemical group 0.000 claims description 8
- 125000001302 tertiary amino group Chemical group 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000000178 monomer Substances 0.000 description 42
- -1 imidazoyl groups Chemical group 0.000 description 20
- 238000005406 washing Methods 0.000 description 14
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- 125000000217 alkyl group Chemical group 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000004744 fabric Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 5
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 239000002253 acid Chemical group 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 229920002554 vinyl polymer Polymers 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000004530 micro-emulsion Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000007870 radical polymerization initiator Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
- JLIDVCMBCGBIEY-UHFFFAOYSA-N 1-penten-3-one Chemical compound CCC(=O)C=C JLIDVCMBCGBIEY-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 2
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- QYZFTMMPKCOTAN-UHFFFAOYSA-N n-[2-(2-hydroxyethylamino)ethyl]-2-[[1-[2-(2-hydroxyethylamino)ethylamino]-2-methyl-1-oxopropan-2-yl]diazenyl]-2-methylpropanamide Chemical compound OCCNCCNC(=O)C(C)(C)N=NC(C)(C)C(=O)NCCNCCO QYZFTMMPKCOTAN-UHFFFAOYSA-N 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
- LRRBNLHPFPHVCW-UHFFFAOYSA-N 2,3-dihydroxybutanedioic acid;hydrogen peroxide Chemical compound OO.OC(=O)C(O)C(O)C(O)=O LRRBNLHPFPHVCW-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- AOUSBQVEVZBMNI-UHFFFAOYSA-N 2-bromoethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCBr AOUSBQVEVZBMNI-UHFFFAOYSA-N 0.000 description 1
- CDZAAIHWZYWBSS-UHFFFAOYSA-N 2-bromoethyl prop-2-enoate Chemical compound BrCCOC(=O)C=C CDZAAIHWZYWBSS-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- GPOGMJLHWQHEGF-UHFFFAOYSA-N 2-chloroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCl GPOGMJLHWQHEGF-UHFFFAOYSA-N 0.000 description 1
- WHBAYNMEIXUTJV-UHFFFAOYSA-N 2-chloroethyl prop-2-enoate Chemical compound ClCCOC(=O)C=C WHBAYNMEIXUTJV-UHFFFAOYSA-N 0.000 description 1
- JWCDUUFOAZFFMX-UHFFFAOYSA-N 2-ethenoxy-n,n-dimethylethanamine Chemical compound CN(C)CCOC=C JWCDUUFOAZFFMX-UHFFFAOYSA-N 0.000 description 1
- RAMTWFWSBOIROB-UHFFFAOYSA-N 2-ethenyl-2-phenyloxirane Chemical compound C=1C=CC=CC=1C1(C=C)CO1 RAMTWFWSBOIROB-UHFFFAOYSA-N 0.000 description 1
- ONUXAGYOFJLIQM-UHFFFAOYSA-N 2-ethenylnaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=C(C=C)C=CC2=C1 ONUXAGYOFJLIQM-UHFFFAOYSA-N 0.000 description 1
- IXPWKHNDQICVPZ-UHFFFAOYSA-N 2-methylhex-1-en-3-yne Chemical compound CCC#CC(C)=C IXPWKHNDQICVPZ-UHFFFAOYSA-N 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical class CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- REEBWSYYNPPSKV-UHFFFAOYSA-N 3-[(4-formylphenoxy)methyl]thiophene-2-carbonitrile Chemical compound C1=CC(C=O)=CC=C1OCC1=C(C#N)SC=C1 REEBWSYYNPPSKV-UHFFFAOYSA-N 0.000 description 1
- QAEFQMLTVALDSP-UHFFFAOYSA-N 3-bromopropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCBr QAEFQMLTVALDSP-UHFFFAOYSA-N 0.000 description 1
- OXSSBGISRIDMME-UHFFFAOYSA-N 3-bromopropyl prop-2-enoate Chemical compound BrCCCOC(=O)C=C OXSSBGISRIDMME-UHFFFAOYSA-N 0.000 description 1
- IWTYTFSSTWXZFU-UHFFFAOYSA-N 3-chloroprop-1-enylbenzene Chemical compound ClCC=CC1=CC=CC=C1 IWTYTFSSTWXZFU-UHFFFAOYSA-N 0.000 description 1
- XNRXPKPCWXCKRX-UHFFFAOYSA-N 3-chloropropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCl XNRXPKPCWXCKRX-UHFFFAOYSA-N 0.000 description 1
- KWCPPCKBBRBYEE-UHFFFAOYSA-N 3-chloropropyl prop-2-enoate Chemical compound ClCCCOC(=O)C=C KWCPPCKBBRBYEE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 125000000174 L-prolyl group Chemical group [H]N1C([H])([H])C([H])([H])C([H])([H])[C@@]1([H])C(*)=O 0.000 description 1
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 1
- 239000004472 Lysine Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical compound CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000000592 heterocycloalkyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- UUORTJUPDJJXST-UHFFFAOYSA-N n-(2-hydroxyethyl)prop-2-enamide Chemical compound OCCNC(=O)C=C UUORTJUPDJJXST-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000005271 tributylamino group Chemical group 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- GDJZZWYLFXAGFH-UHFFFAOYSA-M xylenesulfonate group Chemical group C1(C(C=CC=C1)C)(C)S(=O)(=O)[O-] GDJZZWYLFXAGFH-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、衣料用液体洗浄剤組成物に関し、更に詳しく
は、非イオン界面活性剤及び特定の？リオキシアルキレ
ン型非イオン界面活性剤と特定の高分子ラテックスを含
有する。衣類のフェルト収縮防止性、洗浄時の手のヌル
つき、泡切れの良好な液体洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a liquid detergent composition for clothing, and more particularly, to a liquid detergent composition for clothing, and more particularly to a nonionic surfactant and a specific surfactant. Contains a lyoxyalkylene type nonionic surfactant and a specific polymer latex. This invention relates to a liquid detergent composition that has good properties in preventing felt shrinkage of clothing, preventing hands from becoming sticky during washing, and having good foam removal properties.
ウール製品等の衣類を洗濯機によシ洗濯すると強い機械
力のため衣類が収縮する、いわゆるフェルト収縮の問題
があった。このため。When clothes such as wool products are washed in a washing machine, there is a problem of so-called felt shrinkage, in which the clothes shrink due to strong mechanical force. For this reason.
ウール製品の洗濯は、洗面器等の器に水又はぬるま湯を
入れ、洗剤を溶解させて衣類を浸漬する、いわゆる手洗
い法が採用されてきた。For washing wool products, a so-called hand-washing method has been adopted, in which the clothes are soaked in water or lukewarm water in a container such as a washbasin, in which detergent is dissolved.
しかしながら、この方法でもフェルト収縮の問題は依然
として生じており、また比較的濃厚な洗濯液に手を長時
間浸すため１手のヌルつき、泡切れが悪いという問題も
あった。However, even with this method, the problem of felt shrinkage still occurs, and since the hands are immersed in a relatively thick washing liquid for a long time, there are also problems that the hands become slimy and the suds are difficult to remove.
そこで１本発明者らは、斯かる問題点を解決せんと鋭意
研究を行った結果、高分子ラテックスと特定の非イオン
界面活性剤を配合すれば上記問題点が解決されることを
見い出し、本発明を完成した。Therefore, the inventors of the present invention have conducted intensive research to solve these problems, and have discovered that the above problems can be solved by blending polymer latex with a specific nonionic surfactant. Completed the invention.
すなわち１本発明は次の成分（ａ）％（ｂ）及び（ｃ）
（＆） カチオン性基又は３級アミノ基を有する高分
子ラテックスを高分子として
００１〜５重量％
（ｂ） ＨＩ、Ｂ値が２０以上の？リオキシアルキレ
ン型非イオン界面活性剤 ００１〜５重量％（ｃ）
（ｂ）以外の非イオン界面活性剤１０〜５０重量％
を含有することを特徴とする液体洗浄剤組成物を提供す
るものである。That is, 1 the present invention comprises the following components (a)% (b) and (c)
(&) 001 to 5% by weight of a polymer latex having a cationic group or a tertiary amino group (b) Does the HI and B value exceed 20? Lyoxyalkylene type nonionic surfactant 001-5% by weight (c)
The present invention provides a liquid cleaning composition characterized by containing 10 to 50% by weight of a nonionic surfactant other than (b).
本発明で用いる（ａ）成分であるカチオン性基又は３級
アミノ基を有する高分子ラテックス（以下「含窒素高分
子ラテックス」と略称する）は１例えばカチオン性基又
は３級アミノ基を有する単量体（以下「含窒素モノマー
」と略称する）又はこれと他の水不溶性の重合性単量体
をマイクロエマルションないし可溶化の状態で重合させ
ることにより製造される。The component (a) used in the present invention, a polymer latex having a cationic group or a tertiary amino group (hereinafter abbreviated as "nitrogen-containing polymer latex"), is a monomer having a cationic group or a tertiary amino group. (hereinafter abbreviated as "nitrogen-containing monomer") or other water-insoluble polymerizable monomers in a microemulsion or solubilized state.
このマイクロエマルション状態は、非イオン性界面活性
剤を用いて転相温度付近の適切な温度を選んだり、アニ
オン性界面活性剤を高級アルコール、非イオン性界面活
性剤等の適当な補助界面活性剤と組合せることによシ実
現できる。また、可溶化状態は重合性単量体に対して多
量の界面活性剤を用いることにより達成できる。This microemulsion state can be achieved by selecting an appropriate temperature near the phase inversion temperature using a nonionic surfactant, or by adding an anionic surfactant to an appropriate co-surfactant such as a higher alcohol or a nonionic surfactant. This can be achieved by combining it with Further, the solubilized state can be achieved by using a large amount of surfactant relative to the polymerizable monomer.
これらの内、特に好適なのは、非イオン性界面活性剤を
用い１重合源度を転相温度付近として単量体と水との界
面張力を１ｄｙｎｅ／Ｃ１１以下、より好ましくはＱ
５ ｄｙｎｅ ７ｃｍ以下とし、マイクロエマルション
状態として重合を行わせる方法である。Among these, particularly preferred is a method in which a nonionic surfactant is used, one polymerization degree is set near the phase inversion temperature, and the interfacial tension between the monomer and water is 1 dyne/C11 or less, more preferably Q
This is a method in which polymerization is carried out in a microemulsion state using 5 dyne of 7 cm or less.
含窒素モノマーとしては５次の一般式（１）又〔式中ｓ
ＲＩ 、ｎ、およびＲ８は炭素数１ないし１８のアル
キル基もしくは置換アルキル基又は水素であシ、王者は
同一でも異なっていてもよく、あるいは王者のうち王者
が連結して隣接する窒素原子と共にビリゾル基、イミダ
ゾイル基の如き複素環、シクロアルキル基。As the nitrogen-containing monomer, the 5th order general formula (1) or [s in the formula
RI, n, and R8 are an alkyl group or a substituted alkyl group having 1 to 18 carbon atoms, or hydrogen, and the champions may be the same or different, or the champions of the champions may be connected together with the adjacent nitrogen atom to form a bilisol. groups, heterocycles such as imidazoyl groups, and cycloalkyl groups.
ヘテロシクロアルキル基を形成してもよく、Ｙはハロゲ
ンあるいは酸残基を示す〕
で表わされるカチオン性基又は３級アミノ基を有するエ
チレン性不飽和含窒素モノマ一単位が挙げられる。A heterocycloalkyl group may be formed, and Y represents a halogen or an acid residue.
このエチレン性不飽和含窒素モノマ一単位は１例えば下
記の如く工業的に容易に共重合あるいは重合物の化学反
応によって含窒素高分子ラテックスとすることができる
。すなわち、その例としては。One unit of this ethylenically unsaturated nitrogen-containing monomer can be industrially easily converted into a nitrogen-containing polymer latex by copolymerization or chemical reaction of a polymer as described below. That is, for example.
■ ビニルピリジン、２−メチル−５−ビニルぎりシン
、２−エチルー５−ビニル？リシンの如きモノビニルピ
リシン類；Ｎ、Ｎ−ゾメチルアミノスチレン、Ｎ、Ｎ−
ゾメチルアミノメテルスチレンの如きシアルキルアミノ
基を有するスチレン類；Ｎ、Ｎ−ジメチルアミノエチル
メタクリレート、Ｎ、Ｎ−ジメチルアミノエチルアクリ
レ−）、Ｎ、Ｎ−ジエチルアミノエチルメタクリレート
、Ｎ、Ｎ−ジエチルアミノエチルアクリレ−）、Ｎ、Ｎ
−ゾメチルアミノデロビルメタクリレート、Ｎ、Ｎ−ジ
メチルアミノゾロビルアクリレート。■ Vinylpyridine, 2-methyl-5-vinylgiricine, 2-ethyl-5-vinyl? Monovinylpyriscines such as lysine; N,N-zomethylaminostyrene, N,N-
Styrenes having a sialkylamino group such as zomethylaminomethylstyrene; N,N-dimethylaminoethyl methacrylate, N,N-dimethylaminoethyl acrylate), N,N-diethylaminoethyl methacrylate, N,N-diethylamino ethyl acrylate), N, N
-Zomethylaminoderovir methacrylate, N,N-dimethylaminozorobyl acrylate.
Ｎ、Ｎ−ジエチルアミノゾロビルメタクリレート％ Ｎ
、Ｎ−ゾエチルアミノｆロピルアクリレートの如きアク
リル酸又はメタクリル酸のシアルキルアミノ基を有する
エステル類；２−ジメチルアミノエチルビニルエーテル
の如キシアルキルアミノ基を有するビニルエーテル類；
Ｎ−（Ｎ、’＋Ｎ’−ゾメチルアミノエチル）メタクリ
ルアミド、Ｎ−（Ｎ’、Ｎ’−ジメチルアミノエチル）
アクリルアミド、Ｎ−（Ｎ’、Ｎ’−ジエチルアミノエ
チル）メタクリルアミド、Ｎ−（Ｎ’、Ｎ’−ジエチル
アミノエチル）アクリルアミド、Ｎ−（Ｎ’、Ｎ’−ゾ
メチルアミノデロビル）メタクリルアミド、Ｎ−（Ｎ’
、Ｎ’−ゾメチルアミノデロビル）アクリルアミド、Ｎ
−（Ｎ’、Ｎ’−ジエチルアミノプロビル）メタクリル
アミド、Ｎ−（Ｎ’、Ｎ’−ジエチルアミノゾロピル）
アクリルアミドの如きシアルキルアミノ基を有するアク
リルアミドあるいはメタクリルアミド類と水不溶性のエ
チレン性不飽和単量体とを公知の方法で共重合して得ら
れる重合物。さらに、これらを公知の４級化剤１例えば
・・ロダン化アルキル（アルキル基の炭素数１ないし１
８．ノーロダンとしては塩素、臭素、ヨウ素）、塩化ペ
ンシルまたは臭化ペンシル等のノーログン化ベンシル、
メタンスルホン酸、ベンゼンスルホン酸またはトルエン
スルホン酸等のアルキルあるいはアリールスルホン酸の
アルキルエステル（アルキル基の炭素数１ないし１８）
。N,N-diethylaminozorobyl methacrylate% N
, esters of acrylic acid or methacrylic acid having a sialkylamino group, such as N-zoethylamino f-ropylacrylate; vinyl ethers having a oxyalkylamino group, such as 2-dimethylaminoethyl vinyl ether;
N-(N,'+N'-zomethylaminoethyl)methacrylamide, N-(N',N'-dimethylaminoethyl)
Acrylamide, N-(N',N'-diethylaminoethyl)methacrylamide, N-(N',N'-diethylaminoethyl)acrylamide, N-(N',N'-zomethylaminoderovil)methacrylamide, N -(N'
, N'-zomethylaminoderovir) acrylamide, N
-(N',N'-diethylaminopropyl)methacrylamide, N-(N',N'-diethylaminozolopyl)
A polymer obtained by copolymerizing an acrylamide or methacrylamide having a sialkylamino group such as acrylamide with a water-insoluble ethylenically unsaturated monomer by a known method. Furthermore, these are added to a known quaternizing agent 1, such as a rhodanized alkyl (alkyl group having 1 to 1 carbon atoms).
8. Examples of norodane include chlorine, bromine, iodine), norogonated benzyl such as pencil chloride or pencil bromide,
Alkyl esters of alkyl or arylsulfonic acids such as methanesulfonic acid, benzenesulfonic acid or toluenesulfonic acid (alkyl group has 1 to 18 carbon atoms)
.
および硫酸シアルキル（アルキル基の炭素数１ないし４
）等で４級化した重合物。and sialkyl sulfate (alkyl group has 1 to 4 carbon atoms)
) and other polymers.
■ クロルメチルスチレン、３−クロル−１−プロペン
、３−ブロム−１−プロペン、２−クロルエチルアクリ
レ−）、 ２−クロルエチルメタクリレート、２−ブロ
モエチルアクリレート、２−ブロモエチルメタクリレー
ト、３−クロルプロピルアクリレート、３−クロルプロ
ピルメタクリレート、３−ブロモプロピルアクリレート
、３−ブロモプロピルメタクリレート、４−クロルプロ
ピルアクリレート、４−クロルプロピルメタクリレート
、２−クロルエチルビニルエーテルノ如キハロクン化メ
チル基（−ＣＩ、Ｘ ）を有するエチレン性不飽和単量
体と水不溶性のエチレン性不飽和単量体との共重合体、
又は？リステレンあるいはスチレンと他の水不溶性のエ
チレン性不飽和単量体との共重合体のクロルメチル化重
合体の如き・・ログン化メチル基を有する重合物と、ト
リメチルアミノ、トリエチルアミノ、トリプロピルアミ
ノ、トリブチルアミノ、トリ・アミルアミ７、ｎ−オク
チルジメチルアミノ％ ｎ−ドデシルゾメチルアミノ、
ｎ−テトラデシルゾメチルアミノの如き脂肪族３級アミ
ノあるいはジメチルアニリン、ジエチルアニリン、トリ
ペンシルアミノの如き芳香族アミノとの反応物。■ Chlormethylstyrene, 3-chloro-1-propene, 3-bromo-1-propene, 2-chloroethyl acrylate), 2-chloroethyl methacrylate, 2-bromoethyl acrylate, 2-bromoethyl methacrylate, 3- Chlorpropyl acrylate, 3-chloropropyl methacrylate, 3-bromopropyl acrylate, 3-bromopropyl methacrylate, 4-chloropropyl acrylate, 4-chloropropyl methacrylate, 2-chloroethyl vinyl ether, halocunated methyl group (-CI, ) A copolymer of an ethylenically unsaturated monomer and a water-insoluble ethylenically unsaturated monomer,
Or? Such as a chloromethylated copolymer of listerene or styrene and other water-insoluble ethylenically unsaturated monomers... Polymers having a rogynated methyl group, trimethylamino, triethylamino, tripropylamino, Tributylamino, triamylami7, n-octyldimethylamino% n-dodecylzomethylamino,
A reaction product with an aliphatic tertiary amino such as n-tetradecylzomethylamino or an aromatic amino such as dimethylaniline, diethylaniline, tripentylamino.
■ 工？キシ基を有するエチレン性不飽和単量体１例え
ば（メタ）アクリル酸グリシゾル。■ Engineering? Ethylenically unsaturated monomer 1 having a xyl group, such as glycisol (meth)acrylate.
ビニルフェニルグリシゾルエーテル、ビニルフェニルエ
チレンオキシド、アリルグリシゾルエーテル等と水不溶
性のエチレン性不飽和単量体との共重合によって得られ
る重合体に２級アミノを作用させて工献キシ基を開環せ
しめると同時に３級アミノ基を導入したもの及び次いで
上記■に記載の方法でこれを４級化したもの、
■ ２−ヒドロキシエチルアクリレート、２−ヒドロキ
シエチルメタクリレート、２−ヒドロキシ７’ｏビルア
クリレート、２−ヒドロキシエチルアクリレート、Ｎ−
２−ヒドロキシエチルアクリルアミドの如き水酸基を有
するエチレン性不飽和単量体と水不溶性のエチレン性不
飽和単量体との共重合体あるいは水不溶性のエチレン性
不飽和単量体とビニルアルコールの脂肪酸エステルとの
共重合体のケン化物の如き水酸基を有する重合物とグリ
シゾルトリメチルアンモニウム塩酸塩あるいは３−クロ
ロ−２−ヒドロキシゾロピルトリメチルアンモニウム塩
の如きカチオン化剤との反応物。A polymer obtained by copolymerizing vinyl phenyl glycysol ether, vinyl phenyl ethylene oxide, allyl glycysol ether, etc. with a water-insoluble ethylenically unsaturated monomer is reacted with secondary amino to open the engineered xy group. 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate, 2-hydroxy 7'ovir acrylate, 2-Hydroxyethyl acrylate, N-
A copolymer of an ethylenically unsaturated monomer having a hydroxyl group such as 2-hydroxyethyl acrylamide and a water-insoluble ethylenically unsaturated monomer, or a fatty acid ester of a water-insoluble ethylenically unsaturated monomer and vinyl alcohol. A reaction product of a polymer having a hydroxyl group such as a saponified copolymer with a cationizing agent such as glycizoltrimethylammonium hydrochloride or 3-chloro-2-hydroxyzolopyltrimethylammonium salt.
■ 上記■に記載の如き３級アミノ基を有するエチレン
性不飽和単量体を上記■に記載の如き４級化剤を使用し
て４級化するか、あるいは上記■に記載の如きクロルメ
チル基を有するエチレン性不飽和単量体を上記■に記載
の脂肪族３級アミノ、芳香族アミノと反応せしめること
によって得られるカチオン基を有するエチレン性不飽和
単量体と水不溶性のエチレン性不飽和単量体との共重合
物、
等が挙げられる。■ The ethylenically unsaturated monomer having a tertiary amino group as described in (■) above is quaternized using a quaternizing agent as described in (1) above, or the chloromethyl group as described in (1) above is used. An ethylenically unsaturated monomer having a cationic group obtained by reacting an ethylenically unsaturated monomer having the above with an aliphatic tertiary amino or an aromatic amino described in (1) above and a water-insoluble ethylenically unsaturated monomer. Examples include copolymers with monomers, and the like.
以上の■〜■は必ずしも全て４級化物あるいは塩にする
必要はなく、一般式（１）の如く３級塩の形であってよ
い。この３級アミノ基は水溶液中（中性ないし酸性溶液
）においては弱いカチオン性を有するものである。All of the above compounds (1) to (2) do not necessarily have to be quaternized products or salts, and may be in the form of tertiary salts as shown in general formula (1). This tertiary amino group has weak cationic properties in an aqueous solution (neutral to acidic solution).
上記■〜■の高分子の調製に用いる水不溶性の重合性単
量体としては、乳化重合で使用される公知の単量体のす
べてを挙げることができ１例えばエチレン、プロピレン
、イソブチン、ブテン−１等のエチレン系不飽和単量体
：スチレン、α−メチルスチレン、ビニルトルエン、へ
ロダン化スチレン、ジビニルベンゼン等の芳香族ビニル
単量体；アクリル酸エチル、アクリル酸ブチル、アクリ
ル酸２−エチルヘキシル等のアルキル基の炭素数が１〜
２０個のアクリル酸エステル；メタクリル酸メチル、メ
タクリル酸ブチル、メタクリル酸ラウリル等の炭素数が
１〜２０個のメタクリル酸エステル；酢酸ビニル、グロ
ビオン酸ビニル等のビニルエステル；エテルビニルエー
テル、ブチルビニルエーテル等の炭素数が１〜２０個の
ビニルエーテル：メテルビニルケトン、エチルビニルケ
トン等の炭素数が１〜２０個のビニルケトン；アクリロ
ニトリル。The water-insoluble polymerizable monomers used in the preparation of the polymers ① to ② above include all known monomers used in emulsion polymerization. For example, ethylene, propylene, isobutyne, butene Ethylenically unsaturated monomers such as 1st class: aromatic vinyl monomers such as styrene, α-methylstyrene, vinyltoluene, herodanized styrene, and divinylbenzene; ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate The number of carbon atoms in the alkyl group is 1 to
20 acrylic esters; methacrylic esters with 1 to 20 carbon atoms such as methyl methacrylate, butyl methacrylate, and lauryl methacrylate; vinyl esters such as vinyl acetate and vinyl globionate; ether vinyl ether, butyl vinyl ether, etc. Vinyl ethers having 1 to 20 carbon atoms: Vinyl ketones having 1 to 20 carbon atoms such as metervinyl ketone and ethyl vinyl ketone; acrylonitrile.
メタクリレートリル等のビニルシアン単量体；塩化ビニ
ル、臭化ビニル、塩化ビニリデン、臭化ビニリデン等の
・・ログン化ビニル及び・・ログン化ビニリデン、１，
３−プタゾエン、２−メチル−１，３−プタゾエン等の
脂肪族共役シアン等を挙げることができる。これらの単
量体は単独でも又２種以上を混合しても使用することが
でき、中でもアクリレート、メタクリレートなどのα、
β−不飽和カルボン酸エステル系七ツ糸上を用いるのが
好ましく、更に上記単量体に無水マレイン酸もしくｔｉ
水水性性モノマー、スチレンスルホン酸（塩）％ビニル
ナフタレンスルホン酸（塩）。Vinyl cyanide monomers such as methacrylate trile; vinyl chloride, vinyl bromide, vinylidene chloride, vinylidene bromide, vinyl rogonide and vinylidene rogonide, 1,
Examples include aliphatic conjugated cyanogens such as 3-putazoene and 2-methyl-1,3-putazoene. These monomers can be used alone or in combination of two or more, and among them, α, acrylate, methacrylate, etc.
It is preferable to use β-unsaturated carboxylic acid ester-based seven threads, and the monomers include maleic anhydride or ti
Water Aqueous Monomer, Styrene Sulfonic Acid (Salt)% Vinylnaphthalene Sulfonic Acid (Salt).
アクリル酸（塩）等を加え共重合することも出来る。It is also possible to copolymerize by adding acrylic acid (salt) or the like.
本発明の含窒素高分子ラテックスの調製に当っての含窒
素モノマーと水不溶性の重合性単量体との比は、含窒素
モノマーが００５〜５５％であることが望ましい。In preparing the nitrogen-containing polymer latex of the present invention, the ratio of the nitrogen-containing monomer to the water-insoluble polymerizable monomer is preferably 0.05 to 55%.
含窒素高分子ラテックスを製造するための最も好ましい
方法は、水が仕込まれた反応容器中に界面活性剤を加え
て水溶液を調製し。The most preferred method for producing nitrogen-containing polymer latex is to prepare an aqueous solution by adding a surfactant to a reaction vessel filled with water.
これを界面活性剤ミセルが転相する温度近傍にて加熱攪
拌下、単量体と水との界面張力が１ ｄｙｎｅ／ｃＩＬ
以下、好ましくはＯ〜Ｑ ５ ｄｙｎｅ／１になる状態
を保持しつつ重合性単量体。This was heated and stirred at a temperature near the phase inversion temperature of surfactant micelles until the interfacial tension between the monomer and water was 1 dyne/cIL.
Hereinafter, the polymerizable monomer is preferably maintained in a state of O to Q 5 dyne/1.
必要ならばラジカル重合開始剤の水溶液を加えて重合を
開始し、次いで界面活性剤水溶液と単量体相との界面張
力が上記範囲外にならないように重合性単量体を徐々に
加えて重合を行う方法である。If necessary, add an aqueous solution of a radical polymerization initiator to initiate polymerization, and then gradually add a polymerizable monomer so that the interfacial tension between the aqueous surfactant solution and the monomer phase does not fall outside the above range. This is the way to do it.
ここで、ラジカル重合開始剤としては、例えば過硫酸カ
リウム、過硫酸ナトリウム、過硫酸アンモニウム等の過
硫酸塩、２．２’−アゾビス（２−アミゾノデロノＱン
）鉱酸塩、アゾビスシアノブアレリン酸及びそのアルカ
リ金属塩及びアンモニウム塩、 １ 、１’−７ソヒス
シクロヘキサンカルポニトリル等のアゾ化合物、酒石酸
−過酸化水素、ロンガリッ）−過酸化物、アスコルビン
酸−過酸化物等のレドックス系開始剤等があげられ、こ
れらのうちでカチオン性界面活性剤を重合系として使用
する場合は２．２′−アゾビス（２−アミゾノデロ／Ｑ
ン）鉱酸塩、その他の重合系においては過硫酸塩が好適
に用いられる。ラジカル重合開始剤の量は重合体を構成
する単量体１００重量部に対し０１〜５重量部、好まし
くは０１〜３重量部である。Here, examples of the radical polymerization initiator include persulfates such as potassium persulfate, sodium persulfate, and ammonium persulfate, 2,2'-azobis(2-amizonoderonoQ) mineral acid salts, and azobiscyanobuarelin. Acids and their alkali metal salts and ammonium salts, azo compounds such as 1, 1'-7 sohiscyclohexanecarponitrile, tartaric acid-hydrogen peroxide, redox system initiation such as rongaric acid-peroxide, ascorbic acid-peroxide, etc. Among these, when using a cationic surfactant as a polymerization system, 2,2'-azobis(2-amizonodero/Q
) Persulfates are preferably used in mineral acid salts and other polymerization systems. The amount of the radical polymerization initiator is 01 to 5 parts by weight, preferably 01 to 3 parts by weight, based on 100 parts by weight of the monomers constituting the polymer.
上記方法において１反応源度は、転相温度近傍の可溶化
領域内での最高の温度であり、５０〜９０℃の範囲が好
ましい。また重合に要する時間は単量体の種類１組成、
濃度、ラゾカル重合開始剤の濃度１重合温度等によって
変わるが、通常は５〜５０時間の範囲が好ましい。In the above method, one reaction temperature is the highest temperature in the solubilization region near the phase inversion temperature, preferably in the range of 50 to 90°C. In addition, the time required for polymerization depends on the type of monomer, composition,
Although it varies depending on the concentration, the concentration of the razocal polymerization initiator, the polymerization temperature, etc., a range of 5 to 50 hours is usually preferred.
含窒素高分子ラテックスは１以上説明したような分子中
にカチオン性基又は３級アミノ基を有するものが好まし
いが、これにとどまらず非カチオン性高分子ラテックス
に、カチオン性基又は３級アミノ基を有する高分子を。The nitrogen-containing polymer latex preferably has at least one cationic group or tertiary amino group in the molecule as described above, but the non-cationic polymer latex may also have a cationic group or tertiary amino group. A polymer with
保護コロイド剤として作用せしめたものであっても良い
。It may also act as a protective colloid.
蒸上の含窒素高分子ラテックスは通常２００〜ａ ｏ
ｏ ｐｐｍ以上の残存モノマーを含有するので１本発明
の液体洗浄剤組成物知配合、使用するためにはこれを除
去するのが好ましい。The nitrogen-containing polymer latex used for steaming is usually 200~a.o.
Since it contains residual monomers of 0 ppm or more, it is preferable to remove this in order to formulate and use the liquid detergent composition of the present invention.
残存上ツマ−の除去手段としては、例えば減圧蒸留、減
圧下における水蒸気蒸留、減圧下における薄膜分離、空
気の吹き込みによるノ５プリング、吸着剤による吸着等
の方法が挙げられる。Examples of the means for removing the remaining upper particles include methods such as distillation under reduced pressure, steam distillation under reduced pressure, thin film separation under reduced pressure, pulling by blowing air, and adsorption with an adsorbent.
また、含窒素高分子ラテックスの平均粒子径はＱＯＯ５
〜０．２μｍであり、かつこの範囲に入る粒子が該含窒
素尚分子ラテックス全体の９５％以上となることが好ま
しい。更に。In addition, the average particle diameter of the nitrogen-containing polymer latex is QOO5
~0.2 μm, and particles within this range preferably account for 95% or more of the entire nitrogen-containing molecular latex. Furthermore.
ガラス転位温度（Ｔｆ ）が３００°に以下のものであ
ることが好ましい。Preferably, the glass transition temperature (Tf) is less than or equal to 300°.
本発明の衣料用液体洗剤は、蒸上の如くして得られた（
ｂ）成分を液体洗剤基剤に直接添加配合するか、又は所
望の濃度まで濃縮した懸濁液を添加配合する方法によシ
製造される。The liquid laundry detergent of the present invention is obtained by steaming (
b) It is manufactured by adding and blending the ingredients directly to a liquid detergent base, or by adding and blending a suspension concentrated to a desired concentration.
（ｂ）成分は、液体洗剤組成物中に、水分を留去した残
分として００１〜５重量％（以下、単に％で示す）、特
に０．０５〜５％配合されるのが好ましい。Component (b) is preferably blended in the liquid detergent composition in an amount of 0.01 to 5% by weight (hereinafter simply expressed as %), particularly 0.05 to 5%, as a residue after water is distilled off.
また、本発明の（ｂ）成分の）ＩＬＢ値が２０以上の？
ｌ）オキシアルキレン型非イオン性界面活性剤として
は、ポリオキシエチレンアルキルエーテル、ポリオキシ
エチレンアルキルフェニルエーテル、？リエテレン／
ｌｊ ：ｆｆ −ｋ脂肪酸エステル−１？リオキシエチ
レンソルビタン脂肪酸エステル、？リオキシエチレング
リセリン脂肪酸エステル、？リオキシエテレンソルビッ
ト脂肪酸ニスデル、飲すオキシエチレン？リオキシゾロ
ビレンアルキルエーテル、ポリオキシエチレンヒマシ油
・硬化ヒマシ油等の活性剤のうちＨＬＢ値２０以上のも
のが挙ケラレ、特に、ポリオキシエチレンアルキルエー
テル、？′リエチレングリコール脂肪酸エステルのＨＬ
Ｂ値２０以上のものが好ましい。Moreover, the component (b) of the present invention has an ILB value of 20 or more?
l) As the oxyalkylene type nonionic surfactant, polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether, ? Rieteren/
lj:ff-k fatty acid ester-1? Lioxyethylene sorbitan fatty acid ester? Lyoxyethylene glycerin fatty acid ester? Lioxyethylene sorbitol fatty acid Nisder, oxyethylene to drink? Among the activators such as lyoxyzolobylene alkyl ether, polyoxyethylene castor oil and hydrogenated castor oil, those with HLB value of 20 or more cause vignetting, especially polyoxyethylene alkyl ether? 'HL of lyethylene glycol fatty acid ester
Those with a B value of 20 or more are preferable.
なお１本明細書中において、 ＨＬＢ値は次式で定めら
れる値を用いた。Note that in this specification, the HLB value is determined by the following formula.
ＨＬＢ ＝ΣＣ親水基の基数）−Σ（親油基の基数）＋
７上式における主なＨＬＢ基数
以下余白
蒸上の本発明（ｂ）成分の含有量は、全組成中の００１
〜５％、好ましくは０１〜３％が適当でるｐ、ｏ、ｏ１
％未満では効果が小さく。HLB = ΣC number of hydrophilic groups) - Σ (number of lipophilic groups) +
7 The content of the component (b) of the present invention in the main HLB base number or less in the above formula is 001 in the total composition.
-5%, preferably 01-3% p, o, o1
If it is less than %, the effect is small.
５％を超え゛ると泡立ちを阻害するため好ましくない。If it exceeds 5%, foaming will be inhibited, which is not preferable.
本発明で洗浄主基剤として使用する（ｂ）以外の非イオ
ン界面活性剤（ｃ）成分は通常洗剤に用いられるもので
あればいずれも用いることができるが、一般にＨＬＢ
１３〜１８程度のものが使用され、特に下記のものが好
ましい。The nonionic surfactant (c) component other than (b) used as the main detergent base in the present invention can be any of those commonly used in detergents, but generally HLB
Those having a molecular weight of about 13 to 18 are used, and the following are particularly preferred.
（１］ 平均炭素数１０〜２０のアルキル基又はアル
ケニル基ヲ有し、１〜２０モルのエチレンオキサイドを
付加した？リオキシエチレンアルキル又はアルケニルエ
ーテル。(1) A ?lioxyethylene alkyl or alkenyl ether having an alkyl or alkenyl group having an average carbon number of 10 to 20 and to which 1 to 20 moles of ethylene oxide is added.
（２） 平均炭素数６〜１２のアルキル基を有し。(2) It has an alkyl group having an average carbon number of 6 to 12.
１〜２０モルのエチレンオキサイドを付加したポリオキ
シエチレンアルキルフェニルエーテル。Polyoxyethylene alkylphenyl ether with 1 to 20 moles of ethylene oxide added.
（ｂ）以外の非イオン界面活性剤は組成物中に１０〜５
０％配合される。Nonionic surfactants other than (b) are present in the composition at a concentration of 10 to 5
Contains 0%.
尚１本発明の液体洗浄剤組成物中には、必要に応じて、
メタノール、エタノール、プロ、ｅノール等の脂肪族低
級１価アルコール；エチレングリコール、ジエチレング
リコール、プロピレングリコール、ゾデロぎレンゲリコ
ール、グリセリン、ゾグリセリン等の低級多価アルコー
ル：ベンゼンスルホン酸塩、ノＱラドルエンスルホン酸
塩、キシレンスルホン酸塩、クメンスルホン酸塩、安息
香酸塩等の芳香族スルホン酸塩又はカルダン酸塩、染料
、顔料などを添加することも出来る。Note that the liquid cleaning composition of the present invention may contain, if necessary,
Aliphatic lower monohydric alcohols such as methanol, ethanol, pro, e-nol; Lower polyhydric alcohols such as ethylene glycol, diethylene glycol, propylene glycol, zoderogylene glycol, glycerin, zoglycerin: benzene sulfonate, no-Qradolene Aromatic sulfonates or cardates such as sulfonates, xylene sulfonates, cumene sulfonates, benzoates, dyes, pigments, etc. can also be added.
次に参考例及び実施例を挙げて本発明を更に詳しく説明
する。Next, the present invention will be explained in more detail with reference to Reference Examples and Examples.
参考例１
（１）攪拌機付きセ・♀ラブル７ラスコに水２００１、
？リオキシエチレン（３５）ノニルフェニルエーテル１
６ｔ 及Ｕ過硫酸アンモン０６２を仕込み、窒素で充分
置換した。次いで窒素ガスを吹き込んで攪拌しながら６
２℃に加温し、２−エチルへキシルメタクリレート９５
を及（ＪＮ、Ｎ’−ジエチルアミノエテルメタクリレー
ト５？を混合した液を約２時間を要して滴下し、更に６
時間重合をおこなった。Reference example 1 (1) Water 2001 in a Se-♀ Rubble 7 Lasco with a stirrer,
? Lioxyethylene (35) nonylphenyl ether 1
6 tons and U ammonium persulfate 062 were charged, and the mixture was sufficiently purged with nitrogen. Next, blow in nitrogen gas and stir while stirring.
Warm to 2°C and add 2-ethylhexyl methacrylate 95
(JN,N'-diethylaminoether methacrylate 5?) was added dropwise over a period of about 2 hours.
Time polymerization was performed.
反応終了後冷却し、２００メツシユの金網でＦＪＬラテ
ックスＡ（２−エテルヘキシルメタクリレート／ジエチ
ルアミノエテルメタクリレ−）＝９５１５．残存モノマ
ー量は３００ｐｐｍ ）を得た。After the reaction was completed, it was cooled, and FJL latex A (2-ethylhexyl methacrylate/diethylaminoether methacrylate) = 9515. The amount of residual monomer was 300 ppm).
（ｉｉ） （ｉ）で得たラテックスＡを９０℃で４時
間水蒸気蒸留し、残存モノマー量４０ ＰＰｍの精製ラ
テックスＡ（重量平均粒子径００７μｍ１粒子径が００
０５〜０２μｍのものは全体の１ｏ。(ii) Latex A obtained in (i) was steam-distilled at 90°C for 4 hours to obtain purified latex A with a residual monomer content of 40 PPm (weight average particle size 007 μm 1 particle size 00
05 to 02 μm is 10 in total.
％）を得た。%) was obtained.
参考例２
参考例１− （ｉ）（ｉｉ）と同様にして、ラテックス
Ｂ（ｎ−ブチルアクリレート／ジメチルアミノエチルア
クリレート＝９５１５、残存モノマー量は３５ ｐｐｒ
ｆ１％重量平均粒子径０．１０μｍ。Reference Example 2 In the same manner as Reference Example 1-(i) and (ii), latex B (n-butyl acrylate/dimethylaminoethyl acrylate = 9515, residual monomer amount was 35 ppr)
f1% weight average particle diameter 0.10 μm.
粒子径０． ＯＯ５〜０２μｍのものが全体の９６％）
及びラテックスＣ（ｎ−ブチルアクリレート／メタクロ
イルオキシエチレントリメチルアンモニウムクロリド９
９／１、残存モノマーｉ１３０ｐｐｍｓ重量平均粒子径
０．０９μｍ％粒子径０００５〜０２μｍのものが全体
の１００％）を得た。Particle size 0. 96% of the total is OO5~02μm)
and Latex C (n-butyl acrylate/methacroyloxyethylene trimethylammonium chloride 9
9/1, residual monomer i: 130 ppms, weight average particle size: 0.09 μm, particle size: 0005 to 02 μm (100% of the total).
実施例１
第１表の組成の液体洗浄剤を調製し、フェルト収縮防止
性、洗濯時の手の感触及びすすぎ性を評価した。Example 1 A liquid detergent having the composition shown in Table 1 was prepared, and its anti-shrinkage properties, hand feel during washing, and rinsability were evaluated.
１）フェルト収縮防止性
（１）供試布の調製
大きさ１１０Ｘ１０の三方をロックミシンでかがったウ
ールの未加工布を常温の水道水に３０分間浸漬後、脱水
槽にて３０秒脱水し、網の上に載せて平干しし、２０℃
、６５％ＲＨの室で４時間以上調湿した。この布に油性
のマジックで４ケ所印を付け、それぞれに番号を付した
。再度２０℃、６５％ＲＨで調湿した後、長さを測定し
くタテ”ｌ＋ ’：、 ヨ：ｆｆ ｌ）τ、ｂ１）、こ
の長さを原長（Ｒ，Ｍ、）とした。1) Anti-shrinkage properties of felt (1) Preparation of test cloth A raw wool cloth with a size of 110 x 10 sewn on three sides using a lock sewing machine was immersed in tap water at room temperature for 30 minutes, and then dehydrated for 30 seconds in a dehydration tank. Place on a wire rack to dry flat at 20°C.
The humidity was controlled for 4 hours or more in a room with 65% RH. Four marks were made on this cloth with an oil-based marker and a number was attached to each. After conditioning the humidity again at 20° C. and 65% RH, the length was measured (vertical “l + ”:, y: ff l) τ, b1), and this length was taken as the original length (R, M, ).
（２）洗濯方法
ターグー０−トメ−ター（Ｔｅｒｇ −０−Ｔｏｍｅｔ
＠ｒ ）を用い、（１）で得た供試布３枚を１つの？ッ
トに入れｈ１２ｏｒｐｍで１０分間回転させ洗濯をおこ
なった。各洗剤濃度はＱ２ｉ５％とし。(2) Washing method Terg-0-Tomet
@r ), combine the three test fabrics obtained in (1) into one ? The clothes were washed by placing them in a washing machine and spinning at 12 orpm for 10 minutes. The concentration of each detergent was Q2i5%.
水温は２０℃とした。すすぎとしては、１回目を？ット
の中で流水すすぎをおこない２回目は？りの手洗い桶中
で流水すすぎをおこなった。次いで、この供試布を洗濯
機脱水槽の壁につけて３０、秒脱水後網の上に載せて平
干しして乾燥させ、２０℃、６５％ＲＨで４時間以上調
湿した。The water temperature was 20°C. As for the first rinse? What about the second time rinsing with running water in the bathtub? I rinsed my hands with running water in a hand washing tub. Next, this sample fabric was applied to the wall of a washing machine dehydration tank and dehydrated for 30 seconds, then placed on a net to dry flat, and the humidity was controlled at 20° C. and 65% RH for 4 hours or more.
更に、先に（１）で付した印について再度それらの間の
長さを測定しくタテ’！＋’！ヨコｂＩｔｂ、）、これ
から次式に従ってフェルト収縮率及び面積収縮率を算出
した。Furthermore, measure the length between the marks made in (1) above again, vertically! +'! horizontal bItb, ), from which the felt shrinkage rate and area shrinkage rate were calculated according to the following equations.
（収縮率の計算（ｔＷｓＴＭ９よね）〕Ｒ，Ｍ、 ：洗
濯前の測定値（原長）
Ｗ、Ｍ、 ：洗濯後の測定値
〔面積収縮率の算出〕
Ｗ、Ｓ、 ：ヨコ方向の収縮率
Ｉ、、Ｓ、 ：タテ方向の収縮率
２）洗濯時の手の感触評価
１０人のノ９ネラーによる洗濯時（１０ｔのたらいに３
０℃水道水５を入れ、ウール未加工布及びアクリルシャ
ーシをそれぞれ１００２づつ合計２００ｆ及び洗剤１２
５ Ｉｌｌ入れた液）の手のヌルつきについて感触テス
トを行なった。(Calculation of shrinkage rate (tWsTM9)) R, M, : Measured value before washing (original length) W, M, : Measured value after washing [Calculation of area shrinkage rate] W, S, : Shrinkage in the horizontal direction Rate I,,S,: Shrinkage rate in the vertical direction 2) Hand feel evaluation during washing When washed by 10 No. 9 washers (3 in a 10 ton tub)
Add 55% of 0°C tap water, 100% each of unprocessed wool cloth and acrylic chassis for a total of 200f, and 12% detergent.
A tactile test was conducted to determine whether the liquid (5 Ill) had a slimy feel on the hands.
２：手のヌルつきが非常にある
１： り ややある
０ ： ＩＩ はとんどない評価は、１０
人の評価点の平均により行なったっ
３）すすぎ性評価
２）と同様の方法にて、５分洗潅した後衣料を脱水機に
よシ脱水３０秒後、３０°Ｃ水道水５ｔを入れ、押し洗
いすすぎ１分後の泡の量を肉眼判定により評価した。2: Hands feel very slippery 1: Slightly smooth 0: II is extremely rough Rating: 10
3) Rinseability Evaluation Using the same method as in 2), after washing for 5 minutes, put the clothes in a dehydrator. After 30 seconds of dehydration, add 5 tons of 30°C tap water. The amount of foam 1 minute after pressing and rinsing was evaluated by visual judgment.
２：タライの液面全体に泡がある １：タライの液面の１／２に泡がある ０：タライの液面に泡がほとんどない 以下余白 2: There are bubbles all over the liquid surface of the colander. 1: There are bubbles on 1/2 of the liquid level in the tank 0: There are almost no bubbles on the liquid surface of the tray. Margin below
Claims (1)
テックスを高分子として０．０１〜５重量％（ｂ）ＨＬ
Ｂ値が２０以上のポリオキシアルキレン型非イオン界面
活性剤０．０１〜５重量％ （ｃ）（ｂ）以外の非イオン界面活性剤１０〜５０重量
％を含有することを特徴とする液体洗浄剤組成物。 ２、高分子ラテックスの平均粒子径（重量平均）が０．
００５〜０．２μｍで、かつ粒子径０．００５〜０．２
μｍのものが全体の９５重量％以上である特許請求の範
囲第１項記載の液体洗浄剤組成物。[Claims] 1. The following components (a), (b) and (c) (a) 0.01 to 5% by weight of polymer latex having a cationic group or tertiary amino group ( b) H.L.
A liquid cleaning characterized by containing 0.01 to 5% by weight of a polyoxyalkylene type nonionic surfactant having a B value of 20 or more (c) 10 to 50% by weight of a nonionic surfactant other than (b) agent composition. 2. The average particle diameter (weight average) of the polymer latex is 0.
005-0.2μm, and particle size 0.005-0.2
2. The liquid detergent composition according to claim 1, wherein 95% by weight or more of the liquid detergent composition has micrometers.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9496287A JPS63260993A (en) | 1987-04-17 | 1987-04-17 | Liquid detergent composition |
| US07/064,706 US4746455A (en) | 1986-06-27 | 1987-06-22 | Liquid detergent composition for clothing articles |
| DE3789786T DE3789786T2 (en) | 1986-06-27 | 1987-06-24 | Liquid detergent composition for articles of clothing. |
| ES87109093T ES2056052T3 (en) | 1986-06-27 | 1987-06-24 | LIQUID DETERGENT COMPOSITION FOR CLOTHING. |
| EP87109093A EP0251188B1 (en) | 1986-06-27 | 1987-06-24 | Liquid detergent composition for clothing articles |
| CA000540543A CA1296593C (en) | 1986-06-27 | 1987-06-25 | Liquid detergent composition for clothing articles |
| HK47995A HK47995A (en) | 1986-06-27 | 1995-03-30 | Liquid detergent composition for clothing articles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9496287A JPS63260993A (en) | 1987-04-17 | 1987-04-17 | Liquid detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63260993A true JPS63260993A (en) | 1988-10-27 |
Family
ID=14124553
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9496287A Pending JPS63260993A (en) | 1986-06-27 | 1987-04-17 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63260993A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003535986A (en) * | 2000-06-06 | 2003-12-02 | ビーエーエスエフ アクチェンゲゼルシャフト | Use of cationically modified particulate hydrophobic polymers as additives for rinses, finishes, detergents and cleaning agents |
-
1987
- 1987-04-17 JP JP9496287A patent/JPS63260993A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003535986A (en) * | 2000-06-06 | 2003-12-02 | ビーエーエスエフ アクチェンゲゼルシャフト | Use of cationically modified particulate hydrophobic polymers as additives for rinses, finishes, detergents and cleaning agents |
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