JPS6325603B2 - - Google Patents

Info

Publication number: JPS6325603B2
Authority: JP; Japan
Prior art keywords: resin; chelate; reaction; ethylamino; chelate resin
Prior art date: 1984-05-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP10119184A

Other languages

English (en)

Japanese (ja)

Other versions

JPS60123508A (ja

Inventor

Toshiro Yokoyama

Toshishige Suzuki

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

National Institute of Advanced Industrial Science and Technology AIST

Original Assignee

Agency of Industrial Science and Technology

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-05-19

Filing date

1984-05-19

Publication date

1988-05-26

1984-05-19 Application filed by Agency of Industrial Science and Technology filed Critical Agency of Industrial Science and Technology

1984-05-19 Priority to JP10119184A priority Critical patent/JPS60123508A/ja

1985-07-02 Publication of JPS60123508A publication Critical patent/JPS60123508A/ja

1988-05-26 Publication of JPS6325603B2 publication Critical patent/JPS6325603B2/ja

Status Granted legal-status Critical Current

Links

229920005989 resin Polymers 0.000 claims description 45
239000011347 resin Substances 0.000 claims description 45
239000013522 chelant Substances 0.000 claims description 22
238000004519 manufacturing process Methods 0.000 claims description 5
CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 claims description 3
125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 3
125000001424 substituent group Chemical group 0.000 claims description 3
125000004105 2-pyridyl group Chemical group N1=C([*])C([H])=C([H])C([H])=C1[H] 0.000 claims description 2
125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 claims description 2
238000001179 sorption measurement Methods 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 10
125000005843 halogen group Chemical group 0.000 description 8
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
238000000034 method Methods 0.000 description 5
229920000642 polymer Polymers 0.000 description 5
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 4
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
150000001412 amines Chemical class 0.000 description 4
229910021645 metal ion Inorganic materials 0.000 description 4
239000002351 wastewater Substances 0.000 description 4
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
-1 2-[2-(2-pyridyl)-ethylamino]-ethylamino group Chemical group 0.000 description 3
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
230000007423 decrease Effects 0.000 description 3
229910001385 heavy metal Inorganic materials 0.000 description 3
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 3
239000003446 ligand Substances 0.000 description 3
229910052750 molybdenum Inorganic materials 0.000 description 3
239000011733 molybdenum Substances 0.000 description 3
229910052757 nitrogen Inorganic materials 0.000 description 3
230000035484 reaction time Effects 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
239000004793 Polystyrene Substances 0.000 description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000000921 elemental analysis Methods 0.000 description 2
229910052736 halogen Inorganic materials 0.000 description 2
150000002367 halogens Chemical class 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
239000000178 monomer Substances 0.000 description 2
IPWSANYYLVGECF-UHFFFAOYSA-N n'-(2-pyridin-2-ylethyl)ethane-1,2-diamine Chemical compound NCCNCCC1=CC=CC=N1 IPWSANYYLVGECF-UHFFFAOYSA-N 0.000 description 2
229920002223 polystyrene Polymers 0.000 description 2
BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
239000002994 raw material Substances 0.000 description 2
239000013535 sea water Substances 0.000 description 2
SESSOVUNEZQNBV-UHFFFAOYSA-M sodium;2-bromoacetate Chemical compound [Na+].[O-]C(=O)CBr SESSOVUNEZQNBV-UHFFFAOYSA-M 0.000 description 2
239000000243 solution Substances 0.000 description 2
239000002904 solvent Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
229910052720 vanadium Inorganic materials 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
229920001328 Polyvinylidene chloride Polymers 0.000 description 1
JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
125000000217 alkyl group Chemical group 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
KDPAWGWELVVRCH-UHFFFAOYSA-N bromoacetic acid Chemical compound OC(=O)CBr KDPAWGWELVVRCH-UHFFFAOYSA-N 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
238000007265 chloromethylation reaction Methods 0.000 description 1
229910017052 cobalt Inorganic materials 0.000 description 1
239000010941 cobalt Substances 0.000 description 1
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000010949 copper Substances 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
238000005695 dehalogenation reaction Methods 0.000 description 1
239000003480 eluent Substances 0.000 description 1
235000019441 ethanol Nutrition 0.000 description 1
239000010842 industrial wastewater Substances 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
229910052759 nickel Inorganic materials 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000573 polyethylene Polymers 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
229920005990 polystyrene resin Polymers 0.000 description 1
229920003053 polystyrene-divinylbenzene Polymers 0.000 description 1
229920000915 polyvinyl chloride Polymers 0.000 description 1
239000004800 polyvinyl chloride Substances 0.000 description 1
239000005033 polyvinylidene chloride Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
125000004076 pyridyl group Chemical group 0.000 description 1
230000009257 reactivity Effects 0.000 description 1
FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
238000005979 thermal decomposition reaction Methods 0.000 description 1

Landscapes

Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP10119184A 1984-05-19 1984-05-19 ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法 Granted JPS60123508A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP10119184A JPS60123508A (ja)	1984-05-19	1984-05-19	ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP10119184A JPS60123508A (ja)	1984-05-19	1984-05-19	ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
JP14009082A Division JPS5939442B2 (ja)	1982-08-11	1982-08-11	新規キレ−ト樹脂の製造方法

Publications (2)

Publication Number	Publication Date
JPS60123508A JPS60123508A (ja)	1985-07-02
JPS6325603B2 true JPS6325603B2 (cs)	1988-05-26

Family

ID=14294061

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP10119184A Granted JPS60123508A (ja)	1984-05-19	1984-05-19	ピリジルアルキルアミノポリカルボン酸型キレ−ト樹脂の製造方法

Country Status (1)

Country	Link
JP (1)	JPS60123508A (cs)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP5017801B2 (ja) *	2005-05-25	2012-09-05	日立化成工業株式会社	キレート樹脂

1984
- 1984-05-19 JP JP10119184A patent/JPS60123508A/ja active Granted

Also Published As

Publication number	Publication date
JPS60123508A (ja)	1985-07-02

Publication	Publication Date	Title
US5078978A (en)	1992-01-07	Pyridine-containing alkoxysilanes bonded to inorganic supports and processes of using the same for removing and concentrating desired ions from solutions
JPS5850138B2 (ja)	1983-11-09	水不溶性キレ−ト交換樹脂
US4281086A (en)	1981-07-28	Polymer bound multidentate complexes
JPS6325603B2 (cs)	1988-05-26
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