JPS6324060A - Target of sputtering device - Google Patents

Target of sputtering device

Info

Publication number
JPS6324060A
JPS6324060A JP9490686A JP9490686A JPS6324060A JP S6324060 A JPS6324060 A JP S6324060A JP 9490686 A JP9490686 A JP 9490686A JP 9490686 A JP9490686 A JP 9490686A JP S6324060 A JPS6324060 A JP S6324060A
Authority
JP
Japan
Prior art keywords
target
substrate
sputtering
thin film
plasma
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9490686A
Other languages
Japanese (ja)
Inventor
Yoshiichi Takada
高田 芳一
Yasushi Tanaka
靖 田中
Akira Takase
高瀬 朗
Yasushi Ueno
康 上野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Engineering Corp
Original Assignee
NKK Corp
Nippon Kokan Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NKK Corp, Nippon Kokan Ltd filed Critical NKK Corp
Priority to JP9490686A priority Critical patent/JPS6324060A/en
Publication of JPS6324060A publication Critical patent/JPS6324060A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target

Abstract

PURPOSE:To remarkably increase the sputtering rate by using a porous target produced by powder metallurgy as the title target at the time of forming the thin film of a ferromagnetic material on the surface of a substrate by magnetron sputtering. CONSTITUTION:Gaseous Ar 10 is enclosed at about 10<-3>Torr in a vacuum chamber 2 which is evacuated by vacuum pumps 7 and 8 to a high vacuum, and a high voltage is impressed by an electric power source 1 between the ferromagnetic target 3 backed with a permanent magnet 4 and a substrate 6 to be treated to generate plasma between the target and the substrate. Consequently, Ar is ionized by the plasma, the target 3 is sputtered, and the thin film of the material of the target 3 is formed on the substrate 6. In this case, the target 3 is formed with a porous material having voids and obtained by molding and sintering the fine particles of the raw material by powder metallurgy. As a result, a magnetic circuit formed by the permanent magnet 4 and the target 3 is leaked to the surface of the target to facilitate the generation of plasma, sputtering is accelerated, and the thin film of the ferromagnetic material of the target 3 can be formed on the substrate 6 at a high rate.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明はスパッタリング装置のターゲットの構成に関
する。より詳しくは真空容器の中に被加工物(一方の電
柵)とターゲット(他の電極)を設け、この2つの電極
の間にプラズマを発生させ、強磁性材料からなるターゲ
ットの一部を蒸発させて被加工物の表面に薄膜を形成さ
せるための多孔質ターゲットに関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to the structure of a target for a sputtering apparatus. More specifically, a workpiece (one electric fence) and a target (another electrode) are placed in a vacuum container, and plasma is generated between these two electrodes to evaporate part of the target made of ferromagnetic material. The present invention relates to a porous target for forming a thin film on the surface of a workpiece.

〔従来の技術] 近年、薄膜6u気記録媒体、あるいは薄膜磁気ヘッド等
の薄膜磁性材料の製造法とて、スパッタリング法が一般
的になりつつある。その理由として挙げられるのは。
[Prior Art] In recent years, the sputtering method has become common as a method for manufacturing thin film magnetic materials such as thin film 6U recording media or thin film magnetic heads. The reasons for this are:

(1)、下地基板との付着力の強い8膜が得られる。(1) 8 films with strong adhesion to the underlying substrate are obtained.

(2)、広い面積上に均一な厚さの膜が作れる。(2) A film of uniform thickness can be created over a wide area.

(3)、ターゲット組成とほぼ等しい組成の薄膜が得ら
れる。
(3) A thin film having approximately the same composition as the target composition can be obtained.

(4)、酸化物等め絶縁材料も薄膜化できる。(4) Insulating materials such as oxides can also be made thinner.

からである。更に、工業的な製造という観点から見ると
、高速で成膜できることが好ましく、このために、種々
のスパッタ方式の中でマグネトロンスパッタ方式が多く
使われている。
It is from. Furthermore, from the viewpoint of industrial manufacturing, it is preferable to be able to form a film at high speed, and for this reason, among the various sputtering methods, the magnetron sputtering method is often used.

第1図は従来技術及びこの発明に係る装置の説明図であ
る。図において1は電源(直流あるいは高周波)、2は
内圧を1O−3Torr程度に調圧されたチャンバー、
3:ま強磁性材料からなるターゲット、4は永久磁石、
5は6n気回路を構成するためのヨーク、5aは他方の
電源1に接読され被加工物である基板6を取り付けるた
めの基板ホルダー、7は真空チャンバー2内を真空にす
るための油回転ポンプ、8(よ超高真空 (約1 x 10−’To r r)を得るためのクラ
イオソープションポンプ、9はArボンベ1o内の流出
ガスの流出を制御するマスフローコントローラ、+、−
はこの装置を直流電源によって動作させるときの極性を
示している。
FIG. 1 is an explanatory diagram of a conventional technique and a device according to the present invention. In the figure, 1 is a power source (DC or high frequency), 2 is a chamber whose internal pressure is regulated to about 10-3 Torr,
3: Target made of ferromagnetic material, 4: Permanent magnet,
5 is a yoke for configuring a 6n air circuit; 5a is a substrate holder connected to the other power source 1 and used to attach a substrate 6, which is a workpiece; 7 is an oil rotor for evacuating the inside of the vacuum chamber 2. pump, 8 (cryosorption pump for obtaining an ultra-high vacuum (approximately 1 x 10-'Torr), 9 a mass flow controller for controlling the outflow of gas in the Ar cylinder 1o, +, -
indicates the polarity when operating this device with a DC power supply.

次にこの動作について説明する。先ず油回転ポンプ7に
よって続いてクライオソープションポンプ8によって真
空チャンバー2内の圧力を1O−7Torr<らいに吸
引する。次にマスフローコントローラー9を通じてAr
ボンベ10内のArガスを導入し、真空チャンバ2内の
圧力を1O−3Torr台に調整する。ここで電源1を
動作させればターゲット3の表面付近に高密度Arプラ
ズマを形成し、Arイオンによりターゲット3をスパッ
タするから、ターゲット3を構成している分子のイオン
が飛び出して基板6の表面に薄膜を形成する。この薄膜
の形成速度は非磁性金属で数千〜2000人/min、
磁性金属の場合では数百〜数千人、/ m i n程度
と極めて遅いものである。
Next, this operation will be explained. First, the pressure inside the vacuum chamber 2 is sucked to 10-7 Torr by the oil rotary pump 7 and then by the cryosorption pump 8. Next, through the mass flow controller 9, Ar
Ar gas in the cylinder 10 is introduced, and the pressure in the vacuum chamber 2 is adjusted to about 10-3 Torr. If the power supply 1 is operated here, a high-density Ar plasma is formed near the surface of the target 3 and the target 3 is sputtered with Ar ions, so the ions of the molecules that make up the target 3 fly out and reach the surface of the substrate 6. Form a thin film on the surface. The formation rate of this thin film is several thousand to 2000 people/min for non-magnetic metals.
In the case of magnetic metals, it is extremely slow, on the order of several hundred to several thousand people/min.

すなわち、磁性金属をスパッタする場合になぜスパッタ
速度が遅くなるかというと、第1図に示すマグネトロン
スパッタの場合、ターゲット3の表面に強磁界を印加す
る必要があるのに、現在のようなターゲットの構成では
、磁界がターゲット3内に吸い込まれてしまい表面付近
に磁界が漏洩しにくいからである。ターゲット3の成分
が高j磁率になるような場合には、この影響がはなはだ
しい。従ってこのような場合にはターゲット3の厚みを
薄くし、磁界をターゲット3の表面からもれ出させる必
要がある。この結果として、−枚のターゲット3あたり
から生産される6丑性薄膜のユは減少し、ターゲット3
を交換するための作業量は増大し、更に、ターゲット3
が脆性を示す場合には、薄く加工するために多大の労力
を要し、歩留も低くなる。
In other words, the reason why the sputtering speed is slow when sputtering magnetic metals is that in the case of magnetron sputtering shown in Fig. 1, it is necessary to apply a strong magnetic field to the surface of the target 3, but the current target This is because, in the configuration, the magnetic field is sucked into the target 3, making it difficult for the magnetic field to leak near the surface. This effect is significant when the component of the target 3 has a high magnetic flux. Therefore, in such a case, it is necessary to reduce the thickness of the target 3 so that the magnetic field leaks out from the surface of the target 3. As a result, the number of 6-thin films produced from around target 3 decreases, and
The amount of work to replace target 3 will increase, and
When the material exhibits brittleness, it takes a great deal of effort to process it into a thinner material, and the yield rate also decreases.

従って薄膜磁気記録媒体あるいは薄膜磁気ヘッドの製造
のように大量生産する商品に適用する場合には多大の問
題を含むものである。
Therefore, there are many problems when applied to mass-produced products such as the manufacture of thin-film magnetic recording media or thin-film magnetic heads.

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

上記の様に従来のスパッタリング装置の磁性金属から成
るターゲットにおいてはターゲットの厚さが成る値を越
えるとターゲット表面外に洩れる′6ff界が減少する
ためスパッタ速度が低下する。そこでターゲットを薄く
すると、この材質は脆い性質を有するために加工性が悪
く、加工費がかさみ永久磁石への取付時あるいはスパッ
タ時に割れを生じることもあり管理上問題が多かった。
As mentioned above, in a target made of a magnetic metal in a conventional sputtering apparatus, when the thickness of the target exceeds a certain value, the '6ff field leaking outside the target surface decreases, so that the sputtering speed decreases. Therefore, if the target is made thinner, the brittle nature of this material results in poor workability, increases processing costs, and cracks may occur during attachment to a permanent magnet or during sputtering, which poses many management problems.

(問題点を解決するための手段) この発明に係るスパッタリング装置のターゲットにおい
ては、真空容器の中に対向する基板とターゲットを設け
、このターゲットと上記基板の間にプラズマを発生させ
、この基板の表面に上記ターゲットの薄膜を蒸着させる
装置において、上記ターゲットには多孔質材料を使用す
るようにしたものである。
(Means for Solving the Problems) In the target of the sputtering apparatus according to the present invention, a substrate and a target facing each other are provided in a vacuum container, plasma is generated between the target and the substrate, and plasma is generated between the substrate and the substrate. In an apparatus for depositing a thin film of the target on a surface, the target is made of a porous material.

(作用〕 この発明においてはターゲットの原料として強磁性体の
粉末を用いこれを空隙を有するように厚手に成形したも
のを使用する。永久磁石の磁気回路はターゲットの表面
に迄漏洩してプラズマか形成され易くなりスパッタリン
グが盛んに進行する。
(Function) In this invention, ferromagnetic powder is used as the raw material for the target, which is thickly molded to have voids.The magnetic circuit of the permanent magnet leaks to the surface of the target and generates plasma. It becomes easier to form, and sputtering progresses actively.

〔実施例〕〔Example〕

第1図は、この発明に係る装置の説明図である。図にお
いて1〜10は従来の技術とほとんど同一であるので説
明を省略する。但しターゲット3の材Xが顕著に異って
いるのてこの事について述べる。
FIG. 1 is an explanatory diagram of an apparatus according to the present invention. In the figure, numerals 1 to 10 are almost the same as the conventional technology, so the explanation will be omitted. However, we will discuss the fact that the material X of the target 3 is significantly different.

第1実施例としてターゲット3に気孔率の大きい強磁性
材料であるセンダスト合金を用いたので以下に述べる。
In the first embodiment, Sendust alloy, which is a ferromagnetic material with a high porosity, was used for the target 3, which will be described below.

センダスト合金粉の化学成分、平均粒径は、第1表のよ
うである。
The chemical composition and average particle size of the sendust alloy powder are as shown in Table 1.

第工表 センダスト合金製ターゲットの原料表wt%F これを金型内で7t’/cm2の圧力で一軸圧縮により
、3インチ径の円板状に成形後、真空焼結を行う。焼結
温度は1010’C11070t:、1150℃の3水
準とした。真空度は1O−5To’rr<らいて1時間
保持した材料を追加工せずに実施した。
Table 1 Raw material table of Sendust alloy target wt%F This is formed into a disk shape with a diameter of 3 inches by uniaxial compression at a pressure of 7 t'/cm2 in a mold, and then vacuum sintered. The sintering temperature was set at three levels: 1010'C11070t: and 1150°C. The degree of vacuum was 10-5 To'rr<, and the material was held for 1 hour without any additional processing.

第2実施例については第2表に3種の純金属を使用した
ものを示す。
Regarding the second embodiment, Table 2 shows the use of three types of pure metals.

第2表 純金属製ターゲットの原料表 これを第1実施例と同様の焼結条件で焼成したが焼結保
持時間は5時間とした。
Table 2 List of raw materials for pure metal targets This was fired under the same sintering conditions as in the first example, but the sintering holding time was 5 hours.

第3の実施例とて;士第3表に示す二元合金を用い下記
の組合せ1〜3により混合し、これを焼結したものであ
る。
In the third embodiment, the binary alloys shown in Table 3 were mixed in the following combinations 1 to 3, and the mixture was sintered.

第3表 二元合金製ターゲットの原料表組合せ例−1,
2,3は 例−1、Fe粉+Feと17%Si合金粉十Feと10
%A1合金粉 例−2、Fe粉+Feと17%Si合金粉+AI粉 例−3、Fe粉+Si粉十 Feと10%AI合金粉 以上3種類の組合せで、それぞれセンダスト合金組成と
なるよう粉の配分を調整し混合し圧粉、焼結は第1実施
例に準じた。焼結保持時間は5時間とした。
Table 3 Example of raw material table combination for binary alloy target-1,
2 and 3 are Example-1, Fe powder + Fe and 17% Si alloy powder 10 Fe and 10
%A1 alloy powder example-2, Fe powder + Fe and 17% Si alloy powder + AI powder example-3, Fe powder + Si powder + Fe powder and 10% AI alloy powder A combination of 3 types or more, each powder has a sendust alloy composition. Adjusting the distribution, mixing, compacting, and sintering were carried out in accordance with the first embodiment. The sintering holding time was 5 hours.

これらにより出来上がったものの、条件、板厚、空隙率
を第4表に示す。出来上がった円板状ターゲットはその
ままスパッタ用素材とした。
Table 4 shows the conditions, plate thickness, and porosity of the finished product. The completed disk-shaped target was directly used as a material for sputtering.

一方比較材として、溶解鋳造法により第5表に示すよう
な混合比で合金を作製し、機械加工により第4表に示す
ような板厚のものを作製した。
On the other hand, as a comparative material, an alloy was prepared using a melting and casting method at a mixing ratio shown in Table 5, and a plate having a thickness shown in Table 4 was prepared by machining.

第4表 ターゲツト材仕様及び比較材仕様第5表 比較
材成分表 wt% 以上のようにして作製した強磁性ターゲットを用い、第
1図の装置によるマグネトロン、スパッタリングを行な
った。スパッタリング条件は第6表に示す。
Table 4 Target material specifications and comparative material specifications Table 5 Comparative material composition table wt% Using the ferromagnetic target produced as described above, magnetron sputtering was performed using the apparatus shown in FIG. The sputtering conditions are shown in Table 6.

第6表 スパッタリング条件の表 第6表に示す条件下において、所定時間スパッタリング
を行ない、基板6をとり出し、触針式膜厚計により生成
膜厚を測定した。Fe−5i−AI粉末を焼結したター
ゲット3と機械加工により作製したターゲット3との同
じ板厚のものの生成膜厚の比を第2図に示す。明らかに
本発明の方が生成膜厚スピードが速いことがわかる。ま
た第3図は空隙率と膜生成速度比との関係である。
Table 6 Sputtering Conditions Under the conditions shown in Table 6, sputtering was performed for a predetermined period of time, the substrate 6 was taken out, and the thickness of the produced film was measured using a stylus type film thickness meter. FIG. 2 shows the ratio of the film thickness of a target 3 made by sintering Fe-5i-AI powder and a target 3 made by machining, both of which have the same plate thickness. It is clearly seen that the film thickness produced according to the present invention is faster. Moreover, FIG. 3 shows the relationship between porosity and film formation rate ratio.

又スパッタリング終了後、この薄膜を化学分析したとこ
ろ、本発明によって作製した薄膜は、初めに混合したタ
ーゲット3の合金比率と全く同一の組成を示した。
Further, when the thin film was chemically analyzed after sputtering, it was found that the thin film produced according to the present invention had exactly the same composition as the alloy ratio of the target 3 mixed at the beginning.

しかしなから比較例として示した鋳造法ではSlが9.
2%、A1が5,0%を示し、いずれも混合比よりも低
目となった。
However, in the casting method shown as a comparative example, Sl was 9.
2% and A1 was 5.0%, both of which were lower than the mixing ratio.

(発明の効果) この発明は以上説明した通りターゲットの強磁性材料と
して多孔質の粉末焼結法による合金を用いたので以下に
示すような効果がある。
(Effects of the Invention) As explained above, this invention uses a porous alloy produced by a powder sintering method as the ferromagnetic material of the target, and therefore has the following effects.

第一に最終形状(Near  Net  5hape)
が容易に達成でき加工がほとんど不要となる。これはセ
ンダストのような脆性材料の場合大幅なコスト低減につ
ながる。
First, the final shape (Near Net 5hape)
can be easily achieved and almost no machining is required. This leads to significant cost reductions for brittle materials such as sendust.

第二に合金成分を厳密に管理することができるので、ス
パッタ・ターゲット内での成分偏析が絶無となり、個々
のターゲットの成分的中率も高い。
Second, since the alloy components can be strictly controlled, component segregation within the sputter target is completely eliminated, and the component accuracy of each target is high.

第三に高真空中で製造するのでスパッタ時ターゲットの
消耗にともなうボアの開孔による7囲気の汚染を押える
ことができる。
Thirdly, since it is manufactured in a high vacuum, it is possible to prevent contamination of the surrounding atmosphere due to opening of the bore as the target is consumed during sputtering.

第四に粉末性状、焼結条件を這べはボアの分布、形状大
きざを自由に調整することができる。以上の点からポー
ラスターゲット作製には粉末冶金法が極めて有効である
Fourthly, by adjusting the powder properties and sintering conditions, the bore distribution and shape size can be freely adjusted. From the above points, powder metallurgy is extremely effective for producing porous targets.

更に磁性材料をマグネトロンスパッタつまり第1図の方
法で施工するとスパッタ速度を4〜15倍速くすること
ができ、薄膜作成コストを大幅に下げることができる。
Furthermore, if the magnetic material is applied by magnetron sputtering, that is, the method shown in FIG. 1, the sputtering speed can be increased by 4 to 15 times, and the cost of producing a thin film can be significantly reduced.

又ターゲットの作製に関し、ターゲットを機械加工する
必要がなく加工費を大幅に下げることができる。
Further, regarding the production of the target, there is no need to machine the target, and processing costs can be significantly reduced.

又化学成分を粉体の混合比で決められるので、ターゲッ
トの成分管理が容易であり、成分はずれが起きないため
ターゲット製造歩留が高いことである。
In addition, since the chemical components can be determined by the mixing ratio of the powder, it is easy to manage the components of the target, and the target production yield is high because the components do not shift.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図はこの発明及び従来の技術に係る装置の説明図、
第2図はこの発明による膜成生速度と従来の膜成生速度
の比較を板79について示す線図、第3図はこの発明に
よる膜成生速度と従来の膜成生速度の比較を空隙率につ
いて示す線図である。 図において、1は電源、2は真空チャンバー、3はター
ゲット、4は永久6u石、5はヨーク、5aは基板ホル
ダー、6は基板、7は油回転ポンプ、8はクライオソー
プションポンプ、9はマスフローコントローラ、10は
Arボンベである。 代理人 弁理士 佐 藤 正 年 5:ヨーク 50.基板ホルタ− 6:答 板 7、油回転ボンフ″ 8、タライオンーブノヨン木°ンフ“ 9:マヌフローコントローラー 10 : Arボンへ 第 3 図 (扱ツマLユ全で5mm)
FIG. 1 is an explanatory diagram of a device according to the present invention and the conventional technology;
FIG. 2 is a diagram showing a comparison between the film formation rate according to the present invention and the conventional film formation rate for the plate 79, and FIG. It is a line diagram showing a rate. In the figure, 1 is a power supply, 2 is a vacuum chamber, 3 is a target, 4 is a permanent 6u stone, 5 is a yoke, 5a is a substrate holder, 6 is a substrate, 7 is an oil rotary pump, 8 is a cryosorption pump, and 9 is a The mass flow controller 10 is an Ar cylinder. Agent: Patent Attorney Tadashi Sato Year 5: York 50. Substrate Holter 6: Answer Plate 7, Oil rotary bong 8, Tallion wood 9: Manuflow controller 10: To Ar bong Fig. 3 (Total handling knob L 5mm)

Claims (2)

【特許請求の範囲】[Claims] (1).真空容器の中に対向する基板とターゲットを設
け、このターゲットと上記基板の間にプラズマを発生さ
せ、この基板の表面に上記ターゲットの薄膜を蒸着させ
る装置において、上記ターゲットには多孔質材料を使用
することを特徴とするスパッタリング装置のターゲット
(1). A device in which a substrate and a target facing each other are provided in a vacuum container, plasma is generated between the target and the substrate, and a thin film of the target is evaporated on the surface of the substrate, in which a porous material is used for the target. A sputtering device target characterized by:
(2).上記多孔質材料は粉末焼結法により形成した内
部に空隙を含む強磁性体であることを特徴とする特許請
求の範囲第1項記載のスパッタリング装置のターゲット
(2). 2. The target for a sputtering apparatus according to claim 1, wherein the porous material is a ferromagnetic material containing voids inside formed by a powder sintering method.
JP9490686A 1986-04-25 1986-04-25 Target of sputtering device Pending JPS6324060A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9490686A JPS6324060A (en) 1986-04-25 1986-04-25 Target of sputtering device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9490686A JPS6324060A (en) 1986-04-25 1986-04-25 Target of sputtering device

Publications (1)

Publication Number Publication Date
JPS6324060A true JPS6324060A (en) 1988-02-01

Family

ID=14123059

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9490686A Pending JPS6324060A (en) 1986-04-25 1986-04-25 Target of sputtering device

Country Status (1)

Country Link
JP (1) JPS6324060A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4941920A (en) * 1987-11-25 1990-07-17 Hitachi Metals, Ltd. Sintered target member and method of producing same
JPH02200778A (en) * 1989-01-31 1990-08-09 Daido Steel Co Ltd Sputtering target
JPH03278408A (en) * 1989-09-12 1991-12-10 Nikko Kyodo Co Ltd Fe-si-al alloy thin magnetic film and manufacture thereof
WO2013046780A1 (en) * 2011-09-30 2013-04-04 Jx日鉱日石金属株式会社 Fe-Al BASED ALLOY SPUTTERING TARGET

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4941920A (en) * 1987-11-25 1990-07-17 Hitachi Metals, Ltd. Sintered target member and method of producing same
JPH02200778A (en) * 1989-01-31 1990-08-09 Daido Steel Co Ltd Sputtering target
JPH03278408A (en) * 1989-09-12 1991-12-10 Nikko Kyodo Co Ltd Fe-si-al alloy thin magnetic film and manufacture thereof
WO2013046780A1 (en) * 2011-09-30 2013-04-04 Jx日鉱日石金属株式会社 Fe-Al BASED ALLOY SPUTTERING TARGET
JP5554420B2 (en) * 2011-09-30 2014-07-23 Jx日鉱日石金属株式会社 Fe-Al alloy sputtering target

Similar Documents

Publication Publication Date Title
JP3897724B2 (en) Manufacturing method of micro, high performance sintered rare earth magnets for micro products
US4309266A (en) Magnetron sputtering apparatus
US6074279A (en) Process for producing sputtering target
EP3015566B1 (en) Magnetic material sputtering target and method for producing same
WO2004114333A1 (en) Rare earth - iron - boron based magnet and method for production thereof
US20120318669A1 (en) Sputtering target-backing plate assembly
JPH02161617A (en) Production of magnetic recording medium
US5407548A (en) Method for coating a substrate of low resistance to corrosion
JPS6324060A (en) Target of sputtering device
US4885134A (en) Sputtering target and method of preparing the same
US4941920A (en) Sintered target member and method of producing same
JP2001523767A (en) Method for manufacturing Ni-Si magnetron sputtering target and target manufactured by the method
US4966668A (en) Method for the treatment of metal objects
JP2005209669A (en) Rare-earth magnet and magnetic circuit using it
JPS62294159A (en) Method for preventing rust of permanent magnet alloy
JPS63140077A (en) Method and apparatus for producing thin dielectric film
US4476000A (en) Method of making a magnetic film target for sputtering
JPS63118067A (en) Target for sputtering
JP2005097706A (en) Method and apparatus for producing soft magnetic material
JP3545050B2 (en) Sputtering apparatus and sputtering thin film production method
JPS636811A (en) Magnet
CN113957400A (en) Low-cost chromium-silicon alloy target and preparation method thereof
JPH02133570A (en) Sputtering device for multiple body
CN112195449A (en) Method for plating non-magnetic metal on surface layer of diamond powder
US6666901B1 (en) Thermal shock resistant quasicrystalline alloy target