JPS63238008A - Cosmetic - Google Patents
CosmeticInfo
- Publication number
- JPS63238008A JPS63238008A JP7106787A JP7106787A JPS63238008A JP S63238008 A JPS63238008 A JP S63238008A JP 7106787 A JP7106787 A JP 7106787A JP 7106787 A JP7106787 A JP 7106787A JP S63238008 A JPS63238008 A JP S63238008A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic
- particles
- porous spherical
- effect
- spherical cellulose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 24
- 239000002245 particle Substances 0.000 claims abstract description 30
- 229920002678 cellulose Polymers 0.000 claims abstract description 29
- 239000001913 cellulose Substances 0.000 claims abstract description 29
- 230000005484 gravity Effects 0.000 claims description 4
- 239000006071 cream Substances 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 14
- 239000010419 fine particle Substances 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 9
- 238000004140 cleaning Methods 0.000 abstract description 4
- 239000000344 soap Substances 0.000 abstract description 4
- 230000004060 metabolic process Effects 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 210000002374 sebum Anatomy 0.000 abstract description 2
- 239000008280 blood Substances 0.000 abstract 1
- 210000004369 blood Anatomy 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 239000006210 lotion Substances 0.000 abstract 1
- 239000005445 natural material Substances 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000001815 facial effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 210000003491 skin Anatomy 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 3
- 235000011613 Pinus brutia Nutrition 0.000 description 3
- 241000018646 Pinus brutia Species 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- 239000008294 cold cream Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 239000008213 purified water Substances 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 241000220304 Prunus dulcis Species 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000021736 acetylation Effects 0.000 description 1
- 238000006640 acetylation reaction Methods 0.000 description 1
- 235000020224 almond Nutrition 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000007863 gel particle Substances 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- XTUSEBKMEQERQV-UHFFFAOYSA-N propan-2-ol;hydrate Chemical compound O.CC(C)O XTUSEBKMEQERQV-UHFFFAOYSA-N 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 210000000434 stratum corneum Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/28—Rubbing or scrubbing compositions; Peeling or abrasive compositions; Containing exfoliants
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はスクラブ剤として多孔性球状セルロースを配合
した化粧品に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to cosmetics containing porous spherical cellulose as a scrubbing agent.
近年、皮膚の汚れ、角質化表皮などを取り除（目的で使
用する洗顔料、いわゆるスクラブ洗顔料の使用が盛んに
なって来た。現在市場では、スクラブ洗顔料としてはア
プリコツトやアーモンド等の植物種子を砕いたもの、樹
脂系ポリエチレン、軽石等の無機系由来のものを使用し
た洗顔料が出回っている。しかし、これらのスクラブ剤
は硬度が高過ぎて皮膚を傷付けたり、また植物系のもの
では腐敗し易かったりする等の問題点がある。In recent years, the use of facial cleansers that are used to remove skin dirt and keratinized epidermis, so-called scrub facial cleansers, has become popular.Currently on the market, scrub facial cleansers that use plant-based products such as apricots and almonds have become popular. There are facial cleansers on the market that use crushed seeds, resin-based polyethylene, and inorganic products such as pumice.However, these scrubs are too hard and can damage the skin, and they also contain plant-based products. However, there are problems such as being easily corrupted.
セルロース微粒子を含む化粧料としては、特開昭６１〜
１００５１４号公報Ｇこその皮膚付着性、吸液性、被覆
性などを利用した粉末化粧料、俗に言うパウダー、おし
ろいが示されているが、ざらつきのあるセルロース微粒
子の研磨作用を利用したスクラブ洗顔料についてはまだ
知られていない。セルロース微粒子はその製法によって
物性の異なったものが得られるのでスクラブ洗顔料とし
て適当なものを得る可能性がある。Cosmetics containing cellulose fine particles include Japanese Patent Application Laid-Open No. 1983-
Publication No. 100514 G discloses powdered cosmetics that take advantage of skin adhesion, liquid absorption, and covering properties, commonly known as powder, and face powder, but this is a face scrub that uses the abrasive action of rough cellulose fine particles. Fees are not yet known. Since fine cellulose particles can be obtained with different physical properties depending on the manufacturing method, it is possible to obtain particles suitable for facial scrubs.
本発明者らはさきに、セルロース脂肪酸エステルを特別
の方法でゲル粒子とし、該粒子を加水分解してクロマト
グラフ担体などに優れた性質を有する多孔性球状セルロ
ース粒子を得、その製法を特許出願した（特願昭６１〜
２４１６９３号明細書参照）。The present inventors previously made gel particles from cellulose fatty acid ester using a special method, hydrolyzed the particles to obtain porous spherical cellulose particles that have excellent properties as a chromatographic carrier, and filed a patent application for the manufacturing method. (Special application 1986~
241693).
クロマトグラフ担体用粒子は、粒径０．１ ｍｎ＋以下
の大きさであるが上記製法はそれより大きな粒子の製造
にも通用できる。本発明者らは、上記方法によって粒径
０．１〜１．０ ｍｍの多孔性球状粒子を得、スクラブ
剤としての応用を試みたところ、顕著な効果を収めるも
のであることを認め、本発明に到達した。Particles for chromatographic carriers have a particle size of 0.1 mn+ or less, but the above production method can also be used to produce particles larger than that. The present inventors obtained porous spherical particles with a particle size of 0.1 to 1.0 mm by the above method, and when they tried to apply them as a scrubbing agent, they found that they had remarkable effects. invention has been achieved.
即ち、本発明は、粒径０．１〜１．０ ｍｎ＋、かさ比
重０．１〜０．７ ｇ／ｃｃの多孔性球状セルロースが
配合されていることを特徴とする化粧品に関するもので
ある。That is, the present invention relates to a cosmetic product containing porous spherical cellulose having a particle size of 0.1 to 1.0 mn+ and a bulk specific gravity of 0.1 to 0.7 g/cc.
詳しくは本発明は特定の物性を有する多孔性球状セルロ
ース微粒子を含有することにより、洗浄効果あるいはマ
ツサージ効果に優れた化粧品に関するものである。Specifically, the present invention relates to cosmetics that contain porous spherical cellulose fine particles having specific physical properties and have excellent cleaning effects or massage effects.
ここで述べる化粧品としては、石けん、クレンジングク
リーム等の洗浄料、バニシングクリーム、中性クリーム
、コールドクリーム、マツサージクリーム、ボディーク
リーム等のクリーム類、バンク類が挙げられ、粉体化粧
品は除く。Cosmetics mentioned here include detergents such as soaps and cleansing creams, creams such as vanishing creams, neutral creams, cold creams, pine surge creams, and body creams, and banks, and exclude powder cosmetics.
本発明に使用する多孔性球状セルロース微粒子の大きさ
は、化粧品のタイプにより若干異なるが、粒径が０．１
〜１．０ ｍｍ、かさ比重０．１〜０．７ｇ／ｃｃの粒
子が良い。これより小さい粒子になると適度な硬度や弾
力性が得られず、またこれより大きいと研磨作用が過度
になり、また肌への違和感も生じてここち良い使用域が
得られない。The size of the porous spherical cellulose fine particles used in the present invention varies slightly depending on the type of cosmetic product, but the particle size is 0.1
Particles having a diameter of ~1.0 mm and a bulk specific gravity of 0.1 to 0.7 g/cc are preferable. If the particles are smaller than this, appropriate hardness and elasticity cannot be obtained, and if the particles are larger than this, the abrasive action becomes excessive and the skin feels uncomfortable, making it impossible to obtain a comfortable range of use.
本発明で使用する多孔性球状セルロース微粒子の化粧品
への配合量については、これも化粧品のタイプにより異
なるが、化粧品全ｍｌ成の０．１〜５０重量％（以下、
単に％と略す）、好ましくは１〜２０％配合するのが良
い。配合量が０．１％より少ないと球状セルロース微粒
子による洗浄効果やピーリング効果、マツサージ効果が
得られず、また５０％より多（なると化粧品基剤そのも
のの洗浄効果や油分等が低下するので好ましくない。The amount of porous spherical cellulose particles used in the present invention to be incorporated into cosmetics varies depending on the type of cosmetic, but is 0.1 to 50% by weight of the total ml of cosmetics (hereinafter referred to as
(simply abbreviated as %), preferably 1 to 20%. If the amount is less than 0.1%, the cleaning effect, peeling effect, and pine surge effect of the spherical cellulose fine particles cannot be obtained, and if the amount is more than 50%, the cleaning effect and oil content of the cosmetic base itself will decrease, which is not preferable. .
上記の多孔性球状セルロース微粒子を化粧品基剤に配合
する方法としては、いずれの方法でも良いが、ホモジナ
イザーあるいは攪拌機等の分散機を用いると短時間内に
目標とする分散状態を達成することが出来る。Any method may be used to blend the above-mentioned porous spherical cellulose particles into a cosmetic base, but using a dispersing machine such as a homogenizer or a stirrer can achieve the desired dispersion state within a short time. .
本発明の多孔性球状セルロース微粒子入り化粧品は、配
合された適度な硬度と弾力性を有する多孔性球状セルロ
ース微粒子により、石けんだけでは落ちない毛穴の汚れ
、古くなった角質層、皮脂分等をピーリングしてとり除
いたり、またそのマツサージ効果により血行の循環を良
くするとともに、肌の新陳代謝を促すことからシミの予
防および治療効果も期待できる。本発明の化粧品は、セ
ルロースという天然に存在し、安全でかつ入手の容易な
素材を利用している点からも、現在の天然物指向の風調
にマツチした新しい化粧品と言える。The cosmetics containing porous spherical cellulose particles of the present invention use the blended porous spherical cellulose particles with appropriate hardness and elasticity to remove dirt in pores, old stratum corneum, sebum, etc. that cannot be removed with soap alone. In addition, its pine surge effect improves blood circulation and promotes skin metabolism, so it can be expected to be effective in preventing and treating age spots. The cosmetics of the present invention can be said to be new cosmetics that match the current style of natural products, since they utilize cellulose, a naturally occurring, safe, and easily available material.
以下に、製造例、実施例、使用例をあげて本発明の詳細
な説明する。The present invention will be explained in detail below by giving production examples, examples, and usage examples.
製造例
セルローストリアセテート（ダイセル化学工業■製、酢
化度６１％）２５ｇをメタノール３０−を含む塩化メチ
レン１７０−に１解した。この溶液にジブチルフタレー
ト３０ｍＺと塩化メチレン３０ａＺの混合物を加え、撹
拌して均一な溶液としたものを、消泡剤（アンチホーム
Ｅ−２０１，０ｇ）を含む１％ゼラチン０．５１中に約
７５０ ｐｐｎ＋の回転数にて攪拌しながら分散させた
。得られた懸濁液を１％ゼラチン水ＩＮ中にゆっくり攪
拌しながら投入し、１時間攪拌をつづけた。静置後、上
澄みを除き、水−イソプロパツール（１： １）混合物
１１を加えしばらく攪拌した。濾過した後、水で充分に
洗浄した。次いでセルロース微粒子を、イソプロパツー
ル１１中に懸濁させ、７０℃〜８０℃に加熱し、２〜３
時間攪拌した。濾過後、イソプロパツール０．５１で２
回洗浄し、さらに水中に分散させて８０℃で２時間処理
した後、濾過し、十分な水で洗浄した。湿潤状態におい
て、ふるい分けを行い、粒径０．５〜０ 、８５ｍｍ、
かさ比重０．６ｇ／ｃｃの多孔性球状セルロースを得た
。Production Example 25 g of cellulose triacetate (manufactured by Daicel Chemical Industries, Ltd., acetylation degree 61%) was dissolved in 170 methylene chloride containing 30 methanol. A mixture of 30 mZ of dibutyl phthalate and 30 aZ of methylene chloride was added to this solution and stirred to form a homogeneous solution, which was dissolved in 0.51 g of 1% gelatin containing an antifoaming agent (Antiform E-201.0 g) at about 750 ml. The mixture was dispersed while stirring at a rotational speed of ppn+. The resulting suspension was poured into 1% gelatin water IN with slow stirring, and stirring was continued for 1 hour. After standing still, the supernatant was removed, water-isopropanol (1:1) mixture 11 was added, and the mixture was stirred for a while. After filtering, it was thoroughly washed with water. Next, cellulose fine particles were suspended in isopropanol 11, heated to 70°C to 80°C, and heated for 2 to 3 hours.
Stir for hours. After filtration, add isopropanol 0.51 to 2
After washing twice and further dispersing in water and treating at 80° C. for 2 hours, it was filtered and washed with sufficient water. In a wet state, sieving is performed to obtain particles with a particle size of 0.5-0, 85 mm,
Porous spherical cellulose having a bulk specific gravity of 0.6 g/cc was obtained.
実施例 （クレンジングクリーム）
ミツロウ ３．０％固形パラフ
ィン ５．０ワセリン
１５．０流動パラフイン ４１
．０ソルビタン・セスキオレート ４．２精製水
２５．０香料
１．０上記組成物のうち香料と多孔性球状セ
ルロース微粒子以外の各組成物を７０’Ｃに加熱、溶解
した。得られた混合物を４５℃に冷却し、香料および上
記の製造例で得られた粒径ｏ、５〜０．８５ｍ−の多孔
性球状セルロース薇粒子を加え、ホモジナイザーで均一
化して多孔性球状セルロース微粒子入りクレンジングク
リームを得た。Example (Cleansing cream) Beeswax 3.0% solid paraffin 5.0 Vaseline
15.0 Liquid paraffin 41
．． 0 Sorbitan sesquiolate 4.2 Purified water
25.0 fragrance
1.0 Of the above compositions, each of the components other than the fragrance and the porous spherical cellulose particles were heated to 70'C and dissolved. The resulting mixture was cooled to 45°C, and perfume and porous spherical cellulose particles with a particle size o of 5 to 0.85 m obtained in the above production example were added, and the mixture was homogenized with a homogenizer to obtain porous spherical cellulose. A cleansing cream containing fine particles was obtained.
比較例
実施例における多孔性球状セルロース微粒子のみを含ま
ない組成で、実施例の場合と同操作により、多孔性球状
セルロース微粒子を含まない比較用クレンジングクリー
ムを作成した。Comparative Example A comparative cleansing cream not containing porous spherical cellulose particles was prepared using the same procedure as in the example, but with a composition that did not contain only the porous spherical cellulose particles in the example.
上記実施例および比較例で作成した多孔性球状セルロー
ス微粒子入りクレンジングクリームおよび比較用クレン
ジングクリームについて、５人の女性パネラ−によりそ
の使用域を比較した。パネラ−は各クレンジングクリー
ムのそれぞれを適量手のひらにとり、顔全体を指先で円
を描くように軽くマツサージした後、通常の石けん洗顔
を行った。使用頻度は１日２回とし、３日間使用後、比
較用クレンジングクリームに対する多孔性球状セルロー
ス微粒子入りクレンジングクリームの使用域を調べた。Five female panelists compared the range of use of the cleansing creams containing porous spherical cellulose particles prepared in the above Examples and Comparative Examples and the comparative cleansing creams. Panelists placed an appropriate amount of each cleansing cream in their palms, massaged the entire face in a circular motion with their fingertips, and then washed their face with regular soap. The frequency of use was twice a day, and after 3 days of use, the range of use of the cleansing cream containing porous spherical cellulose particles was examined compared to the comparative cleansing cream.
結果を第１表に示した。The results are shown in Table 1.
第１表
第１表より全パネラ−とも多孔性球状セルロース微粒子
入りクレンジングクリームの使用感は良いという結果を
出しており、多孔性球状セルロース緬粒子がスクラブ剤
として、非常に効果的であることが判明した。Table 1 From Table 1, all panelists found that the cleansing cream containing porous spherical cellulose fine particles had a good feel when used, indicating that porous spherical cellulose fine particles are very effective as a scrubbing agent. found.
以下にその他の使用例を示す。Other usage examples are shown below.
使用例１ （コールドクリーム）
ミツロウ １５．０％流動
パラフィン ５０．０精製水
３０６０ホウ砂
ｌ・０使用例２ （パック）Usage example 1 (cold cream) Beeswax 15.0% liquid paraffin 50.0 Purified water
3060 borax
l・0 usage example 2 (pack)
Claims (1)
ｃｃの多孔性球状セルロースが配合されていることを特
徴とする化粧品。Particle size 0.1-1.0mm, bulk specific gravity 0.1-0.7g/
A cosmetic product characterized by containing CC porous spherical cellulose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7106787A JPS63238008A (en) | 1987-03-25 | 1987-03-25 | Cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7106787A JPS63238008A (en) | 1987-03-25 | 1987-03-25 | Cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63238008A true JPS63238008A (en) | 1988-10-04 |
Family
ID=13449809
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7106787A Pending JPS63238008A (en) | 1987-03-25 | 1987-03-25 | Cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63238008A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04124119A (en) * | 1990-09-13 | 1992-04-24 | Merubueeyu Kk | Cleansing cosmetic |
| US5534265A (en) * | 1994-08-26 | 1996-07-09 | The Procter & Gamble Company | Thickened nonabrasive personal cleansing compositions |
| JPH0987165A (en) * | 1995-09-22 | 1997-03-31 | Noevir Co Ltd | Non-aqueous gelatinous skin cleaner |
| US5720961A (en) * | 1994-08-26 | 1998-02-24 | The Procter & Gamble Company | Skin cleansing compositions |
| WO2001052798A1 (en) * | 2000-01-19 | 2001-07-26 | Kao Corporation | Detergent compositions |
| JP2002212020A (en) * | 2001-01-19 | 2002-07-31 | Kohjin Co Ltd | Scrub cosmetic |
| JP2007091717A (en) * | 2005-08-31 | 2007-04-12 | Toyo Shinyaku:Kk | Scrubbing agent |
| WO2014074583A1 (en) * | 2012-11-09 | 2014-05-15 | Johnson & Johnson Consumer Companies, Inc. | Skin care compositions containing cotton and citrus-derived materials |
| WO2014074581A1 (en) * | 2012-11-09 | 2014-05-15 | Johnson & Johnson Consumer Companies, Inc. | Rinse-off skin care compositions containing cellulosic materials |
| EP2907498A1 (en) * | 2014-02-13 | 2015-08-19 | Induchem Ag | Exfoliating cellulose beads and cosmetic uses thereof |
| US9364416B2 (en) | 2012-11-09 | 2016-06-14 | Johnson & Johnson Consumer Inc. | Leave-on compositions containing cellulose materials |
| JP2018118917A (en) * | 2017-01-24 | 2018-08-02 | 株式会社ダイセル | Scrubbing agent and skin cleansing composition |
-
1987
- 1987-03-25 JP JP7106787A patent/JPS63238008A/en active Pending
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04124119A (en) * | 1990-09-13 | 1992-04-24 | Merubueeyu Kk | Cleansing cosmetic |
| US5534265A (en) * | 1994-08-26 | 1996-07-09 | The Procter & Gamble Company | Thickened nonabrasive personal cleansing compositions |
| US5658577A (en) * | 1994-08-26 | 1997-08-19 | The Procter & Gamble Company | Thickened nonabrasive personal cleansing compositions |
| US5720961A (en) * | 1994-08-26 | 1998-02-24 | The Procter & Gamble Company | Skin cleansing compositions |
| US5753245A (en) * | 1994-08-26 | 1998-05-19 | The Procter & Gamble Company | Personal cleansing compositions |
| JPH0987165A (en) * | 1995-09-22 | 1997-03-31 | Noevir Co Ltd | Non-aqueous gelatinous skin cleaner |
| US6509304B1 (en) | 2000-01-19 | 2003-01-21 | Kao Corporation | Fiber-containing detergent composition |
| WO2001052798A1 (en) * | 2000-01-19 | 2001-07-26 | Kao Corporation | Detergent compositions |
| JP4565299B2 (en) * | 2001-01-19 | 2010-10-20 | 株式会社興人 | Scrub cosmetics |
| JP2002212020A (en) * | 2001-01-19 | 2002-07-31 | Kohjin Co Ltd | Scrub cosmetic |
| JP2007091717A (en) * | 2005-08-31 | 2007-04-12 | Toyo Shinyaku:Kk | Scrubbing agent |
| US9549890B2 (en) | 2012-11-09 | 2017-01-24 | Johnson & Johnson Consumer Inc. | Rinse-off skin care compositions containing cellulosic materials |
| WO2014074581A1 (en) * | 2012-11-09 | 2014-05-15 | Johnson & Johnson Consumer Companies, Inc. | Rinse-off skin care compositions containing cellulosic materials |
| CN104768528A (en) * | 2012-11-09 | 2015-07-08 | 强生消费者公司 | Rinse-off skin care compositions containing cellulosic materials |
| CN104780903A (en) * | 2012-11-09 | 2015-07-15 | 强生消费者公司 | Skin care compositions containing cotton and citrus-derived materials |
| US9364416B2 (en) | 2012-11-09 | 2016-06-14 | Johnson & Johnson Consumer Inc. | Leave-on compositions containing cellulose materials |
| US9370478B2 (en) | 2012-11-09 | 2016-06-21 | Johnson & Johnson Consumer Inc. | Skin care compositions containing cotton and citrus-derived materials |
| WO2014074583A1 (en) * | 2012-11-09 | 2014-05-15 | Johnson & Johnson Consumer Companies, Inc. | Skin care compositions containing cotton and citrus-derived materials |
| US9549889B2 (en) | 2012-11-09 | 2017-01-24 | Johnson & Johnson Consumer Inc. | Rinse-off skin care compositions containing cellulosic materials |
| CN104780903B (en) * | 2012-11-09 | 2017-08-08 | 强生消费者公司 | The skin care compositions of material comprising cotton and from citrus |
| US9737473B2 (en) | 2012-11-09 | 2017-08-22 | Johnson & Johnson Consumer Inc. | Leave-on compositions containing cellulose materials |
| EP2907498A1 (en) * | 2014-02-13 | 2015-08-19 | Induchem Ag | Exfoliating cellulose beads and cosmetic uses thereof |
| JP2018118917A (en) * | 2017-01-24 | 2018-08-02 | 株式会社ダイセル | Scrubbing agent and skin cleansing composition |
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