JPS63214379A - Container made of synthetic resin - Google Patents
Container made of synthetic resinInfo
- Publication number
- JPS63214379A JPS63214379A JP62046672A JP4667287A JPS63214379A JP S63214379 A JPS63214379 A JP S63214379A JP 62046672 A JP62046672 A JP 62046672A JP 4667287 A JP4667287 A JP 4667287A JP S63214379 A JPS63214379 A JP S63214379A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- synthetic resin
- printing
- coat layer
- container
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 16
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 16
- 239000003973 paint Substances 0.000 claims abstract description 25
- 239000000178 monomer Substances 0.000 claims abstract description 6
- 229920005989 resin Polymers 0.000 claims abstract description 6
- 239000011347 resin Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims description 4
- 229920005992 thermoplastic resin Polymers 0.000 claims description 4
- -1 polypropylene Polymers 0.000 abstract description 5
- 239000004743 Polypropylene Substances 0.000 abstract description 3
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 3
- 229920001155 polypropylene Polymers 0.000 abstract description 3
- 238000004132 cross linking Methods 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011888 foil Substances 0.000 description 4
- 238000007747 plating Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 230000001678 irradiating effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 1
- 235000019646 color tone Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Wrappers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は外表面にメタリック感を現出した合成樹脂製容
器に関するものである。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a synthetic resin container with a metallic appearance on its outer surface.
〈従来の技術〉
合成樹脂製容器の表面にメタリック感を現出する手段と
して、従来も容器の表面に部分的に印刷をした後メッキ
を施す方法、熱転写箔加工法、パール塗装やホットスタ
ンプ等の加工を組み合わせてクリアコートする方法等が
開発されていた。<Prior art> Conventional methods for creating a metallic appearance on the surface of synthetic resin containers include printing partially on the surface of the container and then plating, thermal transfer foil processing, pearl coating, hot stamping, etc. A clear coating method was developed that combined these processes.
〈発明が解決しようとする問題点〉
然るに従来の前述の方法の内、部分的に印刷をした後メ
ッキを施す方法に於いてはこのメッキと印刷とを組み合
わせた場合にインクが変色し、かつ鮮明な色調が困難と
なり、又メッキと組み合わせる為に文字や絵柄のデザイ
ンに制限があり、更に２色のメタリック感を同時に表現
することが困難である等の問題があった。又熱転写箔加
工法に於いては転写箔に予め蒸着やパール印刷或いは文
字、絵柄を印刷したものを容器の表面に転写するが、表
面の強度が弱い為に後から特別のコート処理をしなけれ
ばならず、コスト高になると共に不良率が多い等の問題
があった。<Problems to be solved by the invention> However, among the conventional methods described above, in the method of partially printing and then plating, when this plating and printing are combined, the ink changes color and There were other problems, such as it was difficult to achieve clear color tones, there were restrictions on the design of letters and pictures due to the combination with plating, and it was also difficult to express the metallic feel of two colors at the same time. In addition, in the thermal transfer foil processing method, the transfer foil is vapor-deposited, pearl printed, or printed with letters and designs in advance and transferred to the surface of the container, but because the strength of the surface is weak, a special coating treatment is required afterwards. However, there were problems such as high cost and high defective rate.
更にパール塗装やホットスタンプを組み合わせてクリア
コートする方法もあるが、工程が複雑で作業性が悪く、
コスト高になると共に不良率が高く実用的でない等の問
題点があった。There is also a clear coat method that combines pearl painting and hot stamping, but the process is complicated and workability is poor.
There were problems such as high cost and high defective rate, making it impractical.
本発明は従来のこれ等の問題点に鑑み開発された全く新
規な技術に関するものである。The present invention relates to a completely new technique developed in view of these conventional problems.
く問題点を解決するための手段〉
本発明は合成樹脂製容器の表面に多官能性モノマー或い
は単官能性モノマー又は光重合性プレポリマーと熱可塑
樹脂を混合してなる架橋構造を持った紫外線硬化型塗料
を塗着すると共に紫外線を照射してこれを硬化してトッ
プコート層を形成し、更にこのトップコート層上にホッ
トスタンプ或いは印刷層を施すことを特徴とした合成樹
脂製容器である。Means for Solving the Problems> The present invention provides ultraviolet rays having a crosslinked structure formed by mixing a polyfunctional monomer, a monofunctional monomer, or a photopolymerizable prepolymer with a thermoplastic resin on the surface of a synthetic resin container. A synthetic resin container characterized by applying a curable paint and curing it by irradiating it with ultraviolet rays to form a top coat layer, and then applying a hot stamp or printing layer on the top coat layer. .
く作用〉 本発明は上述の如く、ＡＳ樹脂、ＡＢＳ樹脂。Effect〉 As mentioned above, the present invention uses AS resin and ABS resin.
ポリプロピレン樹脂、ユリア樹脂、フェノール樹脂、メ
ラミン樹脂等で形成された合成樹脂製容器の表面にホッ
トスタンプや印刷を施すことが可能な架橋構造を持った
紫外線硬化型塗料をトップコートし、更にこのトップコ
ート層の表面にホットスタンプと印刷とを夫々単独又は
組み合わせて施したので、合成樹脂製容器の表面にメタ
リック感を現出することが出来、かつホットスタンプ或
いは印刷層を容器表面のトップコート層に強固に固着せ
しめ、これ等のホットスタンプ或いは印刷層が容器の表
面から脱落することを防止することが出来る。The surface of the synthetic resin container made of polypropylene resin, urea resin, phenol resin, melamine resin, etc. is top coated with an ultraviolet curable paint with a crosslinked structure that allows hot stamping and printing. Since hot stamping and printing are applied to the surface of the coating layer, either singly or in combination, it is possible to create a metallic feel on the surface of the synthetic resin container. The hot stamp or printed layer can be firmly fixed to the surface of the container to prevent it from falling off the surface of the container.
更に本発明に於いてはトップコート層の材料に紫外線硬
化型塗料を用いたので、容器の表面にトップコートを施
した後でその表面に紫外線を照射することによって塗料
を直ちに９０％以上ゲル化して硬化させ、そのトップコ
ート層の表面にホットスタンプや印刷加工をすることが
出来る。Furthermore, in the present invention, since an ultraviolet curable paint is used as the material for the top coat layer, after applying the top coat to the surface of the container, by irradiating the surface with ultraviolet rays, the paint gels by more than 90% immediately. After curing, hot stamping or printing can be performed on the surface of the top coat layer.
〈実施例〉
本発明の一実施例を具体的に説明すると、先ず本発明に
於いてはＡＳ樹脂、ＡＢＳ樹脂、ポリプロピレン樹脂、
ユリア樹脂、フェノール樹脂、メラミン樹脂等の合成樹
脂材料を使用して化粧品。<Example> To specifically explain an example of the present invention, first, in the present invention, AS resin, ABS resin, polypropylene resin,
Cosmetics using synthetic resin materials such as urea resin, phenolic resin, and melamine resin.
薬品等の容器或いは壜のキャップ等の付属品容器を射出
成形する。Injection molding of containers for medicines and accessory containers such as bottle caps.
次にこの様にして成形した容器の表面にホットスタンプ
や印刷を施すことが可能な架橋構造を持った紫外線硬化
型塗料を所定の厚さにトップコートシ、続いてこのトッ
プコートした部分に紫外線を照射し、そのトップコート
を直ちにゲル化させて硬いトップコート層を形成する。Next, the surface of the container formed in this way is top-coated with a UV-curable paint that has a cross-linked structure that can be hot-stamped or printed, and then the top-coated area is coated with UV-curable paint. to immediately gel the top coat to form a hard top coat layer.
更にトップコート層の上に直接所定の文字、絵柄状のホ
ットスタンプ或いは印刷を施すか、或いはアンカーコー
ト層の上にアルミ蒸着層、熱乾燥型の中塗り層、トップ
コート層を夫々順に積層した上にホットスタンプ或いは
印刷を施すことによって本発明に係るメタリック感を有
する金属製品状の美麗で強度性を持った合成樹脂製容器
を製造することが出来る。Further, predetermined letters or pictures were hot-stamped or printed directly on the top coat layer, or an aluminum vapor-deposited layer, a heat-dried intermediate coat layer, and a top coat layer were laminated in order on the anchor coat layer. By applying hot stamping or printing on the container, it is possible to produce a beautiful and strong synthetic resin container in the form of a metallic product according to the present invention.
図により容器の表面にトップコート層、ホットスタンプ
或いは印刷を施す工程等について説明すると次の通りで
ある。The steps of applying a top coat layer, hot stamping or printing on the surface of the container will be explained with reference to the drawings.
第１図に於いて、１は合成樹脂製容器の一部断面拡大基
板であって、その基板ｌの上表面にはパール塗料が０．
５〜５％混入された紫外線硬化型塗料が塗布され、該塗
料が紫外線照射されて硬化したトップコート層２が積層
され、更にその上表面には所定の文字、絵柄等のホット
スタンプ及び印刷が模様層３として施され、全体として
メタリック感を有する容器が構成されている。In FIG. 1, reference numeral 1 denotes a partially enlarged cross-sectional substrate of a synthetic resin container, and the upper surface of the substrate 1 is coated with pearl paint.
An ultraviolet curable paint containing 5 to 5% of the mixture is applied, and a top coat layer 2, which is cured by irradiating the paint with ultraviolet rays, is laminated, and the top surface is further hot-stamped and printed with predetermined characters, patterns, etc. It is applied as a pattern layer 3, and the container as a whole has a metallic feel.
次に第２図はアクリル等の熱乾燥型の塗料にパール顔料
を混入したアンダーコート層２ａとホットスタンプ及び
印刷からなる模様層３との間に前述の如きパール顔料を
全く混入しない紫外線硬化型塗料のみによるトップコー
ト層４が介在されて構成されている。Next, Fig. 2 shows an ultraviolet curing type in which no pearl pigments as mentioned above are mixed between the undercoat layer 2a, which is a heat-drying paint such as acrylic mixed with pearl pigments, and the pattern layer 3, which is made of hot stamping and printing. A top coat layer 4 made of only paint is interposed therebetween.
更に第３図に於いては基板ｌの上表面に熱によって乾燥
する塗料又は紫外線硬化型塗料よりなるアンカーコート
層５．アルミニウム蒸着層６゜熱によって硬化する中塗
層７．トップコート層４及び模様Ｍ３を順に積層するこ
とによって構成している。Furthermore, in FIG. 3, an anchor coat layer 5. made of a heat-drying paint or an ultraviolet curing paint is coated on the upper surface of the substrate l. Aluminum vapor deposited layer 6. Intermediate coating layer cured by heat 7. It is constructed by sequentially laminating the top coat layer 4 and the pattern M3.
上述のトップコート層４に使用される架橋構造を有する
紫外線硬化型塗料の構成について具体例を示すと次の通
りである。A specific example of the structure of the ultraviolet curing paint having a crosslinked structure used for the above-mentioned top coat layer 4 is as follows.
（Ａ）多官能性上ツマ−７〜８８％
１．４−ブタンジオールジアクリレートＬ、Ｓ−ヘキサ
ンジオールジアクリレートジエチレングリコールジアク
リレート
ネオペンチルグリコールジアクリレートトリメチロール
プロパントリアクリレートペンタエリスリトールアクリ
レート
ジベンタエリスリトールへキサアクリレート（Ｂ）単官
能性七ノマー ０〜ＢＯ％
２−エチルへキシルアクリレート
２−ヒドロキシルエチルアクリレート
２−ヒドロキシルプロビルアクリレート（Ｃ）光重合性
プレポリマ一 〇〜８８％ポリエステルアクリレート
ポリウレタンアクリレート
エボキシアクリレート
ポリエーテルアクリレート
オリゴアクリレート
（Ｄ）熱可塑樹脂 ２〜３０％
アクリル系
スチレン系
ポリエステル系
ポリウレタン系
ビニル系
以上の成分をＪ：述の比率で配分した紫外線硬化型塗料
をトップコート層４に使用した処、紫外線を照射した際
に８０％以−ヒのゲル化が生じ直ちに硬化し、その上に
ホットスタンプ，印刷等を引き続いて施すことが出来た
．更に経時によるホットスタンプ，印刷密着のバラツキ
が無く、又紫外線照射のバラツキによる影響も無く，か
つ硬度を−ヒげてもホットスタンプや印刷が極めて良く
密着した．
これ等の作用効果は特に前記（Ｄ）の熱可塑樹詣を一定
量塗料の中に混入して構成した為に得られるものである
と考えられる．
特に本発明者等の実験によると、上述の配合による紫外
線硬化型塗料で構成されたトップコート層４の上表面に
アクリル系，塩素化ポリオレフィン系，塩酢ビ系等を接
着層として用いたホットスタンプホイル及びウレタン系
，エボキシ系の２液硬化型インキを使用すると密着性の
良いかつ表面硬度性の極めて良いメタリック感を持った
合成樹脂製容器を製造することが出来た．
く発明の効果〉
本発明に係る容器は上述の如き構成と作用とを有するの
で、容器の表面に積層された紫外線硬化型塗料を紫外線
の照射によって即時に硬化せしめることが出来、これに
よって作業性を高めることが出来、更にこの紫外線硬化
型塗料の中にパール塗料等を混入することによってメタ
リック感を簡単かつ確実に現出することが出来、かつこ
のトツブコート層の表面にホットスタンプ或いは印刷層
を強固に固着することが出来るので、容器の使用時にこ
れ等のホットスタンプや印刷によって形成された模様が
脱落することを防止することが出来る等の特徴を有する
ものである．(A) Polyfunctional upper 7-88% 1.4-butanediol diacrylate L, S-hexanediol diacrylate diethylene glycol diacrylate neopentyl glycol diacrylate trimethylol propane triacrylate pentaerythritol acrylate diventaerythritol hexa Acrylate (B) Monofunctional heptanomer 0-BO% 2-ethylhexyl acrylate 2-hydroxylethyl acrylate 2-hydroxylpropyl acrylate (C) Photopolymerizable prepolymer 1 0-88% Polyester acrylate Polyurethane acrylate Eboxy acrylate polyether Acrylate oligoacrylate (D) thermoplastic resin 2 to 30% Acrylic styrenic polyester polyurethane vinyl When an ultraviolet curable paint with the above components distributed in the proportions described above is used for the top coat layer 4, ultraviolet rays When it was irradiated, more than 80% gelation occurred and it immediately cured, making it possible to subsequently apply hot stamping, printing, etc. thereon. Furthermore, there was no variation in the adhesion of hot stamps and prints over time, there was no effect from variations in ultraviolet irradiation, and the hot stamps and prints adhered extremely well even if the hardness decreased. It is thought that these effects are particularly achieved by mixing a certain amount of the thermoplastic resin (D) into the paint. In particular, according to experiments conducted by the present inventors, it has been found that a hot coat coating using acrylic, chlorinated polyolefin, salt-vinyl acetate, etc. as an adhesive layer is applied to the top surface of the top coat layer 4, which is composed of an ultraviolet curable paint with the above-mentioned composition. By using stamp foil and two-component curing inks such as urethane and epoxy, we were able to manufacture synthetic resin containers with good adhesion, extremely good surface hardness, and a metallic feel. Effects of the Invention> Since the container according to the present invention has the above-described structure and function, the ultraviolet curable paint layered on the surface of the container can be instantly cured by irradiation with ultraviolet rays, thereby improving workability. Furthermore, by mixing pearl paint etc. into this ultraviolet curable paint, it is possible to easily and reliably create a metallic feel. Since it can be firmly fixed, it is possible to prevent the pattern formed by hot stamping or printing from falling off when the container is used.
第１図は本発明に係る容器の一部断面拡大図、第２図及
び第３図は夫々他例の説明図である．ｌは基板、２はパ
ールコート層、２ａはアンダーコート層、３は模様層、
４はトップコート層、５はアンカーコート層、６はアル
ミニウム蒸着層、７は中塗層である．
第１図FIG. 1 is an enlarged partial sectional view of a container according to the present invention, and FIGS. 2 and 3 are explanatory diagrams of other examples, respectively. 1 is a substrate, 2 is a pearl coat layer, 2a is an undercoat layer, 3 is a pattern layer,
4 is a top coat layer, 5 is an anchor coat layer, 6 is an aluminum vapor deposition layer, and 7 is an intermediate coat layer. Figure 1
Claims (1)
性モノマー又は光重合性プレポリマーと熱可塑樹脂を混
合してなる架橋構造を持った紫外線硬化型塗料を塗着す
ると共に紫外線を照射してこれを硬化してトップコート
層を形成し、更にこのトップコート層上にホットスタン
プ或いは印刷層を施すことを特徴とした合成樹脂製容器
。An ultraviolet curable paint with a crosslinked structure made by mixing a polyfunctional monomer, a monofunctional monomer, or a photopolymerizable prepolymer with a thermoplastic resin is applied to the surface of a synthetic resin container and irradiated with ultraviolet rays. A synthetic resin container characterized by curing the resin to form a top coat layer, and further applying a hot stamp or printing layer on the top coat layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62046672A JPS63214379A (en) | 1987-03-03 | 1987-03-03 | Container made of synthetic resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62046672A JPS63214379A (en) | 1987-03-03 | 1987-03-03 | Container made of synthetic resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63214379A true JPS63214379A (en) | 1988-09-07 |
Family
ID=12753854
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62046672A Pending JPS63214379A (en) | 1987-03-03 | 1987-03-03 | Container made of synthetic resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63214379A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5496587A (en) * | 1993-10-04 | 1996-03-05 | Cimmaster Sports Inc. | Method for printing a metallic appearance on moldable sheet plastic |
| JP2001034173A (en) * | 1999-07-19 | 2001-02-09 | Fuji Seal Inc | Article with thermosensitive label |
-
1987
- 1987-03-03 JP JP62046672A patent/JPS63214379A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5496587A (en) * | 1993-10-04 | 1996-03-05 | Cimmaster Sports Inc. | Method for printing a metallic appearance on moldable sheet plastic |
| JP2001034173A (en) * | 1999-07-19 | 2001-02-09 | Fuji Seal Inc | Article with thermosensitive label |
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