JPS6321263A - Water-resistant lightweight composition - Google Patents
Water-resistant lightweight compositionInfo
- Publication number
- JPS6321263A JPS6321263A JP16421486A JP16421486A JPS6321263A JP S6321263 A JPS6321263 A JP S6321263A JP 16421486 A JP16421486 A JP 16421486A JP 16421486 A JP16421486 A JP 16421486A JP S6321263 A JPS6321263 A JP S6321263A
- Authority
- JP
- Japan
- Prior art keywords
- water
- parts
- lightweight
- weight
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 36
- 239000000203 mixture Substances 0.000 title claims description 23
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 description 16
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 235000019353 potassium silicate Nutrition 0.000 description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 230000005484 gravity Effects 0.000 description 7
- 229910001562 pearlite Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 239000012188 paraffin wax Substances 0.000 description 6
- 239000011162 core material Substances 0.000 description 5
- 238000001723 curing Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 239000005871 repellent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000004568 cement Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000010451 perlite Substances 0.000 description 3
- 235000019362 perlite Nutrition 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 239000011494 foam glass Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000011490 mineral wool Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910018131 Al-Mn Inorganic materials 0.000 description 1
- 229910018182 Al—Cu Inorganic materials 0.000 description 1
- 229910018461 Al—Mn Inorganic materials 0.000 description 1
- 229910018575 Al—Ti Inorganic materials 0.000 description 1
- 229910002551 Fe-Mn Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 239000005332 obsidian Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000011863 silicon-based powder Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- -1 surfactants Chemical compound 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は製造工程時の反応熱を有効に利用して製造され
た、耐水性、防水性、撥水性を有する無機系の軽量組成
物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an inorganic lightweight composition having water resistance, waterproofness, and water repellency, which is manufactured by effectively utilizing the reaction heat during the manufacturing process. It is something.
従来より、軽量で防火性、防音性、断熱性を有する無機
系の軽量体の開発は数多く手がけられてきた。Many efforts have been made to develop lightweight inorganic bodies that are lightweight, fireproof, soundproof, and heat insulating.
例えば木毛セメント板、パーライトモルタル板、フオー
ムグラス板、ガラス繊維板、ロックウール板、水ガラス
系軽量板（発泡板やパーライト板等）等々が知られてい
る。For example, wood wool cement boards, perlite mortar boards, foam glass boards, glass fiber boards, rock wool boards, water glass lightweight boards (foam boards, perlite boards, etc.), and the like are known.
しかしながら木毛セメント板やパーライトモルタル板等
のセメント系のものは、強度が優れている反面、比重が
大きく、重量の点や断熱性の点で必ずしも満足するもの
ではなく、断熱材としての用途は限定されている。However, although cement-based materials such as wood wool cement boards and pearlite mortar boards have excellent strength, they have a large specific gravity, and are not necessarily satisfactory in terms of weight and insulation properties, so they cannot be used as insulation materials. Limited.
また、フオームグラス板は比重に対する圧縮強度（強度
比）に優れ、更に吸水率が小さいという点では特徴ある
軽量体であるが、その製造においては高温にて溶融して
発泡させるという工程を採るために、大型設備と大量の
熱エネルギーを必要とし、又、自由な大きさのものが作
り難いため用途的に限定される。In addition, foam glass plates are unique in that they have excellent compressive strength (strength ratio) to specific gravity and low water absorption, making them lightweight, but the manufacturing process involves melting and foaming at high temperatures. However, it requires large equipment and a large amount of thermal energy, and it is difficult to make products of any size, so the applications are limited.
ガラス繊維板やロックウール板は、無機繊維を無機又は
有機系のバインダーで成形した軽量でかつ断熱性に優れ
た断熱材であるが、繊維状であるがゆえに水を吸い込み
易く、−旦水を吸い込むと極端に断熱性が低下して、本
来の性能を発揮できないこととなる。Glass fiber boards and rock wool boards are lightweight and highly heat-insulating materials made of inorganic fibers molded with inorganic or organic binders. If it is inhaled, its insulation properties will be drastically reduced and it will not be able to exhibit its original performance.
一方、水ガラス系軽量板（発泡硬化させたもの、あるい
はパーライト等の軽量骨材を水ガラスをバインダーとし
て成形したもの等）においては、乾燥又は反応硬化させ
た水ガラスの結合強度が比較的強く、軽量でかつ高強度
の板が得られるため、多くの研究がなされており、一部
には製品化されているものもある。しかしながら、本質
的にはこの系では強いアルカリを含有しているために、
耐水性や白華（エフロ）等の点で欠点を有している。こ
れらの欠点に対しては水ガラスの変性や、硬化剤の研究
開発が種々行われてきているが、はぼ満足のいく耐水性
を得るまでには至っていないため、その用途は限定され
ている。On the other hand, in water glass-based lightweight plates (foam-hardened ones, or molded lightweight aggregates such as perlite with water glass as a binder), the bonding strength of dry or reaction-hardened water glass is relatively strong. Since it is possible to obtain lightweight and high-strength boards, a lot of research has been done on it, and some of it has even been commercialized. However, since this system essentially contains a strong alkali,
It has drawbacks in terms of water resistance and efflorescence. Various efforts have been made to modify water glass and research and develop hardening agents to address these shortcomings, but as satisfactory water resistance has not yet been achieved, its applications are limited. .
〔本発明が解決しようとする手段〕
本発明は上述したような軽量で防火性、断熱性を有し、
しかも耐水性、防火性、撥水性に優れた無機系の軽量組
成物を提供しようとするもので、特定の無機質硬化性組
成物に軽量骨材及びパラフィン系炭化水素を配合し、発
熱反応して硬化せしめることによってなし得たものであ
る。[Means to be solved by the present invention] The present invention is lightweight and has fireproof and heat insulating properties as described above,
Furthermore, the aim is to provide an inorganic lightweight composition with excellent water resistance, fire retardancy, and water repellency, by blending lightweight aggregate and paraffinic hydrocarbons into a specific inorganic curable composition, and performing an exothermic reaction. This was achieved by hardening it.
すなわち、本発明は型枠などに発熱硬化性を有する組成
物を充填して軽量体を製造するに際して、Ａ、水可溶性
アルカリ金属珪酸塩
Ｂ、金属粉末
Ｃ，パラフィン系炭化水素
り、軽量骨材
及び、必要に応じて水を混合する系からなりＤ成分１０
０容量部に対しくＡ＋Ｂ＋Ｃ十水）の土水量が２〜４０
容量部である硬化組成物を充填、硬化せしめることを特
徴とする。That is, when manufacturing a lightweight body by filling a mold or the like with a heat-curing composition, the present invention uses A, a water-soluble alkali metal silicate B, a metal powder C, a paraffinic hydrocarbon, and a lightweight aggregate. and D component 10, which consists of a system in which water is mixed as necessary.
The soil water volume of A + B + C (10 water) for 0 volume part is 2 to 40
It is characterized by filling and curing a volume portion of a curing composition.
このようにして得られる軽量体は、軽量でかつ圧縮強度
が高く防火性に優れており、更に従来の水ガラス系軽量
体に比較して耐水性、撥水性に著しく優れており、複合
パネルの耐火断熱芯材をはじめ、一般断熱材としても非
常に利用価値の高いものである。The lightweight body obtained in this way is lightweight, has high compressive strength, and has excellent fire retardant properties.It also has significantly superior water resistance and water repellency compared to conventional water glass-based lightweight bodies, and is suitable for composite panels. It is extremely useful as a general insulation material, including as a fireproof insulation core material.
以下本発明の内容について詳細に説明する。The contents of the present invention will be explained in detail below.
本発明において、Ａ成分としては水可溶性アルカリ金属
珪酸塩を使用する。これを他の原料物質と混合すること
で強度の優れた硬化体を得ることができる。このＡ成分
を構成するアルカリ成分としては、例えば、リチウム、
ナトリウム、カリウム、ルビジウム等のアルカリ金属を
例示できるが、特にナトリウム、カリウムの場合は安価
で入手し易く、望ましい。In the present invention, a water-soluble alkali metal silicate is used as the A component. By mixing this with other raw materials, a cured product with excellent strength can be obtained. Examples of the alkaline components constituting component A include lithium,
Examples include alkali metals such as sodium, potassium, and rubidium, and sodium and potassium are particularly desirable because they are inexpensive and easily available.
又、Ａ成分は水溶性である限り、その組成やアルカリ物
質とＳｉｎ、とのモル比には制限されるものではない。Further, as long as the A component is water-soluble, there are no restrictions on its composition or the molar ratio of the alkaline substance to Sin.
なお、本発明ではその形態は液状、又は乾燥粉末状いず
れでも良い。In the present invention, the form may be either liquid or dry powder.
次にＢ成分としては金属粉末を使用し、各種の金属元素
及び金属合金又は金属間化合物が使用できる。金属元素
としては１７周期律表のＩＢ、ＩＩＢ、ｎＢ、Ｉ［［Ａ
、ＩＢ、ＩＶＡ、ＩＶＢ、ＶＡ、ＶＢ。Next, as component B, a metal powder is used, and various metal elements, metal alloys, or intermetallic compounds can be used. Metal elements include IB, IIB, nB, I[[A
, IB, IVA, IVB, VA, VB.
ＶＩＢ、■Ｂおよび■族に属するものが好ましく、係る
金属元素としてはＣｒｓ Ｍｎ、Ｔｉｓ Ｚｎ。Those belonging to the VIB, ①B and ① groups are preferred, and examples of such metal elements include Crs Mn and Tis Zn.
■、Ｓ ｉ−、Ｇ ｅ ％ Ｓ ｂ ＳＣＯ％ Ｎ ｔ
、 Ｃｕ −。■, S i-, G e % S b SCO% N t
, Cu-.
ＡＩ、Ｃａ等が例示できる。特にＴｉ、Ｚｒ、■、Ａｌ
、Ｓ ｉｓ Ｇｅ、Ｓｂ、Ｚｎ等は望ましいものである
。合金ないし金属間化合物（金属相互間、もしくは金属
と非金属との化学結合体）の代表的なものを例示すれば
、Ａｌ−３ｔ、Ａｌ−Ｔｉ、Ａ ｌ−Ｍｎ、Ａｌ−Ｃｕ
、、Ｚｎ−３゜Ｚｎ−３ｎ、 Ｃｕ−３ｉｓＦｅ−３
ｉ。Examples include AI and Ca. Especially Ti, Zr, ■, Al
, S is Ge, Sb, Zn, etc. are desirable. Representative examples of alloys or intermetallic compounds (chemical combinations between metals or between metals and non-metals) include Al-3t, Al-Ti, Al-Mn, Al-Cu.
,,Zn-3゜Zn-3n, Cu-3isFe-3
i.
Ｆｅ−Ｍｎ、Ｓ １−Ｎｉ５ Ｃｏ−３ｂ等が挙げられ
る。これらの金属粉末は通常１種又は２種以上を微粉末
の形態で使用する。Examples include Fe-Mn, S1-Ni5Co-3b, and the like. One or more of these metal powders are usually used in the form of fine powder.
Ｃ成分としてはパラフィン系炭化水素を使用するもので
、特に融点が４０℃〜９５℃のものが例示される。また
その形態としては粉末状若しくはエマルション状態のも
のが望ましい。Paraffinic hydrocarbons are used as component C, particularly those having a melting point of 40°C to 95°C. Further, it is desirable that the form thereof be in the form of a powder or an emulsion.
Ｄ成分としては、軽量骨材を使用する。その例として天
然鉱物の発泡又は膨張した物質で膨張パーライト（単に
パーライトと呼ばれる場合がある）。膨張頁岩、膨張バ
ーミキュライト、軽石、シラスバルーン等の他、シリカ
ゲルの発泡体、シリカバルーン、ガラスバルーン、各種
スラグ造粒発泡物、粘土鉱物を造粒して、発泡させたも
の等の人工軽量骨材を含む。これらの中で特に気泡の独
立性が高く、より軽量性に冨み、球状を呈するものが好
ましい。例えば黒曜石系パーライト、シラスバルーン、
シリカゲル発泡体、ガラスバルーン等が例示できる。As component D, a lightweight aggregate is used. An example is expanded pearlite (sometimes simply called pearlite), which is a foamed or expanded substance of natural minerals. In addition to expanded shale, expanded vermiculite, pumice, shirasu balloons, etc., artificial lightweight aggregates such as silica gel foams, silica balloons, glass balloons, various slag granulated foams, and clay minerals granulated and foamed. including. Among these, those that have high cell independence, are more lightweight, and have a spherical shape are particularly preferred. For example, obsidian pearlite, shirasu balloon,
Examples include silica gel foam and glass balloons.
上記の如く本発明に使用する組成物は上記成分より成る
が、その配合比率はＡ成分の固形分の１００重量部に対
して、Ｂ成分２〜１００重量部、Ｃ成分２〜５０重量部
、及び必要に応じて水を適量混合したもの（Ａ＋Ｂ十Ｃ
＋水）とＤ成分の量との比率はＤ成分１００容量部に対
して（Ａ十Ｂ＋Ｃ土水）合計成分を２〜４０容量部とす
るものである。As mentioned above, the composition used in the present invention consists of the above-mentioned components, and the blending ratio is 2 to 100 parts by weight of component B, 2 to 50 parts by weight of component C, per 100 parts by weight of the solid content of component A. and a suitable amount of water mixed as necessary (A+B1C)
The ratio of the amount of component D to the amount of component D is such that the total component (A + water) and the amount of component D is 2 to 40 parts by volume (A + water) and 100 parts by volume of component D.
Ａ成分に対し、Ｂ成分が２重量部より少ない場合は、発
熱反応が弱く、Ｃ成分であるパラフィン系炭化水素が充
分に熔融するまでには至らないため、撥水性が均一に出
す、又、Ａ成分の硬化反応も進まないので耐水性が不十
分となる。一方、１００重量部より多くなると、極端に
反応が早くかつ激しくなるので製造作業上困難をきたし
、又、軽量体内部気泡が極めてポーラスかつ不均一にな
り、強度等の物性が良くない。If the amount of component B is less than 2 parts by weight with respect to component A, the exothermic reaction will be weak and the paraffinic hydrocarbon component C will not be sufficiently melted, so water repellency will not be uniform. The curing reaction of component A also does not proceed, resulting in insufficient water resistance. On the other hand, if the amount exceeds 100 parts by weight, the reaction becomes extremely fast and violent, which causes difficulties in manufacturing operations, and the air bubbles inside the lightweight body become extremely porous and non-uniform, resulting in poor physical properties such as strength.
Ｃ成分が２重量部以下では本来の目的であるところの耐
水性、撥水性をもった軽量体を得ることができない。又
、５０重量部以上では可燃性組成含有比率が相対的に大
きくなるため、防火性能が失われるので望ましくない。If the C component is less than 2 parts by weight, a lightweight body with water resistance and water repellency, which is the original objective, cannot be obtained. Moreover, if it exceeds 50 parts by weight, the content ratio of the combustible composition becomes relatively large, resulting in a loss of fire protection performance, which is not desirable.
又、本発明に使用されるパラフィン系炭化水素は、その
融点が４０℃〜９５℃の範囲内にあるものが望ましい。Further, the paraffinic hydrocarbon used in the present invention desirably has a melting point within the range of 40°C to 95°C.
例えば融点が４０℃より低いものは、夏場など高い気温
下になった場合にパラフィンの軟化等が生じるため、取
扱い上の汚れや物性上の低下が見られるため好ましくな
い。又、融点が９５℃以上のものは、当発明の反応過程
で反応熱によるパラフィン熔解が不十分のままで、撥水
効果にバラツキを生じるようになるので望ましくない。For example, those with a melting point lower than 40° C. are undesirable because paraffin softens when exposed to high temperatures such as in summer, resulting in stains during handling and deterioration in physical properties. Moreover, those having a melting point of 95° C. or higher are not desirable because paraffin melting due to reaction heat remains insufficient during the reaction process of the present invention, resulting in variations in water-repellent effect.
又、用いられるパラフィン系炭化水素の形態は粉末状も
しくは水分散型エマルション状のいずれかであっても良
い。例えば、粉末パラフィン系炭化水素の場合、その粒
径は細かな方が良く、粗粒もしくは塊状では分散に偏り
が生じるので不適当であり、通常は粒径がｌ ｖｓｖａ
以下のものが望ましい。Further, the paraffinic hydrocarbon used may be in the form of either a powder or a water-dispersed emulsion. For example, in the case of powdered paraffinic hydrocarbons, the finer the particle size, the better; coarse particles or lumps are unsuitable because they cause uneven dispersion, and usually the particle size is l vsva
The following are desirable.
上記のいわゆる結合材成分（Ａ４−Ｂ＋Ｃ十水土水量が
Ｄ成分が１００容量部に対して２容量部を下回る場合に
は、軽量骨材同士を十分に結合するまでには至らず、所
望の強度をもった軽量体を得ることはできない。又、４
０容量部を超えた量を入れると、軽量体内部に不均一な
空洞を生じ、断熱性の低下、強度の低下等が見られる。If the above-mentioned so-called binder component (A4-B+C) is less than 2 parts by volume per 100 parts by volume of component D, the lightweight aggregates will not be sufficiently bound together, and the desired strength will not be achieved. It is not possible to obtain a lightweight body with 4.
If the amount exceeds 0 parts by volume, uneven cavities will be created inside the lightweight body, resulting in a decrease in heat insulation and strength.
本発明組成物の製造方法は、成分（Ａ＋Ｂ＋Ｃ＋水）と
軽量骨材であるＤ成分を均一に混合して、板状、ブロッ
ク状等の型枠に充填して硬化させるものである。その場
合、それぞれの成分の混合順序は反応に支障のない限り
、これにこだわるものではない。又、場合によっては反
応促進のため、材料自体を加温したり、あるいは充虜後
全体を加温することも可能である。又、これらの基本成
分に対して、例えばりん酸アルミ、酸化亜鉛、アルミナ
セメント等の水可溶性アルカリ金属珪酸塩の硬化剤や、
炭酸カルシウム、ケイ砂、粘土等の粉末増量材、界面活
性剤等の添加剤、繊維状物質等の強度補強剤等も配合で
きる。又、パネル芯材としてハニカムコアのような中芯
材との併用もできる。The method for producing the composition of the present invention involves uniformly mixing the components (A+B+C+water) and component D, which is a lightweight aggregate, and filling the mixture into a plate-shaped, block-shaped, etc. formwork and hardening the mixture. In that case, the mixing order of each component is not limited as long as it does not interfere with the reaction. In some cases, it is also possible to heat the material itself, or to heat the entire material after filling, in order to accelerate the reaction. In addition, in addition to these basic ingredients, hardening agents for water-soluble alkali metal silicates such as aluminum phosphate, zinc oxide, and alumina cement,
Powder fillers such as calcium carbonate, silica sand, and clay, additives such as surfactants, and strength reinforcing agents such as fibrous substances can also be blended. Moreover, it can also be used in combination with a core material such as a honeycomb core as a panel core material.
本発明において特筆すべき点は、反応硬化過程において
生じる自己発熱により配合中の水分が蒸発すると同時に
、内部に添加しているＣ成分のパラフィン系炭化水素が
溶融することにより、内部及び表面共に、その軽量体全
体が均一に撥水性を帯びた構造となった耐水性の軽量体
が得られるのである。What is noteworthy about the present invention is that the moisture in the compound evaporates due to the self-heating generated during the reaction curing process, and at the same time, the paraffinic hydrocarbon of component C added inside melts, both inside and on the surface. A water-resistant lightweight body can be obtained in which the entire lightweight body has a structure that is uniformly water-repellent.
従来パラフィンワックスを内部に添加して、第水性を持
たせる方法は石膏建材等で試みられている。しかし、そ
れらにおいてはただ単に添加するのみでは十分でなく、
より撥水性を持たせるために硬化後に後処理として、添
加されたパラフィン系炭化水素の融点以上の温度で加熱
処理するという付加工程が必要となる。しかも、後工程
である加熱処理は被熱物が薄物であれば比較的内部まで
加熱され易いが、厚物又はブロック状のものではそれら
の内部まで均一に加温しようとすると、極めて多大な時
間と熱エネルギーを消耗することになり実用的でない。Conventionally, a method of adding paraffin wax inside to impart water-like properties has been attempted with gypsum building materials and the like. However, in these cases, it is not enough to simply add
In order to make the resin more water repellent, an additional step of heat treatment at a temperature higher than the melting point of the added paraffinic hydrocarbon is required as a post-treatment after curing. Moreover, in the heat treatment that is a post-process, if the object to be heated is thin, it is relatively easy to heat it to the inside, but if it is thick or block-shaped, it takes an extremely long time to uniformly heat the inside of the object. This wastes thermal energy and is not practical.
まして断熱性を有している軽量体となると更に内部へ熱
が伝わり難くなるため、なお史実用性に乏しくなる。そ
うした点で本発明では、自己発熱反応を積極的に利用す
ることにより、パラフィン系炭化水素を無機軽量体の内
部で一体溶融させるため、内外部共、はぼ均一性をもっ
た撥水性軽量体を、後加熱処理という余分な工程を必要
とせずに、混合、充填、放置という簡単な操作で作成で
きる点でその有効性は極めて大きいといえる。Furthermore, if the body is lightweight and has heat insulation properties, it becomes even more difficult for heat to be transferred to the inside, making it even less practical. In this respect, in the present invention, the paraffinic hydrocarbon is integrally melted inside the inorganic lightweight body by actively utilizing the self-heating reaction, so the water-repellent lightweight body is extremely uniform both inside and outside. It can be said that it is extremely effective in that it can be prepared by simple operations of mixing, filling, and leaving without the need for an extra step of post-heating treatment.
以上のように本発明によって得られる軽量体は配合比に
よっても異なるが、比重が ０．０５〜０．３程度の軽
さに調整でき、なおかつ耐水性、撥水性を有した防火断
熱材料となる。そのため従来水ガラス系では使用できな
かった水気等のある箇所への応用ができるようになった
。この軽量体は単体で断熱材として使われる他に、種々
の表面化粧板、例えば化粧石綿スレート板、着色亜鉛鉄
板、着色アルミニウム板等と組合せたサンドインチ構造
パネルの防火、耐火芯材としても使用される。As described above, the lightweight body obtained by the present invention can be adjusted to have a specific gravity of about 0.05 to 0.3, although it varies depending on the blending ratio, and is a fireproof and insulating material that is water resistant and water repellent. . Therefore, it has become possible to apply it to areas with moisture, etc., which could not be used with conventional water glass systems. In addition to being used alone as a heat insulating material, this lightweight body can also be used as a fireproof and fireproof core material for sand-inch structural panels in combination with various surface decorative boards, such as decorative asbestos slate boards, colored galvanized iron boards, and colored aluminum boards. be done.
以下、実施例を挙げ本発明の詳細な説明する。 Hereinafter, the present invention will be described in detail with reference to Examples.
なお、各実施例において使用するＡ、Ｂ、Ｃ，Ｄ成分と
する物質を下記表−１に示す。また、各実施例及び比較
例の結果を表−２に示す。The substances used as components A, B, C, and D in each example are shown in Table 1 below. Further, the results of each example and comparative example are shown in Table 2.
また、各実施例によって得られる軽量体試料の諸物性試
験は下記の方法により行ったものである。なお、試験時
条件は温度２０℃、相対湿度６５％である。Further, various physical property tests of the lightweight body samples obtained in each example were conducted by the following methods. Note that the test conditions were a temperature of 20° C. and a relative humidity of 65%.
■）かさ比重：ＪＩＳ Ａ １１６１に準する。■) Bulk specific gravity: According to JIS A 1161.
２）吸水率 ：ＪＩＳ Ａ １１６１に準する。2) Water absorption rate: According to JIS A 1161.
重量％で示す。Expressed in % by weight.
３）圧縮強度：ＪＩＳ Ａ １１６１に準する。3) Compressive strength: According to JIS A 1161.
ｋｇｆ／−で示す。Expressed in kgf/-.
〔実施例１〕
軽量組成物の作成にあたっては次のような工程を採った
。[Example 1] The following steps were taken to create a lightweight composition.
固形分４０％、Ｓ ｉｏ、／Ｎ ａｚｏモル比２．１の
珪酸ソーダ水溶液（Ａ、−１）２５０重量部に対し、金
属アルミニウム粉末（１３−１）を３０重量部、融点が
６８℃のパラフィンワックス粉末（ｃ−１）を１０重量
部、水を５０重量部を計量してポリ容器に投入し、プロ
ペラ式３枚羽根を有したミキサーで約１分量線合してス
ラリーペーストを得た。このペースト１０容量部に対し
て比重０．１３、粒径２〜４１１のパーライト（Ｄ）を
１００容量部投入して２分量線合する。その混合物を内
寸法４０酊×６００鶴Ｘ９０（Ｉｎで、上の押え板に孔
を有する型枠に均一に投入して放置したところ、約２０
分後に発熱して孔より水蒸気が放出した。放冷後、脱型
してそれより４０ｆｉ×４０℃ｍＸ ４９ｍの大きさに
切り出し、前述の方法によりかさ比重と圧縮強度、吸水
率を測定した。To 250 parts by weight of a sodium silicate aqueous solution (A,-1) with a solid content of 40% and a Sio,/N azo molar ratio of 2.1, 30 parts by weight of metallic aluminum powder (13-1) with a melting point of 68 ° C. 10 parts by weight of paraffin wax powder (c-1) and 50 parts by weight of water were weighed and put into a plastic container, and the mixture was mixed in about 1 portion in a propeller-type mixer with three blades to obtain a slurry paste. . To 10 parts by volume of this paste, 100 parts by volume of pearlite (D) having a specific gravity of 0.13 and a particle size of 2 to 411 are added and mixed into two parts. When the mixture was uniformly poured into a mold with internal dimensions of 40mm x 600mm x 90mm (in) and had holes in the upper presser plate and left to stand, it turned out that about 20mm
After a few minutes, heat was generated and water vapor was released from the hole. After cooling, the mold was demolded and cut into a size of 40 fi x 40°C m x 49 m, and the bulk specific gravity, compressive strength, and water absorption rate were measured using the methods described above.
〔実施例２〕
Ｂ成分として金属アルミニウム粉末のかわりに金属珪素
粉末（１３−２）を７５重量部とし、（Ｃ−１）を３重
量部に配合をかえて実施例１と同様の方法で軽量板を作
成した。[Example 2] In the same manner as in Example 1, the B component was changed to 75 parts by weight of metal silicon powder (13-2) instead of metal aluminum powder and 3 parts by weight of (C-1). I made a lightweight board.
〔実施例３〕
（Ａ−２）を２５０重量部とし、（Ｂ−２）を５０重量
部、Ｃ成分としてパラフィンワックスエマルション（Ｃ
−２）を２０重量部秤量して混合したのち、それらの混
合物１５容量部に対しくＤ）を１００容量部を混合して
軽量板を作成した。[Example 3] (A-2) was 250 parts by weight, (B-2) was 50 parts by weight, and C component was a paraffin wax emulsion (C
After weighing and mixing 20 parts by weight of -2), 15 parts by volume of the mixture was mixed with 100 parts by volume of D) to prepare a lightweight board.
〔実施例４〕
（Ａ−２）を２５０重量部とし、（Ｂ−２）を４０重量
部、Ｃ成分としてパラフィンワックスエマルション（Ｃ
−２）を１０重量部秤量して混合／り
したのち、それらの混合物３０容量部に対しくＤ）を１
００容量部を混合して軽量板を作成した。[Example 4] (A-2) was 250 parts by weight, (B-2) was 40 parts by weight, and C component was paraffin wax emulsion (C
- 10 parts by weight of D) are weighed and mixed, and 1 part D) is added to 30 parts by volume of the mixture.
A lightweight board was prepared by mixing 00 parts by volume.
〔比較例１〕
パラフィン系炭化水素を入れない配合で軽量体を作成し
た。（Ａ−２）２５０重量部に対しくＢ−２）５０重量
部混合したもの３０容量部に対し、ｌＯＯ容量部の（Ｄ
）を混合して軽量体を作り物性試験を行ったところ吸水
率が大きく、かつ表面より白華現象が見られた。[Comparative Example 1] A lightweight body was created using a formulation that did not contain paraffinic hydrocarbons. (D
) was mixed to make a lightweight body and a physical property test was conducted, and it was found that the water absorption rate was high and efflorescence was observed from the surface.
〔比較例２〕
Ａ成分の珪酸カリウム水溶液（Ａ、−２）２５０重量部
に対し、（Ｂ−１）を１重量部、（Ｃ−１）を２０重量
部配合したもの２０容量部に対し、（Ｄ）を１００容量
部加えて同様の方法で軽量板を作成した。[Comparative Example 2] For 250 parts by weight of potassium silicate aqueous solution (A, -2) of component A, 1 part by weight of (B-1) and 20 parts by weight of (C-1) were mixed. , (D) were added in the same manner to prepare a lightweight board.
発熱が不十分で、水につけると部分的に溶解した。It did not generate enough heat and partially dissolved when immersed in water.
〔比較例３〕
（Ｂ−１）を１００重量部として他は実施例４と同様の
配合とした。（Ａ−２＋Ｂ−１＋Ｃ−１）の混合時点で
急激な発熱反応が生じて（Ｄ）と混合できなかった。[Comparative Example 3] The same formulation as in Example 4 was used except that (B-1) was 100 parts by weight. At the time of mixing (A-2+B-1+C-1), a rapid exothermic reaction occurred and it was not possible to mix it with (D).
次に（Ａ−２）を５℃まで冷却して反応を遅らせて混合
し、それら混合物２ｏ容量部に対して（Ｄ）を１００容
量部混合してただちに型に入れた。反応後、脱型したと
ころ、内部に不均一な大きい空洞ができていた。Next, (A-2) was cooled to 5°C to delay the reaction and mixed, and 100 parts by volume of (D) was mixed with 20 parts by volume of the mixture, and the mixture was immediately put into a mold. When the mold was demolded after the reaction, large, non-uniform cavities were found inside.
〔比較例４〕
（Ａ−２）を２５０重量部とし、（１３−２）を５０重
量部、（Ｃ−１）を１０重量部、水を５０重量部混合し
たペース）１．５容量部に対しくＤ）を１００容量部混
合した。混合状態はパーライト（Ｄ）表面に混合ペース
トが付着している状態であった。そのまま型に投入して
反応発熱の後、脱型しようとしたが、パーライト間の結
合が弱く、脱型時に崩れた。そのため物性の測定は不能
であった。[Comparative Example 4] 1.5 parts by volume (paste prepared by mixing 250 parts by weight of (A-2), 50 parts by weight of (13-2), 10 parts by weight of (C-1), and 50 parts by weight of water) In contrast, 100 parts by volume of D) were mixed. The mixed state was such that the mixed paste was attached to the surface of the pearlite (D). I poured it into a mold as it was and tried to remove it from the mold after the reaction generated heat, but the bonds between pearlite were weak and collapsed during demolding. Therefore, it was impossible to measure the physical properties.
〔比較例５〕
実施例８と異なり （Ａ−２＋Ｂ−２＋Ｃ−１＋水）の
混合ペーストの量５０容量部に増やして、それに対して
（Ｄ）を１００容量部混合した。型に詰めて軽量体を作
成しようとしたが、反応に伴い不均一な空間が内部に生
じた。脱型時の板の状態で比重は測定したが、あまりに
不均一なため測定できなくなった。[Comparative Example 5] Unlike Example 8, the amount of the mixed paste (A-2+B-2+C-1+water) was increased to 50 parts by volume, and 100 parts by volume of (D) was mixed therewith. An attempt was made to create a lightweight body by stuffing it into a mold, but the reaction created an uneven space inside. The specific gravity was measured in the state of the plate at the time of demolding, but it was impossible to measure because it was too uneven.
７（以上）7 (or more)
Claims (1)
Ｃ＋水）を、 Ｄ、軽量骨材１００容量部 に対して、２〜４０容量部を混合して硬化したことを特
徴とする耐水性軽量組成物。[Scope of Claims] A, based on 100 parts by weight of solid content of water-soluble alkali metal silicate, B, 2 to 100 parts by weight of metal powder, C, 2 to 50 parts by weight of paraffinic hydrocarbon, if necessary. Mixture (A+B+) with an appropriate amount of water
A water-resistant lightweight composition characterized by being cured by mixing 2 to 40 parts by volume of (C+water) with 100 parts by volume of D, lightweight aggregate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16421486A JPH0798698B2 (en) | 1986-07-11 | 1986-07-11 | Water resistant lightweight composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16421486A JPH0798698B2 (en) | 1986-07-11 | 1986-07-11 | Water resistant lightweight composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6321263A true JPS6321263A (en) | 1988-01-28 |
| JPH0798698B2 JPH0798698B2 (en) | 1995-10-25 |
Family
ID=15788834
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16421486A Expired - Lifetime JPH0798698B2 (en) | 1986-07-11 | 1986-07-11 | Water resistant lightweight composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0798698B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11263661A (en) * | 1998-01-13 | 1999-09-28 | Nato Kenkyusho:Kk | Hydraulic silica-based binder, and water and heat resistant solidified body |
-
1986
- 1986-07-11 JP JP16421486A patent/JPH0798698B2/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11263661A (en) * | 1998-01-13 | 1999-09-28 | Nato Kenkyusho:Kk | Hydraulic silica-based binder, and water and heat resistant solidified body |
| JP4557191B2 (en) * | 1998-01-13 | 2010-10-06 | 株式会社ナトー研究所 | Hydraulic silica binder and water / heat resistant solidified body |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0798698B2 (en) | 1995-10-25 |
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| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| EXPY | Cancellation because of completion of term |