JPS6317971A - Yeast fungal pigment and granulation thereof - Google Patents
Yeast fungal pigment and granulation thereofInfo
- Publication number
- JPS6317971A JPS6317971A JP16272686A JP16272686A JPS6317971A JP S6317971 A JPS6317971 A JP S6317971A JP 16272686 A JP16272686 A JP 16272686A JP 16272686 A JP16272686 A JP 16272686A JP S6317971 A JPS6317971 A JP S6317971A
- Authority
- JP
- Japan
- Prior art keywords
- yeast
- pigment
- parts
- fine particle
- particle powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 240000004808 Saccharomyces cerevisiae Species 0.000 title claims abstract description 83
- 239000000049 pigment Substances 0.000 title claims abstract description 47
- 230000002538 fungal effect Effects 0.000 title abstract 3
- 238000005469 granulation Methods 0.000 title description 5
- 230000003179 granulation Effects 0.000 title description 5
- 230000019612 pigmentation Effects 0.000 title 1
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 claims abstract description 79
- 239000000843 powder Substances 0.000 claims abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 25
- 239000002904 solvent Substances 0.000 claims abstract description 11
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims description 20
- 239000010419 fine particle Substances 0.000 claims description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 13
- 241000894006 Bacteria Species 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims description 2
- 239000000945 filler Substances 0.000 abstract description 15
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 230000003287 optical effect Effects 0.000 abstract description 5
- 239000002537 cosmetic Substances 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 17
- 239000006185 dispersion Substances 0.000 description 17
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 17
- 210000004027 cell Anatomy 0.000 description 11
- 230000001580 bacterial effect Effects 0.000 description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 235000019441 ethanol Nutrition 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000009826 distribution Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000001000 micrograph Methods 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 210000005253 yeast cell Anatomy 0.000 description 3
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 235000003534 Saccharomyces carlsbergensis Nutrition 0.000 description 2
- 241001123227 Saccharomyces pastorianus Species 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001542272 Endomycetaceae Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 229920001503 Glucan Polymers 0.000 description 1
- 229920000057 Mannan Polymers 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- -1 acetone Chemical class 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000034303 cell budding Effects 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 210000002421 cell wall Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- LUEWUZLMQUOBSB-GFVSVBBRSA-N mannan Chemical class O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](O[C@H]3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-GFVSVBBRSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000003904 phospholipids Chemical class 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000004252 protein component Nutrition 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011122 softwood Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
Description
【発明の詳細な説明】
（Ａ）産業上の利用分野
本発明は酵母菌を核として、その周囲に微粒子粉体を付
着させ、種々の機能を持つ顔料（以下酵母菌顔料という
）を得るもので、新らしい顔料および新らしい造粒方法
に関するものである。この酵母菌顔料は製紙用の光学的
特性等を付与する填料もしくは顔料、ＰＰＣ用のトナー
、化粧品、その他は寸均−な粒子径の粉体を必要とする
産業に有用である。Detailed Description of the Invention (A) Industrial Field of Application The present invention uses yeast as a core and attaches fine particle powder around it to obtain pigments with various functions (hereinafter referred to as yeast pigments). This article relates to a new pigment and a new granulation method. This yeast pigment is useful as a filler or pigment that imparts optical properties for paper manufacturing, toner for PPC, cosmetics, and other industries that require powder with a uniform particle size.
（Ｂ）従来の技術
日常我々の身の廻りでは種々の粉体もしくは顔料が使わ
れている。(B) Conventional Technology Various powders or pigments are used in our daily life.
例えば、製紙用には、印刷適性、光学的特性等を与える
ため、白色顔料を多く用いてきた。即ち、填料として、
カオリン、タルク、炭酸カルシウム、酸化チタン等。こ
れらは、平均粒子径がサブミクロンから２〜３ミクロン
とかなり微細な粉体が多く、また粒度分布が狭いものも
広いものもある。For example, white pigments have been widely used in paper manufacturing to provide printability, optical properties, and the like. That is, as a filler,
Kaolin, talc, calcium carbonate, titanium oxide, etc. Many of these powders are quite fine, with average particle diameters ranging from submicrons to 2 to 3 microns, and some have narrow particle size distributions while others have wide particle size distributions.
また密度は酸化チタンが約４、それ以外は約２．５程度
でパルプの約１．５に比べかなり大きい。このような微
細かつ密度の大きい顔料を紙の填料として用い、その充
填された状態を顕微鏡で観察すると、紙のフェルトサイ
ド（表側）には顔料の存在が見られるが、ワイヤーサイ
ド（裏側）には填料が流失するため顔料は極くわずかし
か見られない。Further, the density of titanium oxide is about 4, and the density of other materials is about 2.5, which is considerably higher than that of pulp, which is about 1.5. When such fine and dense pigments are used as paper fillers and the filled state is observed under a microscope, the presence of pigments can be seen on the felt side (front side) of the paper, but on the wire side (back side). Since the filler is washed away, only a small amount of pigment can be seen.
これは抄紙工程において、一部の填料がワイヤーを通し
て流失していくことによるもので、填料の歩留りが低下
するのみならず所期の特性も十分発現できないことにな
る。This is because some of the filler is washed away through the wire during the papermaking process, which not only lowers the filler yield but also prevents the desired properties from being fully expressed.
紙を構成する個々のパルプ繊維は、幅数子μ、長さ数ｍ
ｍのものであり、これらのつくる網目構造を歩留り良く
充填し、更にはワイヤーからの流失を防ぐには１０μ以
下（例えば５μ程度）の粒子径の良く揃った顔料か好ま
しい。これに対する改良方法として、あらかじめ凝集剤
を用いて填料を成る大きさに凝集させ、その後抄紙原料
と混合する方法（プレ凝集）が提案されている。これに
より歩留りは向上するが、凝集粒子のコントロールが難
かしいことなど必ずしも所期の特性が得られるとは言え
ない。The individual pulp fibers that make up paper have a width of several μ and a length of several meters.
Pigments with well-uniform particle diameters of 10 μm or less (for example, about 5 μm) are preferable in order to fill the network structure formed by these pigments with a good yield and prevent them from being washed away from the wire. As an improvement method for this, a method has been proposed in which the filler is agglomerated in advance to a certain size using an aggregating agent and then mixed with the papermaking raw material (pre-agglomeration). Although this improves the yield, it cannot necessarily be said that the desired characteristics can be obtained because it is difficult to control aggregated particles.
また、ＯＡの主要な機器で必るＰＰＣにおいてはトナー
が用いられている。トナーは一般に５〜１０μの粒子か
ら成っておりその粒子径および粒度分布がコピーの画質
（品質）に重大な影響を、与える。Furthermore, toner is used in PPC, which is necessary for major OA equipment. Toner generally consists of particles of 5 to 10 microns, and the particle size and particle size distribution have a significant effect on the image quality of the copy.
このようなトナーを作るのには、一般にカーボンブラッ
ク等着色顔料、熱可塑性樹脂、添加剤等を溶融させ、そ
の溶融塊を機械的に砕いて作るもので、所望の粒度分布
のトナーを得るのには、非常な困難を伴なう。To make this kind of toner, it is generally made by melting coloring pigments such as carbon black, thermoplastic resin, additives, etc., and then mechanically crushing the molten mass to obtain toner with the desired particle size distribution. involves great difficulty.
（Ｃ）発明の目的
本発明は新しいタイプの顔料及びその造粒方法に関する
ものである。(C) Object of the Invention The present invention relates to a new type of pigment and a method for granulating the same.
製紙の充填剤について述べると、紙を構成する繊維の網
目構造を歩留り良く充填するには５μ程度の粒子径の揃
ったものが好ましい。Regarding fillers for paper manufacturing, fillers with uniform particle diameters of about 5 μm are preferred in order to fill the network structure of fibers constituting paper with a good yield.
本発明者らは、造粒方法を鋭意検討した結果、酵母菌が
３〜６μの非円状等のほべ゛均一の粒子径を持つのに目
をつけ、これを核にして上記目的に合った顔料の造粒を
行おうとするものである。なお、この方法はＰＰＣトナ
ーの造粒等にも応用が可能である。As a result of intensive study on granulation methods, the present inventors noticed that yeast bacteria have a non-circular and generally uniform particle size of 3 to 6 microns, and used this as a core to achieve the above purpose. The aim is to granulate pigments that match each other. Note that this method can also be applied to granulation of PPC toner.
（Ｄ）発明の構成
本発明は酵母菌の周囲に微粒子粉体を付着させた酵母菌
顔料とその造粒方法であり、この方法は次の過程より成
る。(D) Structure of the Invention The present invention is a yeast pigment in which fine powder particles are attached around yeast bacteria, and a method for granulating the same, and this method consists of the following steps.
即ち ■ 酵母菌の分散過程 ■ 微粒子顔料の分散過程 ■ 親水性溶媒の存在下で■、■の混合過程である。That is, ■ Yeast dispersion process ■ Dispersion process of fine particle pigments ■ This is the mixing process of ■ and ■ in the presence of a hydrophilic solvent.
本発明で使用される酵母菌とは、出芽もしくは***によ
り増殖する微生物の総称であるが、分類として有性生殖
を行なう有胞子酵母とそうでない無胞子酵母とに二大別
され、ともに真菌間に属する。Yeast used in the present invention is a general term for microorganisms that proliferate by budding or fission, but it is divided into two categories: spore-bearing yeast that reproduce sexually and non-spore yeast that do not. belongs to
前者は子のう菌綱原始子のう菌目、エンドマイセタシ工
科［Ｅｎｄｏｍｙｃｅｔａｃｅａｅ］ 、後者は不完全
菌網、クリプトコツカシ工科［ｃｒｙｐｔｏｃｏｃｃａ
ｃｅａｅ ］に属する。The former belongs to the order Protoascomycota of the class Ascomycota and the family Endomycetaceae.
ceae].
上記酵母菌体を構成する成分を大別するとイ、主に細胞
壁を構成するグルカン、マンナン質を基材とした水不溶
性成分
口、主に細胞膜を構成するリン脂質成分ハ、水、もしく
は極性溶媒に可溶性の酵素及びタンパク貿成分
に分けられ、これらは酵母の種類に応じ異なった配分を
取るが、本発明で用いられる酵母菌は組成の如何を問わ
ないものである。また、酵母菌は増殖機能の有無、すな
わち生きていても死んでいても本発明の効果には何ら影
響のないものである。The components that make up the above yeast cells can be roughly divided into (a) water-insoluble components mainly consisting of glucans and mannans that make up the cell wall; (c) phospholipid components that mainly make up the cell membrane; and (c) water or polar solvents. It is divided into soluble enzymes and protein components, and these components are distributed differently depending on the type of yeast, but the composition of the yeast used in the present invention does not matter. Moreover, whether or not yeast has a growth function, that is, whether it is alive or dead, has no effect on the effects of the present invention.
酵母菌の形状は酵母の種類により卵円形、球形、レモン
形、柱状、楕円形など各種の形態のものがあるが、球形
、楕円形、卵円形のごとき形態が好ましい。Yeast bacteria can have various shapes depending on the type of yeast, such as oval, spherical, lemon-shaped, columnar, and elliptical, but spherical, elliptical, and oval shapes are preferable.
酵母分散液を得る方法は、市販の酵母菌（パン酵母とし
てドライまたはペースト状態で市販されているもの等）
或いはビールの廃酵母等を水に分散させても良いし、或
いは炭素源、窒素源等の栄養素源を含む培地で酵母を増
殖させて得られたものをそのまま酵母分散液としても良
い。必要があればＤＨ調節、或いは防腐剤の添加も施さ
れる。The method for obtaining a yeast dispersion is to use commercially available yeast (such as those commercially available as baker's yeast in dry or paste form).
Alternatively, waste beer yeast or the like may be dispersed in water, or a yeast dispersion obtained by growing yeast in a medium containing a nutrient source such as a carbon source and a nitrogen source may be used as it is. If necessary, DH adjustment or preservatives may be added.
またこれに親水性溶媒を添加することも出来る。Moreover, a hydrophilic solvent can also be added to this.
酵母分散液中の酵母菌濃度（乾燥固形分濃度）は特に限
定はされないが、１０〜３０％（Ｗ／Ｗ）が望ましい。The yeast concentration (dry solid content concentration) in the yeast dispersion is not particularly limited, but is preferably 10 to 30% (W/W).
この範囲以下では生産効率が低下する傾向があり、また
、３０％以上になると、急激に分散液の粘度上昇が伴う
場合がある。Below this range, production efficiency tends to decrease, and when it exceeds 30%, the viscosity of the dispersion may suddenly increase.
微粒子顔料の分散液を得る方法は、微粒子粉体と水とを
混合し回転式攪拌機等で良く分散する。A method for obtaining a dispersion of the fine particle pigment is to mix the fine particle powder and water and disperse the mixture well using a rotary stirrer or the like.
この場合必要に応じ分散剤を使用することも出来る。ま
たこれに親水性溶媒を添加することも出来る。In this case, a dispersant may be used if necessary. Moreover, a hydrophilic solvent can also be added to this.
微粒子粉体としては、
Ａ、水または親水性の有機溶媒を含む水溶液に分散し易
いもの
Ｂ、平均粒子径が１μ以下であること
Ｃ９粒子径の分布がは寸均−であること等の特性が要求
される。The fine particle powder has characteristics such as A. It is easily dispersible in water or an aqueous solution containing a hydrophilic organic solvent. B. The average particle size is 1 μ or less. C9. The particle size distribution is uniform. is required.
この目的に使用され得る微粒子粉体としては、酸化チタ
ン、カオリン、炭酸カルシウム、シリカ、水酸化アルミ
ニウム、尿素ホルマリン樹脂、カーボンブラック等が挙
げられる。Particulate powders that can be used for this purpose include titanium oxide, kaolin, calcium carbonate, silica, aluminum hydroxide, urea-formalin resin, carbon black, and the like.
なお、このような粉体を効率良く酵母菌に付着させるた
め、天然もしくは合成樹脂等添加物の使用も可能である
。In addition, in order to efficiently attach such powder to yeast, it is also possible to use additives such as natural or synthetic resins.
親水性溶媒は、酵母菌表面に微粒子粉体を付着させるの
に必要である。本発明に使用され得る親水性溶媒として
は
（ａ）炭素数１〜３の低級アルコール類（ｂ）アセトン
等ケトン類
（Ｃ）エチレングリコール等多価アルコール類等が挙げ
られる。A hydrophilic solvent is necessary to attach the particulate powder to the yeast surface. Hydrophilic solvents that can be used in the present invention include (a) lower alcohols having 1 to 3 carbon atoms, (b) ketones such as acetone, and (C) polyhydric alcohols such as ethylene glycol.
これらの溶媒は、１〜４０％、好ましくは３〜２０％水
性溶液になるようにして用いられる。These solvents are used to give a 1-40% aqueous solution, preferably a 3-20% aqueous solution.
酵母分散液、微粒子粉体分散液、親水性溶媒を含む水性
溶液は一つの容器の中で混合し回転式攪拌機等により混
合攪拌を続けると、微粒子粉体が酵母菌の周囲に付着し
てくる。When an aqueous solution containing a yeast dispersion, a fine particle powder dispersion, and a hydrophilic solvent are mixed in one container and mixed and stirred using a rotary stirrer, etc., the fine particle powder will adhere to the surroundings of the yeast bacteria. .
酵母菌と微粒子粉体の比率は、粉体の形状、大きさ、使
用目的等により異なるが、重量比で１：０．２〜１：１
０好ましくは１：０．５〜１：５が好ましい。The ratio of yeast to fine powder varies depending on the shape, size, purpose of use, etc. of the powder, but the weight ratio is 1:0.2 to 1:1.
0, preferably 1:0.5 to 1:5.
またこの方法は、必ずしも高温、特別なＩＩ域等は必要
なく、比較的短時間に造粒が行われることもその特徴と
して上げられる。Another feature of this method is that it does not necessarily require high temperatures, special II ranges, etc., and granulation can be carried out in a relatively short time.
このようにして得られた酵母菌顔料は、卵内状等の形の
酵母園側々の粒子を核として同様の形に造粒されている
。これは、成る特定の大きさの粉体を必要とする分野、
たとえば製紙工程の充填、塗工、或いはＰＰＣ用のトナ
ーの造粒等に非常に有効に用いられる。The yeast pigment thus obtained is granulated into a similar shape using particles on the sides of the yeast garden in the shape of an oval or the like as cores. This consists of areas that require powder of a specific size,
For example, it is very effectively used for filling and coating in paper manufacturing processes, or for granulating toner for PPC.
（Ｅ）実施例及び参考例
実施例及び参考例によって本発明を更に詳しく説明する
。実施例及び参考例等に示された酵母菌重量は全て乾燥
脱水状態（菌体内、菌体外とも）での重量部数を表わす
。また粉体等のそれも重量部を表わす。(E) Examples and Reference Examples The present invention will be explained in more detail by Examples and Reference Examples. All yeast weights shown in Examples, Reference Examples, etc. represent the number of parts by weight in a dry and dehydrated state (both inside and outside the cells). In addition, parts such as powders are also expressed in parts by weight.
実施例−１
市販の酸化チタンＷ−１０（６原産業（株）製粒子径０
．２〜０．３μ＞１００部と水１２０部を容器に取り、
回転式攪拌機を用いて混合分散した。Example-1 Commercially available titanium oxide W-10 (manufactured by 6 Hara Sangyo Co., Ltd., particle size 0)
．． Take 2~0.3μ>100 parts and 120 parts of water in a container,
The mixture was mixed and dispersed using a rotary stirrer.
次に市販のパン酵母（オリエンタル酵母（株）製生イー
スト、サツ力ロマイセスセレビッシェ（ＳａＣＣｈａｒ
ｏｌｌｌＶＣｅＳ ＣｅｒｅＶｉＳｉａｅ） ５０部を
含む水分散液２５０部（菌体濃度２０％）をつくった。Next, commercially available baker's yeast (Oriental Yeast Co., Ltd. yeast), Satsuromyces cerevisiae (SaCChar
250 parts of an aqueous dispersion (20% bacterial cell concentration) containing 50 parts of C. olllVCeS CereViSiae) was prepared.
これに上記酸化チタン水分散液を添加し回転式攪拌機を
用いて均一に混合したのち、エチルアルコールを５０部
添加し、約１時間混合攪拌を続は酵母菌顔料を得た。こ
の酵母菌顔料を乾燥し電子顕微鏡で観察すると、図１に
示すように個々の菌体の表面に酸化チタンの微粒子が一
様に付着している状態が見られた。The titanium oxide aqueous dispersion was added thereto and mixed uniformly using a rotary stirrer, then 50 parts of ethyl alcohol was added and the mixture was mixed and stirred for about 1 hour to obtain a yeast pigment. When this yeast pigment was dried and observed under an electron microscope, it was found that fine particles of titanium oxide were uniformly attached to the surface of each bacterial cell, as shown in FIG.
実施例−２
市販の炭酸カルシウム白艶華ＰＸ（白石工業（株）製、
粒子径約０．１μ、固形分５０％のペースト）１５０部
に５０部の水を添加し良く混合した。Example-2 Commercially available calcium carbonate Hakuenka PX (manufactured by Shiroishi Kogyo Co., Ltd.)
50 parts of water was added to 150 parts of paste (particle size: about 0.1 μm, solid content: 50%) and mixed well.
次に市販のパン酵母（オリエンタル酵母（株）製生イー
スト、サツ力ロマイセスセレビッシエ（Ｓａｃｃｈａｒ
ｏｍｙｃｅｓ ｃｅｒｅｖｉｓｉａｅ） ５０部を含む
水分散液２５０部（菌体濃度２０％）をつくった。Next, commercially available baker's yeast (Oriental Yeast Co., Ltd. yeast, Saccharomyces cerevisiae)
omyces cerevisiae) 250 parts of an aqueous dispersion (20% bacterial cell concentration) was prepared.
これに上記炭酸カルシウム水分散液を添加し回転式攪拌
機を用いて均一に混合したのち、エチルアルコールを５
０部添加し約１時間混合攪拌を続は酵母菌顔料を得た。Add the above calcium carbonate aqueous dispersion to this and mix uniformly using a rotary stirrer, then add 55% of ethyl alcohol.
After adding 0 parts and mixing and stirring for about 1 hour, a yeast pigment was obtained.
この酵母菌顔料を乾燥し電子顕微鏡で観察すると、図２
に示すように個々の菌体の表面に炭酸カルシウムの微粒
子が一様に付着している状態が見られた。When this yeast pigment was dried and observed under an electron microscope, the results were as shown in Figure 2.
As shown in Figure 2, calcium carbonate particles were observed to be uniformly attached to the surface of each bacterial cell.
実施例−３
市販の酸化チタンＷ−’！Ｏ（６原産業（株）製粒子径
０．２〜０．３μ＞１００部と水１２０部を混合し分散
した。Example-3 Commercially available titanium oxide W-'! 100 parts of O (manufactured by 6 Hara Sangyo Co., Ltd., particle size: 0.2-0.3μ) and 120 parts of water were mixed and dispersed.
次にビール酵母（キリンビール（株）製生イースト、サ
ツ力ロマイセスカールスバーゲンシス（Ｓａｃｃｈａｒ
ｏｍｙｃｅｓ ｃａｒｌｓｂｅｒｇｅｎｓｉｓ） ５
Ｑ部を含む水分散液２５０部（菌体濃度２０％）をつく
った。Next, brewer's yeast (produced yeast produced by Kirin Brewery Co., Ltd.), Saccharomyces carlsbergensis (Sacchar
omyces carlsbergensis) 5
250 parts of an aqueous dispersion containing part Q (bacterial cell concentration 20%) was prepared.
これに上記酸化チタン水分散液を添加し回転式攪拌機を
用いて均一に混合分散したのち、エチルアルコールを５
０部添加し約１時間混合攪拌を続は酵母菌顔料を得た。After adding the titanium oxide aqueous dispersion to this and uniformly mixing and dispersing it using a rotary stirrer, 55% of ethyl alcohol was added.
After adding 0 parts and mixing and stirring for about 1 hour, a yeast pigment was obtained.
この酵母菌顔料を乾燥し電子顕微鏡で観察すると、個々
の菌体の表面に酸化チタンの微粒子が一様に付着してい
る状態が見られた。When this yeast pigment was dried and observed under an electron microscope, it was found that fine particles of titanium oxide were uniformly attached to the surface of each bacterial cell.
実施例−４
エチルアルコール５０部の代りにアセトン２０部を用い
た以外は実施例１と同様にして酸化チタンの微粒子によ
る酵母菌顔料を得た。Example 4 A yeast pigment made of fine particles of titanium oxide was obtained in the same manner as in Example 1 except that 20 parts of acetone was used instead of 50 parts of ethyl alcohol.
比較例−１
エチルアルコール５０部を除いた以外は実施例１と同様
にして酵母菌顔料を得るべく試みた。しかしながら、図
３に示すように酸化チタンの微粒子は菌体表面に均一な
付着はせず、単に混合しただけの状態に過き゛なかった
。Comparative Example 1 An attempt was made to obtain a yeast pigment in the same manner as in Example 1 except that 50 parts of ethyl alcohol was removed. However, as shown in FIG. 3, the titanium oxide fine particles did not adhere uniformly to the surface of the bacterial cells, but were simply mixed together.
比較例−２
市販の炭酸カルシウム、ニスカロン＃１００（三共製粉
（製）重質炭酸カルシウム、平均粒子径２μ、粒度分布
が広い＞１００部と水１００部を混合分散した。次に市
販のパン酵母（オリエンタル酵母（株）製生イースト、
サツ力ロマイセスセレビツシエ（Ｓａｃｃｈａｒｏｍｙ
ｃｅｓ ｃｅｒｅｖｉｓｉａｅ） ５０部を含む水分散
液２５０部（菌体濃度２０％）をつくった。Comparative Example-2 100 parts of commercially available calcium carbonate, Niscalon #100 (manufactured by Sankyo Seifun Co., Ltd.) heavy calcium carbonate, average particle size 2μ, wide particle size distribution>100 parts, and water were mixed and dispersed.Next, commercially available baker's yeast was mixed and dispersed. (Yeast produced by Oriental Yeast Co., Ltd.,
Saccharomyces cerevisiae
ces cerevisiae) 250 parts of an aqueous dispersion (20% bacterial cell concentration) was prepared.
これに上記炭酸カルシウム水分散液を添加し回転式攪拌
機を用いて均一に混合分散したのち、エチルアルコール
を５０部添加し混合攪拌を更に続けた。１時間後この酵
母菌を乾燥し電子顕微鏡で観察すると、図４に示すよう
に炭酸カルシウムは個々の菌体の表面には付着せず、単
に混合されている状態に過ぎなかった。The calcium carbonate aqueous dispersion was added thereto and mixed and dispersed uniformly using a rotary stirrer, then 50 parts of ethyl alcohol was added and mixing and stirring was further continued. After one hour, the yeast cells were dried and observed under an electron microscope. As shown in FIG. 4, calcium carbonate did not adhere to the surface of individual cells, but was simply mixed together.
比較例−３
実施例−１の方法で酸化チタン１５部、水を２０部とし
同様の操作で処理を行なった。これを乾燥し電子顕微鏡
で観察したところ、酸化チタンは個々の菌体の表面には
付着せず、単に混合されている状態に過ぎなかった。Comparative Example 3 A treatment was carried out in the same manner as in Example 1 using 15 parts of titanium oxide and 20 parts of water. When this was dried and observed under an electron microscope, it was found that titanium oxide did not adhere to the surface of individual bacterial cells, but was simply mixed together.
参考例−１
実施例１で得られた酵母菌顔料を用いて下記の配合によ
り手抄紙を作った。Reference Example-1 Using the yeast pigment obtained in Example 1, handmade paper was made according to the following formulation.
記
ＬＢＫＰ （広葉樹パルプ） ７０部ＮＢＫＰ （針
葉樹パルプ＞ ３０部（両者を混合し叩解度４３０
Ｃ３Ｆににする）酵母菌顔料（固形分換算） １５部
（酸化チタンとして１０部）
ニューホール１１００ 、 １部（ディック
バーキュレス（株）製ロジンエマルジョン）
硫酸バンド ３部
これらを混合して０．７％の濃度に調製し抄紙原料とし
、Ｊ Ｉ Ｓ Ｐ８２０９に準拠した手抄試験装置を用
いて抄紙し、常法により加圧脱水、乾燥、カレンダー処
理を行ない手抄紙を作った。この時の填料（酵母菌顔料
）の歩留りは約９０％に達した。LBKP (hardwood pulp) 70 parts NBKP (softwood pulp> 30 parts (both are mixed and the beating degree is 430)
(converted to C3F) Yeast pigment (solid content) 15 parts (10 parts as titanium oxide) Newhall 1100, 1 part (Rosin emulsion manufactured by Dick Bercules Co., Ltd.) Sulfuric acid band 3 parts Mix these to 0. This was prepared to a concentration of .7% and used as a raw material for papermaking, and was made into paper using a handsheet tester compliant with JIS P8209, followed by pressurized dehydration, drying, and calendering in a conventional manner to produce handmade paper. The yield of the filler (yeast pigment) at this time reached approximately 90%.
また、この手抄紙の不透明度は９１％であった。Moreover, the opacity of this handmade paper was 91%.
比較例−４
酵母菌顔料１５部（酸化チタンとして１０部）の代りに
、酸化チタンＷ−１０（６原産業（株）製）１０部を用
いた外は、参考例−１と同様の方法で手抄紙を作った。Comparative Example-4 Same method as Reference Example-1 except that 10 parts of titanium oxide W-10 (manufactured by 6 Hara Sangyo Co., Ltd.) was used instead of 15 parts of yeast pigment (10 parts as titanium oxide). I made handmade paper.
この時の酸化チタンの歩留りは、約７５％に過ぎなかっ
た。またその手抄紙の不透明度は８５％であった。The yield of titanium oxide at this time was only about 75%. The opacity of the handmade paper was 85%.
上記参考例及び比較例−４に見るように酵母菌顔料を紙
の填料として用いた場合、填料の歩留りおよび光学的特
性に非常に大きな効果をもたらすことがわかる。As seen in the above-mentioned Reference Example and Comparative Example-4, it can be seen that when yeast pigment is used as a paper filler, it has a very large effect on the yield and optical properties of the filler.
（Ｆ）発明の効果
実施例の結果より、酵母菌、微粒子粉体、親水性溶媒の
組み合せにより、酵母菌表面に微粒子粉体を均一に付着
させることが出来るようになった。(F) Effect of the Invention From the results of the Examples, it has become possible to uniformly adhere the fine particle powder to the surface of the yeast cell by the combination of the yeast bacteria, the fine particle powder, and the hydrophilic solvent.
その結果、製紙工程の填料への応用で填料歩留り、光学
的特性の向上等に見られるように、従来の技術では達成
できなかった新しい効果をもたらすことが可能になった
。As a result, it has become possible to bring about new effects that could not be achieved with conventional techniques, such as improved filler yield and optical properties when applied to fillers in the paper manufacturing process.
第１〜５図は、酵母菌の周囲の微粒子粉体の付着状態で
、図面に明瞭に表わすことは極めて困難なため写真を使
用。
第１図は、本発明の実施例１の酵母菌顔料の走査顕微鏡
写真。
第２図は、本発明の実施例２の酵母菌顔料の走査顕微鏡
写真。
第３図は、本発明の比較例１の状態の走査顕微鏡写真。
第４図は、本発明の比較例２の状態の走査顕微鏡写真。
第５図は、本発明の実施例、比較例に用いられているパ
ン酵母菌の走査顕微鏡写真。
第１図
第２ｒＩ！Ｊ
第３図
＊ｑｍFigures 1 to 5 show the state of adhesion of fine particles around yeast, which is extremely difficult to clearly represent in drawings, so photographs are used. FIG. 1 is a scanning micrograph of the yeast pigment of Example 1 of the present invention. FIG. 2 is a scanning micrograph of the yeast pigment of Example 2 of the present invention. FIG. 3 is a scanning micrograph of the state of Comparative Example 1 of the present invention. FIG. 4 is a scanning micrograph of the state of Comparative Example 2 of the present invention. FIG. 5 is a scanning micrograph of baker's yeast used in Examples and Comparative Examples of the present invention. Figure 1 2rI! J Figure 3 *qm
Claims (7)
特徴とする酵母菌顔料。(1) A yeast pigment characterized in that the fine particle powder is attached around yeast bacteria.
の範囲第１項記載の酵母菌顔料。(2) The yeast pigment according to claim 1, wherein the yeast is baker's yeast or brewer's yeast.
有色顔料である特許請求の範囲第１項または第２項記載
の酵母菌顔料。(3) The yeast pigment according to claim 1 or 2, wherein the fine particle powder is a white or colored pigment with an average particle diameter of 1 μm or less.
の存在下で混合分散することにより、該酵母菌の周囲に
該微粒子粉体を付着させて得る酵母菌顔料の造粒方法。(4) A method for granulating yeast pigment, which is obtained by mixing and dispersing yeast and fine particle powder in the presence of an aqueous solution containing a hydrophilic solvent, thereby adhering the fine particle powder around the yeast.
の範囲第４項記載の酵母菌顔料の造粒方法。(5) The method for granulating yeast pigment according to claim 4, wherein the yeast is baker's yeast or brewer's yeast.
ケトン類、多価アルコール類である特許請求の範囲第４
項または第５項記載の酵母菌顔料の造粒方法。(6) The hydrophilic solvent is a lower alcohol having 1 to 3 carbon atoms,
Claim 4 which is ketones and polyhydric alcohols
A method for granulating a yeast pigment according to item 1 or 5.
有色顔料である特許請求の範囲第４項または第５項また
は第６項記載の酵母菌顔料の造粒方法。(7) The method for granulating a yeast pigment according to claim 4, 5, or 6, wherein the fine particle powder is a white or colored pigment with an average particle diameter of 1 μm or less.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61162726A JPH0629370B2 (en) | 1986-07-09 | 1986-07-09 | Yeast pigment and granulation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61162726A JPH0629370B2 (en) | 1986-07-09 | 1986-07-09 | Yeast pigment and granulation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6317971A true JPS6317971A (en) | 1988-01-25 |
| JPH0629370B2 JPH0629370B2 (en) | 1994-04-20 |
Family
ID=15760107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61162726A Expired - Lifetime JPH0629370B2 (en) | 1986-07-09 | 1986-07-09 | Yeast pigment and granulation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0629370B2 (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51128478A (en) * | 1975-05-01 | 1976-11-09 | Sanraku Inc | Process for drying microbial cells |
| JPS615777A (en) * | 1984-05-11 | 1986-01-11 | ナビスコ ブランズ インコ−ポレ−テツド | Rehydratable instant active dry yeast |
-
1986
- 1986-07-09 JP JP61162726A patent/JPH0629370B2/en not_active Expired - Lifetime
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51128478A (en) * | 1975-05-01 | 1976-11-09 | Sanraku Inc | Process for drying microbial cells |
| JPS615777A (en) * | 1984-05-11 | 1986-01-11 | ナビスコ ブランズ インコ−ポレ−テツド | Rehydratable instant active dry yeast |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0629370B2 (en) | 1994-04-20 |
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