JPS6317874B2 - - Google Patents
Info
- Publication number
- JPS6317874B2 JPS6317874B2 JP53155949A JP15594978A JPS6317874B2 JP S6317874 B2 JPS6317874 B2 JP S6317874B2 JP 53155949 A JP53155949 A JP 53155949A JP 15594978 A JP15594978 A JP 15594978A JP S6317874 B2 JPS6317874 B2 JP S6317874B2
- Authority
- JP
- Japan
- Prior art keywords
- styrene
- emulsion
- maleic acid
- aqueous emulsion
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 claims description 77
- 239000000123 paper Substances 0.000 claims description 20
- 229920001577 copolymer Polymers 0.000 claims description 17
- 238000004078 waterproofing Methods 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 229920003051 synthetic elastomer Polymers 0.000 claims description 13
- 239000005061 synthetic rubber Substances 0.000 claims description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000000084 colloidal system Substances 0.000 claims description 11
- 239000012188 paraffin wax Substances 0.000 claims description 11
- 239000013032 Hydrocarbon resin Substances 0.000 claims description 10
- 238000004945 emulsification Methods 0.000 claims description 10
- 229920006270 hydrocarbon resin Polymers 0.000 claims description 10
- 230000001681 protective effect Effects 0.000 claims description 10
- 239000001993 wax Substances 0.000 claims description 10
- 150000001447 alkali salts Chemical class 0.000 claims description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 239000004568 cement Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 239000011505 plaster Substances 0.000 claims description 6
- 125000005907 alkyl ester group Chemical group 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000004753 textile Substances 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000005727 Friedel-Crafts reaction Methods 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000010907 mechanical stirring Methods 0.000 claims 2
- 241001385733 Aesculus indica Species 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 229910052602 gypsum Inorganic materials 0.000 description 10
- 239000010440 gypsum Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 238000000576 coating method Methods 0.000 description 8
- -1 alkylbenzene sulfonate Chemical class 0.000 description 7
- 239000004094 surface-active agent Substances 0.000 description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 239000003995 emulsifying agent Substances 0.000 description 6
- 230000035699 permeability Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 235000019441 ethanol Nutrition 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000005886 esterification reaction Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
- 229910052794 bromium Inorganic materials 0.000 description 2
- GXBDYVJMWRTUNT-UHFFFAOYSA-N buta-1,3-diene;2-methylprop-2-enoic acid Chemical compound C=CC=C.CC(=C)C(O)=O GXBDYVJMWRTUNT-UHFFFAOYSA-N 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000032050 esterification Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000010893 paper waste Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229920003169 water-soluble polymer Polymers 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DTCCVIYSGXONHU-CJHDCQNGSA-N (z)-2-(2-phenylethenyl)but-2-enedioic acid Chemical compound OC(=O)\C=C(C(O)=O)\C=CC1=CC=CC=C1 DTCCVIYSGXONHU-CJHDCQNGSA-N 0.000 description 1
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000008387 emulsifying waxe Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- VRQWWCJWSIOWHG-UHFFFAOYSA-J octadecanoate;zirconium(4+) Chemical compound [Zr+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O VRQWWCJWSIOWHG-UHFFFAOYSA-J 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Landscapes
- Paper (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Description
この発明は紙、繊維、セメント製品および石膏
製品の防湿、防水剤に適した水性エマルジヨンの
製造法に関し、特に(1)ワツクス類またはパラフイ
ン類の炭化水素をスチレン−マレイン酸共重合体
のアルカリ塩またはスチレン−マレイン酸共重合
体部分アルキルエステルのアルカリ塩（以下、ス
チレン−マレイン酸共重合体類という。）からな
る群から選択される保護コロイド水溶液の存在下
に水中に強制乳化する水性エマルジヨンの製造
法、(2)上記(1)で得られた水性エマルジヨンに合成
ゴムエマルジヨンを添加する水性エマルジヨンの
製造法および(3)合成炭化水素樹脂、ワツクス類ま
たはパラフイン類の炭化水素をスチレン−マレイ
ン酸共重合体類保護コロイドの存在下に水中に強
制乳化して得られた水性エマルジヨンに合成ゴム
エマルジヨンを添加する水性エマルジヨンの製造
法に関している。
従来、炭化水素樹脂、ワツクスおよび脂肪酸の
水性エマルジヨンは紙、繊維の撥水、防水剤また
建築材料の耐水、防止剤として広く使用されてき
た。しかし、この水性エマルジヨンはその製造に
際し多量の界面活性剤を用いる必要があつた。界
面活性剤の存在は、その固有の性質である親水性
に起因して水性エマルジヨンの撥水、防水剤とし
ての性質に悪影響をおよぼし、防水剤として主体
をなす炭化水素系化合物の性能を十分に発揮でき
なかつた。
この発明は界面活性剤を用いることなく、機械
的手段によりワツクス類またはパラフイン類の炭
化水素をスチレン−マレイン酸共重合体類の保護
コロイドの存在下に水中に予備乳化し、引き続き
高温で強制乳化してから急冷する水性エマルジヨ
ンの製造法、上記のようにして得られた水性エマ
ルジヨンに合成ゴムエマルジヨンを添加する水性
エマルジヨンの製造法および界面活性剤を用いる
ことなく機械的手段により合成炭化水素樹脂、ワ
ツクス類またはパラフイン類の炭化水素をスチレ
ン−マレイン酸共重合体類の保護コロイドの存在
下に水中に予備乳化し、引き続き高温で強制乳化
してから急冷して得られた水性エマルジヨンに合
成ゴムエマルジヨンを添加する水性エマルジヨン
の製造法を提供する。
この発明で使用するスチレン−マレイン酸共重
合体類はワツクス類等とは単に撹拌混合しただけ
では乳化しない。このため高圧下に強制乳化して
いる。
この発明で得られる水性エマルジヨンは繊維、
紙、特に段ボール用ライナー紙に塗布して撥水、
防水性を与える目的およびセメントおよび石膏製
品、特に石膏ボード板の製造の〓練時に添加して
防水、耐水性を製品に与える目的で使用される。
段ボール製造の貼合せ工程では約160〜180℃の
高温に遭遇するので、従来の水性エマルジヨン防
水剤は界面活性剤に基因する熱劣化がしばしば認
められた。しかし、この発明による水性エマルジ
ヨンではこのような熱劣化は認められず、さらに
塗布面の滑り性も改善されている。この発明で得
た水性エマルジヨンを防湿剤として使用すれば、
得らる紙の透湿性は塗布量にもよるが1/2ないし
１／２０に低下できる。また損紙の回収も容易に実施
できる特徴を有している。
一般に石膏製品の耐水処理に際しては、アルキ
ルベンゼンスルホン酸塩系界面活性剤を発泡剤と
して併用している。従来の耐水剤では泡の状態を
不均一にしたり、石膏の硬化速度の低下および製
品強度の低下をもたらす等の欠点があつた。この
発明による水性エマルジヨンは石膏製品に使用し
ても上記の欠点は認められなかつた。
パラフイン、ワツクス類としてはパラフインワ
ツクス、酸化パラフイン、ポリエチレンワツク
ス、モンタンロウ、カルナウバロウ、マイクロク
リスタリンワツクス等がある。
脂肪酸としてはステアリン酸およびオレイン酸
のような高級脂肪酸、またその金属石鹸としては
カルシウム塩、マグネシウム塩、亜鉛塩、アルミ
ニウム塩およびジルコニウム塩が挙げられる。
この発明で用いる合成炭化水素樹脂としはナフ
サ分解時に生成する沸点範囲−20ないし250℃の
C5〜C9留分をフリーデルクラフト反応により重
合して得た軟化点が常温の液状物から約150℃の
固体までのものがある。
炭化水素樹脂の変性に用いる不飽和カルボン酸
としては、例えばマレイン酸、無水マレイン酸、
フマール酸およびイタコン酸のようなα，β−不
飽和多塩基酸ならびにアクリル酸およびメタクリ
ル酸のような不飽和モノカルボン酸があり、炭化
水素樹脂と混合し180〜220℃で加熱反応させて附
加物を得る。
エステル化に用いるアルコールとしては、メチ
ルアルコール、エチルアルコール、プロピルアル
コール、オクチルアルコール、セチルアルコール
およびステアリルアルコールのような一価アルコ
ール、エチレングリコール、プロピレングリコー
ルおよびブチレングリコールのような二価アルコ
ール、それ以外にグリセリンおよびペンタエリス
リトールのような多価アルコールがあり、エステ
ル化反応は180〜220℃で不飽和酸附加物とアルコ
ールとを加熱して行はれ、エステル化度はハーフ
エステルまでである。
保護コロイドとして用いる水溶性高分子化合物
としてはスチレン−マレイン酸共重合体類が用い
られ、分子量1000〜5000の共重合体の無機または
有機アルカリ塩が好ましい。アルカリとしては苛
性カリ、苛性ソーダ、アンモニア、モルホリンお
よびジメチルアミン等が用いられ、特に苛性カリ
が好ましい。
特にスチレン−マレイン酸共重合体またはその
アルキルエステルの塩を保護コロイドとして用い
た水性エマルジヨンをセメントまたは石膏製品の
防水剤として使用すると、カルシウムイオンと反
応して水不溶性のカルシウム塩を形成する。この
結果処理製品の耐水性は著るしく改善される。さ
らにスチレン−マレイン酸共重合体樹脂の高硬度
のために処理製品の曲げ強度も向上する。
この発明で用いる合成ゴムエマルジヨンとして
は、ブタジエン系ゴム、例えばスチレン−ブタジ
エン系、アクリロニトルブタジエン系およびメタ
クリレート−ブタジエン系ゴムのエマルジヨンが
ある。
原料の使用割合は、炭化水素80〜97重量部およ
びスチレン−マレイン酸共重合体塩20〜３重量部
を用いる。所定量の原料を混合、溶融し、保護コ
ロイド用高分子化合物の水溶液に添加し、約50〜
200℃で高剪断力の強力撹拌機を用い、必要あれ
ば加圧下に予備乳化する。引き続き100〜500Kg／
cm2、好ましくは200〜300Kg／cm2の圧力下にピスト
ン型高圧乳化機またはコロイドミルを少なくとも
１回通過させて強制乳化を行い、急冷して所望の
微細粒子の水性エマルジヨンを得る。このエマル
ジヨンは約40％の高濃度で得られる。
このようにして得られた水性エマルジヨンに対
し合成ゴムエマルジヨンを混合するが、その量は
最終エマルジヨンの固形分の10〜50％がゴムエマ
ルジヨン粒子となるように選択する。
さらにこの発明の水性エマルジヨンにおいて、
合成炭化水素樹脂を用いる場合の原料の割合は、
合成炭化水素樹脂３〜80部、好ましくは５〜50
部、炭化水素92〜20部、好ましくは90〜60部およ
び水溶性高分子化合物２〜20部、好ましくは５〜
15部を前記のように予備乳化および強制乳化す
る。次いで得られる水性エマルジヨンに対し最終
エマルジヨン中の合成ゴム固形分が３〜70％、好
ましくは５〜50％になるように合成ゴムエマルジ
ヨンを混合する。
合成ゴムを含む水性エマルジヨンは、ゴムの被
膜形成性およびその弾性に基づき処理紙、セメン
トまたは石膏製品の耐水、防水性ならびに曲げ強
度をさらに改善することができる。
この発明により製造される水性エマルジヨン
は、紙および繊維特に段ボールライナーに塗布し
て防湿、防水性を改善することができ、塗布方法
としてはロールコート、ブラツシユコート、デイ
ツピング等公知の任意の方法が用いられる。また
石膏製品、特に石膏ボード板の製造時に用水に水
性エマルジヨンを添加して石膏を〓練して製品の
防水、耐水性を向上できる。したがつて、得られ
る石膏ボード板は風呂場、洗面所、台所等の水を
使用する場所にも使用することができる。
この発明を次の実施例によりさらに詳細に説明
する。
実施例 １
分散剤の製造
スチレン−マレイン酸共重合体モノメチルエス
テル100部、苛性カリ20部および水1800部を撹拌
機付乳化釜に仕込み、60℃で３時間で溶解して分
散剤溶液を得た。
水性エマルジヨンの製造
融点160〓のパラフインワツクス50部およびポ
リエチレンワツクス50部を140℃で混合、溶融し
た。一方、上記の分散剤溶液をオートクレーブ中
で140℃に加熱した。融融物と分散剤溶液とを固
形分が95：５の割合で混合し、予備乳化を行つ
た。次いでピストン型高圧乳化機を用い400Kg／
cm2の圧力下で通過させ45％濃度のエマルジヨンを
得た。
実施例 ２
融点125〓のパラフインワツクス100部を90℃で
溶融し、これと実施例１の分散剤溶液（60℃）と
を固形分90：10の割合で混合、撹拌して予備乳化
を行つた。次いでピストン型高圧乳化機を用い
200Kg／cm2の圧力下で２回通過させ40％濃度の水
性エマルジヨンを得た。
性能試験
上記実施例で得た水性エマルジヨンの石膏製品
に対する防水効果を試験した。
試験方法
原料：β型半水石膏
水ネリ比：75％
防水剤添加量：２％、３％、４％（固型分）
テストピース：20mm×20mm×80mm
乾燥法：室温２時間および50℃で24時間
吸水率（％）＝（Ｂ−Ａ）／Ａ×100
Ａ：50℃で24時間乾燥後のテストピース重量
Ｂ：25℃の水に所定時間浸漬後のテストピース
重量
測定した吸水率を次表に示す。
This invention relates to a method for producing an aqueous emulsion suitable as a moisture-proofing and waterproofing agent for paper, fibers, cement products, and gypsum products. or an aqueous emulsion force-emulsified in water in the presence of an aqueous solution of a protective colloid selected from the group consisting of alkali salts of partial alkyl esters of styrene-maleic acid copolymers (hereinafter referred to as styrene-maleic acid copolymers). (2) A method for producing an aqueous emulsion in which a synthetic rubber emulsion is added to the aqueous emulsion obtained in (1) above, and (3) A method for producing an aqueous emulsion by adding a synthetic rubber emulsion to the aqueous emulsion obtained in (1) above. The present invention relates to a method for producing an aqueous emulsion in which a synthetic rubber emulsion is added to an aqueous emulsion obtained by forced emulsification in water in the presence of a polymeric protective colloid. Hitherto, aqueous emulsions of hydrocarbon resins, waxes, and fatty acids have been widely used as water-repellent and waterproof agents for paper and textiles, and as waterproofing and waterproofing agents for building materials. However, this aqueous emulsion required the use of a large amount of surfactant during its production. The presence of surfactants has a negative effect on the water repellency and waterproofing properties of aqueous emulsions due to their inherent hydrophilic properties, and the presence of surfactants has a negative effect on the water repellency and waterproofing properties of aqueous emulsions, making it difficult to fully utilize the performance of hydrocarbon compounds, which are the main component of waterproofing agents. I couldn't perform. This invention involves pre-emulsifying wax or paraffin hydrocarbons in water in the presence of a protective colloid of styrene-maleic acid copolymers by mechanical means without using a surfactant, and then force-emulsifying them at high temperatures. A method for producing an aqueous emulsion in which a synthetic rubber emulsion is added to the aqueous emulsion obtained as described above, and a method for producing an aqueous emulsion by adding a synthetic rubber emulsion to the aqueous emulsion obtained as described above, and a method for producing a synthetic hydrocarbon resin or wax by mechanical means without using a surfactant. Synthetic rubber emulsion is added to the aqueous emulsion obtained by pre-emulsifying hydrocarbons such as or paraffins in water in the presence of a protective colloid of styrene-maleic acid copolymers, followed by forced emulsification at high temperature, and then quenching. A method for producing an aqueous emulsion is provided. The styrene-maleic acid copolymers used in this invention do not emulsify with waxes or the like simply by stirring and mixing. For this reason, it is forcibly emulsified under high pressure. The aqueous emulsion obtained by this invention is a fiber,
Apply to paper, especially cardboard liner paper, to make it water repellent.
It is used for the purpose of imparting waterproofness and to impart waterproofness and water resistance to cement and gypsum products, especially when added during mixing in the manufacture of gypsum board boards. Since high temperatures of about 160 to 180°C are encountered in the lamination process of corrugated board manufacturing, conventional water-based emulsion waterproofing agents often suffer from thermal deterioration due to surfactants. However, in the aqueous emulsion according to the present invention, such thermal deterioration is not observed, and the slipperiness of the coated surface is also improved. If the aqueous emulsion obtained in this invention is used as a moisture-proofing agent,
The moisture permeability of the resulting paper can be reduced to 1/2 to 1/20, depending on the amount of coating. It also has the feature of making it easy to collect waste paper. Generally, when waterproofing gypsum products, an alkylbenzene sulfonate surfactant is used as a foaming agent. Conventional waterproofing agents have disadvantages such as making the foam non-uniform, slowing down the curing speed of plaster, and reducing product strength. The aqueous emulsion according to the invention did not exhibit the above-mentioned drawbacks when used in gypsum products. Examples of paraffin and waxes include paraffin wax, oxidized paraffin, polyethylene wax, montan wax, carnauba wax, and microcrystalline wax. Fatty acids include higher fatty acids such as stearic acid and oleic acid, and metal soaps thereof include calcium, magnesium, zinc, aluminum and zirconium salts. The synthetic hydrocarbon resin used in this invention is produced during naphtha decomposition and has a boiling point range of -20 to 250℃.
There are products obtained by polymerizing C 5 to C 9 fractions by Friedel-Crafts reaction that have a softening point ranging from a liquid at room temperature to a solid at about 150°C. Examples of unsaturated carboxylic acids used for modifying hydrocarbon resins include maleic acid, maleic anhydride,
There are α,β-unsaturated polybasic acids such as fumaric acid and itaconic acid, and unsaturated monocarboxylic acids such as acrylic acid and methacrylic acid, which are added by mixing with hydrocarbon resin and heating reaction at 180 to 220°C. get something Alcohols used for esterification include monohydric alcohols such as methyl alcohol, ethyl alcohol, propyl alcohol, octyl alcohol, cetyl alcohol and stearyl alcohol, dihydric alcohols such as ethylene glycol, propylene glycol and butylene glycol, and others. There are polyhydric alcohols such as glycerin and pentaerythritol, and the esterification reaction is carried out by heating the unsaturated acid adduct and alcohol at 180-220°C, and the degree of esterification is up to half ester. Styrene-maleic acid copolymers are used as the water-soluble polymer compound used as the protective colloid, and inorganic or organic alkali salts of copolymers having a molecular weight of 1,000 to 5,000 are preferred. As the alkali, caustic potash, caustic soda, ammonia, morpholine, dimethylamine, etc. are used, and caustic potash is particularly preferred. In particular, when aqueous emulsions using styrene-maleic acid copolymers or salts of their alkyl esters as protective colloids are used as waterproofing agents for cement or plaster products, they react with calcium ions to form water-insoluble calcium salts. As a result, the water resistance of the treated product is significantly improved. Furthermore, the high hardness of the styrene-maleic acid copolymer resin also improves the flexural strength of the treated product. The synthetic rubber emulsions used in this invention include emulsions of butadiene rubbers, such as styrene-butadiene rubbers, acrylonitrobutadiene rubbers, and methacrylate-butadiene rubbers. The proportions of the raw materials used are 80 to 97 parts by weight of the hydrocarbon and 20 to 3 parts by weight of the styrene-maleic acid copolymer salt. A predetermined amount of raw materials are mixed, melted, and added to an aqueous solution of a polymer compound for protective colloid.
Pre-emulsify at 200°C using a powerful stirrer with high shear force and under pressure if necessary. Continue 100-500Kg/
Forced emulsification is carried out by passing at least once through a piston-type high-pressure emulsifier or a colloid mill under a pressure of 200 to 300 Kg/cm 2 , preferably 200 to 300 Kg/cm 2 , and then quenched to obtain the desired fine-particle aqueous emulsion. This emulsion is obtained at a high concentration of about 40%. A synthetic rubber emulsion is mixed into the aqueous emulsion thus obtained, the amount of which is selected so that 10 to 50% of the solid content of the final emulsion is rubber emulsion particles. Furthermore, in the aqueous emulsion of this invention,
The proportion of raw materials when using synthetic hydrocarbon resin is
3 to 80 parts of synthetic hydrocarbon resin, preferably 5 to 50 parts
parts, 92 to 20 parts of hydrocarbon, preferably 90 to 60 parts, and 2 to 20 parts, preferably 5 to 60 parts of water-soluble polymer compound.
Pre-emulsify and force emulsify 15 parts as above. Next, a synthetic rubber emulsion is mixed into the resulting aqueous emulsion so that the final emulsion has a synthetic rubber solid content of 3 to 70%, preferably 5 to 50%. Aqueous emulsions containing synthetic rubber can further improve the water resistance, water resistance and flexural strength of treated paper, cement or plaster products due to the film-forming properties of the rubber and its elasticity. The aqueous emulsion produced according to the present invention can be applied to paper and fibers, especially corrugated board liners, to improve their moisture-proofing and waterproofing properties, and any known coating methods such as roll coating, brush coating, and dipping can be used. used. Furthermore, when manufacturing gypsum products, especially gypsum board boards, an aqueous emulsion can be added to the water used to knead the gypsum to improve the waterproofness and water resistance of the product. Therefore, the obtained gypsum board board can also be used in places where water is used, such as bathrooms, washrooms, and kitchens. This invention will be explained in more detail by the following examples. Example 1 Production of dispersant 100 parts of styrene-maleic acid copolymer monomethyl ester, 20 parts of caustic potassium, and 1800 parts of water were placed in an emulsifying pot with a stirrer, and dissolved at 60°C for 3 hours to obtain a dispersant solution. . Production of aqueous emulsion 50 parts of paraffin wax with a melting point of 160㎓ and 50 parts of polyethylene wax were mixed and melted at 140°C. Meanwhile, the above dispersant solution was heated to 140°C in an autoclave. The melt and the dispersant solution were mixed at a solid content ratio of 95:5 to perform preliminary emulsification. Then, using a piston type high pressure emulsifier, 400Kg/
A 45% concentrated emulsion was obtained by passing under a pressure of cm 2 . Example 2 100 parts of paraffin wax with a melting point of 125〓 was melted at 90°C, and this and the dispersant solution of Example 1 (60°C) were mixed at a solid content ratio of 90:10 and stirred to pre-emulsify. I went. Next, using a piston type high pressure emulsifier
A 40% strength aqueous emulsion was obtained by passing it twice under a pressure of 200 Kg/cm 2 . Performance Test The water-based emulsion obtained in the above example was tested for its waterproofing effect on gypsum products. Test method Raw materials: β-type hemihydrate gypsum water-toner ratio: 75% Waterproofing agent addition amount: 2%, 3%, 4% (solid content) Test piece: 20 mm x 20 mm x 80 mm Drying method: 2 hours at room temperature and 50°C Water absorption rate (%) = (B-A)/A x 100 A: Weight of test piece after drying at 50℃ for 24 hours B: Weight of test piece after being immersed in water at 25℃ for a specified time Measured water absorption rate are shown in the table below.
【表】
実施例 ３
軟化点135〓のパラフインワツクス100部を95℃
で溶融し、これと実施例１の分散溶液（濃度５
％、70℃）222部とを混合して予備乳化した。次
いでピストン型乳化機を用い250Kg／cm2の圧力下
で２回弾過させ40℃以下に急冷させ345％濃度の
エマルジヨンを得た。
実施例 ４
実施例３で得た水性エマルジヨン260部と固形
分50％のスチレン−ブタジエンゴムラテツクス20
部とを混合して35.7濃度のエマルジヨンを得た。
実施例 ５
実施例３で得た水性エマルジヨン231部と固形
分50％のメチルメタクリレート−ブタジエンゴム
ラテツクス30部とを混合して38.3％濃度のエマル
ジヨンを得た。
性能試験
実施例３〜５で得た水性エマルジヨンの紙に対
する防湿効果を試験した。
原紙：60ｇ／m2クラフト紙
塗布方法：バーコーター
塗布量：20ｇ／m2の（エマルジヨンとして）
乾燥方法：熱風乾燥機で105℃、１分間透湿度試
験方法：JIS Z0208（1973）
測定した透湿度を次表に示す。
原紙 450ｇ／m2・24H
実施例３ 60.5ｇ／m2・24H
実施例４ 18.4ｇ／m2・24H
実施例５ 13.7ｇ／m2・24H
実施例 ６
軟化点120℃、臭素価30の合成炭化水素樹脂71
部と融点145〓のパラフインワツクス259部および
ステアリン酸アルミニウム40部をオートクレーブ
に仕込み1.5Kg／cm2の圧力下、120℃の温度にて混
合、溶融した後、スチレン−無水マレイン酸のカ
リウム塩30部、温水600部を加え混合し、同圧力
にて予備乳化を行つた。得られたエマルジヨンを
ピストン型高圧乳化機を用いて300Kg／cm2の圧力
下にて２回通し濃度40％の水性エマルジヨンを得
た。得られたエマルジヨン70部に固形分40％のス
チレン−ブタジエンゴムエマルジヨン30部を加え
混合した。
実施例 ７
軟化点60℃、臭素価55の合成炭化水素樹脂100
部、融点125〓のパラフインワツクス200部、酸価
20、軟化点103℃のポリエチレンワツクス50部お
よびステアリン酸ジルコニウム20部を混合、溶融
した後スチレン−マレイン酸共重合体のアンモニ
ウム塩30部および温水600部を加え予備乳化した。
得られるエマルジヨンをピストン型高圧乳化機を
用いて250Kg／cm2の圧力下で２回通し40％濃度の
水性エマルジヨンを得た。次に水性エマルジヨン
90部に固形分40％のメタクリレート−ブタジエン
ゴムエマルジヨン10部を添加、混合して安定な水
性エマルジヨンを得た。
実施例６〜７で得たエマルジヨンの紙に対する
防湿効果を試験した。
原紙：50ｇ／m2グラフト紙、
塗布方法：バーコーター
塗布量：20ｇ／m3（エマルジヨンとして）
乾燥方法：室温で24時間
透湿度試験方法：JIS Ｚ 0208（1973）測定した
透湿度を次表に示す。
原紙 350ｇ／m2・24H
実施例６ 30ｇ／m2・24H
実施例７ 25ｇ／m2・2H4
実施例６ 160ｇ／m2・24H
（但しゴムエマルジヨン無添加）
実施例３−６の透湿度は従来品（ポリエチレン
ラミネート紙）と同等の値であつた。尚、エマル
ジヨンを塗布した従来品は存在しなかつたので比
較できなかつた。また、ラミネート紙では損紙の
回収が不可能となるといつた欠点があるが、本発
明のエマルジヨンの塗布された紙は回収可能であ
つた。[Table] Example 3 100 parts of paraffin wax with a softening point of 135 was heated at 95°C.
This and the dispersion solution of Example 1 (concentration 5
%, 70°C) and pre-emulsified. Then, using a piston type emulsifier, the mixture was passed twice under a pressure of 250 kg/cm 2 and rapidly cooled to below 40° C. to obtain an emulsion with a concentration of 345%. Example 4 260 parts of the aqueous emulsion obtained in Example 3 and 20 parts of styrene-butadiene rubber latex with a solid content of 50%
An emulsion with a concentration of 35.7% was obtained by mixing 1 part with 35.7 parts. Example 5 231 parts of the aqueous emulsion obtained in Example 3 and 30 parts of methyl methacrylate-butadiene rubber latex with a solid content of 50% were mixed to obtain an emulsion with a concentration of 38.3%. Performance Test The moisture-proofing effect of the aqueous emulsions obtained in Examples 3 to 5 on paper was tested. Base paper: 60g/ m2 Kraft paper Coating method: Bar coater Coating amount: 20g/ m2 (as emulsion) Drying method: Hot air dryer at 105℃ for 1 minute Moisture permeability test Method: JIS Z0208 (1973) Measured permeability The humidity is shown in the table below. Base paper 450g/m 2・24H Example 3 60.5g/m 2・24H Example 4 18.4g/m 2・24H Example 5 13.7g/m 2・24H Example 6 Synthesis with a softening point of 120°C and a bromine number of 30 Hydrocarbon resin 71
259 parts of paraffin wax with a melting point of 145㎜ and 40 parts of aluminum stearate were placed in an autoclave, mixed and melted at a temperature of 120°C under a pressure of 1.5 kg/cm 2 , and then potassium salt of styrene-maleic anhydride was prepared. 30 parts and 600 parts of warm water were added and mixed, and preliminary emulsification was performed at the same pressure. The obtained emulsion was passed twice under a pressure of 300 kg/cm 2 using a piston-type high-pressure emulsifier to obtain an aqueous emulsion with a concentration of 40%. 30 parts of a styrene-butadiene rubber emulsion having a solid content of 40% was added to 70 parts of the obtained emulsion and mixed. Example 7 Synthetic hydrocarbon resin 100 with a softening point of 60°C and a bromine number of 55
200 parts of paraffin wax with a melting point of 125〓, acid value
20, 50 parts of polyethylene wax with a softening point of 103°C and 20 parts of zirconium stearate were mixed and melted, and then 30 parts of ammonium salt of styrene-maleic acid copolymer and 600 parts of hot water were added for pre-emulsification.
The resulting emulsion was passed twice under a pressure of 250 kg/cm 2 using a piston-type high-pressure emulsifier to obtain an aqueous emulsion with a concentration of 40%. Next, water-based emulsion
10 parts of methacrylate-butadiene rubber emulsion having a solid content of 40% was added to 90 parts and mixed to obtain a stable aqueous emulsion. The moisture-proofing effect of the emulsions obtained in Examples 6-7 on paper was tested. Base paper: 50g/ m2 graft paper, Coating method: Bar coater Coating amount: 20g/ m3 (as emulsion) Drying method: 24 hours at room temperature Moisture permeability test Method: JIS Z 0208 (1973) The measured moisture permeability is shown in the table below. Shown below. Base paper 350g/m 2・24H Example 6 30g/m 2・24H Example 7 25g/m 2・2H4 Example 6 160g/m 2・24H (no rubber emulsion added) The moisture permeability of Examples 3-6 was the same as before The value was equivalent to that of the product (polyethylene laminated paper). It should be noted that a comparison could not be made because there was no conventional product coated with emulsion. In addition, laminated paper has the disadvantage that waste paper cannot be recovered, but paper coated with the emulsion of the present invention could be recovered.
Claims (1)
スチレン−マレイン酸共重合体のアルカリ塩また
はスチレン−マレイン酸共重合体部分アルキルエ
ステルのアルカリ塩からなる群から選択される保
護コロイド水溶液と機械的攪はん下に予備乳化
し、引き続き高圧下に強制乳化することからな
る、紙、繊維、セメント製品および石膏製品の防
湿、防水剤として使用する水性エマルジヨンの製
造法。 ２ ワツクス類またはパラフイン類の炭化水素を
スチレン−マレイン酸共重合体のアルカリ塩また
はスチレン−マレイン酸共重合体部分アルキルエ
ステルのアルカリ塩からなる群から選択される保
護コロイド水溶液と機械的攪はん下に予備乳化
し、引き続き高圧下に強制乳化し、得られる水性
エマルジヨンに合成ゴムエマルジヨンを添加する
ことからなる、紙、繊維、セメント製品および石
膏製品の防湿、防水剤として使用する水性エマル
ジヨンの製造法。 ３ ナフサ分解時に生成する沸点範囲−20〜250
℃のC5〜C9留分をフリーデルクラフト反応によ
り重合して得た合成炭化水素樹脂、ワツクス類ま
たはパラフイン類の炭化水素をスチレン−マレイ
ン酸共重合体のアルカリ塩またはスチレン−マレ
イン酸共重合体部分アルキルエステルのアルカリ
塩からなる群から選択される保護コロイド水溶液
と機械的攪はん下に予備乳化し、引き続き高圧下
に強制乳化し、得られる水性エマルジヨンに合成
ゴムエマルジヨンを添加することからなる、紙、
繊維、セメント製品および石膏製品の防湿、防水
剤として使用する水性エマルジヨンの製造法。[Scope of Claims] 1 Hydrocarbons of waxes or paraffins are mixed into an aqueous solution of a protective colloid selected from the group consisting of an alkali salt of a styrene-maleic acid copolymer or an alkali salt of a partial alkyl ester of a styrene-maleic acid copolymer. A process for producing an aqueous emulsion for use as a moisture-proofing and waterproofing agent for paper, textiles, cement products and plaster products, comprising pre-emulsification under mechanical stirring and subsequent forced emulsification under high pressure. 2 Mechanically stirring a wax or paraffin hydrocarbon with an aqueous solution of a protective colloid selected from the group consisting of an alkali salt of a styrene-maleic acid copolymer or an alkali salt of a partial alkyl ester of a styrene-maleic acid copolymer. A method for producing an aqueous emulsion for use as a moisture-proofing and waterproofing agent for paper, textiles, cement products and plaster products, which comprises pre-emulsifying under pressure, followed by forced emulsification under high pressure, and adding a synthetic rubber emulsion to the resulting aqueous emulsion. . 3 Boiling point range produced during naphtha decomposition -20 to 250
Synthetic hydrocarbon resins, waxes, or paraffin hydrocarbons obtained by polymerizing C5 to C9 fractions at ℃ by Friedel-Crafts reaction are combined with alkali salts of styrene-maleic acid copolymers or styrene-maleic acid copolymers. Pre-emulsifying with an aqueous solution of a protective colloid selected from the group consisting of alkali salts of polymeric partial alkyl esters under mechanical stirring, followed by forced emulsification under high pressure, and adding a synthetic rubber emulsion to the resulting aqueous emulsion. Naru, paper,
Process for producing aqueous emulsions for use as moisture-proofing and waterproofing agents for textiles, cement products and plaster products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15594978A JPS5594983A (en) | 1978-12-18 | 1978-12-18 | Preparing water-proof aqueous emulsion |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15594978A JPS5594983A (en) | 1978-12-18 | 1978-12-18 | Preparing water-proof aqueous emulsion |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5594983A JPS5594983A (en) | 1980-07-18 |
| JPS6317874B2 true JPS6317874B2 (en) | 1988-04-15 |
Family
ID=15617041
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15594978A Granted JPS5594983A (en) | 1978-12-18 | 1978-12-18 | Preparing water-proof aqueous emulsion |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5594983A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004346239A (en) * | 2003-05-23 | 2004-12-09 | San Nopco Ltd | Wax-metallic soap composite emulsion dispersion |
| WO2014049625A1 (en) | 2012-09-28 | 2014-04-03 | Conser Spa | Continuous process for producing epichlorohydrin from glycerol |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6273993B1 (en) | 1992-07-01 | 2001-08-14 | Michelman, Inc. | Method of dispersing wax from a hot melt wax-coated paper |
| CN101565603A (en) * | 2009-05-22 | 2009-10-28 | 广西丰林木业集团股份有限公司 | Waterproof agent for fibreboard |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51111851A (en) * | 1975-02-27 | 1976-10-02 | Kiyoji Naruse | Aqueous emulsion of atactic polypropylene |
| JPS53131979A (en) * | 1977-04-22 | 1978-11-17 | Mitsubishi Chem Ind Ltd | Paraffin emulsion and its composition |
| JPS5420009A (en) * | 1977-07-15 | 1979-02-15 | Kiyoji Naruse | Aqueous dispersion compositions of wax and production thereof |
-
1978
- 1978-12-18 JP JP15594978A patent/JPS5594983A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS51111851A (en) * | 1975-02-27 | 1976-10-02 | Kiyoji Naruse | Aqueous emulsion of atactic polypropylene |
| JPS53131979A (en) * | 1977-04-22 | 1978-11-17 | Mitsubishi Chem Ind Ltd | Paraffin emulsion and its composition |
| JPS5420009A (en) * | 1977-07-15 | 1979-02-15 | Kiyoji Naruse | Aqueous dispersion compositions of wax and production thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004346239A (en) * | 2003-05-23 | 2004-12-09 | San Nopco Ltd | Wax-metallic soap composite emulsion dispersion |
| JP4528909B2 (en) * | 2003-05-23 | 2010-08-25 | サンノプコ株式会社 | Wax-metal soap composite emulsion dispersion |
| WO2014049625A1 (en) | 2012-09-28 | 2014-04-03 | Conser Spa | Continuous process for producing epichlorohydrin from glycerol |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5594983A (en) | 1980-07-18 |
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